ATE276263T1 - Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren - Google Patents

Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren

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Publication number
ATE276263T1
ATE276263T1 AT97939348T AT97939348T ATE276263T1 AT E276263 T1 ATE276263 T1 AT E276263T1 AT 97939348 T AT97939348 T AT 97939348T AT 97939348 T AT97939348 T AT 97939348T AT E276263 T1 ATE276263 T1 AT E276263T1
Authority
AT
Austria
Prior art keywords
group substituted
polymerization process
metal complexes
olefin polymerization
cyclopentadienyl group
Prior art date
Application number
AT97939348T
Other languages
English (en)
Inventor
Jerzy Klosin
William J Kruper Jr
Peter N Nickias
Jasson T Patton
David R Wilson
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE276263T1 publication Critical patent/ATE276263T1/de

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/02Cp or analog bridged to a non-Cp X anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT97939348T 1996-08-08 1997-07-28 Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren ATE276263T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08
US3481996P 1996-12-19 1996-12-19
PCT/US1997/013170 WO1998006727A1 (en) 1996-08-08 1997-07-28 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Publications (1)

Publication Number Publication Date
ATE276263T1 true ATE276263T1 (de) 2004-10-15

Family

ID=26697575

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97939348T ATE276263T1 (de) 1996-08-08 1997-07-28 Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren

Country Status (24)

Country Link
US (1) US6268444B1 (de)
EP (1) EP0923589B1 (de)
JP (1) JP3407074B2 (de)
KR (1) KR100528754B1 (de)
CN (1) CN1114609C (de)
AR (1) AR009035A1 (de)
AT (1) ATE276263T1 (de)
AU (1) AU719500B2 (de)
BR (1) BR9711124A (de)
CA (1) CA2262910C (de)
CO (1) CO4870708A1 (de)
CZ (1) CZ42399A3 (de)
DE (1) DE69730718T2 (de)
EG (1) EG21365A (de)
ES (1) ES2224266T3 (de)
HU (1) HUP9902581A3 (de)
ID (1) ID18004A (de)
MY (1) MY132554A (de)
NO (1) NO326005B1 (de)
NZ (1) NZ333878A (de)
SK (1) SK15399A3 (de)
TR (1) TR199900487T2 (de)
TW (1) TW455595B (de)
WO (1) WO1998006727A1 (de)

