DE602005013949D1 - Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren - Google Patents

Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren

Info

Publication number
DE602005013949D1
DE602005013949D1 DE602005013949T DE602005013949T DE602005013949D1 DE 602005013949 D1 DE602005013949 D1 DE 602005013949D1 DE 602005013949 T DE602005013949 T DE 602005013949T DE 602005013949 T DE602005013949 T DE 602005013949T DE 602005013949 D1 DE602005013949 D1 DE 602005013949D1
Authority
DE
Germany
Prior art keywords
aluminum phosphate
oligomerization
catalysts
ethylene
phosphate compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602005013949T
Other languages
English (en)
Inventor
John R Briggs
David W Butler
Timothy T Wenzel
William C Brooks
Teresa L Fortin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of DE602005013949D1 publication Critical patent/DE602005013949D1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0252—Nitrogen containing compounds with a metal-nitrogen link, e.g. metal amides, metal guanidides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/83—Aluminophosphates (APO compounds)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE602005013949T 2004-03-16 2005-02-24 Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren Active DE602005013949D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55367504P 2004-03-16 2004-03-16
PCT/US2005/005841 WO2005092503A1 (en) 2004-03-16 2005-02-24 Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene

Publications (1)

Publication Number Publication Date
DE602005013949D1 true DE602005013949D1 (de) 2009-05-28

Family

ID=34961002

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602005013949T Active DE602005013949D1 (de) 2004-03-16 2005-02-24 Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren

Country Status (8)

Country Link
US (2) US7399895B2 (de)
EP (1) EP1747063B1 (de)
CN (1) CN1929919A (de)
AT (1) ATE428499T1 (de)
BR (1) BRPI0507523A (de)
DE (1) DE602005013949D1 (de)
ES (1) ES2321632T3 (de)
WO (1) WO2005092503A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2070593B1 (de) * 2007-12-06 2010-08-04 Saudi Basic Industries Corporation Katalysatorzusammensetzung und Verfahren zur Herstellung linearer Alphaolefine
US8084659B2 (en) * 2008-10-22 2011-12-27 Lummus Technology, Inc. Hexene upgrading
WO2016129848A1 (ko) * 2015-02-12 2016-08-18 주식회사 엘지화학 올레핀 올리고머화 방법
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
CN115926034A (zh) * 2022-11-28 2023-04-07 浙江石油化工有限公司 一种高强度防水用聚乙烯薄膜的制备方法

