IT1277696B1 - Catalizzatori per la polimerizzazione di alfa-olefine - Google Patents

Catalizzatori per la polimerizzazione di alfa-olefine

Info

Publication number
IT1277696B1
IT1277696B1 IT95MI002731A ITMI952731A IT1277696B1 IT 1277696 B1 IT1277696 B1 IT 1277696B1 IT 95MI002731 A IT95MI002731 A IT 95MI002731A IT MI952731 A ITMI952731 A IT MI952731A IT 1277696 B1 IT1277696 B1 IT 1277696B1
Authority
IT
Italy
Prior art keywords
olefine
alfa
catalysts
polymerization
Prior art date
Application number
IT95MI002731A
Other languages
English (en)
Inventor
Viviano Banzi
Paolo Biagini
Roberto Santi
Giampiero Borsotti
Gabriele Lugli
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Publication of ITMI952731A0 publication Critical patent/ITMI952731A0/it
Priority to IT95MI002731A priority Critical patent/IT1277696B1/it
Priority to ES96119042T priority patent/ES2160757T3/es
Priority to DE69614814T priority patent/DE69614814T2/de
Priority to EP96119042A priority patent/EP0780395B1/en
Priority to US08/761,140 priority patent/US5917072A/en
Priority to MXPA/A/1996/006464A priority patent/MXPA96006464A/xx
Priority to KR1019960068263A priority patent/KR100430636B1/ko
Priority to BR9606135A priority patent/BR9606135A/pt
Priority to CA002193713A priority patent/CA2193713C/en
Priority to CN96121599A priority patent/CN1099426C/zh
Priority to TW085115846A priority patent/TW428001B/zh
Priority to JP34405396A priority patent/JP4014681B2/ja
Publication of ITMI952731A1 publication Critical patent/ITMI952731A1/it
Application granted granted Critical
Publication of IT1277696B1 publication Critical patent/IT1277696B1/it

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
IT95MI002731A 1995-12-22 1995-12-22 Catalizzatori per la polimerizzazione di alfa-olefine IT1277696B1 (it)

Priority Applications (12)

Application Number Priority Date Filing Date Title
IT95MI002731A IT1277696B1 (it) 1995-12-22 1995-12-22 Catalizzatori per la polimerizzazione di alfa-olefine
ES96119042T ES2160757T3 (es) 1995-12-22 1996-11-28 Catalizadores para la polimerizacion de alfa-olefinas.
DE69614814T DE69614814T2 (de) 1995-12-22 1996-11-28 Alpha-Olefinpolymerizationskatalysatoren
EP96119042A EP0780395B1 (en) 1995-12-22 1996-11-28 Catalysts for the polymerization of alpha-olefins
US08/761,140 US5917072A (en) 1995-12-22 1996-12-06 Catalysts for the polymerization of alpha-olefins
MXPA/A/1996/006464A MXPA96006464A (en) 1995-12-22 1996-12-16 Catalysts for polymerization dealfa-olefi
KR1019960068263A KR100430636B1 (ko) 1995-12-22 1996-12-19 알파-올레핀의중합용촉매
BR9606135A BR9606135A (pt) 1995-12-22 1996-12-20 Catalisadores para a polimerização de alfa-olefinas
CA002193713A CA2193713C (en) 1995-12-22 1996-12-20 Catalysts for the polymerization of alpha-olefins
CN96121599A CN1099426C (zh) 1995-12-22 1996-12-20 用于α－烯烃聚合的催化剂
TW085115846A TW428001B (en) 1995-12-22 1996-12-21 Catalysts for the polymerization of alpha-olefins
JP34405396A JP4014681B2 (ja) 1995-12-22 1996-12-24 アルファ−オレフィン重合用触媒

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT95MI002731A IT1277696B1 (it) 1995-12-22 1995-12-22 Catalizzatori per la polimerizzazione di alfa-olefine

Publications (3)

Publication Number Publication Date
ITMI952731A0 ITMI952731A0 (it) 1995-12-22
ITMI952731A1 ITMI952731A1 (it) 1997-06-22
IT1277696B1 true IT1277696B1 (it) 1997-11-11

Family

ID=11372797

Family Applications (1)

