DE602005014361D1 - Durch silylhalogenid substituierte cyclopentadienylkomplexe der gruppe 6 - Google Patents

Durch silylhalogenid substituierte cyclopentadienylkomplexe der gruppe 6

Info

Publication number
DE602005014361D1
DE602005014361D1 DE602005014361T DE602005014361T DE602005014361D1 DE 602005014361 D1 DE602005014361 D1 DE 602005014361D1 DE 602005014361 T DE602005014361 T DE 602005014361T DE 602005014361 T DE602005014361 T DE 602005014361T DE 602005014361 D1 DE602005014361 D1 DE 602005014361D1
Authority
DE
Germany
Prior art keywords
group
cyclopentadienyl
substituted
complexes
optionally
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602005014361T
Other languages
English (en)
Inventor
Shahram Mihan
Markus Enders
Pablo Fernandez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of DE602005014361D1 publication Critical patent/DE602005014361D1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0225—Complexes comprising pentahapto-cyclopentadienyl analogues
    • B01J2531/023—Phospholyl ligands, i.e. [CnP(5-n)Rn]- in which n is 0-4 and R is H or hydrocarbyl, or analogous condensed ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0225—Complexes comprising pentahapto-cyclopentadienyl analogues
    • B01J2531/0233—Aza-Cp ligands, i.e. [CnN(5-n)Rn]- in which n is 0-4 and R is H or hydrocarbyl, or analogous condensed ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE602005014361T 2004-08-17 2005-08-16 Durch silylhalogenid substituierte cyclopentadienylkomplexe der gruppe 6 Active DE602005014361D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102004039877A DE102004039877A1 (de) 2004-08-17 2004-08-17 Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
US62295804P 2004-10-27 2004-10-27
PCT/EP2005/008848 WO2006018264A2 (en) 2004-08-17 2005-08-16 Cyclopentadienyl complexes of group 6 substituted by silyl halides

Publications (1)

Publication Number Publication Date
DE602005014361D1 true DE602005014361D1 (de) 2009-06-18

Family

ID=39356566

Family Applications (2)

Application Number Title Priority Date Filing Date
DE102004039877A Withdrawn DE102004039877A1 (de) 2004-08-17 2004-08-17 Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
DE602005014361T Active DE602005014361D1 (de) 2004-08-17 2005-08-16 Durch silylhalogenid substituierte cyclopentadienylkomplexe der gruppe 6

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE102004039877A Withdrawn DE102004039877A1 (de) 2004-08-17 2004-08-17 Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6

Country Status (7)

