MX388983B - Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. - Google Patents

Copolimeros de propileno-etileno aleatorios y proceso para su preparacion.

Info

Publication number
MX388983B
MX388983B MX2016014076A MX2016014076A MX388983B MX 388983 B MX388983 B MX 388983B MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 388983 B MX388983 B MX 388983B
Authority
MX
Mexico
Prior art keywords
sup
ethylene copolymers
preparation
random propylene
content
Prior art date
Application number
MX2016014076A
Other languages
English (en)
Other versions
MX2016014076A (es
Inventor
Caroline Cathelin
Dario Liguori
Davide Tartari
Fabrizio Piemontesi
Giampiero Morini
Gianni Vitale
Simona Guidotti
Original Assignee
Basell Poliolefine Italia Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=50639342&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX388983(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Poliolefine Italia Srl filed Critical Basell Poliolefine Italia Srl
Publication of MX2016014076A publication Critical patent/MX2016014076A/es
Publication of MX388983B publication Critical patent/MX388983B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6423—Component of C08F4/64 containing at least two different metals
    • C08F4/6425—Component of C08F4/64 containing at least two different metals containing magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26—Use as polymer for film forming

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Copolímeros de propileno-etileno que muestran un contenido de etileno entre un 0,1% y un 10% en peso, una distribución del peso molecular (MWD), expresada en términos de Mw/Mn, mayor a 3,0 y un contenido de fracción soluble en xileno (XS) y contenido de etileno (C2) tal que el punto definido por los valores cae debajo de la línea dada por la ecuación XS= 1,0296·e0,435C2 muestran una alta transparencia y una temperatura de fusión baja.
MX2016014076A 2014-05-06 2015-05-06 Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. MX388983B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14167178 2014-05-06
PCT/EP2015/059919 WO2015169831A1 (en) 2014-05-06 2015-05-06 Random propylene-ethylene copolymers and process for their preparation

Publications (2)

Publication Number Publication Date
MX2016014076A MX2016014076A (es) 2017-02-14
MX388983B true MX388983B (es) 2025-03-20

Family

ID=50639342

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016014076A MX388983B (es) 2014-05-06 2015-05-06 Copolimeros de propileno-etileno aleatorios y proceso para su preparacion.

Country Status (9)

Country Link
US (1) US9676883B2 (es)
EP (1) EP3140328B1 (es)
JP (1) JP6307178B2 (es)
KR (1) KR101764561B1 (es)
CN (1) CN106232643B (es)
BR (1) BR112016024633B1 (es)
MX (1) MX388983B (es)
RU (1) RU2662152C2 (es)
WO (1) WO2015169831A1 (es)

Families Citing this family (11)

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BR112016023909B1 (pt) 2014-05-06 2022-09-27 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno e filme de extrusão plana compreendendo os mesmos
US10562990B2 (en) 2015-09-10 2020-02-18 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
EP3170864B1 (en) * 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
BR112019009248B1 (pt) 2016-12-05 2023-02-07 Basell Poliolefine Italia S.R.L Copolímeros de propileno heterofásicos
RU2734534C1 (ru) * 2017-07-19 2020-10-20 Базелл Полиолефин Италия С.Р.Л. Сополимеры пропилена
WO2019241063A1 (en) 2018-06-11 2019-12-19 W.R. Grace & Co.-Conn. Propylene-ethylene copolymer compositions suitable for hot fill packaging of foodstuffs
US11680118B2 (en) * 2018-06-29 2023-06-20 Borealis Ag C2C3 random copolymer composition
CN112469745B (zh) * 2018-08-22 2023-11-24 巴塞尔聚烯烃意大利有限公司 无规丙烯-乙烯共聚物
TW202104290A (zh) 2019-05-29 2021-02-01 奧地利商柏列利斯股份公司 C2c3隨機共聚物
KR20240076546A (ko) 2022-11-22 2024-05-30 한화토탈에너지스 주식회사 공중합성이 개선된 프로필렌계 공중합체의 제조방법
KR20250041439A (ko) 2023-09-18 2025-03-25 한화토탈에너지스 주식회사 폴리프로필렌 제조용 고체촉매 및 블록공중합체 제조방법

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JPS5582103A (en) 1978-12-15 1980-06-20 Mitsubishi Petrochem Co Ltd Production of alpha-olefin polymer
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BR112016023909B1 (pt) * 2014-05-06 2022-09-27 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno e filme de extrusão plana compreendendo os mesmos
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Also Published As

Publication number Publication date
EP3140328A1 (en) 2017-03-15
EP3140328B1 (en) 2020-11-18
KR20160143857A (ko) 2016-12-14
KR101764561B1 (ko) 2017-08-02
BR112016024633A2 (pt) 2017-08-15
BR112016024633B1 (pt) 2022-05-03
JP2017514000A (ja) 2017-06-01
RU2016145451A (ru) 2018-06-07
WO2015169831A1 (en) 2015-11-12
MX2016014076A (es) 2017-02-14
RU2662152C2 (ru) 2018-07-24
CN106232643A (zh) 2016-12-14
CN106232643B (zh) 2019-02-26
RU2016145451A3 (es) 2018-06-07
US9676883B2 (en) 2017-06-13
US20170073444A1 (en) 2017-03-16
JP6307178B2 (ja) 2018-04-04

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