BRPI0417550A - composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas - Google Patents
composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinasInfo
- Publication number
- BRPI0417550A BRPI0417550A BRPI0417550-6A BRPI0417550A BRPI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A BR PI0417550 A BRPI0417550 A BR PI0417550A
- Authority
- BR
- Brazil
- Prior art keywords
- transition metal
- metal compound
- organometallic transition
- bisciclopentadienyl
- catalyst system
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
- C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
- C07C13/553—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
"COMPOSTO DE METAL DE TRANSIçãO ORGANOMETáLICO, SISTEMA DE LIGANTE BISCICLOPENTADIENILA, SISTEMA CATALISADOR E PREPARAçãO DE POLIOLEFINAS". A presente invenção refere-se a compostos de metais de transição organometálicos de fórmula (I), em que M¬ 1¬, X, n, Z, R¬ 1¬ - R¬ 8¬ e A são conforme definidos nas reivindicações, sistemas de ligante bisciclopentadienila com esse padrão de substituição, sistemas catalisadores compreendendo pelo menos um dos compostos de metais de transição organometálicos da presente invenção, um processo para a preparação de poliolefinas por polimerização ou copolimerização de pelo menos uma olefina na presença de um dos sistemas catalisadores da presente invenção, o uso dos sistemas de ligante bisciclopentadienila da presente invenção para a preparação de compostos de metais de transição organometálicos e um processo para a preparação de compostos de metais de transição organometálicos usando os sistemas de ligante bisciclopentadienila.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10358082A DE10358082A1 (de) | 2003-12-10 | 2003-12-10 | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
US54166804P | 2004-02-03 | 2004-02-03 | |
PCT/EP2004/013827 WO2005058916A2 (en) | 2003-12-10 | 2004-12-06 | Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0417550A true BRPI0417550A (pt) | 2007-03-27 |
BRPI0417550B1 BRPI0417550B1 (pt) | 2015-10-27 |
Family
ID=34672618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0417550A BRPI0417550B1 (pt) | 2003-12-10 | 2004-12-06 | composto de metal de transição organometálico, processo para preparação do mesmo, sistema de ligante bisciclopentadienila, uso do mesmo, sistema catalisador e processo para preparação de poliolefinas |
Country Status (10)
Country | Link |
---|---|
US (1) | US7452949B2 (pt) |
EP (1) | EP1692144B1 (pt) |
JP (1) | JP4823071B2 (pt) |
CN (1) | CN100473669C (pt) |
AT (1) | ATE464312T1 (pt) |
BR (1) | BRPI0417550B1 (pt) |
DE (1) | DE10358082A1 (pt) |
ES (1) | ES2341453T3 (pt) |
RU (1) | RU2362779C2 (pt) |
WO (1) | WO2005058916A2 (pt) |
Families Citing this family (73)
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DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
ATE445650T1 (de) * | 2004-05-04 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ataktischen 1- butenpolymeren |
DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
WO2006097500A1 (en) * | 2005-03-18 | 2006-09-21 | Basell Polyolefine Gmbh | Metallocene compounds |
RU2410388C2 (ru) | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
KR101289946B1 (ko) | 2005-03-23 | 2013-07-26 | 바젤 폴리올레핀 게엠베하 | 올레핀의 중합 방법 |
EP1861435B1 (en) * | 2005-03-23 | 2016-01-13 | Basell Polyolefine GmbH | Process for the polymerization of olefins |
WO2006117285A1 (en) | 2005-05-03 | 2006-11-09 | Basell Polyolefine Gmbh | Process for the polymerization of alpha olefins |
WO2006120177A2 (en) | 2005-05-11 | 2006-11-16 | Basell Poliolefine Itatia S.R.L. | Polymerization process for preparing polyolefin blends |
RU2008101445A (ru) * | 2005-06-13 | 2009-07-20 | Базелль Полиолефине Гмбх (De) | Способ сополимеризации пропилена |
