WO2004112108A1 - 露光方法、基板ステージ、露光装置、及びデバイス製造方法 - Google Patents
露光方法、基板ステージ、露光装置、及びデバイス製造方法 Download PDFInfo
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- WO2004112108A1 WO2004112108A1 PCT/JP2004/008578 JP2004008578W WO2004112108A1 WO 2004112108 A1 WO2004112108 A1 WO 2004112108A1 JP 2004008578 W JP2004008578 W JP 2004008578W WO 2004112108 A1 WO2004112108 A1 WO 2004112108A1
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- Prior art keywords
- substrate
- liquid
- peripheral wall
- substrate stage
- space
- Prior art date
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70216—Mask projection systems
- G03F7/70341—Details of immersion lithography aspects, e.g. exposure media or control of immersion liquid supply
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B27/00—Photographic printing apparatus
- G03B27/32—Projection printing apparatus, e.g. enlarger, copying camera
- G03B27/52—Details
- G03B27/58—Baseboards, masking frames, or other holders for the sensitive material
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
- G03F7/2041—Exposure; Apparatus therefor in the presence of a fluid, e.g. immersion; using fluid cooling means
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70691—Handling of masks or workpieces
- G03F7/707—Chucks, e.g. chucking or un-chucking operations or structural details
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70691—Handling of masks or workpieces
- G03F7/70716—Stages
Definitions
- the present invention relates to an exposure method for exposing a pattern image to a substrate via a projection optical system and a liquid, a substrate stage for supporting the substrate, an exposure apparatus, and a device manufacturing method.
- Semiconductor devices and liquid crystal display devices are manufactured by a so-called photolithography technique that transfers a pattern formed on a mask onto a photosensitive substrate.
- the exposure apparatus used in the photolithography process has a mask stage for supporting a mask and a substrate stage for supporting a substrate, and sequentially moves the mask stage and the substrate stage to project a mask pattern onto a projection optical system. It is transferred to the substrate via
- further improvement in the resolution of the projection optical system has been desired in order to cope with higher integration of device patterns.
- the resolution of the projection optical system increases as the exposure wavelength used decreases and as the numerical aperture of the projection optical system increases. For this reason, the exposure wavelength used in the exposure apparatus is becoming shorter year by year, and the numerical aperture of the projection optical system is also increasing.
- the mainstream exposure wavelength is 248 nm of a KrF excimer laser, but a shorter wavelength of 193 nm of an ArF excimer laser is also being put into practical use.
- the depth of focus (D OF) is as important as the resolution.
- the resolution R and the depth of focus ⁇ are respectively expressed by the following equations.
- ⁇ is the exposure wavelength
- ⁇ is the numerical aperture of the projection optical system
- k 2 is the process coefficient
- the liquid immersion method disclosed in International Publication No. 99 / '4955 pamphlet has been proposed.
- the space between the lower surface of the projection optical system and the substrate surface is filled with a liquid such as water or an organic solvent to form an immersion region, and the wavelength of the exposure light in the liquid is 'n (where n is the refractive index of the liquid, which is usually about 1.2 to 1.6), is used to improve the resolution and increase the depth of focus by about 11 times.
- the above-mentioned prior art has the following problems.
- the above-mentioned prior art has a configuration in which a space between an end surface on the image plane side of a projection optical system and a substrate (wafer) is locally filled with a liquid.
- a shot region ′ near the center of the substrate is exposed, the liquid substrate is exposed. No outflow occurs.
- the projection area 100 of the projection optical system is assigned to the peripheral area (edge area) E of the substrate P, and the edge area E of the substrate P is to be exposed, The liquid flows out of the substrate P, and the liquid immersion area is not formed well, thereby causing a problem that the projected pattern image is deteriorated.
- the escaping liquid causes inconveniences such as generation of ⁇ ⁇ in mechanical parts around the substrate stage that supports the substrate P, and leakage of the stage drive system. Further, if the escaping liquid goes around the back surface of the substrate and enters between the substrate and the substrate stage (substrate holder), there is a disadvantage that the substrate stage cannot hold the substrate well.
- bubbles may be mixed into the liquid due to a step or a gap between the substrate P and the substrate stage. In this case, the exposure light is scattered due to the influence of the bubbles, or the bubbles are scattered on the substrate P due to the bubbles. Inconveniences such as that the pattern is not imaged occur. Also, when liquid enters the gap, there is a possibility that (1) electric leakage may occur.
- An object of the present invention is to provide an exposure method, a substrate stage, an exposure apparatus, and a device manufacturing method that can perform exposure in a state where a region is formed.
- the present invention employs the following configuration corresponding to FIGS. 1 to 26 shown in the embodiment.
- the exposure method according to the present invention is directed to an exposure method for exposing a substrate (P) by projecting an image of a pattern onto the substrate (P) via a projection optical system (PL) and a liquid (1).
- the side surface (PB) of P) is liquid-repellent.
- the side surface of the substrate is subjected to the lyophobic treatment, it is possible to prevent liquid from penetrating between, for example, a member (substrate stage) disposed so as to surround the substrate and the side surface of the substrate. Therefore, it is possible to prevent liquid from entering the back surface of the substrate. In addition, bubbles are prevented from being mixed into the liquid, and the edge region of the substrate can be exposed while the liquid immersion region is well formed.
- the exposure method according to the present invention is directed to an exposure method for exposing a substrate (P) by projecting an image of a pattern onto the substrate (P) via a projection optical system (PL) and a liquid (1).
- the back surface (PC) of P) is liquid-repellent.
- the back surface of the substrate is subjected to the liquid-repellent treatment, it is possible to prevent liquid from entering between the substrate holder holding the back surface of the substrate and the back surface of the substrate, for example. Therefore, exposure can be performed while holding the substrate well.
- the substrate stage (PST) of the present invention exposes the substrate (P) by projecting an image of a pattern onto the substrate (P) via the projection optical system (PL) and the liquid (1).
- a substrate stage used for exposure and movable while holding a substrate (P) is characterized in that at least a part of the surface (31, 33A, 36, 37) is lyophobic.
- the substrate stage (PST) of the present invention forms an immersion area (AR2) on a part of the substrate (P), and forms the liquid immersion area (AR2) on the substrate (P) via the projection optical system (PL) and the liquid (1).
- AR2 immersion area
- PL projection optical system
- the substrate stage that holds the substrate (P) In the substrate stage that holds the substrate (P), it is placed around the same height as the substrate (P) around the substrate (P). A flat portion (31) is formed, and a concave portion (32) in which the substrate (P) is arranged is formed inside the flat portion (31), and a gap (A) between the flat portion (32) and the substrate (P) is formed. The substrate (P) is exposed while the liquid is filled with the liquid (1).
- An exposure apparatus (EX) according to the present invention includes the substrate stage (PST) described above.
- a device manufacturing method of the present invention is characterized by using the above-described exposure method or an exposure apparatus (EX) equipped with the above-described substrate stage (PST).
- the edge region of the substrate can be immersed in the immersion light while the immersion region is well formed, and a device having desired performance can be manufactured.
- the substrate stage (PST) of the present invention is a substrate stage that can move while holding a substrate (P) to be exposed, and is formed inside a first peripheral wall (33) and the first peripheral wall (33).
- a second peripheral wall (46) and a support portion (34) formed inside the second peripheral wall (46), and the space (38) surrounded by the second peripheral wall (46) is set to a negative pressure.
- the substrate (P) is held by the support portion (34).
- At least the double peripheral wall is provided around the supporting portion that supports the substrate, so that even if liquid infiltrates between the member arranged to surround the substrate and the side surface of the substrate, Liquid can be prevented from entering the back side of the device or the vacuum system for creating a negative pressure in the space.
- the substrate stage (PST) of the present invention is a substrate stage which can hold and move a substrate (P) as an object to be exposed, and includes a support part (34) for supporting the substrate (P) and a support part (34). It is placed around the supported substrate (P), and the surface of the substrate (P) A gap adjusting section (31) for reducing the gap between the flat section (31), which is substantially flush, and the notch (NT, OF) of the substrate (P) supported by the support section (34) and the flat section (31). 1 50, 15 1, 1 52, 1 53).
- the gap between the cutout portion of the substrate and the flat portion around the cutout portion is reduced by the gap adjustment portion, so that the intrusion of the liquid between the cutout portion and the flat portion of the substrate can be suppressed. . Therefore, it is possible to prevent the liquid from entering the back surface side of the substrate or the like.
- the substrate stage (PST) of the present invention is a substrate stage that can move while holding a substrate (P) to be exposed, and includes a peripheral wall (33, 33N, 33F) and a peripheral wall (33, 33N, 33F). F), and a supporting portion (34) formed inside the peripheral wall (33, 33N, 33F).
- the peripheral wall (33, 33N, 33F) is formed in accordance with the shape of the cutout (NT, OF) of the substrate (P).
- the space (38) surrounded by the peripheral wall (33, 33N, 33F) is set to a negative pressure, whereby the substrate (P) is held on the support portion (34).
- the peripheral wall according to the shape of the cutout portion of the substrate, it is possible to suppress a disadvantage that a large gap is formed between the substrate and the peripheral wall, and to smoothly apply a negative pressure to the space surrounded by the peripheral wall. Can be Therefore, the substrate can be satisfactorily held by the support portion, and the intrusion of the liquid into the back surface or the space of the substrate can be suppressed.
- the substrate stage (PST) of the present invention comprises a support portion (34) for supporting the substrate (P), the support portion (34) and a support portion ( 34).
- the intake force near the notch (NT, OF) of the substrate (P) is It is characterized in that it has been made smaller.
- the suction force through the suction port near the notch where a large gap is easily formed between the substrate and the substrate stage is made smaller than the suction force through the suction port around the notch.
- the exposure apparatus (EX) of the present invention is held by the substrate stage (PST) described above.
- the substrate (P) is irradiated with exposure light (EL) through the projection optical system (PL) and the liquid (LQ), and the substrate (P) is subjected to immersion exposure.
- a device manufacturing method of the present invention uses the above-described exposure apparatus (EX).
- a liquid immersion exposure can be performed on a board
- FIG. 1 is a schematic configuration diagram showing an embodiment of the exposure apparatus of the present invention.
- FIG. 2 is a schematic configuration diagram showing a liquid supply mechanism and a liquid recovery mechanism.
- FIG. 3 is a plan view of the substrate stage.
- FIG. 4 is a cross-sectional view of a principal part showing one embodiment of the substrate stage of the present invention.
- FIG. 5 is a schematic diagram showing a substrate holder that is attached to and detached from the substrate stage.
- FIG. 6 is a sectional view of a main part showing another embodiment of the substrate stage of the present invention.
- 7A to 7C are schematic diagrams showing an example of a procedure for arranging a liquid in a space.
- FIG. 8 is a cross-sectional view of a main part showing another embodiment of the substrate stage of the present invention.
- FIG. 9 is a plan view of a substrate stage according to another embodiment of the present invention.
- FIG. 10 is a plan view of a substrate stage according to another embodiment of the present invention.
- FIG. 11 is a plan view of a substrate stage according to another embodiment of the present invention.
- FIG. 12 is a plan view of a substrate stage according to another embodiment of the present invention.
- FIG. 13 is a view showing one embodiment of a substrate according to the exposure method of the present invention.
- FIGS. 14A to 14B are plan views of a substrate stage according to another embodiment of the present invention.
- FIGS. 15A to 15B are plan views of a substrate stage according to another embodiment of the present invention.
- FIGS. 16A to 16B are views showing one embodiment of a substrate according to the exposure method of the present invention.
- FIG. 17 is a view showing one embodiment of a substrate according to the exposure method of the present invention.
- FIG. 18 is a plan view of a substrate stage according to another embodiment of the present invention.
- FIGS. 19A to 19B are main-portion cross-sectional views of a substrate stage according to another embodiment of the present invention.
- 20A to 20B are cross-sectional views of main parts of a substrate stage according to another embodiment of the present invention.
- 21A to 21B are diagrams showing another embodiment of the gap adjusting unit according to the present invention.
- FIG. 22 is a diagram showing another embodiment of the gap adjusting section according to the present invention.
- FIG. 23 is a diagram showing another embodiment of the gap adjusting section according to the present invention.
- FIG. 24 is a sectional view of a main part of a substrate stage according to another embodiment of the present invention.
- 25A to 25B are diagrams of a substrate stage according to another embodiment of the present invention.
- FIG. 26 is a flowchart showing an example of a semiconductor device manufacturing process.
- FIG. 27 is a schematic diagram for explaining the problem of the conventional exposure method. BEST MODE FOR CARRYING OUT THE INVENTION ''
- FIG. 1 is a schematic configuration diagram showing an embodiment of the exposure apparatus of the present invention.
- an exposure apparatus EX includes a mask stage MST that supports a mask M, a substrate stage PST that supports a substrate P, and an illumination optical system IL that illuminates the mask M supported by the mask stage MST with exposure light EL.
- a projection optical system PL for projecting and exposing the pattern image of the mask M illuminated by the exposure light EL onto the substrate P supported on the substrate stage PST, and a control device CONT for controlling the overall operation of the entire exposure apparatus EX. It has.
- the exposure apparatus EX of the present embodiment is an immersion exposure apparatus to which the immersion method is applied in order to substantially shorten the exposure wavelength to improve the resolution and substantially widen the depth of focus.
- pure water is used as the liquid 1.
- the exposure apparatus EX controls the projection optical system PL by the liquid 1 supplied from the liquid supply mechanism 10 while at least transferring the pattern image of the mask M onto the substrate P.
- the liquid immersion area AR2 is formed on at least a part of the substrate P including the projection area AR1.
- the exposure apparatus EX fills the liquid 1 between the optical element 2 at the tip of the projection optical system PL and the surface (exposure surface) of the substrate P, and fills the space between the projection optical system PL and the substrate P
- the pattern image of the mask M is projected onto the substrate P via the liquid 1 and the projection optical system PL, and the substrate P is exposed.
- the exposure apparatus EX a scanning type in which the pattern formed on the mask M is exposed on the substrate P while the mask M and the substrate P are synchronously moved in different directions (opposite directions) in the scanning direction.
- An example in which an exposure apparatus (a so-called scanning stepper) is used will be described.
- the direction coincident with the optical axis AX of the projection optical system PL is the Z-axis direction
- the direction of the synchronous movement (scanning direction) between the mask M and the substrate P in a plane perpendicular to the Z-axis direction is the X-axis direction.
- the direction perpendicular to the Z-axis direction and the Y-axis direction is the Y-axis direction.
- directions around the X axis, the Y axis, and the Z axis are defined as ⁇ X, ⁇ ⁇ , and, respectively.
- the “substrate” includes a semiconductor wafer coated with a photo resist, which is a photosensitive material
- the “mask” includes a reticle on which a device pattern to be reduced and projected onto the substrate is formed.
- the illumination optical system IL illuminates the mask ⁇ ⁇ ⁇ supported by the mask stage MS ⁇ with the exposure light EL, and includes an exposure light source, an optical integrator for equalizing the illuminance of a light beam emitted from the exposure light source, It has a condenser lens that condenses the exposure light EL from the optical integrator, a relay lens system, and a variable field stop that sets the illumination area on the mask M by the exposure light EL in a slit shape.
- a predetermined illumination area on the mask M is illuminated with the exposure light EL having a uniform illuminance distribution by the illumination optical system IL.
- the exposure light EL emitted from the illumination optical system IL includes, for example, ultraviolet emission lines (g-line, h-line, and i-line) emitted from a mercury lamp and KrF excimer laser light (wavelength: 248 nm). And other deep ultraviolet light (DUV light) and ArF excimer laser light (wavelength: 193 nm). 2 Vacuum ultraviolet light (VUV light) such as laser light (wavelength: 157 nm) is used. In the present embodiment, ArF excimer laser light is used. As described above, the liquid 1 in the present embodiment is pure water, and can be transmitted even if the exposure light EL is ArF excimer laser light. Pure water is used for ultraviolet emission lines (g-line, h-line, i-line) and KrF excimer laser light (wavelength: 248 nm). Can also transmit deep ultraviolet light (DUV light).
- ultraviolet emission lines g-line, h-line, and i-line
- UV light deep ultraviolet light
- the mask stage MST supports the mask M, and can move two-dimensionally in a plane perpendicular to the optical axis AX of the projection optical system P, that is, in the XY plane, and can rotate slightly in the ⁇ Z direction.
- the mask stage MST is driven by a mask stage driving device MSTD such as a rear air motor.
- the mask stage driving device MSTD is controlled by the control device CONT.
- a moving mirror 50 is provided on the mask stage MST.
- a laser interferometer 51 is provided at a position facing the movable mirror 50. The position and the rotation angle of the mask M on the mask stage MST in the two-dimensional direction are measured in real time by the laser interferometer 51, and the measurement results are output to the control unit C CNT.
- the control device CONT drives the mask stage driving device MSD based on the measurement result of the laser interferometer 51, thereby positioning the mask M supported by the mask stage MST.
- the projection optical system PL projects and exposes the pattern of the mask M onto the substrate ⁇ at a predetermined projection magnification ⁇ , and includes a plurality of optics including an optical element (lens) 2 provided at the front end of the substrate ⁇ . These optical elements are supported by a lens barrel ⁇ .
- the projection optical system PL is a reduction system whose projection magnification is, for example, 1Z4 or 1/5.
- the projection optical system PL may be either a unity magnification system or a magnification system.
- the optical element 2 at the tip of the projection optical system PL of the present embodiment is provided so as to be detachable (replaceable) from the lens barrel PK, and the liquid 1 in the liquid immersion area AR 2 comes into contact with the optical element 2. I do.
- the optical element 2 is made of fluorite. Since fluorite has a high affinity for water, the liquid 1 can be brought into close contact with almost the entire liquid contact surface 2a of the optical element .2. That is, in the present embodiment, the liquid (water) 1 having a high affinity for the liquid contact surface 2 a of the optical element 2 is supplied, so that the liquid contact surface 2 a of the optical element 2 The adhesion is high, and the optical path between the optical element 2 and the substrate P can be reliably filled with the liquid 1.
- the optical element 2 may be quartz having a high affinity for water. Alternatively, the liquid contact surface 2a of the optical element 2 may be subjected to a hydrophilic (lyophilic) treatment to further enhance the affinity with the liquid 1. Also, since the lens barrel PK is in contact with the liquid (water) 1 near the tip, at least the tip is resistant to cracks such as Ti (titanium '). Made of resistant metal.
- the substrate stage PST can move while supporting (holding) the substrate P as an object to be exposed.
- the Z stage 52 holds the substrate P via the substrate holder PH, and supports the Z stage 52.
- An XY stage 53 and a base 54 for supporting the XY stage 53 are provided.
- the substrate stage PST is driven by a substrate stage driving device PSTD such as a linear motor.
- the substrate stage driving device PSTD is controlled by the control device CONT.
- the position of the substrate P in the XY direction (the position in a direction substantially parallel to the image plane of the projection optical system PL) is controlled. That is, the Z stage 52 controls the force position and the tilt angle of the substrate P to adjust the surface of the substrate P to the image plane of the projection optical system PL by the auto-focus method and the auto-leveling method.
- the stage 53 positions the substrate P in the X-axis direction and the Y-axis direction. It goes without saying that the fe, Z stage and XY stage may be provided integrally.
- a movable mirror 55 is provided on the substrate stage PST (Z stage 52).
- a laser interferometer 56 is provided at a position facing the movable mirror 55. The position and the rotation angle of the substrate P on the substrate stage PST in the two-dimensional direction are measured in real time by the laser interferometer 56, and the measurement results are output to the control device CONT.
- the control device C • NT determines the position of the substrate P supported by the substrate stage PST by driving the substrate stage driving device PSTD based on the measurement result of the laser interferometer 56.
- a plate 30 surrounding the substrate P is provided on the substrate stage PST (Z series 52).
- the plate portion 30 is provided integrally with the Z stage 52, and a concave portion 32 is formed on the side of the plate portion 30.
- the plate section 30 and the Z stage 52 may be provided separately.
- the substrate holder PH for holding the substrate P is disposed in the recess 32.
- the plate portion 30 has a flat surface (flat portion) 31 having substantially the same height as the surface of the substrate P held by the substrate holder PH arranged in the portion 32.
- the liquid supply mechanism 10 supplies a predetermined liquid 1 onto the substrate P, and includes a first liquid supply unit 11 and a second liquid supply unit 12 capable of supplying the liquid 1, and a first liquid supply unit.
- the first and second supply members 13 and 14 are arranged close to the surface of the substrate P, and are provided at different positions in the plane direction of the substrate P. Specifically, the first supply member 13 of the liquid supply mechanism 10 is provided on one side (one X side) in the scanning direction with respect to the projection area AR1, and the second supply member 14 is provided on the other side (+ X Side).
- Each of the first and second liquid supply units 11 and 12 includes a tank for storing the liquid 1, a pressure pump, and the like.
- the supply pipes 11A and 12A and the supply members 13 and The liquid 1 is supplied onto the substrate P via each of 14.
- the liquid supply operation of the first and second liquid supply units 11 and 12 is controlled by the control device CONT, and the control device CONT controls the first and second liquid supply units 11 and 12 with respect to the substrate P.
- the liquid supply amount per unit time can be independently controlled.
- Each of the first and second liquid supply units 11 and 12 has a liquid temperature adjustment mechanism, and has a temperature (for example, 23 ° C.) substantially equal to the temperature in the chamber in which the device is housed.
- the liquid 1 is supplied onto the substrate P.
- the liquid recovery mechanism 20 recovers the liquid 1 on the substrate P, and has first and second recovery members 2 having recovery ports 23 A and 24 A arranged close to the surface of the substrate P.
- the first and second liquid recovery units 2 connected to the first and second recovery members 23 and 24 via recovery pipes 21 1 and 22 having flow paths, respectively. 1, 2, and 2.
- the first and second liquid recovery units 21 and 22 include, for example, a suction device such as a vacuum pump, and a tank for storing the recovered liquid 1, and transfer the liquid 1 on the substrate P to the first and second liquid collection units. Recover through recovery members 23, 24 and recovery tubes 21A, 22A.
- the liquid recovery operation of the first and second liquid recovery units 21 and 22 is controlled by the control device CONT, and the control device C ⁇ NT is controlled by the first and second liquid recovery units 21 and 22 per unit time. Collection amount Can be controlled.
- At least a portion of the first and second supply members 13 and 14 and the first and second recovery members 23 and 24 that comes into contact with the liquid is formed of a material including stainless steel.
- the first and second supply members 13 and 14 and the first and second recovery members 23 and 24 are formed of SUS316 of stainless steel.
- at least one of the first and second supply members 13 and 14 and the first and second recovery members 23 and 24 formed of stainless steel (SUS316) has a liquid contact surface that contacts the liquid.
- a surface treatment for example, “G0LDEP” treatment or “G0LDEP WHITE” treatment of Kogyo Pantech Co., Ltd. can be mentioned.
