ES2094461T3 - Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores. - Google Patents

Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.

Info

Publication number
ES2094461T3
ES2094461T3 ES93201185T ES93201185T ES2094461T3 ES 2094461 T3 ES2094461 T3 ES 2094461T3 ES 93201185 T ES93201185 T ES 93201185T ES 93201185 T ES93201185 T ES 93201185T ES 2094461 T3 ES2094461 T3 ES 2094461T3
Authority
ES
Spain
Prior art keywords
sub
radicals
catalysts
sup
zirconium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93201185T
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English (en)
Inventor
Howard William Turner
Gregory George Hlatky
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26678640&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2094461(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2094461T3 publication Critical patent/ES2094461T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Uso, en la preparación de un catalizadorpara la polimerización de olefinas, diolefinas y/omonómeros acetilénicamente insaturados, de unanión de fórmula [(M') m+ Q1Q2...Qn] d& 8722; en la que:M' es un metal o metaloide del Grupo V-B a VI-Ade la Tabla Periódica de los Elementos; es decirlos Grupos V-B; VI-B; VII-B; VIII; I-B; II-B; III-A; IV-A y V-A;Q1 a Qn se seleccionan independientemente delGrupo que consiste en radicales hidruro, radicalesdialquilamido, radicales alcóxido y arilóxido;radicales hidrocarbilo e hidrocarbilo sustituido yradicales organometaloide y uno cualquiera, perono más que uno de Q1 a Qn puede ser un radicalhaluro, seleccionándose los restantes Q1 a Qnindependientemente de los radicales precedentes;m es un número entero desde 1 a 7; n es unnúmero entero desde 2 a 8; y n-m = d, conteniendo elanión carbonos aromáticos sustituidoso estando sustituido con fluor de tal manera queresistan la degradación.
ES93201185T 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores. Expired - Lifetime ES2094461T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US880087A 1987-01-30 1987-01-30
US13348087A 1987-12-22 1987-12-22

Publications (1)

Publication Number Publication Date
ES2094461T3 true ES2094461T3 (es) 1997-01-16

Family

ID=26678640

Family Applications (5)

Application Number Title Priority Date Filing Date
ES91113752T Expired - Lifetime ES2094174T5 (es) 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.
ES99201940T Expired - Lifetime ES2237031T3 (es) 1987-01-30 1988-01-27 Procedimiento para la preparacion de un producto polimero con un catalizador que consiste en un par ionico.
ES93201186T Expired - Lifetime ES2150931T5 (es) 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.
ES99201939T Expired - Lifetime ES2229620T3 (es) 1987-01-30 1988-01-27 Producto polimerico preparado con un catalizador que comprende un par de iones.
ES93201185T Expired - Lifetime ES2094461T3 (es) 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.

Family Applications Before (4)

Application Number Title Priority Date Filing Date
ES91113752T Expired - Lifetime ES2094174T5 (es) 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.
ES99201940T Expired - Lifetime ES2237031T3 (es) 1987-01-30 1988-01-27 Procedimiento para la preparacion de un producto polimero con un catalizador que consiste en un par ionico.
ES93201186T Expired - Lifetime ES2150931T5 (es) 1987-01-30 1988-01-27 Catalizadores, metodo para preparar estos catalizadores y metodo para usar dichos catalizadores.
ES99201939T Expired - Lifetime ES2229620T3 (es) 1987-01-30 1988-01-27 Producto polimerico preparado con un catalizador que comprende un par de iones.

Country Status (20)

Country Link
EP (6) EP0277004A1 (es)
JP (5) JP2965572B2 (es)
KR (1) KR960015192B1 (es)
AT (5) ATE145211T1 (es)
AU (1) AU617990B2 (es)
BR (1) BR8805026A (es)
CA (3) CA1339142C (es)
CZ (1) CZ57988A3 (es)
DE (6) DE3855668T2 (es)
DK (1) DK548888A (es)
ES (5) ES2094174T5 (es)
FI (1) FI101477B (es)
HU (1) HU211065B (es)
IL (1) IL85097A (es)
NO (1) NO179589C (es)
PL (1) PL159196B1 (es)
PT (1) PT86672A (es)
RU (2) RU2139291C1 (es)
WO (1) WO1988005793A1 (es)
YU (2) YU45838B (es)

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