WO2007042252A1 (en) * | 2005-10-14 | 2007-04-19 | Basell Polyolefine Gmbh | Hybrid catalyst systems supported on magnesium halide |
ATE526337T1 (de) * | 2006-03-17 | 2011-10-15 | Basell Polyolefine Gmbh | Metallocenverbindungen |
JP2009533382A (ja) * | 2006-04-12 | 2009-09-17 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
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DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
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MX2010004470A (es) * | 2007-10-25 | 2010-07-28 | Lummus Novolen Technology Gmbh | Sintesis racemoselectiva de compuestos de ansa-metaloceno, compuestos de ansa-metaloceno catalizadores que los comprenden, procesos para producir un polimero de olefina mediante el uso de los catalizadores y homo- y co-polimeros de olefina. |
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WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
EP2402353B1 (en) * | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
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KR20010023057A (ko) * | 1997-08-19 | 2001-03-26 | 가즈토 도미나가 | 프로필렌계 중합체 조성물 및 이로부터 제조된 필름 |
DE19808253A1 (de) | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
EP1062219B1 (en) * | 1998-03-11 | 2002-08-28 | The Dow Chemical Company | Integrated process for preparation of diene complexes |
DE19816154A1 (de) | 1998-04-09 | 1999-10-21 | Bernhard Rieger | Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination |
DE19833170A1 (de) * | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
ES2280674T3 (es) * | 1998-11-25 | 2007-09-16 | Basell Polyolefine Gmbh | Monohalogenuros de metaloceno. |
CN100575324C (zh) | 1999-12-23 | 2009-12-30 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物,配体体系,催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
CN1447959A (zh) * | 2000-07-13 | 2003-10-08 | 促销咨询公司 | 促销系统 |
DE10158656A1 (de) | 2001-11-30 | 2003-06-26 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
DE60213452T2 (de) | 2001-11-30 | 2007-08-23 | Basell Polyolefine Gmbh | Metallocene und verfahren zur herstellung von propylenpolymeren |
ATE383379T1 (de) * | 2002-12-04 | 2008-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von1-buten-polymeren |
ATE423784T1 (de) * | 2003-05-28 | 2009-03-15 | Basell Polyolefine Gmbh | Bisindenyl-zirconium-komplexe zur olefinpolymerisation |
-
2003
- 2003-12-10 DE DE10358082A patent/DE10358082A1/de not_active Withdrawn
-
2004
- 2004-12-06 CN CNB2004800363141A patent/CN100473669C/zh active Active
- 2004-12-06 EP EP04803537A patent/EP1692144B1/en not_active Revoked
- 2004-12-06 US US10/581,985 patent/US7452949B2/en active Active
- 2004-12-06 AT AT04803537T patent/ATE464312T1/de not_active IP Right Cessation
- 2004-12-06 RU RU2006124537/04A patent/RU2362779C2/ru active
- 2004-12-06 WO PCT/EP2004/013827 patent/WO2005058916A2/en active Application Filing
- 2004-12-06 JP JP2006543449A patent/JP4823071B2/ja active Active
- 2004-12-06 ES ES04803537T patent/ES2341453T3/es active Active
- 2004-12-06 BR BRPI0417550A patent/BRPI0417550B1/pt active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
DE10358082A1 (de) | 2005-07-14 |
EP1692144A2 (en) | 2006-08-23 |
CN100473669C (zh) | 2009-04-01 |
CN1890272A (zh) | 2007-01-03 |
JP2007513906A (ja) | 2007-05-31 |
BRPI0417550B1 (pt) | 2015-10-27 |
ES2341453T3 (es) | 2010-06-21 |
WO2005058916A3 (en) | 2005-11-03 |
RU2006124537A (ru) | 2008-01-20 |
EP1692144B1 (en) | 2010-04-14 |
ATE464312T1 (de) | 2010-04-15 |
RU2362779C2 (ru) | 2009-07-27 |
US20070155919A1 (en) | 2007-07-05 |
US7452949B2 (en) | 2008-11-18 |
WO2005058916A2 (en) | 2005-06-30 |
JP4823071B2 (ja) | 2011-11-24 |
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