- FIG. 2 is a plan view showing a schematic configuration of the liquid supply mechanism 10 and the liquid recovery mechanism 20.
- the projection area AR 1 of the projection optical system PL is set in a slit shape (rectangular shape) having the Y-axis direction (non-scanning direction) as a longitudinal direction, and the liquid 1 is filled.
- the immersion area AR2 is formed on a part of the substrate Pi: so as to include the projection area AR1.
- the first supply member 13 of the liquid supply mechanism 10 for forming the liquid immersion area AR 2 of the projection area AR 1 is provided on one side (1 X side) in the scanning direction with respect to the projection area AR 1.
- the second supply member 14 is provided on the other side (+ X side).
- Each of the first and second supply members 13 and 14 is formed in a substantially arc shape in plan view, and the size of the supply ports 13A and 14A in the Y-axis direction is at least the projection area AR1. It is set to be larger than the size in the Y-axis direction.
- the supply ports 13A and 14A formed in a substantially arc shape in plan view are arranged so as to sandwich the projection area AR1 in the scanning direction (X-axis direction).
- the liquid supply mechanism 10 simultaneously supplies the liquid 1 on both sides of the projection area AR1 via the supply ports 13A and 14A of the first and second supply units 13 and 14.
- Each of the first and second recovery members 23 and 24 of the liquid recovery mechanism 20 has recovery ports 23 A and 24 A continuously formed in an arc shape so as to face the surface of the substrate P.
- the first and second collection members 23 and 24 arranged to face each other form a substantially annular collection port.
- the first and second collection members 23 and 24 have their respective collection ports 23A and 24A connected to the first and second supply members 13 and 14 of the liquid supply mechanism 10.
- the projection area ARl Further, a plurality of partition members 25 are provided inside the collection port continuously formed so as to surround the projection area AR1.
- the liquid 1 supplied onto the substrate P from the supply ports 13A and 14A of the first and second supply members 13 and 14 is applied to the lower end surface of the tip (optical element 2) of the projection optical system PL and the substrate P It is supplied so that it spreads between and.
- the liquid 1 flowing out of the first and second supply members 13 and 14 with respect to the projection area AR 1 is outside the projection area AR 1 from the first and second supply members 13 and 14.
- the first and second collection members 23 and 24 are disposed at the collection ports 23A and 24A.
- the liquid supply amount per unit time supplied before the projection area A R1 in the scanning direction is set to be larger than the liquid supply amount supplied on the opposite side.
- the controller CONT controls the projection area AR1 to supply the liquid amount from the one X side (that is, the supply port 13A) to the + X side (that is, the supply amount).
- the amount of liquid from the + X side to the projection area AR1 is changed from the amount of liquid from the 1X side.
- the liquid recovery amount per unit time before the projection area AR 1 is set to be smaller than the liquid recovery amount on the opposite side.
- the collection amount from the + X side (that is, the collection port 24A) with respect to the projection area AR1 is made larger than the collection amount from one X side (that is, the collection port 23A).
- a moving mirror 55 is arranged at two mutually perpendicular edges of the stage 52.
- a concave portion 32 is formed at a substantially central portion of the Z stage 52, and the substrate P holding the substrate P is provided in the concave portion 32.
- a holder PH is provided around the substrate P.
- a plate portion 30 having a flat surface (flat portion) 31 having substantially the same height as the surface of the substrate P is provided integrally with the Z stage 52.
- the substrate holder PH includes a substantially annular peripheral wall portion 33, and a plurality of support portions 34 disposed inside the peripheral wall portion 33 and holding (supporting) the substrate P.
- the peripheral wall part 33 is disposed around the support part 34, and the support part 34 is one side inside the peripheral wall part 33. It is arranged like.
- the flat surface 31 of the plate portion 30 is disposed around the substrate P supported by the support portion 34 and is provided so as to be substantially flush with the surface of the substrate P supported by the support portion 34.
- a predetermined gap A is formed between the side surface PB of the substrate P held by the substrate holder PH and the plate portion 30.
- the upper end surface of the peripheral wall 33 has a relatively wide width, but actually has a width of only about 1 to 2 mm.
- the two corners of the flat surface 31 of the plate portion 30 are wide, and one of the wide portions is provided with a reference mark FM used for aligning the mask M and the substrate P with respect to a predetermined position. ing. Further, various sensors such as an illuminance sensor are provided around the substrate P on the substrate stage PST. In the present embodiment, the reference mark FM is provided on the plate portion 30. However, a reference mark member for arranging the reference mark FM on the substrate stage PST is provided separately from the plate portion 30. Is also good.
- FIG. 4 is an enlarged sectional view of a main part of a substrate stage PST holding the substrate P.
- a substrate holder PH for holding a substrate P is arranged inside a concave portion 32 of the Z stage 52 (plate portion 30).
- the recess 32 is formed inside the flat surface 31, and the inner surface 36 of the recess 32 is adjacent to the flat surface 31.
- the peripheral wall portion 33 and the support portion 34 formed inside the peripheral wall portion 33 are provided on a substantially disk-shaped base portion 35 that constitutes a part of the substrate holder PH.
- Each of the support portions 34 has a trapezoidal shape when viewed in cross section, and the substrate P has its back surface PC held on the upper end surfaces 34 A of the plurality of support portions 34.
- the support portion 34 is shown relatively large in the figure, a large number of very small pin-shaped support portions are actually formed inside the peripheral wall portion 33.
- the upper surface 33A of the peripheral wall portion 33 is a flat surface.
- the height of the peripheral wall portion 33 is smaller than the height of the support portion 34, and a gap B is formed between the substrate P supported by the support portion 34 and the peripheral wall portion 33.
- the gap B is smaller than the gap A between the inner surface 36 of the recess 32 and the side surface PB of the substrate P.
- the gap A is preferably about 0.1 to 1.0 mm in consideration of the manufacturing error of the outer shape of the substrate P and the mounting accuracy of the substrate P, and the gap B is about 2.0 to 5.0 ⁇ ⁇ . It is.
- Gap C is formed in
- the diameter of the substrate holder PH is formed smaller than the diameter of the substrate P
- the gap A is smaller than the gap C.
- notches (alignment flats, notches, etc.) for alignment are not formed in the substrate P
- the substrate P is substantially circular
- the gap A is 0.1 l over the entire circumference. mn! ⁇ 1. O mm prevents liquid inflow.
- a photoresist (photosensitive material) 90 is applied to the surface PA, which is the exposed surface of the substrate P.
- the photosensitive material 90 is a photosensitive material for ArF excimer laser (for example, TARF-P6100 manufactured by Tokyo Ohka Kogyo Co., Ltd.), and has liquid repellency (water repellency).
- the angle is about 70-80 °.
- the side surface PB of the substrate P is subjected to a liquid repellent treatment (water repellent treatment).
- a liquid repellent treatment water repellent treatment
- the photosensitive material 9 ° having liquid repellency is also applied to the side surface PB of the substrate P.
- the photosensitive material 90 is also applied to the back surface PC of the substrate P and subjected to a liquid repellent treatment.
- a part of the surface of the Z stage 52 (substrate stage PST) 'is subjected to a liquid-repellent treatment so as to be liquid-repellent.
- the flat surface 31 and the inner surface 36 of the Z stage 52 have liquid repellency.
- a part of the surface of the substrate holder PH is also subjected to the lyophobic treatment so as to be lyophobic.
- the upper surface 33A and the side surface 37 of the peripheral wall portion 33 of the substrate holder PH have liquid repellency.
- a liquid repellent material such as a fluororesin material or an acrylic resin material is applied, or a thin film made of the liquid repellent material is attached.
- a liquid-repellent material for making the liquid-repellent a material that is insoluble in liquid 1 is used. Note that the Z stage 52 and the entire substrate holder PH may be formed of a material having liquid repellency (such as a fluororesin).
- the substrate stage PST includes a suction device 40 for making the first space 38 surrounded by the peripheral wall 33 of the substrate holder PH a negative pressure.
- the suction device 40 includes a plurality of suction ports 41 provided on the upper surface of the base portion 35 of the substrate holder PH, a vacuum portion 42 including a vacuum pump provided outside the substrate stage PST, and a base. And a flow path 43 formed inside the suction section 35 and connecting each of the plurality of suction ports 41 to the vacuum section 42. I have.
- the suction ports 41 are provided at a plurality of predetermined positions on the upper surface of the base portion 35 other than the support portion 34, respectively.
- the suction device 40 suctions gas (air) in the first space 38 formed between the peripheral wall portion 33, the base portion 35, and the substrate P supported by the support portion 34.
- the substrate P is sucked and held on the support portion 34 by setting the leverage first space 38 to a negative pressure. Since the gap B between the back surface PC of the substrate P and the upper surface 33 A of the peripheral wall portion 33 is small, the negative pressure in the first space 38 is maintained.
- the substrate stage PST includes a recovery unit (recovery means) 60 for recovering the liquid 1 flowing into the second space 39 between the inner surface 36 of the recess 32 and the side surface 37 of the substrate holder PH.
- the recovery unit 60 has a tank 61 capable of storing the liquid 1 and a flow path 62 provided inside the Z stage 52 and connecting the space 39 and the tank 61. ing.
- the inner wall surface of the flow path 62 is also subjected to a liquid-repellent treatment.
- the Z stage 52 has a flow connecting the second space 39 between the inner surface 36 of the recess 32 and the side surface 37 of the substrate holder PH and the space (atmospheric space) outside the Z stage 52.
- Road 45 is formed. Gas (air) can flow between the second space 39 and the outside of the Z stage 52 via the flow path 45, and the second space 39 is set at almost atmospheric pressure.
- the substrate holder PH is detachably provided to the Z stage 52.
- the contact surface 57 of the Z stage 52 with the substrate holder PH is lyophobic by being subjected to lyophobic treatment
- the back surface 58 of the substrate holder PH which is the contact surface with the Z stage 52, is also lyophobic. It is liquid treated and has liquid repellency.
- the lyophobic treatment for the contact surface 57 and the back surface 58 can be performed by applying a lyophobic material such as a fluorine-based resin material or an acryl-based resin material.
- the immersion area AR 2 of the liquid 1 is partially covered by the surface PA of the substrate P and the flat surface 31 of the plate portion 30. It is formed to cover a part.
- the side surface PB of the substrate P and the inner surface 36 facing the side surface PB are liquid-repellent, the liquid 1 in the liquid immersion area AR 2 has a gap A Hardly penetrates into the gap A, and hardly flows into the gap A due to its surface tension. Therefore, even when the edge region E of the substrate P is exposed, the immersion exposure can be performed while the liquid 1 is well held under the projection optical system PL.
- the liquid 1 forming the liquid immersion area AR 2 is prevented from being excessively spread to the outside of the plate portion 30, and the liquid immersion area
- the AR 2 can be formed favorably, and inconveniences such as outflow and scattering of the liquid 1 can be prevented. Further, since the substrate P has no notch such as a notch, the liquid 1 may not flow from the notch.
- the liquid 1 in the immersion area AR 2 slightly flows into the second space 39 through the gap A, the liquid is repelled by the back surface PC of the substrate P and the upper surface 33 A of the peripheral wall portion 33. Since the liquid processing is performed and the gap B is sufficiently small, the liquid 1 does not flow into the first space 38 set to a negative pressure in order to hold the substrate P by suction to the support portion 34. Thus, it is possible to prevent a disadvantage that the liquid 1 flows into the suction port 41 and the substrate P cannot be suction-held. '
- the liquid 1 flowing into the second space 39 is recovered to the tank 61 of the recovery unit 60 via the flow path 62, thereby suppressing outflow (leakage) and scattering of the liquid 1 to peripheral devices. be able to.
- the second space 39 since the inner surface 36 of the concave portion 32 forming the second space 39, the side surface 37 of the substrate holder PH, or the flow path 62 are lyophobic, the second space 39 The inflowing liquid 1 does not stay in the second space 39, but flows smoothly through the flow path 62, and returns to the tank 61 once again.
- the suction operation of the suction device 40 By the way, by the suction operation of the suction device 40, the gas (air) in the second space 39 flows into the first space 38 via the gap B, and the liquid 1 in the liquid immersion area AR 2 is accordingly conveyed. There is a possibility that the liquid immersion area AR 2 may become unstable due to the penetration into the second space 39 via the gap A.
- the gap between the inner surface 36 of the recess 32 and the side surface 37 of the substrate holder PH is larger than the gap A between the side surface PB of the substrate P and the inner surface 36 of the recess 32.
- Is set and the second space 39 is open to the atmosphere through the flow path 45, so that the air passing through the gap B flows in from the outside through the flow path 45 and passes through the gap C.
- Most of the air (Liquid 1) passed through the gap A is small.
- the suction force applied to the liquid via the gap A can be made smaller than the surface tension of the body 1, and the liquid 1 in the immersion area AR 2 flows into the second space 39 via the gap A. Can be suppressed.
- a gas (air) supply device 45 ' is connected to the other end of the flow path 45 opposite to the one end connected to the second space 39, and the inner surface 36 of the recess 32 and the substrate holder are connected.
- the second space 39 between the PH side 37 and the PH side 37 may be made positive pressure, specifically, set slightly higher than the atmospheric pressure. Thereby, the inconvenience that the liquid 1 in the immersion area AR2 flows into the space 39 via the gap A can be suppressed.
- the second space 39 is made excessively positive, the gas (air) in the second space 39 flows into the liquid 1 in the immersion area AR 2 via the gap A, and bubbles are generated in the liquid 1.
- the second space 39 be set to approximately atmospheric pressure (slightly higher than atmospheric pressure) because of the inconvenience of mixing.
- the gap between the Z stage 52 and the substrate hologram PH through the gap A is provided.
- the inconvenience of the liquid 1 entering the second space 39 can be prevented. Therefore, when exposing the edge region E of the substrate P, the exposure can be performed in a state where the liquid immersion region A R 2 is well formed while suppressing mixing of bubbles into the liquid 1 and the like.
- the liquid 1 can be prevented from flowing into the second space 39 inside the substrate stage PST, it is possible to prevent the device from generating short-circuit leakage.
- the liquid repellent treatment is performed on the back surface 58 of the substrate holder PH detachable from the Z stage 52 and the contact surface 57 of the Z stage 52 with the substrate holder PH.
- the flow of the liquid 1 between the back surface 58 of the substrate holder PH and the contact surface 57 of the Z stage 52 can be suppressed. Therefore, it is possible to prevent the occurrence of cracks on the back surface 58 of the substrate holder PH and the contact surface 57 of the Z stage 52.
- the substrate holder PH When liquid ⁇ : 1 enters between the back surface 58 of the Z stage 52 and the contact surface 57 of the Z stage 52, the substrate holder PH and the Z stage 52 may adhere to each other and become difficult to separate. Making it liquid makes separation easier.
- the substrate holder PH and the substrate stage PST are detachable, but the substrate holder PH may be provided integrally with the substrate stage PST.
- the photosensitive material 90 is applied to the entire surface of the front surface PA, the side surface PB, and the rear surface PC of the substrate P for lyophobic treatment, but the region where the gap A is formed, that is, the substrate P
- the liquid repellent treatment may be performed only on the side surface PB and the region where the gap B is formed, that is, only the region of the back surface PC of the substrate P facing the upper surface 33 A of the peripheral wall portion 33.
- the gap A is sufficiently small and the liquid repellency (contact angle) of the material applied for the liquid repellent treatment is sufficiently large, the liquid 1 flows into the second space 39 via the gap A.
- the liquid repellent treatment may not be performed on the back surface PC of the substrate P on which the gap B is formed, and only the side surface PB of the substrate P may be subjected to the liquid repellent treatment.
- the side surface of the substrate P and the inner surface 36 of the substrate stage PST opposed thereto, the side surface 37 of the substrate holder PH and the inner surface 36 of the substrate stage PST opposed thereto, and the back surface of the substrate P Although the liquid-repellent treatment is performed on the upper surface 33A of the peripheral wall portion 33 facing the liquid-repellent surface, only one of the opposing surfaces may be subjected to the liquid-repellent treatment.
- the flat surface 31 of the plate portion 30 is subjected to liquid repellent treatment.f
- liquid repellent treatment for example, when the flat surface 31 of the plate portion 30 is sufficiently large, or when the scanning speed of the substrate P for the liquid 1 is sufficient. Liquid 1 in the immersion area AR 2 Since the likelihood of the liquid 1 flowing out is low, it is possible to prevent the liquid 1 from flowing out or scattered without treating the flat surface 31 with the Zen solution.
- a part of the region in the immediate vicinity of the substrate P may be annularly subjected to the lyophobic treatment.
- liquid repellency of the flat surface 31 of the substrate stage PST and the liquid repellency of the inner surface 36 may be different. That is, the contact angle of the liquid 1 on the flat surface 31 and the contact angle of the liquid 1 on the inner surface 36 may be different.
- the height of the peripheral wall portion 33 is lower than the height of the support portion 34, and a gap B is formed between the back surface PC of the substrate P and the upper surface 33A of the peripheral wall portion 33.
- the back surface PC of the substrate P may come into contact with the upper surface 33 A of the peripheral wall portion 33.
- the photosensitive material 90 having liquid repellency is applied to the side surface PB and the back surface PC of the substrate P as the liquid repellent treatment, but the side surface PB and the back surface PC are coated with a photosensitive material other than the photosensitive material 90.
- a predetermined material having liquidity may be applied.
- a protective layer called a top coat layer (a film for protecting the photosensitive material 90 from a liquid) may be applied to the upper layer of the photosensitive material 90 applied to the surface PA which is the exposed surface of the substrate P.
- the material for forming the top coat layer (for example, a fluorine-based resin material) has liquid repellency (water repellency) at a contact angle of about 110 °, for example. Therefore, the top coat layer forming material may be applied to the side surface P B and the back surface P C of the substrate P.
- a material having liquid repellency other than the material for forming the photosensitive material 90 9 top coat layer may be applied.
- a fluororesin material or an acrylic resin material is applied, or the like.
- the material may be applied to the substrate stage PST and the substrate holder PH, or conversely, the material used for the liquid repellent treatment of the substrate stage PST and the substrate holder PH may be applied to the side surface PB and the back surface PC of the substrate P. It may be.
- the top coat layer is often provided to prevent the liquid 1 in the liquid immersion area AR 2 from penetrating into the photosensitive material 90.
- the top coat layer may have a trace of the liquid 1 deposited on the top coat layer (so-called Even if a watermark was formed, the watermark was removed together with the topcoat layer by removing the topcoat layer after the immersion exposure. A predetermined process such as a development process can be performed later.
- the top coat layer is formed of, for example, a fluorine-based resin material, it can be removed using a fluorine-based solvent. This eliminates the need for a device for removing the watermark (for example, a substrate cleaning device for removing the watermark) and the like, and has a simple configuration in which the top coat layer is removed with a solvent. Process processing can be performed favorably.
- the liquid 1 can be held in the second space 39 between the side surface 36 of the concave portion 32 and the side surface 37 of the substrate holder PH.
- the liquid repellent treatment is not performed on the side surface PB of the substrate P in the present embodiment.
- the liquid repellent treatment is applied only to a part of the peripheral surface 33A of the substrate holder PH facing the upper surface 33A.
- a photosensitive material 90 is applied to a surface PA which is an exposure surface of the substrate P.
- the liquid repellent treatment is not performed on the inner surface 36 of the substrate stage PST and the side surface 37 of the substrate holder PH, and the upper surface 33 A of the peripheral wall portion 33 of the substrate holder PH is not subjected to the lyophobic treatment. Liquid repellent treatment is applied only to
- a second peripheral wall portion 46 is formed inside the peripheral wall portion 33.
- the support part 34 for supporting the substrate P is formed inside the second peripheral wall part 46.
- the height of the peripheral wall portion 33 and the height of the second peripheral wall portion 46 are substantially the same.
- the height of the peripheral wall portion 33 and the height of the second peripheral wall portion 46 are lower than the support portion 34.
- the width of the upper surface 46 A of the second peripheral wall portion 46 is smaller than the width of the upper surface 33 A of the peripheral wall portion 33, but may be the same or the upper surface of the second peripheral wall portion 46.
- the width of 46 A may be larger than the width of 33 A on the upper surface of the peripheral wall portion 33.
- the height of the upper surface 46 A of the peripheral wall portion 46 may be different from the height of the upper surface 33 A of the peripheral wall portion 33, and the upper surface 46 A of the second peripheral wall portion 46 may be located on the back surface of the substrate P. You may be in contact.
- An annular buffer space 47 is formed between the peripheral wall 33 and the second peripheral wall 46.
- a channel 48 is connected to the buffer space 47.
- the flow path 48 has one end connected to the buffer space 47 and the other end connected to a space (atmospheric space) outside the substrate stage PST.
- the buffer space 47 between the peripheral wall portion 33 and the second peripheral wall portion 46 is opened to the atmosphere, and the pressure in the buffer space 47 is set to approximately atmospheric pressure.
- the substrate stage PST includes a liquid supply device 70 that can supply liquid to the second space 39.
- the liquid supply device 70 is formed inside the supply part 71 capable of sending out liquid and the Z stage 52, and has one end connected to the second space 39 and the other end connected to the supply part 71. And a flow path 72.
- the liquid supply device 70 also has a function of collecting the liquid 1 in the second space 39.
- FIGS. 7A to 7C are diagrams showing a procedure for filling the second space 39 with the liquid 1.
- the water level (height) of the liquid 1 in the second space 39 is lower than the height of the peripheral wall portion 33. Set lower. In this state, the liquid 1 may be removed from the second space 39.
- FIG. 7B after the substrate P is loaded onto the substrate holder PH by a loader device (not shown), the first space surrounded by the suction device 40 force S and the second peripheral wall portion 46 is used.
- the substrate P is sucked and held by the support portion 34 of the substrate holder PH.
- the liquid 1 is supplied to the second space 39 by the liquid supply device 70, whereby the second space 39 is filled with the liquid 1.
- the liquid supply device 70 applies the liquid 1 to the second space 3 until the liquid surface 1 reaches the same height (water level) as the flat surface 31 of the plate portion 30 and the surface of the substrate P held by the substrate holder PH.
- an operation opposite to the operation described with reference to FIGS. 7A to 7C may be performed. That is, after the completion of the immersion exposure, the liquid supply device 70 having a liquid collecting function collects the liquid 1 in the second space 39. Next, the suction device 40 releases the suction holding of the substrate P by the substrate holder PH. Next, an unloader device (not shown) unloads (unloads) the substrate P on the substrate holder PH.
- the flat surface 3 1 of the plate 30 and the substrate P By filling the space 3 9 with the liquid 1, the flat surface 3 1 of the plate 30 and the substrate P The surface PA is almost flush with the space 1 via the liquid 1 in the space 39. That is, the gap between the flat portion 31 and the substrate P is filled with the liquid 1. As a result, even when the liquid 1 is arranged on the gap A in order to perform the immersion exposure on the edge area E of the substrate P, it is possible to prevent inconvenience such as bubbles being mixed into the liquid 1 in the immersion area AR 2. However, exposure can be performed with the liquid immersion area AR 2 formed well.
