ATE464312T1 - Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen - Google Patents

Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen

Info

Publication number
ATE464312T1
ATE464312T1 AT04803537T AT04803537T ATE464312T1 AT E464312 T1 ATE464312 T1 AT E464312T1 AT 04803537 T AT04803537 T AT 04803537T AT 04803537 T AT04803537 T AT 04803537T AT E464312 T1 ATE464312 T1 AT E464312T1
Authority
AT
Austria
Prior art keywords
transition metal
metal compound
organometallic transition
polyolefins
biscyclopentadienylligand
Prior art date
Application number
AT04803537T
Other languages
English (en)
Inventor
Yoshikuni Okumura
Ev Ilya Nifant
Michael Elder
Pavel Ivchenko
Vladimir Bagrov
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34672618&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE464312(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE464312T1 publication Critical patent/ATE464312T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C07C13/553Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00Systems containing at least three condensed rings
    • C07C2603/02Ortho- or ortho- and peri-condensed systems
    • C07C2603/04Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT04803537T 2003-12-10 2004-12-06 Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen ATE464312T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10358082A DE10358082A1 (de) 2003-12-10 2003-12-10 Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US54166804P 2004-02-03 2004-02-03
PCT/EP2004/013827 WO2005058916A2 (en) 2003-12-10 2004-12-06 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins

Publications (1)

Publication Number Publication Date
ATE464312T1 true ATE464312T1 (de) 2010-04-15

Family

ID=34672618

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04803537T ATE464312T1 (de) 2003-12-10 2004-12-06 Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen

Country Status (10)

Country Link
US (1) US7452949B2 (de)
EP (1) EP1692144B1 (de)
JP (1) JP4823071B2 (de)
CN (1) CN100473669C (de)
AT (1) ATE464312T1 (de)
BR (1) BRPI0417550B1 (de)
DE (1) DE10358082A1 (de)
ES (1) ES2341453T3 (de)
RU (1) RU2362779C2 (de)
WO (1) WO2005058916A2 (de)