Families Citing this family (149)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5968337A (en) * 1996-04-18 1999-10-19 Battelle Memorial Institute Apparatus and method for constant flow oxidizing of organic materials
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
WO2002083754A1 (en) 2001-04-12 2002-10-24 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
WO2000001766A1 (en) 1998-07-01 2000-01-13 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
ES2356612T3 (es) 1998-11-02 2011-04-11 Dow Global Technologies Inc. Interpolímeros de etileno/alfa-olefina/dieno reo-fluidificantes y su preparación .
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
JP2002536451A (ja) * 1999-02-05 2002-10-29 ボウルダー・サイエンティフィック・カンパニー シリル化及びn‐シリル化された化合物の合成
CN1357012A (zh) * 1999-04-20 2002-07-03 英国石油化学品有限公司 延迟活性载体上的烯烃聚合催化剂组合物及其制备和使用方法
AU3902300A (en) 1999-04-29 2000-11-17 Dow Chemical Company, The Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
AU3764600A (en) * 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
DE60001557T2 (de) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland Metallkomplexe mit heteroatom-enthaltende brücke für olefinpolymerisationsverfahren
EP1102778B1 (de) 1999-06-04 2003-04-02 Basell Polyolefine GmbH Verfahren zur herstellung titankomplexen
EP1194431B1 (de) 1999-06-04 2005-06-22 Dow Global Technologies Inc. Borsubstituierte cyclopentadiene und metallkomplexe dieser liganden
DE19927766A1 (de) * 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
CA2393793C (en) * 1999-12-10 2009-09-29 Jerzy Klosin Substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1253158A1 (de) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituierte Gruppe 4-Metallkomplexe, Katalysatoren und Verfahren zur Olefinpolymerisation
US6825295B2 (en) * 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
ATE292148T1 (de) * 2000-01-18 2005-04-15 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
US6906160B2 (en) 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
US20050010039A1 (en) * 2002-03-14 2005-01-13 Graf David D Polycyclic fused heteroring compounds metal complexes and polymerization process
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
ATE402222T1 (de) 2002-10-17 2008-08-15 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US6927264B2 (en) * 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US7737205B2 (en) * 2003-07-28 2010-06-15 Dow Global Technologies Inc Thermoplastic vulcanizates and process to prepare them
US7531601B2 (en) 2003-08-19 2009-05-12 Dow Global Technologies, Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
WO2005092503A1 (en) * 2004-03-16 2005-10-06 Union Carbide Chemicals & Plastics Technology Corporation Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
AR048273A1 (es) 2004-03-17 2006-04-12 Dow Global Technologies Inc Composicion catalizadora que comprende un agente de enlace para la formacion de copolimeros de etileno
MXPA06010481A (es) 2004-03-17 2006-12-19 Dow Global Technologies Inc Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de multiples bloques de olefina superior.
SG151301A1 (en) 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation
US8273826B2 (en) 2006-03-15 2012-09-25 Dow Global Technologies Llc Impact modification of thermoplastics with ethylene/α-olefin interpolymers
EP1763542B1 (de) * 2004-06-16 2011-04-06 Dow Global Technologies Inc. Verfahren zur auswahl von polymerisationsmodifikatoren
JP4988568B2 (ja) * 2004-07-08 2012-08-01 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合触媒系およびその使用方法
US8093341B2 (en) * 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
EP1845101A4 (de) 2005-01-28 2010-02-24 Sumitomo Chemical Co Verfahren zur herstellung eines alkoxytitankomplexes
CN101142245B (zh) 2005-03-17 2012-08-08 陶氏环球技术有限责任公司 用于形成立体无规多嵌段共聚物的包含梭移剂的催化剂组合物
JP2008533276A (ja) 2005-03-17 2008-08-21 ダウ グローバル テクノロジーズ インコーポレイティド タクチック/アタクチックマルチブロックコポリマー形成用の可逆的移動剤を含む触媒組成物
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
ZA200707869B (en) 2005-03-17 2009-09-30 Dow Global Technologies Inc Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins
US8287949B2 (en) 2005-07-07 2012-10-16 Dow Global Technologies Inc. Aqueous dispersions
AR058449A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Copolimeros de bloque de olefina cataliticos via un agente de transferencia polimerizable
CA2622599A1 (en) * 2005-09-15 2007-03-29 Dow Global Technolgies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
EP1951511B1 (de) 2005-10-26 2018-09-12 Dow Global Technologies LLC Mehrlägige elastische artikel
US8785531B2 (en) * 2006-07-06 2014-07-22 Dow Global Technologies Llc Dispersions of olefin block copolymers
BRPI0714747A2 (pt) * 2006-09-06 2013-05-14 Dow Global Technologies Inc pano entrelaÇado , roupa , fibra apropriada para artigos tÊxteis , artigo entrelaÇado empenado e artigo entrelaÇado circular
US8476326B2 (en) * 2006-09-22 2013-07-02 Dow Global Technologies Llc Fibrillated polyolefin foam
WO2008057881A2 (en) * 2006-11-01 2008-05-15 Dow Global Technologies Inc. Polyurethane compositions and articles prepared therefrom, and methods for making the same
WO2008067538A2 (en) * 2006-11-30 2008-06-05 Dow Global Technologies Inc. Stretch fabrics with wrinkle resistance and garment
KR20090086422A (ko) * 2006-11-30 2009-08-12 다우 글로벌 테크놀로지스 인크. 고중량 신축성 포를 위한 올레핀 블록 조성물
BRPI0717715A2 (pt) * 2006-11-30 2013-10-22 Dow Global Technologies Inc Tecido e peça de vestuário
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8288470B2 (en) 2006-12-21 2012-10-16 Dow Global Technologies Llc Polyolefin compositions and articles prepared therefrom, and methods for making the same
TW200842215A (en) * 2007-01-16 2008-11-01 Dow Global Technologies Inc Cone dyed yarns of olefin block compositions
DE602008006667D1 (de) * 2007-01-16 2011-06-16 Dow Global Technologies Llc Farbfeste fasern und kleidungsstücke aus olefinblockzusammensetzungen
AU2008206334A1 (en) * 2007-01-16 2008-07-24 Dow Global Technologies Inc. Stretch fabrics and garments of olefin block polymers
US9006380B2 (en) * 2007-04-24 2015-04-14 Dow Global Technologies Llc Thermoforming, scratch-resistant, low gloss compositions comprising interpolymers of ethylene/α-olefins
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
ITMI20070878A1 (it) * 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ES2446294T3 (es) 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
KR20100041818A (ko) * 2007-07-09 2010-04-22 다우 글로벌 테크놀로지스 인크. 섬유에 적합한 올레핀 블럭 혼성중합체 조성물
EP2170604B1 (de) 2007-07-13 2019-05-15 Dow Global Technologies LLC Ethylen-/alpha-olefin interpolymere auf basis von harten blöcken mit niedriger kristallinität
WO2009012153A1 (en) * 2007-07-13 2009-01-22 Dow Global Technologies Inc. Viscosity index improver for lubricant compositions
JP5996162B2 (ja) 2007-07-13 2016-09-21 ダウ グローバル テクノロジーズ エルエルシー 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー
CN104212538A (zh) * 2007-07-13 2014-12-17 陶氏环球技术有限责任公司 润滑剂组合物的粘度指数改性剂
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
US20090105374A1 (en) * 2007-09-28 2009-04-23 Dow Global Technologies Inc. Thermoplastic olefin composition with improved heat distortion temperature
CN101883798A (zh) * 2007-12-05 2010-11-10 三井化学株式会社 共聚物橡胶、橡胶组合物和橡胶成形体
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
CN102015874B (zh) * 2008-02-29 2014-08-27 陶氏环球技术有限责任公司 包括乙烯/α-烯烃嵌段互聚物的取向膜
ES2959468T3 (es) 2008-06-18 2024-02-26 Dow Global Technologies Llc Procesos para controlar la incrustacion y mejorar las composiciones
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
CN102388092B (zh) 2009-02-25 2014-03-12 陶氏环球技术有限责任公司 制备包含乙烯/α-烯烃嵌段互聚物的泡沫制品的飞龙法
WO2010151433A1 (en) 2009-06-26 2010-12-29 Dow Global Technologies Inc. Process selectively polymerizing ethylene and catalyst therefor
KR101678247B1 (ko) 2009-07-28 2016-11-21 유니베이션 테크놀로지즈, 엘엘씨 지지된 기하학적 구속 촉매를 사용한 중합 방법
US8324416B2 (en) 2009-07-29 2012-12-04 Dow Global Technologies, Llc Multifunctional chain shuttling agents
CN102498133B (zh) 2009-07-29 2013-10-30 陶氏环球技术有限责任公司 双头基或多头基的链穿梭剂以及它们用于制备嵌段共聚物的用途
ES2638913T3 (es) * 2009-08-31 2017-10-24 Dow Global Technologies Llc Catalizador y procedimiento para polimerizar una olefina y poliolefina preparada mediante el mismo
US8784996B2 (en) 2009-11-24 2014-07-22 Dow Global Technologies Llc Extrusion coating composition
US8679639B2 (en) 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition
BR112012020720B1 (pt) 2010-02-19 2020-01-21 Dow Global Technologies Llc processo para polimerizar um monômero olefínico
US8202954B2 (en) 2010-02-19 2012-06-19 Dow Global Technologies Llc Metal-ligand complexes and catalysts
WO2012027448A1 (en) 2010-08-25 2012-03-01 Dow Global Technologies Llc Process for polymerizing a polymerizable olefin and catalyst therefor
WO2012103080A1 (en) 2011-01-26 2012-08-02 Dow Global Technologies Llc Process for making a polyolefin-polysiloxane block copolymer
WO2012155022A1 (en) 2011-05-12 2012-11-15 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
WO2013061974A1 (ja) 2011-10-24 2013-05-02 三菱化学株式会社 熱可塑性エラストマー組成物及びその製造方法
CN104379680B (zh) 2012-08-03 2017-11-28 埃克森美孚化学专利公司 具有长链支化的乙烯基封端的聚烯烃
US8957172B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Nonsymmetric catalysts comprising salan ligands
EP2880096B1 (de) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von polyalphaolefinen unter verwendung von modifizierten salankatalysatorverbindungen und damit hergestellte polyalphaolefine
WO2014022008A1 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
CN104364321A (zh) 2012-08-03 2015-02-18 埃克森美孚化学专利公司 含Salan 配体的卤化催化剂
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2914636A4 (de) 2012-11-02 2016-07-06 Exxonmobil Chem Patents Inc Geträgerte salankatalysatoren
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
CN105392776B (zh) 2013-06-20 2019-02-12 埃克森美孚化学专利公司 硫代-Salalen催化剂
WO2014204681A1 (en) 2013-06-20 2014-12-24 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
CN105992774B (zh) 2013-06-20 2018-08-24 埃克森美孚化学专利公司 Salenol催化剂
KR101774615B1 (ko) 2013-12-02 2017-09-04 주식회사 엘지화학 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법
US9290589B2 (en) 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
BR112016012971B1 (pt) 2013-12-19 2021-06-08 Dow Global Technologies Llc complexo de metal-ligante, catalisador e processo para preparar uma poliolefina
WO2015152974A1 (en) 2014-03-31 2015-10-08 Exxonmobil Chemical Patents Inc. Phenylene-bridged salalen catalysts
EP3237539B1 (de) 2014-12-23 2019-01-30 Dow Global Technologies LLC Thermoplastisches vulkanisat mit einem blockverbundstoff
BR112017012916B1 (pt) 2014-12-23 2021-11-30 Dow Global Technologies Llc Composição de vulcanizado termoplástico
US10773246B2 (en) 2015-01-06 2020-09-15 Scg Chemicals Co., Ltd. SiO2-layered double hydroxide microspheres and methods of making them
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
CN114685703A (zh) 2015-04-20 2022-07-01 埃克森美孚化学专利公司 包含氟化物化的载体的催化剂组合物及其使用方法
US10640583B2 (en) 2015-04-20 2020-05-05 Exxonmobil Chemical Patents, Inc. Catalyst composition comprising fluorided support and processes for use thereof
WO2016196293A1 (en) * 2015-05-29 2016-12-08 Dow Global Technologies Llc A process for producing a polyolefin
CN107787336B (zh) 2015-06-30 2021-05-28 陶氏环球技术有限责任公司 用于制备基于乙烯的聚合物的聚合方法
EP3356374B1 (de) 2015-09-30 2025-09-24 Dow Global Technologies LLC Zwei- oder mehrendige kompositionen geeignet für revesible kettenübertragung und verfahren zur deren hertellung
JP7041621B2 (ja) 2015-12-15 2022-03-24 ダウ グローバル テクノロジーズ エルエルシー エチレン/α-オレフィンのインターポリマーから作製された架橋発泡体
WO2017192226A1 (en) 2016-05-03 2017-11-09 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
GB201610457D0 (en) * 2016-06-15 2016-07-27 Scg Chemicals Co Ltd Catalysts
CN109937217B (zh) 2016-09-30 2021-09-14 陶氏环球技术有限责任公司 适用于链梭移的多头或双头组合物和其制备方法
CN109963888A (zh) 2016-09-30 2019-07-02 陶氏环球技术有限责任公司 用于制备适用于链梭移的多头或双头组合物的方法
CN109952324B (zh) 2016-09-30 2023-06-09 陶氏环球技术有限责任公司 适用于链梭移的封端多头或双头组合物和其制备方法
KR101980683B1 (ko) * 2017-01-06 2019-05-22 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
US20200247936A1 (en) 2017-03-15 2020-08-06 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
WO2018170227A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
SG11201908518VA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
CN110603274B (zh) 2017-03-15 2022-09-30 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
WO2018170138A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
WO2019064247A1 (ko) 2017-09-29 2019-04-04 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
KR20200135420A (ko) 2018-03-19 2020-12-02 다우 글로벌 테크놀로지스 엘엘씨 규소-말단화된 유기-금속 화합물 및 이를 제조하는 방법
WO2020140064A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Organometallic chain transfer agents
CN113454130B (zh) 2018-12-28 2024-12-13 陶氏环球技术有限责任公司 遥爪聚烯烃和用于制备遥爪聚烯烃的方法
KR20210119985A (ko) 2018-12-28 2021-10-06 다우 글로벌 테크놀로지스 엘엘씨 불포화 폴리올레핀을 포함하는 경화성 조성물
KR102880619B1 (ko) 2018-12-28 2025-11-04 다우 글로벌 테크놀로지스 엘엘씨 텔레켈릭 폴리올레핀을 포함하는 경화성 조성물
BR112021012808A2 (pt) 2018-12-28 2021-11-03 Dow Global Technologies Llc Composição curável
WO2020174346A1 (ko) * 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR102714698B1 (ko) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR20220042394A (ko) 2019-07-31 2022-04-05 다우 글로벌 테크놀로지스 엘엘씨 지글러-나타 촉매 및 수소화 전구촉매를 사용한 용액 공정에서의 에틸렌의 중합
KR102778393B1 (ko) * 2019-09-27 2025-03-11 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
BR112023000641A2 (pt) 2020-07-17 2023-01-31 Dow Global Technologies Llc Processo de polimerização de monômeros de olefina
CN113264963A (zh) * 2021-05-19 2021-08-17 青岛科技大学 一种耐高温高活性限定几何构型催化剂的制备与应用
CN115894573B (zh) * 2022-11-11 2024-11-12 天津科技大学 一种限制几何构型含氮侧臂茂茚金属衍生物及其合成方法
CN117467047A (zh) * 2023-02-21 2024-01-30 中化学科学技术研究有限公司 一种烯烃聚合催化剂及其制备方法和应用
CN116284514A (zh) * 2023-02-28 2023-06-23 天津科技大学 限制几何构型的阳离子茂金属催化剂、及其合成方法和应用
CN119978024B (zh) * 2025-03-11 2025-11-04 浙江大学 一种氮氧螯合过渡金属配合物催化剂及其制备方法和应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5621126A (en) 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
ES2087339T3 (es) 1991-05-27 1996-07-16 Hoechst Ag Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares.
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
ATE286918T1 (de) 1991-10-15 2005-01-15 Basell Polyolefine Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
CN1046289C (zh) 1993-06-24 1999-11-10 陶氏化学公司 钛(ⅱ)或锆(ⅱ)络合物和由它们制得的加成聚合催化剂
SK282416B6 (sk) 1993-09-17 2002-01-07 Bp Chemicals Limited Spôsob výroby etylénového polyméru s dlhým reťazcom vetvenia v plynnej fáze
JP3795072B2 (ja) 1993-11-18 2006-07-12 出光興産株式会社 遷移金属化合物,オレフィン重合用触媒,該触媒を用いたオレフィン系重合体の製造方法
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
DE69502028T2 (de) 1994-10-31 1998-12-10 Dsm N.V., Heerlen Katalytische zusammensetzung und verfahren zur olefinpolymerisation
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung

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