- the gap B is sufficiently small, and since the upper surface 33 A of the peripheral wall portion 33 and a part of the rear surface PC of the substrate P opposed thereto are liquid-repellent, the second space 39 The liquid 1 does not flow into the buffer space 47 via the gap B. Furthermore, since the buffer space 47 is opened to the atmosphere via the flow path 48 and is set to almost the atmospheric pressure, even if the suction device 40 keeps the first space 38 at a negative pressure, the second space 3 The liquid 1 filled with 9 can be prevented from flowing into the buffer space 47 side. Even if the liquid slightly passes through the gap B, the infiltrated liquid can be captured in the buffer space 47.
- the substrate stage PST has a configuration including a liquid supply device 70 capable of supplying the liquid 1 to the second space 39 and recovering the liquid 1 in the second space 39.
- the liquid 1 can be supplied or recovered freely according to whether or not the substrate P is placed on the substrate holder PH, so that it is possible to prevent the liquid 1 from flowing out to peripheral devices. That is, when the second space 39 is filled with the liquid 1, for example, the liquid 1 in the liquid immersion area AR 2 is arranged on the gap A, and the buffer space 47 is made to have a negative pressure through the flow path 48. It is conceivable that the second space 39 is filled with the liquid 1 on the gap A.
- the liquid level of the liquid 1 in the second space 39 is considered. Since the height of the liquid is higher than the height of the peripheral wall portion 33, there is a problem that the liquid 1 flows into, for example, the upper surface 33A of the peripheral wall portion 33 3the buffer space 47 side.
- the liquid supply device 70 capable of supplying and recovering the liquid 1 to and from the second space 39, the liquid 1 in the second space 39 may be recovered before unloading the substrate P. Therefore, the outflow of the liquid 1 can be prevented.
- a gas supply device 48 ′ is connected to the other end of the flow path 48 opposite to the one end connected to the buffer space 47, and the buffer space 47 is made positive pressure, specifically, atmospheric pressure. It may be set slightly higher. As a result, the liquid 1 in the second space 39 is The inconvenience of flowing into the buffer space 47 via the gap B and eventually into the first space 38 can be prevented. In this case, if the buffer space 47 is made excessively positive, the liquid 1 in the second space 39 will be mixed with the gas (air) in the buffer space 47 via the gap A in the liquid immersion area AR 2 It is preferable that the buffer space 47 be set to almost atmospheric pressure (slightly higher than atmospheric pressure) because of the inconvenience of flowing into the liquid 1 and introducing bubbles into the liquid 1.
- the gas supply device 48 ' is provided with a suction function, and the gas supply device 48' reduces the pressure in the buffer space 47 between the peripheral wall portion 33 and the second peripheral wall portion 46, for example, the atmospheric pressure.
- the pressure in the buffer space 47 may be arbitrarily adjustable, for example, by setting it slightly lower (low negative pressure) and higher than the pressure in the first space 38.
- the substrate P has a configuration in which a part of the back surface PC is liquid-repellent.
- the entire surface of the back surface PC may be liquid-repellent, or the side surface PB may be liquid-repellent.
- the side surface 37 of the substrate holder PH and the inner surface 36 of the concave portion 32 may be subjected to a liquid-repellent treatment.
- the substrate P and the upper surface 33 A of the peripheral portion 33 opposed thereto may be made lyophobic.
- the upper surface of the second peripheral wall portion 46 may be made lyophobic by subjecting the upper surface 46 A of the second peripheral wall portion 46 to liquid repellent treatment or the like.
- the substrate P, the substrate holder P H, and the substrate stage P ST may have liquid repellency as in the first embodiment and the modifications thereof.
- FIG. 8 is a view showing another embodiment of the substrate stage PST of the present invention.
- the substrate stage PST controls the pressure of the second space 39 between the inner surface 36 of the recess 32 and the side surface 37 of the substrate holder PH by the first space surrounded by the peripheral wall portion 33.
- a second suction device 80 for setting the pressure to be lower than the pressure of the space 38 is provided.
- the second suction device 80 is connected to the second space 39 via a flow path 62, a tank 61 capable of storing the liquid 1, and a pump connected to the tank 61 via a valve 63. 6 and 4 are provided.
- the operations of the second suction device 80 and the suction device 40 are controlled by the control device C ONT.
- the liquid repellent treatment is not performed on the side surface PB and the back surface PC of the substrate P. Further, the inner surface 36 of the concave portion 32, the side surface 37 of the substrate holder PH, and the upper surface 33A of the peripheral wall portion 33 are not subjected to the liquid-repellent treatment.
- the control device CONT uses the suction device 40 and the (2) The operation of the suction device 80 is controlled so that the pressure in the second space 39 is lower than the pressure in the first space 38.
- the liquid 1 in the immersion area AR 2 on the gap A flows into the second space 39 via the gap A, and then does not flow into the first space 38 via the gap B. 2 Collected in tank 61 of suction device 80.
- the tank 61 is provided with a discharge channel 61A, and the liquid 1 is discharged from the discharge channel 61A when a predetermined amount of the liquid 1 is accumulated.
- the liquid 1 having passed through the gap A does not enter the first space 38 side, and the second suction device Collected in tank 61 of 80. Therefore, immersion exposure can be performed in a state in which the substrate P is favorably sucked and held while preventing the liquid 1 from flowing into the suction port 41. Then, the liquid 1 that has passed through the gap A is recovered in the tank 61, so that inconvenience such as outflow or scattering of the liquid 1 to the outside of the apparatus can be avoided.
- the substrate P (side surface, etc.), the substrate holder PH (upper surface 33 A of the peripheral wall portion 33, etc.), the substrate stage PST At least a part of each of the flat surfaces 31 and the side surfaces 36 can be made lyophobic.
- a part of the substrate stage PST and a part of the surface of the substrate holder PH are subjected to the lyophobic treatment.
- the upper surface 34A of the support portion 34 of the substrate holder PH may be subjected to a liquid-repellent treatment. This suppresses the formation of liquid adhesion marks (water marks) on the upper surface 34 A of the support portion 34, and maintains the flatness of the support surface defined by the plurality of support portions 34. it can.
- liquid infiltration, outflow, and scattering are suppressed by performing lyophobic treatment on surfaces that may be in contact with or adhere to liquid (water). Also, even if liquid adheres, it can be easily removed.
- the substrate P is substantially circular, and by disposing a substantially annular plate portion 30 around it, the plate portion 30 (the inner side surface 36 of the concave portion 32) and the substrate P are formed.
- a gap A is formed below the specified value with the side surface PB. If the plate P has a notch such as a notch or an orientation flat (orientation flat), the shape of the plate 30 (the inner surface 36 of the recess 32) is set according to the notch of the substrate P, and the notch is formed.
- the gap A can be kept below a predetermined value also in the section.
- FIG. 9 is a plan view of the substrate stage PST supporting the substrate P having the notch portion NT as viewed from above.
- the plate portion 30 is provided with a projection 150 corresponding to the shape of the notch portion NT of the substrate P, and the inner surface 36 of the concave portion 32 of the Z stage 51 is provided with a projection portion.
- a convex portion 36 N is formed so as to form 150.
- the protrusion 150 has a function as a gap adjustment unit for reducing the gap between the notch NT of the substrate P supported by the support 34 and the flat surface 31 of the plate 30. It is formed integrally with the flat surface 31 (plate portion 30).
- a gap A is formed between the notch NT and the projection 150.
- the surface and the upper surface of the protrusion 150 facing the substrate P are subjected to the liquid repellent treatment as in the previous embodiment, and are also repelled to the side surface of the notch portion NT of the substrate P.
- Liquid treatment has been applied.
- the lyophobic treatment of the projection 150 is performed by applying a fluorine resin material or the like as described above, and the lyophobic treatment of the notch NT is performed by applying a photosensitive material.
- the above-mentioned top coat layer forming material (such as a fluororesin material) may be applied to the notch portion NT.
- a concave portion 37N is formed on the side surface 37 of the substrate holder PH so as to face the convex portion 36N of the inner side surface 36 of the concave portion 32 with a predetermined gap, according to the shape of the notch portion NT.
- a peripheral wall portion 33 N formed according to the shape of the notch portion NT, and inside the peripheral wall portion 33 N, as shown in FIG. Similarly, a plurality of support portions 34 and suction ports 41 are provided (omitted in FIG. 9). Further, as in the above-described embodiment, the upper surface of the peripheral wall portion 33N is liquid repellent. When holding the substrate P on the support portion 34, gas is sucked through the suction port 41, and the first space 38 (not shown in FIG. 9) surrounded by the peripheral wall portion 33N is set to a negative pressure.
- the notch NT can be temporarily set. Even if the liquid intrudes from the gap A of the part NT, it is possible to prevent the soaked liquid from flowing into the inside of the peripheral wall 33 N.
- the notch NT is exaggerated, but is actually about 2 to 3 mm, and the shape of the notch NT is not limited to the shape shown in FIG.
- FIG. 10 is a plan view of a substrate stage PST supporting a substrate P having an orientation flat portion OF as viewed from above.
- the plate portion 30 is provided with a flat portion 151 corresponding to the shape of the orientation flat portion ⁇ F of the substrate P, and the inner surface 36 of the concave portion 32 of the Z stage 51 is provided with a flat portion.
- a flat portion 36F is formed so as to form ⁇ 151.
- the flat portion 151 has a function as a gap adjusting portion for reducing the gap between the orientation flat portion OF of the substrate P supported by the support portion 34 and the flat surface 31 of the plate portion 30. It is formed integrally with the flat surface 31 (plate portion 30).
- a gap A is formed between the orientation flat portion OF and the flat portion 151.
- the liquid repellent treatment is applied to the surface and the upper surface of the flat portion 151 facing the substrate P (orientation flat portion OF), and the liquid repellency treatment is also applied to the orientation flat portion OF.
- the lyophobic treatment of the flat portion 151 is performed by applying a fluororesin material or the like as described above.
- the lyophobic treatment of F is performed by applying a photosensitive material.
- a flat portion 37F is formed on the side surface 37 of the substrate holder PH so as to face the flat portion of the inner side surface 36 of the concave portion 32 with a predetermined gap according to the shape of the orientation flat portion OF. Further, on the upper surface of the substrate holder PH for holding the substrate P, there is provided a peripheral wall portion 33F conforming to the shape of the orientation flat portion OF. Inside the peripheral wall portion 33F, as shown in FIG. A plurality of support portions 34 and suction ports 41 are provided (omitted in FIG. 10).
- the gap A can be kept below a predetermined value, and the substrate P and the substrate stage can be maintained. Liquid 1 between P ST (plate part 30) Can be prevented from entering.
- the size and shape of the notch portion (notch portion, orientation flat portion) and the like may change depending on the substrate P.
- the notch portion of the substrate P and the plate portion 30 It may not be possible to keep the gap A between them below the specified value.
- the gap A between the cutout portion of the substrate P and the plate portion 30 cannot be kept below a predetermined value due to a manufacturing error of the outer shape of the substrate P or the mounting accuracy of the substrate P with respect to the substrate stage PST. There is a possibility.
- a projecting member 152 having a projecting portion 152 A according to the shape of the notch portion NT of the substrate P is provided so as to be movable, and is provided in a direction approaching and separating from the substrate P.
- the gap A between the notch portion NT and the projection member 152 can be kept to a predetermined value or less.
- the protruding members 15 2 are arranged in concave portions 30 D provided in a part of the plate portion 30, and are moved along the XY plane by a driving mechanism (not shown). Has become.
- the control device CONT moves the protrusion member 152 through the drive mechanism to form a predetermined gap A between the protrusion member 152 and the notch portion NT.
- the surface and the upper surface facing the substrate P (notch portion NT) and the side surfaces facing the recesses 30 D of the plate portion 30 are subjected to liquid-repellent treatment.
- the notch part NT is also liquid-repellent.
- a gap D is formed between the protruding member 15 2 and the plate portion 30. (The concave portion 30 D).
- the gap D is smaller than the gap A, Since the side of the concave portion 30D and the projection material 152 facing the concave portion 30D of the plate portion 30 is lyophobic, penetration of the liquid 1 into the gap D is prevented.
- the description of the parts common to FIG. 9 is omitted.
- FIG. 12 is a view showing a movably provided flat member 1553 having a flat surface 1553A according to the shape of the orientation flat portion OF of the substrate P.
- FIG. 12 By moving the flat member 153 toward and away from the substrate P, even if the size of the orientation flat portion OF changes, the gap A between the orientation flat portion OF and the flat member 153 can be reduced. It can be kept below a predetermined value.
- the flat member 15 3 is provided in a part of the plate portion 30. It is arranged in the concave portion 3 OD, and is moved along the XY plane by a drive mechanism (not shown).
- the control unit CONT moves the flat member 153 via the drive mechanism to form a predetermined gap A between the flat part wood 153 and the orientation flat part OF.
- the liquid repellent treatment is applied to the surface and upper surface of the flat member 153 facing the substrate P (orientation flat portion OF) and the side surface of the plate portion 30 facing the recess 30D. Liquid repellent treatment is also applied to the section OF.
- a gap D is formed between the flat member 1 53 and the plate portion 30 (recess 30D).
- the gap D is smaller than the gap A, and the recess 30D of the plate portion 30 and the flat member 1 are formed.
- the side surface of the plate portion 30 facing the concave portion 30D is lyophobic, so that the infiltration of the liquid 1 into the gap D is prevented.
- the description of the parts common to FIG. 10 is omitted.
- the protrusion member 152 (flat member 153) is provided so as to be exchangeable with respect to the substrate stage PST, and a plurality of protrusion members 152 (flat members 153) having different shapes or sizes are prepared in advance.
- the gap A can be set to a predetermined value by replacing the protruding member 1 52 (flat member 1 53) according to the shape and size of the cutout of the board P placed on the board stage PST. It can be kept below.
- the gap A near the cutout portion of the substrate P is predetermined. It should just be below the value.
- the protrusion member 152 (the flat member 153) is moved so as to form the gap A between the notch (notch portion and the orientation flat portion) of the substrate P.
- the plate portion 30 provided around P can be provided so as to be movable along the XY plane, and the gap A between the substrate P and the plate portion 30 can be adjusted to a predetermined value or less.
- the inconvenience of liquid entering the PST can be avoided. Furthermore, before carrying (loading) the substrate P onto the substrate stage PST, the size and shape (distortion) of the substrate P or the size and shape of the cutout portion of the substrate P are measured, and based on the measurement results. Each member may be moved so that the gap A is equal to or less than a predetermined value. As a result, not only the infiltration of the liquid from the gap A can be prevented more reliably, but also the edge of the substrate P can be prevented from being damaged.
- the liquid may exceed the upper surface 33 A of the peripheral wall portion 33 (46), but the liquid may exceed the upper surface 33 A of the peripheral wall portion 33. Since liquid can be caught in the buffer space 47, it is possible to prevent liquid from entering the first space 38. In addition, in order to prepare for such a case, a structure for recovering the liquid that has entered the buffer space 47 may be adopted.
- the notch (notch, orifice) of the substrate P supported by the support 34 and the flat surface 31 of the plate 30 to prevent penetration of the liquid 1 into between the protrusion 1 5 0 as the gap adjusting unit, flat 1 isolation portion 1 5 1, movable projecting members 1 5 2, provided flat member 1 5 3 Configuration.
- the symbol NT in FIG. 13, the notch portion of the substrate P and the notch portion NT ′ of the substrate P can be reduced by making the notch portion NT ′ of the substrate P as small as possible so that the liquid 1 does not enter.
- the liquid 1 can be prevented from penetrating into the space between the plate 1 and the plate portion 30.
- the notch shown in FIG. 13 has a rounded shape without an acute angle portion.
- the position of the notch may be different depending on the process conditions of the circuit formed on the substrate P and the pattern of the mask M, and the substrate P may be placed on the substrate stage PST. is there.
- the notch is placed with the notch facing the Y side
- the notch is placed + Sometimes placed with the X side facing.
- a plate portion 30 having a projection 150 is provided rotatably, and the plate portion 30 is rotated according to the position of the notch of the substrate P supported by the support portion 34.
- the substrate holder PH on which the peripheral wall portion 33N having the concave portion 37N is formed also rotates in accordance with the position of the notch portion NT.
- the projection 150 (and the projection 36N) serving as the gap adjusting section may be provided so as to be movable in the rotation direction (the ⁇ direction).
- the substrate holder PH on which the plate portion 30 having the flat portion 151 and the peripheral wall portion 33F having the flat portion 37F can be provided rotatably in accordance with the position of the orientation flat portion OF. By doing so, it is possible to prevent the liquid 1 from entering between the plate portion 30 and the substrate P (notch portion) regardless of the position of the notch portion of the substrate P.
- the entire substrate stage PST may be rotated so that the projection 150 of the plate portion 30 is aligned with the position of the notch portion NT of the substrate P supported by the support portion.
- FIG. 15A shows a state in which the notch portion NT is directed to the ⁇ Y side
- FIG. 15B shows a state in which the notch portion NT is directed to the + X side.
- a laser interferometer 56X is arranged at a position distant to the + X side of the substrate stage PST
- a laser interferometer 56Y is arranged at a position distant to the + Y side.
- the laser is disposed even when the substrate stage PST rotates by disposing the movable mirrors 55 at each of at least three edges of the substrate stage PST formed in a rectangular shape in plan view. Either moving mirror 55 can be opposed to each of the interferometers 56X and 56Y.
- the notch of the substrate P is mainly used at the time of a bri-alignment process, which is a rough alignment process when the substrate P is placed on the substrate stage PST. Specifically, the position of the notch is optically detected, and a briar alignment process is performed based on the detection result.
- the notch portion (notch portion) NT formed on the substrate P is covered with a covering member 300 having light transmittance, so that the notch portion NT is optically interposed through the covering member 300. Plate 30 and the notch NT (covered) when the substrate P is placed on the substrate stage PST.
- the disadvantage of forming a large gap with the member 300) can be prevented.
- the covering member 300 may be put on each of the plurality of notch portions NT. it can.
- the plate portion 30 substrate stage PST
- the covering member 300 in accordance with the plurality of notch portions NT.
- the hole can be optically detected and the substrate P can be aligned.
- the hole may be a small-diameter through hole that does not allow the liquid LQ to pass through, or may be a dimple-shaped hole (recess) that does not penetrate the substrate P.
- FIG. 17 shows an example in which a plurality of small through-holes 301 having a diameter of, for example, about 0: 5 mm are formed at predetermined positions of the substrate P.
- FIG. 18 is a plan view showing another embodiment of the present invention. Note that the same members as those in FIG. 4 are denoted by the same reference numerals, and detailed description is omitted.
- protrusion members 152 as gap adjustment portions are provided at a plurality of positions near the edge of the substrate P supported by the support portion 34, respectively.
- the first projection member 152Y is provided near one Y-side edge of the substrate P
- the second projection member 152X is provided near the + X-side edge.
- Each of these protrusion members 152Y and 152X is provided so as to be movable in the ⁇ -axis direction (in the vertical direction).
- a notch portion (notch portion NT) is formed in the substrate ⁇ near the edge on one side.
- FIG. 19A is a cross-sectional view near the first protrusion member 152Y
- FIG. 19B is a cross-sectional view near the second protrusion member 152X.
- the protrusion members 152 (152Y, 152X) are supported by the elastic members 302.
- the elastic member is constituted by a coil spring member
- the protruding member 152 is supported on the upper surface (contact surface) 57 of the stage 52 via the coil panel member. I have.
- the projecting member 15 2 Y is not pressed down on the substrate P, and the upward biasing force of the coil spring member 302 causes Notch Located inside the NT.
- the gap between the notch portion NT of the substrate P supported by the support portion 34 and the flat surface 31 of the plate portion 30 can be reduced by the projecting member 152 Y.
- the projecting member 15 X arranged at a position where there is no notch portion NT is pressed from above by the substrate P, and the coil spring member 302 shrinks. As a result, the projection member 152X is disposed below the substrate P.
- the protrusion member 15 2 X is disposed inside the notch portion NT, and the protrusion member 15 2 Y Is arranged below the substrate P.
- the gap between the notch portion NT of the substrate P supported by the support portion 34 and the flat surface 31 of the plate portion 30 can be reduced.
- the upper surface and side surfaces of the projecting wood 15 2 are made to be liquid-repellent by performing liquid-repellent treatment or the like. Can be more effectively prevented.
- FIGS. 20A to 20B are cross-sectional views illustrating another embodiment of the present invention.
- the embodiment of FIGS. 20A to 20B is a modification of the embodiment of FIGS. 19A to 19B, and the same members are denoted by the same reference numerals.
- the lower surface of the projection member 152 is connected to the upper end of the rod-shaped support member 303.
- a through-hole 52K is provided in a part of the Z stage 52, and the support member 303 is disposed inside the through-hole 52K so as to be movable in the Z-axis direction.
- the lower end of the support member 303 is exposed below the Z stage 52, and the lower end of the support member 303 is connected to the flange member 304.
- a leaf spring member 305 attached to the lower surface of the Z stage 52 is in contact with the lower surface of the flange member 304.
- FIGS. 19A to 19B as shown in FIG. 2OA, when the notch portion NT of the substrate P and the projection member 152 are aligned, the panel panel The projecting member 152 is lifted upward by the urging force of the member 305, and is disposed inside the notch portion NT.
- FIG. 20B when the notch portion NT of the substrate P is not aligned with the projection member 152, the projection member 152 is pressed down by the substrate P, and Located below P. Also in this case, the infiltration of the liquid 1 can be effectively prevented by making the upper surface and the side surfaces of the projection members 152 liquid-soluble.
- 21A to 21B are sectional views showing another embodiment of the present invention.
- the protruding member 152 is connected to a plate portion 30 (or a predetermined position of the substrate stage PST) via a hinge portion 360.
- the hinge portion 360 supports the projection member 152 so as to be rotatable in the ⁇ Y direction.
- the hinge portion 360 incorporates a panel member, and supports the projection member 152 so as to urge it in the direction of arrow y1 in FIG. 21B. That is, the hinge portion 360 has an urging force on the projection member 152 in a direction in which the upper surface of the projection member 152 and the surface of the substrate P are substantially flush.
- a stopper is provided on the hinge portion 2006 so that the rotation of the projection member 152 can be performed in a state where the upper surface of the projection 152 and the surface of the substrate P are substantially flush with each other. Stopped. Then, as shown in FIG. 21A, in a state where the notch portion NT of the substrate P is aligned with the protrusion member 152, the protrusion member 152 is disposed on the ⁇ side of the notch portion NT. On the other hand, as shown in FIG. 21B, in a state where the notch portion NT of the substrate P is not aligned with the projection member 152, the projection member 152 is pressed down by the substrate P, and It is arranged below. Also in this case, the infiltration of the liquid 1 can be effectively prevented by making the upper surface and the side surfaces of the projection members 152 liquid-repellent.
- the projection member 152 is configured to move by the panel member (elastic member).
- the projection member 152 may be moved by using a predetermined actuator. In this case, for example, before mounting the substrate P on the substrate stage PST, position information of the notch portion NT is obtained. Then, after mounting the substrate P on the substrate stage PST, based on the obtained position information, a predetermined projection member 152 of the plurality of projection members 152 provided on the substrate stage PST is actuated. It is also possible to drive using a to arrange the protruding member 15 2 inside the notch NT.
- the protruding members 15 2 are provided so as to be detachable from the substrate stage PST, and an operator or the like manually moves the notch NT of the substrate P on the substrate stage PST without using an actuator.
- the protrusion members 152 may be arranged.
- a protruding member that can be attached to and detached from the substrate stage PST 1 5 A robot arm capable of holding 2 may arrange the protruding member 152 on the side of the notch NT of the substrate P on the substrate stage PS.
- FIG. 22 is a diagram showing an example in which the protrusion member 152 is disposed inside the notch portion NT using an actuator.
- the projection member 152 is attached to one end (tip) of a rod-shaped support member 307, and the other end (base end) of the support member 307 is an actuator 308. It is connected to the.
- the actuator 308 is capable of rotating the support member 307 to which the projection member 152 is attached around the base end of the support member 307 as a rotation center.
- the actuator 308 rotates the support member 307 in the ⁇ Y direction. By rotating the support member 307, the actuator 308 can dispose the projection member 152 attached to the distal end of the support member 307 inside the notch portion NT.
- the liquid 1 can be effectively prevented from entering by making the upper surface and side surfaces of the projection members 152 liquid-repellent.
- the actuator 308 removes the projection member 152 from the notch portion NT of the substrate P by rotating the support member 307 in the opposite direction. Can be.
- the sheet-like member 309 is preferably liquid-repellent, and for example, a sheet-like member (Teflon sheet) made of polytetrafluoroethylene (Teflon (registered trademark)) can be used.
- the sheet-like member 309 may be formed in an annular shape, and the entire gap between the substrate P and the flat surface 31 may be covered with the sheet-like member 309.
- the projection members 152 are replaceable. It is preferable that the protrusion members 152 have liquid repellency, but the liquid repellency may deteriorate with time. Therefore, by exchanging the projection members 152 in accordance with the deterioration of the liquid repellency, it is possible to effectively prevent the penetration of the liquid 1 by using the projection members 152 having a desired liquid repellency. it can.
- the case where the projecting member 15 2 is disposed in the notch portion NT has been described as an example.
- the orientation flat portion ⁇ F formed on the substrate P It is also applicable to a flat member corresponding to.
- the flat member is arranged at a predetermined position, and the orientation flat portion ⁇ F of the substrate P supported by the support portion 34 and the flat surface 3 of the plate portion 30 are formed. By reducing the gap with 1, liquid 1 can be prevented from entering.
- FIG. 24 is a sectional view showing another embodiment of the present invention.
- the substrate stage PST includes a peripheral wall portion 33, a second peripheral wall portion 46 formed inside the peripheral wall portion 33, and a support portion formed inside the second peripheral wall portion 46. 3 and 4 are provided.
- the suction device 40 performs a suction operation through the suction port 41, and the substrate P is sucked to the support portion 34 by making the first space 38 surrounded by the second peripheral wall portion 46 a negative pressure.
- the buffer space 47 is open to the atmosphere via the flow path 48, and the pressure in the buffer space 47 is set to substantially the atmospheric pressure.
- the buffer space 47 may be set slightly higher than the atmospheric pressure or lower than the atmospheric pressure by the gas supply device 48 ′ having a pressure adjusting function, and the first space 38 The pressure may be set to a higher level (lower negative pressure) than the pressure of the pressure.
- the height of the peripheral wall portion 33 is provided lower than the support portion 34.
- the height of the second peripheral wall part 46 is also provided lower than the support part 34. Further, the upper surface 33 A of the peripheral wall portion 33 is subjected to a liquid repellent treatment and has liquid repellency. The surface 46 A of the second peripheral wall portion 46 is also subjected to the liquid repellent treatment and has liquid repellency.
- only one of the upper surface 33 A of the first peripheral wall portion 33 and the upper surface 36 A of the second peripheral wall portion 36 may be made lyophobic.
- the liquid LQ is not filled in the second space 39 between the inner surface 36 of the recess 32 and the side surface 37 of the substrate holder PH.
- the second space 39 is A second suction device 80 for collecting the liquid LQ flowing into the second space 39 is connected.
- the second suction device 80 has the same configuration as that described with reference to FIG. 8, and the pressure in the second space 39 can be made lower than the pressure in the buffer space 47.
- the tank 61 may be provided as shown in FIG. 4 without providing the pump 64 and the valve 63. Further, as shown in FIG. 4, the second space 39 may be open to the atmosphere.
- the pressure in the buffer space 47 slightly higher than the atmospheric pressure by using the gas supply device 48. This prevents the liquid 1 from entering the buffer space 47 from the gap B between the upper surface 33 A of the first peripheral wall 33 and the substrate P even if the liquid 1 slightly enters from the gap A. Can be 'suppressed'. Further, the liquid that has entered the second space 39 can be recovered.
- the first space 38 When holding the substrate P on the support portion 34, the first space 38 is set to a negative pressure, and the pressure of the buffer space 47 is set higher than that of the first space 38.
- the pressure in the buffer space 47 is set to substantially the atmospheric pressure or higher than the atmospheric pressure.
- the pressure in the buffer space 47 is set to be high, so that the liquid 1 flows through the first space 3 through the buffer space 47. 8, which prevents inconvenience of penetrating into the back side of the substrate P and the suction port 41.
- the liquid 1 that has entered between the cutout portion and the flat surface 31 is buffered.
- the inconvenience of infiltrating into the space 47 or the first space 38 can be reduced.
- the liquid may exceed the upper surface 33 A of the peripheral wall portion 33, but the liquid exceeding the upper surface 33 A of the peripheral wall portion 33 may be in the buffer space. Since the liquid can be caught at 47, it is possible to prevent the liquid from entering the first space 38.
- a structure may be adopted in which the liquid that has entered the buffer space 47 is collected.
- the side surface PB and the back surface PC of the substrate P and the flat surface 31 and the inner surface 36 of the plate portion 30 are made lyophobic. Is also good.
- the lyophobic treatment of at least a part of each surface of the substrate P, the substrate holder PH, and the substrate stage PST described in the embodiment of FIG. 4 and its modified example can be appropriately combined with the embodiment described in FIG. it can.
- the negative pressure in the first space 38 can be maintained in the second peripheral wall 46, so that a buffer space 47 and a second space 39 are formed in a part of the first peripheral wall 33. May be provided.
- FIG. 25A to 25B are views showing another embodiment of the present invention, FIG. 25A is a plan view, and FIG. 25B is a sectional view taken along the line AA of FIG. 25A.
- the same members as those in the embodiment shown in FIG. 3 are denoted by the same reference numerals, and detailed description is omitted.
- the substrate stage PST includes a plurality of suction ports (suction ports) 41 for holding the substrate P by suction on the support portion.
- a second peripheral wall portion 46 ' is partially formed inside a part of the peripheral wall # 33.
- the second peripheral wall portion 46 ' is provided at a position corresponding to the notch portion NT (or the orientation flat portion) of the substrate P supported by the support portion.
- the second peripheral wall portion 46 ' has an upper surface 46A' having a substantially arc shape in a plan view, and both ends are connected to the peripheral wall portion 33.
- a buffer space 47 ' is formed between the peripheral wall 33 and the second peripheral wall 46'.
- the buffer space 47 ' is formed near the notch portion NT of the substrate P supported by the support portion.
- each of the 33 and the second peripheral wall portion 46 ' is provided lower than that of the support portion 34, and their upper surfaces have liquid repellency.
- the plurality of suction ports 41 provided in the first space 38 are connected to a vacuum section (vacuum system) 42 via a flow path 43.
- the suction port 41 ′ provided in the buffer space 47 ′ near the notch portion NT of the substrate P passes through the second flow path 43 ′ to the second vacuum section (second section) independent of the vacuum section 42. 2 vacuum system) Connected to 42 '.
- the suction force (gas suction amount per unit time) of the second vacuum section 42 ′ is set to be weaker than the suction force of the vacuum section 42.
- the suction force via the suction port 41 ′ near the notch portion NT of the go board P is smaller than the suction force via the suction port 41 surrounding the suction port.
- the suction force through the suction ports 41 near the notch portion NT of the substrate P is made smaller than the suction force through the other suction ports 41, so that the notch portion NT of the substrate P is flat with the notch portion NT.
- the gap between the surface 3 1 (plate portion 30) is larger than the gap between the side surface PB of the substrate P other than the notch portion NT and the flat surface 31, and the liquid 1 penetrates and is structured. Even if there is, the inconvenience of the liquid 1 entering between the notch NT and the flat surface 31 can be suppressed.
- the structure that recovers the liquid that has entered the buffer space 47 ′ is connected.
- the vacuum system connected to the suction port 41 ′ is connected to the other suction port 41.
- the suction force in the vicinity of the notch portion NT of the substrate P may be reduced without being separated from the vacuum system.
- the diameter of the suction port 41 ′ near the notch portion NT of the substrate P may be smaller than that of the other suction ports 41.
- the density of the suction ports in the vicinity of the notch portion NT may be smaller than the density of the suction ports disposed around the suction ports.
- the suction port may not be provided near the notch portion NT of the substrate P.
- suction is not performed from the suction port provided near the notch portion NT of the substrate P. You can.
- the second peripheral wall portion 46 ′ is It does not have to be formed.
- the side surface PB and the back surface PC of the substrate P, the flat surface 31 and the inner surface 3 of the plate portion 30 are provided.
- 6 may be made lyophobic.
- the pressure of the liquid forming the liquid immersion area AR 2 is large, the liquid easily penetrates from the gap existing on the substrate stage PST (eg, the gap around the substrate P). Therefore, when the liquid immersion area AR2 is formed on the gap on the substrate stage PST, the pressure of the liquid may be reduced.
- the liquid pressure directly under the supply ports 13 A and 14 A of the liquid supply mechanism 10 may increase.Therefore, the supply ports 13 A and 14 A of the liquid supply mechanism 10 are connected to the substrate stage PST. When facing the upper gap, reducing the pressure of the liquid can suppress the intrusion of the liquid from the gap.
- the liquid 1 is composed of pure water. Pure water can be easily obtained in large quantities at semiconductor manufacturing factories and the like, and has the advantage of not adversely affecting the photoresist on the substrate P, optical elements (lenses), and the like. In addition, pure water has no adverse effect on the environment and has an extremely low impurity content. Can be expected. When the purity of pure water supplied from a factory or the like is low, the exposure apparatus may have an ultrapure water producing device.
- the refractive index n of pure water (water) with respect to the exposure light EL having a wavelength of about 193 nm is said to be approximately 1.44, and an ArF excimer laser light (wavelength 1) is used as the light source of the exposure light EL.
- the wavelength is shortened to 1./'n, that is, about 134 nm, and a high resolution is obtained.
- the depth of focus is expanded about n times, that is, about 1.44 times as compared with that in the air, if the same depth of focus as that used in the air can be secured, the projection The numerical aperture of the optical system PL can be further increased, and this also improves the resolution.
- the numerical aperture NA of the projection optical system may be 0.9 to 1.3.
- the numerical aperture NA of the projection optical system is increased as described above, the imaging performance may be deteriorated by the polarization effect with the random polarized light conventionally used as the exposure light. Is desirable.
- the line pattern of the mask (reticle) line and space pattern Linearly illuminated along the length of the line pattern, and a large amount of diffracted light of the s-polarized light component (TE-polarized light component), that is, the polarized light component along the longitudinal direction of the line pattern, is emitted from the mass (reticle) pattern. It is good to be done.
- the space between the projection optical system PL and the resist applied to the substrate P surface is filled with liquid, the space between the projection optical system PL and the base applied to the resist applied to the P surface is air (gas). Since the transmittance of the diffracted light of the S-polarized light component (TE-polarized light component), which contributes to the improvement of contrast, on the resist surface is higher than in the case of High imaging performance can be obtained even in cases exceeding 1.0.
- a phase shift mask such as a line saw disclosed in Japanese Patent Application Laid-Open No. Hei 6-188169, an oblique incidence illumination method (particularly a diball illumination method) adapted to the longitudinal direction of the turn, and the like are appropriately combined. It is more effective when combined.
- an ArF excimer laser is used as exposure light, and a fine line and space pattern (for example, a line of about 25 to 50 nm
- a fine line and space pattern for example, a line of about 25 to 50 nm
- the mask M acts as a polarizing plate due to the wave guide effect, thereby reducing the contrast. Since the S-polarized component (TE-polarized component) diffracted light is emitted from the mask M more than the P-polarized component (TM-polarized component) diffracted light, it is desirable to use the linearly polarized illumination described above.
- the mask M is illuminated with randomly polarized light, high resolution performance can be obtained even when the numerical aperture NA of the projection optical system PL is as large as 0.9 to 1.3.
- the P-polarized component TM-polarized component
- the S-polarized component TE-polarized component
- an Ar F excimer laser is used as the exposure light, and a line-and-space pattern larger than 25 nm is formed on the substrate P using a projection optical system PL with a reduction ratio of about 1/4.
- the diffracted light of the S-polarized component (TE-polarized component) is emitted from the mask M more than the diffracted light of the P-polarized component (TM-polarized component), so the numerical aperture of the projection optical system PL High resolution performance can be obtained even when NA is as large as 0.9 to 1.3.
- a linearly polarized illumination aligned with the longitudinal direction of the mask (reticle) line pattern In addition to Akira (S-polarized illumination), as disclosed in Japanese Patent Application Laid-Open No.
- Hei 6-53120 a polarized illumination method that linearly polarizes in the tangential (circumferential) direction of a circle centered on the optical axis has Combination with the oblique illumination method is also effective.
- the mask (reticle ') pattern includes not only line patterns extending in a predetermined direction but also line patterns extending in a plurality of different directions, the same applies to Japanese Patent Application Laid-Open No. Hei 6-53120. As described in Japanese Patent Application Laid-Open No.
- the optical element 2 is attached to the tip of the projection optical system PL, and this lens can be used to adjust the optical characteristics of the projection optical system PL, for example, aberrations (spherical aberration, coma, etc.).
- the optical element attached to the tip of the projection optical system PL may be an optical plate used for adjusting the optical characteristics of the projection optical system PL.
- a parallel plane plate that can transmit the exposure light EL may be used.
- the optical element is not replaced by the optical element but is replaced by the pressure. You may fix firmly so that it may not move.
- the space between the projection optical system PL and the surface of the substrate P is filled with the liquid 1.
- a force bar glass made of a parallel flat plate is attached to the surface of the substrate P.
- the structure which fills the liquid 1 may be sufficient.
- the liquid 1 of the present embodiment is water, but may be a liquid other than water.
- the light source of the exposure light EL is an F 2 laser
- the F 2 laser light does not transmit water, so the liquid 1 can transmit the F 2 laser light, for example, perfluoropolyether (PFPE) Or a fluorinated fluid such as fluorinated oil.
- PFPE perfluoropolyether
- fluorinated fluid such as fluorinated oil.
- other liquids that have transparency to the exposure light EL have the highest possible refractive index, and are stable with respect to the photoresist applied to the projection optical system PL and the surface of the substrate P ( It is also possible to use, for example, Seda Oil. Also in this case, the surface treatment is performed according to the polarity of the liquid 1 to be used.
- the substrate P in each of the above embodiments is not only a semiconductor wafer for manufacturing a semiconductor device, but also a glass substrate for a display device and a cell for a thin-film magnetic head.
- Lamic wafers, or original masks or reticles (synthetic quartz, silicon wafers) used in exposure equipment, etc. are applied.
- the exposure apparatus EX is a step-and-scan type scanning exposure apparatus (scanning stepper) that scans and exposes the pattern of the mask M by synchronously moving the mask M and the substrate P, as well as the mask M and the substrate.
- the present invention can also be applied to a step-and-repeat type projection exposure apparatus (stepper) in which the pattern of the mask M is exposed collectively while the substrate P is stationary and the substrate P is sequentially moved stepwise.
- the present invention is also applicable to a step-and-stitch type exposure apparatus that transfers at least two patterns on the substrate P while partially overlapping each other.
- a reduced image of the first pattern is projected onto the substrate P using a projection optical system (for example, a refraction projection optical system that does not include a reflective element at 1/8 reduction magnification) while the first pattern and the substrate P are almost stationary.
- a reduced image of the second pattern is partially overlapped with the first pattern on the substrate P using the projection optical system while the second pattern and the substrate P are almost stationary. It can be applied to a stitch type batch optical device that performs batch exposure.
- the present invention is also applicable to a twin-stage type exposure apparatus disclosed in JP-A-10-163099, JP-A-10-214783, and JP-T-2000-505958.
- the types of exposure equipment SEX are not limited to semiconductor equipment manufacturing exposure equipment that exposes a semiconductor element pattern to the substrate P, but may also be used for liquid crystal display element manufacturing or display manufacturing exposure equipment, thin film magnetic heads, imaging devices ( It can be widely applied to an exposure apparatus for manufacturing a reticle or a mask, or the like.
- each of the stages PST and MST may be of a type that moves along a guide or a guideless type that does not have a guide.
- the drive mechanism for each stage PST and MST is a magnet unit with a two-dimensionally arranged magnet and an armature unit with a two-dimensionally arranged coil, facing each other by electromagnetic force.
- the plane motor that drives each stage PST, MS ⁇ may be ffl.
- one of the magnet unit and the armature unit may be connected to the stage PST, MS #, and the other of the magnet unit and the armature unit may be provided on the moving surface side of the stage PST, MST.
- the reaction force generated by the movement of the substrate stage PST is not transmitted to the projection optical system PL, as described in JP-A-8-166475 (US Pat. No. 5,528,118). It may be mechanically released to the floor (ground) using a frame member.
- the reaction force generated by the movement of the mask stage MST is described in Japanese Patent Application Laid-Open No. H8-330224 (US S / N 08/416, 558) so as not to be transmitted to the projection optical system PL.
- a frame member may be used to mechanically escape to the floor (ground).
- the exposure apparatus EX of the embodiment of the present application is configured by assembling various subsystems including the respective components listed in the claims of the present application so as to maintain predetermined mechanical accuracy, electrical accuracy, and optical accuracy. Manufactured. Before and after this assembly, in order to ensure these various precisions, adjustments to achieve optical precision for various optical systems, adjustments to achieve mechanical precision for various mechanical systems, and various electrical systems Is adjusted to achieve electrical accuracy.
- the process of assembling the exposure apparatus from various subsystems includes mechanical connection, wiring connection of electric circuits, and piping connection of pneumatic circuits among the various subsystems. It goes without saying that there is an individual assembly process for each subsystem before the assembly process from these various subsystems to the exposure apparatus. When the process of assembling the various subsystems into the exposure apparatus is completed, comprehensive adjustments are made to ensure the various precisions of the entire exposure apparatus. It is desirable that the exposure apparatus be manufactured in a clean room where the temperature, cleanliness, etc. are controlled.
- a micro device such as a semiconductor device has a step 201 for designing the function and performance of the micro device, and a step 202 for manufacturing a mask (reticle) based on the design step.
- Step 203 for manufacturing a substrate which is a substrate of a device
- Step 204 for exposing a mask pattern to a substrate using the exposure apparatus EX of the above-described embodiment Step for assembling a device (dicing process, bonding It is manufactured through the steps of 205, the inspection step 206, etc.
- a liquid immersion area can be formed well even when exposing an edge area of a substrate, and exposure can be performed in a state where liquid infiltration and liquid outflow to the outside of the substrate stage are suppressed, and desired performance is achieved.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
Abstract
Description
Claims
Priority Applications (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020137020081A KR101528089B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020147007168A KR101520591B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
JP2005507005A JP4415939B2 (ja) | 2003-06-13 | 2004-06-11 | 露光方法、基板ステージ、露光装置、及びデバイス製造方法 |
KR1020057023920A KR101242815B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조방법 |
KR1020187028939A KR20180112884A (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020157002702A KR101729866B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020127025739A KR101528016B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020127028313A KR101421866B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020167026062A KR101940892B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
KR1020117020347A KR101290021B1 (ko) | 2003-06-13 | 2004-06-11 | 노광 방법, 기판 스테이지, 노광 장치, 및 디바이스 제조 방법 |
EP18162502.1A EP3401946A1 (en) | 2003-06-13 | 2004-06-11 | Exposure apparatus and device manufacturing method |
EP04746086.0A EP1641028B1 (en) | 2003-06-13 | 2004-06-11 | Exposure method, substrate stage, exposure apparatus and method for manufacturing device |
US11/297,324 US7483119B2 (en) | 2003-06-13 | 2005-12-09 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US11/448,927 US20060227312A1 (en) | 2003-06-13 | 2006-06-08 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US12/007,450 US8040491B2 (en) | 2003-06-13 | 2008-01-10 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US12/232,063 US8208117B2 (en) | 2003-06-13 | 2008-09-10 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US12/232,064 US8384880B2 (en) | 2003-06-13 | 2008-09-10 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US13/753,969 US9019467B2 (en) | 2003-06-13 | 2013-01-30 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US13/754,112 US9268237B2 (en) | 2003-06-13 | 2013-01-30 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US14/696,898 US9846371B2 (en) | 2003-06-13 | 2015-04-27 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
US15/664,319 US20170329234A1 (en) | 2003-06-13 | 2017-07-31 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
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JP2003169904 | 2003-06-13 | ||
JP2003-169904 | 2003-06-13 | ||
JP2003-383887 | 2003-11-13 | ||
JP2003383887 | 2003-11-13 | ||
JP2004039654 | 2004-02-17 | ||
JP2004-39654 | 2004-02-17 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US11/297,324 Continuation US7483119B2 (en) | 2003-06-13 | 2005-12-09 | Exposure method, substrate stage, exposure apparatus, and device manufacturing method |
Publications (1)
Publication Number | Publication Date |
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WO2004112108A1 true WO2004112108A1 (ja) | 2004-12-23 |
Family
ID=33556144
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2004/008578 WO2004112108A1 (ja) | 2003-06-13 | 2004-06-11 | 露光方法、基板ステージ、露光装置、及びデバイス製造方法 |
Country Status (7)
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US (9) | US7483119B2 (ja) |
EP (5) | EP3401946A1 (ja) |
JP (11) | JP4415939B2 (ja) |
KR (9) | KR101729866B1 (ja) |
HK (3) | HK1196900A1 (ja) |
TW (7) | TWI467634B (ja) |
WO (1) | WO2004112108A1 (ja) |
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