DE602004019647D1 - Bisindenyl-zirconium-komplexe zur olefinpolymerisation - Google Patents

Bisindenyl-zirconium-komplexe zur olefinpolymerisation

Info

Publication number
DE602004019647D1
DE602004019647D1 DE602004019647T DE602004019647T DE602004019647D1 DE 602004019647 D1 DE602004019647 D1 DE 602004019647D1 DE 602004019647 T DE602004019647 T DE 602004019647T DE 602004019647 T DE602004019647 T DE 602004019647T DE 602004019647 D1 DE602004019647 D1 DE 602004019647D1
Authority
DE
Germany
Prior art keywords
olefin polymerization
present
zirconium complexes
bisindenyl zirconium
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE602004019647T
Other languages
English (en)
Inventor
Yoshikuni Okumura
Naka Seidel
Lars Koelling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2003124541 external-priority patent/DE10324541A1/de
Priority claimed from DE10341026A external-priority patent/DE10341026A1/de
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of DE602004019647D1 publication Critical patent/DE602004019647D1/de
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/081Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
DE602004019647T 2003-05-28 2004-05-27 Bisindenyl-zirconium-komplexe zur olefinpolymerisation Expired - Fee Related DE602004019647D1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE2003124541 DE10324541A1 (de) 2003-05-28 2003-05-28 Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US48693703P 2003-07-14 2003-07-14
DE10341026A DE10341026A1 (de) 2003-09-03 2003-09-03 Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
PCT/EP2004/005688 WO2004106351A1 (en) 2003-05-28 2004-05-27 Bisindenyl zirconium complexes for use in the polymerisation of olefins

Publications (1)

Publication Number Publication Date
DE602004019647D1 true DE602004019647D1 (de) 2009-04-09

Family

ID=33493745

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602004019647T Expired - Fee Related DE602004019647D1 (de) 2003-05-28 2004-05-27 Bisindenyl-zirconium-komplexe zur olefinpolymerisation

Country Status (6)

Country Link
US (1) US20060252637A1 (de)
EP (1) EP1636245B1 (de)
JP (1) JP2007505947A (de)
AT (1) ATE423784T1 (de)
DE (1) DE602004019647D1 (de)
WO (1) WO2004106351A1 (de)

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US8178636B2 (en) 2004-05-04 2012-05-15 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
BRPI0513109A (pt) 2004-07-22 2008-04-29 Basell Polyolefine Gmbh composição polimérica de buteno-1
EP1769009A1 (de) 2004-07-22 2007-04-04 Basell Polyolefine GmbH Verfahren zur herstellung von fraktionierbaren 1-buten-polymeren
DE102004039877A1 (de) 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
CN101163738B (zh) * 2005-04-21 2011-07-13 巴塞尔聚烯烃意大利有限责任公司 双轴取向丙烯聚合物膜
BRPI0613343A2 (pt) * 2005-06-13 2011-01-04 Basell Polyolefine Gmbh processo para a copolimerização de propileno
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7858717B2 (en) 2006-03-17 2010-12-28 Basell Polyolefine Gmbh Metallocene compounds
WO2007116034A1 (en) 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
US8097681B2 (en) * 2006-08-30 2012-01-17 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
US8097682B2 (en) 2006-08-30 2012-01-17 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
KR20100101092A (ko) * 2007-10-25 2010-09-16 루머스 노보렌 테크놀로지 게엠베하 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 폴리머생산방법, 및 올레핀 호모- 및 코폴리머
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CN108409895A (zh) * 2011-07-08 2018-08-17 博瑞立斯有限公司 催化剂
JP6176015B2 (ja) 2012-11-01 2017-08-09 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2746301B1 (de) 2012-12-21 2018-05-30 Borealis AG Katalysator
CN104870462B (zh) 2012-12-21 2018-04-10 博里利斯股份公司 催化剂
EP2746289B1 (de) 2012-12-21 2017-09-27 Borealis AG Katalysatoren
JP5710035B2 (ja) 2013-02-27 2015-04-30 日本ポリエチレン株式会社 メタロセン化合物およびオレフィン重合体の製造方法
US9249239B2 (en) * 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9644047B2 (en) 2013-07-17 2017-05-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
JP6361524B2 (ja) * 2014-02-19 2018-07-25 日本ポリエチレン株式会社 メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法
EP2995629B1 (de) 2014-09-12 2018-03-07 Borealis AG Verfahren zur Herstellung von Propylencopolymeren in Gasphase
WO2016038211A1 (en) 2014-09-12 2016-03-17 Borealis Ag Process for the preparation of copolymers of propylene
KR102384765B1 (ko) * 2014-11-26 2022-04-07 스미또모 가가꾸 가부시키가이샤 화합물의 제조 방법
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
EP3303422B1 (de) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Herstellung von heterophasischen polymeren in gas- oder schlämmephase
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
CN107690441A (zh) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 聚合物在气相或淤浆相中的单反应器制备
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR102412130B1 (ko) * 2017-12-26 2022-06-23 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법 및 이로부터 제조된 촉매를 이용하는 폴리프로필렌의 제조방법
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
KR20220094212A (ko) 2019-10-30 2022-07-05 차이나 페트로리움 앤드 케미컬 코포레이션 메탈로센 화합물, 및 이의 제조 방법 및 적용
CN114890987B (zh) * 2022-04-13 2023-12-19 万华化学集团股份有限公司 一种硫酚-噻吩配体及其制备方法、烯烃聚合催化剂及其制备方法、应用

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JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US6787618B1 (en) * 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
DE69710838T2 (de) * 1996-04-22 2002-10-31 Japan Polyolefins Co Ltd Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren
ATE301624T1 (de) * 1997-03-07 2005-08-15 Basell Polyolefine Gmbh Verfahren zur herstellung substituierter indanone,die substituierte indanone und daraus hergestelle metallocene
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE19833170A1 (de) * 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
RU2276671C2 (ru) * 1999-12-23 2006-05-20 Базель Полиолефине Гмбх Металлоцены, способ сополимеризации пропилена и этилена, статистические сополимеры пропилена с этиленом
DE10158656A1 (de) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
KR100780111B1 (ko) * 2003-05-08 2007-11-28 노볼렌 테크놀로지 홀딩스 씨.브이. 폴리프로필렌 수지 조성물

Also Published As

Publication number Publication date
ATE423784T1 (de) 2009-03-15
JP2007505947A (ja) 2007-03-15
US20060252637A1 (en) 2006-11-09
EP1636245B1 (de) 2009-02-25
EP1636245A1 (de) 2006-03-22
WO2004106351A1 (en) 2004-12-09

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8339 Ceased/non-payment of the annual fee