IT1275573B - Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine - Google Patents

Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine

Info

Publication number
IT1275573B
IT1275573B ITMI951562A ITMI951562A IT1275573B IT 1275573 B IT1275573 B IT 1275573B IT MI951562 A ITMI951562 A IT MI951562A IT MI951562 A ITMI951562 A IT MI951562A IT 1275573 B IT1275573 B IT 1275573B
Authority
IT
Italy
Prior art keywords
polymerization
zone
olefins
alpha
gas phase
Prior art date
Application number
ITMI951562A
Other languages
English (en)
Inventor
Gabriele Govoni
Roberto Rinaldi
Massimo Covezzi
Paolo Galli
Original Assignee
Spherilene Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Spa filed Critical Spherilene Spa
Publication of ITMI951562A0 publication Critical patent/ITMI951562A0/it
Priority to ITMI951562A priority Critical patent/IT1275573B/it
Priority to TW085108604A priority patent/TW460482B/zh
Priority to MX9702102A priority patent/MX9702102A/es
Priority to RU97106749/04A priority patent/RU2167164C2/ru
Priority to KR1019970701830A priority patent/KR100436464B1/ko
Priority to TR97/00212T priority patent/TR199700212T1/xx
Priority to ES96927553T priority patent/ES2130842T3/es
Priority to CN96191095A priority patent/CN1110506C/zh
Priority to CZ19971202A priority patent/CZ290223B6/cs
Priority to DE69601569T priority patent/DE69601569T2/de
Priority to AU67348/96A priority patent/AU719107C/en
Priority to EP96927553A priority patent/EP0782587B1/en
Priority to PL96319349A priority patent/PL187165B1/pl
Priority to NZ315601A priority patent/NZ315601A/xx
Priority to RO97-00547A priority patent/RO118876B1/ro
Priority to UA97041838A priority patent/UA52590C2/uk
Priority to AT96927553T priority patent/ATE176914T1/de
Priority to CA002200428A priority patent/CA2200428C/en
Priority to DK96927553T priority patent/DK0782587T3/da
Priority to PCT/EP1996/003189 priority patent/WO1997004015A1/en
Priority to JP50604397A priority patent/JP3787687B2/ja
Priority to HU9702440A priority patent/HUP9702440A3/hu
Priority to BR9606569A priority patent/BR9606569A/pt
Priority to IL12048296A priority patent/IL120482A/xx
Priority to ZA9606125A priority patent/ZA966125B/xx
Priority to EG68496A priority patent/EG21069A/xx
Priority to US08/684,411 priority patent/US5698642A/en
Publication of ITMI951562A1 publication Critical patent/ITMI951562A1/it
Priority to NO19971282A priority patent/NO313051B1/no
Priority to BG101414A priority patent/BG62814B1/bg
Application granted granted Critical
Publication of IT1275573B publication Critical patent/IT1275573B/it
Priority to US08/943,748 priority patent/US6413477B1/en
Priority to CNB991009282A priority patent/CN1149234C/zh
Priority to GR990400857T priority patent/GR3029770T3/el
Priority to HK00101587.7A priority patent/HK1022706B/xx
Priority to US10/016,843 priority patent/US20020061264A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B01J8/388—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
ITMI951562A 1995-07-20 1995-07-20 Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine IT1275573B (it)

Priority Applications (34)

Application Number Priority Date Filing Date Title
ITMI951562A IT1275573B (it) 1995-07-20 1995-07-20 Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
TW085108604A TW460482B (en) 1995-07-20 1996-07-16 Process and apparatus for the gas-phase polymerization of alpha-olefins
AT96927553T ATE176914T1 (de) 1995-07-20 1996-07-17 Verfahren und vorrichtung zur gasphasenpolymerisation von alpha-olefinen
PCT/EP1996/003189 WO1997004015A1 (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
KR1019970701830A KR100436464B1 (ko) 1995-07-20 1996-07-17 알파-올레핀의기상중합방법및장치
TR97/00212T TR199700212T1 (tr) 1995-07-20 1996-07-17 Alfa-Olefinlerin gaz-fazinda polimerizasyonu icin islem ve aygit.
ES96927553T ES2130842T3 (es) 1995-07-20 1996-07-17 Procedimiento y aparato para la polimerizacion de alfaolefinas en fase de gas.
CN96191095A CN1110506C (zh) 1995-07-20 1996-07-17 α－烯烃的气相聚合法及所用装置
CZ19971202A CZ290223B6 (cs) 1995-07-20 1996-07-17 Způsob a zařízení pro polymeraci alfa-olefinů v plynné fázi
DE69601569T DE69601569T2 (de) 1995-07-20 1996-07-17 Verfahren und vorrichtung zur gasphasenpolymerisation von alpha-olefinen
AU67348/96A AU719107C (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
EP96927553A EP0782587B1 (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
PL96319349A PL187165B1 (pl) 1995-07-20 1996-07-17 Sposób i urządzenie do polimeryzacji alfa-olefin w fazie gazowej
NZ315601A NZ315601A (en) 1995-07-20 1996-07-17 Gas phase polymerisation of olefins in which growing polymer particles are recycled under gravity from a first zone through a second zone and back to the first zone
RO97-00547A RO118876B1 (ro) 1995-07-20 1996-07-17 Procedeu de polimerizare în fază gazoasă a alfa - olefinelor şi instalaţie pentru obţinerea acestora
UA97041838A UA52590C2 (uk) 1995-07-20 1996-07-17 СПОСІБ ТА ПРИСТРІЙ ДЛЯ ГАЗОФАЗОВОЇ ПОЛІМЕРИЗАЦІЇ <font face="Symbol">a</font>-ОЛЕФІНІВ
MX9702102A MX9702102A (es) 1995-07-20 1996-07-17 Procedimiento y aparato para la polimerzacion de fase gaseosa de alfa-olefinas.
CA002200428A CA2200428C (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
DK96927553T DK0782587T3 (da) 1995-07-20 1996-07-17 Fremgangsmåde og apparat til gasfasepolymerisation af alfa-olefiner
RU97106749/04A RU2167164C2 (ru) 1995-07-20 1996-07-17 Способ и устройство для газофазной полимеризации альфа-олефинов
JP50604397A JP3787687B2 (ja) 1995-07-20 1996-07-17 α−オレフィン類の気相重合方法と装置
HU9702440A HUP9702440A3 (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
BR9606569A BR9606569A (pt) 1995-07-20 1996-07-17 Processo e aparelho para a polímerização em fase gasosa de alfa-olefinas
IL12048296A IL120482A (en) 1995-07-20 1996-07-17 Process and apparatus for the gas-phase polymerization of alpha-olefins
EG68496A EG21069A (en) 1995-07-20 1996-07-18 Process and apparatus for gas-phase polymerization of alpha olefins
ZA9606125A ZA966125B (en) 1995-07-20 1996-07-18 Process and apparatus for the gas-phase polymerization of alpha-olefins.
US08/684,411 US5698642A (en) 1995-07-20 1996-07-19 Process and apparatus for the gas-phase polymerization of α-olefins
NO19971282A NO313051B1 (no) 1995-07-20 1997-03-19 Fremgangsmåte og apparatur for gassfasepolymerisering av <alfa>-olefiner
BG101414A BG62814B1 (bg) 1995-07-20 1997-04-15 Метод и апарат за полимеризация в газова фаза на алфа-олефини
US08/943,748 US6413477B1 (en) 1995-07-20 1997-10-03 Process and apparatus for the gas-phase polymerization of α-olefins
CNB991009282A CN1149234C (zh) 1995-07-20 1999-01-06 α-烯烃的气相聚合法及所用装置
GR990400857T GR3029770T3 (en) 1995-07-20 1999-03-23 Process and apparatus for the gas-phase polymerization of alpha-olefins
HK00101587.7A HK1022706B (en) 1995-07-20 2000-03-15 Process and apparatus for the gas-phase polymerization of alpha-olefins
US10/016,843 US20020061264A1 (en) 1995-07-20 2001-12-14 Process and apparatus for the gas-phase polymerization of alpha-olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI951562A IT1275573B (it) 1995-07-20 1995-07-20 Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine

Publications (3)

Publication Number Publication Date
ITMI951562A0 ITMI951562A0 (it) 1995-07-20
ITMI951562A1 ITMI951562A1 (it) 1997-01-20
IT1275573B true IT1275573B (it) 1997-08-07

Family

ID=11372011

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI951562A IT1275573B (it) 1995-07-20 1995-07-20 Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine

Country Status (29)

Country Link
US (3) US5698642A (it)
EP (1) EP0782587B1 (it)
JP (1) JP3787687B2 (it)
KR (1) KR100436464B1 (it)
CN (2) CN1110506C (it)
AT (1) ATE176914T1 (it)
BG (1) BG62814B1 (it)
BR (1) BR9606569A (it)
CA (1) CA2200428C (it)
CZ (1) CZ290223B6 (it)
DE (1) DE69601569T2 (it)
DK (1) DK0782587T3 (it)
EG (1) EG21069A (it)
ES (1) ES2130842T3 (it)
GR (1) GR3029770T3 (it)
HU (1) HUP9702440A3 (it)
IL (1) IL120482A (it)
IT (1) IT1275573B (it)
MX (1) MX9702102A (it)
NO (1) NO313051B1 (it)
NZ (1) NZ315601A (it)
PL (1) PL187165B1 (it)
RO (1) RO118876B1 (it)
RU (1) RU2167164C2 (it)
TR (1) TR199700212T1 (it)
TW (1) TW460482B (it)
UA (1) UA52590C2 (it)
WO (1) WO1997004015A1 (it)
ZA (1) ZA966125B (it)

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DE10260733B4 (de) * 2002-12-23 2010-08-12 Outokumpu Oyj Verfahren und Anlage zur Wärmebehandlung von eisenoxidhaltigen Feststoffen
DE10260741A1 (de) 2002-12-23 2004-07-08 Outokumpu Oyj Verfahren und Anlage zur Wärmebehandlung von feinkörnigen Feststoffen
DE10260737B4 (de) * 2002-12-23 2005-06-30 Outokumpu Oyj Verfahren und Anlage zur Wärmebehandlung von titanhaltigen Feststoffen
DE10260734B4 (de) * 2002-12-23 2005-05-04 Outokumpu Oyj Verfahren und Anlage zur Herstellung von Schwelkoks
DE10260731B4 (de) 2002-12-23 2005-04-14 Outokumpu Oyj Verfahren und Anlage zur Wärmebehandlung von eisenoxidhaltigen Feststoffen
DE10260739B3 (de) 2002-12-23 2004-09-16 Outokumpu Oy Verfahren und Anlage zur Herstellung von Metalloxid aus Metallverbindungen
DE10260738A1 (de) 2002-12-23 2004-07-15 Outokumpu Oyj Verfahren und Anlage zur Förderung von feinkörnigen Feststoffen
EP1599506B1 (en) 2003-03-05 2008-04-30 Basell Poliolefine Italia S.r.l. Control method in a polymerization process
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MY136027A (en) 2003-04-02 2008-07-31 Basell Poliolefine Spa Polyolefin masterbatch and composition suitable for injection molding
TW200427763A (en) 2003-04-03 2004-12-16 Basell Poliolefine Spa Impact resistant polyolefin compositions
DE10317533A1 (de) * 2003-04-16 2004-11-04 Basell Polyolefine Gmbh Verfahren zur diskontinuierlichen Katalysatordosierung in einen Gasphasenwirbelschichtreaktor
US6759489B1 (en) 2003-05-20 2004-07-06 Eastern Petrochemical Co. Fluidized bed methods for making polymers
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US7572860B2 (en) 2003-08-05 2009-08-11 Basell Poliolefine Italia S.R.L. Polyolefin articles
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