Country Link
US (1) US7795167B2 (de)
EP (1) EP1778400B1 (de)
JP (1) JP2008509956A (de)
AT (1) ATE430620T1 (de)
DE (2) DE102004039877A1 (de)
ES (1) ES2325217T3 (de)
WO (1) WO2006018264A2 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE425172T1 (de) * 2003-12-16 2009-03-15 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
EP1694719A2 (de) * 2003-12-19 2006-08-30 Basell Polyolefine GmbH Monocyclopentadienylkomplexe
KR100999592B1 (ko) * 2007-02-15 2010-12-08 주식회사 엘지화학 새로운 시클로펜타디에닐 리간드를 갖는 4족 전이금속화합물, 이의 제조방법 및 이를 이용한 올레핀계 중합체의제조방법
WO2011160828A1 (en) 2010-06-25 2011-12-29 Basell Polyolefine Gmbh Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) * 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) * 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4015059A (en) * 1975-12-29 1977-03-29 Union Carbide Corporation Fused ring catalyst and ethylene polymerization process therewith
DE2727245C3 (de) * 1977-06-16 1980-06-26 Brintzinger, Hans, Prof. Dr., 7750 Konstanz Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0507876B1 (de) 1990-01-02 1995-05-17 Exxon Chemical Patents Inc. Ionische metallocenkatalysatoren auf träger für olefinpolymerisation
DE69514661T2 (de) 1994-06-24 2000-08-03 Exxon Chemical Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und gebrauch
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
DE69703438T2 (de) 1996-03-29 2001-03-08 Dow Chemical Co Metallocen cokatalysator
DE19710615A1 (de) 1997-03-14 1998-09-17 Studiengesellschaft Kohle Mbh Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
CN1113890C (zh) 1996-11-15 2003-07-09 蒙特尔技术有限公司 杂环金属茂和聚合催化剂
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
EP0931099A1 (de) 1997-03-07 1999-07-28 Basell Polyolefine GmbH Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
DE19719103A1 (de) * 1997-05-06 1998-11-12 Targor Gmbh Stereorigide Metallocenverbindung
WO1999005153A1 (de) * 1997-07-28 1999-02-04 Targor Gmbh Verfahren zur herstellung von metallocenen
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
EP0931814A1 (de) * 1998-01-21 1999-07-28 Fina Research S.A. Polyolefine und ihre Verwendung
DE19833170A1 (de) * 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
US6160145A (en) 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
JP5008794B2 (ja) 1998-11-25 2012-08-22 バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング メタロセンモノハロゲン化物
DE19858016A1 (de) * 1998-12-16 2000-06-21 Basf Ag Neue Metallocenkomplexe
DE19935592A1 (de) * 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
US6437161B1 (en) * 1999-08-13 2002-08-20 Basf Aktiengesellschaft Monocyclopentadienyl complexes of chromium, molybdenum or tungsten
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US20060089253A1 (en) 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
DE60321822D1 (de) 2002-12-20 2008-08-07 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
JP2007505947A (ja) 2003-05-28 2007-03-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法

Also Published As

Publication number Publication date
DE102004039877A1 (de) 2006-02-23
JP2008509956A (ja) 2008-04-03
WO2006018264A2 (en) 2006-02-23
ES2325217T3 (es) 2009-08-28
ATE430620T1 (de) 2009-05-15
US20080097053A1 (en) 2008-04-24
WO2006018264A3 (en) 2006-09-14
EP1778400B1 (de) 2009-05-06
US7795167B2 (en) 2010-09-14
EP1778400A2 (de) 2007-05-02

Similar Documents

Publication Publication Date Title
BRPI0417550A (pt) composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas
ATE256136T1 (de) Metallocene
DE602004019647D1 (de) Bisindenyl-zirconium-komplexe zur olefinpolymerisation
WO2000037512A3 (en) Olefin polymerization catalysts, their production and use
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
TR200103809T2 (tr) Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri
TW200720238A (en) Intramolecular prins reaction and catalysts suitable therefor (citronellall to isopulegol)
DE602005014361D1 (de) Durch silylhalogenid substituierte cyclopentadienylkomplexe der gruppe 6
WO2010036025A3 (en) TRANSITION METAL CATALYTIC SYSTEMS AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α- OLEFINS USING THE SAME.
AU2003280428A8 (en) Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
NO20071630L (no) Fremgangsmate for telomerisering av ikke-sykliske olefiner
TW200635968A (en) Method for producing cyclic olefin addition copolymer, cyclic olefin addition copolymer and use thereof
EP1475383A4 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
PL375955A1 (en) Monocyclopentadienyl complexes
ATE403682T1 (de) Herstellung von katalysatorsystemen
BR0210981B1 (pt) processo de preparaÇço de complexos metÁlicos e processo de hidrossililaÇço de compostos etilenicamente e/ou acetilenicamente insaturados
ATE425172T1 (de) Monocyclopentadienylkomplexe
ATE364047T1 (de) Monocyclopentadienylkomplexe
AU2003258599A8 (en) Monocyclopentadienyl complexes
WO2005058983A3 (en) Monocyclopentadienyl complexes
EP2220127A4 (de) Verfahren zur herstellung eines kugelförmigen trägers für einen olefinpolymerisationskatalysator
AU2003283286A1 (en) Racemoselective preparation of isolable ansa-metallocene biphenoxide complexes
BRPI0516675A (pt) composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10
WO2007143328A3 (en) Single-site catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins

Legal Events

Date Code Title Description
8364 No opposition during term of opposition