Application Number Title Priority Date Filing Date
IT95MI002731A IT1277696B1 (it) 1995-12-22 1995-12-22 Catalizzatori per la polimerizzazione di alfa-olefine

Country Status (11)

Country Link
US (1) US5917072A (it)
EP (1) EP0780395B1 (it)
JP (1) JP4014681B2 (it)
KR (1) KR100430636B1 (it)
CN (1) CN1099426C (it)
BR (1) BR9606135A (it)
CA (1) CA2193713C (it)
DE (1) DE69614814T2 (it)
ES (1) ES2160757T3 (it)
IT (1) IT1277696B1 (it)
TW (1) TW428001B (it)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5689961A (en) 1996-01-30 1997-11-25 Organogenesis Inc. Ice seeding apparatus for cryopreservation systems
US6693157B2 (en) * 2002-04-08 2004-02-17 Equistar Chemicals, Lp Olefin polymerization catalysts containing triquinane ligands
US6774078B1 (en) * 2003-04-23 2004-08-10 Equistar Chemicals, Lp Olefin polymerization catalysts based on annulated cyclopentadienyl ligands
EP1650232A1 (en) * 2004-10-25 2006-04-26 Total Petrochemicals Research Feluy LDPE-Like polymers with bisindenyl-based ligands having different rings
EP2523983B1 (en) 2010-01-14 2018-03-21 ExxonMobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
WO2011102946A1 (en) 2010-02-19 2011-08-25 Exxonmobil Chemical Parents Inc. Elastomeric polymer blends and processes for their production
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
WO2016076969A1 (en) 2014-11-12 2016-05-19 Exxonmobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
KR101975695B1 (ko) 2015-06-15 2019-05-07 엑손모빌 케미칼 패턴츠 인코포레이티드 연속 용액 중합 공정
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
ES2894028T3 (es) * 2017-09-28 2022-02-11 Univation Tech Llc Síntesis de compuestos orgánicos cíclicos y metalocenos
BR122022024561B1 (pt) * 2017-09-28 2023-12-12 Univation Technologies, Llc Composto
WO2020060745A1 (en) 2018-09-19 2020-03-26 Exxonmobil Chemical Patents Inc. Devolatilization processes
EP3856752A1 (en) * 2018-09-28 2021-08-04 Dow Global Technologies LLC Synthesis of substituted cyclopentadiene compounds and metallocenes
WO2020068419A1 (en) 2018-09-28 2020-04-02 Dow Global Technologies Llc Synthesis of cyclopentenones
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
EP4077424A2 (en) 2019-12-17 2022-10-26 ExxonMobil Chemical Patents Inc. Solution polymerization process for making high-density polyethylene long-chain branching
WO2023097161A1 (en) 2021-11-23 2023-06-01 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1178732A (en) * 1981-06-09 1984-11-27 Eiji Aoishi Polyvinyl chloride resinous composition and product thereof
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
KR950000743A (ko) * 1993-06-28 1995-01-03 카렌 엘. 존슨 에틸렌/프로필렌 공중합체 고무
JP3247923B2 (ja) * 1993-12-21 2002-01-21 三井化学株式会社 新規メタロセン化合物及びそれを用いたオレフィンの重合方法
IT1273661B (it) * 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
JP3338190B2 (ja) * 1994-08-17 2002-10-28 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法

Also Published As

Publication number Publication date
TW428001B (en) 2001-04-01
CA2193713C (en) 2006-10-03
ITMI952731A0 (it) 1995-12-22
CN1158861A (zh) 1997-09-10
CN1099426C (zh) 2003-01-22
US5917072A (en) 1999-06-29
CA2193713A1 (en) 1997-06-23
BR9606135A (pt) 1998-11-03
EP0780395B1 (en) 2001-08-29
MX9606464A (es) 1997-09-30
DE69614814D1 (de) 2001-10-04
DE69614814T2 (de) 2002-04-11
EP0780395A1 (en) 1997-06-25
ES2160757T3 (es) 2001-11-16
ITMI952731A1 (it) 1997-06-22
KR100430636B1 (ko) 2004-06-16
JP4014681B2 (ja) 2007-11-28
KR970033038A (ko) 1997-07-22
JPH09188711A (ja) 1997-07-22

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