Families Citing this family (79)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
US8178636B2 (en) * 2004-05-04 2012-05-15 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102004056104A1 (de) * 2004-11-19 2006-05-24 Basell Polyolefine Gmbh Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7803887B2 (en) * 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
EP1861435B1 (de) * 2005-03-23 2016-01-13 Basell Polyolefine GmbH Verfahren zur polymerisation von olefinen
EP1877453A1 (de) * 2005-05-03 2008-01-16 Basell Polyolefine GmbH Verfahren zur polymerisation von alpha-olefinen
US7985799B2 (en) 2005-05-11 2011-07-26 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefin blends
AU2006259143A1 (en) * 2005-06-13 2006-12-21 Basell Polyolefine Gmbh Process for the copolymerization of propylene
KR20080067629A (ko) * 2005-10-14 2008-07-21 바젤 폴리올레핀 게엠베하 할로겐화 마그네슘상에 담지된 하이브리드 촉매 시스템
JP2009530341A (ja) * 2006-03-17 2009-08-27 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物類
US7834205B2 (en) * 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
EP2010579A1 (de) * 2006-04-21 2009-01-07 Basell Polyolefine GmbH Verfahren zur herstellung von ethylen-propylen-copolymeren
US8742042B2 (en) * 2006-04-21 2014-06-03 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
US8076259B2 (en) * 2007-10-04 2011-12-13 Basell Polyolefine Gmbh Process for the preparation of catalyst paste and products thereof
BRPI0722163A2 (pt) * 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Síntese racemoseletiva de compostos de ansa-metaloceno, compostos de ansa-metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso dos catalisadores, e homo- e copolímeros de olefina
JP5409294B2 (ja) * 2008-12-17 2014-02-05 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP2402353B1 (de) 2010-07-01 2018-04-25 Borealis AG Gruppe-4-Metallocene als Katalysatoren zur Olefinpolymerisation
EP2402354B1 (de) 2010-07-01 2016-03-02 Borealis AG Verfahren zur Polymerisierung von Olefinen unter Verwendung von Gruppe-4-Metallocenen als Katalisatoren
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2676972A1 (de) 2012-06-19 2013-12-25 Basell Polyolefine GmbH Verfahren zum Erhalt einer Polyolefinzusammensetzung
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2722346A1 (de) 2012-10-18 2014-04-23 Borealis AG Polymerisationsverfahren und Katalysator
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2914638A4 (de) 2012-10-31 2016-07-27 Exxonmobil Chem Patents Inc Propylencopolymer-zusammensetzungen und verfahren zur herstellung davon
CN104870462B (zh) 2012-12-21 2018-04-10 博里利斯股份公司 催化剂
EP2746301B1 (de) 2012-12-21 2018-05-30 Borealis AG Katalysator
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
WO2015009479A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358586A (zh) 2013-07-17 2016-02-24 埃克森美孚化学专利公司 环丙基取代的茂金属催化剂
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
CN105377905B (zh) 2013-07-17 2018-09-14 埃克森美孚化学专利公司 茂金属和由其衍生的催化剂组合物
EP3022236B1 (de) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Verfahren mit substituierten metallocenkatalysatoren und produkte daraus
CN103980395B (zh) * 2014-04-30 2016-08-24 中国科学院化学研究所 一种可用于3d打印的超高分子量无规聚丙烯树脂及其制备方法和应用
KR101580591B1 (ko) 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
EP2995629B1 (de) 2014-09-12 2018-03-07 Borealis AG Verfahren zur Herstellung von Propylencopolymeren in Gasphase
CN106795239A (zh) 2014-09-12 2017-05-31 博里利斯股份公司 制备丙烯共聚物的方法
EP3225610B1 (de) * 2014-11-26 2021-09-29 Sumitomo Chemical Company, Limited Verfahren zur herstellung von polymeren mittels kupplungsreaktionen
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
EP3303423A1 (de) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Einzelreaktor-herstellung von polymeren in der gas- oder suspensionsphase
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
KR101846412B1 (ko) * 2016-12-06 2018-05-18 한화케미칼 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
CN110352195B (zh) 2016-12-29 2022-11-11 博里利斯股份公司 催化剂
JP6984128B2 (ja) * 2016-12-29 2021-12-17 日本ポリエチレン株式会社 ポリエチレン樹脂の製造方法並びに当該方法により製造されたポリエチレン樹脂を用いた太陽電池封止材および太陽電池モジュール
KR102065719B1 (ko) * 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매
EP3694811B1 (de) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Unterstütztes katalysatorsystem
US11001657B2 (en) 2017-10-25 2021-05-11 Exxonmobil Chemical Patents Inc. Unbridged indacenyl metallocenes
US11214631B2 (en) * 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
EP3710491B1 (de) * 2017-11-14 2025-01-01 ExxonMobil Chemical Patents Inc. (di)siliciumverbrückte metallocene zur herstellung von polyethylen mit breiter molekulargewichtsverteilung und molekulargewicht
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
KR102530448B1 (ko) * 2019-03-13 2023-05-08 주식회사 엘지화학 전이 금속 화합물 및 이를 포함하는 촉매 조성물
JP7278653B2 (ja) * 2019-06-11 2023-05-22 エルジー・ケム・リミテッド プロピレン-エチレンランダム共重合体
KR102524952B1 (ko) * 2019-06-13 2023-04-24 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
US12421334B2 (en) 2019-06-13 2025-09-23 Lg Chem, Ltd. Hybrid supported metallocene catalyst and method of preparing polypropylene using the same
US20220315680A1 (en) 2019-08-22 2022-10-06 Exxonmobil Chemical Patents Inc. Isotactic Propylene Homopolymers and Copolymers Produced with C1 Symmetric Metallocene Catalysts
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2022015094A1 (ko) * 2020-07-16 2022-01-20 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
WO2022108973A1 (en) 2020-11-23 2022-05-27 Exxonmobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
US20250002617A1 (en) 2021-09-02 2025-01-02 ExxonMobil Technology and Engineering Company C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
CN115160470B (zh) * 2022-07-18 2023-06-30 宁夏清研高分子新材料有限公司 一种tpx聚合物的制备方法、催化剂及其制备方法
WO2025016566A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025051400A1 (en) 2023-09-07 2025-03-13 Borealis Ag Methods of producing metallocene catalyst components
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03181920A (ja) * 1989-12-12 1991-08-07 Matsushita Electric Ind Co Ltd 光電子集積回路
DE69033368T3 (de) 1990-01-02 2008-07-03 Exxon Chemical Patents, Inc. Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation
CA2117699C (en) * 1993-01-11 2001-05-29 Mikio Hashimoto Propylene polymer compositions
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE69514661T2 (de) 1994-06-24 2000-08-03 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsystem, ihre herstellung und gebrauch
EP0728773B1 (de) * 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
EP0741371B1 (de) 1995-05-01 2002-10-23 Agfa-Gevaert Verfahren zur Wiedergabe eines Strahlungsbildes
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US6121182A (en) 1996-04-22 2000-09-19 Japan Polyolafins Co., Ltd. Polyolefin production catalyst and method of preparing polyolefins
JPH10265588A (ja) * 1997-01-24 1998-10-06 Mitsui Chem Inc オレフィン系共重合体製収縮フィルム
US5789634A (en) 1997-02-05 1998-08-04 Boulder Scientific Company Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst intermediates
AU7332398A (en) 1997-03-07 1998-09-29 Targor Gmbh Method for producing olefin polymers with a higher melting point
CN100451024C (zh) 1997-03-07 2009-01-14 巴塞尔聚烯烃股份有限公司 金属茂化合物和茚类化合物以及其应用
DE19733017A1 (de) 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE69841203D1 (de) * 1997-08-19 2009-11-12 Idemitsu Kosan Co Filme aus nukleierten propylenpolymerzusammensetzungen
DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6084115A (en) 1998-03-11 2000-07-04 The Dow Chemical Company Diene complexes of group 4 metals and process of preparation
DE19816154A1 (de) 1998-04-09 1999-10-21 Bernhard Rieger Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
AU1272100A (en) 1998-11-25 2000-06-13 Targor Gmbh Metallocene monohalogenides
EP1548023B1 (de) 1999-12-23 2013-08-14 Basell Polyolefine GmbH Übergangsmetallverbindung, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen
US20040050724A1 (en) 2000-07-13 2004-03-18 Grul Derek John Promotional system
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
WO2003045964A1 (en) * 2001-11-30 2003-06-05 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
WO2004050724A1 (en) * 2002-12-04 2004-06-17 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US20060252637A1 (en) * 2003-05-28 2006-11-09 Basell Polyolefine Gmbh Bisindenyl zirconium complexes for use in the polymerization of olefins