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588790A (en) * 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) * 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US5030431A (en) * 1985-08-29 1991-07-09 W. R. Grace & Co.-Conn. High pore volume and pore diameter aluminum phosphate
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
FR2634212B1 (fr) * 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5376612A (en) * 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
US5451645A (en) * 1989-08-10 1995-09-19 Phillips Petroleum Company Process for olefin polymerization
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5137997A (en) * 1991-04-22 1992-08-11 Phillips Petroleum Company Olefin polymerization catalysts and processes
US5104841A (en) * 1991-04-22 1992-04-14 Phillips Petroleum Company Olefin polymerization catalysts and processes
US5137994A (en) * 1991-05-23 1992-08-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the simultaneous trimerization and copolymerization of ethylene
US5210338A (en) * 1991-10-25 1993-05-11 Ethyl Corporation Catalyzed chain growth process
US5352749A (en) * 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) * 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5276220A (en) * 1992-06-18 1994-01-04 Ethyl Corporation Actinide catalyzed chain growth process
US5552361A (en) * 1993-11-04 1996-09-03 W. R. Grace & Co.-Conn. Aluminum phosphate composition with high pore volume and large pore diameter, process for its production and use thereof
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
TW279167B (de) * 1993-03-12 1996-06-21 Sumitomo Chemical Co
US5462999A (en) * 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
CA2161419C (en) * 1993-04-26 1999-05-04 Marc Louis Dechellis Process for polymerizing monomers in fluidized beds
FR2705252B1 (fr) * 1993-05-19 1995-07-21 Bp Chemicals Snc Procédé d'introduction d'un solide dans un réacteur et appareillage.
ZA943399B (en) * 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5461123A (en) * 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5616661A (en) * 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5886704A (en) * 1996-05-03 1999-03-23 Mitsubishi Electric Information Technology Center America, Inc. System and method for exploring light spaces
AU719500B2 (en) * 1996-08-08 2000-05-11 Dow Chemical Company, The 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
EP0861854A4 (de) * 1996-08-21 2000-10-18 Japan Polyolefins Co Ltd Verfahren zur herstellung von ethylenischem polymer
US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US5783512A (en) * 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US5965756A (en) * 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
AU726123B2 (en) * 1996-12-19 2000-11-02 Dow Chemical Company, The 3-aryl substituted indenyl containing metal complexes and polymerization process
US6150297A (en) * 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
US6036762A (en) * 1998-04-30 2000-03-14 Sambasivan; Sankar Alcohol-based precursor solutions for producing metal phosphate materials and coating
US6555634B1 (en) * 1999-05-13 2003-04-29 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
CN1495188A (zh) * 1999-12-10 2004-05-12 取代的第4族金属配合物，催化剂和烯烃聚合方法
JP4964389B2 (ja) * 2000-06-30 2012-06-27 ダウ グローバル テクノロジーズ エルエルシー 多環式、縮合環化合物、金属錯体及び重合方法
US6461415B1 (en) * 2000-08-23 2002-10-08 Applied Thin Films, Inc. High temperature amorphous composition based on aluminum phosphate

Also Published As

Publication number Publication date
US7399895B2 (en) 2008-07-15
US20080220967A1 (en) 2008-09-11
US20070161503A1 (en) 2007-07-12
CN1929919A (zh) 2007-03-14
ATE428499T1 (de) 2009-05-15
EP1747063A1 (de) 2007-01-31
BRPI0507523A (pt) 2007-07-03
ES2321632T3 (es) 2009-06-09
WO2005092503A1 (en) 2005-10-06
EP1747063B1 (de) 2009-04-15

Similar Documents

Publication Publication Date Title
EA200401474A1 (ru) Способ получения катализатора полимеризации олефинов
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
ATE424422T1 (de) Dual-site- olefinpolymerisationskatalysatorzusammensetzung
EA200600017A1 (ru) Покрытие, наносимое методом экструзии
NO20022851L (no) Fremgangsmåte for polymerisasjon
PL359783A1 (en) Catalytic solid supported on calcined hydrotalcite for olefinic polymerisation
BR0312210A (pt) atividores e sistemas catalìticos heterocìclicos contendo nitrogênio para polimerização de olefina
WO2000050470A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
GB0302429D0 (en) Catalytic composition for dimerizing,co-dimerizing,oligomerizing and polymerizing olefins
FR2880018B1 (fr) Production de propylene mettant en oeuvre la dimerisation de l'ethylene en butene-1, l'hydro-isomerisation en butene-2 et la metathese par l'ethylene
WO2001083571A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
MX337111B (es) Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina.
DE602005013949D1 (de) Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren
WO2004060930A3 (en) Processes for transitioning between metallocene and ziegler-natta polymerization catalysts
WO2007131010A3 (en) Aluminoxane compositions, their preparation, and their use in catalysis
WO2008036591A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2011056423A3 (en) Catalyst compounds and use thereof
EA200400420A1 (ru) Способ производства сополимеров пропилена
WO2011056431A3 (en) Catalyst compounds and use thereof
PL375955A1 (en) Monocyclopentadienyl complexes
WO2007076398A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2008011269A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
DE602007010594D1 (de) Polymerisierung von ethylen und alpha-olefinen mit imino-chinolinol-komplexen
GB0302430D0 (en) Catalytic composition containing an aluminoxane for dimerizing,co-dimerizing,oligomerizing and polymerizing olefins
DE60020108D1 (de) Polymerisation von ethylen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition