DE3855668D1 - Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zur deren Anwendung - Google Patents

Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zur deren Anwendung

Info

Publication number
DE3855668D1
DE3855668D1 DE3855668T DE3855668T DE3855668D1 DE 3855668 D1 DE3855668 D1 DE 3855668D1 DE 3855668 T DE3855668 T DE 3855668T DE 3855668 T DE3855668 T DE 3855668T DE 3855668 D1 DE3855668 D1 DE 3855668D1
Authority
DE
Germany
Prior art keywords
sub
radicals
catalysts
sup
zirconium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
DE3855668T
Other languages
English (en)
Other versions
DE3855668T2 (de
Inventor
Howard William Turner
Gregory George Hlatky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26678640&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE3855668(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE3855668D1 publication Critical patent/DE3855668D1/de
Application granted granted Critical
Publication of DE3855668T2 publication Critical patent/DE3855668T2/de
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
DE3855668T 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zur deren Anwendung Revoked DE3855668T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US880087A 1987-01-30 1987-01-30
US13348087A 1987-12-22 1987-12-22

Publications (2)

Publication Number Publication Date
DE3855668D1 true DE3855668D1 (de) 1996-12-19
DE3855668T2 DE3855668T2 (de) 1997-03-20

Family

ID=26678640

Family Applications (6)

Application Number Title Priority Date Filing Date
DE3856577T Expired - Lifetime DE3856577T2 (de) 1987-01-30 1988-01-27 Verfahren zur Herstellung eines Polymerisationproduktes mit einem aus einen Ionenpaar bestehenden Katalysator
DE3855666T Expired - Lifetime DE3855666T3 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3855666A Expired - Lifetime DE3855666T4 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3856424T Expired - Lifetime DE3856424T3 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3856574T Expired - Lifetime DE3856574T3 (de) 1987-01-30 1988-01-27 Mit einem Katalysator der ein Ionenpaar enthält hergestelltes Polymerprodukt
DE3855668T Revoked DE3855668T2 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zur deren Anwendung

Family Applications Before (5)

Application Number Title Priority Date Filing Date
DE3856577T Expired - Lifetime DE3856577T2 (de) 1987-01-30 1988-01-27 Verfahren zur Herstellung eines Polymerisationproduktes mit einem aus einen Ionenpaar bestehenden Katalysator
DE3855666T Expired - Lifetime DE3855666T3 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3855666A Expired - Lifetime DE3855666T4 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3856424T Expired - Lifetime DE3856424T3 (de) 1987-01-30 1988-01-27 Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
DE3856574T Expired - Lifetime DE3856574T3 (de) 1987-01-30 1988-01-27 Mit einem Katalysator der ein Ionenpaar enthält hergestelltes Polymerprodukt

Country Status (20)

Country Link
EP (6) EP0277004A1 (de)
JP (5) JP2965572B2 (de)
KR (1) KR960015192B1 (de)
AT (5) ATE286515T1 (de)
AU (1) AU617990B2 (de)
BR (1) BR8805026A (de)
CA (3) CA1339142C (de)
CZ (1) CZ57988A3 (de)
DE (6) DE3856577T2 (de)
DK (1) DK548888A (de)
ES (5) ES2150931T5 (de)
FI (1) FI101477B1 (de)
HU (1) HU211065B (de)
IL (1) IL85097A (de)
NO (1) NO179589C (de)
PL (1) PL159196B1 (de)
PT (1) PT86672A (de)
RU (2) RU2062649C1 (de)
WO (1) WO1988005793A1 (de)
YU (2) YU45838B (de)

Families Citing this family (650)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331228A (ja) * 1971-11-18 1993-12-14 Idemitsu Kosan Co Ltd ポリオレフィンの製造方法
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US7163907B1 (en) * 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
SU1723116A1 (ru) * 1988-04-15 1992-03-30 Оренбургский Государственный Медицинский Институт Штамм бактерий BacILLUS SUвтILIS, используемый дл получени препарата дл профилактики и лечени воспалительных процессов и аллергических заболеваний
US5223468A (en) * 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US4892851A (en) † 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5243002A (en) * 1988-07-15 1993-09-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US5225500A (en) * 1988-07-15 1993-07-06 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5223467A (en) * 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US5158920A (en) * 1988-07-15 1992-10-27 Fina Technology, Inc. Process for producing stereospecific polymers
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5162278A (en) * 1988-07-15 1992-11-10 Fina Technology, Inc. Non-bridged syndiospecific metallocene catalysts and polymerization process
JP3048591B2 (ja) * 1989-04-11 2000-06-05 三井化学株式会社 シンジオタクチックポリオレフィンの製造方法
US6255425B1 (en) 1989-04-28 2001-07-03 Mitsui Chemicals, Inc. Syndiotactic polypropylene copolymer and extruded polypropylene articles
JP2795474B2 (ja) * 1989-07-27 1998-09-10 三井化学株式会社 オレフィン重合用触媒成分およびオレフィン重合用触媒ならびにオレフィンの重合方法
US5004820A (en) * 1989-08-07 1991-04-02 Massachusetts Institute Of Technology Preparation of chiral metallocene dihalides
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US6686488B2 (en) 1989-08-31 2004-02-03 The Dow Chemical Company Constrained geometry addition polymerization catalysts
US6075077A (en) * 1989-08-31 2000-06-13 The Dow Chemical Company Asphalt, bitumen, and adhesive compositions
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US6825369B1 (en) 1989-09-14 2004-11-30 The Dow Chemical Company Metal complex compounds
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
US5036034A (en) * 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
DE69026907T2 (de) * 1989-10-10 1996-10-10 Fina Technology Metallocenkatalysator mit Lewissäure und Alkylaluminium
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
CA2027146C (en) * 1989-10-10 2001-07-17 Abbas Razavi Process and catalyst for producing syndiotactic polymers
CA2027123C (en) * 1989-10-30 2001-09-04 Michael J. Elder Metallocene catalysts for polymerization of olefins
DE69026679T3 (de) * 1989-10-30 2005-10-06 Fina Technology, Inc., Houston Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US5145818A (en) * 1989-12-29 1992-09-08 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
ES2141797T5 (es) * 1990-01-02 2008-06-01 Exxonmobil Chemical Patents Inc. Catalizadores ionicos de metalocenos soportados para la polimerizacion de olefinas.
AU7324491A (en) * 1990-02-09 1991-09-03 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
JP3020250B2 (ja) * 1990-04-09 2000-03-15 三井化学株式会社 シンジオタクチックポリプロピレンの製造方法
US5516739A (en) * 1990-04-20 1996-05-14 The University Of North Carolina At Chapel Hill Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide
EP0551277B2 (de) * 1990-06-22 2005-03-09 ExxonMobil Chemical Patents Inc. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
EP0500944B1 (de) * 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
WO1992005208A1 (en) * 1990-09-14 1992-04-02 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY
DE69129405T3 (de) * 1990-10-05 2001-10-04 Idemitsu Kosan Co Verfahren zur herstellung von cycloolefinpolymeren und cycloolefincopolymeren
EP0513380B2 (de) * 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Verfahren zur herstellung von olefinpolymeren
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2840462B2 (ja) * 1990-12-28 1998-12-24 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5262498A (en) * 1991-01-12 1993-11-16 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
US5169818A (en) * 1991-01-12 1992-12-08 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) * 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
JP3117231B2 (ja) * 1991-03-11 2000-12-11 三井化学株式会社 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法
JP2939354B2 (ja) * 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
ATE154367T1 (de) * 1991-03-27 1997-06-15 Idemitsu Kosan Co Verfahren zur herstellung eines styrolpolymerisats
JP2927566B2 (ja) * 1991-03-28 1999-07-28 出光興産株式会社 スチレン系共重合体の製造方法
EP0505997B1 (de) * 1991-03-29 1997-05-28 Idemitsu Kosan Company Limited Verfahren zur Herstellung eines Homo- oder Copolymerisates des Styrols
EP0516018B1 (de) 1991-05-27 1996-03-27 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
US5886117A (en) * 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
TW300901B (de) 1991-08-26 1997-03-21 Hoechst Ag
KR100262831B1 (ko) * 1991-11-07 2000-08-01 벤 씨. 카덴헤드 폴리올레핀의 제조방법
WO1993011172A1 (en) * 1991-11-25 1993-06-10 Exxon Chemical Patents Inc. Polyonic transition metal catalyst composition
TW309523B (de) * 1991-11-30 1997-07-01 Hoechst Ag
TW254950B (de) * 1992-03-02 1995-08-21 Shell Internat Res Schappej Bv
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5455307A (en) * 1992-04-03 1995-10-03 Exxon Chemical Patents Inc. Polymeric stabilizers for polyolefins
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
EP0572990B2 (de) * 1992-06-04 2000-08-16 MITSUI TOATSU CHEMICALS, Inc. Verfahren zur Herstellung von einem Ethylencopolymeren
ATE164169T1 (de) * 1992-06-18 1998-04-15 Montell Technology Company Bv Verfahren zur herstellung eines ethylenischen copolymerisats
DE69326463T2 (de) * 1992-07-01 2000-05-04 Exxon Chemical Patents Inc Olefinpolymerisationskatalysatoren auf basis von uebergangsmetallen
US5407882A (en) * 1992-08-04 1995-04-18 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
DE69333470T2 (de) * 1992-10-28 2004-08-19 Idemitsu Kosan Co. Ltd. Olefincopolymere und verfahren zu ihrer herstellung
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5322728A (en) * 1992-11-24 1994-06-21 Exxon Chemical Patents, Inc. Fibers of polyolefin polymers
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
GB9226905D0 (en) * 1992-12-24 1993-02-17 Wellcome Found Pharmaceutical preparation
TW274100B (de) 1993-02-12 1996-04-11 Hoechst Ag
DE4304310A1 (de) * 1993-02-12 1994-08-18 Hoechst Ag Teilkristalline Cycloolefin-Copolymer-Folie
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
EP0690079B1 (de) * 1993-02-22 2002-07-03 Idemitsu Kosan Company Limited Ethylencopolymer, dieses enthaltende thermoplastische harzzusammensetzung und verfahren zu seiner herstellung
WO1994019382A1 (en) * 1993-02-24 1994-09-01 Idemitsu Kosan Co., Ltd. Propylene block copolymer, process for producing the same, and modified copolymer produced therefrom
JP3077940B2 (ja) * 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
DE69427999T3 (de) * 1993-06-07 2012-09-27 Mitsui Chemicals, Inc. Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens
PL175846B1 (pl) * 1993-06-24 1999-02-26 Dow Chemical Co Kompleksy tytanu (II) i sposób polimeryzacji addycyjnej
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
IT1271407B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti
US5475067A (en) * 1993-09-16 1995-12-12 Exxon Chemical Patents Inc. Process for polyolefin production using short residence time reactors
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
FI945959A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
US6391817B1 (en) 1993-12-28 2002-05-21 Exxonmobil Chemical Patents Inc. Method for producing a prepolymerized catalyst
US5674950A (en) * 1994-03-07 1997-10-07 Exxon Chemical Patents Inc. Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof
US5691422A (en) * 1994-03-07 1997-11-25 Exxon Chemical Patents Inc. Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
US5502017A (en) * 1994-03-10 1996-03-26 Northwestern University Metallocene catalyst containing bulky organic group
EP0750642B1 (de) * 1994-03-17 2000-01-05 Exxon Chemical Patents Inc. Sprühgetrockneter emulsionspolymer als katalysatorträger
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
KR100388331B1 (ko) * 1994-04-11 2003-10-11 미쓰이 가가쿠 가부시키가이샤 프로필렌중합체조성물의제조방법및프로필렌중합체조성물
EP0816395B1 (de) * 1994-04-11 2000-07-19 Mitsui Chemicals, Inc. Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
DE4416894A1 (de) * 1994-05-13 1995-11-16 Witco Gmbh Verfahren zur Synthese von Mono- und Dimethylmetallocenen und deren Lösungen speziell für den Einsatz zur Polymerisation von Olefinen
DE4420456A1 (de) * 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
ES2313762T3 (es) * 1994-06-13 2009-03-01 Basell Polyolefine Gmbh Compuestos de metales de transicion.
US5936041A (en) * 1994-06-17 1999-08-10 Exxon Chemical Patents Inc Dispersant additives and process
US5561216A (en) * 1994-07-01 1996-10-01 University Of North Carolina At Chapel Hill Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide
DE4424227A1 (de) 1994-07-09 1996-01-11 Hoechst Ag Organometallverbindung
BR9508269A (pt) * 1994-07-11 1999-06-01 Exxon Chemical Patents Inc Dispersante solúvel em óleo processo para a produção do mesmo uso do dispersante e composição oleaginosa
US6465384B1 (en) * 1994-08-02 2002-10-15 The Dow Chemical Company Biscyclopentadienyl diene complexes
TW369547B (en) 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
DE4434640C1 (de) 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
DE4436113A1 (de) 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
US5565128A (en) * 1994-10-12 1996-10-15 Exxon Chemical Patents Inc Lubricating oil mannich base dispersants derived from heavy polyamine
EP0745615B1 (de) * 1994-12-20 2004-07-28 Mitsui Chemicals, Inc. Verfahren zur herstellung von ethylenpolymer und ethylenpolymer
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
CN1076282C (zh) 1995-03-02 2001-12-19 三井化学株式会社 聚丙烯复合膜
ATE172992T1 (de) * 1995-06-12 1998-11-15 Targor Gmbh Übergangsmetallverbindung
US5766713A (en) * 1995-06-14 1998-06-16 Exxon Chemical Patents Inc. Elastomeric vehicle hoses
US5674613A (en) 1995-06-14 1997-10-07 Exxon Chemical Patents Inc. Electrical devices including ethylene, a-olefin, vinyl norbornene elastomeric polymers
KR19990028461A (ko) * 1995-06-28 1999-04-15 알베르투스 빌헬무스 요아네스 ㅔ스트라텐 유기금속 화합물을 포함한 촉매 조성물
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
US5652202A (en) * 1995-08-15 1997-07-29 Exxon Chemical Patents Inc. Lubricating oil compositions
EP0791627A4 (de) 1995-09-13 1998-11-25 Mitsui Petrochemical Ind Harzzusammensetzung und ihre verwendung
US5558802A (en) * 1995-09-14 1996-09-24 Exxon Chemical Patents Inc Multigrade crankcase lubricants with low temperature pumpability and low volatility
GB9519381D0 (en) 1995-09-22 1995-11-22 Exxon Chemical Patents Inc Rubber toughened blends
EP0856526B1 (de) * 1995-10-18 2002-08-28 Chisso Corporation Olefin(co)polymerzusammensetzung, verfahren zu dessen herstellung, katalysator for olefin(co)polymerisation und verfahren zu dessen herstellung
DE19539650A1 (de) * 1995-10-25 1997-04-30 Studiengesellschaft Kohle Mbh Zirconocene und Hafnocene mit borylierten Cyclopentadienyl-Liganden und das Verfahren zu ihrer Herstellung
IT1276070B1 (it) 1995-10-31 1997-10-24 Siac It Additivi Carburanti Processo per la preparazione di polimeri a base di etilene a basso peso molecolare
DE19546501A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
DE19546500A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Verfahren zur Herstellung eines Cycloolefincopolymeren
CA2192862A1 (en) 1995-12-15 1997-06-16 Frederick John Karol Process for the production of long-chain branched polyolefins
IT1277696B1 (it) 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
EP0889910B1 (de) * 1996-03-27 2003-03-19 Dow Global Technologies Inc. Lösungspolymerisationsverfahren mit dispergierten katalysator-aktivierer
ES2129323B1 (es) 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
EP1083188A1 (de) 1999-09-10 2001-03-14 Fina Research S.A. Katalysator und Verfahren zur Herstellung von syndiotaktischen / ataktischen Block-Polyolefinen
GB9617507D0 (en) 1996-08-21 1996-10-02 Exxon Chemical Patents Inc Chemically modified elastomeres and blends thereof
ATE256706T1 (de) * 1996-10-30 2004-01-15 Repsol Quimica Sa Katalysatorsysteme für die polymerisation und die copolymerisation von alpha-olefinen
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica Sa Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
ES2154017T3 (es) 1996-10-31 2001-03-16 Repsol Quimica Sa Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas.
DE69721807T2 (de) 1996-11-15 2004-03-04 Basell Polyolefine Gmbh Heterocyclische metallocene und polymerisationskatalysatoren
US5763533A (en) * 1996-12-10 1998-06-09 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5952427A (en) * 1996-12-10 1999-09-14 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US6110858A (en) * 1996-12-18 2000-08-29 Tosoh Corporation Olefin polymerization catalysts and process for producing olefin polymers
US6660816B2 (en) 1996-12-20 2003-12-09 Sumitomo Chemical Company, Limited Process for preparing olefin polymers
CN1216553A (zh) 1996-12-20 1999-05-12 住友化学工业株式会社 烯烃聚合物及其薄膜或片材,以及烯烃聚合物的制造方法
US6180736B1 (en) 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
EP0856546A1 (de) 1997-01-31 1998-08-05 Dsm N.V. Verzweigte Polyolefine
KR100432537B1 (ko) 1997-01-31 2004-08-16 미쓰이 가가쿠 가부시키가이샤 윤활유,윤활유조성물,연료유조성물
EP0856524A1 (de) 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogene Katalysatorzusammensetzungen zur Polymerisation von Olefinen, Verfahren zu deren Herstellung und deren Verwendung
BR9806952A (pt) 1997-02-07 2000-03-21 Exxon Chemical Patents Inc Preparação de macrÈmeros contendo vinila.
WO1998034971A1 (en) 1997-02-07 1998-08-13 Exxon Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
DE19707236A1 (de) 1997-02-24 1998-08-27 Targor Gmbh Katalysatorzusammensetzung
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
EP0972800A4 (de) 1997-04-02 2004-06-16 Chisso Corp Modifizierte olefin-(co)polymer zusammensetzung, verfahren zu deren herstellung und modifizierte olefin-(co)polymer formmasse
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
GB9713741D0 (en) 1997-06-27 1997-09-03 Bp Chem Int Ltd Polymerisation catalysts
JP3120370B2 (ja) 1997-07-30 2000-12-25 オーテックス株式会社 光潜在性重合開始剤
DE19732804A1 (de) 1997-07-30 1999-02-04 Bayer Ag Katalysatoren auf Basis von Fulven-Metallkomplexen
EP1000093B1 (de) * 1997-08-01 2001-12-12 The Dow Chemical Company Zwiterionischer katalysator aktivator
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7026404B2 (en) 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6100224A (en) * 1997-10-01 2000-08-08 Exxon Chemical Patents Inc Copolymers of ethylene α-olefin macromers and dicarboxylic monomers and derivatives thereof, useful as additives in lubricating oils and in fuels
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
CA2309174A1 (en) 1997-11-07 1999-05-20 Bayer Aktiengesellschaft Method for producing fulvene metal complexes
KR100422025B1 (ko) 1997-12-01 2004-03-10 아사히 가세이 가부시키가이샤 올레핀 중합용 촉매 및 상기 촉매를 사용한 올레핀의 중합방법
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
SG74682A1 (en) 1997-12-22 2000-08-22 Mitsui Chemicals Inc Catalyst component for ethylenically unsaturated monomer polymerization catalyst for ethylenically unsaturated monomer polymerization and process for ethylenically unsaturated monomer polymerization using said catalyst
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19804970A1 (de) 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE19808254A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Chemische Verbindung
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
EA200000902A1 (ru) 1998-03-04 2001-04-23 Эксон Кемикэл Пейтентс Инк. Способ высокотемпературной полимеризации олефинов
DE19812881A1 (de) 1998-03-24 1999-10-07 Bayer Ag Neue dendrimere Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung als Katalysatoren
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
ES2211013T3 (es) 1998-04-27 2004-07-01 Repsol Quimica S.A. Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas.
US6342568B1 (en) 1998-05-06 2002-01-29 Mitsui Chemicals, Inc. Metallocene compound, and process for preparing polyolefin by using it
CA2327497A1 (en) 1998-05-13 1999-11-18 Exxon Chemical Patents, Inc. Propylene homopolymers and methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
WO1999064476A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
EP1867663B1 (de) 1998-06-25 2009-03-25 Idemitsu Kosan Co., Ltd. Propylenpolymer und Zusammensetzung damit, Formobjekt und Laminat damit sowie Verfahren zur Herstellung von Propylenpolymer und einer Zusammensetzung damit
DE19828271A1 (de) 1998-06-25 1999-12-30 Elenac Gmbh Verfahren zur Herstellung eines geträgerten Katalysatorsystems
EP1098934A1 (de) 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastische mischung mit kristallpolymeren und kristallisierbaren polymeren des propens
ATE355308T1 (de) * 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
CA2337003A1 (en) * 1998-07-17 2000-01-27 Arquimedes R. Karam Process for polymerizing a cationically polymerizable olefin
BR9913647B1 (pt) 1998-08-26 2008-11-18 polipropileno ramificado e processo para produzir o mesmo.
US6177527B1 (en) * 1998-09-08 2001-01-23 Union Carbide Chemical & Plastics Technology Corporation Process for the preparation of polyethylene or polypropylene
US6555494B2 (en) 1998-10-23 2003-04-29 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components
US6462212B1 (en) 1998-10-23 2002-10-08 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6812182B2 (en) 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6492292B2 (en) 1998-10-23 2002-12-10 Albemarle Corporation Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components
KR100581796B1 (ko) 1998-10-29 2006-05-23 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 압출 가공성을 갖는 에틸렌 알파-올레핀엘라스토머성 중합체 조성물
US6147173A (en) * 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
DE19858016A1 (de) 1998-12-16 2000-06-21 Basf Ag Neue Metallocenkomplexe
DE69938061D1 (de) * 1998-12-21 2008-03-13 Exxonmobil Chem Patents Inc Verfahren zur herstellung von verzweigten ethylen-propylen copolymeren
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
JP2002540260A (ja) 1999-03-29 2002-11-26 ビーエーエスエフ アクチェンゲゼルシャフト オレフィンの重合
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
DE19917985A1 (de) 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
US6479598B1 (en) 1999-07-20 2002-11-12 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with BF3 catalyst
JP3808243B2 (ja) 1999-07-27 2006-08-09 三井化学株式会社 軟質樹脂組成物
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
KR100614993B1 (ko) 1999-08-13 2006-08-25 바젤 폴리올레핀 게엠베하 에틸렌과 Ｃ₃-Ｃ₁₂α 올레핀의 공중합체
CN1209404C (zh) 1999-09-01 2005-07-06 埃克森化学专利公司 透气膜及其制备方法
US6403743B1 (en) 1999-09-14 2002-06-11 Exxonmobil Chemical Patents Inc. Petroleum resins and their production with supported catalyst
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
WO2001032758A1 (en) 1999-11-04 2001-05-10 Exxon Chemical Patents Inc. Propylene copolymer foams and their use
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
WO2001046278A2 (en) 1999-12-21 2001-06-28 Exxon Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
US6852809B2 (en) 1999-12-27 2005-02-08 Sumitomo Chemical Company, Limited Catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer
EP2267041B1 (de) 2000-01-26 2015-07-08 Mitsui Chemicals, Inc. Olefin-Multiblockcopolymer mit sehr niedriger Polydispersität und Verfahren zu seiner Herstellung
DE10003581A1 (de) 2000-01-28 2001-08-02 Bayer Ag Metallorganische Verbindungen mit anellierten Indenyl Liganden
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
EP1209179B1 (de) 2000-03-31 2005-11-02 Mitsui Chemicals, Inc. Verfahren zur herstellung einer polyolefinzusammensetzung
DE10017430A1 (de) 2000-04-07 2001-10-11 Basf Ag Polymerisationskatalysator
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
DE10017660A1 (de) 2000-04-08 2001-10-11 Basf Ag Verfahren zur Herstellung eines Katalysatorsystems für die Polymerisation von Olefinen
DE10022497A1 (de) 2000-05-09 2001-11-15 Bayer Ag Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden
US6635733B2 (en) 2000-05-23 2003-10-21 Chisso Corporation Elastomeric polypropylene
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
DE10025412A1 (de) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
US6346636B1 (en) 2000-06-23 2002-02-12 Exxonmobil Chemical Patents, Inc. Siloxy substituted cocatalyst activators for olefin polymerization
US6541410B1 (en) 2000-06-23 2003-04-01 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
TW541318B (en) 2000-07-04 2003-07-11 Mitsui Chemicals Inc Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
JP2004502697A (ja) 2000-07-06 2004-01-29 ビーエーエスエフ　アクチェンゲゼルシャフト 金属化合物、およびオレフィン重合における該金属化合物の使用法
BR0107037A (pt) 2000-07-26 2003-06-10 Mitsui Chemicals Inc Polìmero de poliolefina ramificada e método de preparação da mesma
WO2002010227A1 (en) 2000-08-02 2002-02-07 Univation Technologies, Llc Method for producing highly productive supported ionic catalyst for gas phase polymerization
EP1260525B1 (de) 2000-08-22 2012-12-12 Idemitsu Kosan Co., Ltd. 1-butenpolymer und geformtes produkt welches aus diesem polymer besteht
DE60141777D1 (de) 2000-09-07 2010-05-20 Mitsui Chemicals Inc Polare Gruppen enthaltendes Olefin-Copolymer, Verfahren zu seiner Herstellung, dieses Copolymer enthaltende thermoplastische Harzzusammensetzung und deren Verwendung
US7074736B2 (en) 2000-10-31 2006-07-11 Rohm And Haas Company Hydrozirconated matrix and process for polyolefin production
WO2002038628A2 (en) 2000-11-07 2002-05-16 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
DE10059633A1 (de) 2000-12-01 2002-06-20 Hte Ag Verfahren und Vorrichtung zur Überführung von luftempfindlichen Substanzen
JP2007186718A (ja) * 2000-12-19 2007-07-26 Sunallomer Ltd オレフィン重合用触媒、オレフィン重合用触媒成分およびその保存方法ならびにオレフィン重合体の製造方法
BR0116320A (pt) 2000-12-19 2004-01-13 Sunallomer Ltd Catalisador de polimerização de olefina, componentes de catalisador de polimerização de olefina e processo para sua armazenagem, processo de produção de polìmeros de olefina
ATE485319T1 (de) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
DE10127926A1 (de) 2001-06-08 2002-12-12 Bayer Ag 1,3-disubstituierte Indenkomplexe
AU2002315077A1 (en) 2001-06-20 2003-01-08 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
JP2005522406A (ja) 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
CN1328032C (zh) 2001-07-25 2007-07-25 倍耐力轮胎公司 连续生产弹性体合成物的方法和设备
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
KR100440480B1 (ko) 2001-08-31 2004-07-14 주식회사 엘지화학 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법
EP1300423A1 (de) 2001-09-27 2003-04-09 Atofina Research S.A. Katalysatorsystem aus einer Mischung von Katalysatorbestandteilen zur Herstellung einer Polyolefinmischung
EP1298148A1 (de) 2001-09-27 2003-04-02 Atofina Research S.A. Katalysatorbestandteil, der ein Metallocen mit zwei Tetrahydroindenyl-Liganden enthält, zur Herstellung eines Polyolefins
CN100434444C (zh) 2001-10-19 2008-11-19 旭化成株式会社 烯烃聚合催化剂及使用该催化剂的烯烃聚合方法
WO2003040070A2 (en) 2001-11-02 2003-05-15 Exxonmobil Chemical Patents Inc. Dicops containing acetylenic substituents
EP1308450A3 (de) 2001-11-06 2003-10-01 Symyx Technologies, Inc. Titan-substituierte Pyridyl-Amin-Komplexe, Katalysatoren, und Verfahren zur Polymerisierung von Ethylen und Styren
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US7077977B2 (en) 2001-12-05 2006-07-18 Exxonmobil Chemical Patents Inc. Bulky borate activations
US7964128B2 (en) 2001-12-19 2011-06-21 Pirelli Pneumatici S.P.A. Process and apparatus for continuously producing an elastomeric composition
CN1268651C (zh) 2001-12-21 2006-08-09 陶氏环球技术公司 使烯烃聚合物中酸性或含卤化合物成为惰性的添加剂
CA2368724C (en) 2002-01-21 2011-06-14 Bayer Inc. Process for preparing isobutylene-based polymers
DE10211386A1 (de) 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
US6794514B2 (en) 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
US6841502B2 (en) 2002-04-24 2005-01-11 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US7060848B2 (en) 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7091292B2 (en) 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US8236215B2 (en) 2002-07-11 2012-08-07 Pirelli Pneumatici S.P.A. Process and apparatus for continuously producing an elastomeric composition
EP1527112B1 (de) 2002-07-31 2007-10-31 ExxonMobil Chemical Patents Inc. Silanvernetztes polyethylen
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
EP1531163A4 (de) * 2002-08-19 2006-06-28 Japan Polypropylene Corp Verfahren zur herstellung von polyolefin
CA2493274A1 (en) 2002-09-05 2004-03-18 Exxonmobil Chemical Patents Inc. Stretch film
EP1403288A1 (de) 2002-09-27 2004-03-31 ATOFINA Research Hafnocenverbindungen enthaltendes Dual-site Katalysatorsystem zur Herstellung von bimodalen Polyolefinen
EP2511305B1 (de) 2002-09-27 2019-05-29 Mitsui Chemicals, Inc. Verbrückte Metallocenverbindung zur Olefinpolymerisierung und Verfahren zur Polymerisierung von Olefin unter Verwendung davon
EP1403293A1 (de) 2002-09-27 2004-03-31 ATOFINA Research Société Anonyme Metallocenkatalysatorbestandteil, der ein Silyl Gruppe-enthaltender Cyclopentadienylring enthält
US7943700B2 (en) 2002-10-01 2011-05-17 Exxonmobil Chemical Patents Inc. Enhanced ESCR of HDPE resins
JP4728643B2 (ja) 2002-10-02 2011-07-20 ダウ グローバル テクノロジーズ エルエルシー 液状およびゲル状の低分子量エチレンポリマー類
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
JP4972284B2 (ja) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合のための複数触媒系及びそれらから生成されたポリマー
EP1554343B1 (de) 2002-10-17 2008-07-23 Dow Global Technologies Inc. Hochgefüllte polymerzusammensetzungen
AU2003301539A1 (en) 2002-10-23 2004-05-13 Mitsui Chemicals, Inc. Magnesium-containing carrier components and application thereof to olefin polymerization
DE10251513A1 (de) 2002-11-04 2004-05-19 Basf Ag Übergangsmetallkatalysatoren für (Co)Polymerisation von olefinischen Monomeren
US20040102311A1 (en) 2002-11-21 2004-05-27 Abbas Razavi Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
FR2852015B1 (fr) 2003-03-07 2007-06-22 Composantes catalytiques a geometrie contrainte comprenant un ligant fluorenyle et basees sur des metaux du groupe iiib
EP1985638B1 (de) 2003-03-28 2010-02-17 Mitsui Chemicals, Inc. Propylen-Copolymer, Polypropylen-Zusammensetzung, Verwendung davon, Übergangsmetallverbindungen und Katalysatoren zur Olefin-Polymerisation
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
CN101831022B (zh) 2003-08-19 2012-07-04 陶氏环球技术有限责任公司 适用于热熔粘合剂的共聚体及其制备方法
US8349929B2 (en) 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US8357749B2 (en) 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US7803865B2 (en) 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US8158711B2 (en) 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
FR2860170B1 (fr) 2003-09-29 2006-04-21 Atofina Res Liquides ioniques pour catalyseurs de polymerisation d'olefines
FR2860238B1 (fr) 2003-09-29 2006-07-21 Atofina Res Polyethylene bimodal
SG131121A1 (en) 2003-10-22 2007-04-26 Sumitomo Chemical Co Process for producing modified particle, carrier or catalyst component for addition polymerization, pre-polymerized catalyst component therefor, catalyst therefor, and addition polymer
WO2005063829A1 (en) 2003-12-23 2005-07-14 Basell Polyolefine Gmbh Catalyst system for olefin polymerization
US7211536B2 (en) 2004-10-22 2007-05-01 Fina Technology, Inc. Supported metallocene catalysts and their use in producing stereospecific polymers
EP1571163A1 (de) 2004-03-02 2005-09-07 Total Petrochemicals Research Feluy Ionische Flüssigkeiten als Lösungsmittel für Metallocenkatalyse
US7122691B2 (en) 2004-03-30 2006-10-17 Sumitomo Chemical Company, Limited Process for producing compound, catalyst component for addition polymerization, process for producing catalyst for addition polymerization, and process for producing addition polymer
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
US7592402B2 (en) 2004-04-30 2009-09-22 Sumitomo Chemical Company, Limited Process for producing modified particle; carrier; catalyst component for addition polymerization; process for producing catalyst for addition polymerization; and process for producing addition polymer
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
US7256296B2 (en) 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
WO2006036748A2 (en) 2004-09-22 2006-04-06 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
JP2008516068A (ja) 2004-10-13 2008-05-15 エクソンモービル・ケミカル・パテンツ・インク エラストマー性反応ブレンド組成物
US8093341B2 (en) 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
US7399874B2 (en) 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
EP1661921B1 (de) 2004-11-26 2019-07-17 Mitsui Chemicals, Inc. Synthetische Schmieröle und Schmierölzusammensetzung deren
WO2006066126A2 (en) 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US7588706B2 (en) 2004-12-16 2009-09-15 Exxonmobil Chemical Patents Inc. Multi-layer films with improved properties
DE602005026993D1 (de) 2004-12-21 2011-04-28 Dow Global Technologies Inc Klebstoffzusammensetzung auf polypropylenbasis
WO2006123759A1 (ja) 2005-05-18 2006-11-23 Mitsui Chemicals, Inc. オレフィン重合用触媒、オレフィン重合体の製造方法、プロピレン系共重合体の製造方法、プロピレン重合体、プロピレン系重合体組成物およびこれらの用途
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US7935760B2 (en) 2005-06-22 2011-05-03 Exxonmobil Chemical Patents Inc. Process of making a heterogeneous polymer blend
US7951872B2 (en) 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
US7928164B2 (en) 2005-06-22 2011-04-19 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and process of making the same
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
JP5079223B2 (ja) 2005-06-29 2012-11-21 出光興産株式会社 水分散性ポリオレフィン系樹脂組成物
EP1741486A1 (de) 2005-07-07 2007-01-10 Total Petrochemicals Research Feluy Katalysatorsysteme auf Basis von macrocyclischen Liganden
WO2007011832A1 (en) * 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
WO2007011462A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
EP1746111A1 (de) 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisationskatalysatorsystem basiert auf Dioxim-Liganden
CA2615982C (en) 2005-07-19 2012-02-21 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
EP1746112A1 (de) 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisationskatalysator auf Basis von Monooximliganden
US7989670B2 (en) 2005-07-19 2011-08-02 Exxonmobil Chemical Patents Inc. Process to produce high viscosity fluids
KR101141359B1 (ko) 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
ES2722200T3 (es) 2005-10-25 2019-08-08 Gen Cable Technologies Corp Composiciones de aislamiento libres de plomo mejoradas que contienen polímeros de metaloceno
BRPI0619338B1 (pt) 2005-10-26 2018-02-27 Dow Global Technologies Inc., Artigo tendo pelo menos duas camadas, fibra e tela
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
EP1806369A1 (de) 2005-12-22 2007-07-11 DSMIP Assets B.V. Zwitterionischer Katalysator mit einem Amidinliganden
EP1963347B1 (de) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
AU2006329980A1 (en) 2005-12-16 2007-07-05 Dow Global Technologies Inc. Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same
EP1801130A1 (de) 2005-12-22 2007-06-27 DSMIP Assets B.V. Zwitterionischer Katalysator mit einem monoanionischen zweizähnigen Iminliganden
EP1801131A1 (de) 2005-12-22 2007-06-27 DSMIP Assets B.V. Zwitterionischer Cyclopentadiengruppe enthaltender Katalysator
EP1803744A1 (de) 2005-12-22 2007-07-04 DSMIP Assets B.V. Zwitterionischer Katalysator mit einem Guanidinliganden
EP1801113A1 (de) 2005-12-22 2007-06-27 DSM IP Assets B.V. Zwitterionischer Phosphinimin-Katalysator
EP1803745A1 (de) 2005-12-22 2007-07-04 DSMIP Assets B.V. Zwitterionischer Katalysator mit einem Ketiminliganden
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
US20090127751A1 (en) 2006-03-10 2009-05-21 Mitsui Chemicals, Inc. Process for Producing Molded Product by Inflation Molding
EP1832579A1 (de) 2006-03-10 2007-09-12 Total Petrochemicals Research Feluy Polymerisation von Olefinen mit einem Komplex enthaltend einen Imino-Hydroxychinolin Liganden
EP2006071B1 (de) 2006-03-27 2012-02-22 Mitsui Chemicals, Inc. Verfahren zur herstellung eines formkörpers durch breitschlitzdüsenformen
JP2007261201A (ja) 2006-03-29 2007-10-11 Mitsui Chemicals Inc ブロー成形による成形体の製造方法
WO2007114009A1 (ja) 2006-03-30 2007-10-11 Mitsui Chemicals, Inc. 射出成形による成形体の製造方法
EP1847555A1 (de) 2006-04-18 2007-10-24 Borealis Technology Oy Mehrfach verzweigtes Polypropylen
EP1849791A1 (de) 2006-04-24 2007-10-31 Total Petrochemicals Research Feluy Polymerisation von Ethylen und Alpha-olefinen mit Pyridino-Iminophenolkomplexen
KR101060838B1 (ko) 2006-04-24 2011-08-30 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용비스-아릴아릴옥시 촉매계
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
WO2007136494A2 (en) 2006-05-17 2007-11-29 Dow Global Technologies Inc. Ethylene/ alpha-olefin/ diene solution polymerization process
CN101454356B (zh) * 2006-05-30 2011-11-09 雅宝公司 单位点催化剂活化剂、其制备方法及其在催化剂和烯烃聚合中的用途
US8921290B2 (en) 2006-06-06 2014-12-30 Exxonmobil Research And Engineering Company Gear oil compositions
US8834705B2 (en) 2006-06-06 2014-09-16 Exxonmobil Research And Engineering Company Gear oil compositions
US8299007B2 (en) 2006-06-06 2012-10-30 Exxonmobil Research And Engineering Company Base stock lubricant blends
US8501675B2 (en) 2006-06-06 2013-08-06 Exxonmobil Research And Engineering Company High viscosity novel base stock lubricant viscosity blends
US8535514B2 (en) 2006-06-06 2013-09-17 Exxonmobil Research And Engineering Company High viscosity metallocene catalyst PAO novel base stock lubricant blends
JP5555490B2 (ja) 2006-07-19 2014-07-23 エクソンモービル・ケミカル・パテンツ・インク メタロセン触媒を用いたポリオレフィンの製造方法
EP2050771B1 (de) 2006-07-31 2020-07-15 Mitsui Chemicals, Inc. Folie oder laminat, umfassend ethylenharz oder ethylenharzzusammensetzung
WO2008047878A1 (fr) 2006-10-20 2008-04-24 Mitsui Chemicals, Inc. Copolymère, modificateur de viscosité d'huile lubrifiante et composition d'huile lubrifiante
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
WO2008075717A1 (ja) 2006-12-19 2008-06-26 Mitsui Chemicals, Inc. オレフィン重合用固体状触媒、オレフィン重合方法及び該重合方法によって得られるオレフィン重合体粒子
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
EP2102282B1 (de) 2006-12-22 2011-02-09 Basell Polyolefine GmbH Multimodale polyethylenzusammensetzung, mischkatalysaotr und verfahren zur herstellung der zusammensetzung
US20100028578A1 (en) 2007-01-16 2010-02-04 Prime Polymer Co., Ltd. Blow molding ethylene resin composition and blow molded article therefrom
WO2008109628A1 (en) 2007-03-07 2008-09-12 Dow Global Technologies Inc. Tethered supported transition metal complex
DE102007015707A1 (de) 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
EP2169003B1 (de) 2007-06-14 2014-05-07 Mitsui Chemicals, Inc. Thermoplastische elastomerzusammensetzung
JP5226973B2 (ja) 2007-06-15 2013-07-03 三井化学株式会社 エチレン系共重合体、該共重合体を含む組成物ならびにその用途
MY152879A (en) 2007-07-04 2014-11-28 Mitsui Chemicals Inc Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts
US8513478B2 (en) 2007-08-01 2013-08-20 Exxonmobil Chemical Patents Inc. Process to produce polyalphaolefins
EP2112176A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Olefinpolymerisationskatalysatoren, deren Herstellung und Benutzung
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
ES2435568T3 (es) 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
CN105294779A (zh) 2007-11-19 2016-02-03 三井化学株式会社 交联茂金属化合物以及使用其的烯烃聚合用催化剂、以及使用该催化剂得到的乙烯系聚合物
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
EP2112173A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Katalysatorverbindungen und ihre Verwendung
EP2083046A1 (de) 2008-01-25 2009-07-29 ExxonMobil Chemical Patents Inc. Thermoplastische Elastomerzusammensetzungen
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins
EP2134801B1 (de) 2008-02-18 2011-11-02 Basell Polyolefine GmbH Poylmer-haftzusammensetzung
EP2093229A1 (de) 2008-02-25 2009-08-26 Total Petrochemicals Research Feluy Postmetallocen-Komplexe basierend auf bis(naphtoxy) Pyridin- und bis(naphtoxy) Thiophenliganden zur Polymerisierung von Ethylen und Alpha-Olefinen
US8865959B2 (en) 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production
EP2103634A1 (de) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Herstellung propylen-basierter polymere
KR101280685B1 (ko) 2008-03-27 2013-07-01 미쓰이 가가쿠 가부시키가이샤 수지 조성물 및 그 용도
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
CN104059283B (zh) 2008-03-31 2017-04-12 三井化学株式会社 树脂组合物和熔融袋
WO2009123800A1 (en) 2008-03-31 2009-10-08 Exxonmobil Chemical Patents Inc. Production of shear-stable high viscosity pao
EP2113507A1 (de) 2008-04-28 2009-11-04 Total Petrochemicals Research Feluy Steril gehinderte metallische Bidentat- und Tridentat-Naphthoxy-Iminkomplexe
US7939610B2 (en) 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US8283400B2 (en) 2008-06-09 2012-10-09 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8431642B2 (en) 2008-06-09 2013-04-30 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8242198B2 (en) 2008-06-09 2012-08-14 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
JP2011528738A (ja) 2008-07-23 2011-11-24 バーゼル・ポリオレフィン・ゲーエムベーハー 両立しないオレフィン重合触媒系間の変移方法
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
CN102731694B (zh) 2008-08-01 2015-04-01 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
WO2010021304A1 (ja) 2008-08-19 2010-02-25 三井化学株式会社 混合触媒によるオレフィン重合体の製造方法
US8394746B2 (en) 2008-08-22 2013-03-12 Exxonmobil Research And Engineering Company Low sulfur and low metal additive formulations for high performance industrial oils
CN102197081B (zh) 2008-08-29 2013-08-21 巴塞尔聚烯烃股份有限公司 注塑用聚乙烯
US8399586B2 (en) 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
WO2010033601A1 (en) 2008-09-16 2010-03-25 Dow Global Technologies Inc. Polymeric compositions and foams, methods of making the same, and articles prepared from the same
MX349957B (es) 2008-09-25 2017-08-21 Basell Polyolefine Gmbh Composicion de polietileno lineal de baja dencidad (lldpe) resistente a impactos y peliculas hechas de la misma.
CA2736415A1 (en) 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
US8664129B2 (en) 2008-11-14 2014-03-04 Exxonmobil Chemical Patents Inc. Extensible nonwoven facing layer for elastic multilayer fabrics
US10161063B2 (en) 2008-09-30 2018-12-25 Exxonmobil Chemical Patents Inc. Polyolefin-based elastic meltblown fabrics
US9168718B2 (en) 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
US9498932B2 (en) 2008-09-30 2016-11-22 Exxonmobil Chemical Patents Inc. Multi-layered meltblown composite and methods for making same
EP2172499A1 (de) 2008-10-03 2010-04-07 Total Petrochemicals Research Feluy Chemische Mischungen aus Polyolefinen und Polyhydroxycarbonsäuren
US8476205B2 (en) 2008-10-03 2013-07-02 Exxonmobil Research And Engineering Company Chromium HVI-PAO bi-modal lubricant compositions
EP2172498A1 (de) 2008-10-03 2010-04-07 Total Petrochemicals Research Feluy Modifizierung von mit Single-Site-Katalysatoren hergestellten Polyolefinen
EP2172490A1 (de) 2008-10-03 2010-04-07 Ineos Europe Limited Polimerisationsverfahren
EP2204375A1 (de) 2008-12-12 2010-07-07 Total Petrochemicals Research Feluy Herstellung von monoarylsubstituierten, methylenverbrückten substituierten Cyclopentadienyl-Fluorenyl-Liganden und davon abgeleitete Zirkoniumkomplexe
CN102245698B (zh) 2008-12-15 2014-01-08 埃克森美孚化学专利公司 热塑性烯烃组合物
RU2515900C2 (ru) 2008-12-18 2014-05-20 Юнивейшн Текнолоджиз, Ллк Способ обработки зародышевого слоя реакции полимеризации
US8481658B2 (en) 2008-12-23 2013-07-09 Basell Polyolefine Gmbh Method for transitioning between incompatible olefin polymerization catalyst systems
ES2546088T4 (es) 2009-02-27 2015-10-15 Exxonmobil Chemical Patents Inc. Laminados no tejidos biaxialmente elásticos con zonas inelásticas
WO2010113975A1 (ja) 2009-03-30 2010-10-07 三井化学株式会社 オレフィンと共役ジエンとの共重合体、およびその製造方法
KR101327598B1 (ko) 2009-04-21 2013-11-12 가부시키가이샤 프라임 폴리머 올레핀 중합체의 제조 방법
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
EP2435526A4 (de) 2009-05-29 2012-10-31 Exxonmobil Chem Patents Inc Polyolefinhaftzusammensetzungen und herstellungsverfahren dafür
US9017593B2 (en) 2009-06-16 2015-04-28 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
EP2450361B1 (de) 2009-07-01 2017-10-25 Mitsui Chemicals, Inc. Organometallische verbindungen und verfahren zu ihrer herstellung
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
US20110020619A1 (en) 2009-07-23 2011-01-27 Van Den Bossche Linda M Polypropylene-Based Elastomer Coating Compositions
US20110054117A1 (en) 2009-08-27 2011-03-03 Hall Gregory K Polyolefin Adhesive Compositions and Method of Making Thereof
US8716201B2 (en) 2009-10-02 2014-05-06 Exxonmobil Research And Engineering Company Alkylated naphtylene base stock lubricant formulations
IN2012DN02445A (de) 2009-10-02 2015-08-21 Exxonmobil Chem Patents Inc
CN102725251B (zh) 2009-10-19 2015-11-25 沙索技术有限公司 聚合物的形成减少的烯属化合物的低聚合
WO2011053406A1 (en) 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
US8668975B2 (en) 2009-11-24 2014-03-11 Exxonmobil Chemical Patents Inc. Fabric with discrete elastic and plastic regions and method for making same
EP2510019A2 (de) 2009-12-07 2012-10-17 Univation Technologies, LLC Verfahren zur reduktion der statischen aufladung eines katalysators und verfahren zur verwendung des katalysators zur herstellung von polyolefinen
EP2513166B1 (de) 2009-12-18 2017-04-05 Basell Polyolefine GmbH Verfahren zur herstellung von geträgerten katalysatoren
JP5514838B2 (ja) 2009-12-21 2014-06-04 三井化学株式会社 シンジオタクティックα‐オレフィン重合体の製造方法
CA2782873C (en) 2009-12-24 2016-06-28 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
EP2357035A1 (de) 2010-01-13 2011-08-17 Ineos Europe Limited Polymerpulveraufbewahrungs- und/oder -transport- und/oder -entgasungsgefäßen
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
JP5602249B2 (ja) 2010-01-14 2014-10-08 エクソンモービル・ケミカル・パテンツ・インク 連続的溶液重合のための方法および装置
JP5750453B2 (ja) 2010-01-22 2015-07-22 エクソンモービル・ケミカル・パテンツ・インク 潤滑油組成物及びそれらの製造方法
JP5498588B2 (ja) 2010-01-27 2014-05-21 エクソンモービル・ケミカル・パテンツ・インク コポリマー、その組成物及びそれらの製造方法
US8759267B2 (en) 2010-02-01 2014-06-24 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
US8598103B2 (en) 2010-02-01 2013-12-03 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient
US8642523B2 (en) 2010-02-01 2014-02-04 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
US8748362B2 (en) 2010-02-01 2014-06-10 Exxonmobile Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient
US8728999B2 (en) 2010-02-01 2014-05-20 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
CN102791481B (zh) 2010-03-12 2015-07-08 埃克森美孚化学专利公司 弹性熔喷层压体构造及其制造方法
ES2665963T3 (es) 2010-04-30 2018-04-30 Basell Polyolefine Gmbh Filamento o fibra de polímero
EP2383301A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
EP2383298A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
JP2013529718A (ja) 2010-07-06 2013-07-22 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
CN102958955A (zh) 2010-07-06 2013-03-06 提克纳有限公司 超高分子量聚乙烯、其制备和用途
WO2012006230A1 (en) 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
WO2012004680A2 (en) 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
JP2013531111A (ja) 2010-07-06 2013-08-01 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの繊維及び膜、それらの製造及び使用
KR20130100067A (ko) 2010-07-06 2013-09-09 티코나 게엠베하 고분자량 폴리에틸렌 성형품, 이의 제조 및 용도
KR20130124170A (ko) 2010-07-06 2013-11-13 티코나 게엠베하 고 분자량 폴리에틸렌의 제조 방법
WO2012015576A1 (en) 2010-07-28 2012-02-02 Exxonmobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
SG186165A1 (en) 2010-07-28 2013-01-30 Exxonmobil Chem Patents Inc Viscosity modifiers comprising blends of ethylene-based copolymers
CA2802109C (en) 2010-07-28 2015-04-07 Exxonmobil Chemical Patents Inc. Viscosity modifiers comprising blends of ethylene-based copolymers
US9815915B2 (en) 2010-09-03 2017-11-14 Exxonmobil Chemical Patents Inc. Production of liquid polyolefins
WO2012051239A1 (en) 2010-10-15 2012-04-19 Exxonmobil Chemical Patents Inc. Polypropylene-based adhesive compositions
RU2608124C2 (ru) 2010-11-29 2017-01-13 Инеос Коммершиал Сервисиз Юк Лимитед Способ контроля полимеризации
EP2646480B1 (de) 2010-11-30 2016-04-13 Univation Technologies, LLC Verfahren zur polymerisierung von olefinen mit extrahierten metallcarboxylatsalzen
CN103298843B (zh) 2010-11-30 2015-08-19 尤尼威蒂恩技术有限责任公司 具有改进的流动特征的催化剂组合物及其制造和使用方法
EP2465876A1 (de) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Aktivierung von Trägern
EP2665754A1 (de) 2011-01-20 2013-11-27 Ineos Commercial Services UK Limited Aktivierung von stützen
US9029478B2 (en) 2011-02-07 2015-05-12 Equistar Chemicals, Lp High clarity polyethylene films
EP2675844B1 (de) 2011-02-15 2017-10-11 ExxonMobil Chemical Patents Inc. Thermoplastische polyolefinmischungen
TWI555574B (zh) 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
WO2012134721A2 (en) 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
EP2688922A4 (de) 2011-03-25 2015-03-04 Exxonmobil Chem Patents Inc Durch alkenmetathese hergestellte amphiphile blockpolymere
US9248630B2 (en) 2011-04-08 2016-02-02 Ineos Europe Ag Laminate comprising a polyolefin layer adhered to a base layer
RU2598023C2 (ru) 2011-05-13 2016-09-20 Юнивейшн Текнолоджиз, Ллк Полученные распылительной сушкой каталитические композиции и способы полимеризации, в которых они применяются
JP5697747B2 (ja) 2011-05-18 2015-04-08 三井化学株式会社 プロピレン系共重合体、プロピレン系共重合体組成物、その成形体およびその発泡体、およびそれらの製造方法
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
US9279023B2 (en) 2011-06-24 2016-03-08 Ineos Europe Ag Slurry phase polymerisation process
SI2739655T1 (sl) 2011-08-05 2017-11-30 Total Research & Technology Feluy Katalizatorji za pripravo polietilena z ultravisoko molekulsko maso (UHMWPE)
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
CN104024264A (zh) * 2011-09-20 2014-09-03 道康宁公司 含金属的硅氢加成催化剂以及含该催化剂的组合物
US9321945B2 (en) 2011-09-30 2016-04-26 Equistar Chemicals, Lp Systems, methods and compositions for production of tie-layer adhesives
WO2013048848A2 (en) 2011-09-30 2013-04-04 Exxonmobil Chemical Patents Inc. Dynamic modulation of metallocene catalysts
SG11201401128UA (en) 2011-10-10 2014-04-28 Exxonmobil Res & Eng Co High efficiency engine oil compositions
CN103874714B (zh) 2011-10-17 2016-06-22 英尼奥斯欧洲股份公司 聚合物脱气工艺控制
IN2014CN04332A (de) 2011-12-14 2015-09-04 Ineos Europe Ag
KR20140107278A (ko) 2011-12-19 2014-09-04 티코나 게엠베하 고 분자량 폴리에틸렌의 제조 방법
US9234054B2 (en) 2011-12-19 2016-01-12 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
EP2800754B1 (de) 2011-12-19 2017-06-28 Saudi Basic Industries Corporation (Sabic) Verfahren zur herstellung von metallocenkomplexen
US9902847B2 (en) 2011-12-27 2018-02-27 Mitsui Chemicals, Inc. 4-methyl-1-pentene (co)polymer composition, and film and hollow molded product composed of the composition
EP2799486B1 (de) 2011-12-28 2017-08-23 Mitsui Chemicals, Inc. Polymerzusammensetzung auf ethylenbasis und formkörper daraus
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
JP6088548B2 (ja) 2012-02-03 2017-03-01 エクソンモービル ケミカル パテンツ インコーポレイテッド 油改質剤として有用なポリマー組成物を製造する方法
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
SG11201405812VA (en) 2012-03-21 2014-10-30 Mitsui Chemicals Inc Method for producing olefin polymer
EP2833415B1 (de) 2012-03-28 2018-05-02 Mitsui Chemicals, Inc. Dichtmaterial für solarzellen und solarzellenmodul
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
US20130281340A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Lubricant Compositions Comprising Ethylene Propylene Copolymers and Methods for Making Them
BR112014023743B1 (pt) 2012-05-10 2020-10-20 Dow Global Technologies Llc. aparelhagem para liberação de um aditivo a um sítio de reação ou misturação e método para liberação de um aditivo a um sítio de reação ou misturação
WO2014006069A1 (en) 2012-07-06 2014-01-09 Total Research & Technology Feluy Process for the polymerization of olefins
WO2014047542A1 (en) 2012-09-24 2014-03-27 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene
KR101640356B1 (ko) 2012-09-25 2016-07-15 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체의 제조 방법 및 올레핀 중합체
US9458261B2 (en) 2012-09-25 2016-10-04 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst, and olefin polymer production process
WO2014069604A1 (ja) 2012-11-02 2014-05-08 出光興産株式会社 粘接着剤組成物及びこれを用いた粘着テープ
CN104768981B (zh) 2012-11-02 2017-10-24 出光兴产株式会社 聚烯烃、含有其的粘接剂组合物和使用其的粘接胶带
IN2015DN03103A (de) 2012-11-12 2015-10-02 Univation Tech Llc
CN104781291B (zh) 2012-11-15 2018-02-13 出光兴产株式会社 丙烯系聚合物和热熔粘接剂
EP2746320A1 (de) 2012-12-20 2014-06-25 Basell Polyolefine GmbH Polyethylenzusammensetzung mit hohen mechanischen Eigenschaften
WO2014099303A1 (en) 2012-12-21 2014-06-26 Exxonmobil Chemical Patents Inc. Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
CN110551424B (zh) 2012-12-28 2022-07-29 陶氏环球技术有限责任公司 涂料组合物和由其制成的物品
EP2922925B1 (de) 2012-12-28 2019-12-04 Dow Global Technologies LLC Beschichtungszusammensetzungen
EP2945737B1 (de) 2013-01-14 2019-03-13 Univation Technologies, LLC Verfahren zur herstellung von katalysatorsystemen mit erhöhter produktivität
EP2945972B1 (de) 2013-01-18 2023-10-11 Dow Global Technologies LLC Polymerisationsverfahren zur herstellung von hochmolekulare polyolefine
CN104955852B (zh) 2013-01-22 2018-01-02 道达尔研究技术弗吕公司 具有连续输送的烯烃聚合工艺
RS54566B1 (en) 2013-01-22 2016-06-30 Total Research & Technology Feluy OLEPHIN POLYMERIZATION PROCEDURE WITH CONTINUOUS EMISSION
EP2759554A1 (de) 2013-01-23 2014-07-30 Total Research & Technology Feluy Verfahren zur Herstellung von Olefin/3-methyl-1-buten-Copolymeren
US10548367B2 (en) 2013-01-29 2020-02-04 Exxonmobil Chemical Patents Inc. Footwear sole comprising a propylene-based elastomer, footwear comprising said sole, and methods of making them
JP2016506979A (ja) 2013-01-30 2016-03-07 ユニベーション・テクノロジーズ・エルエルシー 改善した流動を有する触媒組成物を作製するためのプロセス
JP6000439B2 (ja) 2013-02-20 2016-09-28 株式会社プライムポリマー 二軸延伸フィルムおよびエチレン系重合体組成物
CN105008414A (zh) 2013-02-22 2015-10-28 出光兴产株式会社 丙烯系聚合物和热熔粘接剂
CN104994948B (zh) 2013-02-27 2017-11-24 三井化学株式会社 烯烃多聚化用催化剂以及在该催化剂存在下进行的烯烃多聚体的制造方法
JP5951108B2 (ja) 2013-03-12 2016-07-13 三井化学株式会社 オレフィン重合体の製造方法およびオレフィン重合用触媒
EP2984111A4 (de) 2013-04-11 2016-11-30 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen unter verwendung von metallocen-polymerisationskatalysatoren und copolymeren davon
WO2014176187A1 (en) 2013-04-23 2014-10-30 Exxonmobil Chemical Patents Inc. Pyridyldiamide metal catalysts and processes to produce polyolefins
WO2014192767A1 (ja) 2013-05-27 2014-12-04 出光興産株式会社 ホットメルト接着剤用ベースポリマー及びホットメルト接着剤
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
JP2016530360A (ja) 2013-07-17 2016-09-29 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒を使用する方法およびそれに由来する生成物
EP3022238B1 (de) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
EP3022237B1 (de) 2013-07-17 2018-10-03 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
US9671047B2 (en) 2013-10-14 2017-06-06 Basell Polyolefine Gmbh Polyethylene of raised temperature resistance
WO2015056787A1 (ja) 2013-10-18 2015-04-23 三井化学株式会社 エチレン・α－オレフィン共重合体を含有する接着剤
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
JP2016540076A (ja) 2013-12-06 2016-12-22 トタル リサーチ アンド テクノロジー フエリユイ 長い分岐鎖を有するポリプロピレン
BR112016016900B8 (pt) 2014-02-13 2022-05-17 Mitsui Chemicals Inc Copolímero de etileno-alfa-olefina-polieno não conjugado, artigo moldado, composição, método de fabricação deste copolímero, composição para uma junta de vedação, junta de vedação, composição para formação de uma mangueira e mangueira
EP3106475B1 (de) 2014-02-13 2019-08-28 Mitsui Chemicals, Inc. Verfahren zur herstellung von ethylen-/alpha-olefin-copolymeren
EP3106481B1 (de) 2014-02-14 2019-12-25 Mitsui Chemicals, Inc. Copolymer aus ethylen/alpha-olefin/nichtkonjugiertem polyen, herstellungsverfahren dafür und verwendung davon
EP3112398B1 (de) 2014-02-28 2019-08-21 Mitsui Chemicals, Inc. Vernetztes produkt sowie herstellungsverfahren und verwendung davon und ethylencopolymer
RU2655174C2 (ru) 2014-03-28 2018-05-24 Митсуи Кемикалс, Инк. Олефиновая смола и способ её получения
JP6618891B2 (ja) 2014-03-28 2019-12-11 三井化学株式会社 エチレン／α−オレフィン共重合体および潤滑油
MX2016012458A (es) 2014-03-28 2017-01-06 Mitsui Chemicals Inc Resina basada en olefina, metodo para producirla y composicion de resina basada en propileno.
CN114957529A (zh) 2014-04-02 2022-08-30 尤尼威蒂恩技术有限责任公司 连续性组合物及其制备和使用方法
CN106795449B (zh) 2014-09-10 2020-08-07 三井化学株式会社 润滑油组合物
CN107108777B (zh) 2014-11-12 2021-02-05 埃克森美孚化学专利公司 增塑剂的纯化及其在聚合物生产方法和装置中的用途
WO2016093266A1 (ja) 2014-12-09 2016-06-16 三井化学株式会社 プロピレン系樹脂組成物
ES2698255T3 (es) 2015-01-23 2019-02-01 Total Res & Technology Feluy Polipropileno bimodal y proceso para la preparación del mismo
US10414843B2 (en) 2015-03-10 2019-09-17 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
JP6426829B2 (ja) 2015-03-20 2018-11-21 三井化学株式会社 熱可塑性エラストマー組成物およびその製造方法
TWI683847B (zh) 2015-03-20 2020-02-01 日商三井化學股份有限公司 熱可塑性彈性體組成物、其用途、其製造方法、乙烯．α-烯烴．非共軛多烯共聚合體及其用途
WO2016158661A1 (ja) 2015-03-31 2016-10-06 三井化学株式会社 樹脂組成物およびその用途
WO2016172097A1 (en) 2015-04-20 2016-10-27 Univation Technologies, Llc Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
EP3286202B1 (de) 2015-04-20 2019-03-13 Univation Technologies, LLC Verbrückte bi-aromatische liganden und daraus hergestellte übergangsmetallverbindungen
ES2955681T3 (es) 2015-04-27 2023-12-05 Univation Tech Llc Composiciones de catalizador soportado que tienen propiedades de flujo mejoradas y preparación de las mismas
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
TR201819970T4 (tr) 2015-07-15 2019-01-21 Total Res & Technology Feluy Polietilen ürün hazırlamaya yönelik proses.
CN108137764A (zh) 2015-09-28 2018-06-08 电化株式会社 交联共聚物及其制造方法
JP6545813B2 (ja) 2015-11-09 2019-07-17 三井化学株式会社 潤滑油用粘度調整剤、潤滑油用添加剤組成物および潤滑油組成物
WO2017105614A1 (en) 2015-12-16 2017-06-22 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions
CA3018952C (en) 2016-03-31 2023-06-27 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
CN106046212B (zh) * 2016-07-04 2018-06-15 吉林大学 非桥连两性离子型单茂金属配合物及其用途
US10647626B2 (en) 2016-07-12 2020-05-12 Chevron Phillips Chemical Company Lp Decene oligomers
MX2019008213A (es) 2017-01-13 2019-09-05 Total Res & Technology Feluy Polipropilenos y composiciones de polipropileno de alta pureza para moldeo.
JP6741790B2 (ja) 2017-01-16 2020-08-19 三井化学株式会社 自動車ギア用潤滑油組成物
BR112019017366B1 (pt) 2017-02-20 2023-03-07 Mitsui Chemicals, Inc Laminado, mangueira e método para produzir o referido laminado
CN110520471B (zh) 2017-02-28 2022-05-24 埃克森美孚化学专利公司 用油增量的双峰茂金属合成的epdm制备的热塑性硫化橡胶
CN115872822A (zh) 2017-07-06 2023-03-31 三井化学株式会社 烯烃多聚化用催化剂及在该催化剂存在下进行的烯烃多聚体的制造方法
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
KR102405495B1 (ko) 2017-12-01 2022-06-08 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매계 및 이를 사용하기 위한 중합 방법
US11028196B2 (en) 2017-12-22 2021-06-08 Exxonmobil Chemical Patents Inc. Polyolefin compositions
WO2019160710A1 (en) 2018-02-19 2019-08-22 Exxonmobil Chemical Patents Inc. Catalysts, catalyst systems, and methods for using the same
US11905348B2 (en) 2018-03-20 2024-02-20 Mitsui Chemicals, Inc. Ethylene/alpha-olefin/non-conjugated polyene copolymer, method for producing the same, and use thereof
CN112437790B (zh) 2018-06-13 2024-04-23 埃克森美孚化学专利公司 聚烯烃共混物组合物
CN112703210B (zh) 2018-07-23 2022-10-28 埃克森美孚化学专利公司 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品
WO2020041096A1 (en) 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US10843980B2 (en) 2018-08-22 2020-11-24 Exxonmobil Research And Engineering Company Manufacturing a base stock from ethanol
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
WO2020060745A1 (en) 2018-09-19 2020-03-26 Exxonmobil Chemical Patents Inc. Devolatilization processes
US11285465B2 (en) 2018-09-27 2022-03-29 Exxonmobil Chemical Patents Inc. C1,C2-bridged ligands and catalysts
US20220041847A1 (en) 2018-12-04 2022-02-10 Mitsui Chemicals, Inc. Resin composition containing 4-methyl-1-pentene copolymer, and film for capacitors
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
JP2022522649A (ja) 2019-02-20 2022-04-20 フイナ・テクノロジー・インコーポレーテツド 低い反りを有するポリマー組成物
BR112021018486A2 (pt) 2019-03-19 2021-11-23 Mitsui Chemicals Inc Composição de resina de propileno, artigo conformado e polímero de propileno
CN113646343A (zh) 2019-04-05 2021-11-12 埃克森美孚化学专利公司 来自具有故意热梯度的环管反应器的宽分子量分布聚合物产物
CN113646074B (zh) 2019-04-05 2023-05-09 埃克森美孚化学专利公司 控制聚烯烃产物的分子量分布和化学组成分布
EP4011961A4 (de) 2019-08-08 2023-07-12 Prime Polymer Co., Ltd. Propylenharzzusammensetzung und formartikel
WO2021034471A1 (en) 2019-08-16 2021-02-25 Exxonmobil Chemical Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
US11492427B2 (en) 2019-10-29 2022-11-08 ExxonMobile Chemicals Patents Inc. Production of gradient copolymers using monomer and comonomer concentration gradients in a loop reactor
US20230075830A1 (en) 2019-12-03 2023-03-09 Basell Polyolefine Gmbh Polyethylene composition for filaments or fibers
BR112022008804A2 (pt) 2019-12-03 2022-07-26 Basell Polyolefine Gmbh Composição de polietileno, filamento ou fibra, e, itens fabricados
EP4077424A2 (de) 2019-12-17 2022-10-26 ExxonMobil Chemical Patents Inc. Lösungspolymerisationsverfahren zur herstellung von langkettigen polyethylenverzweigungen hoher dichte
WO2021153532A1 (ja) 2020-01-30 2021-08-05 三井化学株式会社 ポリアミド組成物
WO2021188256A1 (en) 2020-03-18 2021-09-23 Exxonmobil Chemical Patents Inc. Extrusion blow molded articles and processes for making same
WO2021236322A1 (en) 2020-05-19 2021-11-25 Exxonmobil Chemical Patents Inc. Extrusion blow molded containers and processes for making same
US20230242745A1 (en) 2020-06-03 2023-08-03 Exxonmobil Chemical Patents Inc Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom
JP2023532133A (ja) 2020-07-02 2023-07-26 セラニーズ・インターナショナル・コーポレーション メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法
JPWO2022024687A1 (de) 2020-07-31 2022-02-03
CN116829642A (zh) 2021-01-18 2023-09-29 三井化学株式会社 水分散体组合物、该水分散体组合物的制造方法及乙烯·α-烯烃共聚物酸改性物
JPWO2022186053A1 (de) 2021-03-05 2022-09-09
CN117120490A (zh) 2021-03-31 2023-11-24 三井化学株式会社 乙烯－α-烯烃共聚物、热塑性树脂组合物和膜
JPWO2022210845A1 (de) 2021-03-31 2022-10-06
US20220340723A1 (en) 2021-04-26 2022-10-27 Fina Technology, Inc. Thin Single-Site Catalyzed Polymer Sheets
EP4342915A1 (de) 2021-05-20 2024-03-27 Mitsui Chemicals, Inc. Harzzusammensetzung, verwendung davon und verfahren zur herstellung davon
CA3237354A1 (en) 2021-11-05 2023-05-11 Exxonmobil Chemical Patents Inc. Syndiotactic propylene-based ethylene-propylene copolymers
WO2023081327A1 (en) 2021-11-05 2023-05-11 Chevron Oronite Company Llc Lubricating oil composition with viscosity modifier based on syndiotactic propylene-based ethylene-propylene copolymers with improved properties
CN118202023A (zh) 2021-11-05 2024-06-14 埃克森美孚化学专利公司 聚丙烯粘度改性剂及其润滑油
KR20240035555A (ko) 2021-11-16 2024-03-15 미쓰이 가가쿠 가부시키가이샤 수지 조성물 및 그의 용도
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes
WO2023225428A1 (en) 2022-05-18 2023-11-23 Exxonmobil Chemical Patents Inc. Polyethylene compositions and processes for their production

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE551488A (de) * 1955-10-05
CA849081A (en) † 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
US4704491A (en) * 1985-03-26 1987-11-03 Mitsui Petrochemical Industries, Ltd. Liquid ethylene-alpha-olefin random copolymer, process for production thereof, and use thereof
JPH0780930B2 (ja) † 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5218071A (en) † 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers

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