Also Published As

Publication number Publication date
US20070155919A1 (en) 2007-07-05
RU2362779C2 (ru) 2009-07-27
WO2005058916A3 (en) 2005-11-03
WO2005058916A2 (en) 2005-06-30
JP2007513906A (ja) 2007-05-31
JP4823071B2 (ja) 2011-11-24
CN1890272A (zh) 2007-01-03
EP1692144B1 (de) 2010-04-14
DE10358082A1 (de) 2005-07-14
EP1692144A2 (de) 2006-08-23
BRPI0417550A (pt) 2007-03-27
US7452949B2 (en) 2008-11-18
BRPI0417550B1 (pt) 2015-10-27
ES2341453T3 (es) 2010-06-21
RU2006124537A (ru) 2008-01-20
CN100473669C (zh) 2009-04-01

Similar Documents

Publication Publication Date Title
ATE464312T1 (de) Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen
DE602004019647D1 (de) Bisindenyl-zirconium-komplexe zur olefinpolymerisation
ATE328912T1 (de) Herstellung eines katalysatorbestandteils zur olefinpolymerisation
ATE344268T1 (de) Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
DE69811077D1 (de) Verfahren zur herstellung von alpha-olefinen
MXPA04001348A (es) NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS.
DE60120141D1 (de) Herstellung eines Katalysatorbestandteils zur Olefinpolymerisation
ATE274530T1 (de) Katalysator zur ethylen homo und copolymerisation
DE59711103D1 (de) Metallocene
WO2001044324A3 (en) Polymerization of olefins
MY133678A (en) Catalyst system and process for the polymerization of olefins
MXPA04001350A (es) COMPUESTOS DE FOSFITO NOVEDOSOS Y COMPLEJOS METaLICOS DE FOSFITO NOVEDOSOS.
TR200103809T2 (tr) Magnezyum/geçiş metali alkoksid komplekslerinin yapılma yöntemleri ve bunlardan yapılan polimerizasyon katalizörleri
RU94035670A (ru) Способ полимеризации олефинов
DE60100252D1 (de) Verfahren zur herstellung von hex-1-en
DE60334073D1 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
DE69919753D1 (de) Ein katalysator zur ethylen homo- und co-polymerisation
BR0212763A (pt) Difosfinas e sua utilização em sìntese assimétrica
DE602004016198D1 (de) Verfahren zur polymerisation von olefinen
AU2003240728A1 (en) Transition metal compounds their preparation and their use in catalyst systems for the polymerization and copolymerization of olefins
DE602004003686D1 (de) Integriertes verfahren zur herstellung von olefinderivaten
MY138994A (en) Ziegler-natta catalyst for olefin polymerization including aryloxy group and method for polymerization of olefin using the same
DE50304411D1 (de) Metallkomplexe von Iminohydroxamsäuren
ATE384730T1 (de) Verfahren zur herstellung von palladium(0)- haltigen verbindungen
ATE417867T1 (de) Verfahren zur darstellung von polyethylen und katalysatorvorstufe

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties