CN105647715A - 洗涤剂产品 - Google Patents
洗涤剂产品 Download PDFInfo
- Publication number
- CN105647715A CN105647715A CN201610051670.5A CN201610051670A CN105647715A CN 105647715 A CN105647715 A CN 105647715A CN 201610051670 A CN201610051670 A CN 201610051670A CN 105647715 A CN105647715 A CN 105647715A
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- CN
- China
- Prior art keywords
- long filament
- less
- present
- agent
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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Abstract
本发明提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出选自下列的特性:a)根据本文所述的基重测试方法测量的小于500g/m2的基重;b)根据本文所述的伸长率测试方法测量的大于10%的纵向峰值伸长率;c)根据本文所述的模量测试方法测量的小于1500g/cm2的几何平均模量;以及d)它们的混合。
Description
本申请是国际申请日为2011年6月30日、国家申请号为201180033278.3(国际申请号为PCT/US2011/042657)、发明名称为“洗涤剂产品”的申请的分案申请。
技术领域
本发明涉及洗涤剂产品,更具体地讲涉及包含一种或多种活性剂的洗涤剂产品,以及制备它们的方法。
背景技术
洗涤剂产品是本领域已知的。例如,浸渍有和/或涂覆有洗涤剂组合物的聚酯非织造织物是本领域已知的,如现有技术图1和2所示。如现有技术的图1和2所示,已知的非织造基底10由可溶解纤维12制成,其中非织造基底10涂覆有和/或浸渍在如活性剂的添加剂14中,而不是如活性剂的添加剂14存在于可溶解纤维12中。此类洗涤剂产品的实例是可从TheDialCorporation商购获得的Complete3-in-1LaundrySheets。
此外,由洗涤剂组合物的铸膜液形成的制造制品也是本领域已知的,并且是可以LaundrySheets从DizolveGroupCorporation商购获得。
然而,此类已知的洗涤剂产品和/或制品表现出负面影响,它们给消费者带来问题。例如,已知的洗涤剂产品和/或制品是相当硬的和/或不可挠曲的,其硬度通过本文所述的板硬度测试方法进行测量。此外,洗涤剂产品和/或制品通常递送此类低含量的洗涤剂组合物和/或洗涤剂活性剂,使得清洁性能低于消费者的期望。另一个负面影响是洗涤剂产品和/或制品在洗涤操作后可能留下洗涤剂产品和/或制品的残留部分,例如聚酯非织造基底在洗涤操作期间不溶解。
按照前述内容,很明显,需要克服与上述已知洗涤剂产品和/或制品相关联的负面影响的洗涤剂产品。
发明内容
本发明通过提供新型洗涤剂产品满足上述需要。
在本发明的一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出通过本文所述的基重测试方法测量的小于500g/m2、和/或小于450g/m2、和/或小于400g/m2、和/或小于350g/m2、和/或小于300g/m2、和/或小于250g/m2、和/或小于200g/m2的基重。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出通过本文所述的厚度测试方法测量的小于50密耳、和/或小于40密耳、和/或小于30密耳、和/或小于25密耳、和/或小于20密耳、和/或大于0.01密耳、和/或大于0.1密耳、和/或大于1密耳、和/或大于2密耳、和/或大于5密耳的厚度。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出通过本文所述的厚度测试方法测量的大于0.01mm、和/或大于0.05mm、和/或大于0.1mm、和/或至约20mm、和/或至约10mm、和/或至约5mm、和/或至约21mm、和/或至约0.5mm、和/或至约0.3mm的厚度。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出通过本文所述的模量测试方法测量的小于20,000g/cm2、和/或小于15,000g/cm2、和/或小于12,000g/cm2、和/或小于10,000g/cm2、和/或小于8,000g/cm2、和/或大于10g/cm2、和/或大于50g/cm2、和/或大于100g/cm2、和/或大于500g/cm2、和/或大于1,000g/cm2的几何平均模量。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的伸长率测试方法测量的大于10%、和/或大于20%、和/或大于30%、和/或大于50%、和/或至约200%、和/或至约100%、和/或至约75%的纵向峰值伸长率。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的伸长率测试方法测量的大于10%、和/或大于20%、和/或大于30%、和/或大于50%、和/或至约200%、和/或至约100%、和/或至约75%的横向峰值伸长率。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的干破裂测试方法测量的小于5000g、和/或小于4000g、和/或小于3000g、和/或小于2500g、和/或小于2000g、和/或小于1500g、和/或至约100g、和/或至约300g、和/或至约500g的干破裂。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的密度测试方法测量的小于0.38g/cm3、和/或小于0.35g/cm3、和/或小于0.33g/cm3、和/或小于0.31g/cm3、和/或小于28g/cm3、和/或小于25g/cm3的密度。
在本发明的另一个实例中,提供了包含一种或多种活性剂的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的板硬度测试方法测量的小于50N*mm、和/或小于40N*mm、和/或小于30N*mm、和/或小于20N*mm、和/或小于15N*mm、和/或小于10N*mm、和/或小于7N*mm、和/或小于5N*mm、和/或小于3N*mm的板硬度。
在本发明的另一个实例中,提供了包含多种长丝的非织造纤维网,其中所述长丝的至少一种包含一种或多种长丝形成材料和一种或多种活性剂,所述活性剂当所述长丝暴露于预期用途的条件时能够从所述长丝中释放,其中存在于所述长丝中的一种或多种长丝形成材料的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计为50%或更低,并且存在于所述长丝中的一种或多种活性剂的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计为50%或更高。
在本发明的另一个实例中,提供了包含多种长丝的非织造纤维网,其中所述长丝的至少一种包含一种或多种长丝形成材料和一种或多种活性剂,所述活性剂当所述长丝的形态改变时能够从所述长丝中释放,其中存在于所述长丝中的一种或多种长丝形成材料的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计小于65%,并且存在于所述长丝中的一种或多种活性剂的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计大于35%。
在本发明的另一个实例中,提供了包含多种长丝的非织造纤维网,其中所述长丝的至少一种包含一种或多种长丝形成材料和一种或多种可摄取的活性剂,所述活性剂当被动物摄取时能够从所述长丝中释放,其中存在于所述长丝中的一种或多种长丝形成材料的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计小于80%,并且存在于所述长丝中的一种或多种活性剂的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计大于20%。
在本发明的另一个实例中,提供了包含多种长丝的非织造纤维网,其中所述长丝的至少一种包含一种或多种长丝形成材料和一种或多种无香料活性剂,其中存在于所述长丝中的无香料活性剂的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计大于35%,并且其中所述长丝当暴露于预期用途的条件时释放一种或多种无香料活性剂。
因此,本发明提供了洗涤剂产品及制备此类洗涤剂产品的方法。
附图说明
图1是由涂覆有添加剂的可溶解纤维制成的现有技术非织造基底的示意图;
图2是沿图1的线2-2截取的图1的剖面图;
图3是根据本发明的长丝的示意图;
图4是根据本发明的非织造纤维网实例的示意图;
图5是适于制备根据本发明的长丝的设备的示意图;并且
图6是适于纺丝根据本发明的长丝的模头的示意图。
发明详述
定义
如本文所用,“共形成的纤维结构”指纤维结构包含多个长丝和多个纤维。在一个实例中,共形成的纤维结构包含淀粉长丝和木浆纤维。
本文所用的“长丝”是指一种延长颗粒,其具有的长度大大超过其直径,即长度对直径的比率至少约10。
本发明的长丝可经由合适的纺丝方法例如熔喷法和/或纺粘法从长丝形成组合物纺丝得到。
本发明的长丝可为单组分和/或多组分。例如,所述长丝可包括双组分长丝。双组分长丝可为任何形式,例如并列型、芯鞘型、海岛型等。
本发明的长丝的长度大于或等于5.08cm(2英寸)、和/或大于或等于7.62cm(3英寸)、和/或大于或等于10.16cm(4英寸)、和/或大于或等于15.24cm(6英寸)。
通常认为长丝天然是连续的或基本上连续的。长丝相对地比纤维更长(纤维长度小于5.08cm)。长丝的非限制性实例包括熔喷和/或纺粘长丝。
在一个实例中,一种或多种纤维可由本发明的长丝形成,例如当长丝被切成较短长度(例如小于5.08cm的长度)时形成纤维。因此,在一个实例中,本发明也包括由本发明的长丝制成的纤维,例如包含一种或多种长丝形成材料和一种或多种添加剂如活性剂的纤维。因此,除非另外指明,本发明涉及的长丝和/或多个长丝也包括由此类长丝和/或多个长丝制成的纤维。通常认为纤维相对于长丝是天然不连续的,长丝被认为是天然连续的。
如本文所用,“长丝形成组合物”是指适于制备(例如通过熔喷法和/或纺粘法制备)本发明的长丝的组合物。长丝形成组合物包含一种或多种长丝形成材料,其表现出使得它们适于纺丝成长丝的特性。在一个实例中,长丝形成材料包含聚合物。除了一种或多种长丝形成材料外,长丝形成组合物还可包含一种或多种添加剂,例如一种或多种活性剂。此外,长丝形成组合物可包含一种或多种极性溶剂例如水;一种或多种(例如所有的)长丝形成材料和/或一种或多种(例如所有的)活性剂溶解和/或分散在所述溶剂中。
在如图3所示的一个实例中,由本发明的长丝形成组合物制成的本发明的长丝16使得一种或多种添加剂18(例如一种或多种活性剂)可存在于长丝中,而不是存在于长丝上,例如现有技术图1和2所示的涂层。只要从中产生本发明的长丝,存在于长丝形成组合物中的长丝形成材料的总含量和活性剂的总含量可为任何合适的量。
在一个实例中,一种或多种添加剂如活性剂可存在于长丝中,并且一种或多种附加的添加剂如活性剂可存在于长丝表面上。在另一个实例中,本发明的长丝可包含一种或多种添加剂如活性剂,其在初始制造时存在于长丝中,但是随后在暴露于长丝预期用途的条件之前和/或在暴露于长丝预期用途的条件时缓释到长丝表面。
如本文所用,“长丝形成材料”是指诸如聚合物或能够产生聚合物的单体的材料,其表现出适于制备长丝的特性。在一个实例中,所述长丝形成材料包含一种或多种取代聚合物如阴离子聚合物、阳离子聚合物、两性离子聚合物、和/或非离子聚合物。在另一个实例中,所述聚合物可包括羟基聚合物如聚乙烯醇(“PVOH”)、和/或多糖如淀粉、和/或淀粉衍生物如乙氧基化淀粉和/或酸解淀粉。在另一个实例中,所述聚合物可包含聚乙烯和/或对苯二甲酸。在另一个实例中,所述长丝形成材料是极性溶剂可溶解的材料。
如本文所用,“添加剂”是指存在于本发明长丝中的任何材料,其不是长丝形成材料。在一个实例中,添加剂包括活性剂。在另一个实例中,添加剂包括加工助剂。在另一个实例中,添加剂包括填料。在一个实例中,添加剂包括存在于长丝中的任何材料,如果其不存在于长丝中将不会导致长丝丧失其长丝结构,换句话讲,其缺失不会导致长丝丧失其固体形式。在另一个实例中,添加剂例如活性剂包括非聚合物材料。
在另一个实例中,添加剂包括长丝的增塑剂。本发明的合适增塑剂的非限制性实例包括多元醇、共聚多元醇、多元羧酸、聚酯和聚二甲基硅氧烷共聚多元醇。可用多元醇实例包括但不限于甘油、双甘油、丙二醇、乙二醇、丁二醇、戊二醇、环己烷二甲醇、己二醇、2,2,4-三甲基戊烷-1,3-二醇、聚乙二醇(200-600)、季戊四醇、糖醇(如山梨醇、甘露醇、乳糖醇)、以及其它一元和多元低分子量醇(例如C2-C8-醇);单糖、二糖和低聚糖,如果糖、葡萄糖、蔗糖、麦芽糖、乳糖、高果糖玉米糖浆固体和糊精、以及抗坏血酸。
在一个实例中,增塑剂包括甘油、和/或丙二醇、和/或甘油衍生物如丙氧基化甘油。在另一个实例中,增塑剂选自:甘油、乙二醇、聚乙二醇、丙二醇、缩水甘油、脲、山梨醇、木糖醇、麦芽糖醇、糖、乙烯双甲酰胺、氨基酸、以及它们的混合物。
在另一个实例中,添加剂包含交联剂,所述交联剂适于交联存在于本发明长丝中的一种或多种长丝形成材料。在一个实例中,交联剂包括能够将羟基聚合物交联到一起(例如经由羟基聚合物的羟基部分)的交联剂。合适交联剂的非限制性实例包括咪唑啉酮、多元羧酸、以及它们的混合物。在一个实例中,交联剂包括脲乙二醛加合物交联剂,例如二羟基咪唑啉酮如二羟基亚乙基脲(“DHEU”)。交联剂可存在于本发明的长丝形成组合物和/或长丝中以控制长丝的溶解度和/或在溶剂如极性溶剂中的溶解。
在另一个实例中,添加剂包括流变改性剂例如剪切改性剂和/或延伸改性剂。流变改性剂的非限制性实例包括但不限于聚丙烯酰胺、聚氨酯和聚丙烯酸酯,它们可用于本发明的长丝。流变改性剂的非限制性实例可从TheDowChemicalCompany(Midland,MI)商购获得。
在另一个实例中,添加剂包括一种或多种着色剂和/或染料,它们被混入本发明的长丝以在长丝暴露于预期用途的条件时和/或活性剂从长丝中释放出来时和/或长丝的形态改变时提供视觉信号。
在另一个实例中,添加剂包括一种或多种剥离剂和/或润滑剂。合适的剥离剂和/或润滑剂的非限制性实例包括脂肪酸、脂肪酸盐、脂肪醇、脂肪酸酯、磺化脂肪酸酯、乙酸脂肪胺、脂肪酸酰胺、硅氧烷、氨基硅氧烷、含氟聚合物、以及它们的混合物。在一个实例中,将剥离剂和/或润滑剂施用于长丝,换句话讲在形成长丝后施用。在一个实例中,在收集长丝到收集装置上以形成非织造材料之前将一种或多种剥离剂/润滑剂施用于长丝。在另一个实例中,在接触一种或多种非织造纤维网如一叠非织造纤维网之前将一种或多种剥离剂/润滑剂施用于由本发明的长丝形成的非织造纤维网。在另一个实例中,在长丝和/或非织造纤维网接触表面如工艺体系中使用的设备表面之前将一种或多种剥离剂/润滑剂施用于本发明的长丝和/或包含长丝的非织造纤维网,从而有利于去除长丝和/或非织造纤维网和/或用于避免本发明的长丝层和/或非织造纤维网彼此粘连,甚至在无意间达到上述目的。在一个实例中,剥离剂/润滑剂包括颗粒。
在另一个实例中,添加剂包括一种或多种抗粘连剂和/或防粘剂。合适的抗粘连剂和/或防粘剂的非限制性实例包括淀粉、淀粉衍生物、交联聚乙烯吡咯烷酮、交联纤维素、微晶纤维素、二氧化硅、金属氧化物、碳酸钙、滑石、云母、以及它们的混合物。
如本文所用,“预期用途的条件”是指当本发明的长丝用于一种或多种其设计用途时暴露的温度条件、物理条件、化学条件和/或机械条件。例如,如果长丝和/或包含长丝的非织造纤维网被设计用于洗衣机的衣物洗涤护理目的,预期用途的条件将包括在衣物洗涤运行期间存在于洗衣机中的那些温度条件、化学条件、物理条件和/或机械条件,包括任何洗涤水。在另一个实例中,如果长丝和/或包含长丝的非织造纤维网被设计用于人毛发护理目的洗发剂,预期用途的条件将包括在用洗发剂洗涤人类毛发期间存在的那些温度条件、化学条件、物理条件和/或机械条件。同样地,如果长丝和/或包含长丝的非织造纤维网被设计用于手洗盘碟或盘碟洗涤机洗涤盘碟,预期用途的条件将包括在盘碟洗涤运行期间存在于盘碟洗涤水和/或盘碟洗涤机中的那些温度条件、化学条件、物理条件和/或机械条件。
如本文所用,“活性剂”是指在外部环境中产生对长丝和/或包含本发明长丝的非织造纤维网的预期效应的添加剂,例如当长丝暴露于长丝和/或包含长丝的非织造纤维网的预期用途条件时产生效应。在一个实例中,活性剂包括添加剂,其处理表面如硬质表面(即,厨房的工作台面、浴缸、盥洗室、抽水马桶、洗碗池、地面、墙面、牙齿、汽车、窗、镜子、碟)和/或软质表面(即,织物、毛发、皮肤、地毯、作物、植物)。在另一个实例中,活性剂包括添加剂,其产生化学反应(即,起泡、冒泡、着色、加温、冷却、起泡、消毒和/或澄清和/或氯化,例如在澄清水和/或消毒水和/或氯化水中产生化学反应)。在另一个实例中,活性剂包括添加剂,其处理环境(即,脱臭、纯化、给空气加香)。在一个实例中,所述活性剂原位形成,例如在包含活性剂的长丝形成期间形成,例如所述长丝可包含水溶性聚合物(例如淀粉)和表面活性剂(例如阴离子表面活性剂),其可产生聚合物复合物或聚集体,起到活性剂的作用,用于处理织物表面。
如本文所用,“处理”相对于处理表面指所述活性剂提供对表面或环境的有益效果。处理包括调节和/或立即改善表面或环境的外观、清洁度、气味、纯度和/或触感。在一个实例中涉及处理角质组织(例如皮肤和/或毛发)表面的处理指调节和/或立即改善角质组织的美容外观和/或触感。例如,“调节皮肤、毛发、或指/趾甲(角质组织)状况”包括:增厚皮肤、毛发或指/趾甲(例如,构造皮肤的表皮和/或真皮和/或皮下[例如,皮下脂肪或肌肉]层,和可适用的指甲和发干的角质层)以减少皮肤、毛发或指/趾甲的萎缩;增加真皮-表皮边界(也称为网缘)的卷曲;防止皮肤或毛发弹性的损失(功能性皮肤蛋白的损失、破坏和/或失活)例如弹性组织变性、松垂、皮肤损失或毛发变形的反冲;防止黑色素或非黑色素改变皮肤、毛发或指/趾甲的颜色,例如眼袋、疹斑(例如,由如红斑痤疮引起的不均匀红色)(以下称作为“红斑”)、灰黄(灰色、由毛细管扩张或蛛形血管引起的褪色、以及毛发变灰。
在另一个实例中,处理指从织物制品如衣服、毛巾、亚麻布,和/或硬质表面如厨房的工作台面和/或包括罐和盘子的盘碟上去除污渍和/或气味。
如本文所用,“织物护理活性剂”是指当施用于织物时提供有益效果和/或改善织物的活性剂。对织物的有益效果和/或改善的非限制性实例包括清洁(例如通过表面活性剂清洁)、去污效果、减少污渍、去皱、恢复颜色、静电控制、抗皱、耐久压熨、减少磨损、防磨损、起球/小球去除、抗起球/小球、去垢、防垢(包括去垢性)、形状保持、减少缩水、柔软性、芳香、抗菌、抗病毒、抗臭和去除气味。
如本文所用,“盘碟洗涤活性剂”是指当施用于盘碟、玻璃器具、塑料制品、罐、盘子、器皿、和/或烹饪板时提供对盘碟、玻璃器具、罐、盘子、和/或烹饪板的有益效果和/或改善的活性剂。对盘碟、玻璃器具、塑料制品、罐、盘子、器皿、和/或烹饪板的有益效果和/或改善的非限制性实例包括食品和/或去垢、清洁(例如通过表面活性剂清洁)、去污效果、减少污渍、去除油脂、去除水垢和/或防水垢、玻璃和金属护理、消毒、闪亮和抛光。
如本文所用,“硬质表面活性剂”是指当施用于地面、厨房的工作台面、洗碗池、窗、镜子、淋浴、沐浴、和/或盥洗室时提供对地面、厨房的工作台面、洗碗池、窗、镜子、淋浴、沐浴、和/或盥洗室的有益效果和/或改善的活性剂。对地面、厨房的工作台面、洗碗池、窗、镜子、淋浴、沐浴、和/或盥洗室的有益效果和/或改善的非限制性实例包括食品和/或去垢、清洁(例如通过表面活性剂清洁)、去污效果、减少污渍、去除油脂、去除水垢和/或防水垢、水垢去除、消毒、闪亮、抛光和清新。
如本文所用,“重量比”是指长丝中基于干燥长丝和/或干燥洗涤剂产品的形成材料(g或%)重量对长丝中基于干重的添加剂如活性剂(g或%)重量的比率。
如本文所用,“羟基聚合物”包括任何含羟基的聚合物,它们可被混入本发明的长丝中,例如作为长丝形成材料被混入。在一个实施例中,本发明的羟基聚合物包括按重量计大于10%、和/或大于20%、和/或大于25%的羟基部分。
如本文所用,“能够生物降解的”对于材料如长丝整体和/或长丝内的聚合物如长丝形成材料指长丝和/或聚合物在市政固体垃圾堆肥厂中能够发生和/或确实发生物理降解、化学降解、热降解和/或生物降解,使得至少5%和/或至少7%和/或至少10%的初始长丝和/或聚合物在30天后转化成二氧化碳,这根据OECD(1992)GuidelinefortheTestingofChemicals301B;ReadyBiodegradability-CO2Evolution(ModifiedSturmTest)Test测量,该文献以引用方式并入本文。
如本文所用,“不能够生物降解的”对于材料如长丝整体和/或长丝内的聚合物如长丝形成材料指长丝和/或聚合物在市政固体垃圾堆肥厂中不能够发生物理降解、化学降解、热降解和/或生物降解,使得至少5%的初始长丝和/或聚合物在30天后转化成二氧化碳,这根据OECD(1992)GuidelinefortheTestingofChemicals301B;ReadyBiodegradability-CO2Evolution(ModifiedSturmTest)Test测量,该文献以引用方式并入本文。
如本文所用,“非热塑性”对于材料如长丝整体和/或长丝内的聚合物如长丝形成材料是指长丝和/或聚合物表现出无熔点和/或软化点,这在缺乏增塑剂如水、甘油、山梨醇、脲等的情况下允许它在压力下流动。
如本文所用,“非热塑性、能够生物降解的长丝”是指表现出如上所述能够生物降解的和非热塑性的特性的长丝。
如本文所用,“非热塑性、不能够生物降解的长丝”是指表现出如上所述不能够生物降解的和非热塑性的特性的长丝。
如本文所用,“热塑性”对于材料如长丝整体和/或长丝内的聚合物如长丝形成材料是指长丝和/或聚合物在某一温度下表现出具有熔点和/或软化点,这在缺乏增塑剂的情况下允许它在压力下流动。
如本文所用,“热塑性、能够生物降解的长丝”是指表现出如上所述能够生物降解的和热塑性的特性的长丝。
如本文所用,“热塑性、不能够生物降解的长丝”是指表现出如上所述不能够生物降解的和热塑性的特性的长丝。
如本文所用,“不含纤维素的”指在长丝中存在按重量计小于5%、和/或小于3%、和/或小于1%、和/或小于0.1%、和/或0%的纤维素聚合物、纤维素衍生物聚合物和/或纤维素共聚物。在一个实例中,“不含纤维素的”是指在长丝中存在按重量计小于5%、和/或小于3%、和/或小于1%、和/或小于0.1%、和/或0%的纤维素聚合物。
如本文所用,“极性溶剂可溶解的材料”是指在极性溶剂中可混溶的材料。在一个实例中,极性溶剂可溶解的材料可混溶在醇和/或水中。换句话讲,极性溶剂可溶解的材料是在环境条件下能够与极性溶剂如醇和/或水形成稳定(在形成均匀溶液超过5分钟后不发生相分离)均匀溶液的材料。
如本文所用,“醇可溶解的材料”是指可混溶在醇中的材料。换句话讲,它是在环境条件下能够与醇形成稳定(在形成均匀溶液超过5分钟后不发生相分离)均匀溶液的材料。
如本文所用,“水可溶解的材料”是指可混溶在水中的材料。换句话讲,它是在环境条件下能够与水形成稳定(在形成均匀溶液超过5分钟后不发生分离)均匀溶液的材料。
如本文所用,“非极性溶剂可溶解的材料”是指在非极性溶剂中可混溶的材料。换句话讲,非极性溶剂可溶解的材料是能够与非极性溶剂形成稳定(在形成均匀溶液超过5分钟后不发生相分离)均匀溶液的材料。
如本文所用,“环境条件”是指73°F±4°F(约23℃±2.2℃)和50%±10%的相对湿度。
本文所用的“重均分子量”是指按照规程用凝胶渗透色谱法测定的重均分子量,所述规程见于“ColloidsandSurfacesA.PhysicoChemical&EngineeringAspects,第162卷,2000年,第107-121页。
如本文所用,“长度”对于长丝指沿长丝从一端至另一端的长度。如果长丝中有打结、卷曲或弯曲,那么所述长度为沿着长丝完整线路的长度。
如本文所用,对于长丝“直径”是根据本文所述的直径测试方法(DiameterTestMethod)测量的。在一个实例中,本发明的长丝表现出小于100μm、和/或小于75μm、和/或小于50μm、和/或小于25μm、和/或小于20μm、和/或小于15μm、和/或小于10μm、和/或小于6μm、和/或大于1μm、和/或大于3μm的直径。
如本文所用,“触发条件”在一个实例中是指用于刺激或启动或促成长丝改变的任何行为或事件,例如丧失或改变长丝的物理结构和/或释放添加剂如活性剂。在另一个实例中,触发条件可存在于环境中,例如当将本发明的长丝和/或非织造纤维网和/或膜加到水中时触发条件存在于水中。换句话讲,水中除了将本发明的长丝和/或非织造纤维网和/或膜加到水中的事实之外没有改变发生。
如本文所用,“形态改变”对于长丝的形态改变是指长丝发生其物理结构的改变。本发明长丝的形态改变的非限制性实例包括溶解、熔融、溶胀、起皱、破碎成段、膨胀、变长、变短、以及它们的组合。本发明的长丝当暴露于预期用途的条件时可完全或基本上丧失它们的长丝物理结构或者它们可发生形态改变或者它们可保留或基本上保留它们的长丝物理结构。
“按干燥长丝和/或干燥洗涤剂产品重量计”是指长丝和/或洗涤剂产品已经在温度为73°F±4°F(约23℃±2.2℃)并且相对湿度为50%±10%的设定条件室内调整2小时后立即测量该长丝和/或洗涤剂产品的重量。在一个实例中,“按干燥长丝和/或干燥洗涤剂产品重量计”是指包含按长丝和/或干燥洗涤剂产品重量计小于20%、和/或小于15%、和/或小于10%、和/或小于7%、和/或小于5%、和/或小于3%、和/或至0%、和/或至大于0%的水分如水(例如游离水)的长丝和/或干燥洗涤剂产品,这根据本文所述的水含量测试方法进行测量。
如本文所用,“总含量”对于例如存在于长丝和/或干燥洗涤剂产品中的一种或多种活性剂的总含量是指所有受试材料如活性剂的总重量或总重量%。换句话讲,长丝和/或洗涤剂产品可包含按干燥长丝和/或干燥洗涤剂产品重量计25%的阴离子表面活性剂,按干燥长丝和/或干燥洗涤剂产品重量计15%的非离子表面活性剂,按重量计10%的螯合剂,以及5%的香料,从而存在于长丝中的活性剂总含量大于50%;即按干燥长丝和/或干燥洗涤剂产品重量计55%。
如本文所用,“洗涤剂产品”是指固体形式,例如矩形固体,有时称为片,其包含一种或多种活性剂如织物护理活性剂、盘碟洗涤活性剂、硬质表面活性剂、以及它们的混合物。在一个实例中,本发明的洗涤剂产品包含一种或多种表面活性剂、一种或多种酶、一种或多种香料、和/或一种或多种抑泡剂。在另一个实例中,本发明的洗涤剂产品包含助洗剂和/或螯合剂。在另一个实例中,本发明的洗涤剂产品包含漂白剂。
在一个实例中,洗涤剂产品包含纤维网,例如非织造纤维网。
如本文所用,“纤维网”是指任何性质或来源彼此相关联的纤维和/或长丝形成的集合,例如纤维结构,和/或纤维和/或长丝形成的洗涤剂产品,例如连续长丝。在一个实例中,所述纤维网是矩形固体,其包含经由纺丝工艺而非浇铸工艺形成的纤维和/或长丝。
对于本发明目的,如本文所用并一般由EuropeanDisposablesandNonwovensAssociation(EDANA)定义的“非织造纤维网”是指任何性质或来源的纤维和/或长丝形成的片,例如连续长丝,它们已经通过任何装置形成纤维网,并且可通过除编织或针织外的任何装置结合到一起。通过湿磨法获得的毛毡不是非织造纤维网。在一个实例中,根据本发明的非织造纤维网是指在某一结构内有序排列长丝以行使功能。在一个实例中,本发明的非织造纤维网是包括多组两个或更多个和/或三个或更多个长丝的排列,它们彼此间纠缠或换句话讲彼此相连以形成非织造纤维网。在一个实例中,本发明的非织造纤维网除本发明的长丝外还可包含一种或多种固体添加剂如颗粒和/或纤维。
如本文所用,“颗粒”指颗粒状物质和/或粉末。在一个实例中,所述长丝和/或纤维可转化成粉末。
本文所用的冠词“一种”当用于本文时,例如“一种阴离子表面活性剂”或“一种纤维”,被理解为指一种或多种受权利要求书保护的或所述的物质。
除非另外指明,所有百分比和比率均按重量计算。除非另外指明,所有百分比和比率均基于总组合物计算。
除非另外指明,所有组分或组合物含量均是关于该组分或组合物的活性物质含量,不包括可能存在于市售源中的杂质,例如残余溶剂或副产品。
长丝
本发明的长丝包含一种或多种长丝形成材料。除了长丝形成材料之外,所述长丝还可包含一种或多种活性剂,例如所述活性剂当所述长丝暴露于预期用途的条件时能够从所述长丝中释放,其中存在于所述长丝中的一种或多种长丝形成材料的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计小于80%,并且存在于所述长丝中的一种或多种活性剂的总含量按干燥长丝重量计和/或按干燥洗涤剂产品重量计大于20%。
在一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计约100%、和/或大于95%、和/或大于90%、和/或大于85%、和/或大于75%、和/或大于50%的一种或多种长丝形成材料。例如,所述长丝形成材料可包括聚乙烯醇和/或淀粉。
在另一个实例中,本发明的长丝包含一种或多种长丝形成材料和一种或多种活性剂,其中存在于长丝中的长丝形成材料的总含量按干燥长丝和/或干燥洗涤剂产品重量计为约5%至小于80%,并且存在于长丝中的活性剂的总含量按干燥长丝和/或干燥洗涤剂产品重量计大于20%至约95%。
在一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计至少10%、和/或至少15%、和/或至少20%、和/或小于80%、和/或小于75%、和/或小于65%、和/或小于60%、和/或小于55%、和/或小于50%、和/或小于45%、和/或小于40%的长丝形成材料,以及按干燥长丝和/或干燥洗涤剂产品重量计大于20%、和/或至少35%、和/或至少40%、和/或至少45%、和/或至少50%、和/或至少60%、和/或小于95%、和/或小于90%、和/或小于85%、和/或小于80%、和/或小于75%的活性剂。
在一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计至少5%、和/或至少10%、和/或至少15%、和/或至少20%、和/或小于50%、和/或小于45%、和/或小于40%、和/或小于35%、和/或小于30%、和/或小于25%的长丝形成材料,以及按干燥长丝和/或干燥洗涤剂产品重量计大于50%、和/或至少55%、和/或至少60%、和/或至少65%、和/或至少70%、和/或小于95%、和/或小于90%、和/或小于85%、和/或小于80%、和/或小于75%的活性剂。在一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计大于80%的活性剂。
在另一个实例中,存在于长丝中的一种或多种长丝形成材料和活性剂的重量比(长丝形成材料总含量对活性剂总含量的重量比)为4.0或更低、和/或3.5或更低、和/或3.0或更低、和/或2.5或更低、和/或2.0或更低、和/或1.85或更低、和/或小于1.7、和/或小于1.6、和/或小于1.5、和/或小于1.3、和/或小于1.2、和/或小于1、和/或小于0.7、和/或小于0.5、和/或小于0.4、和/或小于0.3、和/或大于0.1、和/或大于0.15、和/或大于0.2。
在另一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计约10%和/或约15%至小于80%的长丝形成材料如聚乙烯醇聚合物和/或淀粉聚合物,以及按干燥长丝和/或干燥洗涤剂产品重量计大于20%至约90%和/或至约85%的活性剂。所述长丝还可包含增塑剂如甘油和/或pH调节剂如柠檬酸。
在另一个实例中,本发明的长丝包含按干燥长丝和/或干燥洗涤剂产品重量计约10%和/或约15%至小于80%的长丝形成材料如聚乙烯醇聚合物和/或淀粉聚合物,以及按干燥长丝和/或干燥洗涤剂产品重量计大于20%至约90%和/或至约85%的活性剂,其中长丝形成材料对活性剂的重量比为4.0或更低。所述长丝还可包含增塑剂如甘油和/或pH调节剂如柠檬酸。
在本发明的另一个实例中,长丝包含一种或多种长丝形成材料和一种或多种活性剂,所述活性剂选自:酶、漂白剂、助洗剂、螯合剂、感觉剂、分散剂、以及它们的混合物,当长丝暴露于预期用途的条件时它们是能够释放的和/或被释放。在一个实例中,长丝包含按干燥长丝和/或干燥洗涤剂产品重量计总含量小于95%、和/或小于90%、和/或小于80%、和/或小于50%、和/或小于35%、和/或至约5%、和/或至约10%、和/或至约20%的长丝形成材料,并且包含按干燥长丝和/或干燥洗涤剂产品重量计总含量大于5%、和/或大于10%、和/或大于20%、和/或大于35%、和/或大于50%、和/或大于65%、和/或至约95%、和/或至约90%、和/或至约80%的活性剂,所述活性剂选自:酶、漂白剂、助洗剂、螯合剂、以及它们的混合物。在一个实例中,活性剂包括一种或多种酶。在另一个实例中,活性剂包括一种或多种漂白剂。在另一个实例中,活性剂包括一种或多种助洗剂。在另一个实例中,活性剂包括一种或多种螯合剂。
在本发明的另一个实例中,本发明的长丝可包含活性剂,所述活性剂如果变成空气传播的话可产生健康和/或安全方面的问题。例如,长丝可用于防止长丝内的酶变成空气传播的。
在一个实例中,本发明的长丝可为熔喷长丝。在一个实例中,本发明的长丝可为纺粘长丝。在另一个实例中,长丝在释放一种或多种它的活性剂之前和/或之后可为中空长丝。
本发明的长丝可为亲水性的或疏水性的。可表面处理和/或内部处理长丝以改变长丝的固有亲水性或疏水性特性。
在一个实例中,长丝表现出根据本文所述的直径测试方法测量的小于100μm、和/或小于75μm、和/或小于50μm、和/或小于25μm、和/或小于10μm、和/或小于5μm、和/或小于1μm的直径。在另一个实例中,本发明的长丝表现出根据本文所述的直径测试方法测量的大于1μm的直径。本发明的长丝的直径可用于控制存在于该长丝中的一种或多种活性剂的释放速率和/或损失速率和/或改变长丝的物理结构。
所述长丝可包含两种或更多种不同的活性剂。在一个实例中,所述长丝包含两种或更多种不同的活性剂,其中所述两种或更多种不同的活性剂彼此相容。在另一个实例中,所述长丝包含两种或更多种不同的活性剂,其中所述两种或更多种不同的活性剂彼此不相容。
在一个实例中,所述长丝可在该长丝内包含一种活性剂,并且在该长丝的外表面如长丝的涂层上包含一种活性剂。在长丝外表面上的活性剂可与长丝中存在的活性剂相同或不同。如果不同,所述活性剂可彼此相容或不相容。
在一个实例中,可将一种或多种活性剂均匀分配到或基本上均匀分配到长丝各处。在另一个实例中,可将一种或多种活性剂分配到长丝内的不连续区域。在另一个实例中,将至少一种活性剂均匀地或基本上均匀地分配到长丝各处,并且将至少另一种活性剂分配成在长丝内的一个或多个不连续区域。在另一个实例中,将至少一种活性剂分配成长丝内的一个或多个不连续区域,并且将至少一种其他活性剂分配成在长丝内不同于第一不连续区域的一个或多个不连续区域。
所述长丝可用作不连续制品。在一个实例中,可将长丝施用于和/或沉积在载体基质上,例如擦拭物、纸巾、卫生纸、面巾纸、卫生巾、棉塞、尿布、成人失禁制品、洗碗布、烘干机纸、衣物洗涤片、衣物洗涤棒、干洗片、结网、滤纸、织物、衣服、内衣等。
此外,可收集多个本发明的长丝并将它们压成膜,因此产生包含一种或多种长丝形成材料和一种或多种可从膜中释放的活性剂的膜,例如当所述膜暴露于预期用途的条件时释放。
在一个实例中,本发明的膜表现出根据本文所述的溶解度测量方法(DissolutionTestMethod)测量的每克样品平均崩解时间为小于120秒/克(s/g)、和/或小于100s/g、和/或小于80s/g、和/或小于55s/g、和/或小于50s/g、和/或小于40s/g、和/或小于30s/g、和/或小于20s/g。
在另一个实例中,本发明的膜表现出根据本文所述的溶解度测量方法测量的每克样品平均溶解时间为小于950秒/克(s/g)、和/或小于900s/g、和/或小于800s/g、和/或小于700s/g、和/或小于600s/g、和/或小于550s/g。
在一个实例中,本发明的膜表现出根据本文所述的厚度测量方法测量大于0.01mm、和/或大于0.05mm、和/或大于0.1mm、和/或至约20mm、和/或至约10mm、和/或至约5mm、和/或至约2mm、和/或至约0.5mm、和/或至约0.3mm的厚度。
长丝形成材料
长丝形成材料是任何合适的材料,例如表现出适于制备长丝的特性的聚合物或能够产生聚合物的单体,如通过纺丝工艺制备长丝。
在一个实例中,长丝形成材料可包括极性溶剂可溶解的材料,如醇可溶解的材料和/或水可溶解的材料。
在另一个实例中,长丝形成材料可包括非极性溶剂可溶解的材料。
在另一个实例中,长丝形成材料可包括极性溶剂可溶解的材料并且不含(按干燥长丝和/或干燥洗涤剂产品重量计小于5%、和/或小于3%、和/或小于1%、和/或0%)非极性溶剂可溶解的材料。
在另一个实例中,长丝形成材料可为成膜材料。在另一个实例中,长丝形成材料可为合成的或天然来源的,并且它可发生化学、酶促和/或物理改变。
在本发明的另一个实例中,长丝形成材料可包含选自下列的聚合物:来源于丙烯酸类单体如烯键式不饱和羧基单体以及烯键式不饱和单体的聚合物、聚乙烯醇、聚丙烯酸酯、聚甲基丙烯酸酯、丙烯酸和丙烯酸甲酯的共聚物、聚乙烯吡咯烷酮、聚环氧烷、淀粉和淀粉衍生物、支链淀粉、胶质、羟丙基甲基纤维素、甲基纤维素和羧基甲基纤维素。
在另一个实例中,长丝形成材料可包含选自下列的聚合物:聚乙烯醇、聚乙烯醇衍生物、淀粉、淀粉衍生物、纤维素衍生物、半纤维素、半纤维素衍生物、蛋白质、藻酸钠、羟丙基甲基纤维素、脱乙酰壳多糖、脱乙酰壳多糖衍生物、聚乙二醇、四氢呋喃、聚乙烯吡咯烷酮、羟甲基纤维素、羟乙基纤维素、以及它们的混合物。
在另一个实例中,长丝形成材料包含选自下列的聚合物:支链淀粉、羟丙基甲基纤维素、羟乙基纤维素、羟丙基纤维素、聚乙烯吡咯烷酮、羧甲基纤维素、藻酸钠、黄原胶、黄蓍胶、瓜尔胶、阿拉伯树胶、聚丙烯酸、甲基丙烯酸甲酯共聚物、羧乙烯基聚合物、糊精、果胶、甲壳质、果聚糖、爱生兰、胶原、胶质、玉米素、谷蛋白、大豆蛋白、酪蛋白、聚乙烯醇、淀粉、淀粉衍生物、半纤维素、半纤维素衍生物、蛋白质、脱乙酰壳多糖、脱乙酰壳多糖衍生物、聚乙二醇、四氢呋喃、羟甲基纤维素、以及它们的混合物。
极性溶剂可溶解的材料
极性溶剂可溶解的材料的非限制性实例包括极性溶剂可溶解的聚合物。极性溶剂可溶解的聚合物可为合成的或天然来源的,并且可发生化学和/或物理改变。在一个实例中,极性溶剂可溶解的聚合物表现出至少10,000g/mol、和/或至少20,000g/mol、和/或至少40,000g/mol、和/或至少80,000g/mol、和/或至少100,000g/mol、和/或至少1,000,000g/mol、和/或至少3,000,000g/mol、和/或至少10,000,000g/mol、和/或至少20,000,000g/mol、和/或至约40,000,000g/mol、和/或至约30,000,000g/mol的重均分子量。
在一个实例中,极性溶剂可溶解的聚合物选自:醇可溶解的聚合物、水溶性聚合物、以及它们的混合物。水溶性聚合物的非限制性实例包括水溶性羟基聚合物、水溶性热塑性聚合物、水溶性能够生物降解的聚合物、水溶性不能够生物降解的聚合物、以及它们的混合物。在一个实例中,水溶性聚合物包括聚乙烯醇。在另一个实例中,水溶性聚合物包括淀粉。在另一个实例中,水溶性聚合物包括聚乙烯醇和淀粉。
a.水溶性羟基聚合物-依照本发明的水溶性羟基聚合物的非限制性实施例包括多元醇,如聚乙烯醇、聚乙烯醇衍生物、聚乙烯醇共聚物、淀粉、淀粉衍生物、淀粉共聚物、脱乙酰壳多糖、脱乙酰壳多糖衍生物、脱乙酰壳多糖共聚物、纤维素衍生物如纤维素醚和纤维素酯衍生物、纤维素共聚物、半纤维素、半纤维素衍生物、半纤维素共聚物、树胶、阿拉伯聚糖、半乳聚糖、蛋白质和多种其它多糖、以及它们的混合物。
在一个实例中,本发明的水溶性羟基聚合物包括多糖。
本文所用术语“多糖”是指天然多糖和多糖衍生物和/或改性多糖。合适地水溶性多糖包括但不限于淀粉、淀粉衍生物、脱乙酰壳多糖、脱乙酰壳多糖衍生物、纤维素衍生物、半纤维素、半纤维素衍生物、树胶、阿拉伯聚糖、半乳聚糖、以及它们的混合物。水溶性多糖可表现出约10,000g/mol至约40,000,000g/mol、和/或大于100,000g/mol、和/或大于1,000,000g/mol、和/或大于3,000,000g/mol、和/或大于3,000,000g/mol至约40,000,000g/mol的重均分子量。
水溶性多糖可包括非纤维素、和/或非纤维素衍生物、和/或非纤维素共聚物水溶性多糖。此类非纤维素水溶性多糖可选自:淀粉、淀粉衍生物、脱乙酰壳多糖、脱乙酰壳多糖衍生物、半纤维素、半纤维素衍生物、树胶、阿拉伯聚糖、半乳聚糖、以及它们的混合物。
在另一个实例中,本发明的水溶性羟基聚合物包括非热塑性聚合物。
水溶性羟基聚合物可具有约10,000g/mol至约40,000,000g/mol、和/或大于100,000g/mol、和/或大于1,000,000g/mol、和/或大于3,000,000g/mol、和/或大于3,000,000g/mol至约40,000,000g/mol的重均分子量。较高和较低分子量的水溶性羟基聚合物可与具有某个期望重均分子量的羟基聚合物联合使用。
诸如水溶性羟基聚合物例如天然淀粉的熟知改性,包括化学改性和/或酶改性。例如,天然淀粉可被酸稀化、羟乙基化、羟丙基化和/或氧化。此外,水溶性羟基聚合物可包含臼齿形玉米淀粉。
天然存在的淀粉一般是直链淀粉和D-葡萄糖单位的支链淀粉聚合物的混合物。直链淀粉基本上是D-葡萄糖单位通过(1,4)-α-D键接合的线型聚合物。支链淀粉是D-葡萄糖单位的高度支化聚合物,所述D-葡萄糖单位通过(1,4)-α-D键和(1,6)-α-D键在支化点接合。天然存在的淀粉通常包含相对高含量的支链淀粉,例如玉米淀粉(64-80%支链淀粉)、蜡质玉米(93-100%支链淀粉)、稻(83-84%支链淀粉)、马铃薯(约78%支链淀粉)和小麦(73-83%支链淀粉)。虽然所有淀粉是本文潜在可用的,本发明最常用的是高支链淀粉的天然淀粉,其来源于农业来源,这具有供应充足、易于补充和廉价的优点。
如本文所用,“淀粉”包括任何天然存在的未改性淀粉、改性淀粉、合成淀粉、以及它们的混合物,以及直链淀粉或支链淀粉部分的混合物;所述淀粉可通过物理方法、化学方法、或生物学方法、或它们的组合进行改性。本发明对未改性或改性淀粉的选择可取决于期望的最终产物。在本发明的一个实施方案中,用于本发明的淀粉或淀粉混合物具有按淀粉或其混合物重量计约20%至约100%,更典型地约40%至约90%,甚至更典型地约60%至约85%的支链淀粉含量。
合适的天然存在的淀粉可包括但不限于玉米淀粉、马铃薯淀粉、甘薯淀粉、小麦淀粉、西谷椰子淀粉、木薯淀粉、米淀粉、大豆淀粉、竹竽淀粉、支链淀粉、蕨根淀粉、藕淀粉、蜡质玉米淀粉和高直链淀粉玉米淀粉。天然存在的淀粉尤其是玉米淀粉和小麦淀粉是优选的淀粉聚合物,这是因为它们的经济性和可用性。
可以用其它单体来接枝本文的聚乙烯醇以改变它的性能。已经成功地将大量单体接枝到聚乙烯醇上。此类单体的非限制性实例包括乙酸乙烯酯、苯乙烯、丙烯酰胺、丙烯酸、2-甲基丙烯酸羟乙酯、丙烯腈、1,3-丁二烯、异丁烯酸甲酯、甲基丙烯酸、马来酸、衣康酸、乙烯基磺酸钠、烯丙基磺酸钠、甲基丙烯磺酸钠、烯丙基苯基醚磺酸钠、甲代烯丙基苯基醚磺酸钠、2-丙烯酰胺-甲基丙磺酸(AMP)、偏二氯乙烯、氯乙烯、乙烯胺和多种丙烯酸酯。
在一个实例中,水溶性羟基聚合物选自:聚乙烯醇、羟甲基纤维素、羟乙基纤维素、羟丙基甲基纤维素、以及它们的混合物。合适的聚乙烯醇的非限制性实例包括可从SekisuiSpecialtyChemicalsAmerica,LLC(Dallas,TX)以商标商购获得的那些。合适的羟丙基甲基纤维素的非限制性实例包括可从DowChemicalCompany(Midland,MI)以商标商购获得的那些,包括上文提到的羟丙基甲基纤维素的组合。
b.水溶性热塑性聚合物-合适的水溶性热塑性聚合物的非限制性实例包括热塑性淀粉和/或淀粉衍生物、聚乳酸、多羟基链烷酸酯、聚己内酯、聚酯酰胺和某些聚酯、以及它们的混合物。
本发明的水溶性热塑性聚合物可为亲水性的或疏水性的。水溶性热塑性聚合物可经表面处理和/或内部处理以改变热塑性聚合物的固有亲水性或疏水性特性。
水溶性热塑性聚合物可包括能够生物降解的聚合物。
可使用任何合适的重均分子量的热塑性聚合物。例如,根据本发明的热塑性聚合物的重均分子量大于约10,000g/mol、和/或大于约40,000g/mol、和/或大于约50,000g/mol、和/或小于约500,000g/mol、和/或小于约400,000g/mol、和/或小于约200,000g/mol。
非极性溶剂可溶解的材料
非极性溶剂可溶解的材料的非限制性实例包括非极性溶剂可溶解的聚合物。合适的非极性溶剂可溶解的材料的非限制性实例包括纤维素、甲壳质、甲壳质衍生物、聚烯烃、聚酯、它们的共聚物、以及它们的混合物。聚烯烃的非限制性实例包括聚丙烯、聚乙烯、以及它们的混合物。聚酯的非限制性实例包括聚对苯二甲酸乙二醇酯。
非极性溶剂可溶解的材料可包含不能够生物降解的聚合物如聚丙烯、聚乙烯和某些聚酯。
可使用任何合适的重均分子量的热塑性聚合物。例如,根据本发明的热塑性聚合物的重均分子量大于约10,000g、和/或大于约40,000g、和/或大于约50,000g/mol、和/或小于约500,000g/mol、和/或小于约400,000g/mol、和/或小于约200,000g/mol。
活性剂
活性剂是一类添加剂,其经设计并旨在提供对除长丝本身之外的某些事物的有益效果,例如提供对长丝外部环境的有益效果。活性剂可为任何合适的添加剂,其在长丝的预期用途条件下产生预期的效应。例如,活性剂可选自:个人清洁和/或调理剂,例如毛发护理剂如洗发剂和/或毛发着色剂、毛发调理剂、皮肤护理剂、防晒剂和皮肤调理剂;衣物洗涤护理和/或调理剂如织物护理剂、织物调理剂、织物软化剂、织物抗皱剂、织物护理抗静电剂、织物护理去污剂、去垢剂、分散剂、抑泡剂、促泡剂、消泡剂和织物清新剂;液体和/或粉末盘碟洗涤剂(用于手洗餐具洗涤和/或自动洗碗机用途)、硬质表面护理剂、和/或调理剂、和/或抛光剂;其他清洁和/或调理剂如抗微生物剂、香料、漂白剂(如氧化漂白剂、过氧化氢、过碳酸盐漂白剂、过硼酸盐漂白剂、氯漂白剂)、漂白活化剂、螯合剂、助洗剂、乳液、增白剂、空气护理剂、地毯护理剂、染料转移抑制剂、水软化剂、水硬化剂、pH调节剂、酶、絮凝剂、泡腾剂、防腐剂、美容剂、卸妆剂、发泡剂、沉积助剂、聚集体形成剂、粘土、增稠剂、胶乳、二氧化硅、干燥剂、气味控制剂、止汗剂、凉爽剂、加温剂、吸收凝胶剂、抗炎剂、染料、颜料、酸和碱;液体处理活性剂;农业活性剂;工业活性剂;可摄取的活性剂如治疗剂、牙齿美白剂、牙齿护理剂、漱口剂、牙周牙龈护理剂、食用剂、膳食剂、维生素、矿物;水处理剂如水澄清和/或水消毒剂、以及它们的混合物。
合适的美容剂、皮肤护理剂、皮肤调理剂、毛发护理剂、和毛发调理剂的非限制性实例在CTFACosmeticIngredientHandbook,第二版,TheCosmetic,Toiletries,andFragranceAssociation,Inc.1988,1992中进行了描述。
一类或多类化学制品可用于上文列出的一种或多种活性剂。例如,表面活性剂可用于上述任何数目的活性剂。同样,漂白剂可用于织物护理、硬质表面清洁、盘碟洗涤以及甚至牙齿美白。因此,本领域的普通技术人员将会知道基于长丝和/或由其制成的非织造织物的期望预期用途来选择活性剂。
例如,如果本发明的长丝和/或由其制成的非织造织物将被用于毛发护理和/或调理,那么可选择一种或多种合适的表面活性剂例如发泡表面活性剂以提供当其暴露于长丝和/或混入长丝的非织造织物的预期用途条件时对消费者的期望有益效果。
在一个实例中,如果本发明的长丝和/或由其制成的非织造织物被设计或旨在用于洗衣操作中的衣物洗涤,那么可选择一种或多种合适的表面活性剂和/或酶和/或助洗剂和/或香料和/或抑泡剂和/或漂白剂以提供当其暴露于长丝和/或混入长丝的非织造织物的预期用途条件时对消费者的期望有益效果。在另一个实例中,如果本发明的长丝和/或由其制成的非织造织物被设计用于洗衣操作中的衣物洗涤和/或盘碟洗涤操作中的盘碟清洁,那么长丝可包含衣物洗涤剂组合物或盘碟洗涤剂组合物。
在一个实例中,活性剂包括无香料活性剂。在另一个实例中,活性剂包括无表面活性剂的活性剂。在另一个实例中,活性剂包括不可摄取活性剂,换句话讲不是可摄取的活性剂的活性剂。
表面活性剂
合适表面活性剂的非限制性实例包括阴离子表面活性剂、阳离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂、以及它们的混合物。长丝也可包括辅助表面活性剂。对于设计用作衣物洗涤剂和/或盘碟洗涤剂的长丝,表面活性剂的总含量将足以提供清洁,包括清洁污渍和/或去除气味,并且一般介于约0.5%至约95%的范围内。此外,包含两种或更多种表面活性剂的表面活性剂体系被设计用于衣物洗涤剂和/或盘碟洗涤剂的长丝,其可包括所有阴离子表面活性剂体系、包含阴离子-非离子表面活性剂混合物、或非离子-阳离子表面活性剂混合物或低发泡非离子表面活性剂的混合型表面活性剂体系。
本文的表面活性剂可为直链或支化的。在一个实例中,合适的直链表面活性剂包括来源于农用化学品油如椰子油、棕榈仁油、大豆油、或其他植物油的那些。
a.阴离子表面活性剂
合适的阴离子表面活性剂的非限制性实例包括但不限于烷基硫酸盐、烷基醚硫酸盐、支化的烷基硫酸盐、支化的烷基烷氧基化物、支化的烷基烷氧基化物硫酸盐、中链支化的烷基芳基磺酸盐、硫酸化单酸甘油酯、磺化烯烃、烷基芳基磺酸盐、伯烷烃或仲烷烃磺酸盐、琥珀酸烷基酯磺酸盐、酰基牛磺酸盐、酰基羟乙基磺酸盐、烷基甘油基醚磺酸盐、磺化甲酯、磺化脂肪酸、烷基磷酸盐、酰基谷氨酸盐、酰基肌氨酸盐、磺基乙酸烷基酯、酰化肽、烷基醚羧酸盐、酰基乳酸盐、阴离子含氟表面活性剂、月桂酰谷氨酸钠、以及它们的组合。
适用于本文的烷基硫酸盐和烷基醚硫酸盐包括具有相应的式ROSO3M和RO(C2H4O)xSO3M的材料,其中R为具有约8个至约24个碳原子的烷基或烯基,x为1至10,并且M为水溶性阳离子如铵、钠、钾和三乙醇胺。其他合适的阴离子表面活性剂在McCutcheon’s“DetergentsandEmulsifiers”北美版(1986年),AlluredPublishingCorp.和McCutcheon’s,FunctionalMaterials,北美版(1992),AlluredPublishingCorp中进行了描述。
在一个实例中,用于本发明的长丝的阴离子表面活性剂包括C9-C15烷基苯磺酸盐(LAS)、C8-C20烷基醚硫酸盐如烷基聚(乙氧基)硫酸盐、C8-C20烷基硫酸盐、以及它们的混合物。其他阴离子表面活性剂包括甲酯磺酸盐(MES)、仲烷烃磺酸盐、甲酯乙氧基化物(MEE)、磺化酸酐、以及它们的混合物。
在另一个实例中,阴离子表面活性剂选自:C11-C18烷基苯磺酸盐(“LAS”)和伯支链无规C10-C20烷基硫酸盐(“AS”)、C10-C18仲(2,3)烷基硫酸盐,其式为CH3(CH2)x(CHOSO3 -M+)CH3和CH3(CH2)y(CHOSO3 -M+)CH2CH3,其中x和(y+1)是至少约7,优选地至少约9的整数,并且M是水增溶阳离子尤其是钠离子、不饱和硫酸盐如油基硫酸盐、C10-C18α-磺化脂肪酸酯、C10-C18烷基糖苷硫酸酯盐、C10-C18烷基烷氧基硫酸盐(“AExS”),其中x为1-30,并且C10-C18烷基烷氧基甲酸酯如包含1-5个乙氧基单位、中链支化的烷基硫酸盐,如US6,020,303和US6,060,443中所讨论的那些;中链支化的烷基烷氧基硫酸盐,如US6,008,181和US6,020,303中所述;改性烷基苯磺酸盐(MLAS),如WO99/05243、WO99/05242和WO99/05244中所讨论的那些;甲酯磺酸盐(MES);和α-烯烃磺酸盐(AOS)。
其他可使用的合适阴离子表面活性剂是烷基酯磺酸盐表面活性剂,包括C8-C20羧酸(即,脂肪酸)的磺化直链酯。其他可使用的合适的阴离子表面活性剂包括皂盐、C8-C22伯仲链烷磺酸酯、C8-C24烯烃磺酸酯、磺化多元羧酸、C8-C24烷基聚乙二醇醚硫酸盐(包含至多10摩尔环氧乙烷);烷基甘油磺酸盐、脂肪酰甘油磺酸盐、脂肪油酰甘油硫酸盐、烷基酚环氧乙烷醚硫酸盐、石蜡磺酸盐、烷基磷酸盐、羟乙基磺酸盐如酰基羟乙基磺酸盐、N-酰基牛磺酸盐、烷基琥珀酰胺酸盐和磺基琥珀酸盐、磺基琥珀酸单酯(例如饱和的和不饱和的C12-C18单酯)和磺基琥珀酸二酯(例如饱和的和不饱和的C6-C12二酯)、烷基多醣的硫酸盐如烷基多聚葡萄糖苷硫酸盐、和烷基多乙氧基羧酸盐如具有式RO(CH2CH2O)k-CH2COO-M+的那些,其中R是C8-C22烷基,k为0至10的整数,并且M为可溶性成盐阳离子。
其他示例性的阴离子表面活性剂是C10-C16直链烷基苯磺酸的碱金属盐,优选C11-C14直链烷基苯磺酸的碱金属盐。在一个实例中,所述烷基是直链的。此类直链烷基苯磺酸盐被称为“LAS”。此类表面活性剂和它们的制备方法描述于例如美国专利公开2,220,099和2,477,383中。在另一个实例中,直链烷基苯磺酸盐包括直链烷基苯磺酸钠和/或钾,其中烷基上的平均碳原子数为约11至14。C11-C14直链烷基苯磺酸钠如C12直链烷基苯磺酸钠是此类表面活性剂的具体实例。
另一种示例性的阴离子表面活性剂包括直链或支化的乙氧基化的烷基硫酸盐表面活性剂。此类物质还被称为烷基醚硫酸盐或烷基多乙氧基化硫酸盐,它们是符合式:R′-O-(C2H4O)n-SO3M的那些,其中R′为C8-C20烷基,n为约1至20,并且M为成盐阳离子。在一个具体的实施方案中,R′为C10-C18烷基,n为约1至15,并且M为钠、钾、铵、烷基铵、或链烷醇铵。在更具体的实施方案中,R′为C12-C16,n为约1至6,并且M为钠。通常以混合物的形式使用烷基醚硫酸盐,该混合物包含不同的R′链长和不同的乙氧基化度。通常,上述混合物还将不可避免地包含某些非乙氧基化烷基硫酸盐物质,即,上述乙氧基化烷基硫酸盐式中n=0的表面活性剂。非乙氧基化烷基硫酸盐还可单独加入到本发明组合物中,并用作或用于可能存在的任何阴离子表面活性剂组分中。非烷氧基化(如非乙氧基化)烷基醚硫酸盐表面活性剂的具体实施例是经由高级C8-C20脂肪醇硫酸盐化作用制得的那些。常规的伯烷基硫酸盐表面活性剂具有通式:R”OSO3 -M+,其中R”通常为C8-C20烷基,所述烃基可以是直链或支链的,并且M为水增溶阳离子。在具体的实施方案中,R”为C10-C15烷基,并且M为碱金属,更具体地R”为C12-C14烷基,并且M为钠。可用于本文的阴离子表面活性剂的具体非限制性实例包括:a)C11-C18烷基苯磺酸盐(LAS);b)C10-C20伯烷基、支链烷基和无规烷基硫酸盐(AS);c)具有下式的C10-C18仲(2,3)-烷基硫酸盐:
其中M为氢或提供电中性的阳离子,并且所有的M单元,无论是与表面活性剂还是与辅助成分缔合,均可以为氢原子或阳离子,这取决于被技术人员分离的形式或在其中使用化合物的体系的相对pH,其中合适阳离子的非限制性实例包括钠、钾、铵、以及它们的混合物,并且x是至少约7和/或至少约9的整数,并且y是至少8和/或至少9的整数;d)C10-C18烷基烷氧基硫酸盐(AEzS),其中z例如为1-30;e)C10-C18烷基烷氧基羧酸盐,优选包括1个至5个乙氧基单元;f)中链支化的烷基硫酸盐,如美国专利公开6,020,303和6,060,443所述;g)中链支化的烷基烷氧基硫酸盐,如美国专利公开6,008,181和6,020,303所述;h)改性的烷基苯磺酸盐(MLAS),如WO99/05243、WO99/05242、WO99/05244、WO99/05082、WO99/05084、WO99/05241、WO99/07656、WO00/23549和WO00/23548中所述;i)甲酯磺酸盐(MES);和j)α-烯烃磺酸盐(AOS)。
b.阳离子表面活性剂
适合的阳离子表面活性剂的非限制实例包括但不限于具有式(I)的那些:
其中R1、R2、R3和R4各自独立地选自(a)约1个至约26个碳原子的脂族基团,或(b)具有至多22个碳原子的芳族基团、烷氧基、聚氧化烯、烷基酰氨基、羟基烷基、芳基或烷基芳基;X为成盐阴离子,如选自卤离子(例如氯离子、溴离子)、乙酸根、柠檬酸根、乳酸根、乙醇酸根、磷酸根、硝酸根、硫酸根和烷基硫酸根的那些。在一个实例中,烷基硫酸根为甲基硫酸根和/或乙基硫酸根。
具有通式(I)的适宜季铵阳离子表面活性剂可包括鲸蜡基三甲基氯化铵、二十二烷基三甲基氯化铵(BTAC)、硬脂基三甲基氯化铵、鲸蜡基氯化吡啶、十八烷基三甲基氯化铵、十六烷基三甲基氯化铵、辛基二甲基苄基氯化铵、癸基二甲基苄基氯化铵、硬脂基二甲基苄基氯化铵、氯化双癸基二甲基铵、双十二烷基二甲基氯化铵、双十八烷基二甲基氯化铵、二硬脂基二甲基氯化铵、牛油基三甲基氯化铵、椰油基三甲基氯化铵、2-乙基己基硬脂基二甲基氯化铵、二棕榈酰乙基二甲基氯化铵、PEG-2油基氯化铵、以及这些的盐,其中氯离子被卤素(例如溴离子)、乙酸根、柠檬酸根、乳酸根、乙醇酸根、磷酸根、硝酸根、硫酸根、或烷基硫酸根替代。
合适的阳离子表面活性剂的非限制性实例可以商标购自AkzoNobelSurfactants(CHicago,IL)。
在一个实例中,合适的阳离子表面活性剂包括季铵表面活性剂,例如具有最多26个碳原子的季铵表面活性剂,其包括:如US6,136,769中所述的烷氧基化季铵(AQA)表面活性剂;如6,004,922中所述的二甲基羟乙基季铵;二甲基羟乙基月桂基氯化铵;如WO98/35002、WO98/35003、WO98/35004、WO98/35005和WO98/35006中所述的多胺阳离子表面活性剂;如美国专利4,228,042、4,239,6604,260,529和US6,022,844中所述的阳离子酯表面活性剂;和如US6,221,825和WO00/47708中所述的氨基表面活性剂,例如酰氨基丙基二甲基胺(APA)。
其他合适的阳离子表面活性剂包括伯、仲和叔脂肪胺的盐。在一个实施方案中,此类胺的烷基具有约12个至约22个碳原子,并且可为取代或未取代的。这些胺通常与酸联合使用以提供阳离子物质。
阳离子表面活性剂可包括阳离子酯表面活性剂,其具有下式:
其中R1是C5-C31直链或支化的烷基、烯基或烷芳基链或M-.N+(R6R7R8)(CH2)s;X和Y独立地选自:COO、OCO、O、CO、OCOO、CONH、NHCO、OCONH和NHCOO,其中X或Y中的至少其中一个是COO、OCO、OCOO、OCONH或NHCOO基;R2、R3、R4、R6、R7和R8独立地选自:烷基、烯基、羟烷基、羟基烯基和烷芳基,它们具有1个至4个碳原子;并且R5独立地为氢或C1-C3烷基;其中m、n、s和t的值独立地在0至8的范围内,b的值在0至20的范围内,并且a、u和v的值独立地为0或1,前提条件是u或v中的至少其中一个必须是1;并且其中M是抗衡阴离子。在一个实例中,R2、R3和R4独立地选自CH3和-CH2CH2OH。在另一个实例中,M选自:卤离子、甲基硫酸根、硫酸根、硝酸根、氯离子、溴离子、或碘离子。
可选择本发明的阳离子表面活性剂用于个人清洁用途。在一个实例中,为了提供易于漂洗感、流变学和湿调理有益效果的平衡,此类阳离子表面活性剂可被包括在长丝和/或纤维内,其总含量按重量计为约0.1%至约10%、和/或约0.5%至约8%、和/或约1%至约5%、和/或约1.4%至约4%。多种阳离子表面活性剂包括一-和二-烷基链阳离子表面活性剂,其可用于本发明组合物。在一个实例中,为了提供所期望的凝胶基质和润湿调理有益效果,阳离子表面活性剂包括单烷基链阳离子表面活性剂。为了提供均衡的润湿调理有益效果,所述单烷基阳离子表面活性剂是具有一个长烷基链的那些,所述烷基链具有12个至22个碳原子、和/或16个至22个碳原子、和/或18个至22个碳原子。与氮连接的其它基团独立地选自具有1个至约4个碳原子的烷基、或具有最多约4个碳原子的烷氧基、聚氧化烯基、烷基酰氨基、羟烷基、芳基或烷基芳基。上述单烷基阳离子表面活性剂包括,例如单烷基季铵盐和单烷基胺。单烷基季铵盐包括例如具有非官能化烷基长链的那些。单烷基胺包括例如单烷基酰氨基胺及其盐。也可单独使用其它的阳离子表面活性剂如二烷基链阳离子表面活性剂,或与单烷基链阳离子表面活性剂组合使用。上述二烷基链阳离子表面活性剂包括例如二烷基(14-18)二甲基氯化铵、二牛油烷基二甲基氯化铵、二氢化牛油烷基二甲基氯化铵、二硬脂基二甲基氯化铵和双十六烷基二甲基氯化铵。
在一个实例中,阳离子酯表面活性剂在衣物洗涤条件下是可水解的。
c.非离子表面活性剂
合适的非离子表面活性剂的非限制性实例包括烷氧基化醇(AE)和烷基苯酚、多羟基脂肪酸酰胺(PFAA)、烷基聚葡糖苷(APG)、C10-C18甘油醚等。
在一个实例中,用于本发明的非离子表面活性剂的非限制性实例包括:C12-C18烷基乙氧基化物,如购自Shell的非离子表面活性剂;C6-C12烷基酚烷氧基化物,其中烷氧基化物单元是乙烯氧基和丙烯氧基单元的混合物;C12-C18醇和C6-C12烷基酚与环氧乙烷/环氧丙烷嵌段烷基多胺乙氧基化物的缩合物,例如得自BASF的如US6,150,322中所讨论的C14-C22中链支化醇BA;如US6,153,577、US6,020,303和US6,093,856中所讨论的C14-C22中链支化烷基烷氧基化物BAEx,其中x为1-30;如1986年1月26日公布的Llenado的U.S.4,565,647中所讨论的烷基多糖;具体地讲,如US4,483,780和US4,483,779中所讨论的烷基多苷;如US5,332,528中所讨论的多羟基洗涤剂酸酰胺;以及如US6,482,994和WO01/42408中所讨论的醚封端的聚(烷氧基化)醇表面活性剂。
适于本发明的可商购获得的非离子表面活性剂的实例包括:均售自DowChemicalCompany的15-S-9(C11-C15直链醇与9摩尔环氧乙烷的缩合产物)和24-L-6NMW(C12-C14伯醇与6摩尔具有窄分子量分布的环氧乙烷的缩合产物);售自ShellChemicalCompany的45-9(C14-C15直链醇与9摩尔环氧乙烷的缩合产物)、23-3(C12-C13直链醇与3摩尔环氧乙烷的缩合产物)、45-7(C14-C15直链醇与7摩尔环氧乙烷的缩合产物)和45-5(C14-C15直链醇与5摩尔环氧乙烷的缩合产物);EOB(C13-C15醇与9摩尔环氧乙烷的缩合产物),其售自TheProcter&GambleCompany;以及售自Hoechst的GenapolLAO3O或O5O(C12-C14醇与3或5摩尔环氧乙烷的缩合产物)。非离子表面活性剂可表现出的HLB范围为约8至约17和/或约8至约14。还可使用与环氧丙烷和/或环氧丁烷的缩合产物。
用于本发明的半极性非离子表面活性剂的非限制性实例包括:水溶性氧化胺,其包含一个具有约10个至约18个碳原子的烷基部分和2个选自下列的部分:包含约1个至约3个碳原子的烷基部分和羟烷基部分;水溶性氧化膦,其包含一个具有约10个至约18个碳原子的烷基部分和2个选自下列的部分:包含约1个至约3个碳原子的烷基部分和羟烷基部分;和水溶性亚砜,所述水溶性亚砜包含一个具有约10至个约18个碳原子的烷基部分和选自下列的部分:具有约1个至约3个碳原子的烷基部分和羟烷基部分。参见WO01/32816、US4,681,704和US4,133,779。
可用于本发明的另一类非离子表面活性剂包括多羟基脂肪酸酰胺表面活性剂,其具有下式:
其中R1是氢、或C1-4烃基、2-羟乙基、2-羟丙基、或它们的混合物,R2是C5-31烃基,并且Z是多羟基烃基,其具有直接连接到所述链上的至少3个羟基的直链烃基链,或它们的烷氧基化衍生物。在一个实例中,R1是甲基,R2是C11-15烷基直链或C15-17烷基或烯基直链,如椰子烷基或它们的混合物,并且Z来源于发生还原胺化反应的还原糖如葡萄糖、果糖、麦芽糖、乳糖。典型的实例包括C12-C18和C12-C14N-甲基葡糖胺。
烷基多糖表面活性剂也可用作本发明的非离子表面活性剂。
烷基苯酚的聚乙烯、聚丙烯和聚丁烯氧化物缩合物也适用作本发明的非离子表面活性剂。这些化合物包括烷基苯酚的缩合产物,所述烷基苯酚具有的烷基包含约6个至约14个碳原子,与环氧烷形成直链或支链的构型。这种类型的可商购获得的非离子表面活性剂包括CO-630,其购自GAFCorporation;和X-45、X-114、X-100以及X-102,它们均购自DowChemicalCompany。
对于自动盘碟洗涤用途,可使用低发泡非离子表面活性剂。合适的低发泡非离子表面活性剂在US7,271,138第7栏第10行至第7栏第60行中公开。
其他合适的非离子表面活性剂的实例是可商购获得的表面活性剂,其购自BASF;可商购获得的化合物,其购自BASF;以及可商购获得的表面活性剂,其购自BASF。
d.两性离子表面活性剂
两性离子或两性表面活性剂的非限制性实例包括:仲胺和叔胺的衍生物;杂环仲胺和叔胺的衍生物;或季铵、季或叔锍化合物的衍生物。两性离子表面活性剂的实施例参见美国专利3,929,678第19栏第38行至第22栏第48行;甜菜碱,其包括烷基二甲基甜菜碱和椰油二甲基酰胺丙基甜菜碱、C8-C18(例如C12-C18)氧化胺和磺基和羟基甜菜碱,如N-烷基-N,N-二甲基氨基-1-丙磺酸盐,其中烷基可以是C8-C18以及在某些实施方案中来自C10-C14。
e.两性表面活性剂
两性表面活性剂的非限制性实例包括仲胺或叔胺的脂族衍生物、或杂环仲胺和叔胺的脂族衍生物(其中脂族基团可为直链或支链)、以及它们的混合物。一个脂族取代基可包含至少约8个碳原子,例如约8个至约18个碳原子,并且至少一个包含水增溶性阴离子基团,例如羧基、磺酸根、硫酸根。适宜两性表面活性剂的实例参见美国专利公开3,929,678第19栏第18行至35行。
f.辅助表面活性剂
除了上述表面活性剂之外,长丝也可包含辅助表面活性剂。对于衣物洗涤剂和/或盘碟洗涤剂,它们通常包含多种类型表面活性剂的混合物,从而获得对多种污垢和污渍以及在多种使用条件下的广泛清洁性能。广泛的这些辅助表面活性剂可用于本发明的长丝。阴离子、非离子、两性和两性离子类别和这些辅助表面活性剂物质的典型列表在上文中给出并且也可见于美国专利公开3,664,961。换句话讲,本文的表面活性剂体系也可包括一种或多种辅助表面活性剂,其选自非离子表面活性剂、阳离子表面活性剂、阴离子表面活性剂、两性离子表面活性剂或它们的混合物。辅助表面活性剂的选择可以由所需的有益效果决定。所述表面活性剂体系可包含按所述组合物的重量计0%至约10%,或约0.1%至约5%,或约1%至约4%的其他辅助表面活性剂。
g.胺中和的阴离子表面活性剂
本发明的阴离子表面活性剂和/或阴离子辅助表面活性剂可以酸形式存在,可将其中和以形成表面活性剂盐。在一个实例中,长丝可包含盐形式的表面活性剂。用于中和的典型试剂包括碱性金属抗衡离子如氢氧化物,例如氢氧化钠或氢氧化钾。用于中和酸形式的阴离子表面活性剂和阴离子辅助表面活性剂的其他试剂包括氨、胺、或链烷醇胺。在一个实例中,所述中和剂包括链烷醇胺,例如选自下列的链烷醇胺:单乙醇胺、二乙醇胺、三乙醇胺、以及本领域已知的其他直链或支化的链烷醇胺;例如2-氨基-1-丙醇、1-氨丙醇、一异丙醇胺、或1-氨基-3-丙醇。可部分完成或全部完成胺中和,例如可用钠或钾中和部分阴离子表面活性剂并且可用胺或链烷醇胺中和部分阴离子表面活性剂。
香料
一种或多种香料和/或香料原材料如谐香剂和/或香可混入一种或多种本发明的长丝。所述香料可包含选自下列的香料成分:醛香料成分、酮香料成分、以及它们的混合物。
本发明的长丝可包括一种或多种香料和/或香料成分。用作香料和/或香料成分的众多天然和合成化学成分包括但不限于醛、酮、酯、以及它们的混合物。还包括各种天然提取物和精油,其包括各成分的复杂混合物,如橙油、柠檬油、玫瑰提取物、熏衣草、麝香植物、绿叶刺蕊草、凤仙花精油、檀木油、松油、雪松等。精制香料可包括此类成分的极端复杂的混合物。在一个实例中,成品香料通常占按干燥长丝和/或干燥洗涤剂产品重量计约0.01%至约2%。
香料递送体系
某些香料递送体系,制备某些香料递送体系的方法和此类香料递送体系的应用公开于USPA2007/0275866A1中。香料递送体系的非限制性实例包括以下体系:
I.聚合物辅助递送(PAD):该香料递送技术使用聚合材料递送香料物质。一些实例是典型的水溶性或部分水溶性材料凝聚成不溶性带电或中性聚合物、液晶、热熔融物、水凝胶、充有香料的塑料、微胶囊、纳米胶乳和微米胶乳、聚合物膜形成剂和聚合物吸收剂、聚合物吸附剂等。PAD包括但不限于:
a.)基质体系:所述芳香剂溶解或分散在聚合物基质或颗粒中。香料,例如,可以1)在配制到所述产品中之前分散到聚合物中,或2)在产品配制期间或之后,与聚合物分别添加。尽管已知许多其它可控制香料释放的触发,香料从聚合物中的扩散是普通的触发,这将允许或增加香料从聚合物基质体系中释放的速率,所述的体系被沉积到或施用到期望的表面(部位)。吸收和/或吸附到聚合物颗粒、膜、溶液等之上或颗粒、膜、溶液等之内是该技术的方面。有机材料(如,乳液)组成的纳-或微-颗粒是实例。适宜的颗粒包括各式各样的材料,包括但不限于聚缩醛、聚丙烯酸酯、聚丙烯酸类、聚丙烯腈、聚酰胺、聚芳醚酮、聚丁二烯、聚丁烯、聚对苯二甲酸丁二醇酯、聚氯丁二烯、聚乙烯、聚对苯二甲酸乙二醇酯、对苯二甲酸亚环已基二亚甲酯、聚碳酸酯、聚氯丁二烯、聚羟基链烷酸酯、聚酮、聚酯、聚乙烯、聚醚酰亚胺、聚醚砜、氯化聚乙烯、聚酰亚胺、聚异戊二烯、聚乳酸、聚甲基戊烯、聚苯醚、聚苯硫醚、聚邻苯二甲酰胺、聚丙烯、聚苯乙烯、聚砜、聚乙酸乙烯酯、聚氯乙烯、以及基于丙烯腈-丁二烯、乙酸纤维素、乙烯-醋酸乙烯、乙烯-乙烯醇、苯乙烯-丁二烯、乙酸乙烯酯-乙烯的聚合物或共聚物、以及它们的混合物。
“标准”体系是指为保持所述预加载的香料与所述聚合物相关联直至香料释放的时刻或多个时刻的目的“预加载的”的那些。取决于香料释放的速率,此类聚合物还会抑制纯产品气味并提供浓郁度和/或保质期有益效果。关于此类体系的一个挑战为获得介于以下之间理想的平衡:1)产品中的稳定性(在载体内保持香料直至你需要它)和2)适时的释放(在使用期间或从干燥部位)。获得此类稳定性在产品中的贮藏和产品老化期间是尤其重要的。该挑战对于含水基的、含表面活性剂的产品,如重垢型液体衣物洗涤剂是尤其明显的。当配制成含水基的产品时,有效获得的许多“标准”基质体系变成“平衡”体系。人们可选择“平衡”体系或贮存体系,所述贮存体系具有可接受的产品中的扩散稳定性和可获得的对于释放的触发(如摩擦)。“平衡”体系为其中所述香料和聚合物可被单独加入所述产品中,并且介于香料和聚合物之间的平衡相互作用导致在一个或多个消费者接触点上的有益效果(相对于不具有聚合物辅助递送技术的游离香料)。所述聚合物还可用香料预加载;然而,在产品贮藏期间,部分或所有的香料可扩散达到平衡,所述平衡包括具有与所述聚合物相关联的期望的香料原料(PRM)。然后所述聚合物携带所述香料至表面,并且释放通常经由香料扩散。此类平衡体系聚合物的使用具有降低纯产品的纯产品气味强度的可能性(通常在预加载的标准体系的情况下更是如此)。此类聚合物的沉积用来“平坦”释放特性并提供增加的保质期。如上文所述,此类保质期将通过抑制初始强度获得,并且可使配制人员能够使用更高影响或低气味检测阈值(ODT)或低科法兹指数(KI)PRM以获得FMOT有益效果而无需太强或扭曲的初始强度。重要的是,香料释放发生在施用的时间框之内,以影响期望的消费者触点或若干触点。适宜的微颗粒和微乳胶以及它们的制造方法可存在于USPA2005/0003980A1。基质体系也包括热熔融粘合剂和香料塑料。此外,疏水改性的多糖可被配制到发香产品中以增加香料沉积和/或改善香料释放。所有此类基质体系包括例如多糖和纳米乳液可与其它PDT包括其它PAD体系如香料微胶囊(PMC)形式的PAD贮存体系结合。聚合物辅助递送(PAD)基质体系可包括描述于下列参考文献中的那些:美国专利申请2004/0110648A1、2004/0092414A1、2004/0091445A1和2004/0087476A1;以及美国专利6,531,444、6,024,943、6,042,792、6,051,540、4,540,721和4,973,422。
硅氧烷也是可用作PDT的聚合物的实例,并可以类似于聚合物辅助递送“基质体系”的方式提供发香有益效果。此类PDT被称之为硅氧烷辅助递送(SAD)。人们可用香料预负载硅氧烷,或使用它们作为如PAD所述的平衡体系。适宜的硅氧烷以及制备它们的方法存在于WO2005/102261、USPA20050124530A1、USPA20050143282A1和WO2003/015736中。官能化的硅氧烷还可被使用,如USPA2006/003913A1中所描述的。硅氧烷的实例包括聚二甲基硅氧烷和聚烷基二甲基硅氧烷。其它实例包括带有胺官能团的那些,其可被用来提供与胺辅助递送(AAD)和/或聚合物辅助递送(PAD)和/或胺反应产物(ARP)相关联的有益效果。其它此类实例可存在于USP4,911,852、USPA2004/0058845A1、USPA2004/0092425A1和USPA2005/0003980A1中。
b.)贮存体系:贮存体系还被称为核/壳型技术,或其中芳香剂可被用作保护性外壳的香料释放控制膜包裹的技术。在微胶囊内部的材料被称之为芯、内相或填充物,而壁有时被称为外壳、包衣或膜。微粒或压敏胶囊或微胶囊是这些技术的实例。现在发明的微胶囊由多种工序形成,所述工序包括但不限于包衣、挤出、喷雾干燥、界面、原位和模板聚合。可能的外壳材料在它们对水的稳定性上变化巨大。在最稳定之中的是聚羟甲脲(PMU)基的材料,其可在水溶液(或产品)中保持某些PRM甚至更长的一段时间。此类体系包括但不限于脲甲醛和/或三聚氰胺甲醛。稳定的外壳材料包括基于聚丙烯酸脂的材料,其以在存在包含水溶性或水分散性丙烯酸烷基酸共聚物、碱或碱盐的阴离子乳化剂的情况下,油溶性或分散性胺与多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物、油溶酸和引发剂的反应产物的形式获得。可制备胶质基的微胶囊以便它们在水中快速或缓慢溶解,取决于例如交联度。可获得许多其它胶囊壁材料并观察到在香料扩散稳定性程度上的变化。不受理论的束缚,例如,一旦沉积到表面时从胶囊中香料释放的速率通常为产品中香料扩散稳定性的相反顺序。同样,例如,脲甲醛和三聚氰胺甲醛微胶囊通常需要不同于或除扩散释放以外的释放机理,如机械力(如摩擦、压力、剪切应力),其用来打破所述胶囊并增加香料(芳香剂)释放的速率。其它触发包括熔融、溶解、水解或其它化学反应、电磁辐射等。预加载微胶囊的使用需要在产品中稳定性和在应用中和/或在表面上(在部位上)释放的适当比率,以及PRM适当的选择。基于脲甲醛和/或三聚氰胺甲醛的微胶囊是相对稳定的,尤其在近中性含水基的溶液中。这些材料可需要摩擦触发,这不会适用于所有产品的应用。其它微胶囊材料(如胶质)在含水基的产品中会不稳定,并且当在产品中老化时,甚至会提供减少的有益效果(相对于游离香料对照物)。刮擦生香技术为PAD的另一个实例。香料微胶囊(PMC)可包括下列参考文献中所描述的那些:美国专利申请:2003/0125222A1;2003/215417A1;2003/216488A1;2003/158344A1;2003/165692A1;2004/071742A1;2004/071746A1;2004/072719A1;2004/072720A1;2006/0039934A1;2003/203829A1;2003/195133A1;2004/087477A1;2004/0106536A1;和美国专利6,645,479B1;6,200,949B1;4,882,220;4,917,920;4,514,461;6,106,875和4,234,627、3,594,328以及USRE32713、PCT专利申请:WO2009/134234A1、WO2006/127454A2、WO2010/079466A2、WO2010/079467A2、WO2010/079468A2、WO2010/084480A2。
II.分子辅助递送(MAD):非聚合材料或分子也可用来改善香料的递送。不受理论的束缚,香料可与有机材料非共价地相互作用,导致改变的沉积和/或释放。此类有机材料的非限制性实例包括但不限于:疏水材料,如有机油、蜡、矿物油、凡士林、脂肪酸或酯、糖、表面活性剂、脂质体、和甚至其它香料原料(香料油),以及天然油,包括身体和/或其它污垢。香料固定剂为另一个实例。在一个方面,非聚合材料或分子具有大于约2的CLogP。分子辅助递送(MAD)也可包括描述于USP7,119,060和USP5,506,201中的那些。
III.纤维辅助递送(FAD):部位自身的选择或使用可用来改善香料的递送。实际上,所述部位自身可为香料递送技术。例如,不同的织物类型如棉或聚酯在关于吸引和/或保持和/或释放香料能力上将具有不同的特性。沉积到纤维上或纤维内香料的量可通过选择纤维并且也通过纤维的历史或处理以及通过任何纤维涂层或处理剂来改变。纤维可为织造的和非织造的,以及天然的或合成的。天然纤维包括由植物、动物和地质作用制备的那些,包括但不限于纤维素材料,如棉、亚麻布、大麻、黄麻、亚麻、苎麻和菠萝麻,以及用来制造纸材和布料的纤维。纤维辅助递送可包括木质纤维的使用,如热力学木浆和漂白的或未漂白的牛皮纸浆或亚硫酸盐纸浆。动物纤维由大量特定蛋白,如丝绸、腱、肠线和毛发(包括羊毛)组成。基于合成化学的聚合物纤维包括但不限于聚酰胺尼龙、PET或PBT聚酯、苯酚甲醛(PF)、聚乙烯醇纤维(PVOH)、聚氯乙烯纤维(PVC)、聚烯烃(PP和PE)以及丙烯酸类聚合物。所有此类纤维可用香料预加载,然后加入产品中,所述产品可包含或可不包含游离香料和/或一种或多种香料递送技术。在一个方面,所述纤维可在用香料加载之前加到产品中,然后通过添加香料用香料加载,所述香料可扩散至纤维、至产品中。不受理论的束缚,所述香料可被吸收至纤维上或纤维内,例如,在产品贮藏期间,然后在一个或多个精确的或消费者触点时刻释放。
IV.胺辅助递送(AAD):胺辅助递送技术方法采用包含胺基的材料以在产品使用期间提高香料沉积或调节香料释放。在该方法中不需要在添加至产品之前预络合或预反应所述香料原料和胺。在一个方面,适用于本文的包含胺的AAD材料可为非芳族的,例如聚烷基亚胺,如聚乙烯亚胺(PEI)或聚乙烯胺(PVAm),或芳族的,例如邻氨基苯甲酸盐。此类材料还可为聚合的或非聚合的。在一个方面,此类材料包含至少一种伯胺。不受理论的约束,对于聚合的胺,通过聚合物辅助递送,该技术将允许相对胺官能团同样的低ODT香料香味(如醛、酮、烯酮)增加的保质期和受控释放,以及其它PRM的递送。没有该技术,挥发性的顶香会损失太快,留下中香和底香对顶香更高的比率。聚合的胺的使用允许更高含量的顶香和其它PRM被用来获得新近的保质期而不会导致纯产品气味比期望的更浓郁,或允许顶香和其它PRM更有效地使用。在一个方面,AAD体系在大于约中性的pH下递送PRM是有效的。不受理论的束缚,其中更多的AAD体系的胺被去质子化的条件会导致对于PRM,如醛和酮,包括不饱和的酮和烯酮,如二氢大马酮去质子化的胺增加的亲和性。在另一方面,聚合的胺在小于约中性的pH下递送PRM是有效的。不受理论的束缚,其中更多的AAD体系的胺被质子化的条件会导致对于PRM如醛和酮质子化的胺的亲和性降低,和对于广泛范围的PRM聚合物骨架的亲和性强烈。在该方面,聚合物辅助递送可递送更多的发香有益效果;此类体系为AAD的子类,并且可被称作胺聚合物辅助递送或APAD。在一些情况下,当所述APAD被用于具有小于7的pH的组合物中时,此类APAD体系还可被认为是聚合物辅助递送(PAD)。在又一方面,AAD和PAD体系会与其它材料,如阴离子表面活性剂或聚合物相互作用以形成凝聚层和/或凝聚层似的体系。在另一方面,包含不同于氮,例如硫、磷或硒杂原子的材料可被用作替代胺化合物。在又一方面,前述替代化合物可与胺化合物联合使用。在又一方面,单个分子可包含胺部分和一个或多个替代的杂原子部分,例如,硫醇、膦和硒醇。适宜的AAD体系以及其制造方法可存在于US专利申请2005/0003980A1、2003/0199422A1、2003/0036489A1、2004/0220074A1和USP6,103,678中。
V.环糊精递送体系(CD):该技术方法使用环状的低聚糖或环糊精来改善香料的递送。通常形成香料和环糊精(CD)络合物。此类络合物可以被预形成、原位形成或在所述部位上或内形成。不受理论的束缚,水的损失会起到将平衡向CD-香料络合物方向转移,尤其是如果其它辅助成分(如表面活性剂)没有以高浓度存在而与香料竞争环糊精腔体。如果暴露于水或增加含水量发生在稍后的时间点,可获得浓郁度有益效果。此外,环糊精允许香料配制人员增加在选择PRM上的灵活性。环糊精可用香料预加载或与香料单独加入以获得期望的香料稳定性、沉积或释放有益效果。适宜的CD以及其制造方法可存在于USPA2005/0003980A1和2006/0263313A1中和US专利5,552,378、3,812,011、4,317,881、4,418,144和4,378,923中。
VI.淀粉胶囊包封调和物(SEA):使用淀粉胶囊包封调和物(SEA)技术能够通过例如加入成分如淀粉将液体香料转换加工成固体,调节所述香料的特性。所述有益效果包括在产品贮藏期间,尤其是在非水性的条件下增加香料驻留。一旦暴露于水,香料浓郁度可被触发。也可获得在精确的其它时刻的有益效果,因为所述淀粉允许产品配制人员选择PRM或PRM浓度,所述浓度通常在没有SEA存在下不能被使用。另一个技术实例包括使用其它有机和无机材料,如二氧化硅以将香料从液体转变成固体。适宜的SEA以及其制造方法可存在于USPA2005/0003980A1和USP6,458,754B1中。
VII.无机的载体递送体系(ZIC):该技术涉及使用多孔的沸石或其它无机材料来递送香料。载有香料的沸石可与辅助成分或不与辅助成分一起使用,例如用来施用载有香料的沸石(PLZ),以在产品贮藏期间或在使用期间或从所述干燥部位改变其香料释放特性。适宜的沸石和无机载体及其制造方法可见于USPA2005/0003980A1和US专利5,858,959、6,245,732B1、6,048,830和4,539,135中。二氧化硅为ZIC的另一种形式。适宜的无机载体的另一个实例包括无机的小管,其中所述香料或其它活性物质被包含在纳米或微米小管的管腔内。在一个方面,所述载有香料的无机小管(或载有香料的Tubule或PLT)为矿物质纳米或微米小管,如多水高岭土或多水高岭土与其它无机材料,包括其它粘土的混合物。所述PLT技术还可在所述小管的内部和/或外部包括附加的成分,用于改善产品中的扩散稳定性,沉积在期望的部位之目的,或用于控制加载的香料的释放。单体材料和/或聚合材料(包括淀粉胶囊包封)可被用来包覆、填塞、加盖或换句话讲胶囊包封所述PLT。适宜的PLT体系及其制造方法可存在于USP5,651,976中。
VIII.前香料(PP):该技术是指香料技术,所述技术起因于香料材料与其它基质或化学物质反应以形成具有介于一种或多种PRM和一种或多种载体之间的共价键的材料。所述PRM被转化成称作前PRM(即,前香料)的新材料,然后其可在暴露于触发如水或光照时释放所述初始PRM。前香料可提供增强的香料递送特性,如增加香料沉积、保质期、稳定性、保持力等。前香料包括单体(非聚合的)或聚合的那些,并且可为预成形的或可在平衡条件下原位形成,如在产品中的贮藏期间或在润湿或干燥部位上可能存在的那些。前香料非限制性实例包括Michael加合物(如β-氨基酮)、芳族或非芳族亚胺(席夫碱)、唑烷、β-酮基酯和原酸酯。另一个方面包括化合物,所述化合物包含一种或多种能够释放PRM的β-氧代或β-硫代羰基部分,例如,α-β-不饱和的酮、醛或羧酸酯。用于香料释放典型的触发为暴露于水;尽管其它触发可包括酶、热、光照、pH变化、自氧化、平衡移动、浓度或离子强度以及其它的改变。对于含水基的产品,光照触发的前香料是尤其适合的。此类光-前香料(PPP)包括但不限于在触发时释放香豆素衍生物以及香料和/或前香料的那些。释放出的前香料可通过任何上述触发释放一种或多种PRM。在一个方面,当暴露于光照和/或水分触发时,所述光-前香料释放氮基的前香料。在另一方面,由所述光-前香料释放的所述氮基的前香料释放一种或多种PRM,所述PRM选自例如,醛、酮(包括烯酮)和醇。还在另一个方面,所述PPP释放二羟基香豆素衍生物。所述光照触发的前香料还可为释放香豆素衍生物和香料醇的酯在一个方面,所述前香料为安息香双甲醚衍生物,如USPA2006/0020459A1中所述。在另一方面,所述前香料为3′,5′-安息香双甲醚(DMB)衍生物,其在暴露于电磁辐射时释放醇。在又一方面,所述前香料释放一种或多种低ODT的PRM,包括叔醇,如里哪醇、四氢里哪醇或二氢月桂烯醇。适宜的前香料及其制造方法可见于US专利7,018,978B2、6,987,084B2、6,956,013B2、6,861,402B1、6,544,945B1、6,093,691、6,277,796B1、6,165,953、6,316,397B1、6,437,150B1、6,479,682B1、6,096,918、6,218,355B1、6,133,228、6,147,037、7,109,153B2、7,071,151B2、6,987,084B2、6,610,646B2和5,958,870中,以及可见于USPA2005/0003980A1和USPA2006/0223726A1中。
a.)胺反应产物(ARP):就本专利申请的目的而言,ARP是PP的子集或种类。还可以使用“反应性”聚胺,胺官能度在其中是与一种或多种PRM预反应的,以形成胺反应产物(ARP)。通常所述反应性的胺为伯胺和/或仲胺,并可为聚合物或单体的(非聚合物)的一部分。此类ARP还可与附加的PRM混合在一起以提供聚合物辅助递送和/或胺辅助递送有益效果。聚合胺的非限制性实例包括基于聚烷基亚胺的聚合物,如聚乙烯亚胺(PEI)或聚乙烯胺(PVAm)。单体(非聚合的)胺的非限制性实例包括羟基胺,如2-氨基乙醇及其烷基取代的衍生物和芳族胺,如邻氨基苯甲酸盐。所述ARP可与香料预混合或在免洗型或洗去型应用中单独添加。在另一方面,包含不同于氮,例如氧、硫、磷或硒杂原子的材料可被用作替代胺化合物。在又一方面,前述替代化合物可与胺化合物联合使用。在又一方面,单个分子可包含胺部分和一个或多个替代的杂原子部分,例如,硫醇、膦和硒醇。所述有益效果可包括香料改善的递送以及受控的香料释放。适宜的ARPs以及其制造方法可见于USPA2005/0003980A1和USP6,413,920B1中。
漂白剂
本发明的长丝可包含一种或多种漂白剂。合适的漂白剂的非限制性实例包括过氧酸、过硼酸盐、过碳酸盐、氯漂白剂、彩漂粉、次氯酸盐漂白剂、漂白剂前体、漂白活化剂、漂白催化剂、过氧化氢、漂白增强剂、光漂白剂、漂白酶、自由基引发剂、过氧漂白剂、以及它们的混合物。
本发明的长丝可包括一种或多种漂白剂,其含量按干燥长丝和/或干燥洗涤剂产品重量计可为约1%至约30%、和/或约5%至约20%。如果存在,漂白活化剂在本发明的长丝中的含量按干燥长丝和/或干燥洗涤剂产品重量计可为约0.1%至约60%、和/或约0.5%至约40%。
漂白剂的非限制性实例包括彩漂粉、过硼酸盐漂白剂、过羧酸漂白剂及其盐、过氧漂白剂、过硫酸盐漂白剂、过碳酸盐漂白剂、以及它们的混合物。此外,漂白剂的非限制性实例在美国专利4,483,781、美国专利公开申请740,446、欧洲专利申请0133354、美国专利4,412,934、以及美国专利4,634,551中公开。
漂白活化剂(例如酰基内酰胺)的非限制性实例在美国专利4,915,854;4,412,934;4,634,551;和4,966,723中公开。
在一个实例中,漂白剂包含过渡金属漂白催化剂,其可被包封。过渡金属漂白催化剂通常包含过渡金属离子,例如来自过渡金属的过渡金属离子选自:Mn(II)、Mn(III)、Mn(IV)、Mn(V)、Fe(II)、Fe(III)、Fe(IV)、Co(I)、Co(II)、Co(III)、Ni(I)、Ni(II)、Ni(III)、Cu(I)、Cu(II)、Cu(III)、Cr(II)、Cr(III)、Cr(IV)、Cr(V)、Cr(VI)、V(III)、V(IV)、V(V)、Mo(IV)、Mo(V)、Mo(VI)、W(IV)、W(V)、W(VI)、Pd(II)、Ru(II)、Ru(III)和Ru(IV)。在一个实例中,过渡金属选自:Mn(II)、Mn(III)、Mn(IV)、Fe(II)、Fe(III)、Cr(II)、Cr(III)、Cr(IV)、Cr(V)和Cr(VI)。所述过渡金属漂白催化剂通常包含配体,例如大多环配体如交联的大多环配体。所述过渡金属离子可与配体配合。此外,所述配体可包含至少四个配位原子,其中至少两个为桥头配位原子。适宜的过渡金属漂白催化剂的非限制性实例描述于U.S.5,580,485、U.S.4,430,243;U.S.4,728,455;U.S.5,246,621;U.S.5,244,594;U.S.5,284,944;U.S.5,194,416;U.S.5,246,612;U.S.5,256,779;U.S.5,280,117;U.S.5,274,147;U.S.5,153,161;U.S.5,227,084;U.S.5,114,606;U.S.5,114,611、EP549,271A1;EP544,490A1;EP549,272A1;和EP544,440A2中。在一个实例中,合适的过渡金属漂白催化剂包括锰基催化剂,例如在美国专利5,576,282中公开的催化剂。在另一个实例中,合适的钴漂白催化剂在U.S.5,597,936和U.S.5,595,967中进行了描述。上述钴催化剂易于通过已知的方法制备,例如美国专利5,597,936和5,595,967中所提出的方法。在另一个实例中,合适的过渡金属漂白催化剂包括配体如双哌啶的过渡金属络合物,如WO05/042532A1所述。
除氧化漂白剂之外的漂白剂也是本领域已知的,并且可在本文中利用(例如光活化漂白剂如磺化锌和/或铝酞菁(美国专利4,033,718,其以引用方式并入本文))、和/或预成形的有机过酸如过氧羧酸或其盐、和/或过氧磺酸或其盐。在一个实例中,合适的有机过酸包括邻苯二甲酰氨基过氧乙酸或其盐。当存在时,所述光活化漂白剂如磺化酞菁锌可存在于本发明的长丝中,其含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.025%至约1.25%。
增白剂
本领域已知的任何光学增白剂或其他增白或美白剂可混入本发明的长丝,其含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.01%至约1.2%。可用于本发明的商用光学增白剂可分成几亚类,它们包括但不一定限于二苯乙烯、吡唑啉、香豆素、羧酸、次甲基花青、5,5-二氧化硫芴、唑、5元和6元环杂环衍生物、以及其它杂项剂。此类增白剂的实例在“TheProductionandApplicationofFluorescentBrighteningAgents”,M.Zahradnik,PublishedbyJohnWiley&Sons,NewYork(1982)中进行了描述。用于本组合物的光学增白剂的具体非限制性实例是在美国专利4,790,856和美国专利3,646,015中鉴定的那些。
织物着色剂
本发明的长丝可包括织物着色剂。合适的织物着色剂的非限制性实例包括小分子染料和聚合染料。适宜的小分子染料包括选自下列的小分子染料:属于直接蓝、直接红、直接紫、酸性蓝、酸性红、酸性紫、碱性蓝、碱性紫和碱性红颜色索引(C.I.)类别的染料、或它们的混合物。在另一实例中,适宜的聚合物染料选自:以商标(Milliken,Spartanburg,SouthCarolina,USA)销售的织物-实体着色剂、由至少一种活性染料形成的染料-聚合物共轭物、以及选自由包含以下部分的聚合物组成的组的聚合物:羟基部分、伯胺部分、仲胺部分、硫醇部分、以及它们的混合物。在另一方面,适宜的聚合物染料选自:(Milliken,Spartanburg,SouthCarolina,USA)紫CT、与活性蓝、活性紫或活性红染料共轭的羟甲基纤维素(CMC)如与C.I.活性蓝19共轭的CMC,由Megazyme,Wicklow,Ireland以产品名AZO-CM-CELLULOSE,产品代码S-ACMC销售、烷氧基化的三苯基-甲烷聚合着色剂、烷氧基化的噻吩聚合着色剂、以及它们的混合物。
有用的调色染料的非限制性实例包括存在于US7,205,269;US7,208,459;和US7,674,757B2中的那些。例如织物调色染料可选自:三芳基甲烷碱性蓝和碱性紫染料、次甲基碱性蓝和碱性紫染料、蒽醌碱性蓝和碱性紫染料、偶氮染料碱性蓝16、碱性蓝65、碱性蓝66、碱性蓝67、碱性蓝71、碱性蓝159、碱性紫19、碱性紫35、碱性紫38、碱性紫48、嗪染料、碱性蓝3、碱性蓝75、碱性蓝95、碱性蓝122、碱性蓝124、碱性蓝141、尼罗蓝A和占吨染料碱性紫10、烷氧基化三苯甲烷聚合着色剂;烷氧基化噻吩聚合着色剂;噻唑染料;以及它们的混合物。
在一个实例中,织物调色染料包括增白剂,其存在于WO08/87497A1中。这些增白剂可特征在于以下结构(I):
其中R1和R2可独立地选自:
a)[(CH2CR′HO)x(CH2CR″HO)yH]
其中R’选自:H、CH3、CH2O(CH2CH2O)zH、以及它们的混合物;
其中R”选自:H、CH2O(CH2CH2O)zH、以及它们的混合物;其中x+y≤5;其中y≥1;并且其中z=0至5
b)R1=烷基、芳基或芳烷基,并且R2=[(CH2CR′HO)x(CH2CR″HO)yH]
其中R’选自:H、CH3、CH2O(CH2CH2O)zH、以及它们的混合物;
其中R”选自:H、CH2O(CH2CH2O)zH、以及它们的混合物;其中x+y≤10;其中y≥1;并且其中z=0至5
c)R1=[CH2CH2(OR3)CH2OR4],并且R2=[CH2CH2(OR3)CH2OR4]其中R3选自:H、(CH2CH2O)zH、以及它们的混合物;并且其中z=0至10;
其中R4选自:(C1-C16)烷基、芳基、以及它们的混合物;并且
d)其中R1和R2可独立地选自氧化苯乙烯、缩水甘油基甲基醚、异丁基缩水甘油基醚、异丙基缩水甘油基醚、叔丁基缩水甘油基醚、2-乙基己基缩水甘油基醚和缩水甘油基十六烷基醚的氨基加成产物,接着加成1个至10个烯化氧单元。
在另一个实例中,合适的增白剂可特征在于以下结构(II):
其中R’选自:H、CH3、CH2O(CH2CH2O)zH、以及它们的混合物;其中R”选自:H、CH2O(CH2CH2O)zH、以及它们的混合物;其中x+y≤5;其中y≥1;并且其中z=0至5
在另一个实例中,合适的增白剂可特征在于以下结构(III):
这种增白剂通常称为“紫DD”。紫DD通常是具有总计5个EO基的混合物。这种结构通过以下选择结构I的下列侧基获得,所述侧基如下表I中上文“部分a”所示:
表I
R1 | R2 | |||||||
R’ | R” | X | y | R’ | R” | X | y | |
a | H | H | 3 | 1 | H | H | 0 | 1 |
b | H | H | 2 | 1 | H | H | 1 | 1 |
c=b | H | H | 1 | 1 | H | H | 2 | 1 |
d=a | H | H | 0 | 1 | H | H | 3 | 1 |
使用的其他增白剂包括在US2008/34511A1(Unilever)中所述的那些。在一个实例中,所述增白剂包含“紫13”。
染料转移抑制剂
本发明的长丝可包括一种或多种染料转移抑制剂,其抑制染料在清洁过程中从一个织物转移到另一个织物上。通常,这种染料转移抑制剂包括聚乙烯吡咯烷酮聚合物、聚胺N-氧化物聚合物、N-乙烯基吡咯烷酮和N-乙烯基咪唑的共聚物、酞菁锰、过氧化物酶,以及它们的混合物。如果使用,这些试剂含量按干燥长丝和/或干燥洗涤剂产品重量计通常为约0.01%至约10%、和/或约0.01%至约5%、和/或约0.05%至约2%。
螯合剂
本发明的长丝可包含一种或多种螯合剂,例如一种或多种铁和/或锰和/或其他金属离子螯合剂。这样的螯合剂可选自氨基羧酸盐、氨基膦酸盐、多官能取代的芳族螯合剂以及它们的混合物。如果使用,这些螯合剂含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.1%至约15%、和/或约0.1%至约10%、和/或约0.1%至约5%、和/或约0.1%至约3%。
本领域的技术人员可选择螯合剂以提供重金属(例如铁)螯合作用,不会由于过度结合钙离子对酶稳定性造成负面影响。本发明使用的螯合剂的非限制性实例存在于US7445644、US7585376和US2009/0176684A1中。
可用的螯合剂包括重金属螯合剂如二亚乙基三胺五乙酸(DTPA)和/或儿茶酚,包括但不限于钛试剂。在其中使用双螯合剂体系的多个实施方案中,螯合剂可为DTPA和钛试剂。
DTPA具有以下核心分子结构:
钛试剂还被称为1,2-二羟基苯-3,5-二磺酸,其为儿茶酚家族中的一员,并且具有下文所示的核心分子结构:
使用其他的磺化儿茶酚。除了二磺酸之外,术语“钛试剂”还可包括一-或二-磺酸盐,例如二钠磺酸盐,其具有与二磺酸相同的核心分子结构。
适用于本文的其他螯合剂可选自:氨基羧酸盐、氨基膦酸盐、多官能取代的芳族螯合剂、以及它们的混合物。在一个实例中,螯合剂包括但不限于:HEDP(羟乙烷二亚甲基膦酸);MGDA(甲基甘氨酸二乙酸);GLDA(谷氨酸-N,N-二乙酸);以及它们的混合物。
不期望受理论的限制,据信这些物质的有益效果部分是由于它们通过形成可溶解的螯合物将重金属离子从洗涤溶液中除去的特殊能力;其他有益效果包括防止形成无机膜或无机垢。其他用于本文的合适螯合剂是市售的DEQUEST系列,以及来自Monsanto,DuPont和Nalco,Inc.的螯合剂。
用作螯合剂的氨基羧酸盐包括但不限于乙二胺四乙酸盐、N-(羟乙基)乙烯二胺三乙酸盐、次氮基三乙酸盐、1,2-乙二胺四丙酸盐、三亚乙基四胺六乙酸盐、二亚乙基三胺五乙酸盐、和乙醇亚氨二醋酸、碱金属、铵、和其取代铵盐、以及它们的混合物。当允许本发明的长丝包含至少低水平的总磷时,氨基膦酸盐也适用作本发明组合物中的螯合剂,并且包括乙二胺四(亚甲基膦酸)。在一个实例中,这些氨基膦酸盐不含具有超过约6个碳原子的烷基或烯基。多官能取代的芳族螯合剂也可用于本发明组合物。参见1974年5月21日公布的授予Connor等人的美国专利3,812,044。酸形式的此类化合物的非限制性实例是二羟基二磺基苯,如1,2-二羟基-3,5-二磺基苯。
在一个实例中,能够生物降解的螯合剂包括1,2-乙二胺二琥珀酸盐(“EDDS”),例如[S,S]异构体,如US4,704,233所述。可使用EDDS的三钠盐。在另一个实例中,也可使用EDDS的镁盐。
一种或多种螯合剂可存在于本发明的长丝中,其含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.2%至约0.7%、和/或约0.3%至约0.6%。
抑泡剂
可将用于减少或抑制泡沫形成的化合物掺入本发明的长丝。泡沫抑制可能在所谓的“高浓度清洁过程”中和在前加载式洗衣机中尤其重要,所述清洁过程如美国专利4,489,455和4,489,574所述。
可使用广泛的材料作为抑泡剂,并且抑泡剂是本领域的技术人员熟知的。参见例如“KirkOthmerEncyclopediaofChemicalTechnology”第三版,第7卷,第430至447页(JohnWiley&Sons,Inc.,1979)。抑泡剂的实例包括单羧脂肪酸及其可溶性盐、高分子量烃如石蜡、脂肪酸酯(例如脂肪酸甘油三酯)、一元醇的脂肪酸酯、脂族C18-C40酮(例如硬脂酮)、N-烷基化氨基三嗪、优选地具有低于约100℃的熔点的含蜡烃、硅氧烷抑泡剂和二级醇。抑泡剂在美国专利2,954,347;4,265,779;4,265,779;3,455,839;3,933,672;4,652,392;4,978,471;4,983,316;5,288,431;4,639,489;4,749,740;和4,798,679;4,075,118;欧洲专利申请89307851.9;EP150,872;以及DOS2,124,526中进行了描述。
对于本发明的设计用于自动洗衣机的任何长丝和/或包含此类长丝的非织造织物,不应形成溢流出洗衣机的泡沫。当使用时,存在的抑泡剂的量优选为“抑泡量”。“抑泡量”是指所述组合物的配制人员能够选择这种将足以控制泡沫的泡沫控制剂的量而产生在自动洗衣机中使用的低度起泡的衣物洗涤剂。
本文长丝将一般包含按干燥长丝和/或干燥洗涤剂产品重量计0%至约10%的抑泡剂。当用作抑泡剂时,例如一元脂肪酸及其盐的量按干燥长丝和/或干燥洗涤剂产品重量计可为至多约5%、和/或约0.5%至约3%。当利用时,通常用于长丝的硅氧烷抑泡剂的含量按干燥长丝和/或干燥洗涤剂产品重量计为至多约2.0%,但是可使用更高的量。当利用时,通常用于长丝的一元硬脂磷酸盐抑泡剂的含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.1%至约2%。当利用时,通常用于长丝的烃抑泡剂的含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.01%至约5.0%,但是可使用更高的含量。当利用时,通常用于长丝的醇抑泡剂的含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.2%至约3%。
增泡剂
如果期望高度起泡,可将增泡剂如C10-C16链烷醇酰胺混入长丝,其含量通常为按干燥长丝和/或干燥洗涤剂产品重量计0%至约10%、和/或约1%至约10%。C10-C14单乙醇和二乙醇酰胺举例说明了典型的一类这种增泡剂。与高起泡辅助表面活性剂,如以上提到的氧化胺、甜菜碱和磺基甜菜碱一起使用这种增泡剂也是有利的。如果需要,可将水溶性镁和/或钙盐如MgCl2、MgSO4、CaCl2、CaSO4等加入长丝以提供附加的泡沫,其含量为按干燥长丝和/或干燥洗涤剂产品重量计约0.1%至约2%。
软化剂
一种或多种软化剂可存在于长丝中。软化剂的非限制性实例包括季铵化合物如季铵酯化合物、硅氧烷如聚硅氧烷、粘土如绿土、以及它们的混合物。
在一个实例中,软化剂包括织物软化剂。织物软化剂的非限制性实例包括无形绿土,例如在U.S.4,062,647中描述的那些,以及本领域已知的其他织物软化剂。当存在时,织物软化剂在长丝中的含量按干燥长丝和/或干燥洗涤剂产品重量计可为约0.5%至约10%、和/或约0.5%至约5%。织物软化粘土可与胺和/或阳离子软化剂联合使用,如在U.S.4,375,416和U.S.4,291,071中公开的那些阳离子软化剂。阳离子软化剂也可在无织物软化粘土的情况下使用。
调理剂
本发明的长丝可包括一种或多种调理剂如高熔点脂肪族化合物。高熔点脂肪族化合物可具有约25℃或更高的熔点,并且可选自:脂肪醇、脂肪酸、脂肪醇衍生物、脂肪酸衍生物、以及它们的混合物。表现出低熔点(小于25℃)的此类脂肪化合物不旨在被包括用作调理剂。高熔点脂肪族化合物的非限制性实例可见于1993年“InternationalCosmeticIngredientDictionary”,第五版;和1992年“CTFACosmeticIngredientHandbook”,第二版中。
本发明的长丝可包括一种或多种高熔点脂肪族化合物,其含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.1%至约40%、和/或约1%至约30%、和/或约1.5%至约16%、和/或约1.5%至约8%。所述调理剂可提供调理有益效果,例如在施用期间产生的湿毛发和/或织物的光滑感、干燥毛发和/或织物的柔软性和/或湿润感。
本发明的长丝可包含阳离子聚合物作为调理剂。当存在时,长丝中的阳离子聚合物的浓度通常按干燥长丝和/或干燥洗涤剂产品重量计介于约0.05%至约3%、和/或约0.075%至约2.0%、和/或约0.1%至约1.0%的范围内。合适的阳离子聚合物的非限制性实例可具有在约3至约9、和/或约4至约8的pH下至少0.5meq/gm、和/或至少0.9meq/gm、和/或至少1.2meq/gm、和/或至少1.5meq/gm的阳离子电荷密度。在一个实例中,适用作调理剂的阳离子聚合物可具有在约3至约9、和/或约4至约8的pH下小于7meq/gm、和/或小于5meq/gm的阳离子电荷密度。本文中聚合物的“阳离子电荷密度”是指聚合物上的正电荷数与所述聚合物分子量的比率。这种合适阳离子聚合物的重均分子量通常介于约10,000和1千万之间,在一个实施方案中,介于50,000和约5百万之间,并且在另一个实施方案中,介于100,000和约3百万之间。
用于本发明长丝的合适的阳离子聚合物可包含阳离子含氮部分如季铵和/或阳离子质子化氨基部分。任何阴离子抗衡离子都可以与阳离子聚合物联合使用,只要该阳离子聚合物在水中保持可溶,并且只要该抗衡离子与长丝的其他组分在物理上和化学上是相容的,或换句话讲不会不适当地损害长丝的性能、稳定性或美观性。这样的抗衡离子的非限制性实例包括卤素离子(例如氯离子、氟离子、溴离子、碘离子)、硫酸根和甲酯硫酸根。
上述阳离子聚合物的非限制性实施例描述于Estrin、Crosley和Haynes编辑的CTFACosmeticIngredientDictionary,第3版,(TheCosmetic,Toiletry,andFragranceAssociation,Inc.,Washington,D.C.(1982))。
用于本发明长丝的其他合适阳离子聚合物包括阳离子多糖聚合物、阳离子瓜尔胶衍生物、包含季氮的纤维素醚、阳离子合成聚合物、醚化纤维素的阳离子共聚物、瓜尔胶和淀粉。当使用时,本文的阳离子聚合物可溶解在水中。此外,用于本发明长丝的合适阳离子聚合物在U.S.3,962,418、U.S.3,958,581和U.S.2007/0207109A1中进行了描述,它们均以引用方式并入本文。
本发明的长丝可包括非离子聚合物作为调理剂。分子量大于约1000的聚亚烷基二醇可用于本发明。可用的是具有以下通式的那些:
其中R95选自:H、甲基、以及它们的混合物。
长丝可包括硅氧烷作为调理剂。用作调理剂的硅氧烷通常包括水不溶性、水分散性、非挥发性、可形成乳化液体颗粒的液体。用于组合物的适宜的调理剂是通常特征为硅氧烷(例如硅氧烷油、阳离子硅氧烷、硅橡胶纯胶料、高折射硅氧烷和硅氧烷树脂)、有机调理油(例如烃油、聚烯烃和脂肪族酯)或它们的组合物的那些调理剂,或在本文含水表面活性剂基质中形成液体分散颗粒的那些调理剂。上述调理剂应该在物理和化学上与组合物的基本组分相容,并且不会不适当地破坏产品的稳定性、美观性或性能。
调理剂在长丝中的浓度可足以提供所需的护发有益效果。此类浓度可随调理剂、所期望的调理性能、调理剂颗粒的平均尺寸、其它组分的类型和浓度以及其它类似因素而不同。
硅氧烷调理剂的浓度按干燥长丝和/或干燥洗涤剂产品重量计通常介于约0.01%至约10%的范围内。适宜硅氧烷调理剂和硅氧烷的任选悬浮剂的非限制性实例描述于美国重新公布的专利34,584、美国专利5,104,646;5,106,609;4,152,416;2,826,551;3,964,500;4,364,837;6,607,717;6,482,969;5,807,956;5,981,681;6,207,782;7,465,439;7,041,767;7,217,777;美国专利申请2007/0286837A1;2005/0048549A1;2007/0041929A1;英国专利849,433;德国专利DE10036533,它们均以引用方式并入本文;ChemistryandTechnologyofSilicones,NewYork:AcademicPress(1968);GeneralElectricSiliconeRubberProductDataSheetsSE30、SE33、SE54和SE76;SiliconCompounds,PetrarchSystems,Inc.(1984);以及EncyclopediaofPolymerScienceandEngineering,第15卷,第2版,第204-308页,JohnWiley&Sons,Inc.(1989)。
在一个实例中,本发明的长丝也可包含按干燥长丝和/或干燥洗涤剂产品重量计约0.05%至约3%的至少一种有机调理油作为调理剂,其单独使用或者与其他调理剂如硅氧烷(本文所述)联合使用。适用的调理油包括烃油、聚烯烃和脂肪酯。也适用于本文的组合物的是由宝洁公司在美国专利5,674,478和5,750,122中所述的调理剂。在美国专利4,529,586、4,507,280、4,663,158、4,197,865、4,217,914、4,381,919和4,422,853中描述的那些调理剂也适用于本文,所述专利均以引用方式并入本文。
湿润剂
本发明的长丝可包含一种或多种湿润剂。本发明的湿润剂选自多元醇、水溶性烷氧基化非离子聚合物以及它们的混合物。当使用时,湿润剂在长丝中的含量按干燥长丝和/或干燥洗涤剂产品重量计可为约0.1%至约20%、和/或约0.5%至约5%。
悬浮剂
本发明的长丝还可包括悬浮剂,其浓度可在组合物中有效地悬浮分散形式的水不溶性物质或用于调节组合物的粘度。悬浮剂的此类浓度按干燥长丝和/或干燥洗涤剂产品重量计介于约0.1%至约10%、和/或约0.3%至约5.0%的范围内。
合适悬浮剂的非限制性实例包括阴离子聚合物和非离子聚合物(例如聚乙烯树脂聚合物、酰基衍生物、长链氧化胺、以及它们的混合物、脂肪酸的链烷醇胺、长链链烷醇胺的长链酯、甘油酯、具有至少约16个碳原子的脂肪烷基部分的伯胺、具有两个至少约12碳原子的脂肪烷基部分仲胺)。悬浮剂的实例描述于美国专利4,741,855中。
酶
一种或多种酶可存在于本发明的长丝中。合适酶的非限制性实例包括蛋白酶、淀粉酶、脂肪酶、纤维素酶、糖酶,其包括甘露聚糖酶和内切葡聚糖酶、果胶酶、半纤维素酶、过氧化物酶、木聚糖酶、磷脂酶、酯酶、角质酶、角质素酶、还原酶、氧化酶、酚氧化酶、脂氧合酶、木素酶、支链淀粉酶、鞣酸酶、戊聚糖酶、麦拉宁酶、葡聚糖酶、阿拉伯糖苷酶、透明质酸酶、软骨素酶、漆酶、以及它们的混合物。
酶可包括在本发明的长丝中用于多种用途,包括但不限于从基底上去除蛋白质基污渍、碳水化合物基污渍或甘油三酯基污渍,防止织物洗涤时移动染料转移,以及织物修复。在一个实例中,本发明的长丝可包括蛋白酶、淀粉酶、脂肪酶、纤维素酶、过氧化物酶、以及它们任何合适来源的混合物,如植物、动物、细菌、真菌和酵母来源。利用的酶的选择受以下因素的影响,如pH-活性和/或稳定性最适度、热稳定性、以及对存在于长丝内的其他添加剂如活性剂例如助洗剂的稳定性。在一个实例中,所述酶选自:细菌酶(例如细菌淀粉酶和/或细菌蛋白酶)、真菌酶(例如真菌纤维素酶)、以及它们的混合物。
当存在于本发明的长丝中时,所述酶的含量可足以提供“清洁有效量”。术语“清洁有效量”是指能够在基底例如织物、盘碟等上产生清洁、污渍移除、污垢移除、增白、除臭或增进新鲜效果的任何量。实际上,对于目前的商品制剂而言,典型量为按重量计每克本发明的长丝和/或纤维至多约5mg,更典型0.01mg至3mg的活性酶。换句话讲,本发明的长丝将通常包含按干燥长丝和/或干燥洗涤剂产品重量计约0.001%至约5%、和/或约0.01%至约3%、和/或约0.01%至约1%的酶。
在产生所述长丝和/或非织造纤维网和/或膜后,可将一种或多种酶施用于长丝和/或非织造纤维网和/或膜上。
酶材料范围和它们混入本发明的长丝形成组合物(其可为合成洗涤剂组合物)的装置也在以下文献中公开:WO9307263A;WO9307260A;WO8908694A;美国专利3,553,139;4,101,457;和美国专利4,507,219。
酶稳定体系
当酶存在于本发明的长丝和/或纤维中时,所述长丝也可包括酶稳定体系。可通过多种技术稳定酶。酶稳定技术的非限制性实例在以下文献中公开并例示:US3,600,319和3,519,570;EP199,405、EP200,586;和WO9401532A。
在一个实例中,酶稳定体系可包含钙和/或镁离子。
酶稳定体系在本发明的长丝中的含量按干燥长丝和/或干燥洗涤剂产品重量计可为约0.001%至约10%、和/或约0.005%至约8%、和/或约0.01%至约6%。酶稳定体系可为任何与存在于长丝中的酶相容的稳定体系。此类酶稳定体系可由其它制剂活性物质自动提供,或者单独地加入,如由配制人员或酶的生产者加入。此类酶稳定体系可例如包括钙离子、镁离子、硼酸、丙二醇、短链羧酸、硼酸、以及它们的混合物,并且设计用于处理不同的稳定性问题。
助洗剂
本发明的长丝可包含一种或多种助洗剂。合适助洗剂的非限制性实例包括沸石助洗剂、硅铝酸盐助洗剂、硅酸盐助洗剂、磷酸盐助洗剂、柠檬酸,柠檬酸盐、次氮基三乙酸,次氮基三醋酸酯,聚丙烯酸酯、丙烯酸酯/马来酸酯共聚物、以及它们的混合物。
在一个实例中,助洗剂选自硅铝酸盐、硅酸盐、以及它们的混合物,它们可被包括在本发明的长丝中。助洗剂可包括在本文的长丝中用于辅助控制矿物质,尤其是洗涤水中的钙和/或镁硬度,或者用于辅助从表面上除去粒状污垢。还适用于本文的是合成的结晶离子交换材料或其水化物,它们具有链结构和用以下通式I表示的酸酐形式的组合物:x(M2O)·ySiO2·zM′O,其中M是钠和/或钾,M′是钙和/或镁;y/x是0.5至2.0,并且z/x是0.005至1.0,它们在美国专利5,427,711中提出。
长丝可包括的其他合适助洗剂的非限制性实例包括磷酸盐和多磷酸盐例如它们的钠盐;除了碳酸钠或倍半碳酸钠之外的碳酸盐、碳酸氢盐、倍半碳酸盐和碳酸盐矿物;有机一-、二-、三-和四羧酸盐,例如酸、钠、钾或链烷醇铵盐形式的水溶性非表面活性剂羧酸盐,以及低聚的或水溶性的低分子量聚合物羧酸盐,包括脂族和芳族类型的羧酸盐;以及植酸。这些助洗剂可补充有硼酸盐,例如用于pH缓冲目的,或者补充有硫酸盐,例如硫酸钠和任何其它填充剂或载体,它们可能对工程化稳定表面活性剂和/或本发明包含助洗剂的长丝来讲是重要的。
其他助洗剂可选自聚羧酸酯,例如丙烯酸共聚物、丙烯酸和马来酸的共聚物、以及丙烯酸和/或马来酸与具有多种类型附加功能的其他合适烯基单体的共聚物。
助洗剂含量取决于最终用途可能差别很大。在一个实例中,本发明的长丝可包含按干燥长丝重量计至少1%、和/或约1%至约30%、和/或约1%至约20%、和/或约1%至约10%、和/或约2%至约5%的一种或多种助洗剂。
粘土污垢移除剂/抗再沉淀剂
本发明的长丝可包含水溶性乙氧基化胺,其具有粘土污垢移除和抗再沉积特性。此类水溶性乙氧基化胺可存在于本发明的长丝中,其含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.01%至约10.0%、和/或约0.01%至约7%、和/或约0.1%至约5%的一种或多种水溶性乙氧基化胺。合适的粘土污垢移除剂/抗再沉淀剂的非限制性实例在美国专利4,597,898;548,744;4,891,160;欧洲专利申请111,965;111,984;112,592;和WO95/32272中进行了描述。
聚合去垢剂
本发明的长丝可包含聚合去垢剂,下文称为“SRA”。如果利用的话,SRA的量按干燥长丝和/或干燥洗涤剂产品重量计一般为约0.01%至约10.0%、和/或约0.1%至约5%、和/或约0.2%至约3.0%。
SRA通常具有亲水性链段以使疏水性纤维如聚酯和尼龙的表面亲水化,并且具有疏水性链段以沉积在疏水性纤维上,并且保持与其粘附,直至洗涤和漂洗循环完成,从而用作亲水性链段的锚定剂。这可使用SRA处理后出现的污渍更易于在稍后的洗涤过程中被清除。
SRA可包括例如多种带电荷的例如阴离子或者甚至阳离子(参见美国专利公开4,956,447)、以及无电荷的单体单位,并且结构可为直链的、支链的、或者甚至星形的。它们可包括在控制分子量或改变物理或表面活性的性能方面特别有效的封端部分。结构和电荷分配可根据应用于不同的纤维或纺织品类型以及不同的洗涤剂或洗涤剂助剂产品而确定。SRA的非限制性实例描述于美国专利4,968,451;4,711,730;4,721,580;4,702,857;4,877,896;3,959,230;3,893,929;4,000,093;5,415,807;4,201,824;4,240,918;4,525,524;4,201,824;4,579,681;和4,787,989;欧洲专利申请0219048;279,134A;457,205A;以及DE2,335,044中。
聚合分散剂
有利于本发明的长丝利用的聚合分散剂的含量按干燥长丝和/或干燥洗涤剂产品重量计为约0.1%至约7%、和/或约0.1%至约5%、和/或约0.5%至约4%,尤其是在沸石和/或层状硅酸盐助洗剂的存在下更是如此。适用的聚合分散剂可包括聚合聚羧酸盐和聚乙二醇,然而也可使用本领域已知的其它聚合分散剂。例如,广泛的改性或未改性的聚丙烯酸酯、聚丙烯酸酯/马来酸酯、或聚丙烯酸酯/甲基丙烯酸酯是非常有用的。不受理论的限制,据信当与其它助剂(包括较低分子量的聚羧酸盐)组合使用时,聚合分散剂通过结晶生长抑制、粒状去垢性解胶和抗再沉淀来提高洗涤剂助剂的总体性能。聚合分散剂的非限制性实例存在于美国专利公开3,308,067、欧洲专利申请66915、EP193,360和EP193,360中。
烷氧基化聚胺聚合物
本发明的长丝可包括烷氧基化聚胺用于提供垢悬浮、油脂清洁、和/或颗粒清洁。此类烷氧基化聚胺包括但不限于乙氧基化聚乙烯亚胺、乙氧基化己二胺、和它们的硫酸盐。本发明的长丝也可包括聚胺的聚丙氧基化衍生物。可将多种胺和聚烯化亚胺烷氧基化到不同程度,并且任选地进一步改性以提供上述有益效果。一个有用的实例是600g/mol的乙氧基化成20EO基/NH的聚乙烯亚胺核,并且购自BASF。
烷氧基化聚羧酸酯聚合物
本发明的长丝可包括烷氧基化聚羧酸酯如由聚丙烯酸酯制备的那些以提供附加的油脂移除性能。此类材料在WO91/08281和PCT90/01815中进行了描述。化学上,这些材料包含聚丙烯酸酯,其每隔7-8个丙烯酸酯单位具有一个乙氧基侧链。侧链为式-(CH2CH2O)m(CH2)nCH3,其中m为2-3并且n为6-12。所述侧链与聚丙烯酸酯“主链”通过酯键连接以提供“梳型聚合物”结构。分子量可变化,但是通常介于约2000至约50,000的范围内。此类烷氧基化聚羧酸酯的含量可为按干燥长丝和/或干燥洗涤剂产品重量计约0.05%至约10%。
两亲接枝共聚物
本发明的长丝可包括一种或多种两亲接枝共聚物。合适的两亲接枝共聚物的实例包括(i)聚乙二醇主链;和(ii)以及至少一个侧基部分,其选自聚醋酸乙烯酯、聚乙烯醇、以及它们的混合物。可商购获得的两亲接枝共聚物的非限制性实例是SokalanHP22,购自BASF。
溶解助剂
当长丝包含超过40%的表面活性剂或表面活性剂组合物在冷水中使用时,本发明的长丝可混入溶解助剂以加速溶解,从而减少不溶解的或溶解度低的表面活性剂聚集体(有时可能形成)的形成。溶解助剂的非限制性实例包括氯化钠、硫酸钠、氯化钾、硫酸钾、氯化镁、和硫酸镁。
缓冲剂体系
可配制本发明的长丝使得在用于含水清洁操作期间,例如洗涤衣服或盘碟期间,洗涤水将具有介于约5.0和约12之间、和/或介于约7.0和10.5之间的pH。在盘碟洗涤操作的情况下,洗涤水的pH通常介于约6.8和约9.0之间。在衣服洗涤的情况下,洗涤水的pH通常介于7和11之间。将pH调节在可取使用程度的技术包括使用缓冲剂、碱、酸等,并且是本领域的技术人员所熟知的。这些包括使用碳酸钠、柠檬酸或柠檬酸钠、单乙醇胺或其他胺、硼酸或硼酸盐、以及本领域熟知的其他pH调节化合物。
本发明包括用作“低pH”洗涤剂组合物的长丝,并且其尤其适用于本发明的表面活性剂体系且可提供小于8.5、和/或小于8.0、和/或小于7.0、和/或小于7.0、和/或小于5.5、和/或至约5.0的应用pH值。
本发明包括动态洗涤中pH特征的长丝。此类长丝可使用蜡覆盖的柠檬酸颗粒与其他pH控制剂,使得(i)与水接触3分钟后,洗涤液体的pH大于10;(ii)与水接触10分钟后,所述洗涤液体的pH小于9.5;(iii)与水接触20分钟后,所述洗涤液体的pH小于9.0;并且(iv)任选地,其中所述洗涤液体的平衡pH在高于7.0至8.5的范围内。
活性剂的释放
当长丝暴露于触发条件时,长丝能够释放出一种或多种活性剂。在一个实例中,当长丝或部分长丝丧失其同一性时,换句话讲丧失其物理结构时,所述长丝或部分长丝能够释放一种或多种活性剂。例如,当长丝形成材料溶解、熔融或发生一些其他转变步骤而使得长丝结构丧失时,长丝丧失其物理结构。在一个实例中,当长丝的形态改变时,所述长丝释放一种或多种活性剂。
在另一个实例中,当长丝或部分长丝改变其同一性时,换句话讲改变其物理结构而不是丧失其物理结构时,所述长丝或部分长丝能够释放一种或多种活性剂。例如,当长丝形成材料溶胀、起皱、变长、和/或变短但是保留其长丝形成特性时,长丝改变其物理结构。
在另一个实例中,长丝的形态不改变(不丧失或改变其物理结构),所述长丝能够释放一种或多种活性剂。
在一个实例中,当长丝暴露于导致释放活性剂的触发条件时,例如如上所述引起长丝丧失或改变其同一性时,所述长丝能够释放活性剂。触发条件的非限制性实例包括暴露长丝于溶剂、极性溶剂如醇和/或水、和/或非极性溶剂,其可为连续的,取决于是否长丝形成材料包含极性溶剂可溶解的材料和/或非极性溶剂可溶解的材料;暴露长丝于加热,例如暴露于大于75°F、和/或大于100°F、和/或大于150°F、和/或大于200°F、和/或大于212°F的温度;暴露长丝于冷却,例如暴露于小于40°F、和/或小于32°F、和/或小于0°F的温度;暴露长丝于应力,例如暴露于使用长丝的消费者施加的拉伸力;和/或暴露长丝于化学反应;暴露长丝于导致相改变的条件;暴露长丝于pH改变和/或压力改变和/或温度改变;暴露长丝于一种或多种化学制剂,其导致长丝释放一种或多种它的活性剂;暴露长丝于超声焊接;暴露长丝于光照和/或某些波长;暴露长丝于不同的离子强度;和/或暴露长丝于释放自另一种长丝的活性剂。
在一个实例中,当包含长丝的非织造纤维网经历触发步骤时,本发明的长丝能够释放一种或多种活性剂,所述触发步骤选自:预处理在具有非织造纤维网的织物制品上的污渍;通过接触非织造纤维网与水形成洗涤液体;在烘干机中烘干非织造纤维网;在烘干机中加热非织造纤维网;以及它们的组合。
长丝形成组合物
本发明的长丝由长丝形成组合物制成。长丝形成组合物是基于极性溶剂的组合物。在一个实例中,长丝形成组合物是包含一种或多种长丝形成材料和一种或多种活性剂的含水组合物。
根据本文所述的剪切粘度测试方法测得本发明的长丝形成组合物可具有的剪切粘度为约1Pa.s至约25Pa.s、和/或约2Pa.s至约20Pa.s、和/或约3Pa.s至约10Pa.s,这在3,000秒-1的剪切速率和(50℃至100℃)的加工温度下进行测量。
当从长丝形成组合物制备长丝时,可在约50℃至约100℃、和/或约65℃至约95℃、和/或约70℃至约90℃的温度下加工长丝形成组合物。
在一个实例中,长丝形成组合物可包含按重量计至少20%、和/或至少30%、和/或至少40%、和/或至少45%、和/或至少50%至约90%、和/或至约85%、和/或至约80%、和/或至约75%的一种或多种长丝形成材料、一种或多种活性剂、以及它们的混合物。长丝形成组合物可包含按重量计约10%至约80%的极性溶剂,例如水。
长丝形成组合物可显示至少1、和/或至少3、和/或至少5的毛细管数,使得长丝形成组合物可以被有效地聚合物加工成羟基聚合物纤维。
毛细管数是用来表征这种小滴破裂可能性的无量纲数。较大的毛细管数表示流体离开喷丝板时更大的稳定性。毛细管数定义如下:
V是喷丝孔处的流体速度(单位是长度每时间),
η是在喷丝板条件下的流体粘度(单位是质量每长度*时间),
σ是流体的表面张力(单位是质量每时间2)。当将速度、粘度和表面张力表示成一组一致单位时,所得毛细管数将没有自己的单位;各个单位可抵消。
定义毛细管数用于喷丝孔处的条件。流体速度是流体流经喷丝孔的平均速度。平均速度定义如下:
Vol′=体积流速(单位是长度3每时间),
Area=喷丝孔处的横截面积(单位是长度2)。
当喷丝孔是圆孔时,则流体速度可定义如下
R是圆孔半径(单位是长度)。
流体粘度将取决于温度并且可取决于剪切速率。剪切致稀流体的定义包括对剪切速率的依赖。表面张力将取决于流体组成和流体温度。
在纤维纺丝工艺中,当长丝离开喷丝板时需要具有初始稳定性。毛细管数用于表征这种初始稳定性标准。在所述喷丝板的条件下,毛细管数应大于1、和/或大于4。
在一个实例中,长丝形成组合物显示至少1至约50、和/或至少3至约50、和/或至少5至约30的毛细管数。
本发明的长丝形成组合物可具有的剪切粘度为约1Pa.s至约25Pa.s、和/或约2Pa.s至约20Pa.s、和/或约3Pa.s至约10Pa.s,这在3,000s-1的剪切速率和(50℃至100℃)的加工温度下进行测量。
当从长丝形成组合物制备长丝时,可在约50℃至约100℃、和/或约65℃至约95℃、和/或约70℃至约90℃的温度下加工长丝形成组合物。
在一个实例中,纺丝组合物的非挥发性组分可占约20%、和/或30%、和/或40%、和/或45%、和/或50%至约75%、和/或80%、和/或85%、和/或90%。非挥发性组分可由长丝形成材料如主链聚合物、活性剂、以及它们的组合组成。纺丝组合物的挥发性组分将占剩余的百分比,并且介于10%至80%的范围内。
长丝形成组合物可显示至少1、和/或至少3、和/或至少5的毛细管数,使得长丝形成组合物可以被有效地聚合物加工成羟基聚合物纤维。
毛细管数是用来表征这种小滴破裂可能性的无量纲数。较大的毛细管数表示流体离开喷丝板时更大的稳定性。毛细管数定义如下:
V是喷丝孔处的流体速度(单位是长度每时间),
η是在喷丝板条件下的流体粘度(单位是质量每长度*时间),
σ是流体的表面张力(单位是质量每时间2)。当将速度、粘度和表面张力表示成一组一致单位时,所得毛细管数将没有自己的单位;各个单位可抵消。
定义毛细管数用于喷丝孔处的条件。流体速度是流体流经喷丝孔的平均速度。平均速度定义如下:
vol′=体积流速(单位是长度3每时间),
Area=喷丝孔处的横截面积(单位是长度2)。
当喷丝孔是圆孔时,则流体速度可定义如下
R是圆孔半径(单位是长度)。
流体粘度将取决于温度并且可取决于剪切速率。剪切致稀流体的定义包括对剪切速率的依赖。表面张力将取决于流体组成和流体温度。
在长丝纺丝工艺中,当长丝离开喷丝板时需要具有初始稳定性。毛细管数用于表征这种初始稳定性标准。在所述喷丝板的条件下,毛细管数应大于1、和/或大于4。
在一个实例中,长丝形成组合物显示至少1至约50、和/或至少3至约50、和/或至少5至约30的毛细管数。
在一个实例中,长丝形成组合物可包含一种或多种剥离剂和/或润滑剂。合适的剥离剂和/或润滑剂的非限制性实例包括脂肪酸、脂肪酸盐、脂肪醇、脂肪酸酯、磺化脂肪酸酯、乙酸脂肪胺和脂肪酸酰胺、硅氧烷、氨基硅氧烷、含氟聚合物、以及它们的混合物。
在一个实例中,长丝形成组合物可包含一种或多种抗粘连剂和/或防粘剂。适宜的抗粘连剂和/或防粘剂的非限制性实例包括淀粉、改性淀粉、交联聚乙烯吡咯烷酮、交联纤维素、微晶纤维素、二氧化硅、金属氧化物、碳酸钙、滑石和云母。
可将本发明的活性剂在长丝形成之前和/或期间加到长丝形成组合物中和/或可将其在长丝形成之后加到长丝中。例如,在根据本发明的长丝和/或非织造纤维网形成后,可将香料活性剂施用于长丝和/或包含长丝的非织造纤维网。在另一个实例中,在根据本发明的长丝和/或非织造纤维网形成后,可将酶活性剂施用于长丝和/或包含长丝的非织造纤维网。在另一个实例中,在根据本发明的长丝和/或非织造纤维网形成后,可将一种或多种颗粒活性剂如一种或多种可摄取的活性剂如碱式水杨酸铋(其可能不适用于通过纺丝工艺制备长丝)施用于长丝和/或包含长丝的非织造纤维网。
延伸助剂
在一个实例中,长丝包含延伸助剂。延伸助剂的非限制性实例可包括聚合物、其他延伸助剂、以及它们的组合。
在一个实例中,延伸助剂具有至少约500,000Da的重均分子量。在另一个实例中,延伸助剂的重均分子量为约500,000至约25,000,000,在另一个实例中为约800,000至约22,000,000,在另一个实例中为约1,000,000至约20,000,000,并且在另一个实例中为约2,000,000至约15,000,000。高分子量延伸助剂在本发明的一些实例中是优选的,这是由于其提高延伸熔融粘度并减少熔融破裂的能力。
当用于熔喷法时,将有效量的延伸助剂加到本发明的组合物中以视觉上减少纺丝工艺期间的纤维的熔融破裂和毛细管破损,使得能够熔纺出具有相对一致直径的大体上连续的纤维。无论使用何种方法产生长丝,当使用时延伸助剂的量在一个实例中按干燥长丝和/或干燥洗涤剂产品重量计可为约0.001%至约10%,并且在另一个实例中按干燥长丝和/或干燥洗涤剂产品重量计可为约0.005%至约5%,在另一个实例中按干燥长丝和/或干燥洗涤剂产品重量计可为约0.01%至约1%,并且在另一个实例中按干燥长丝和/或干燥洗涤剂产品重量计可为约0.05%至约0.5%。
可用作延伸助剂的聚合物的非限制性实例可包括藻酸盐、角叉菜胶、果胶、甲壳质、瓜尔胶、黄多醣胶、琼脂、阿拉伯树胶、刺梧桐树胶、黄蓍胶、刺槐豆胶、烷基纤维素、羟烷基纤维素、羧基烷基纤维素、以及它们的混合物。
其他延伸助剂的非限制性实例可包括羧基改性的聚丙烯酰胺、聚丙烯酸、聚甲基丙烯酸、聚乙烯醇、聚乙酸乙烯酯、聚乙烯吡咯烷酮、聚乙烯乙酸乙烯酯、聚乙烯亚胺、聚酰胺、聚亚烷基氧化物包括聚环氧乙烷、聚环氧丙烷、聚乙烯环氧丙烷、以及它们的混合物。
制备长丝的方法
可以使用任何合适的方法来制造本发明的长丝。用于制备长丝的合适方法的非限制性实例在下文中进行了描述。
在一个实例中,如本发明所述用于制备长丝的方法包括以下步骤:
a.提供包含一种或多种长丝形成材料和一种或多种活性剂的长丝形成组合物;并且
b.将长丝形成组合物纺丝成一种或多种长丝,其包含一种或多种长丝形成材料和一种或多种活性剂,所述活性剂当长丝暴露于预期用途的条件时能够从所述长丝中释放,其中存在于长丝中的一种或多种长丝形成材料的总含量按干燥长丝和/或干燥洗涤剂产品重量计小于65%和/或50%或更低,并且存在于长丝中的一种或多种活性剂的总含量按干燥长丝和/或干燥洗涤剂产品重量计大于35%和/或50%或更高。
在一个实例中,当形成长丝时,在纺丝步骤期间例如通过干燥除去存在于长丝形成组合物中的任何挥发性溶剂例如水。在一个实例中,大于30%、和/或大于40%、和/或大于50%重量的长丝形成组合物的挥发性溶剂如水在纺丝步骤期间被除去,例如通过干燥产生的长丝被除去。
只要长丝形成组合物产生的长丝包含的长丝中的长丝形成材料的总含量按干燥长丝和/或干燥洗涤剂产品重量计为约5%至50%或更低,并且长丝中的活性剂总含量按干燥长丝和/或干燥洗涤剂产品重量计为50%至约95%,长丝形成组合物可包含任何适量的长丝形成材料和任何适量的活性剂。
在一个实例中,只要长丝形成组合物产生的长丝包含的长丝中的长丝形成材料的总含量按干燥长丝和/或干燥洗涤剂产品重量计为约5%至50%或更低,并且长丝中的活性剂总含量按干燥长丝和/或干燥洗涤剂产品重量计为50%至约95%,长丝形成组合物可包含任何适量的长丝形成材料和任何适量的活性剂,其中长丝形成材料对添加剂的重量比为1或更低。
在一个实例中,长丝形成组合物包含按长丝形成组合物重量计约1%、和/或约5%、和/或约10%至约50%、和/或至约40%、和/或至约30%、和/或至约20%的长丝形成材料;按长丝形成组合物重量计约1%、和/或约5%、和/或约10%至约50%、和/或至约40%、和/或至约30%、和/或至约20%的活性剂;以及按长丝形成组合物重量计约20%、和/或约25%、和/或约30%、和/或约40%、和/或至约80%、和/或至约70%、和/或至约60%、和/或至约50%的挥发性溶剂如水。长丝形成组合物可包含微量的其他活性剂,例如按长丝形成组合物重量计小于10%、和/或小于5%、和/或小于3%和/或小于1%的增塑剂、pH调节剂、和其他活性剂。
通过任何合适的纺丝工艺如熔喷法和/或纺粘法将长丝形成组合物纺制成一种或多种长丝。在一个实例中,通过熔喷法将长丝形成组合物纺制成多种长丝。例如,可将长丝形成组合物从挤出机中泵入熔喷喷丝头。在排出喷丝头的一个或多个长丝形成空穴时,用空气使长丝形成组合物变细,从而产生一个或多个长丝。然后可干燥长丝以除去用于纺丝的任何残余溶剂,例如水。
可在带如成图案的带上收集本发明的长丝以形成包含长丝的非织造纤维网。
洗涤剂产品
包含本发明的一种或多种活性剂的洗涤剂产品与包含一种或多种活性剂的已知洗涤剂产品相比表现出新的特性、特征、和/或它们的组合。这通过如下表II所示的数据示出。
表II
1 LaundryDetergentSheets,可从DizolveGroupCorp.商购获得
2可从TheDialCorporation商购获得
表II,接上表
1 LaundryDetergentSheets,可从DizolveGroupCorp.商购获得
2可从TheDialCorporation商购获得
非织造纤维网
在本发明的一个实例中,所述洗涤剂产品可包含纤维网,例如非织造纤维网。本发明的一种或多种、和/或多种长丝可通过本领域已知的任何合适方法形成非织造纤维网。当非织造纤维网暴露于长丝和/或非织造纤维网的预期用途条件时,非织造纤维网可用于递送来自本发明长丝的活性剂。
虽然本发明的长丝和/或非织造纤维网和/或膜是固体形式,但用于制备本发明长丝的长丝形成组合物也可为液体形式。
在一个实例中,非织造纤维网包含根据本发明的多个相同或基本上相同的组合透视长丝。在另一个实例中,非织造纤维网可包含两种或更多种根据本发明的不同长丝。长丝差异的非限制性实例可为物理差异如直径、长度、质地、形状、硬度、弹性等的差异;化学差异如交联水平、溶解度、熔点、玻璃化转变温度、活性剂、长丝形成材料、颜色、活性剂含量、长丝形成材料含量、长丝上是否存在任何涂层、是否能够生物降解、是否疏水、接触角等等;当长丝暴露于预期用途条件时是否丧失其物理结构的差异;当长丝暴露于预期用途条件时是否改变形态的差异;以及当长丝暴露于预期用途条件时释放一种或多种它的活性剂的速率的差异。在一个实例中,非织造纤维网内的两种或更多种长丝可包含相同长丝形成材料但具有不同的活性剂。这可为其中不同活性剂可能彼此不相容的情况,例如阴离子表面活性剂(如洗发剂活性剂)和阳离子表面活性剂(如毛发调理剂活性剂)。
在另一个实例中,如图4所示,非织造纤维网20可包含两个或更多个不同的层22、24(在本发明的长丝16的非织造纤维网20的Z方向,所述长丝形成非织造纤维网20。层22中的长丝16可与层24中的长丝16相同或不同。每个层22、24可包含多个相同或基本上相同或不同的长丝。例如,非织造纤维网内可以比其他长丝更快的速率释放它们的活性剂的长丝可定位在非织造纤维网的外表面。
在另一个实例中,非织造纤维网可表现出不同的区域,例如不同基重、密度和/或厚度的区域。在另一个实例中,非织造纤维网可在其一个或多个表面上包含纹理。非织造纤维网的表面可包含图案如非随机重复图案。非织造纤维网可用压花图案压花。在另一个实例中,非织造纤维网可包含孔。所述孔可以随机重复图案排列。
在一个实例中,非织造纤维网可包含长丝的不连续区域,该区域不同于非织造纤维网的其他部分。
本发明非织造纤维网的用途的非限制性实例包括但不限于衣物洗涤烘干机基底、洗衣机基底、浴巾、硬质表面清洁和/或抛光基底、地面清洁和/或抛光基底、电池组分、婴儿擦拭物、成人擦拭物、女性卫生擦拭物、卫生纸擦拭物、窗清洁基底、油抑制剂和/或油清除剂基底、驱昆虫剂基底、游泳池化学基底、食品、口气清新剂、除臭剂、垃圾处理袋、包装膜和/或包裹物、伤口敷料、药物递送、建筑绝缘、作物和/或植物覆盖和/或铺垫、胶基底、皮肤护理基底、毛发护理基底、空气护理基底、水处理基底和/或过滤器、抽水马桶清洁基底、糖果基底、宠物食品、牲畜铺垫、牙齿美白基底、地毯清洁基底、以及本发明活性剂的其他用途。
本发明的非织造纤维网可按原样使用或者可涂覆有一种或多种活性剂。
在另一个实例中,可将本发明的非织造纤维网压成膜,例如通过施加压缩力和/或加热非织造纤维网以将非织造纤维网转化成膜。所述膜将包含存在于本发明长丝中的活性剂。可将非织造纤维网完全转化成膜或非织造纤维网的部分,其可在将非织造纤维网部分转化成膜后保留在膜中。所述膜可用于任何合适的目的,活性剂的用途可包括但不限于非织造纤维网例示的用途。
在一个实例中,本发明的非织造纤维网表现出根据本文所述的溶解度测量方法测量的每克样品平均崩解时间小于120秒/克(s/g)、和/或小于100s/g、和/或小于80s/g、和/或小于55s/g、和/或小于50s/g、和/或小于40s/g、和/或小于30s/g、和/或小于20s/g。
在另一个实例中,本发明的非织造纤维网表现出根据本文所述的溶解度测量方法测量的每克样品平均溶解时间小于950s/g、和/或小于900s/g、和/或小于800s/g、和/或小于700s/g、和/或小于600s/g、和/或小于550s/g。
在一个实例中,本发明的非织造纤维网表现出根据本文所述的厚度测量方法测量的大于0.01mm、和/或大于0.05mm、和/或大于0.1mm、和/或至约20mm、和/或至约10mm、和/或至约5mm、和/或至约2mm、和/或至约0.5mm、和/或至约0.3mm的厚度。
自动盘碟洗涤制品
自动盘碟洗涤制品包含一种或多种长丝和/或纤维和/或非织造纤维网和/或本发明的膜以及表面活性剂体系、和任选地本领域已知的一种或多种任选清洁成分,例如用于在自动洗碗机中清洁盘碟的成分。这些任选成分的实例包括:阻垢剂、漂白剂、香料、染料、抗菌剂、酶(例如蛋白酶、淀粉酶)、清洁聚合物(例如烷氧基化聚乙烯亚胺聚合物)、抗再沉积聚合物、水溶助长剂、抑泡剂、羧酸、增稠剂、防腐剂、消毒剂、玻璃和金属护理剂、使自动盘碟洗涤液体一般具有3至14(或者8至11)的pH的pH缓冲装置、或它们的混合物。自动盘碟洗涤活性剂的实例在US5,679,630;US5,703,034;US5,703,034;US5,705,464;US5,962,386;US5,968,881;US6,017,871;US6,020,294中进行了描述。
垢的形成可能是一个问题。它可能由碱土金属碳酸盐、磷酸盐和硅酸盐的沉淀引起。阻垢剂的实例包括聚丙烯酸酯和基于丙烯酸与其他部分结合的聚合物。这些聚合物的磺化类型在不存在磷酸盐制剂的操作中是尤其有效的。阻垢剂的实例包括在US5,783,540,第15栏,1.20-第16栏,1.2;和EP0851022A2,第12页,1.1-20中描述的那些。
在一个实施方案中,提供了自动盘碟洗涤制品,所述自动盘碟洗涤制品包含本发明的长丝和/或纤维和/或非织造纤维网、非离子表面活性剂、磺化聚合物、任选的螯合剂、任选的助洗剂、以及任选的漂白剂、以及它们的混合物。提供了清洁盘碟的方法,所述方法包括将本发明的自动盘碟洗涤制品放入自动洗碗机的步骤。
手洗餐具洗涤制品
手洗餐具制品包含本发明的一种或多种长丝和/或纤维和/或非织造纤维网和/或膜以及表面活性剂体系、和任选地清洁和手护理领域已知的一种或多种任选成分,例如用于用手清洁盘碟的成分。这些任选成分的实例包括:香料、染料、珠光剂、抗菌剂、酶(例如蛋白酶)、清洁聚合物(例如烷氧基化聚乙烯亚胺聚合物)、阳离子聚合物、水溶助长剂、湿润剂、润肤剂、护手剂、聚合泡稳定剂、漂白剂、二胺、羧酸、增稠剂、防腐剂、消毒剂、使盘碟洗涤液体一般具有3至14(或者8至11)的pH的pH缓冲装置、或它们的混合物。手洗餐具洗涤活性剂的实例在US5,990,065;和US6,060,122中进行了描述。
在一个实施方案中,手洗餐具洗涤制品的表面活性剂包括烷基硫酸盐、烷氧基硫酸盐、烷基磺酸盐、烷氧基磺酸盐、烷基芳基磺酸盐、甜菜碱或脂族胺或杂环仲胺和叔胺的衍生物、季铵表面活性剂、胺、单烷氧基化或多烷氧基化醇、烷基多苷、脂肪酸酰胺表面活性剂、C8-C20氨酰胺、一乙醇酰胺、二乙醇酰胺、异丙醇酰胺、多羟基脂肪酸酰胺、以及它们的混合物。
提供了洗涤盘碟的方法,所述方法包括将本发明的手洗餐具洗涤制品置于适于包含脏污盘碟的洗碗池或盆池的步骤。所述洗碗池或盆池可包含水和/或脏污的盘碟。
硬质表面清洁制品
硬质表面清洁制品包含本发明的一种或多种长丝和/或纤维和/或非织造纤维网和/或膜以及任选地清洁领域已知的一种或多种任选成分,例如用于清洁硬质表面的成分,例如酸组分,如提供良好的水垢去除性能的酸组分(例如甲酸、柠檬酸、山梨酸、乙酸、硼酸、马来酸、己二酸、乳酸、苹果酸、丙二酸、乙醇酸、或它们的混合物)。酸性硬质表面清洁制品可包括的成分的实例可包括在US7,696,143中描述的那些。作为另外一种选择,硬质表面清洁制品包含碱组分(例如链烷醇胺、碳酸盐、碳酸氢盐化合物、或它们的混合物)。碱性硬质表面清洁制品中可包括的成分实例可包括US2010/0206328A1中描述的那些。清洁硬质表面的方法包括使用方法中的硬质表面清洁制品或将其用于清洁硬质表面。在一个实施方案中,所述方法包括将硬质表面清洁制品加到桶或类似容器中,在将所述制品加到桶中之前或之后任选地加入水。在另一个实施方案中,所述方法包括将硬质表面清洁制品加到抽水马桶中,任选地在所述制品已经溶解在抽水马桶中包含的水中后洗擦抽水马桶的表面。
抽水马桶清洁头
提供了抽水马桶清洁工具的抽水马桶清洁头,其包含本发明的一种或多种长丝和/或纤维和/或非织造纤维网和/或膜。所述抽水马桶清洁头可为一次性的。所述抽水马桶清洁头可被可拆卸地连接到柄部,以便使用者的手与抽水马桶保持距离。在一个实施方案中,所述抽水马桶清洁头可包含水分散性外壳。继而,水分散性外壳可包含本发明的一种或多种长丝和/或纤维和/或非织造纤维网和/或膜。这种水分散性外壳可包住一个芯。所述芯可包含至少一种颗粒状材料。所述芯的颗粒状材料可包含表面活性剂、有机酸、香料、消毒剂、漂白剂、洗涤剂、酶、颗粒、或它们的混合物。任选地,所述芯可不含纤维素,并且可包含本发明的一种或多种长丝和/或纤维和/或非织造纤维网和/或膜。合适的抽水马桶清洁头的实例可根据共同转让的美国专利申请12/901,804(P&GCase11892)来制备。包含淀粉材料的合适抽水马桶清洁头可根据共同转让的美国专利申请13/073,308(P&Gcase12048)、13/073,274(P&Gcase12049)和/或13/07,3346(P&Gcase12054)来制备。提供了清洁抽水马桶表面的方法,所述方法包括接触抽水马桶表面与本发明的抽水马桶清洁头的步骤。
使用方法
包含根据本发明的一种或多种织物护理活性剂的非织造纤维网或膜可在用于处理织物制品的方法中利用。处理织物制品的方法可包括选自下列的一个或多个步骤:(a)在洗涤所述织物制品前预处理所述织物制品;(b)接触所述织物制品与通过接触所述非织造纤维网或膜与水形成的洗涤液体;(C)使所述织物制品在烘干机中接触所述非织造纤维网或膜;(d)在烘干机中在所述非织造纤维网或膜的存在下干燥所述织物制品;和(e)它们的组合。
在一些实施方案中,所述方法还可包括在接触非织造纤维网或膜与预处理的织物制品之前将其预湿润的步骤。例如,可用水预湿润非织造纤维网或膜,然后粘附到一部分包含拟进行预处理的污渍的织物上。作为另外一种选择,可湿润所述织物并将纤维网或膜置于或粘附到其上。在一些实施方案中,所述方法还可包括选择仅仅一部分非织造纤维网或膜用于处理织物制品的步骤。例如,如果仅有一个织物护理制品需被处理,可切下或切除一部分非织造纤维网或膜并置于或粘附到织物上,或者置于水中以形成相对少量的洗涤液体,然后其可用于预处理织物。用这种方法,使用者可根据手边的任务来定制织物处理方法。在一些实施方案中,至少一部分非织造纤维网或膜可被施用于拟使用装置处理的织物。示例性的装置包括但不限于刷子和海绵。可重复任何一个或多个前述步骤以获得期望的织物处理有益效果。
制备膜的方法
可将本发明的非织造纤维网转化成膜。用于从根据本发明的非织造纤维网制备膜的方法实例包括以下步骤:
a.提供包含多个长丝的非织造纤维网,所述长丝包含长丝形成材料例如极性溶剂可溶解的长丝形成材料;以及
b.将所述非织造纤维网转化成膜。
在本发明的一个实例中,用于从非织造纤维网制备膜的方法包括提供非织造纤维网并将所述非织造纤维网转化成膜的步骤。
将所述非织造纤维网转化成膜的步骤可包括施力于非织造纤维网的步骤。所述力可包括压缩力。可给非织造纤维网施加约0.2MPa、和/或约0.4MPa、和/或约1MPa、和/或至约10MPa、和/或至约8MPa、和/或至约6MPa的压缩力。
所述非织造纤维网可经受至少20毫秒、和/或至少50毫秒、和/或至少100毫秒、和/或至约800毫秒、和/或至约600毫秒、和/或至约400毫秒、和/或至约200毫秒的力。在一个实例中,非织造纤维网经受约400毫秒至约800毫秒的力。
非织造纤维网可在至少50℃、和/或至少100℃、和/或至少140℃、和/或至少150℃、和/或至少180℃、和/或至约200℃的温度下受力。在一个实例中,非织造纤维网在约140℃至约200℃的温度下受力。
非织造纤维网可由一卷非织造纤维网供应。可将所得膜旋拧成一卷膜。
具体实施方式
根据本发明的长丝的非限制性实施例使用小规模设备26产生,其示意图如图5和6所示。适于分批运行的加压槽28填充有长丝形成组合物30,例如适于制备长丝的长丝形成组合物,所述长丝用作织物护理组合物和/或盘碟洗涤组合物。
使用泵32(例如PEPII型泵,其具有5.0立方厘米每转(Cc/rev)的容量,由ParkerHannifinCorporation,ZenithPumpsdivision,ofSanford,N.C.,USA制造)来将长丝形成组合物30泵入冲模34。长丝形成组合物流向冲模34的材料物流通过调节泵32的每分钟转数(rpm)进行控制。管36与槽28、泵32和冲模34相连,以将来自槽28的长丝形成组合物30传送(用箭头表示)到泵32并送入冲模34。如图6所示的冲模34有两行或更多行彼此间隔开的圆形挤出喷嘴38,它们的间距P为约1.524毫米(约0.060英寸)。喷嘴38具有约0.305毫米(约0.012英寸)的单一内径和约0.813毫米(约0.032英寸)的单一外径。每个单独喷嘴38被环形的和分散加宽的孔口40包裹以提供衰减的空气到每个单独喷嘴38。通过喷嘴38挤出的长丝形成组合物30被一般圆柱形的、湿润的空气流环绕并变细,产生长丝42,所述空气流通过环绕所述喷嘴38的孔口40提供。通过用电阻加热器(例如,由Chromalox,DivisionofEmersonElectric,Pittsburgh,Pa.,USA制造的加热器)加热来自源的压缩空气,来提供抽长空气。将适量气流加到衰减空气中以在电加热的、恒温控制的传送管条件下饱和或接近饱和热空气。冷凝物从电加热的恒温控制分离件中除去。长丝42通过干燥空气流进行干燥,所述空气流具有约149℃(约300°F)至约315℃(约600°F)的温度,其由电阻加热器(未示出)通过干燥喷嘴(未示出)提供,并且相对于纺出长丝42的一般方向成90°的角度排出。
可在收集装置如带或织物上收集长丝,在一个实施例中带或织物能够赋予图案,例如通过在带或织物上收集长丝赋予形成的非织造纤维网非随机重复图案。
实施例1-下表1示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作衣物洗涤剂。
表1
1Celvol523,Celanese/Sekisui,分子量85,000-124,000,87-89%水解的
实施例2-下表2示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作衣物洗涤剂。
表2
1Celvol523,Celanese/Sekisui,分子量85,000-124,000,87-89%水解的
实施例3-下表3示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作手洗餐具洗涤剂。
表3
1Celvol523,Celanese/Sekisui,分子量85,000-124,000,87-89%水解的
*计算值
实施例4-下表4示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作衣物洗涤剂。
表4
1Celvol523,Celanese/Sekisui,分子量85,000-124,000,87-89%水解的
实施例5-下表5示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作衣物洗涤剂。
表5
1Celvol523,Celanese/Sekisui,分子量85,000-124,000,87-89%水解的
实施例6-下表6示出本发明的长丝形成组合物的另一个实施例,所述组合物用于制备本发明的长丝和/或非织造纤维网,它们适用作衣物洗涤剂。
表6
1Celvol523,Celanese/Seisui,分子量85,000-124,000,87-89%水解的
*计算值
实施例7-表7A-7F示出根据本发明的长丝形成组合物及其组分以及长丝和/或由其制成的非织造织物的最终组合物的另一个实施例。此类长丝和/或非织造纤维网适用作衣物洗涤剂。
衣物洗涤剂预混合物
表7A
聚乙烯醇(PVOH)预混合物
表7B
材料 | 活性(%) | 份数(%) | 份数(%) | 水(%) |
聚乙烯醇(Celvol 523) | 100% | 23.00 | 23.00 | 0.00 |
水 | 77.00 | 77.00 | ||
23.00 | 100.00 | 77.00 |
增白剂15预混合物
表7C
纺成长丝的长丝形成组合物
表7D
材料 | 活性(%) | 份数(%) | 份数(%) | 水(%) |
PVOH预混合物 | 23.0% | 34.11 | 148.32 | 114.21 |
衣物洗涤剂预混合物 | 67.6% | 58.89 | 87.11 | 28.2251 --> |
93.00 | 235.43 | 142.43 | ||
干燥除水 | 0.00 | (135.43) | (135.43) | |
93.00 | 100.00 | 7.00 |
加到长丝/混入长丝的非织造纤维网的香料组合物(在形成后)
表7E
材料 | 活性(%) | 份数(%) | 份数(%) | 水(%) |
非织造纤维网 | 93% | 92.10 | 99.03 | 6.93 |
香料 | 100% | 0.97 | 0.97 | 0.00 |
93.07 | 100.00 |
长丝/混入长丝的非织造纤维网的最终组合物
表7F
实施例8-表8A示出酶组合物的实施例;即酶颗粒,可将其加到长丝和/或包含本发明长丝的非织造纤维网中。表8B示出根据本发明的非织造纤维网的实施例,其包含表8A的酶颗粒。
表8A
酶组合物 | 重量(g) |
蛋白酶 | 0.0065 |
第一淀粉酶 | 0.0065 |
第二淀粉酶 | 0.012652 --> |
甘露聚糖酶 | 0.0331 |
表8B
酶组合物 | 重量(g) | 重量(%) |
非织造纤维网 | 6.20 | 99.06 |
蛋白酶 | 0.0065 | 0.10 |
第一淀粉酶 | 0.0065 | 0.10 |
第二淀粉酶 | 0.0126 | 0.20 |
甘露聚糖酶 | 0.0331 | 0.53 |
总计 | 6.26 | 100 |
实施例9-表9示出根据本发明的非织造纤维网的实施例,所述纤维网包含在长丝和/或非织造纤维网形成后加到非织造纤维网或一种或多种构成非织造纤维网的长丝中的纤维素酶。
表9
酶组合物 | 重量(g) | 重量(%) |
非织造纤维网 | 6.20 | 99.9 |
纤维素酶 | 0.0062 | 0.1 |
总计 | 6.2062 | 100 |
测试方法
除非另外指明,本文所述的所有测试(包括定义部分描述的那些和以下测试方法)都是在测试之前已经在温度为73°F±4°F(约23℃±2.2℃)和相对湿度为50%±10%的调理室中调理了2小时的样本上进行的。为了本发明的目的,按本文所述进行调理的样本被认为是干样本(如“干长丝”)。此外,所有测试都是在调理室中进行的。
水含量测试方法
使用以下水含量测试方法测试长丝和/或纤维和/或非织造纤维网中存在的水(水分)含量。
在测试前将长丝和/或非织造织物或它们的部分(“样品”)置于调理室中至少24小时,其温度为73°F±4°F(约23℃±2.2℃)并且相对湿度为50%±10%。当在至少5分钟内未发现重量改变时,记录样品重量。将这种重量记录为样品的“平衡重量”。接下来,将样品置于干燥烘箱中24小时以干燥样品,烘箱温度为70℃,相对湿度为约4%。在干燥24小时后,立即给样品称重。将这种重量记录为样品的“干量”。样品的水(水分)含量如下计算:
将3个等分试样样品中的水%(水分)进行平均以提供报告的样品中的水%(水分)。
溶解度测试方法
设备和材料:
600mL烧杯
磁性搅拌器(LablineNo.1250型或等同物)
磁力搅拌棒(5cm)
温度计(1℃至100℃+/-1℃)
模板,不锈钢(3.8cm×3.2cm)
定时器(0-300秒,精确至秒)
35mm幻灯片框,其具有3.8cm×3.2cm的开口面积(购自PolaroidCorporation)
35mm幻灯片框架
辛辛那提市的水或等同物具有以下特性:总硬度=155mg/L,以CaCO3计;钙含量=33.2mg/L;镁含量=17.5mg/L;磷酸盐含量=0.0462
样本制备:
1.从待测试的膜或非织造纤维网(“样品”)上切除3个测试样品,使用模板以确保样品安装在35mm幻灯片框内,其具有24×36mm的开口面积(即3.8cm×3.2cm的样品)。从膜或非织造纤维网上沿膜或非织造纤维网的横向等距切除样品。
2.固定在分开的35mm幻灯片框中的3个样品中的每一个。
3.将磁性搅拌棒置于600mL烧杯中。
4.获取500mL或更多的辛辛那提市的水并用温度计测量水温,并且如果需要,调节水温以保持它处于测试温度;即,5℃。一旦水温达到5℃,用500mL水充满600mL烧杯。
5.接下来,将烧杯置于磁性搅拌器上。开启搅拌器,并且调节搅拌速度直至在水中产生涡旋并且涡旋底部位于600mL烧杯的400mL刻度处。
6.固定在架子中的具有包含在其中的样品的35mm幻灯片框被设计用于使35mm幻灯片框落入烧杯内的水中,例如35mm幻灯片框架的鳄鱼夹被设计用于定位35mm幻灯片框到600mL烧杯中存在的水中。用鳄鱼夹将35mm幻灯片框固定在35mm幻灯片框一个长端的中间,使得35mm幻灯片框的长端与存在于600mL烧杯中的水表面平行。这种构造将定位膜或非织造纤维网表面垂直于水流方向。35mm幻灯片框和幻灯片框架的略微改动的布置实例在美国专利公开6,787,512的图1-3中示出。
7.在一次运动中,将35mm幻灯片框定位在烧杯内的水中央上方的35mm幻灯片框架落下,导致35mm幻灯片框浸入水中,浸入程度足以使得水接触固定在35mm幻灯片框中的膜或非织造纤维网完全暴露的表面区域。一旦水接触膜或非织造纤维网完全暴露的表面区域就开启定时器。当膜或非织造纤维网分裂时发生崩解。当所有可见膜或非织造纤维网从幻灯片框中释放时,将35mm幻灯片框提出水面,同时继续监控水中的不溶解膜或非织造纤维网片段。当所有膜和非织造部分在水中不可见时,溶解发生。
8.每个样品进行三次平行测定。
9.通过样品重量归一化每个崩解和溶解时间以获取每克测试样品的崩解和溶解时间值,其用单位秒/克样品(s/g)表示。记录每克测试样品的三次平行测定的平均崩解和溶解时间。
直径测试方法
非织造纤维网或膜内的不连续长丝或长丝的直径通过使用扫描电镜(SEM)或光学显微镜以及图像分析软件进行测定。选择200-10,000倍的放大率使得长丝被适当地放大以便进行测量。当使用SEM时,将这些样本溅射上金或钯化合物以避免长丝在电子束中带电和振动。使用来自图像(在监视屏上)的测定长丝直径的手动程序,所述图像用SEM或光学显微镜拍摄。使用鼠标器和光标工具,搜寻随机选择的长丝的边缘,然后横跨其宽度(即,垂直于该点的长丝方向)测量至长丝的另一个边缘。比例校准图像分析工具提供比例缩放以获得以μm计的实际读数。对于非织造纤维网或膜内的长丝,使用SEM或光学显微镜随机选择横跨非织造纤维网或膜样品的多个长丝。切除非织造纤维网或膜(或产物内的纤维网)的至少两个部分并用这种方法测试。总共进行至少100次此类测量并且将所有的数据记录下来进行统计分析。所记录的数据用来计算长丝直径的平均值、长丝直径的标准偏差和长丝直径的中值。
另一个有用的统计量为计算低于某个上限的长丝的种群数量。为了测定该统计量,对软件进行编程以计数结果有多少长丝直径低于上限,并且将该数(除以总数据数量并乘以100%)按百分数报告为低于所述上限的百分数,例如低于1微米直径的百分数或%-亚微米。我们将单个圆形长丝的实测直径(以μm计)表示为di。
如果长丝具有非圆形横截面,则对长丝直径的测量值被测定为且设定成等于液压直径,所述液压直径为长丝横截面积的四倍除以长丝横截面的周长(在中空长丝情形中为外周长)。数均直径,或者平均直径如下计算:
厚度方法
非织造纤维网或膜的厚度通过切割非织造纤维网或膜样品的5个样品,使得每个切割样品的尺寸大于购自Thwing-AlbertInstrumentCompany(Philadelphia,PA)的VIRElectronicThicknessTesterModelII的加载底脚装载面进行测量。加载底脚装载面通常具有约3.14平方英寸的圆形表面积。将样本限定在一个水平平面和加载底脚装载面之间。加载底脚装载面对样本施加的围压为15.5g/cm2。平面和加载底脚装载面之间的所得间隙即为每个样品的厚度。计算五个样品的平均厚度作为厚度。结果报告为毫米(mm)。
剪切粘度测试方法
本发明的长丝形成组合物的剪切粘度使用毛细管流变仪(GoettfertRheograph6000,GoettfertUSA,RockHillSC,USA制造)测量。使用直径D为1.0mm、长度L为30mm(即L/D=30)的毛细管冲模来进行测量。冲模连接到流变仪的20mm圆筒的下端,所述圆筒保持在75℃的冲模测试温度。将已预热至冲模测试温度的60g长丝形成组合物的样品加载到流变仪的圆筒部分中。去除样品中所有夹带的空气。以一组选定的速率1,000s-1至10,000s-1将样品从圆筒推过毛细管模。流变仪的软件可利用样品从圆筒到毛细管模时的压力降和样品经过毛细管模的流速来计算表观剪切粘度。对数(表观剪切粘度)可对对数(剪切速率)作出曲线图并且所述曲线图可通过幂律,根据式η=Kγn-1进行拟合,其中K是材料的粘度常数,n是材料的致稀指数,并且γ是剪切速率。本文长丝形成组合物记录的表观剪切粘度是使用幂律关系内推至剪切速率为3,000s-1时计算所得的。
基重测试方法
纤维结构样品的基重通过选择十二(12)个单个纤维结构样品并制备两叠、每叠六个单个样品进行测量。如果单个样品通过穿孔线彼此相连,当堆叠单个样品时穿孔线必须同侧对齐。使用精密切割器将每叠精确切成3.5英寸×3.5英寸的正方形。混合两叠切好的正方形以制备十二个正方形厚的基重垫。然后在顶部加载天平上称重基重垫,最低分辨率为0.01g。顶部加载天平必须使用气流罩以免受空气扰动和其他扰动的影响。当顶部加载天平上的读数恒定时记录重量。基重计算如下:
重均分子量
材料如聚合物的重均分子量(Mw)通过凝胶渗透色谱法(GPC)使用混合床柱进行测定。利用高效液相色谱(HPLC),其具有以下组件:Model600E泵、系统控制器和控制软件3.2版,Model717加自动取样器和CHM-009246柱加热器,全部由WatersCorporation(Milford,MA,USA)制造。所述柱是PLgel20μm混合A柱(凝胶分子量范围介于1,000g/mol至40,000,000g/mol),其长度为600mm且内径为7.5mm,并且保护柱是PLgel20μm,长度50mm,7.5mmID。柱温为55℃并且注射体积为200μL。检测器是增强光学系统(EOS),其包括软件,4.73.04版检测器软件,由WyattTechnology(SantaBarbara,CA,USA)制造,激光散射检测器,具有K5单元和690nm的激光。奇数检测器上的增益设为101。偶数检测器上的增益设为20.9。WyattTechnology′s差异折射计设为50℃。增益设为10。流动相为HPLC级二甲基亚砜,其具有0.1%w/vLiBr,并且流动相流速为1mL/min,等度。运行时间为30分钟。
通过在流动相中溶解材料制备样品,规定为3mg材料/1mL流动相。封盖样品,然后使用磁性搅拌器搅拌约5分钟。然后将样品置于85℃的对流烘箱中60分钟。然后使样品自然冷却至室温。然后通过5μm尼龙膜过滤样品,所述尼龙膜为Spartan-25型,由Schleicher&Schuell(Keene,NH,USA)制造,使用5mL注射器将样品过滤到5毫升(mL)自动取样小瓶中。
对于测量的每个系列的样品(3或更多个材料样品),将溶剂空白样品注入柱中。然后以与上述样品相关的类似方法制备对照样品。对照样品包含2mg/mL的支链淀粉(PolymerLaboratories),其具有47,300g/mol的重均分子量。在分析每组样品前分析对照样品。平行测试空白样品、对照样品和材料测试样品。最后测试空白样品。光散射检测器和差异折射计根据“DawnEOSLightScatteringInstrumentHardwareManual”和“DSPInterferometricRefractometerHardwareManual”运行,它们均由WyattTechnologyCorp.(SantaBarbara,CA,USA)制造,并且二者均以引用的方式并入本文。
使用检测器软件计算样品的重均分子量。使用0.066的dn/dc(折射率随浓度的差异变化)值。修正激光检测器和折射率检测器的基线以去除检测器暗电流和溶剂散射的影响。如果激光检测器信号是饱和的或者显示过多的噪音,它不用于计算分子量。选择分子量表征的区域,使得激光散射和折射率的90°检测器的信号比它们的相应基线噪音水平高3倍以上。通常色谱的高分子量侧由折射率信号限定,并且低分子量侧由激光信号限定。
可使用如检测器软件定义的“一阶席姆图”计算重均分子量。如果样品的重均分子量大于1,000,000g/mol,计算第一和第二阶席姆图,并且使用具有最少回归拟合误差的结果计算分子量。报告的重均分子量是材料试验样本的两次运行的平均值。
伸长率、拉伸强度、TEA和模量测试方法
切下至少八个1英寸宽的洗涤剂产品样品条,所述样品将在纵向上进行测试。切下至少八个横向1英寸宽的样品条。如果纵向和横向不容易辨别,那么横向将为产生较低拉伸峰值载荷的样品条。
使用Thwing-AlbertIntelectIIStandardTensileTester(Thwing-AlbertInstrumentCo.,Philadelphia,Pa.)进行特性的实际测量。将平面夹具插入到单元中并根据Thwing-AlbertIntelectII的操作手册中给出的说明书校准试验机。将仪器十字头速度设定为4.00英寸/分钟并将第1和第2标距设定为4.00英寸。将断裂灵敏度设为20.0克并将样品宽度设为1.00英寸。将能量单位设为TEA并将切线模量捕集设置设为38.1g。
在将洗涤剂产品样品条插入两个夹具之后,可监控仪器张力。如果它显示5克或更高的值,所述洗涤剂产品样品条太紧。反之,如果在开始测试后过了2-3秒的时间还没有任何值被记录下来,则洗涤剂产品样品条太松。
根据拉伸试验机仪器手册中所述启动拉伸试验机。当测试完成时,读数并记录以下值以及测量单位:
拉伸峰值载荷(拉伸强度)(g/in)
峰值伸长率(伸长率)(%)
峰值横向TEA(湿横向TEA)(in-g/in2)
切线模量(干纵向模量和干横向模量)(在15g/cm下)
以相同方式测试每个洗涤剂产品样品,记录上述来自每次测试的测量值。取获取自受试洗涤剂产品的每个特性的平均值以得到该特性的报告值。
计算:
几何平均(GM)干模量=[干纵向模量(在15g/cm下)×干横向模量(在15g/cm下)]的平方根
板硬度测试方法
如本文所用,“板硬度”测试是当平坦样品向下变形形成样品下方的孔时其硬度的量度。对于该测试,将样品模型化为一块无穷大的板,其厚度为“t”,座落在平坦表面上,其中它中心在一个孔上,孔半径为“R”。将中心力“F”施加在直接位于孔中心上方的样品上,使其向下挠曲陷入孔中,挠曲距离为“w”。对于线性弹性材料,可通过下式预测挠曲:
其中“E”是有效的线性弹性模量,“v”是泊松比,“R”是孔半径,而“t”是样品厚度,取在约0.29psi的载荷下对一叠5个样品测得的以毫米表示的厚度。泊松比取0.1(泊松解对该参数并非是高度敏感的,因此由假定值导致的不精确可能是微小的),可将上文公式对“w”重写以预测根据弹性测试结果的有效模量:
使用带有100N负载传感器的MTSAllianceRT/1测试仪(MTSSystemsCorp.,EdenPrairie,Minn.)获得测试结果。当至少2.5平方英寸的一叠五个样品形成的片位于支撑板上的孔(半径15.75mm)中心的上方时,一个半径为3.15mm的钝头探针以20mm/min的速度降下。当探针尖端下降至支撑板平面下1mm时,测试结束。在测试期间记录超过任何0.5mm跨度的最大比降(以克力/mm表示)(这种最大比降一般发生在测试末期)。负载传感器监控施加的力,并且还监控探针尖端相对于支撑板平面的位置。记录峰值载荷,并且使用上文公式预测“E”。
然后可将每单位宽度的板硬度“S”计算为:
并且用单位牛顿毫米表示。Testworks程序使用下式计算硬度:
S=(F/w)[(3+v)R2/16π]
其中“F/w”是最大比降(力除以挠曲),“v”是取作0.1的泊松比,而“R”是环半径。
长丝组成测试方法
为了制备用于长丝组成测量的长丝,所述长丝必须通过除去任何涂层组合物和/或存在于长丝外表面上的可移除材料进行调理。完成这一测试的方法实例是用蒸馏水洗涤长丝3次。然后在73°F±4°F(约23℃±2.2℃)下风干所述长丝直至长丝包含小于10%的水分。然后完成调理长丝的化学分析以测定相对于长丝形成材料和活性剂的长丝组成以及长丝中存在的长丝形成材料或活性剂的含量。
相对于长丝形成材料和活性剂的长丝组成也可通过使用TOF-SIMs或SEM完成横截面分析来测定。测定长丝组成的另一种方法使用荧光染料作为标记。此外,一如既往,长丝的制造商应了解他们的长丝的组成。
本文所公开的量纲和值不应当被理解为严格限于所引用的精确值。相反,除非另外指明,每个这样的量纲均旨在既表示所引用的值,也表示围绕此值的功能上等同的范围。例如,公开为“40mm”的量纲旨在表示“约40mm”。
除非明确排除或换句话讲有所限制,本文中引用的每一个文献,包括任何交叉引用或相关专利或专利申请,均据此以引用方式全文并入本文。任何文献的引用不是对其作为本文所公开的或受权利要求书保护的任何发明的现有技术,或者其单独地或者与任何其它参考文献的任何组合,或者参考、提出、建议或公开任何此类发明的认可。此外,如果此文献中术语的任何含义或定义与以引用方式并入的文献中相同术语的任何含义或定义相冲突,将以此文献中赋予那个术语的含义或定义为准。
尽管已用具体实施例和/或实施方案来说明和描述了本发明,但是对那些本领域的技术人员显而易见的是,在不脱离本发明的实质和范围的情况下能够做出许多其它的改变和变型。因此,所附权利要求旨在涵盖本发明范围内的所有这些改变和变型。
Claims (6)
1.一种洗涤剂产品,所述洗涤剂产品包含多种长丝,其中所述长丝的至少一种包含一种或多种活性剂以及一种或多种水溶性长丝形成材料,存在于所述长丝中的所述一种或多种活性剂的总含量按干燥长丝重量计大于20%,其中所述洗涤剂产品表现出选自下列的特性:
a.根据本文所述的基重测试方法测量的小于500g/m2的基重;
b.根据本文所述的伸长率测试方法测量的大于10%的纵向峰值伸长率;
c.根据本文所述的模量测试方法测量的小于15,000g/cm2的几何平均模量;以及
d.它们的混合,
其中所述一种或多种活性剂包括表面活性剂;
所述洗涤剂产品表现出下列的至少一种:
(i)根据本文所述的水含量测试方法测量的0%至20%的水含量;或
(ii)根据本文所述的溶解度测试方法测量的小于950s/g的平均溶解时间;或
(iii)根据本文所述的溶解度测试方法测量的小于120s/g的平均崩解时间。
2.如权利要求1所述的洗涤剂产品,其中所述洗涤剂产品表现出下列的至少两种:
(i)根据本文所述的水含量测试方法测量的0%至20%的水含量;或
(ii)根据本文所述的溶解度测试方法测量的小于950s/g的平均溶解时间;或
(iii)根据本文所述的溶解度测试方法测量的小于120s/g的平均崩解时间。
3.如权利要求1所述的洗涤剂产品,其中所述洗涤剂产品表现出下列的全部:
(i)根据本文所述的水含量测试方法测量的0%至20%的水含量;或
(ii)根据本文所述的溶解度测试方法测量的小于950s/g的平均溶解时间;或
(iii)根据本文所述的溶解度测试方法测量的小于120s/g的平均崩解时间。
4.如权利要求1所述的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的水含量测试方法测量的0%至20%的水含量。
5.如权利要求1所述的洗涤剂产品,其中所述洗涤剂产品表现出根据本文所述的溶解度测试方法测量的小于950s/g的平均溶解时间。
6.如权利要求1所述的洗涤剂产品,其中所述洗涤剂产品表现出根据溶解度测试方法测量的小于120s/g的平均崩解时间。
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ503232A (en) * | 1999-03-08 | 2001-11-30 | Humatro Corp | Melt processable starch compositions comprising amylopectin and a high polymer (such as polyacrylamide) |
BR112013000101A2 (pt) | 2010-07-02 | 2016-05-17 | Procter & Gamble | filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos |
BR112013000044B1 (pt) | 2010-07-02 | 2022-01-04 | The Procter & Gamble Company | Método para a distribuição de agentes ativos a artigos de tecido ou superfícies duras |
CN105647715B (zh) | 2010-07-02 | 2019-10-25 | 宝洁公司 | 洗涤剂产品 |
JP5540107B2 (ja) | 2010-07-02 | 2014-07-02 | ザ プロクター アンド ギャンブル カンパニー | 不織布ウェブからフィルムを作製する方法 |
US9139802B2 (en) | 2012-01-04 | 2015-09-22 | The Procter & Gamble Company | Active containing fibrous structures with multiple regions |
US10694917B2 (en) | 2012-01-04 | 2020-06-30 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
MX352942B (es) * | 2012-01-04 | 2017-12-14 | Procter & Gamble | Estructuras fibrosas que contienen activos y multiples regiones que tienen densidades diferentes. |
EP2800831B1 (en) * | 2012-01-04 | 2020-12-16 | The Procter and Gamble Company | Fibrous structures comprising particles and methods for making same |
EP2817454B1 (en) * | 2012-02-22 | 2016-11-09 | The Procter and Gamble Company | Fibrous structures and methods for making same |
US20130284637A1 (en) | 2012-04-30 | 2013-10-31 | Danisco Us Inc. | Unit-dose format perhydrolase systems |
BR112014027872B1 (pt) * | 2012-05-11 | 2020-11-24 | Basf Se | polietilenoimina etoxilada, e, uso de um polímero de polialquilenimina etoxilada solúvel em água |
DE102012208286A1 (de) * | 2012-05-16 | 2013-11-21 | Henkel Ag & Co. Kgaa | Wasserarmes, flüssiges Waschmittel mit aus nachwachsenden Rohstoffen gewonnenen Tensiden |
GB2502339B (en) * | 2012-05-25 | 2018-02-07 | Cosmetic Warriors Ltd | Solid cosmetic composition |
US8968517B2 (en) | 2012-08-03 | 2015-03-03 | First Quality Tissue, Llc | Soft through air dried tissue |
MX2015014318A (es) | 2013-04-12 | 2015-12-08 | Procter & Gamble | Estructuras fibrosas que muestran valores de indices de blancura mejorados. |
WO2014168942A1 (en) * | 2013-04-12 | 2014-10-16 | The Procter & Gamble Company | Fibrous structures comprising polysaccharide filaments |
BR112015032340A2 (pt) * | 2013-06-27 | 2017-07-25 | Procter & Gamble | composições e artigos para cuidados pessoais |
CA2928748C (en) * | 2013-10-25 | 2020-03-10 | Matthew Gary Mckee | Fibrous elements comprising an acrylamide-based copolymer and fibrous structures employing same |
US9375502B2 (en) * | 2013-10-29 | 2016-06-28 | American Covers, Inc. | Air freshener with scented string |
EP3805350B1 (en) | 2013-12-09 | 2024-03-06 | The Procter & Gamble Company | Fibrous structures including an active agent and having a graphic printed thereon |
CN106413683A (zh) | 2014-04-22 | 2017-02-15 | 宝洁公司 | 可溶性固体结构体形式的组合物 |
BR112016024698B1 (pt) * | 2014-04-22 | 2022-05-24 | The Procter & Gamble Company | Filamentos e estruturas fibrosas que empregam os mesmos |
US9861559B2 (en) | 2014-05-05 | 2018-01-09 | The Procter & Gamble Company | Consumer product comprising a porous, dissolvable, fibrous web solid structure with a silicone coating |
US9861558B2 (en) | 2014-05-05 | 2018-01-09 | The Procter & Gamble Company | Methods of forming an aqueous treatment liquor by dissolving a porous solid with a benefit agent coating |
US9827173B2 (en) | 2014-05-05 | 2017-11-28 | The Procter & Gamble Company | Porous dissolvable solid structure with two benefit agents and methods of forming an aqueous treatment liquor therefrom |
US9867762B2 (en) * | 2014-05-05 | 2018-01-16 | The Procter & Gamble Company | Consumer product comprising a porous dissolvable solid structure and silicone conditioning agent coating |
US9937111B2 (en) * | 2014-05-05 | 2018-04-10 | The Procter & Gamble Company | Consumer product comprising a fibrous web solid structure with a silicone conditioning agent coating |
US9877899B2 (en) * | 2014-05-05 | 2018-01-30 | The Procter & Gamble Company | Consumer product comprising a fibrous web structure with a silicone conditioning agent coating |
US20150313805A1 (en) | 2014-05-05 | 2015-11-05 | The Procter & Gamble Company | Consumer Products |
EP3142625A4 (en) * | 2014-05-16 | 2017-12-20 | First Quality Tissue, LLC | Flushable wipe and method of forming the same |
US20210022931A1 (en) | 2014-06-02 | 2021-01-28 | Tethis, Inc. | Absorbent articles with biocompostable properties |
US10980912B2 (en) * | 2014-06-02 | 2021-04-20 | Tethis, Inc. | Absorbent articles with biocompostable properties |
US12059334B2 (en) | 2014-06-02 | 2024-08-13 | Tethis, Inc. | Absorbent articles with biocompostable properties |
EP2982735B2 (en) | 2014-08-07 | 2021-07-07 | The Procter & Gamble Company | Laundry detergent composition |
BR112017007305A2 (pt) | 2014-10-10 | 2017-12-19 | Procter & Gamble | estruturas fibrosas com aberturas e métodos para a produção das mesmas |
WO2016077594A1 (en) | 2014-11-12 | 2016-05-19 | First Quality Tissue, Llc | Cannabis fiber, absorbent cellulosic structures containing cannabis fiber and methods of making the same |
MX2017006716A (es) | 2014-11-24 | 2018-03-21 | First Quality Tissue Llc | Papel tisu suave producido usando una tela estructurada y prensado energetico eficiente. |
CA2967986C (en) | 2014-12-05 | 2023-09-19 | Structured I, Llc | Manufacturing process for papermaking belts using 3d printing technology |
EP3034589A1 (en) * | 2014-12-17 | 2016-06-22 | The Procter and Gamble Company | Detergent composition |
EP3034588B1 (en) | 2014-12-17 | 2019-04-24 | The Procter and Gamble Company | Detergent composition |
EP3034596B2 (en) | 2014-12-17 | 2021-11-10 | The Procter & Gamble Company | Detergent composition |
EP3034597A1 (en) | 2014-12-17 | 2016-06-22 | The Procter and Gamble Company | Detergent composition |
TWI528978B (zh) * | 2014-12-27 | 2016-04-11 | 財團法人紡織產業綜合研究所 | 碳酸纖維膜 |
US10245221B2 (en) | 2015-05-07 | 2019-04-02 | Celeb LLC | Stabilized color depositing shampoo |
US9889080B2 (en) | 2015-05-07 | 2018-02-13 | Celeb LLC | Color depositing shampoo |
US10538882B2 (en) | 2015-10-13 | 2020-01-21 | Structured I, Llc | Disposable towel produced with large volume surface depressions |
WO2017066465A1 (en) | 2015-10-13 | 2017-04-20 | First Quality Tissue, Llc | Disposable towel produced with large volume surface depressions |
US11220394B2 (en) | 2015-10-14 | 2022-01-11 | First Quality Tissue, Llc | Bundled product and system |
CN108474141B (zh) * | 2016-01-21 | 2020-11-13 | 宝洁公司 | 包含聚环氧乙烷的纤维元件 |
MX2018009679A (es) | 2016-02-11 | 2019-07-04 | Correa o tela que incluye capas poliméricas para una máquina de fabricación de papel. | |
US20170314206A1 (en) | 2016-04-27 | 2017-11-02 | First Quality Tissue, Llc | Soft, low lint, through air dried tissue and method of forming the same |
US10773405B2 (en) * | 2016-06-30 | 2020-09-15 | The Gillette Company Llc | Shaving aid for razor cartridges comprising a nano-filament comprising a core and sheath |
WO2018039623A1 (en) | 2016-08-26 | 2018-03-01 | Structured I, Llc | Method of producing absorbent structures with high wet strength, absorbency, and softness |
DE102016217303A1 (de) | 2016-09-12 | 2018-03-15 | Henkel Ag & Co. Kgaa | Filament zur Herstellung eines Wasch- oder Reinigungsmittelprodukts, Wasch- oder Reinigungsmittelprodukt, Verfahren zur Herstellung von Filament und Wasch- oder Reinigungsmittelprodukt sowie Druckvorlage für das Wasch- oder Reinigungsmittelprodukt |
US10422078B2 (en) | 2016-09-12 | 2019-09-24 | Structured I, Llc | Former of water laid asset that utilizes a structured fabric as the outer wire |
US11583489B2 (en) | 2016-11-18 | 2023-02-21 | First Quality Tissue, Llc | Flushable wipe and method of forming the same |
JP6882519B2 (ja) | 2017-01-27 | 2021-06-02 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 発泡性凝集粒子を含む溶解性固形構造体形態の組成物 |
US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
MX2019008762A (es) | 2017-01-27 | 2019-09-18 | Procter & Gamble | Composiciones en la forma de estructuras solidas solubles. |
EP4197598A1 (en) * | 2017-01-27 | 2023-06-21 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697906B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
KR102360242B1 (ko) * | 2017-01-27 | 2022-02-09 | 더 프록터 앤드 갬블 캄파니 | 수용성 섬유질 구조체 및 입자를 포함하는 수용성 단위 용량 물품 |
US10975339B2 (en) | 2017-05-16 | 2021-04-13 | The Procter & Gamble Company | Active agent-containing articles |
US10975340B2 (en) | 2017-05-16 | 2021-04-13 | The Procter & Gamble Company | Active agent-containing fibrous structure articles |
MX2019013048A (es) | 2017-05-16 | 2019-12-11 | Procter & Gamble | Composiciones acondicionadoras para el cuidado del cabello en la forma de estructuras solidas solubles. |
USD844450S1 (en) | 2017-07-12 | 2019-04-02 | Korex Canada Company | Detergent pouch |
US10619309B2 (en) | 2017-08-23 | 2020-04-14 | Structured I, Llc | Tissue product made using laser engraved structuring belt |
CA3075254C (en) * | 2017-09-08 | 2023-12-12 | Lg Household & Health Care Ltd. | Laundry sheet |
WO2019059608A1 (ko) * | 2017-09-22 | 2019-03-28 | (주)아모레퍼시픽 | 모발 관리용 조성물 |
WO2019108142A2 (en) * | 2017-11-30 | 2019-06-06 | Hayat Kimya Sanayi Anonim Sirketi | Unit dose cleaning product having hydrophilic spin-finish |
WO2019147532A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
CA3086689C (en) | 2018-01-26 | 2023-05-09 | The Procter & Gamble Company | Process for making water-soluble articles by cutting a fibrous web in a tessellated pattern |
JP2021507055A (ja) * | 2018-01-26 | 2021-02-22 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 繊維基材を有する一体型洗濯用洗剤物品 |
US10857756B2 (en) | 2018-01-26 | 2020-12-08 | The Procter & Gamble Company | Process of making a multi-ply fibrous water soluble product |
US20190233785A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
CA3087284C (en) | 2018-01-26 | 2023-05-02 | The Procter & Gamble Company | Water-soluble unit dose articles comprising enzyme |
US20190233970A1 (en) * | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Process for Making an Article of Manufacture |
US10683618B2 (en) | 2018-01-26 | 2020-06-16 | The Procter & Gamble Company | Process of making a multi-ply fibrous water soluble product |
WO2019168829A1 (en) | 2018-02-27 | 2019-09-06 | The Procter & Gamble Company | A consumer product comprising a flat package containing unit dose articles |
EP3790377A1 (en) * | 2018-05-09 | 2021-03-17 | Sabanci Universitesi | Greenhouse cover loaded with pesticide providing controlled release |
WO2019222126A1 (en) | 2018-05-14 | 2019-11-21 | The Procter & Gamble Company | Oral care compositions comprising metal ions |
US11911492B2 (en) | 2018-05-14 | 2024-02-27 | The Procter & Gamble Company | Oral care compositions comprising metal ions |
SG11202009868TA (en) | 2018-05-15 | 2020-11-27 | Essity Hygiene & Health Ab | Fibrous product |
US11697538B2 (en) | 2018-06-21 | 2023-07-11 | First Quality Tissue, Llc | Bundled product and system and method for forming the same |
US11738927B2 (en) | 2018-06-21 | 2023-08-29 | First Quality Tissue, Llc | Bundled product and system and method for forming the same |
JP1629688S (zh) | 2018-07-16 | 2019-04-15 | ||
US10982176B2 (en) | 2018-07-27 | 2021-04-20 | The Procter & Gamble Company | Process of laundering fabrics using a water-soluble unit dose article |
US11666514B2 (en) | 2018-09-21 | 2023-06-06 | The Procter & Gamble Company | Fibrous structures containing polymer matrix particles with perfume ingredients |
US20200190433A1 (en) | 2018-12-14 | 2020-06-18 | The Procter & Gamble Company | Foaming Fibrous Structures Comprising Particles and Methods for Making Same |
WO2020159860A1 (en) | 2019-01-28 | 2020-08-06 | The Procter & Gamble Company | Recycleable, renewable, or biodegradable package |
EP3942008A1 (en) | 2019-03-19 | 2022-01-26 | The Procter & Gamble Company | Process of reducing malodors on fabrics |
EP3712238A1 (en) * | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Process for manufacturing a fibrous water-soluble unit dose article |
EP3712237A1 (en) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
DE102019203801A1 (de) * | 2019-03-20 | 2020-09-24 | Henkel Ag & Co. Kgaa | Handgeschirrspülmittel umfassend Glutaminsäure Komplexbildner |
JP2022534415A (ja) * | 2019-05-28 | 2022-07-29 | エルジー ハウスホールド アンド ヘルスケア リミテッド | ポリオールまたは金属イオン塩化物を含む溶解性洗濯用シート |
MX2021014994A (es) | 2019-06-13 | 2022-01-24 | Procter & Gamble | Kits que comprenden composiciones de dosis unitaria para el cuidado bucal. |
MX2021013141A (es) | 2019-06-28 | 2021-12-10 | Procter & Gamble | Articulos fibrosos solidos disolubles que contienen surfactantes anionicos. |
CN114173749A (zh) | 2019-06-28 | 2022-03-11 | 宝洁公司 | 水溶性个人清洁产品和用途 |
CN114025738A (zh) | 2019-07-03 | 2022-02-08 | 宝洁公司 | 包含阳离子表面活性剂和可溶性酸的纤维结构 |
CN114144156B (zh) | 2019-07-31 | 2024-08-13 | 宝洁公司 | 包括包含天然或改性淀粉的纤维元件的水溶性个人清洁产品、用途、方法和套盒 |
USD939359S1 (en) | 2019-10-01 | 2021-12-28 | The Procter And Gamble Plaza | Packaging for a single dose personal care product |
US11766366B2 (en) | 2019-11-01 | 2023-09-26 | Tethis, Inc. | Absorbent hygienic articles with sensors and biocompostable elements |
MX2022002875A (es) | 2019-10-14 | 2022-03-25 | Procter & Gamble | Bolsita biodegradable y/o para compost domestico que contiene un articulo solido. |
MX2022003979A (es) | 2019-11-20 | 2022-04-26 | Procter & Gamble | Estructura solida soluble porosa. |
MX2022005532A (es) | 2019-12-01 | 2022-06-08 | Procter & Gamble | Composiciones acondicionadoras para el cabello con un sistema de conservacion que contiene benzoato de sodio y glicoles y/o esteres de glicerilo. |
USD962050S1 (en) | 2020-03-20 | 2022-08-30 | The Procter And Gamble Company | Primary package for a solid, single dose beauty care composition |
USD941051S1 (en) | 2020-03-20 | 2022-01-18 | The Procter And Gamble Company | Shower hanger |
USD965440S1 (en) | 2020-06-29 | 2022-10-04 | The Procter And Gamble Company | Package |
EP4188554A1 (en) | 2020-07-31 | 2023-06-07 | The Procter & Gamble Company | Water-soluble fibrous pouch containing prills for hair care |
WO2022036353A1 (en) | 2020-08-11 | 2022-02-17 | The Procter & Gamble Company | Moisturizing hair conditioner compositions containing brassicyl valinate esylate |
CN116472021A (zh) | 2020-08-11 | 2023-07-21 | 宝洁公司 | 含有芸苔油醇缬氨酸酯乙磺酸盐的清洁冲洗毛发调理剂组合物 |
US11633336B2 (en) | 2020-08-11 | 2023-04-25 | The Procter & Gamble Company | Low viscosity hair conditioner compositions containing brassicyl valinate esylate |
US11344492B2 (en) | 2020-09-14 | 2022-05-31 | Milliken & Company | Oxidative hair cream composition containing polymeric colorant |
US11351106B2 (en) | 2020-09-14 | 2022-06-07 | Milliken & Company | Oxidative hair cream composition containing thiophene azo colorant |
JP2023553395A (ja) | 2020-12-01 | 2023-12-21 | ザ プロクター アンド ギャンブル カンパニー | 可溶化抗ふけ活性物質を含有する水性ヘアコンディショナー組成物 |
CA3219441A1 (en) | 2021-05-11 | 2022-11-17 | The Procter & Gamble Company | Oral care compositions comprising block copolymer |
CN113529278B (zh) * | 2021-06-21 | 2022-06-21 | 五邑大学 | 一种交联型纳米纤维膜及其制备方法与应用 |
US11753609B1 (en) | 2021-09-01 | 2023-09-12 | Venus Laboratories, Inc. | Eco-friendly laundry sheet comprising a poly(2-ethyl-2-oxazoline) binder |
CN114214750B (zh) * | 2022-01-13 | 2023-09-15 | 天津工业大学 | 一种阻燃聚丙烯腈复合纤维及其制备方法和应用 |
US11464384B1 (en) | 2022-03-31 | 2022-10-11 | Techtronic Cordless Gp | Water soluable package for a floor cleaner |
WO2023196214A1 (en) | 2022-04-04 | 2023-10-12 | The Procter & Gamble Company | Unit-dose oral care compositions comprising fluoride |
IL294539B2 (en) | 2022-07-05 | 2023-07-01 | Capsule Minimal Ltd | A fast-dissolving cartridge array and industrial systems and methods for its production |
WO2024152299A1 (en) | 2023-01-19 | 2024-07-25 | The Procter & Gamble Company | Methods for making three-dimensional webs |
US12070171B2 (en) | 2023-01-20 | 2024-08-27 | Sharkninja Operating Llc | Extraction cleaner |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1658831A (zh) * | 2002-06-07 | 2005-08-24 | 宝洁公司 | 用于皮肤或毛发的清洁制品 |
US20090041820A1 (en) * | 2007-08-07 | 2009-02-12 | Wu Margaret M | Functional polymer compositions |
Family Cites Families (1031)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US34584A (en) | 1862-03-04 | Improvement in rakes for harvesters | ||
US548744A (en) | 1895-10-29 | Electric switch | ||
CA166297A (en) | 1915-08-27 | 1915-11-30 | Stinson V. Clayton | Window shade mechanism |
US1421350A (en) | 1920-08-14 | 1922-06-27 | Frederick N Windridge | Hair-cutting machine |
BE406221A (zh) | 1933-11-15 | |||
US2220099A (en) | 1934-01-10 | 1940-11-05 | Gen Aniline & Flim Corp | Sulphonic acids |
US2124526A (en) | 1937-04-22 | 1938-07-26 | Timken Roller Bearing Co | Diaphragm closure for bearings |
US2356168A (en) | 1941-08-16 | 1944-08-22 | Clarence W Mabley | Soap leaf |
US2438091A (en) | 1943-09-06 | 1948-03-16 | American Cyanamid Co | Aspartic acid esters and their preparation |
BE498391A (zh) | 1944-10-16 | |||
BE498392A (zh) | 1945-11-09 | |||
US2477383A (en) | 1946-12-26 | 1949-07-26 | California Research Corp | Sulfonated detergent and its method of preparation |
US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
GB656210A (en) | 1948-10-07 | 1951-08-15 | British Celanese | Improvements relating to cleansing materials for toilet use |
US2613185A (en) | 1951-03-30 | 1952-10-07 | Micro Proc Equipment Inc | Composite detergent bar |
US2658072A (en) | 1951-05-17 | 1953-11-03 | Monsanto Chemicals | Process of preparing amine sulfonates and products obtained thereof |
US2694668A (en) | 1952-03-10 | 1954-11-16 | Abbott Lab | Liquid multiple vitamin preparation and process of preparing the same |
US2826551A (en) | 1954-01-04 | 1958-03-11 | Simoniz Co | Nontangling shampoo |
BE551361A (zh) | 1955-10-27 | |||
US2809971A (en) | 1955-11-22 | 1957-10-15 | Olin Mathieson | Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same |
US3152046A (en) | 1956-11-09 | 1964-10-06 | Kapral Ales Maria | Selenium disulfide dispersions |
GB849433A (en) | 1957-08-22 | 1960-09-28 | Raymond Woolston | Hair washing preparations |
NL125761C (zh) | 1959-05-23 | |||
US3157611A (en) | 1961-05-12 | 1964-11-17 | Air Reduction | Aqueous film forming compositions containing polyvinyl alcohol and a phosphate ester |
US3308067A (en) | 1963-04-01 | 1967-03-07 | Procter & Gamble | Polyelectrolyte builders and detergent compositions |
US3293718A (en) | 1963-07-01 | 1966-12-27 | Du Pont | Apparatus for forming non-woven web structures |
US3236733A (en) | 1963-09-05 | 1966-02-22 | Vanderbilt Co R T | Method of combatting dandruff with pyridinethiones metal salts detergent compositions |
DE1195013B (de) | 1963-09-24 | 1965-06-16 | Spitzner Arzneimittelfabrik G | Verfahren zur Herstellung von geformten, festen Badezusaetzen |
NL6507328A (zh) | 1964-06-12 | 1965-12-13 | ||
US3332880A (en) | 1965-01-04 | 1967-07-25 | Procter & Gamble | Detergent composition |
CH490889A (de) | 1965-08-02 | 1970-05-31 | Ciba Geigy | Verfahren zur Einkapselung von in einer Flüssigkeit fein verteilter Substanz |
NL136759C (zh) | 1966-02-16 | |||
US3553139A (en) | 1966-04-25 | 1971-01-05 | Procter & Gamble | Enzyme containing detergent composition and a process for conglutination of enzymes and detergent composition |
US3519570A (en) | 1966-04-25 | 1970-07-07 | Procter & Gamble | Enzyme - containing detergent compositions and a process for conglutination of enzymes and detergent compositions |
US3452382A (en) | 1966-05-25 | 1969-07-01 | Samuel Kazdan | Tooth cleansing device |
US3426440A (en) | 1966-06-24 | 1969-02-11 | Monsanto Co | Detergent fluidized drying process |
US3463308A (en) | 1966-11-11 | 1969-08-26 | Deneke Karl Heinz | Vending device for pins,needles,hardware or the like |
US3761418A (en) | 1967-09-27 | 1973-09-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
US3600319A (en) | 1968-06-25 | 1971-08-17 | Procter & Gamble | Process for application of enzymes to spray-dried detergent granules |
US3570122A (en) | 1968-12-11 | 1971-03-16 | Vernco Corp | Drive finger for a clipper blade |
US3589007A (en) | 1969-02-24 | 1971-06-29 | Wahl Clipper Corp | Electric hair clipper |
US3653383A (en) | 1969-07-30 | 1972-04-04 | Freeze Dry Products | Algin sponge and process therefor |
US3646015A (en) | 1969-07-31 | 1972-02-29 | Procter & Gamble | Optical brightener compounds and detergent and bleach compositions containing same |
US3664961A (en) | 1970-03-31 | 1972-05-23 | Procter & Gamble | Enzyme detergent composition containing coagglomerated perborate bleaching agent |
US3695989A (en) | 1970-08-12 | 1972-10-03 | Robert E Albert | Cold water soluble foam plastic package |
US3812044A (en) | 1970-12-28 | 1974-05-21 | Procter & Gamble | Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent |
JPS5233195B2 (zh) | 1971-09-30 | 1977-08-26 | ||
US3753196A (en) | 1971-10-05 | 1973-08-14 | Kulite Semiconductor Products | Transducers employing integral protective coatings and supports |
CA989557A (en) | 1971-10-28 | 1976-05-25 | The Procter And Gamble Company | Compositions and process for imparting renewable soil release finish to polyester-containing fabrics |
JPS5517823B2 (zh) | 1972-05-16 | 1980-05-14 | ||
US3958581A (en) | 1972-05-17 | 1976-05-25 | L'oreal | Cosmetic composition containing a cationic polymer and divalent metal salt for strengthening the hair |
GB1440913A (en) | 1972-07-12 | 1976-06-30 | Unilever Ltd | Detergent compositions |
ZA734721B (en) | 1972-07-14 | 1974-03-27 | Procter & Gamble | Detergent compositions |
CH575453A5 (zh) | 1972-08-01 | 1976-05-14 | Ciba Geigy Ag | |
GB1407997A (en) | 1972-08-01 | 1975-10-01 | Procter & Gamble | Controlled sudsing detergent compositions |
US3859125A (en) | 1972-10-10 | 1975-01-07 | Gilbreth Co | Soluble coated paper |
JPS5230973B2 (zh) | 1972-11-18 | 1977-08-11 | ||
CA1018893A (en) | 1972-12-11 | 1977-10-11 | Roger C. Birkofer | Mild thickened shampoo compositions with conditioning properties |
US3875300A (en) | 1972-12-18 | 1975-04-01 | Ortho Pharma Corp | Composition for sustained release of a medicament and method of using same |
US4051081A (en) | 1973-03-14 | 1977-09-27 | Bayer Aktiengesellschaft | Process for making hydrophilic polyurethane foams |
US3904543A (en) | 1973-08-07 | 1975-09-09 | Morton Norwich Products Inc | Detergent film |
US4033718A (en) | 1973-11-27 | 1977-07-05 | The Procter & Gamble Company | Photoactivated bleaching process |
US3954113A (en) | 1973-12-14 | 1976-05-04 | Colgate-Palmolive Company | Method of and means for cleaning hair between shampoos and methods for preparing such means |
US3964500A (en) | 1973-12-26 | 1976-06-22 | Lever Brothers Company | Lusterizing shampoo containing a polysiloxane and a hair-bodying agent |
US4217914A (en) | 1974-05-16 | 1980-08-19 | L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
US4422853A (en) | 1974-05-16 | 1983-12-27 | L'oreal | Hair dyeing compositions containing quaternized polymer |
US3959230A (en) | 1974-06-25 | 1976-05-25 | The Procter & Gamble Company | Polyethylene oxide terephthalate polymers |
US3929678A (en) | 1974-08-01 | 1975-12-30 | Procter & Gamble | Detergent composition having enhanced particulate soil removal performance |
US3943949A (en) | 1974-11-26 | 1976-03-16 | Johnson & Johnson | Flavored dental articles |
US4133779A (en) | 1975-01-06 | 1979-01-09 | The Procter & Gamble Company | Detergent composition containing semi-polar nonionic detergent and alkaline earth metal anionic detergent |
US4024078A (en) | 1975-03-31 | 1977-05-17 | The Procter & Gamble Company | Liquid detergent composition |
US4000093A (en) | 1975-04-02 | 1976-12-28 | The Procter & Gamble Company | Alkyl sulfate detergent compositions |
US4089945A (en) | 1975-06-30 | 1978-05-16 | The Procter & Gamble Company | Antidandruff shampoos containing metallic cation complex to reduce in-use sulfide odor |
US4197865A (en) | 1975-07-04 | 1980-04-15 | L'oreal | Treating hair with quaternized polymers |
AT365448B (de) | 1975-07-04 | 1982-01-11 | Oreal | Kosmetische zubereitung |
US4075118A (en) | 1975-10-14 | 1978-02-21 | The Procter & Gamble Company | Liquid detergent compositions containing a self-emulsified silicone suds controlling agent |
US4101457A (en) | 1975-11-28 | 1978-07-18 | The Procter & Gamble Company | Enzyme-containing automatic dishwashing composition |
US4349531A (en) | 1975-12-15 | 1982-09-14 | Hoffmann-La Roche Inc. | Novel dosage form |
US4033365A (en) | 1976-01-23 | 1977-07-05 | Johnson & Johnson | Flavored dental articles |
US4020156A (en) | 1976-02-13 | 1977-04-26 | Norda Incorporated | Controlled fragrance releasing crystal beads |
US4196190A (en) | 1976-07-19 | 1980-04-01 | Rohm And Haas Company | Acrylic hair setting resins having high resistance to moisture and rapid removability from the hair with shampoo |
JPS5315471A (en) | 1976-07-27 | 1978-02-13 | Hausu Shiyokuhin Kougiyou Kk | Container for frying noodles |
US4152416A (en) | 1976-09-17 | 1979-05-01 | Marra Dorothea C | Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness |
US4201824A (en) | 1976-12-07 | 1980-05-06 | Rhone-Poulenc Industries | Hydrophilic polyurethanes and their application as soil-release, anti-soil redeposition, and anti-static agents for textile substrates |
US4180558A (en) | 1978-08-21 | 1979-12-25 | Hoffmann-La Roche Inc. | Unit dosage forms |
US4234627A (en) | 1977-02-04 | 1980-11-18 | The Procter & Gamble Company | Fabric conditioning compositions |
FR2380359A1 (fr) | 1977-02-10 | 1978-09-08 | Rhone Poulenc Ind | Proteines filees et procede d'obtention desdites proteines |
US4149551A (en) | 1977-03-28 | 1979-04-17 | The Procter & Gamble Company | Method of conditioning hair using a flexible substrate |
US4260529A (en) | 1978-06-26 | 1981-04-07 | The Procter & Gamble Company | Detergent composition consisting essentially of biodegradable nonionic surfactant and cationic surfactant containing ester or amide |
US4228042A (en) | 1978-06-26 | 1980-10-14 | The Procter & Gamble Company | Biodegradable cationic surface-active agents containing ester or amide and polyalkoxy group |
FR2407980A1 (fr) | 1977-11-02 | 1979-06-01 | Rhone Poulenc Ind | Nouvelles compositions anti-salissure et anti-redeposition utilisables en detergence |
US4342813A (en) | 1978-03-14 | 1982-08-03 | Phillips Petroleum Company | Method for the production of a fused nonwoven fabric |
USD266829S (en) | 1978-04-10 | 1982-11-09 | Tdk Electronics Co., Ltd. | Packaging container |
EP0005035B1 (en) | 1978-04-19 | 1981-09-23 | Imperial Chemical Industries Plc | A method of preparing a tubular product by electrostatic spinning |
US4206196A (en) | 1978-06-06 | 1980-06-03 | The Procter & Gamble Company | Hair conditioning article and a method of its use |
DE2961223D1 (en) | 1978-06-20 | 1982-01-14 | Procter & Gamble | Washing and softening compositions and processes for making them |
US4272511A (en) | 1978-06-23 | 1981-06-09 | L'oreal | Cosmetic compositions for treating hair |
US4536361A (en) | 1978-08-28 | 1985-08-20 | Torobin Leonard B | Method for producing plastic microfilaments |
EP0008830A1 (en) | 1978-09-09 | 1980-03-19 | THE PROCTER & GAMBLE COMPANY | Suds-suppressing compositions and detergents containing them |
DE2964114D1 (en) | 1978-11-20 | 1982-12-30 | Procter & Gamble | Detergent composition having textile softening properties |
US4239660A (en) | 1978-12-13 | 1980-12-16 | The Procter & Gamble Company | Detergent composition comprising a hydrolyzable cationic surfactant and specific alkalinity source |
JPS5953038B2 (ja) | 1979-04-07 | 1984-12-22 | メルシャン株式会社 | サイクロデキストリンの製造法 |
US4286016A (en) | 1979-04-12 | 1981-08-25 | The Drackett Company | Pouch bleach |
US4340583A (en) | 1979-05-23 | 1982-07-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4663158A (en) | 1979-07-02 | 1987-05-05 | Clairol Incorporated | Hair conditioning composition containing cationic polymer and amphoteric surfactant and method for use |
US4507280A (en) | 1979-07-02 | 1985-03-26 | Clairol Incorporated | Hair conditioning composition and method for use |
US4323683A (en) | 1980-02-07 | 1982-04-06 | The Procter & Gamble Company | Process for making pyridinethione salts |
US4379753A (en) | 1980-02-07 | 1983-04-12 | The Procter & Gamble Company | Hair care compositions |
US4345080A (en) | 1980-02-07 | 1982-08-17 | The Procter & Gamble Company | Pyridinethione salts and hair care compositions |
USRE32713E (en) | 1980-03-17 | 1988-07-12 | Capsule impregnated fabric | |
US4514461A (en) | 1981-08-10 | 1985-04-30 | Woo Yen Kong | Fragrance impregnated fabric |
US4315965A (en) | 1980-06-20 | 1982-02-16 | Scott Paper Company | Method of making nonwoven fabric and product made thereby having both stick bonds and molten bonds |
US4529586A (en) | 1980-07-11 | 1985-07-16 | Clairol Incorporated | Hair conditioning composition and process |
JPS57146600A (en) | 1981-03-06 | 1982-09-10 | Japan Maize Prod | Recovery of gamma-cyclodextrin |
JPS5756562A (en) | 1980-09-20 | 1982-04-05 | Uni Charm Corp | Nonwoven fabric and production thereof |
US4470982A (en) | 1980-12-22 | 1984-09-11 | The Procter & Gamble Company | Shampoo compositions |
EP0066915B1 (en) | 1981-05-30 | 1987-11-11 | THE PROCTER & GAMBLE COMPANY | Detergent composition containing performance additive and copolymeric compatibilizing agent therefor |
US4378923A (en) | 1981-07-09 | 1983-04-05 | Nippon Kokan Kabushiki Kaisha | Binding device for elongated pipes |
JPS5821608A (ja) | 1981-07-31 | 1983-02-08 | Kenji Nakamura | パツク化粧シ−ト及びその製造方法 |
GR76237B (zh) | 1981-08-08 | 1984-08-04 | Procter & Gamble | |
US4364837A (en) | 1981-09-08 | 1982-12-21 | Lever Brothers Company | Shampoo compositions comprising saccharides |
AU8557482A (en) | 1981-09-22 | 1983-03-31 | West Point-Pepperell Inc. | Mattress covering |
GR77641B (zh) | 1981-09-25 | 1984-09-25 | Procter & Gamble | |
US4489574A (en) | 1981-11-10 | 1984-12-25 | The Procter & Gamble Company | Apparatus for highly efficient laundering of textiles |
EP0094959B1 (en) | 1981-11-27 | 1987-07-08 | TOROBIN, Leonard B | Method and apparatus for producing microfilaments |
LU83949A1 (fr) | 1982-02-16 | 1983-09-02 | Oreal | Composition destinee au traitement des matieres keratiniques contenant au moins un polymere cationique et au moins un latex anionique |
US4565647B1 (en) | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
US4483780A (en) | 1982-04-26 | 1984-11-20 | The Procter & Gamble Company | Detergent compositions containing polyglycoside and polyethoxylate detergent surfactants |
US4483779A (en) | 1982-04-26 | 1984-11-20 | The Procter & Gamble Company | Detergent compositions comprising polyglycoside and polyethoxylate surfactants and anionic fluorescer |
JPS58216109A (ja) | 1982-06-10 | 1983-12-15 | Pola Chem Ind Inc | 乾燥性膜状化粧料及び積層膜状化粧料 |
US4412934A (en) | 1982-06-30 | 1983-11-01 | The Procter & Gamble Company | Bleaching compositions |
US4483781A (en) | 1983-09-02 | 1984-11-20 | The Procter & Gamble Company | Magnesium salts of peroxycarboxylic acids |
US4489455A (en) | 1982-10-28 | 1984-12-25 | The Procter & Gamble Company | Method for highly efficient laundering of textiles |
US4415617A (en) | 1982-11-26 | 1983-11-15 | Trustee For David Roth | Base fabric for the manufacture of embroidery and lace and method of its preparation |
EP0111965B1 (en) | 1982-12-23 | 1989-07-26 | THE PROCTER & GAMBLE COMPANY | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
US4597898A (en) | 1982-12-23 | 1986-07-01 | The Proctor & Gamble Company | Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties |
DE3380307D1 (en) | 1982-12-23 | 1989-09-07 | Procter & Gamble | Ethoxylated amine polymers having clay soil removal/anti-redeposition properties useful in detergent compositions |
EP0112592B1 (en) | 1982-12-23 | 1989-08-23 | THE PROCTER & GAMBLE COMPANY | Zwitterionic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions |
US4891160A (en) | 1982-12-23 | 1990-01-02 | The Proctor & Gamble Company | Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties |
EP0116845B1 (en) | 1983-02-18 | 1989-12-20 | AlliedSignal Inc. | Consolidation of polyethylene fibrous networks |
US5135804A (en) | 1983-02-18 | 1992-08-04 | Allied-Signal Inc. | Network of polyethylene fibers |
US4540721A (en) | 1983-03-10 | 1985-09-10 | The Procter & Gamble Company | Method of providing odor to product container |
US4539135A (en) | 1983-06-01 | 1985-09-03 | Colgate Palmolive Co. | Perfume-containing carrier for laundry compositions |
US4635351A (en) | 1983-06-01 | 1987-01-13 | Motorola, Inc. | Method and machine for providing alternator pole pieces |
GB8321404D0 (en) | 1983-08-09 | 1983-09-07 | Interox Chemicals Ltd | Tablets |
US4507219A (en) | 1983-08-12 | 1985-03-26 | The Proctor & Gamble Company | Stable liquid detergent compositions |
US4637859A (en) * | 1983-08-23 | 1987-01-20 | The Procter & Gamble Company | Tissue paper |
US4727410A (en) | 1983-11-23 | 1988-02-23 | Cabot Technical Ceramics, Inc. | High density integrated circuit package |
GB8401875D0 (en) | 1984-01-25 | 1984-02-29 | Procter & Gamble | Liquid detergent compositions |
US4681704A (en) | 1984-03-19 | 1987-07-21 | The Procter & Gamble Company | Detergent composition containing semi-polar nonionic detergent alkaline earth metal anionic detergent and amino alkylbetaine detergent |
US4525524A (en) | 1984-04-16 | 1985-06-25 | The Goodyear Tire & Rubber Company | Polyester composition |
JPS60251906A (ja) | 1984-05-30 | 1985-12-12 | Dow Corning Kk | シリコ−ン消泡剤組成物の製造方法 |
US4634551A (en) | 1985-06-03 | 1987-01-06 | Procter & Gamble Company | Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain |
AU93078S (en) | 1984-07-02 | 1986-07-31 | Smith Kline And French Laboratories Ltd | A tablet |
CA1279452C (en) | 1984-09-18 | 1991-01-29 | Toa Nenryo Kogyo K.K. | Nonwoven fabric of water-soluble resin fibers |
US4790856A (en) | 1984-10-17 | 1988-12-13 | Colgate-Palmolive Company | Softening and anti-static nonionic detergent composition with sulfosuccinamate detergent |
US4579681A (en) | 1984-11-08 | 1986-04-01 | Gaf Corporation | Laundry detergent composition |
USRE34584E (en) | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
CA1261276A (en) | 1984-11-09 | 1989-09-26 | Mark B. Grote | Shampoo compositions |
JPS61132664A (ja) | 1984-11-27 | 1986-06-20 | 日本バイリーン株式会社 | ポリビニルアルコ−ル系繊維を含む不織布の製造方法 |
US4702857A (en) | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
GB8504733D0 (en) | 1985-02-23 | 1985-03-27 | Procter & Gamble Ltd | Detergent compositions |
FR2579192B1 (fr) | 1985-03-22 | 1987-10-09 | Valet Jean Marie | Dispositif de plissement et de pressage-lissage de capsule de surbouchage |
DE3685769T2 (de) | 1985-04-15 | 1993-01-21 | Procter & Gamble | Fluessige reinigungsmittel mit einer oberflaechenaktiven verbindung, einem proteolytischen enzym und borsaeure. |
US5094853A (en) | 1985-04-26 | 1992-03-10 | S. C. Johnson & Son, Inc. | Method of preparing a water-soluble stable arthropodicidally-active foam matrix |
DE3516425A1 (de) | 1985-05-08 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von formkoerpern und folien aus thermotropen polymeren sowie derart hergestellte formkoerper und folien |
US4652392A (en) | 1985-07-30 | 1987-03-24 | The Procter & Gamble Company | Controlled sudsing detergent compositions |
US4683001A (en) | 1985-08-23 | 1987-07-28 | Kimberly-Clark Corporation | One step dry-and-shine polishing cloth |
JPH0796493B2 (ja) | 1985-09-26 | 1995-10-18 | サンスタ−株式会社 | 浴用剤 |
JPH0653657B2 (ja) | 1985-09-26 | 1994-07-20 | サンスタ−株式会社 | 浴用剤 |
JPS6281432A (ja) | 1985-10-04 | 1987-04-14 | Shiseido Co Ltd | 水溶性高分子成形物 |
JPS6281462A (ja) | 1985-10-06 | 1987-04-14 | Katsuhiko Masuda | 耐熱・耐食性塗料用ベヒクル |
DE3536530A1 (de) | 1985-10-12 | 1987-04-23 | Basf Ag | Verwendung von pfropfcopolymerisaten aus polyalkylenoxiden und vinylacetat als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
JPS62156348A (ja) | 1985-12-28 | 1987-07-11 | 東燃料株式会社 | プルラン不織布 |
US4728455A (en) | 1986-03-07 | 1988-03-01 | Lever Brothers Company | Detergent bleach compositions, bleaching agents and bleach activators |
JPH0312343Y2 (zh) | 1986-03-24 | 1991-03-25 | ||
US4711730A (en) | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
JPS6346251A (ja) | 1986-08-13 | 1988-02-27 | Kao Corp | 冷水可溶性シ−ト状物 |
US4723362A (en) | 1986-08-25 | 1988-02-09 | Boerger Daniel A | Drive device for clippers |
US4892758A (en) | 1986-10-17 | 1990-01-09 | Kimberly-Clark Corporation | Cleaning product |
US4704233A (en) | 1986-11-10 | 1987-11-03 | The Procter & Gamble Company | Detergent compositions containing ethylenediamine-N,N'-disuccinic acid |
US4915854A (en) | 1986-11-14 | 1990-04-10 | The Procter & Gamble Company | Ion-pair complex conditioning agent and compositions containing same |
US5280079A (en) | 1986-11-20 | 1994-01-18 | Allied Colloids Limited | Absorbent products and their manufacture |
US4822613A (en) | 1986-12-15 | 1989-04-18 | S. C. Johnson & Son, Inc. | Water-soluble foamable insecticidally-active compositions |
JPS63156715A (ja) | 1986-12-19 | 1988-06-29 | Teisan Seiyaku Kk | 即効性の徐放化製剤 |
ES2018568B3 (es) | 1986-12-24 | 1991-04-16 | Rhone-Poulenc Chimie | Latex antirredepositable para el lavado de articulos textiles |
US4721580A (en) | 1987-01-07 | 1988-01-26 | The Procter & Gamble Company | Anionic end-capped oligomeric esters as soil release agents in detergent compositions |
US4976953A (en) | 1987-03-06 | 1990-12-11 | The Procter & Gamble Company | Skin conditioning/cleansing compositions containing propoxylated glycerol derivatives |
US5034421A (en) | 1988-12-13 | 1991-07-23 | Fuisz Pharmaceutical Ltd. | Moderated spun fibrous system and method of manufacture |
US4885107A (en) | 1987-05-08 | 1989-12-05 | The Procter & Gamble Company | Shampoo compositions |
US4798679A (en) | 1987-05-11 | 1989-01-17 | The Procter & Gamble Co. | Controlled sudsing stable isotropic liquid detergent compositions |
JP2569352B2 (ja) | 1987-06-12 | 1997-01-08 | 東レ株式会社 | 高強度水溶性ポリビニルアルコール系繊維およびその製造法 |
US4877896A (en) | 1987-10-05 | 1989-10-31 | The Procter & Gamble Company | Sulfoaroyl end-capped ester of oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles |
JPH01172319A (ja) | 1987-12-25 | 1989-07-07 | Nissan Setsuken Kk | 発泡性入浴剤組成物 |
US4787989A (en) | 1988-01-13 | 1988-11-29 | Gaf Corporation | Anionic soil release compositions |
US4882220A (en) | 1988-02-02 | 1989-11-21 | Kanebo, Ltd. | Fibrous structures having a durable fragrance |
US5208104A (en) | 1988-02-10 | 1993-05-04 | Toray Industries, Inc. | High-tenacity water-soluble polyvinyl alcohol fiber and process for producing the same |
GB8803114D0 (en) | 1988-02-11 | 1988-03-09 | Bp Chem Int Ltd | Bleach activators in detergent compositions |
EP0404806B1 (en) | 1988-03-14 | 1992-03-11 | Novo Nordisk A/S | Stabilized particulate composition |
GB8806016D0 (en) | 1988-03-14 | 1988-04-13 | Danochemo As | Encapsulated photoactivator dyes for detergent use |
US5120888A (en) * | 1988-04-14 | 1992-06-09 | Kimberly-Clark Corporation | Surface-segregatable, melt-extrudable thermoplastic composition |
DE68928836T2 (de) | 1988-04-14 | 1999-03-11 | Kimberly-Clark Corp., Neenah, Wis. | Oberflächen-modifizierte, schmelz-extrusionsfähige thermoplastische Zusammensetzung |
JPH01313418A (ja) | 1988-06-13 | 1989-12-18 | Shin Etsu Chem Co Ltd | シート状浴用材 |
US4978471A (en) | 1988-08-04 | 1990-12-18 | Dow Corning Corporation | Dispersible silicone wash and rinse cycle antifoam formulations |
US4983316A (en) | 1988-08-04 | 1991-01-08 | Dow Corning Corporation | Dispersible silicone antifoam formulations |
DE3826670C2 (de) | 1988-08-05 | 1994-11-17 | Framatome Connectors Int | Flachkontaktsteckhülse |
US5444113A (en) | 1988-08-08 | 1995-08-22 | Ecopol, Llc | End use applications of biodegradable polymers |
US4968451A (en) | 1988-08-26 | 1990-11-06 | The Procter & Gamble Company | Soil release agents having allyl-derived sulfonated end caps |
JPH0275650A (ja) | 1988-09-12 | 1990-03-15 | Kuraray Co Ltd | 水溶性フイルム |
US4911852A (en) | 1988-10-07 | 1990-03-27 | The Procter & Gamble Company | Liquid laundry detergent with curable amine functional silicone for fabric wrinkle reduction |
IT1227383B (it) | 1988-11-22 | 1991-04-08 | Promo Int Srl | Prodotto per la detersione cutanea, per l'igiene e la pulizia. |
JPH0753349Y2 (ja) | 1988-12-15 | 1995-12-06 | 三洋電機株式会社 | マイクロフォン装置 |
US4973422A (en) | 1989-01-17 | 1990-11-27 | The Procter & Gamble Company | Perfume particles for use in cleaning and conditioning compositions |
US5061481A (en) | 1989-03-20 | 1991-10-29 | Kobayashi Kose Co., Ltd. | Cosmetic composition having acryl-silicone graft copolymer |
ATE124422T1 (de) | 1989-04-12 | 1995-07-15 | Procter & Gamble | Festes verbraucherprodukt, welches feinteilige cyclodextrin-komplexe enthält. |
GB8908416D0 (en) | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
JPH02280771A (ja) | 1989-04-24 | 1990-11-16 | Descente Ltd | 経皮薬物徐放繊維及び経皮薬物徐放繊維で構成した被服素材 |
US5110678A (en) | 1989-04-27 | 1992-05-05 | Kuraray Company Limited | Synthetic polyvinyl alcohol fiber and process for its production |
US5055384A (en) | 1989-05-10 | 1991-10-08 | Agfa Gevaert Aktiengesellschaft | Granulated photographic fixative and its preparation |
US4956447A (en) | 1989-05-19 | 1990-09-11 | The Procter & Gamble Company | Rinse-added fabric conditioning compositions containing fabric sofening agents and cationic polyester soil release polymers and preferred cationic soil release polymers therefor |
JPH0340879A (ja) | 1989-07-07 | 1991-02-21 | Kuraray Co Ltd | 薬効性繊維及びその製造方法 |
US5166276A (en) | 1989-07-12 | 1992-11-24 | Mitsubishi Petrochemical Company Ltd. | Polymer for hair-care products |
DE3923144A1 (de) | 1989-07-13 | 1991-01-24 | Wolff Walsrode Ag | Verfahren zur herstellung von hydrokolloidmischungen mit verbesserter dispergierbarkeit |
FR2650180B1 (fr) | 1989-07-31 | 1995-03-03 | Chisso Corp | Procede de production d'une feuille facilement soluble dans l'eau a base d'acide hyaluronique ou de hyaluronate et feuille ainsi obtenue |
US5100658A (en) | 1989-08-07 | 1992-03-31 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
US5106609A (en) | 1990-05-01 | 1992-04-21 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
US5104646A (en) | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
DE3927254A1 (de) | 1989-08-18 | 1991-02-21 | Reifenhaeuser Masch | Verfahren und spinnduesenaggregat fuer die herstellung von kunststoff-faeden und/oder kunststoff-fasern im zuge der herstellung von einem spinnvlies aus thermoplastischem kunststoff |
JPH0742019B2 (ja) | 1989-09-05 | 1995-05-10 | 株式会社東京機械製作所 | 輪転機における料紙走行張力および料紙切断位置の制御装置 |
JPH03101618A (ja) | 1989-09-13 | 1991-04-26 | Kuraray Co Ltd | 薬効性繊維及びその製造法 |
NZ235372A (en) * | 1989-10-10 | 1992-05-26 | Wrigley W M Jun Co | Slow release delivery system made by fibre melt spinning techniques producing a fibre about 1mm diameter, exterior is substantially wall material and core mostly active agent dispersed through the fibre material which is porous overall |
GB8927361D0 (en) | 1989-12-04 | 1990-01-31 | Unilever Plc | Liquid detergents |
JP2627344B2 (ja) | 1990-01-23 | 1997-07-02 | 工業技術院長 | 水溶性アルギン繊維及びその製造方法 |
GB9003017D0 (en) | 1990-02-09 | 1990-04-04 | Euro Celtique Sa | Pharmaceutical formulation |
GB9003741D0 (en) | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
CA2013485C (en) | 1990-03-06 | 1997-04-22 | John Michael Gardlik | Solid consumer product compositions containing small particle cyclodextrin complexes |
EP0454358A3 (en) | 1990-04-23 | 1993-01-13 | Merck & Co. Inc. | Polysaccharide fibers |
US5100657A (en) | 1990-05-01 | 1992-03-31 | The Procter & Gamble Company | Clean conditioning compositions for hair |
US6406797B1 (en) | 1990-05-17 | 2002-06-18 | Cryovac, Inc. | Coextruded packaging film |
DE4016002A1 (de) | 1990-05-18 | 1991-11-21 | Basf Ag | Verwendung von wasserloeslichen oder wasserdispergierbaren gepfropften proteinen als zusatz zu wasch- und reinigungsmitteln |
DE69125310T2 (de) | 1990-05-21 | 1997-07-03 | Unilever Nv | Bleichmittelaktivierung |
US5220033A (en) | 1990-06-13 | 1993-06-15 | Shin-Etsu Chemical Co., Ltd. | Siloxane compounds and their preparation |
EP0474173B1 (en) | 1990-09-04 | 1996-04-10 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Biodegradable melt-molded articles and laminates derived therefrom, and their use |
SK25293A3 (en) | 1990-09-28 | 1994-01-12 | Procter & Gamble | Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions |
WO1992006603A1 (en) | 1990-10-10 | 1992-04-30 | Fuisz Technologies Ltd. | Taste masked medicated floss |
USD351345S (en) | 1990-10-30 | 1994-10-11 | Chesapeake Packaging Company | Food container |
JP3362040B2 (ja) | 1990-11-30 | 2003-01-07 | イーストマン ケミカル カンパニー | 脂肪族−芳香族コポリエステル |
DE4105095A1 (de) | 1991-02-19 | 1992-08-20 | Linde Ag | Verfahren zur prozesssteuerung in spaltoefen zur olefinherstellung |
GB9108136D0 (en) | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
US5102129A (en) | 1991-05-14 | 1992-04-07 | Roberts Neil H | Game apparatus |
NZ242597A (en) | 1991-05-14 | 1995-07-26 | Grace W R & Co | Co-extruded water soluble laminated polymeric film and methods of extruding it |
USD334420S (en) | 1991-05-14 | 1993-03-30 | Ecolab Inc. | Chemical detergent block |
EP0513692A1 (en) | 1991-05-17 | 1992-11-19 | Air Products And Chemicals, Inc. | Water soluble multilayer film for packaging alkaline materials |
US5261426A (en) | 1991-05-30 | 1993-11-16 | Creative Products Resource Associates, Ltd. | Hydrophilic foam pad for hair styling |
EP0522817A1 (en) | 1991-07-11 | 1993-01-13 | Unilever Plc | Process for preparing manganese complexes |
GB9118242D0 (en) | 1991-08-23 | 1991-10-09 | Unilever Plc | Machine dishwashing composition |
ES2167319T3 (es) | 1991-10-07 | 2002-05-16 | Genencor Int | Granulo que contiene una enzima revestida. |
JPH05344873A (ja) | 1991-10-09 | 1993-12-27 | Nippon Green Ueebu Kk | 水に可溶ないちょう葉抽出物製剤の製造方法 |
WO1993007260A1 (en) | 1991-10-10 | 1993-04-15 | Genencor International, Inc. | Process for dust-free enzyme manufacture |
GB9123422D0 (en) | 1991-11-05 | 1991-12-18 | Unilever Plc | Detergent composition |
GB9124581D0 (en) | 1991-11-20 | 1992-01-08 | Unilever Plc | Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions |
US5153161A (en) | 1991-11-26 | 1992-10-06 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
EP0544490A1 (en) | 1991-11-26 | 1993-06-02 | Unilever Plc | Detergent bleach compositions |
US5194416A (en) | 1991-11-26 | 1993-03-16 | Lever Brothers Company, Division Of Conopco, Inc. | Manganese catalyst for activating hydrogen peroxide bleaching |
PL170554B1 (pl) | 1991-12-17 | 1996-12-31 | Fuisz Technologies Ltd | Sposób wytwarzania kompozycji przeciwwrzodowej PL PL PL |
CA2070589C (en) | 1991-12-19 | 2000-11-28 | Kimberly-Clark Corporation | Method of preparing a nonwoven web of poly (vinyl alcohol) fibers |
CA2085642A1 (en) | 1991-12-20 | 1993-06-21 | Ronald Hage | Bleach activation |
GB9127060D0 (en) | 1991-12-20 | 1992-02-19 | Unilever Plc | Bleach activation |
US5427711A (en) | 1991-12-29 | 1995-06-27 | Kao Corporation | Synthesized inorganic ion exchange material and detergent composition containing the same |
JPH05329276A (ja) | 1992-05-20 | 1993-12-14 | Mitsui & Co Ltd | 水溶性有色バルーン |
JP3040879B2 (ja) | 1992-05-27 | 2000-05-15 | 株式会社奥村組 | 建築材料の吸音率の測定方法および測定装置 |
US5518730A (en) | 1992-06-03 | 1996-05-21 | Fuisz Technologies Ltd. | Biodegradable controlled release flash flow melt-spun delivery system |
EP0646164B1 (en) | 1992-06-15 | 1997-05-07 | The Procter & Gamble Company | Liquid laundry detergent compositions with silicone antifoam agent |
US5256779A (en) | 1992-06-18 | 1993-10-26 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
JP3047145B2 (ja) | 1992-06-29 | 2000-05-29 | 東邦化学工業株式会社 | 両性界面活性化合物 |
US5284944A (en) | 1992-06-30 | 1994-02-08 | Lever Brothers Company, Division Of Conopco, Inc. | Improved synthesis of 1,4,7-triazacyclononane |
EP0825254B1 (en) | 1992-07-02 | 2001-10-04 | Novozymes A/S | Alkalophilic Bacillus sp. AC13 and xylanase obtainable therefrom |
WO1994002377A1 (en) | 1992-07-20 | 1994-02-03 | E.I. Du Pont De Nemours And Company | Cellular-air water-soluble film packaging |
GB2270030B (en) | 1992-08-19 | 1996-06-19 | Courtaulds Plc | Method of producing fibre or film |
WO1994004656A2 (en) | 1992-08-20 | 1994-03-03 | Kao Corp | ALIQUOTE PACKAGING DETERGENT USING WATER-SOLUBLE FILM |
JP3398183B2 (ja) | 1992-08-20 | 2003-04-21 | 花王株式会社 | 水溶性フィルムを用いた分包包装洗剤 |
US5280117A (en) | 1992-09-09 | 1994-01-18 | Lever Brothers Company, A Division Of Conopco, Inc. | Process for the preparation of manganese bleach catalyst |
US5501238A (en) | 1993-01-11 | 1996-03-26 | Von Borstel; Reid W. | Cigarette filter containing a humectant |
US5691015A (en) | 1993-01-25 | 1997-11-25 | Aicello Chemical Co., Ltd. | Composite film bags for packaging |
DE69409683T2 (de) | 1993-02-02 | 1998-09-17 | Tokai Pulp Kk | Wärmeempfindlich klebendes, wasserlösliches oder wasserdispergierbares Papier, und Verfahren zu seiner Herstellung |
ZA94676B (en) | 1993-02-03 | 1994-08-03 | Rohm & Haas | Reduction of microfoam in spray-applied waterborne composition. |
US5538735A (en) | 1993-02-19 | 1996-07-23 | Ahn; Sam S. | Method of making a drug delivery system using hollow fibers |
GB2275685B (en) | 1993-03-03 | 1997-04-30 | Johnson & Johnson Medical | Water soluble wound dressing materials |
US5429628A (en) | 1993-03-31 | 1995-07-04 | The Procter & Gamble Company | Articles containing small particle size cyclodextrin for odor control |
JPH072272A (ja) | 1993-06-15 | 1995-01-06 | Nippon Chibagaigii Kk | 水溶性フィルムを用いた薬剤包装材料及び包装容器 |
US5651976A (en) | 1993-06-17 | 1997-07-29 | The United States Of America As Represented By The Secretary Of The Navy | Controlled release of active agents using inorganic tubules |
US5409703A (en) | 1993-06-24 | 1995-04-25 | Carrington Laboratories, Inc. | Dried hydrogel from hydrophilic-hygroscopic polymer |
US5415807A (en) | 1993-07-08 | 1995-05-16 | The Procter & Gamble Company | Sulfonated poly-ethoxy/propoxy end-capped ester oligomers suitable as soil release agents in detergent compositions |
US5520924A (en) | 1993-07-09 | 1996-05-28 | Mizu Systems Corporation | Methods and articles for administering drug to the oral cavity |
EP0636716B1 (en) | 1993-07-29 | 1999-01-20 | Kuraray Co., Ltd. | Water soluble polyvinyl alcohol-based fiber |
US5391368A (en) | 1993-08-09 | 1995-02-21 | Revlon Consumer Products Corporation | Hair styling shampoos |
US5470492A (en) | 1993-09-10 | 1995-11-28 | The Procter & Gamble Company | Dryer-activated fabric conditioning articles with soft polyester substrate |
JP3357453B2 (ja) | 1993-09-10 | 2002-12-16 | 花王株式会社 | 液体柔軟仕上剤組成物並びに新規第4級アンモニウム塩並びに該塩の製造法 |
JP2923181B2 (ja) | 1993-09-20 | 1999-07-26 | フジックス株式会社 | 高濃度のカルシウムを含有する水溶性粉末およびその製造方法 |
US5457895A (en) | 1993-10-01 | 1995-10-17 | R. P. Scherer Corporation | Method of identifying freeze-dried dosage forms |
BR9407834A (pt) | 1993-10-14 | 1997-05-13 | Procter & Gamble | Composições de limpeza contendo protease |
ATE174389T1 (de) | 1993-10-15 | 1998-12-15 | Kuraray Co | Wasserlösliche, schmelzklebende binderfasern aus polyvinylalkohol, diese fasern enthaltende vliesstoffe und verfahren zur herstellung dieser faser und dieses vliesstoffes |
AU5616094A (en) | 1993-11-22 | 1995-06-13 | Chemia Corporation | Air freshener and moth and insect repellant products |
US5470424A (en) | 1993-11-30 | 1995-11-28 | Kimberly-Clark Corporation | Process for forming liquid impermeable sheet material having a fibrous surface and products formed thereby |
JPH07173724A (ja) | 1993-12-20 | 1995-07-11 | Kuraray Co Ltd | 水溶性ポリビニルアルコール系バインダー繊維とその熱圧着法 |
GB9403911D0 (en) | 1994-03-01 | 1994-04-20 | Univ Manchester | Porous films |
USD357115S (en) | 1994-04-21 | 1995-04-11 | Abrams Richard W | Contact lens package |
USD358025S (en) | 1994-04-21 | 1995-05-09 | Martin W Anthony | Contact lens package |
US5506201A (en) | 1994-04-29 | 1996-04-09 | International Flavors & Fragrances Inc. | Formulation of a fat surfactant vehicle containing a fragrance |
PE6995A1 (es) | 1994-05-25 | 1995-03-20 | Procter & Gamble | Composicion que comprende un polimero de polialquilenoamina etoxilado propoxilado como agente de separacion de sucio |
WO1995034628A1 (en) | 1994-06-13 | 1995-12-21 | Unilever N.V. | Bleach activation |
EP0765421B1 (en) * | 1994-06-17 | 2000-05-03 | The Procter & Gamble Company | Lotioned tissue paper |
GB9414305D0 (en) | 1994-07-15 | 1994-09-07 | C V Lab Ltd | Alginate fibre, process for the preparation thereof and use |
GB9415720D0 (en) | 1994-08-03 | 1994-09-21 | Environmental Polymers Ltd | Extrusion and moulding apparatus and method |
US5470653A (en) | 1994-08-05 | 1995-11-28 | Isolyser Company, Inc. | Disposable mop heads |
US5705183A (en) | 1994-11-16 | 1998-01-06 | Phillips Company | Cotton candy coated medication and a method for making and administering the same |
US5968881A (en) | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
JPH10513214A (ja) | 1995-02-02 | 1998-12-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | コバルトキレート化触媒を含む自動皿洗い組成物 |
US5534179A (en) | 1995-02-03 | 1996-07-09 | Procter & Gamble | Detergent compositions comprising multiperacid-forming bleach activators |
DE19510825A1 (de) | 1995-03-24 | 1996-09-26 | Henkel Kgaa | Korrosionsschützender Reiniger für verzinnten Stahl |
US5533636A (en) | 1995-03-28 | 1996-07-09 | Reiker; Kenneth H. | Reversible escutcheon |
US5682618A (en) | 1995-04-03 | 1997-11-04 | Minnesota Mining And Manufacturing Company | Viral resistant seam for protective apparel, and method of manufacturing same |
IN187510B (zh) | 1995-05-22 | 2002-05-11 | Kuraray Co | |
JPH08325133A (ja) | 1995-05-26 | 1996-12-10 | Tokuyasu:Kk | 洗浄保湿剤 |
CN1138091A (zh) | 1995-06-14 | 1996-12-18 | 曹德胜 | 一次性肥皂纸及制造方法 |
US5673576A (en) | 1995-06-14 | 1997-10-07 | Chen; Carson Ko-Sheng | Locking device for cars |
US5597936A (en) | 1995-06-16 | 1997-01-28 | The Procter & Gamble Company | Method for manufacturing cobalt catalysts |
CN1192774A (zh) | 1995-06-16 | 1998-09-09 | 普罗格特-甘布尔公司 | 包含钴催化剂的自动洗餐具用组合物 |
DE69625549T2 (de) | 1995-06-27 | 2003-05-15 | Kao Corp., Tokio/Tokyo | Pflaster mit wasserlöslicher Klebeschicht |
BR9609893A (pt) | 1995-08-07 | 1999-05-25 | Unilever Nv | Composição liquida de limpeza e processo para a indução de uma fase lamelar numa composição |
USD378180S (en) | 1995-08-14 | 1997-02-25 | Packaging Corporation Of America | Catering tray |
WO1997009472A1 (fr) | 1995-09-05 | 1997-03-13 | Kuraray Co., Ltd. | Fibres a base d'alcool de polyvinyle ayant une excellente resistance a l'eau bouillante et procede de production |
US5849378A (en) | 1995-09-07 | 1998-12-15 | Taylor Packaging Corporation | Vertical right angle package hinge |
US5576282A (en) | 1995-09-11 | 1996-11-19 | The Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
CZ80798A3 (cs) | 1995-09-18 | 1998-09-16 | The Procter & Gamble Company | Částice pro praní a granulovaný detergentní prostředek je obsahující |
JP4121556B2 (ja) | 1995-09-18 | 2008-07-23 | ザ プロクター アンド ギャンブル カンパニー | デリバリーシステム |
JP3474981B2 (ja) | 1995-10-11 | 2003-12-08 | 花王株式会社 | 浴用剤 |
HU226870B1 (en) | 1995-10-23 | 2010-01-28 | Clopay Plastic Prod Co | Product, apparatus and process for strip lamination of a polymer film and nonwoven or woven webs |
US5703034A (en) | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
GB9522314D0 (en) | 1995-11-01 | 1996-01-03 | Bristol Myers Squibb Co | Water soluble films |
US5750122A (en) | 1996-01-16 | 1998-05-12 | The Procter & Gamble Company | Compositions for treating hair or skin |
US5674478A (en) | 1996-01-12 | 1997-10-07 | The Procter & Gamble Company | Hair conditioning compositions |
AT403919B (de) | 1996-02-02 | 1998-06-25 | Danubia Petrochem Polymere | Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen |
JP3595057B2 (ja) * | 1996-02-09 | 2004-12-02 | 花王株式会社 | シート状化粧料組成物 |
US6365142B1 (en) | 1996-02-28 | 2002-04-02 | The Procter & Gamble Company | Hair conditioning compositions which provide superior wet hair feel attributes and which are substantially free of quaternary ammonium compounds |
US5840675A (en) | 1996-02-28 | 1998-11-24 | The Procter And Gamble Company | Controlled released fabric care article |
DE19607851A1 (de) | 1996-03-01 | 1997-09-04 | Bayer Ag | Polyfunktionelle Reaktivfarbstoffe |
EP0824563B1 (en) | 1996-03-04 | 2005-06-15 | General Electric Company | Silicone aminopolyalkyleneoxide block copolymers |
US6022844A (en) | 1996-03-05 | 2000-02-08 | The Procter & Gamble Company | Cationic detergent compounds |
US5672576A (en) | 1996-03-15 | 1997-09-30 | The Procter & Gamble Co. | High lather styling shampoos |
ES2216128T3 (es) | 1996-03-22 | 2004-10-16 | THE PROCTER & GAMBLE COMPANY | Sistema de liberacion que tiene una zeolita cargada con una barrera de liberacion. |
US6245732B1 (en) | 1996-03-22 | 2001-06-12 | The Procter Gamble Co. | Delivery system having release inhibitor loaded zeolite and method for making same |
US5756438A (en) | 1996-03-26 | 1998-05-26 | The Andrew Jergens Company | Personal cleansing product |
US5958870A (en) | 1996-04-01 | 1999-09-28 | The Procter & Gamble Company | Betaine ester compounds of active alcohols |
US5976454A (en) | 1996-04-01 | 1999-11-02 | Basf Aktiengesellschaft | Process for producing open-celled, inorganic sintered foam products |
JP3525174B2 (ja) | 1996-04-10 | 2004-05-10 | チッソ株式会社 | 水崩壊性布帛及び不織布 |
PH11997056158B1 (en) | 1996-04-16 | 2001-10-15 | Procter & Gamble | Mid-chain branched primary alkyl sulphates as surfactants |
EG21623A (en) | 1996-04-16 | 2001-12-31 | Procter & Gamble | Mid-chain branced surfactants |
EG22088A (en) | 1996-04-16 | 2002-07-31 | Procter & Gamble | Alkoxylated sulfates |
TR199802223T2 (xx) | 1996-05-03 | 1999-02-22 | The Procter & Gamble Company | Katyonik y�zey aktif maddeler ve de�i�tirilmi� poliamin kir da��t�c�lar i�eren deterjan bile�imleri. |
MA25183A1 (fr) | 1996-05-17 | 2001-07-02 | Arthur Jacques Kami Christiaan | Compositions detergentes |
JPH101824A (ja) | 1996-06-11 | 1998-01-06 | Kuraray Co Ltd | 徐放性複合繊維 |
JP3741170B2 (ja) | 1996-06-21 | 2006-02-01 | チッソ株式会社 | 水崩壊性複合繊維及び不織布、吸収性物品 |
TW399096B (en) | 1996-07-03 | 2000-07-21 | Kao Corp | The sheet-like article for laundry |
US6093691A (en) | 1996-08-19 | 2000-07-25 | The Procter & Gamble Company | Rinse added fabric softening compositions and method of use for the delivery of fragrance derivatives |
US6147037A (en) | 1996-08-19 | 2000-11-14 | The Procter & Gamble Company | Fragrance delivery systems |
US6028016A (en) * | 1996-09-04 | 2000-02-22 | Kimberly-Clark Worldwide, Inc. | Nonwoven Fabric Substrates Having a Durable Treatment |
US8828432B2 (en) | 1996-10-28 | 2014-09-09 | General Mills, Inc. | Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles |
US6103678A (en) | 1996-11-07 | 2000-08-15 | The Procter & Gamble Company | Compositions comprising a perfume and an amino-functional polymer |
JPH10158700A (ja) * | 1996-11-26 | 1998-06-16 | Kao Corp | 洗浄剤 |
US6150322A (en) | 1998-08-12 | 2000-11-21 | Shell Oil Company | Highly branched primary alcohol compositions and biodegradable detergents made therefrom |
US6093856A (en) | 1996-11-26 | 2000-07-25 | The Procter & Gamble Company | Polyoxyalkylene surfactants |
JP3828217B2 (ja) | 1996-12-03 | 2006-10-04 | 株式会社クラレ | ポリビニルアルコール系繊維及びその製造方法 |
ZA9711269B (en) | 1996-12-19 | 1998-06-23 | Procter & Gamble | Dryer added fabric softening compositions and method of use for the delivery of fragrance derivatives. |
WO1998026758A2 (en) | 1996-12-19 | 1998-06-25 | Rhodia Inc. | Concentrated surfactant mixtures |
ZA9711272B (en) | 1996-12-19 | 1998-06-23 | Procter & Gamble | Dryer-activated fabric conditioning and antistatic compositions with improved perfume longevity. |
US5990065A (en) | 1996-12-20 | 1999-11-23 | The Procter & Gamble Company | Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution |
US5783540A (en) | 1996-12-23 | 1998-07-21 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets delivering a rinse aid benefit |
DE69739959D1 (de) | 1996-12-23 | 2010-09-23 | Givaudan Nederland Services B | Parfüm enthaltende zusammensetzungen |
US6210600B1 (en) | 1996-12-23 | 2001-04-03 | Lever Brothers Company, Division Of Conopco, Inc. | Rinse aid compositions containing scale inhibiting polymers |
EP0958342B1 (en) | 1996-12-31 | 2003-07-09 | The Procter & Gamble Company | Thickened, highly aqueous liquid detergent compositions |
GB2321900A (en) | 1997-02-11 | 1998-08-12 | Procter & Gamble | Cationic surfactants |
AR011665A1 (es) | 1997-02-11 | 2000-08-30 | Procter & Gamble | Detergente o composicion de limpieza o componente de la misma que comprende agentes tensioactivos y un blanqueador liberador de oxigeno |
WO1998035004A1 (en) | 1997-02-11 | 1998-08-13 | The Procter & Gamble Company | Solid detergent compositions |
AU6152098A (en) | 1997-02-11 | 1998-08-26 | Procter & Gamble Company, The | Liquid cleaning composition |
AR012033A1 (es) | 1997-02-11 | 2000-09-27 | Procter & Gamble | Composicion detergente o componente que contiene un surfactante cationico |
DE19705364C2 (de) | 1997-02-12 | 1998-12-17 | Ott Kg Lewa | Verfahren und Vorrichtung zur Sprühverteilung mittels Ultraschall |
US5858959A (en) | 1997-02-28 | 1999-01-12 | Procter & Gamble Company | Delivery systems comprising zeolites and a starch hydrolysate glass |
JP3138765B2 (ja) | 1997-03-10 | 2001-02-26 | 小林製薬株式会社 | 水解性清掃布 |
JP3103839B2 (ja) | 1997-03-14 | 2000-10-30 | トスコ株式会社 | 吸水性ポリウレタンフォーム及びその製造方法 |
CN1255160A (zh) * | 1997-03-20 | 2000-05-31 | 普罗格特-甘布尔公司 | 与具有一种超级吸收材料的清洁用具一起使用的洗涤剂组合物和包括这二者的成套用具 |
US6037319A (en) | 1997-04-01 | 2000-03-14 | Dickler Chemical Laboratories, Inc. | Water-soluble packets containing liquid cleaning concentrates |
US6417156B1 (en) | 1997-04-09 | 2002-07-09 | R. J. Reynolds Tobacco Company | Anti-static article |
EP0872544A1 (en) | 1997-04-14 | 1998-10-21 | The Procter & Gamble Company | Dry effervescent granules and granular compositions comprising the same |
USD399260S (en) | 1997-04-17 | 1998-10-06 | Roland Thimote | Traffic sign system |
US5911224A (en) | 1997-05-01 | 1999-06-15 | Filtrona International Limited | Biodegradable polyvinyl alcohol tobacco smoke filters, tobacco smoke products incorporating such filters, and methods and apparatus for making same |
USD416103S (en) | 1997-05-02 | 1999-11-02 | M. Anaam Hashmi | Front surfaces of a set of vehicle lenses |
USD398847S (en) | 1997-05-23 | 1998-09-29 | Redex Packaging Corp. | Food package |
US6316397B1 (en) | 1997-06-27 | 2001-11-13 | The Procter & Gamble Co. | Pro-fragrance linear acetals and ketals |
USD407640S (en) | 1997-07-18 | 1999-04-06 | S. C. Johnson & Son, Inc. | Dispenser package |
AU8124398A (en) | 1997-07-21 | 1999-02-16 | Procter & Gamble Company, The | Process for making alkylbenzenesulfonate surfactants from alcohols and products thereof |
PH11998001775B1 (en) | 1997-07-21 | 2004-02-11 | Procter & Gamble | Improved alkyl aryl sulfonate surfactants |
ID26172A (id) | 1997-07-21 | 2000-11-30 | Procter & Gamble | Proses pembuatan surfaktan-surfaktan alkilbenzenasulfonat dan produk-produknya |
AU8124498A (en) | 1997-07-21 | 1999-02-16 | Procter & Gamble Company, The | Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof |
KR100391190B1 (ko) | 1997-07-21 | 2003-07-12 | 더 프록터 앤드 갬블 캄파니 | 개선된 알킬벤젠설포네이트 계면활성제 |
DE69814870T2 (de) | 1997-07-21 | 2004-05-06 | The Procter & Gamble Company, Cincinnati | Reinigungsmittelzusammensetzungen mit kristallinitätsstörenden tensiden |
EP0998516A1 (en) | 1997-08-02 | 2000-05-10 | The Procter & Gamble Company | Ether-capped poly(oxyalkylated) alcohol surfactants |
ATE286867T1 (de) | 1997-08-08 | 2005-01-15 | Procter & Gamble | Verfahren zur herstellung von oberflächaktiven verbindungen mittels adsorptiven trennung |
USD408223S (en) | 1997-08-29 | 1999-04-20 | La Bourguignonne | Baking dish with collar |
US6420625B1 (en) | 1997-09-12 | 2002-07-16 | Kimberly-Clark Worldwide, Inc. | Breathable, liquid-impermeable, apertured film/nonwoven laminate and process for making same |
AU739044B2 (en) | 1997-09-15 | 2001-10-04 | Procter & Gamble Company, The | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
US6010719A (en) | 1997-09-16 | 2000-01-04 | Universiteit Gent | Freeze-dried disintegrating tablets |
US6042792A (en) | 1997-09-18 | 2000-03-28 | International Flavors & Fragrances Inc. | Apparatus for preparing a solid phase microparticulate composition |
US6645479B1 (en) | 1997-09-18 | 2003-11-11 | International Flavors & Fragrances Inc. | Targeted delivery of active/bioactive and perfuming compositions |
US6074997A (en) | 1997-09-26 | 2000-06-13 | The Andrew Jergens Company | Method of manufacturing an improved cleansing bar with filler and excellent aesthetic properties |
JP3611456B2 (ja) | 1997-09-30 | 2005-01-19 | 日研化学株式会社 | テオフィリン徐放性錠剤 |
CN1083499C (zh) | 1997-10-07 | 2002-04-24 | 可乐丽股份有限公司 | 聚乙烯醇类阻燃纤维 |
TR200000914T2 (tr) | 1997-10-07 | 2000-08-21 | The Procter & Gamble Company | Çok düşük seviyede hidrofilik, kesme kuvvetiyle incelen polimer içeren, sert yüzeyler için deterjan bileşimi |
US6106875A (en) | 1997-10-08 | 2000-08-22 | Givaudan Roure (International) Sa | Method of encapsulating flavors and fragrances by controlled water transport into microcapsules |
WO1999018928A1 (en) | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Personal cleansing compositions comprising mid-chain branched surfactants |
US5863887A (en) | 1997-12-01 | 1999-01-26 | Precision Fabrics Group, Inc. | Laundry compositions having antistatic and fabric softening properties, and laundry detergent sheets containing the same |
CN1088356C (zh) | 1997-12-11 | 2002-07-31 | 华健医药科技股份有限公司 | 拔粉刺贴片 |
US6106849A (en) | 1998-01-21 | 2000-08-22 | Dragoco Gerberding & Co. Ag | Water soluble dry foam personal care product |
DE19803362A1 (de) | 1998-01-29 | 1999-08-05 | Sartorius Gmbh | Geschäumte poröse Membranen aus thermoplastischen Polymeren sowie Verfahren und Vorrichtung zu ihrer Herstellung |
US6130193A (en) | 1998-02-06 | 2000-10-10 | Precision Fabrics Group, Inc. | Laundry detergent compositions containing silica for laundry detergent sheets |
SG93823A1 (en) | 1998-02-13 | 2003-01-21 | Givaudan Roure Int | Aryl-acrylic acid esters |
DK1056739T3 (da) | 1998-02-24 | 2003-06-02 | Procter & Gamble | Hidtil ukendte cykliske pro-parfumer med modificeret frigivelseshastighed af duftstofråmaterialealkohol |
WO1999051715A1 (en) | 1998-04-06 | 1999-10-14 | The Procter & Gamble Company | Electrostatically coated non-particulate detergent product |
NO991661L (no) | 1998-04-09 | 1999-10-11 | Nat Starch Chem Invest | Ikke-ionisk derivatiserte stivelser og deres anvendelse i ikke-aerosol haarkosmetiske sammensetninger med lav VOC |
US6479682B1 (en) | 1998-04-20 | 2002-11-12 | Givaudan Sa | Compounds having protected hydroxy groups |
ES2273468T3 (es) | 1998-04-20 | 2007-05-01 | Givaudan Sa | Compuestos con grupos hidroxilo protegidos. |
USD418750S (en) | 1998-04-21 | 2000-01-11 | The Mead Corporation | Carton |
AU3048199A (en) | 1998-04-23 | 1999-11-16 | Procter & Gamble Company, The | Encapsulated perfume particles and detergent compositions containing said particles |
AU7275698A (en) | 1998-05-01 | 1999-11-23 | Procter & Gamble Company, The | Laundry detergent and/or fabric care compositions comprising a modified antimicrobial protein |
US6133228A (en) | 1998-05-28 | 2000-10-17 | Firmenich Sa | Slow release of fragrant compounds in perfumery using 2-benzoyl benzoates, 2-alkanoyl benzoates or α-keto esters |
US6207782B1 (en) | 1998-05-28 | 2001-03-27 | Cromption Corporation | Hydrophilic siloxane latex emulsions |
US6020425A (en) | 1998-06-01 | 2000-02-01 | Kimberly-Clark Worldwide, Inc. | Unmodified polyvinyl alcohol films and fibers and methods of making the same |
US6413920B1 (en) | 1998-07-10 | 2002-07-02 | Procter & Gamble Company | Amine reaction compounds comprising one or more active ingredient |
USD427902S (en) | 1998-07-10 | 2000-07-11 | Tenneco Packaging Inc. | Food container |
DE69925712T2 (de) * | 1998-07-23 | 2006-03-23 | Kao Corporation | Wäscheartikel in tuchform |
JP2000053998A (ja) | 1998-08-05 | 2000-02-22 | Kenji Sakamoto | 錠剤型洗浄剤 |
USD443389S1 (en) | 1998-08-11 | 2001-06-05 | Benckiser, N.V. | Detergent tablet |
WO2000013680A2 (en) | 1998-09-09 | 2000-03-16 | Quadrant Holdings Cambridge Limited | Filamentous amorphous carbohydrate compositions and therapeutic delivery vehicles comprising them |
US6596298B2 (en) | 1998-09-25 | 2003-07-22 | Warner-Lambert Company | Fast dissolving orally comsumable films |
AU2705600A (en) | 1998-10-01 | 2000-05-01 | University Of Akron, The | Process and apparatus for the production of nanofibers |
JP2002527606A (ja) | 1998-10-20 | 2002-08-27 | ザ、プロクター、エンド、ギャンブル、カンパニー | 改良アルキルベンゼンスルホネートを含有した洗濯洗剤 |
EP1123369B1 (en) | 1998-10-20 | 2006-03-01 | The Procter & Gamble Company | Laundry detergents comprising modified alkylbenzene sulfonates |
AU1131400A (en) | 1998-10-23 | 2000-05-15 | Procter & Gamble Company, The | Fragrance pro-accords and aldehyde and ketone fragrance libraries |
USD444914S1 (en) | 1998-10-28 | 2001-07-10 | Gisela Friesenhahn | Detergent tablet |
US6051540A (en) | 1998-11-05 | 2000-04-18 | International Flavors & Fragrances Inc. | Method employing drum chilling and apparatus therefor for producing fragrance-containing long lasting solid particle |
JP2000169896A (ja) * | 1998-12-11 | 2000-06-20 | Kao Corp | 洗濯用品 |
EP1010783B1 (en) | 1998-12-16 | 2004-05-12 | Kuraray Co., Ltd. | Thermoplastic polyvinyl alcohol fibers and method for producing them |
JP2000212828A (ja) | 1999-01-18 | 2000-08-02 | Kuraray Co Ltd | ポリビニルアルコ―ル系繊維及びその製造方法 |
US6552024B1 (en) | 1999-01-21 | 2003-04-22 | Lavipharm Laboratories Inc. | Compositions and methods for mucosal delivery |
US6029808A (en) | 1999-01-29 | 2000-02-29 | Johnson & Johnson Vision Products, Inc. | Primary package for contact lens |
USD418415S (en) | 1999-02-03 | 2000-01-04 | Tenneco Packaging Inc. | Wall structure for a container |
AU3361000A (en) | 1999-02-10 | 2000-08-29 | Procter & Gamble Company, The | Low density particulate solids useful in laundry detergents |
JP2000229841A (ja) | 1999-02-15 | 2000-08-22 | Kanebo Ltd | 混合タイプ入浴剤 |
US6274162B1 (en) | 2000-01-14 | 2001-08-14 | Bpsi Holdings, Inc. | Elegant film coating system |
US6321457B1 (en) | 1999-02-24 | 2001-11-27 | Richard L. Lariviere, Jr. | Cutting template and method of using same |
US20020081732A1 (en) | 2000-10-18 | 2002-06-27 | Bowlin Gary L. | Electroprocessing in drug delivery and cell encapsulation |
NZ503232A (en) * | 1999-03-08 | 2001-11-30 | Humatro Corp | Melt processable starch compositions comprising amylopectin and a high polymer (such as polyacrylamide) |
CN1268558A (zh) | 1999-03-24 | 2000-10-04 | 尹小林 | 多功能一次性洗洁膜 |
US20020018906A1 (en) | 1999-04-06 | 2002-02-14 | Bert Thomas Clark | Soluble membrane strenghed paper products |
US6319510B1 (en) | 1999-04-20 | 2001-11-20 | Alayne Yates | Gum pad for delivery of medication to mucosal tissues |
US6034043A (en) | 1999-04-20 | 2000-03-07 | Lever Brothers Company, Division Of Conopco, Inc. | Mild antimicrobial liquid cleansing formulations comprising polyvalent cation or cations for improving an antimicrobial effectiveness |
US6329353B1 (en) | 1999-05-12 | 2001-12-11 | Goldschmidt Chemical Corporation | Clear personal care formulations containing quaternary ammonium compounds and other nitrogen-containing compounds |
US6177391B1 (en) | 1999-05-27 | 2001-01-23 | Alam Zafar | One time use disposable soap and method of making |
US6861402B1 (en) | 1999-06-01 | 2005-03-01 | The Procter & Gamble Company | Pro-fragrances |
US6818606B1 (en) | 1999-06-16 | 2004-11-16 | Kao Corporation | Article for use in washing in sheet form |
AU7136000A (en) | 1999-07-19 | 2001-02-05 | Avantgarb, Llc | Nanoparticle-based permanent treatments for textiles |
WO2001007194A1 (de) | 1999-07-23 | 2001-02-01 | Linde Aktiengesellschaft | Verfahren und vorrichtung zum schweissen mit kompensation des schweissverzugs |
WO2001010421A1 (en) * | 1999-08-06 | 2001-02-15 | Board Of Regents, The University Of Texas System | Drug releasing biodegradable fiber implant |
DE19944416A1 (de) | 1999-09-16 | 2001-03-22 | Henkel Kgaa | Klarspülmittel |
JP3101618B1 (ja) | 1999-09-22 | 2000-10-23 | 花野商事株式会社 | 粉体離型剤の塗布方法 |
JP3703661B2 (ja) | 1999-10-05 | 2005-10-05 | ユニ・チャーム株式会社 | ゲル化合物を含有する水解性の繊維シート |
US6943200B1 (en) | 1999-10-05 | 2005-09-13 | Procter & Gamble Company | Water unstable foam compositions |
DE19947684A1 (de) | 1999-10-05 | 2001-04-12 | Henkel Kgaa | Filmbildendes Hautreinigungsmittel |
AU1191201A (en) | 1999-10-05 | 2001-05-10 | Procter & Gamble Company, The | Elastic article |
GB2355008A (en) | 1999-10-05 | 2001-04-11 | Procter & Gamble | Foam matrix coating material |
EP1237996A1 (en) | 1999-10-05 | 2002-09-11 | The Procter & Gamble Company | Water unstable foam |
WO2001032815A1 (en) | 1999-10-29 | 2001-05-10 | The Procter & Gamble Company | Laundry detergent compositions with fabric care |
JP3544156B2 (ja) | 1999-10-29 | 2004-07-21 | 花王株式会社 | シート状洗濯用品の製造方法 |
US6790814B1 (en) | 1999-12-03 | 2004-09-14 | Procter & Gamble Company | Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes |
MXPA02005744A (es) | 1999-12-08 | 2002-09-18 | Procter & Gamble | Agentes tensioactivos de alcohol poli(oxialquilado) bloqueador con eter. |
US6207274B1 (en) * | 1999-12-21 | 2001-03-27 | International Flavors & Fragrances Inc. | Fragrance containing fiber |
USD450378S1 (en) | 1999-12-21 | 2001-11-13 | Nidec Copal Corporation | Fan motor |
US6200949B1 (en) | 1999-12-21 | 2001-03-13 | International Flavors And Fragrances Inc. | Process for forming solid phase controllably releasable fragrance-containing consumable articles |
DE10085395T1 (de) | 1999-12-27 | 2002-12-05 | Kimberly Clark Co | Fasern, die eine kontrollierte Abgabe eines aktiven Mittels zur Verfügung stellen |
DE10000223A1 (de) | 2000-01-05 | 2001-07-12 | Basf Ag | Mikrokapselzubereitungen und Mikrokapseln enthaltende Wasch- und Reinigungsmittel |
AU2004202461B2 (en) | 2000-01-28 | 2007-11-22 | Smithkline Beecham Corporation | Electrospun pharmaceutical compositions |
PL356924A1 (en) | 2000-01-28 | 2004-07-12 | Smithkline Beecham Corporation | Electrospun pharmaceutical compositions |
USD442353S1 (en) | 2000-02-07 | 2001-05-22 | Mary A. Macias | Underarm clothing shield |
US6995125B2 (en) | 2000-02-17 | 2006-02-07 | The Procter & Gamble Company | Detergent product |
USD515915S1 (en) | 2000-02-22 | 2006-02-28 | Fragrance & Skincare S.L. | Receptacle, in particular for single-use cosmetic products |
USD441869S1 (en) | 2000-02-22 | 2001-05-08 | Johnson & Johnson Medical Ltd. | Wound care pad |
DE10009248C2 (de) | 2000-02-28 | 2002-06-27 | Freudenberg Carl Kg | Medizinisches Verbandsmaterial |
NZ517459A (en) * | 2000-03-07 | 2002-09-27 | Humatro Corp | Starch product comprising starch and a plasticiser or diluent |
FR2806307B1 (fr) | 2000-03-20 | 2002-11-15 | Mane Fils V | Preparation parfumee solide sous forme de microbilles et utilisation de ladite preparation |
BR0110124A (pt) * | 2000-04-17 | 2003-02-11 | Unilever Nv | Produto de limpeza de cuidado pessoal, de uso único, descarcavél,e, métodos para preparar o mesmo, e para a limpeza da pele e do cabelo |
JP4510221B2 (ja) | 2000-04-19 | 2010-07-21 | 株式会社クラレ | 熱溶融性のポリビニルアルコール系重合体組成物 |
GB2361707A (en) | 2000-04-28 | 2001-10-31 | Procter & Gamble | Pouched compositions |
US6831051B2 (en) | 2000-04-28 | 2004-12-14 | The Procter & Gamble Company | Pouched compositions |
US6835678B2 (en) | 2000-05-04 | 2004-12-28 | Kimberly-Clark Worldwide, Inc. | Ion sensitive, water-dispersible fabrics, a method of making same and items using same |
EP1280493A1 (en) | 2000-05-09 | 2003-02-05 | The Procter & Gamble Company | Composite fabric panel for disposable absorbent articles |
US6576575B2 (en) | 2000-05-15 | 2003-06-10 | Kimberly-Clark Worldwide, Inc. | Dispersible adherent article |
JP2001322668A (ja) | 2000-05-16 | 2001-11-20 | Nippon Synthetic Chem Ind Co Ltd:The | 薬剤包装用フィルム |
ES2288998T3 (es) | 2000-05-17 | 2008-02-01 | Henkel Kommanditgesellschaft Auf Aktien | Cuerpos moldeados de detergentes o productos de limpieza. |
US6610646B2 (en) | 2000-06-01 | 2003-08-26 | The Procter & Gamble Company | Enhanced duration fragrance delivery system having a non-distorted initial fragrance impression |
WO2001093823A1 (en) | 2000-06-02 | 2001-12-13 | Quest International B.V. | Improvements in or relating to perfumes |
KR20020003442A (ko) | 2000-07-03 | 2002-01-12 | 김대원 | 세정용 시트 조성물 |
GB2365018A (en) | 2000-07-24 | 2002-02-13 | Procter & Gamble | Water soluble pouches |
WO2002010257A1 (de) | 2000-07-27 | 2002-02-07 | Ge Bayer Silicones Gmbh & Co. Kg | Polyammonium-polysiloxan-verbindungen, verfahren zu ihrer herstellung und ihre verwendung |
US7041767B2 (en) | 2000-07-27 | 2006-05-09 | Ge Bayer Silicones Gmbh & Co. Kg | Polysiloxane polymers, method for their production and the use thereof |
DE10036533B4 (de) | 2000-07-27 | 2005-02-03 | Ge Bayer Silicones Gmbh & Co. Kg | Verwendung von polyquarternären Polysiloxanen als waschbeständige hydrophile Weichmacher |
US6608121B2 (en) | 2000-08-07 | 2003-08-19 | Kuraray Co., Ltd. | Water-soluble resin composition and water-soluble film |
GB0021113D0 (en) | 2000-08-25 | 2000-10-11 | Reckitt & Colmann Prod Ltd | Improvements in or relating to containers |
US6623694B1 (en) | 2000-08-29 | 2003-09-23 | Bath & Body Works, Inc. | Non-foaming water fountain and composition |
GB2366794A (en) | 2000-09-13 | 2002-03-20 | Procter & Gamble | Process for making a foam component |
GB2366797A (en) | 2000-09-13 | 2002-03-20 | Procter & Gamble | Process for making foam component by pressurising/depressurising |
EP1326787B2 (en) | 2000-10-18 | 2008-10-22 | Reckitt Benckiser N.V. | Cleaning compositions packaged in ethoxylated polyvinylalcohol materials |
CN1473193A (zh) | 2000-10-31 | 2004-02-04 | 宝洁公司 | 洗涤剂片剂的再混合 |
US20020094938A1 (en) | 2000-11-08 | 2002-07-18 | The Procter & Gamble Company | Photo-labile pro-fragrance conjugates |
US6531444B1 (en) | 2000-11-09 | 2003-03-11 | Salvona, Llc | Controlled delivery system for fabric care products |
US6503521B1 (en) | 2000-11-22 | 2003-01-07 | L'ORéAL S.A. | Fiber-containing base composition for use with mascara |
US7125828B2 (en) | 2000-11-27 | 2006-10-24 | The Procter & Gamble Company | Detergent products, methods and manufacture |
JP2002179509A (ja) | 2000-12-12 | 2002-06-26 | Takasago Internatl Corp | 抗カビ香料組成物 |
NZ508818A (en) | 2000-12-12 | 2002-10-25 | Humatro Corp | Electro-spinning process for making starch filaments for flexible structure |
US6898819B2 (en) | 2000-12-18 | 2005-05-31 | The Procter & Gamble Company | Disposable tooth cleaning article |
US6959346B2 (en) | 2000-12-22 | 2005-10-25 | Mosaid Technologies, Inc. | Method and system for packet encryption |
WO2002051381A1 (fr) | 2000-12-26 | 2002-07-04 | Takeda Chemical Industries, Ltd. | Substance poreuse et son procede de fabrication |
US20020098994A1 (en) | 2001-01-22 | 2002-07-25 | Alam Zafar | One time use disposable paper soap and method of making |
USD462900S1 (en) | 2001-01-23 | 2002-09-17 | Kao Corporation | Package |
EP1227152A1 (en) | 2001-01-30 | 2002-07-31 | Société des Produits Nestlé S.A. | Bacterial strain and genome of bifidobacterium |
US6946501B2 (en) | 2001-01-31 | 2005-09-20 | The Procter & Gamble Company | Rapidly dissolvable polymer films and articles made therefrom |
USD449881S1 (en) | 2001-02-01 | 2001-10-30 | Ecolab Inc. | Tablet |
JP2002226895A (ja) | 2001-02-05 | 2002-08-14 | Kao Corp | 液体洗浄剤組成物 |
US20030045446A1 (en) | 2001-02-12 | 2003-03-06 | Dihora Jiten Odhavji | Delivery system having encapsulated porous carrier loaded with additives |
GB0106560D0 (en) | 2001-03-16 | 2001-05-02 | Quest Int | Perfume encapsulates |
US6514484B2 (en) | 2001-03-19 | 2003-02-04 | The Procter & Gamble Company | Systems for delivering a cosmetic and/or therapeutic active to oral surfaces using an integral carrier |
WO2002076425A2 (en) | 2001-03-22 | 2002-10-03 | Battelle (Memorial Institute) | Manufacturing dissolvable dosage forms |
US6878368B2 (en) | 2001-03-29 | 2005-04-12 | San-Ei Kagaku Co., Ltd. | Composition for blending to hair treating agents and a hair treating agent |
US6956013B2 (en) | 2001-04-10 | 2005-10-18 | The Procter & Gamble Company | Photo-activated pro-fragrances |
EP1251147B1 (en) | 2001-04-20 | 2004-09-08 | Kuraray Co., Ltd. | Water-soluble film and package using the same |
WO2002090479A1 (en) | 2001-05-04 | 2002-11-14 | The Procter & Gamble Company | Perfumed particles and articles containing the same |
WO2002090474A1 (en) | 2001-05-04 | 2002-11-14 | Coatings For Industry, Inc. | Coating composition |
US6946506B2 (en) | 2001-05-10 | 2005-09-20 | The Procter & Gamble Company | Fibers comprising starch and biodegradable polymers |
US20020187181A1 (en) | 2001-05-14 | 2002-12-12 | 3M Innovative Properties Company | System for delivering cosmetics and pharmaceuticals |
US6713011B2 (en) | 2001-05-16 | 2004-03-30 | The Research Foundation At State University Of New York | Apparatus and methods for electrospinning polymeric fibers and membranes |
US6685956B2 (en) | 2001-05-16 | 2004-02-03 | The Research Foundation At State University Of New York | Biodegradable and/or bioabsorbable fibrous articles and methods for using the articles for medical applications |
GB2375542A (en) | 2001-05-17 | 2002-11-20 | Reckitt Benckiser | Water soluble container |
RU19735U1 (ru) | 2001-05-31 | 2001-10-10 | Общество с ограниченной ответственностью "Белек" | Устройство для обработки поверхностей |
EP1401380B1 (en) | 2001-06-22 | 2005-10-12 | Unilever Plc | Hair conditioning compositions |
AUPR619001A0 (en) | 2001-07-06 | 2001-08-02 | Small, Wayne Russell | Fork body bearing assembly for a shearing handpiece |
US7118530B2 (en) | 2001-07-06 | 2006-10-10 | Science Applications International Corp. | Interface for a system and method for evaluating task effectiveness based on sleep pattern |
US20030032573A1 (en) | 2001-07-11 | 2003-02-13 | Tanner Paul Robert | Cleansing compositions containing chelating surfactants |
EP1275368A1 (en) | 2001-07-14 | 2003-01-15 | Givaudan SA | Composition for adding perfumes to water soluble films |
GB0118027D0 (en) | 2001-07-24 | 2001-09-19 | Unilever Plc | Polymer products |
GB0119935D0 (en) | 2001-08-16 | 2001-10-10 | Quest Int | Perfume containing composition |
DE10140597A1 (de) | 2001-08-18 | 2003-03-06 | Kuraray Specialities Europe | Teilvernetzter Polyvinylalkohol |
US20030045441A1 (en) | 2001-08-28 | 2003-03-06 | Unilever Home And Personal Care, Usa, Division Of Conopco, Inc. | Water-soluble package with hydrophobic capsules in the film |
US20030069154A1 (en) | 2001-08-28 | 2003-04-10 | Unilever Home And Personal Care, Usa, Division Of Conopco, Inc. | Water-soluble package containing a fluid composition with a visually discrete capsule or emulsion or dispersion layer |
JP2003073700A (ja) | 2001-09-04 | 2003-03-12 | Komecho:Kk | 紙石鹸 |
US20030125220A1 (en) | 2001-09-11 | 2003-07-03 | The Procter & Gamble Company | Compositions comprising photo-labile perfume delivery systems |
JP2003082397A (ja) | 2001-09-11 | 2003-03-19 | Komecho:Kk | 紙石鹸 |
GB0122665D0 (en) | 2001-09-20 | 2001-11-14 | Cussons Int Ltd | Dispenser for personal care composition |
US20040253434A1 (en) | 2001-10-09 | 2004-12-16 | Patel Shilpan Pravinchandra | Method of manufacturing embedded water soluble film carrier |
US7357891B2 (en) | 2001-10-12 | 2008-04-15 | Monosol Rx, Llc | Process for making an ingestible film |
GB0125458D0 (en) | 2001-10-23 | 2001-12-12 | Unilever Plc | Water soluble package and liquid contents thereof |
US6607717B1 (en) | 2001-10-24 | 2003-08-19 | Dow Corning Corporation | Silicon based quaternary ammonium functional compositions and their applications |
US6482969B1 (en) | 2001-10-24 | 2002-11-19 | Dow Corning Corporation | Silicon based quaternary ammonium functional compositions and methods for making them |
US7025813B2 (en) | 2001-10-25 | 2006-04-11 | Agfa-Gevaert | Ink composition containing a particular type of dye, and corresponding ink-jet printing process |
US20030209166A1 (en) | 2001-10-25 | 2003-11-13 | Luc Vanmaele | Ink composition containing a particular type of dye, and corresponding ink jet printing process |
US7491407B2 (en) | 2001-10-31 | 2009-02-17 | North Carolina State University | Fiber-based nano drug delivery systems (NDDS) |
US20030186826A1 (en) | 2001-11-01 | 2003-10-02 | The Procter & Gamble Company | Method of using personal care compositions containing a high density, water disintegratable, polymeric foam |
US20030180242A1 (en) | 2001-11-01 | 2003-09-25 | The Procter & Gamble Company | Personal care compositions containing a water-disintegratable polymeric foam |
US7192896B2 (en) * | 2001-11-15 | 2007-03-20 | 3M Innovative Properties Company | Disposable cleaning product |
JP2003213038A (ja) | 2001-11-16 | 2003-07-30 | Natl Starch & Chem Investment Holding Corp | デンプンを含有するフィルム |
US20030099691A1 (en) | 2001-11-16 | 2003-05-29 | Susan Lydzinski | Films containing starch |
CN1357613A (zh) | 2001-11-22 | 2002-07-10 | 成都洁利康实业发展有限公司 | 全融型纸香皂及其制备方法 |
JP4694785B2 (ja) | 2001-12-13 | 2011-06-08 | フイルメニツヒ ソシエテ アノニム | 活性分子を制御放出するための化合物 |
GB0129983D0 (en) | 2001-12-14 | 2002-02-06 | Unilever Plc | Unit dose products |
GB0130498D0 (en) | 2001-12-20 | 2002-02-06 | Unilever Plc | Process for production of detergent tablets |
KR20040070276A (ko) | 2001-12-27 | 2004-08-06 | 닛폰고세이가가쿠고교 가부시키가이샤 | 폴리비닐알콜계 필름 |
AU2003214310B2 (en) | 2002-01-11 | 2006-11-02 | Rhodianyl | Use of zinc sulfide as an anti-mite agent |
JP4338117B2 (ja) | 2002-01-11 | 2009-10-07 | 日本合成化学工業株式会社 | アルカリ性物質包装用ポリビニルアルコール系フィルム |
WO2003061817A1 (de) | 2002-01-24 | 2003-07-31 | Bayer Aktiengesellschaft | Mikrokapseln enthaltende koagulate |
US7287650B2 (en) | 2002-01-31 | 2007-10-30 | Kx Technologies Llc | Structures that inhibit microbial growth |
US20030141662A1 (en) | 2002-01-31 | 2003-07-31 | Kost Pete M. | Coin-like game playing aide |
US6723160B2 (en) * | 2002-02-01 | 2004-04-20 | The Procter & Gamble Company | Non-thermoplastic starch fibers and starch composition for making same |
US20030158344A1 (en) | 2002-02-08 | 2003-08-21 | Rodriques Klein A. | Hydrophobe-amine graft copolymer |
US20050003048A1 (en) | 2002-02-11 | 2005-01-06 | Edizone, Lc | Electrolyte-containing orally soluble films |
WO2003071012A1 (en) | 2002-02-19 | 2003-08-28 | Polymer Group, Inc. | Dissolvable polyvinyl alcohol nonwoven |
GB2385857B (en) | 2002-02-27 | 2004-04-21 | Reckitt Benckiser Nv | Washing materials |
US6897190B2 (en) | 2002-02-28 | 2005-05-24 | The Procter & Gamble Company | Detergent compositions including dispersible polyolefin wax and method for using same |
AU2003228268A1 (en) | 2002-03-04 | 2003-09-22 | Buckley, Chad | Improved polyvinyl alcohol film and method of producing the same |
US7074426B2 (en) | 2002-03-27 | 2006-07-11 | Frank Kochinke | Methods and drug delivery systems for the treatment of orofacial diseases |
GB0207647D0 (en) | 2002-04-03 | 2002-05-15 | Dow Corning | Emulsions |
US7053034B2 (en) | 2002-04-10 | 2006-05-30 | Salvona, Llc | Targeted controlled delivery compositions activated by changes in pH or salt concentration |
US20040175404A1 (en) | 2002-04-15 | 2004-09-09 | Adi Shefer | Moisture triggered sealed release system |
US20030194416A1 (en) | 2002-04-15 | 2003-10-16 | Adl Shefer | Moisture triggered release systems comprising aroma ingredients providing fragrance burst in response to moisture |
US20030199412A1 (en) | 2002-04-17 | 2003-10-23 | Gargi Gupta | Fragrance containing cleaning product |
US20030215417A1 (en) | 2002-04-18 | 2003-11-20 | The Procter & Gamble Company | Malodor-controlling compositions comprising odor control agents and microcapsules containing an active material |
US20030216488A1 (en) | 2002-04-18 | 2003-11-20 | The Procter & Gamble Company | Compositions comprising a dispersant and microcapsules containing an active material |
CN100496480C (zh) | 2002-04-22 | 2009-06-10 | 宝洁公司 | 在含水表面活性剂组合物中包括含锌物质的个人护理组合物 |
USD479561S1 (en) | 2002-04-24 | 2003-09-09 | Dennis R. Meyer | Hang tag |
US7208460B2 (en) | 2002-04-26 | 2007-04-24 | Salvona Ip, Llc | Multi component controlled delivery system for soap bars |
US6740631B2 (en) | 2002-04-26 | 2004-05-25 | Adi Shefer | Multi component controlled delivery system for fabric care products |
US6825161B2 (en) | 2002-04-26 | 2004-11-30 | Salvona Llc | Multi component controlled delivery system for soap bars |
USD476854S1 (en) | 2002-05-08 | 2003-07-08 | Kraft Foods Holdings, Inc. | Bowl |
ATE318541T1 (de) | 2002-05-24 | 2006-03-15 | Procter & Gamble | Waschmittelsystem |
DE60301823T2 (de) | 2002-06-19 | 2006-05-18 | Unilever N.V. | Waschmittelbeutel |
JP4151885B2 (ja) | 2002-07-12 | 2008-09-17 | 旭化成ケミカルズ株式会社 | 水分散性セルロースおよびその製造方法 |
US20030017208A1 (en) | 2002-07-19 | 2003-01-23 | Francis Ignatious | Electrospun pharmaceutical compositions |
GB2390998A (en) | 2002-07-20 | 2004-01-28 | Reckitt Benckiser Nv | Use of a hygroscopic compound in the bonding of water soluble sheets |
TW200410714A (en) | 2002-08-07 | 2004-07-01 | Smithkline Beecham Corp | Electrospun amorphous pharmaceutical compositions |
US20060083784A1 (en) | 2002-08-07 | 2006-04-20 | Smithkline Beecham Corporation | Amorphous pharmaceutical compositions |
US20040029762A1 (en) | 2002-08-09 | 2004-02-12 | Charles Hensley | Dry, solid, thin, non-elastic, frangible surfactant sheet |
US6730648B2 (en) | 2002-08-14 | 2004-05-04 | Colgate-Palmolive Co. | Unit dose detergent film |
BRPI0305777B1 (pt) | 2002-08-14 | 2018-04-03 | Givaudan Sa | Composição compreendendo um tensoativo e um material encapsulado em uma cápsula, e, cápsulas |
US20040032859A1 (en) | 2002-08-15 | 2004-02-19 | Miao Kai X. | Managing a remote resource |
US7832552B2 (en) | 2002-08-17 | 2010-11-16 | Menicon Co. Ltd. | Duo packaging for disposable soft contact lenses using a substrate |
GB2392167A (en) | 2002-08-22 | 2004-02-25 | Reckitt Benckiser Inc | Composition containing an acid with anionic and nonionic surfactants |
EP1394294A1 (en) | 2002-08-30 | 2004-03-03 | Kuraray Co., Ltd. | High-absorbent polyvinyl alcohol fibers and nonwoven fabric comprising them |
EP1396535B1 (en) | 2002-09-05 | 2004-12-15 | The Procter & Gamble Company | Structured liquid fabric treatment compositions |
US7960326B2 (en) | 2002-09-05 | 2011-06-14 | Kimberly-Clark Worldwide, Inc. | Extruded cleansing product |
DE10241597B4 (de) | 2002-09-07 | 2004-09-16 | Scs Skin Care Systems Gmbh | Seifenzubereitung mit Luftblasen |
US7335631B2 (en) | 2002-09-09 | 2008-02-26 | Symrise, Inc. | Encapsulated perfume compositions in hair and skin products which release a burst of fragrance after initial topical application |
US20050019277A1 (en) | 2002-09-11 | 2005-01-27 | The Procter & Gamble Company | Tooth whitening products |
CN1703155A (zh) | 2002-09-13 | 2005-11-30 | 1-800接触公司 | 接触透镜包装和存放盒体、保持件、系统及其制造和使用方法 |
GB0222964D0 (en) | 2002-10-03 | 2002-11-13 | Unilever Plc | Polymeric film for water soluble package |
US6800295B2 (en) | 2002-10-09 | 2004-10-05 | The Dial Corporation | Water soluble sheet composition |
US7125835B2 (en) | 2002-10-10 | 2006-10-24 | International Flavors & Fragrances Inc | Encapsulated fragrance chemicals |
US20040071742A1 (en) | 2002-10-10 | 2004-04-15 | Popplewell Lewis Michael | Encapsulated fragrance chemicals |
US7585824B2 (en) | 2002-10-10 | 2009-09-08 | International Flavors & Fragrances Inc. | Encapsulated fragrance chemicals |
GB2393968A (en) | 2002-10-12 | 2004-04-14 | Reckitt Benckiser Nv | Carpet cleaning composition |
US7524807B2 (en) | 2002-11-01 | 2009-04-28 | The Procter & Gamble Company | Rinse-off personal care compositions comprising anionic and/or nonionic perfume polymeric particles |
US7316994B2 (en) | 2002-11-01 | 2008-01-08 | The Procter & Gamble Company | Perfume polymeric particles |
US8187580B2 (en) | 2002-11-01 | 2012-05-29 | The Procter & Gamble Company | Polymeric assisted delivery using separate addition |
US20040091445A1 (en) | 2002-11-01 | 2004-05-13 | The Procter & Gamble Company | Rinse-off personal care compositions comprising cationic perfume polymeric particles |
MXPA05004806A (es) | 2002-11-04 | 2005-07-22 | Procter & Gamble | Detergente liquido para lavanderia. |
JP4056859B2 (ja) | 2002-11-11 | 2008-03-05 | 日本合成化学工業株式会社 | 水溶性フィルム |
US7221900B2 (en) | 2002-11-21 | 2007-05-22 | Kimberly-Clark Worldwide, Inc. | Jamming device against RFID smart tag systems |
AU2003276208A1 (en) * | 2002-11-25 | 2004-06-18 | Unilever Plc | Wiping article |
GB0228584D0 (en) | 2002-12-07 | 2003-01-15 | Unilever Plc | Detergent compositions |
US20040108615A1 (en) | 2002-12-09 | 2004-06-10 | Foley Daphne Gayle | Durable water-dispersible foam |
US20040116539A1 (en) | 2002-12-16 | 2004-06-17 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Late variant addition process for personal care products |
US20040116018A1 (en) | 2002-12-17 | 2004-06-17 | Kimberly-Clark Worldwide, Inc. | Method of making fibers, nonwoven fabrics, porous films and foams that include skin treatment additives |
US20040118852A1 (en) | 2002-12-19 | 2004-06-24 | Cryovac, Inc. | Film fracture feature for peelable multilayer package lid |
US6802295B2 (en) | 2002-12-20 | 2004-10-12 | Caterpillar Inc | Air intake shutoff device with connecting linkage |
US8877316B2 (en) | 2002-12-20 | 2014-11-04 | The Procter & Gamble Company | Cloth-like personal care articles |
US20040126585A1 (en) | 2002-12-27 | 2004-07-01 | Kerins John E. | Water dispersible commode/bedpan liner |
US20040170836A1 (en) | 2003-01-07 | 2004-09-02 | The Procter & Gamble Company | Hollow fiber fabrics |
GB0300808D0 (en) | 2003-01-14 | 2003-02-12 | Unilever Plc | Home and personal care compositions with lubricants |
US9068234B2 (en) | 2003-01-21 | 2015-06-30 | Ptc Therapeutics, Inc. | Methods and agents for screening for compounds capable of modulating gene expression |
USD489162S1 (en) | 2003-01-24 | 2004-05-04 | Mars U.K. Limited | Honeycomb biscuit |
US6846784B2 (en) | 2003-01-30 | 2005-01-25 | Access Business Group International Llc | Water soluble pouch package |
US20050180962A1 (en) | 2003-01-30 | 2005-08-18 | Eyal Raz | Inactivated probiotic bacteria and methods of use thereof |
JP2004256799A (ja) | 2003-02-03 | 2004-09-16 | Nippon Shokuhin Kako Co Ltd | 発泡体及び液体農薬用キャリアー |
US20040152616A1 (en) | 2003-02-03 | 2004-08-05 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Laundry cleansing and conditioning compositions |
US20040167256A1 (en) | 2003-02-26 | 2004-08-26 | Verrall Andrew P. | Water soluble film for trigger spray bottle solution |
DE602004028187D1 (de) | 2003-03-10 | 2010-09-02 | Kuraray Co | Polyvinylalkoholfasern und diese enthaltende Vliesstoffe |
GB0305666D0 (en) | 2003-03-12 | 2003-04-16 | Unilever Plc | A water soluble delivery product |
CN1261558C (zh) | 2003-03-13 | 2006-06-28 | 鲁人康 | 肥皂纸 |
US7022656B2 (en) | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
US20050003991A1 (en) | 2003-04-03 | 2005-01-06 | Reg Macquarrie | Film-form compositions for delivery of soaps and detergents |
CN1218996C (zh) | 2003-04-09 | 2005-09-14 | 李秉和 | 速率可控、低温快速水溶性塑料膜 |
US20040202632A1 (en) | 2003-04-10 | 2004-10-14 | Unilever Home & Personal Care Usa, Division Of Conocpo, Inc. | Fragranced solid cosmetic compositions based on a starch delivery system |
KR20040094520A (ko) | 2003-05-03 | 2004-11-10 | 김학용 | 나노섬유 부직포의 제조방법 |
JP4013200B2 (ja) | 2003-05-21 | 2007-11-28 | 味の素株式会社 | シート状パック化粧料およびその製造方法 |
US7323438B2 (en) | 2003-06-13 | 2008-01-29 | Procter & Gamble | Cleansing article with improved handleability |
US7892993B2 (en) | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
US7365043B2 (en) | 2003-06-27 | 2008-04-29 | The Procter & Gamble Co. | Lipophilic fluid cleaning compositions capable of delivering scent |
CN1813085A (zh) | 2003-06-30 | 2006-08-02 | 宝洁公司 | 涂层纳米纤维网 |
US20040266300A1 (en) | 2003-06-30 | 2004-12-30 | Isele Olaf Erik Alexander | Articles containing nanofibers produced from a low energy process |
ATE424472T1 (de) | 2003-07-03 | 2009-03-15 | Oreal | Benetzbares und desintegrierbares kosmetisches erzeugnis |
DE10331767A1 (de) | 2003-07-11 | 2005-02-10 | Kuraray Specialities Europe Gmbh | Verfahren zur Herstellung von Formkörpern |
AU155582S (en) | 2003-07-22 | 2004-05-26 | Reckitt Benckiser Llc | Sponge |
MXPA06000894A (es) | 2003-07-22 | 2006-03-30 | Rhodia | Nuevos sulfatos ramificados para uso en formulaciones para el cuidado personal. |
GB0318182D0 (en) | 2003-08-04 | 2003-09-03 | Univ Liverpool | Porous material and method of production thereof |
EP1512701B1 (en) | 2003-09-05 | 2006-06-07 | The Procter & Gamble Company | Polyvinyl alcohol co-polymer and water-soluble films and pouches formed therefrom |
DE602004025824D1 (de) | 2003-09-08 | 2010-04-15 | Fmc Biopolymer As | Gel-schaum auf biopolymer-basis |
US7271138B2 (en) | 2003-10-16 | 2007-09-18 | The Procter & Gamble Company | Compositions for protecting glassware from surface corrosion in automatic dishwashing appliances |
GB0325432D0 (en) | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
JP3101618U (ja) | 2003-11-12 | 2004-06-17 | 明翰 呉 | 包装袋の構造 |
US7285520B2 (en) | 2003-12-01 | 2007-10-23 | Kimberly-Clark Worldwide, Inc. | Water disintegratable cleansing wipes |
JP2005171063A (ja) | 2003-12-10 | 2005-06-30 | Inoac Corp | 樹脂複合体 |
US7378360B2 (en) | 2003-12-17 | 2008-05-27 | Kimberly-Clark Worldwide, Inc. | Water dispersible, pre-saturated wiping products |
US20050136112A1 (en) | 2003-12-19 | 2005-06-23 | Pediamed Pharmaceuticals, Inc. | Oral medicament delivery system |
US7846462B2 (en) | 2003-12-22 | 2010-12-07 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal care implement containing a stable reactive skin care and cleansing composition |
US20050136772A1 (en) * | 2003-12-23 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Composite structures containing tissue webs and other nonwovens |
US7226899B2 (en) | 2003-12-23 | 2007-06-05 | Kimberly - Clark Worldwide, Inc. | Fibrous matrix of synthetic detergents |
US7297141B2 (en) | 2004-01-20 | 2007-11-20 | Ethicon Endo-Surgery, Inc. | Method for accessing an operative space |
JP2007518751A (ja) | 2004-01-21 | 2007-07-12 | ユニリーバー・ナームローゼ・ベンノートシヤープ | ヘアケア組成物 |
GB0401950D0 (en) | 2004-01-28 | 2004-03-03 | Unilever Plc | Porous bodies and method of production thereof |
CA2496072C (en) | 2004-02-18 | 2007-08-07 | Kuraray Co., Ltd. | Conductive polyvinyl alcohol fiber |
US20050186256A1 (en) | 2004-02-20 | 2005-08-25 | Dihel Deborah L. | Dissolvable film comprising an active ingredient and method of manufacture |
US7985720B2 (en) | 2004-02-27 | 2011-07-26 | Bruce Elliot Kramer | Multicolored cleansing bar and method for the use thereof |
US7015181B2 (en) | 2004-03-08 | 2006-03-21 | Lambino Danilo L | Rehydratable personal care compositions |
EP1574561A1 (en) | 2004-03-11 | 2005-09-14 | The Procter & Gamble Company | Perfumed detergent tablets |
US7754937B2 (en) | 2004-03-18 | 2010-07-13 | Boehringer Technologies, L.P. | Wound packing material for use with suction |
GB0406819D0 (en) | 2004-03-26 | 2004-04-28 | Dow Corning | Controlled release compositions |
US20050220745A1 (en) | 2004-04-01 | 2005-10-06 | L'oreal S.A. | Cosmetic compositions containing swelled silicone elastomer powders and gelled block copolymers |
WO2005106120A1 (en) * | 2004-04-23 | 2005-11-10 | The Procter & Gamble Company | Fibrous structures comprising a transferable agent |
CN1946902A (zh) | 2004-04-23 | 2007-04-11 | 宝洁公司 | 包含表面处理组合物和洗剂组合物的纤维结构 |
US6977116B2 (en) | 2004-04-29 | 2005-12-20 | The Procter & Gamble Company | Polymeric structures and method for making same |
US6988629B2 (en) | 2004-05-13 | 2006-01-24 | Plastipak Packaging, Inc. | Hollow plastic article including a view stripe |
CN100519716C (zh) | 2004-05-31 | 2009-07-29 | 华中师范大学 | 软膜纸香皂及其生产方法和装置 |
US20050281757A1 (en) | 2004-06-17 | 2005-12-22 | Sayed Ibrahim | Oral care film |
FR2871685B1 (fr) | 2004-06-22 | 2006-08-11 | Oreal | Procede de rasage avec un film anhydre ; utilisation d'un film anhydre pour la preparation d'un produit de rasage ; kits de rasage |
US20050287106A1 (en) | 2004-06-22 | 2005-12-29 | Jean-Yves Legendre | Method for shaving with at least one anhydrous film, use of at least one anhydrous film for the preparation of a shaving product, and shaving kits |
DE102004030318B4 (de) | 2004-06-23 | 2009-04-02 | Henkel Ag & Co. Kgaa | Mehrkammer-Pouch |
AR049537A1 (es) | 2004-06-29 | 2006-08-09 | Procter & Gamble | Composiciones de detergentes para lavanderia con colorante entonador |
US7208459B2 (en) | 2004-06-29 | 2007-04-24 | The Procter & Gamble Company | Laundry detergent compositions with efficient hueing dye |
US20060003913A1 (en) | 2004-06-30 | 2006-01-05 | The Procter & Gamble Company | Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents |
US8623341B2 (en) | 2004-07-02 | 2014-01-07 | The Procter & Gamble Company | Personal care compositions containing cationically modified starch and an anionic surfactant system |
US20080279905A1 (en) | 2004-07-02 | 2008-11-13 | Kuraray Co., Ltd. | Fabric and Clothes for Atopic Dermatitis Patients |
ATE410535T1 (de) * | 2004-07-09 | 2008-10-15 | Johnson & Johnson Gmbh | Kosmetischer und/oder dermatologischer absorbierender körperpflegeartikel mit mindestens einer absorbierenden schicht |
US7590232B2 (en) | 2004-07-21 | 2009-09-15 | Carter John A | System and method for tracking individuals |
FR2873896B1 (fr) | 2004-08-06 | 2007-06-01 | Juris Union Ltd | Particule(s) solides(s) soluble(s) a base de fibre(s) alimentaire(s) |
US7767282B2 (en) | 2004-08-10 | 2010-08-03 | E.I. Du Pont De Nemours And Company | Copolymers of vinyl alcohol and itaconic acid and uses thereof |
JP4456959B2 (ja) | 2004-08-20 | 2010-04-28 | 花王株式会社 | 毛髪処理剤 |
EP2009088B1 (en) | 2004-09-23 | 2010-02-24 | Unilever PLC | Laundry treatment compositions |
CN101039721A (zh) | 2004-10-13 | 2007-09-19 | 宝洁公司 | 包含烷基二季铵盐阳离子表面活性剂的护发组合物 |
AU2005296068B2 (en) | 2004-10-13 | 2011-11-10 | The Procter & Gamble Company | Hair conditioning composition comprising tight lamellar gel matrix |
US7674758B2 (en) | 2004-10-22 | 2010-03-09 | The Procter & Gamble Company | Fabric softening compositions comprising free fatty acid |
PL1666579T5 (pl) | 2004-11-22 | 2013-04-30 | Procter & Gamble | Rozpuszczalna w wodzie saszetka zawierająca ciecz |
US20080226919A1 (en) | 2004-11-24 | 2008-09-18 | Kuraray Co., Ltd. | Water-Soluble Film Roll and Method for Paying Out Water-Soluble Film |
USD576753S1 (en) | 2004-12-07 | 2008-09-09 | Matsushita Electric Industrial Co., Ltd. | Lighting fixture with light emitting diode |
US20060128592A1 (en) | 2004-12-10 | 2006-06-15 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Cosmetic effervescent cleansing pillow with water soluble or dispersible packet |
US20060127458A1 (en) | 2004-12-15 | 2006-06-15 | Melba Kiser | Single use personal care sheet |
US20060134410A1 (en) | 2004-12-20 | 2006-06-22 | Mackey Larry N | Polymeric structures comprising an unsubstituted hydroxyl polymer and processes for making same |
US20060135026A1 (en) * | 2004-12-22 | 2006-06-22 | Kimberly-Clark Worldwide, Inc. | Composite cleaning products having shape resilient layer |
EP1835885A1 (en) | 2004-12-23 | 2007-09-26 | Durect Corporation | Polymeric implants, preferably containing a mixture of peg and plg, for controlled release of a gnrh |
US7856989B2 (en) | 2004-12-30 | 2010-12-28 | Philip Morris Usa Inc. | Electrostatically produced fast dissolving fibers |
US20070110792A9 (en) | 2005-01-03 | 2007-05-17 | L'oreal | Cosmetic or dermatological article comprising a medium that is soluble in water |
FR2880262B1 (fr) * | 2005-01-03 | 2013-11-08 | Oreal | Article cosmetique ou dermatologique comportant un support soluble dans l'eau |
US20060160453A1 (en) | 2005-01-14 | 2006-07-20 | Hageun Suh | Breathable composite sheet |
US8197830B2 (en) | 2005-01-18 | 2012-06-12 | Gojo Industries, Inc. | Dissolvable pads for solution delivery to a surface |
US7714086B2 (en) | 2005-02-23 | 2010-05-11 | The Procter & Gamble Company | Polyvinyl alcohol co-polymer, and water-soluble films and pouches formed therefrom |
JP2006249029A (ja) * | 2005-03-11 | 2006-09-21 | Kanebo Ltd | 繊維状化粧料、シート状化粧料、化粧料組成物、及び、化粧方法 |
EP1707657A1 (en) | 2005-03-31 | 2006-10-04 | M & J Fibretech A/S | Process for producing elastic and/or water degradable webs from composite filaments |
WO2006106514A2 (en) | 2005-04-06 | 2006-10-12 | Nicast Ltd. | Electrospun dosage form and method of producing the same |
US20060228319A1 (en) | 2005-04-11 | 2006-10-12 | Vona Samuel A Jr | Personal cleansing and shaving films |
JP4755847B2 (ja) | 2005-05-13 | 2011-08-24 | ユニ・チャーム株式会社 | 水解性の清掃用品およびその製造方法 |
JP4871528B2 (ja) | 2005-05-13 | 2012-02-08 | ユニ・チャーム株式会社 | 水解性の清掃用品 |
JP4693490B2 (ja) | 2005-05-13 | 2011-06-01 | ユニ・チャーム株式会社 | 水解性の清掃用品 |
ATE481444T1 (de) | 2005-05-13 | 2010-10-15 | Procter & Gamble | Funktionalisierte folien |
US20060292098A1 (en) | 2005-05-19 | 2006-12-28 | Scavone Timothy A | Consumer noticeable improvement in wetness protection |
US7736695B2 (en) | 2005-05-23 | 2010-06-15 | Appleton Papers Inc. | Oil-in-water capsule manufacture process and microcapsules produced by such process |
WO2006130647A1 (en) | 2005-06-01 | 2006-12-07 | The Procter & Gamble Company | Water-soluble, liquid-containing pouch |
US8053000B2 (en) | 2005-06-07 | 2011-11-08 | Dr. Reddy's Laboratories Limited | Compositions for drug delivery |
FR2886845B1 (fr) | 2005-06-13 | 2009-07-03 | Oreal | Produit cosmetique solide |
GB2442626A (en) | 2005-06-16 | 2008-04-09 | Nippon Synthetic Chem Ind | Water-soluble film |
US20070041929A1 (en) | 2005-06-16 | 2007-02-22 | Torgerson Peter M | Hair conditioning composition comprising silicone polymers containing quaternary groups |
JP2007001889A (ja) | 2005-06-22 | 2007-01-11 | Mandom Corp | シャンプー組成物 |
JP4128580B2 (ja) | 2005-07-01 | 2008-07-30 | 株式会社クラレ | ポリビニルアルコール系複合繊維 |
US7519776B2 (en) | 2005-07-26 | 2009-04-14 | Invensys Systems, Inc. | Method and system for time-weighted cache management |
DE602006004754D1 (de) | 2005-07-29 | 2009-02-26 | Fiberweb Inc | Flüssigkeitundurchlässiger vliesstoff aus bikomponenten filamenten |
AU2006279593B2 (en) | 2005-08-18 | 2011-06-02 | Colgate-Palmolive Company | Cleansing compositions containing film |
CN1935881B (zh) | 2005-09-21 | 2012-05-09 | 李小鲁 | 水溶性可生物降解材料及其制备方法以及发泡类制品 |
IL171091A (en) | 2005-09-26 | 2011-01-31 | Samuel Icht | Water-soluble detergent film with a print and method of production |
JP2007091954A (ja) | 2005-09-29 | 2007-04-12 | Toshiba Corp | 発泡体、その製造方法、およびその再生方法 |
USD549051S1 (en) | 2005-10-21 | 2007-08-21 | Light My Fire Sweden Ab | Drinking vessel |
US20070099813A1 (en) | 2005-10-27 | 2007-05-03 | Luizzi Joseph M | Effervescent cleansing article |
AR059389A1 (es) | 2005-10-28 | 2008-04-09 | Procter & Gamble | Composicion que contiene catecol modificado anionicamente y polimeros de suspension |
US7585376B2 (en) | 2005-10-28 | 2009-09-08 | The Procter & Gamble Company | Composition containing an esterified substituted benzene sulfonate |
US7901696B2 (en) | 2005-10-31 | 2011-03-08 | J&J Consumer Companies, Inc. | Cosmetic device comprising discrete elements |
CA2629612A1 (en) | 2005-11-22 | 2007-05-31 | Smithkline Beecham Corporation | Foamed substrate and method for making same |
US7910121B2 (en) | 2005-12-07 | 2011-03-22 | L'oreal | Soluble cosmetic article with a thermal effect |
US20070134481A1 (en) | 2005-12-07 | 2007-06-14 | L'oreal | Soluble patch |
FR2894136B1 (fr) * | 2005-12-07 | 2008-01-18 | Oreal | Article cosmetique soluble moussant |
US20070134304A1 (en) | 2005-12-07 | 2007-06-14 | L'oreal | Soluble article for exfoliating the skin |
US20070149435A1 (en) | 2005-12-28 | 2007-06-28 | Kimberly-Clark Worldwide, Inc. | Cleansing composition including microencapsulated delivery vehicles |
US9427391B2 (en) | 2006-01-09 | 2016-08-30 | The Procter & Gamble Company | Personal care compositions containing cationic synthetic copolymer and a detersive surfactant |
BRPI0706732B1 (pt) | 2006-01-23 | 2017-06-06 | Milliken & Co | agente branqueador para composições de cuidado de lavanderia, que é um corante tiazólio |
JP4668798B2 (ja) | 2006-01-25 | 2011-04-13 | 株式会社ツキオカ | 水溶性洗浄用フィルム |
JP4692300B2 (ja) | 2006-01-26 | 2011-06-01 | 日油株式会社 | 毛髪用洗浄剤組成物 |
WO2007089259A1 (en) | 2006-02-02 | 2007-08-09 | The Johns Hopkins University | Therapeutic electrospun fiber compositions |
JP5006061B2 (ja) * | 2006-02-07 | 2012-08-22 | 日本合成化学工業株式会社 | 水溶性ポリビニルアルコール系樹脂製長繊維不織布 |
WO2007093558A2 (en) | 2006-02-14 | 2007-08-23 | L'oréal | Soluble cosmetic article |
ATE551063T1 (de) | 2006-02-15 | 2012-04-15 | Nestec Sa | Verwendung von bifidobacterium longum zur prophylaxe und behandlung von entzündungen |
EP1832273B1 (en) | 2006-03-09 | 2020-02-26 | Noxell Corporation | Thickened hair colourant and bleaching compositions |
US8349232B2 (en) | 2006-03-28 | 2013-01-08 | North Carolina State University | Micro and nanofiber nonwoven spunbonded fabric |
US20090144913A1 (en) | 2006-04-14 | 2009-06-11 | Yu Katherine G | Laundry Article |
US20080090939A1 (en) | 2006-04-20 | 2008-04-17 | Netravali Anil N | Biodegradable soy protein-based compositions and composites formed therefrom |
US20070253926A1 (en) | 2006-04-28 | 2007-11-01 | Tadrowski Tami J | Packaged cleaning composition concentrate and method and system for forming a cleaning composition |
US7745517B2 (en) | 2006-05-02 | 2010-06-29 | Sekisui Specialty Chemicals America, Llc | Polyvinyl alcohol films with improved resistance to oxidizing chemicals |
US7786027B2 (en) | 2006-05-05 | 2010-08-31 | The Procter & Gamble Company | Functionalized substrates comprising perfume microcapsules |
CA2651320A1 (en) | 2006-05-05 | 2007-11-15 | The Procter & Gamble Company | Films with microcapsules |
US20070286837A1 (en) | 2006-05-17 | 2007-12-13 | Torgerson Peter M | Hair care composition comprising an aminosilicone and a high viscosity silicone copolymer emulsion |
US20070275866A1 (en) | 2006-05-23 | 2007-11-29 | Robert Richard Dykstra | Perfume delivery systems for consumer goods |
CA2690716C (en) | 2006-06-08 | 2014-08-05 | Spongeables, Llc | Infused sponge delivery system |
KR100749925B1 (ko) | 2006-06-29 | 2007-08-16 | 주식회사 도루코 | 면도기 |
US7527880B2 (en) | 2006-07-05 | 2009-05-05 | The Procter & Gamble Company | Water-soluble substrate with resistance to dissolution prior to being immersed in water |
WO2008010177A2 (en) | 2006-07-19 | 2008-01-24 | The Procter & Gamble Company | Conditioning composition comprising silicone agent for ease-to-rinse feel and/or clean feel |
EP2046177B1 (en) | 2006-07-31 | 2016-11-30 | The Procter and Gamble Company | Cleansing articles for skin or hair |
US8602036B2 (en) | 2006-08-03 | 2013-12-10 | Philip Morris Usa Inc. | Smoking articles enhanced to deliver additives incorporated within electrospun microfibers and nonofibers, and related methods |
US20080293839A1 (en) | 2006-09-07 | 2008-11-27 | Stobby William G | Stabilized extruded alkenyl aromatic polymer foams and processes for extruding stabilized alkenyl aromatic polymer foams |
DE102006047229A1 (de) | 2006-10-04 | 2008-04-10 | Henkel Kgaa | Wasch- oder Reinigungsmittelabgabesystem |
US20080083420A1 (en) | 2006-10-09 | 2008-04-10 | The Procter & Gamble Company | Hair treatment application system |
US20080087293A1 (en) * | 2006-10-12 | 2008-04-17 | The Procter & Gamble Company | Hair treatment application system |
EP1958532A3 (en) | 2006-10-09 | 2013-06-05 | The Procter and Gamble Company | Hair treatment application system |
US20080220054A1 (en) | 2006-10-13 | 2008-09-11 | Shastri V Prasad | Modulation of drug release rate from electrospun fibers |
US20080095828A1 (en) | 2006-10-18 | 2008-04-24 | Marc Privitera | Cleaning substrates with combinational actives |
US7666343B2 (en) | 2006-10-18 | 2010-02-23 | Polymer Group, Inc. | Process and apparatus for producing sub-micron fibers, and nonwovens and articles containing same |
ATE521375T1 (de) | 2006-10-23 | 2011-09-15 | Eth Zuerich | Implantatmaterial |
WO2008055038A2 (en) | 2006-10-30 | 2008-05-08 | Rutgers, The State University | Electrospun matrices for delivery of hydrophilic and lidophilic compounds |
US20080176985A1 (en) | 2006-11-13 | 2008-07-24 | Verrall Andrew P | Water-soluble film |
CA2669547A1 (en) | 2006-11-13 | 2008-05-29 | The Procter & Gamble Company | Water-soluble detergent pouch |
US7671000B2 (en) | 2006-12-20 | 2010-03-02 | Conopco, Inc. | Stable liquid cleansing compositions comprising fatty acyl isethionate surfactant products with high fatty acid content |
US20080152894A1 (en) | 2006-12-20 | 2008-06-26 | Amcol Health & Beauty Solutions | Treated substrates having improved delivery of impregnated ingredients |
EP2104729B1 (en) | 2007-01-19 | 2010-11-03 | The Procter & Gamble Company | Laundry care composition comprising a whitening agent for cellulosic substrates |
US8077677B2 (en) | 2007-01-31 | 2011-12-13 | Interdigital Technology Corporation | Method and apparatus for paging group handling |
US10149910B2 (en) | 2007-03-01 | 2018-12-11 | The Procter & Gamble Plaza | Compositions and/or articles comprising cyclodextrin complexing material |
US20080215023A1 (en) | 2007-03-01 | 2008-09-04 | Timothy Alan Scavone | Compositions and/or articles comprising cyclodextrin complexing material |
DE102007011606A1 (de) | 2007-03-02 | 2008-09-04 | Carl Freudenberg Kg | Faser-Wirrgelege |
WO2008113071A2 (en) | 2007-03-15 | 2008-09-18 | Grain Processing Corporation | Animal litter, process for preparing animal litter, and method of removal of animal waste |
DE102007016684A1 (de) * | 2007-04-04 | 2008-10-09 | Dr. Schumacher Gmbh | Biologisch abbaubares Mehrschichtsystem |
US8549415B2 (en) | 2007-05-04 | 2013-10-01 | Apple Inc. | Automatically adjusting media display in a personal display system |
GB2449418B (en) | 2007-05-11 | 2010-11-03 | Amcor Flexibles Winterbourne Ltd | Porous films |
US20100018641A1 (en) * | 2007-06-08 | 2010-01-28 | Kimberly-Clark Worldwide, Inc. | Methods of Applying Skin Wellness Agents to a Nonwoven Web Through Electrospinning Nanofibers |
US20090004254A1 (en) | 2007-06-19 | 2009-01-01 | Todd Maibach | Film comprising active drugs |
KR101557273B1 (ko) | 2009-03-17 | 2015-10-05 | 삼성전자주식회사 | 반도체 패키지 |
GB0711992D0 (en) | 2007-06-21 | 2007-08-01 | Reckitt Benckiser Inc | Alkaline hard surface cleaning composition |
FR2919802B1 (fr) | 2007-08-06 | 2011-05-06 | Cll Pharma | Procede de solubilisation d'huiles essentielles dans l'eau |
KR100937625B1 (ko) * | 2007-08-10 | 2010-01-20 | 주식회사 제닉 | 가용성 웹 공극필름 및 이의 제조방법 |
US8329977B2 (en) | 2007-08-22 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable water-sensitive films |
US9096845B2 (en) | 2007-08-29 | 2015-08-04 | Technion Research & Development Foundation Limited | Encapsulation of bacteria and viruses in electrospun fibers |
JP2009079329A (ja) * | 2007-09-27 | 2009-04-16 | Japan Vilene Co Ltd | 徐放性不織布及びその製造方法 |
USD578881S1 (en) | 2007-10-01 | 2008-10-21 | Mars, Incorporated | Transparent container |
US20100098745A1 (en) | 2007-10-11 | 2010-04-22 | Staab Robert J | Methods for delivery of medication using dissolvable devices |
US9968535B2 (en) | 2007-10-26 | 2018-05-15 | The Procter & Gamble Company | Personal care compositions comprising undecyl sulfates |
USD577332S1 (en) | 2007-10-30 | 2008-09-23 | Moore Mark G | Solar module |
US8974814B2 (en) * | 2007-11-12 | 2015-03-10 | California Institute Of Technology | Layered drug delivery polymer monofilament fibers |
CN101161877A (zh) | 2007-11-28 | 2008-04-16 | 盛虹集团有限公司 | 一种具有芳香味的竹炭改性涤纶 |
US8453653B2 (en) | 2007-12-20 | 2013-06-04 | Philip Morris Usa Inc. | Hollow/porous fibers and applications thereof |
US8524790B2 (en) | 2007-12-27 | 2013-09-03 | Industrial Technology Research Institute | Starch film and method for manufacturing starch foam |
WO2009085679A1 (en) | 2007-12-28 | 2009-07-09 | 3M Innovative Properties Company | Composite nonwoven fibrous webs and methods of making and using the same |
WO2009088137A1 (en) | 2008-01-04 | 2009-07-16 | Lg Household & Health Care Ltd. | Functional sheet for delivering laundry actives in low-temperature water |
RU2010125312A (ru) | 2008-01-07 | 2012-02-20 | Дзе Проктер Энд Гэмбл Компани (US) | Моющие средства, имеющие приемлемую окраску |
USD588332S1 (en) | 2008-01-09 | 2009-03-17 | Holley Phelan | Pretzel cracker |
EP2085434A1 (en) | 2008-01-11 | 2009-08-05 | Universita' Degli Studi di Firenze | Disperse dyes soluble in water |
US8765170B2 (en) | 2008-01-30 | 2014-07-01 | The Procter & Gamble Company | Personal care composition in the form of an article |
US20090197787A1 (en) | 2008-02-04 | 2009-08-06 | Eurotab | Multilayer Detergent Tablet |
GB0803165D0 (en) | 2008-02-21 | 2008-04-02 | Unilever Plc | Encapsulated benefit agent |
CA2719637C (en) | 2008-03-27 | 2014-10-28 | Agigma, Inc. | Methods and compositions for the delivery of agents |
US7998888B2 (en) | 2008-03-28 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Thermoplastic starch for use in melt-extruded substrates |
WO2009121900A1 (en) | 2008-04-04 | 2009-10-08 | Akzo Nobel Coatings International B.V. | Encapsulated tinters |
US8029259B2 (en) | 2008-04-11 | 2011-10-04 | Reifenhauser Gmbh & Co. Kg Maschinenfabrik | Array of nozzles for extruding multiple cellulose fibers |
MX337657B (es) | 2008-04-16 | 2016-03-14 | Procter & Gamble | Composicion no espumante para el cuidado personal en forma de un articulo. |
UA37191U (ru) * | 2008-04-21 | 2008-11-25 | Сергей Павлович Борткевич | Устройство регенерации рукавного фильтра |
US20090274906A1 (en) | 2008-05-01 | 2009-11-05 | Appleton Papers Inc. | Particle with low permeance wall |
US20090286437A1 (en) | 2008-05-14 | 2009-11-19 | Kimberly-Clark Worldwide, Inc. | Wipes with rupturable beads |
US8349449B2 (en) | 2008-05-15 | 2013-01-08 | The Clorox Company | Polymer active complex fibers |
CN101280467B (zh) | 2008-05-20 | 2010-09-15 | 暨南大学 | 一种壳聚糖基纳米纤维的制备方法与应用 |
US9308657B2 (en) | 2008-05-30 | 2016-04-12 | The Gillette Company | Blade support for multi-blade razor cartridges |
EP2246031B1 (en) | 2008-06-10 | 2017-06-28 | The Procter & Gamble Company | Stannous chloride and Silica compositions |
EP2133410B1 (en) | 2008-06-13 | 2011-12-28 | The Procter & Gamble Company | Multi-compartment pouch |
DE102008033327A1 (de) | 2008-07-16 | 2010-01-21 | Bayer Innovation Gmbh | Kieselsol-Material mit mindestens einem therapeutisch aktiven Wirkstoff zur Herstellung von biologisch degradierbaren und/oder resorbierbaren Kieselgel-Materialien für die Humanmedizin und/oder Medizintechnik |
AU2009270415B2 (en) * | 2008-07-18 | 2015-09-17 | Nntt Tech Inc | Articles of manufacture releasing an active ingredient |
US7967801B2 (en) | 2008-08-08 | 2011-06-28 | The Procter & Gamble Company | Regionalized topsheet |
EP2323635A2 (de) | 2008-08-08 | 2011-05-25 | Basf Se | Wirkstoffhaltige fasernflächengebilde mit einstellbarer wirkstofffreisetzung, ihre anwendungen und verfahren zu ihrer herstellung |
JP5345354B2 (ja) * | 2008-08-19 | 2013-11-20 | 株式会社ピーアンドピーエフ | シート状皮膚洗浄用具 |
JP5344873B2 (ja) | 2008-08-28 | 2013-11-20 | 三菱電機株式会社 | 炭化珪素半導体装置の製造方法 |
US8049061B2 (en) | 2008-09-25 | 2011-11-01 | Abbott Cardiovascular Systems, Inc. | Expandable member formed of a fibrous matrix having hydrogel polymer for intraluminal drug delivery |
JP2010100966A (ja) | 2008-10-23 | 2010-05-06 | Kaneka Corp | ポリ塩化ビニル系人工毛髪用繊維、人工毛髪およびそれからなる頭飾製品 |
CN102223922B (zh) | 2008-11-25 | 2015-07-22 | 宝洁公司 | 包含凝胶网络和熔融二氧化硅的口腔护理组合物 |
JP5107874B2 (ja) | 2008-11-28 | 2012-12-26 | 住友精化株式会社 | ヨウ素含有微細繊維 |
WO2010077629A2 (en) | 2008-12-08 | 2010-07-08 | The Procter & Gamble Company | Porous, dissolvable solid substrates and surface resident cyclodextrin perfume complexes |
EP2355775B1 (en) | 2008-12-08 | 2017-06-21 | The Procter and Gamble Company | Personal care composition in the form of an article having a hydrophobic surface-resident coating |
MX2011005727A (es) | 2008-12-08 | 2011-06-21 | Procter & Gamble | Composicion de cuidado personal en la forma de un articulo que tiene una estructura solida soluble porosa. |
CN102368997B (zh) | 2008-12-08 | 2013-12-25 | 宝洁公司 | 使用时溶解以递送表面活性剂的制品的制备方法 |
CN102245155B (zh) | 2008-12-08 | 2015-11-25 | 宝洁公司 | 具有可溶性多孔固体结构的制品形式的个人护理组合物 |
US8920905B2 (en) | 2008-12-09 | 2014-12-30 | Sca Hygiene Products Ab | Fibrous product with a rastered embossing and method for producing same |
CN101424009A (zh) | 2008-12-09 | 2009-05-06 | 东华大学 | 一种低温水溶性非织造布的制备方法 |
CN102348772B (zh) | 2009-01-21 | 2015-01-07 | 生物圈工业有限责任公司 | 抗潮湿涂料 |
TWI398264B (zh) | 2009-02-03 | 2013-06-11 | Shiseido Co Ltd | 毛髮調理劑組成物及其低能量製造方法 |
JP5346221B2 (ja) | 2009-02-06 | 2013-11-20 | ユニ・チャーム株式会社 | 水解性不織布 |
CA2695068A1 (en) | 2009-03-02 | 2010-09-02 | Dizolve Group Corporation | Dissolvable laundry detergent sheet |
CN101538745B (zh) | 2009-04-22 | 2010-12-29 | 西南交通大学 | 一种可控释放基因药物的生物降解聚合物超细纤维的制备方法 |
WO2011014401A2 (en) | 2009-07-30 | 2011-02-03 | The Procter & Gamble Company | Oral care articles and methods |
US8309505B2 (en) | 2009-07-30 | 2012-11-13 | The Procter & Gamble Company | Hand dish composition in the form of an article |
US8288332B2 (en) | 2009-07-30 | 2012-10-16 | The Procter & Gamble Company | Fabric care conditioning composition in the form of an article |
US8367596B2 (en) | 2009-07-30 | 2013-02-05 | The Procter & Gamble Company | Laundry detergent compositions in the form of an article |
JP2013512963A (ja) | 2009-12-08 | 2013-04-18 | ザ プロクター アンド ギャンブル カンパニー | 多孔質溶解性固体基材及びカチオン性界面活性剤コンディショナーの表面残留コーティング |
JP5678081B2 (ja) | 2009-12-08 | 2015-02-25 | ザ プロクター アンド ギャンブルカンパニー | パーソナルケア物品の製造方法 |
MX339322B (es) | 2009-12-08 | 2016-05-20 | Procter & Gamble | Un sustrato solido, soluble y poroso y recubrimiento fijo de superficie que comprende microesferas de matriz. |
JP5808336B2 (ja) | 2009-12-08 | 2015-11-10 | ザ プロクター アンド ギャンブルカンパニー | 多孔質溶解性固体基材、及び感水活性物質を含有する表面常在コーティング |
US9173826B2 (en) | 2010-02-16 | 2015-11-03 | The Procter & Gamble Company | Porous, dissolvable solid substrate and surface resident coating comprising a zync pyrithione |
AR080385A1 (es) | 2010-03-09 | 2012-04-04 | Polymers Crc Ltd | Procedimiento para la preparacion de un articulo antimicrobiano |
FR2957610B1 (fr) | 2010-03-17 | 2012-03-23 | Freudenberg Politex Sa | Produit non-tisse contenant des particules organiques et/ou minerales et son procede de fabrication |
USD644541S1 (en) | 2010-03-31 | 2011-09-06 | Julie Beth Schrader | Hexagonal template set used in quilting |
US20110269657A1 (en) | 2010-04-28 | 2011-11-03 | Jiten Odhavji Dihora | Delivery particles |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US20110268778A1 (en) | 2010-04-28 | 2011-11-03 | Jiten Odhavji Dihora | Delivery particles |
USD651096S1 (en) | 2010-05-19 | 2011-12-27 | Ucc Ueshima Coffee Co., Ltd. | Beverage extraction filter |
US8232238B2 (en) | 2010-06-03 | 2012-07-31 | The Clorox Company | Concentrated film delivery systems |
USD640921S1 (en) | 2010-06-25 | 2011-07-05 | H.J. Heinz Company | Container |
US9125811B2 (en) | 2010-06-29 | 2015-09-08 | Kao Corporation | Nanofiber laminate sheet |
RU2640933C1 (ru) | 2010-07-02 | 2018-01-12 | Дзе Проктер Энд Гэмбл Компани | Филаменты, содержащие пригодные для перорального введения активные компоненты, нетканые полотна и способы их изготовления |
BR112013000101A2 (pt) | 2010-07-02 | 2016-05-17 | Procter & Gamble | filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos |
CN105647715B (zh) | 2010-07-02 | 2019-10-25 | 宝洁公司 | 洗涤剂产品 |
JP5540107B2 (ja) | 2010-07-02 | 2014-07-02 | ザ プロクター アンド ギャンブル カンパニー | 不織布ウェブからフィルムを作製する方法 |
CA2803010C (en) | 2010-07-02 | 2015-11-24 | The Procter & Gamble Company | Dissolvable fibrous web structure article comprising active agents |
RU2541952C2 (ru) | 2010-07-02 | 2015-02-20 | Дзе Проктер Энд Гэмбл Компани | Филаменты, содержащие активный агент, нетканые полотна и способы их получения |
CA2803621C (en) | 2010-07-02 | 2015-01-06 | The Procter & Gamble Company | Filaments comprising a non-perfume active agent nonwoven webs and methods for making same |
EP2588091B1 (en) | 2010-07-02 | 2020-04-15 | The Procter and Gamble Company | Methods of delivering a health care active by administering personal health care articles comprising a filament |
US20180163325A1 (en) | 2016-12-09 | 2018-06-14 | Robert Wayne Glenn, Jr. | Dissolvable fibrous web structure article comprising active agents |
BR112013000044B1 (pt) | 2010-07-02 | 2022-01-04 | The Procter & Gamble Company | Método para a distribuição de agentes ativos a artigos de tecido ou superfícies duras |
RU2522186C2 (ru) | 2010-09-14 | 2014-07-10 | Тюрингишес Институт Фюр Текстиль-Унд Кунстштофф-Форшунг Е.В. | Высокофункциональный фильерный нетканый материал, состоящий из содержащих частицы волокон, а также способ его изготовления |
EP2617052B1 (en) | 2010-09-15 | 2022-06-08 | DH Technologies Development Pte. Ltd. | Data independent acquisition of production spectra and reference spectra library matching |
RU2569527C2 (ru) | 2010-11-02 | 2015-11-27 | Дзе Проктер Энд Гэмбл Компани | Разлагаемые упаковки-саше для развивающихся рынков |
USD685436S1 (en) | 2011-01-28 | 2013-07-02 | Glow Europe B.V. | Toy |
US9005635B2 (en) | 2011-03-01 | 2015-04-14 | The Procter & Gamble Company | Articles and processes for making a porous disintegratable solid substrate for personal health care applications |
FI20115226A0 (fi) | 2011-03-07 | 2011-03-07 | Stora Enso Oyj | Kuumasaumautuva pakkausmateriaali, sen valmistusmenetelmä ja siitä valmistettu pakkaus |
GB201104263D0 (en) | 2011-03-14 | 2011-04-27 | Biome Bioplastics Ltd | Bio-resins |
EP2694267B2 (en) | 2011-04-07 | 2020-03-11 | The Procter and Gamble Company | Continuous process of making an article of dissolution upon use to deliver surfactants |
US20120288693A1 (en) | 2011-04-12 | 2012-11-15 | Stanley Scott K | Flexible barrier packaging derived from renewable resources |
EP2698396B1 (en) | 2011-04-14 | 2015-11-25 | Teijin Limited | Reinforcing fiber composite material |
US20120294823A1 (en) | 2011-05-16 | 2012-11-22 | Pornanong Aramwit | Method for preparing silk sericin-PVA scaffold using genipin as crosslinking agent |
WO2013069702A1 (ja) | 2011-11-07 | 2013-05-16 | 日信化学工業株式会社 | 水分散型気化活性物質徐放性製剤 |
JP5719755B2 (ja) | 2011-11-09 | 2015-05-20 | フェザー安全剃刀株式会社 | 安全剃刀 |
JP5821609B2 (ja) | 2011-12-20 | 2015-11-24 | 株式会社Jvcケンウッド | 傾斜角算出装置及び傾斜角算出方法 |
MX352942B (es) | 2012-01-04 | 2017-12-14 | Procter & Gamble | Estructuras fibrosas que contienen activos y multiples regiones que tienen densidades diferentes. |
US10694917B2 (en) | 2012-01-04 | 2020-06-30 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
US9139802B2 (en) | 2012-01-04 | 2015-09-22 | The Procter & Gamble Company | Active containing fibrous structures with multiple regions |
EP2800831B1 (en) | 2012-01-04 | 2020-12-16 | The Procter and Gamble Company | Fibrous structures comprising particles and methods for making same |
AU340842S (en) | 2012-01-17 | 2012-02-09 | Logue & Co Pty Ltd | Blister pack |
US20150102307A1 (en) | 2012-02-29 | 2015-04-16 | Showa Denko K.K. | Electroluminescent element, method for manufacturing electroluminescent element, display device, and illumination device |
JP2015514166A (ja) | 2012-04-19 | 2015-05-18 | ザ プロクター アンド ギャンブルカンパニー | 非ヒドロキシルポリマーを含む繊維要素及びその製造方法 |
USD682622S1 (en) | 2012-08-03 | 2013-05-21 | Adam Christopher Keys | Food bowl vacuum formed from laminar polymeric plastic resin |
MX370280B (es) | 2012-10-12 | 2019-12-09 | Procter & Gamble | Composición para el cuidado personal en la forma de un artículo disoluble. |
US8541081B1 (en) | 2012-10-15 | 2013-09-24 | Cryovac, Inc. | Easy-open, reclosable package |
USD692675S1 (en) | 2012-10-19 | 2013-11-05 | Dsm Ip Assets B.V. | Sheet for use in antiballistic articles |
CN104768520B (zh) | 2012-11-05 | 2017-06-13 | 宝洁公司 | 热处理的沉淀二氧化硅 |
US9393216B2 (en) | 2012-11-06 | 2016-07-19 | University Of Washington Through Its Center For Commercialization | Vaginal matrices: nanofibers for contraception and prevention of HIV infection |
USD694621S1 (en) | 2013-02-18 | 2013-12-03 | Wellpet LLC | Container |
KR20150126956A (ko) | 2013-03-14 | 2015-11-13 | 존슨 앤드 존슨 컨수머 인코포레이티드 | 초친수성 양친매성 공중합체를 포함하는 세정 바아 및 그의 사용 방법 |
US20140265007A1 (en) | 2013-03-14 | 2014-09-18 | Johnson & Johnson Consumer Companies, Inc. | Cleansing bars comprising superhydrophilic amphiphilic copolymers and methods of use thereof |
USD723365S1 (en) | 2013-03-15 | 2015-03-03 | The J.M. Smucker Company | Container |
WO2014152083A1 (en) | 2013-03-15 | 2014-09-25 | The Procter & Gamble Company | Personal care article comprising dissolvable fibers |
EP2969032A1 (en) | 2013-03-15 | 2016-01-20 | The Procter & Gamble Company | Process of forming a dissolvable fiber |
USD712822S1 (en) | 2013-04-19 | 2014-09-09 | Scott David Brusaw | Solar roadway panel |
US20160324741A1 (en) | 2013-06-10 | 2016-11-10 | The Procter & Gamble Company | Oral Compositions Containing Zinc |
EP2818155A1 (en) | 2013-06-26 | 2014-12-31 | Kao Corporation, S.A. | Hair conditioner |
WO2015040488A2 (en) | 2013-08-06 | 2015-03-26 | Rhodia Operations | Sulfate-free structured liquid surfactants |
RU2690000C2 (ru) | 2013-09-06 | 2019-05-30 | Дзе Проктер Энд Гэмбл Компани | Капсулы, содержащие водорастворимые волокнистые материалы стенок, и способы их изготовления |
CN103735428B (zh) | 2013-12-31 | 2015-04-08 | 广州市白云区大荣精细化工有限公司 | 一种角蛋白护发素及其制备方法 |
USD740928S1 (en) | 2014-01-14 | 2015-10-13 | Reckitt Benckiser Llc | Tablet |
USD771788S1 (en) | 2014-01-20 | 2016-11-15 | Turbotec Products, Inc. | Insulated housing for coiled heat exchanger tube |
BR112016024698B1 (pt) | 2014-04-22 | 2022-05-24 | The Procter & Gamble Company | Filamentos e estruturas fibrosas que empregam os mesmos |
CN106413683A (zh) | 2014-04-22 | 2017-02-15 | 宝洁公司 | 可溶性固体结构体形式的组合物 |
US9861558B2 (en) | 2014-05-05 | 2018-01-09 | The Procter & Gamble Company | Methods of forming an aqueous treatment liquor by dissolving a porous solid with a benefit agent coating |
US20150313805A1 (en) | 2014-05-05 | 2015-11-05 | The Procter & Gamble Company | Consumer Products |
US9861559B2 (en) | 2014-05-05 | 2018-01-09 | The Procter & Gamble Company | Consumer product comprising a porous, dissolvable, fibrous web solid structure with a silicone coating |
US9867762B2 (en) | 2014-05-05 | 2018-01-16 | The Procter & Gamble Company | Consumer product comprising a porous dissolvable solid structure and silicone conditioning agent coating |
US9827173B2 (en) | 2014-05-05 | 2017-11-28 | The Procter & Gamble Company | Porous dissolvable solid structure with two benefit agents and methods of forming an aqueous treatment liquor therefrom |
US9877899B2 (en) | 2014-05-05 | 2018-01-30 | The Procter & Gamble Company | Consumer product comprising a fibrous web structure with a silicone conditioning agent coating |
US9937111B2 (en) | 2014-05-05 | 2018-04-10 | The Procter & Gamble Company | Consumer product comprising a fibrous web solid structure with a silicone conditioning agent coating |
USD747066S1 (en) | 2014-05-21 | 2016-01-12 | Pet's Best Life, Llc | Pet treat |
AU359809S (en) | 2014-07-08 | 2015-01-12 | Eurotab | Detergent tablet |
USD774086S1 (en) | 2014-10-06 | 2016-12-13 | Vixlet LLC | Display screen with computer icon |
USD775198S1 (en) | 2014-10-06 | 2016-12-27 | Vixlet LLC | Display screen with icons |
WO2016057376A1 (en) | 2014-10-10 | 2016-04-14 | The Procter & Gamble Company | Soluble fibrous structures and methods for making same |
BR112017007305A2 (pt) | 2014-10-10 | 2017-12-19 | Procter & Gamble | estruturas fibrosas com aberturas e métodos para a produção das mesmas |
USD748240S1 (en) | 2014-10-21 | 2016-01-26 | Pfizer Inc. | Oral delivery product |
USD761516S1 (en) | 2014-12-16 | 2016-07-19 | Mars, Incorporated | Pet treat |
USD798143S1 (en) | 2015-03-17 | 2017-09-26 | Conagra Foods Rdm, Inc. | Rigid tray |
USD797551S1 (en) | 2015-03-17 | 2017-09-19 | Conagra Foods Rdm, Inc. | Rigid tray |
GB2537649A (en) | 2015-04-22 | 2016-10-26 | Cosmetic Warriors Ltd | Composition |
US10633614B2 (en) | 2015-11-02 | 2020-04-28 | Vanguard Soap LLC | Natural laundry soaps |
CN106728634A (zh) | 2015-11-19 | 2017-05-31 | 哈尔滨圣吉药业股份有限公司 | 一种越鞠保和分散片及其制备方法 |
USD808583S1 (en) | 2015-12-31 | 2018-01-23 | LAKMA STREFA Sp. z.o.o. | Packaged detergent |
CN108474141B (zh) | 2016-01-21 | 2020-11-13 | 宝洁公司 | 包含聚环氧乙烷的纤维元件 |
AU201613843S (en) | 2016-01-22 | 2016-09-12 | 3M Innovative Properties Co | Equilateral hexagonal hand pad |
EP3405608B1 (en) | 2016-01-22 | 2020-07-01 | 3M Innovative Properties Company | Scouring pad |
USD866891S1 (en) | 2016-01-22 | 2019-11-12 | 3M Innovative Properties Company | Scouring article |
USD819836S1 (en) | 2016-02-16 | 2018-06-05 | Nmc S.A. | Decorative wall panels |
CN106726634A (zh) | 2016-06-01 | 2017-05-31 | 广州兰洁宝生物科技有限公司 | 一种片状洗发用品 |
USD811922S1 (en) | 2016-09-01 | 2018-03-06 | Karen Lefave | Jewelry article |
WO2018075832A1 (en) | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Stable compact shampoo products with low viscosity and viscosity reducing agent |
USD857156S1 (en) | 2016-11-02 | 2019-08-20 | Innovative Water Care, Llc | Chemical tablet for aquatic systems |
US10736790B2 (en) | 2016-11-22 | 2020-08-11 | Saathi, Inc. | Absorbent article having natural fibers |
USD878694S1 (en) | 2017-06-16 | 2020-03-17 | 3M Innovative Properties Company | Scouring article |
USD866105S1 (en) | 2016-12-22 | 2019-11-05 | 3M Innovative Properties Company | Scouring article |
USD901115S1 (en) | 2016-12-22 | 2020-11-03 | 3M Innovative Properties Company | Scouring article |
CN106916659B (zh) | 2017-01-24 | 2020-05-12 | 纳爱斯集团有限公司 | 一种多层洗衣片及其制备方法 |
JP6882519B2 (ja) | 2017-01-27 | 2021-06-02 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 発泡性凝集粒子を含む溶解性固形構造体形態の組成物 |
MX2019008762A (es) | 2017-01-27 | 2019-09-18 | Procter & Gamble | Composiciones en la forma de estructuras solidas solubles. |
USD811935S1 (en) | 2017-03-09 | 2018-03-06 | Richard D Hughes | Shirt cuff fastener |
USD851344S1 (en) | 2017-03-15 | 2019-06-11 | 3M Innovative Properties Company | Three-layered scouring pad |
USD848102S1 (en) | 2017-03-15 | 2019-05-07 | 3M Innovative Properties Company | Three-layered scouring pad |
MX2019012693A (es) | 2017-04-26 | 2019-12-11 | Procter & Gamble | Composiciones con polimeros anionicos y cationicos. |
US10569286B2 (en) | 2017-05-08 | 2020-02-25 | Ecolab Usa Inc. | Shaped cartridge dispensing systems |
MX2019013048A (es) | 2017-05-16 | 2019-12-11 | Procter & Gamble | Composiciones acondicionadoras para el cuidado del cabello en la forma de estructuras solidas solubles. |
US10975340B2 (en) | 2017-05-16 | 2021-04-13 | The Procter & Gamble Company | Active agent-containing fibrous structure articles |
FR3068243B1 (fr) | 2017-06-30 | 2020-02-14 | L'oreal | Composition solide anhydre comprenant un derive d’acide isethionique, un derive d’acide glutamique, un tensioactif amphotere et des charges |
USD866892S1 (en) | 2017-07-28 | 2019-11-12 | 3M Innovative Properties Company | Scouring pad |
USD850041S1 (en) | 2017-07-31 | 2019-05-28 | 3M Innovative Properties Company | Scouring pad |
USD868159S1 (en) | 2017-08-03 | 2019-11-26 | Innovative Art Concepts, Llc | Stencil |
USD866893S1 (en) | 2017-12-07 | 2019-11-12 | 3M Innovative Properties Company | Scouring sponge |
USD864507S1 (en) | 2017-12-07 | 2019-10-22 | 3M Innovative Properties Company | Scouring pad |
USD862020S1 (en) | 2017-12-08 | 2019-10-01 | 3M Innovative Properties Company | Scouring sponge |
USD877160S1 (en) | 2018-01-30 | 2020-03-03 | Magic Leap, Inc. | Display panel or portion thereof with a transitional mixed reality graphical user interface |
USD868953S1 (en) | 2018-02-08 | 2019-12-03 | The Procter & Gamble Company | Wax article |
USD864422S1 (en) | 2018-03-27 | 2019-10-22 | Cersai Building Material Co., Ltd. | Mosaic tile with notch |
USD857242S1 (en) | 2018-05-01 | 2019-08-20 | Lumicor Inc. | Architectural wall tile with three dimensional elongated hexagon surface |
USD857929S1 (en) | 2018-05-01 | 2019-08-27 | Lumicor Inc | Architectural wall tile with three dimensional hexagon surface |
WO2019222126A1 (en) | 2018-05-14 | 2019-11-21 | The Procter & Gamble Company | Oral care compositions comprising metal ions |
US20190350819A1 (en) | 2018-05-16 | 2019-11-21 | The Procter & Gamble Company | Conditioning hair compositions in the form of dissolvable solid structures |
JP1629688S (zh) | 2018-07-16 | 2019-04-15 | ||
US11666514B2 (en) | 2018-09-21 | 2023-06-06 | The Procter & Gamble Company | Fibrous structures containing polymer matrix particles with perfume ingredients |
USD867717S1 (en) | 2018-10-25 | 2019-11-26 | General Mills, Inc. | Cracker |
CN109589279B (zh) | 2019-01-08 | 2020-03-20 | 明辉实业(深圳)有限公司 | 一种固体洗发水及其制备方法 |
USD910457S1 (en) | 2019-03-14 | 2021-02-16 | Sang Kuk Lee | Mask pack pouch |
JP2021519704A (ja) | 2019-03-25 | 2021-08-12 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 多層溶解性固体物品及びその作製方法 |
USD906802S1 (en) | 2019-06-21 | 2021-01-05 | Ann Chi | Hexagonal container |
MX2021013141A (es) | 2019-06-28 | 2021-12-10 | Procter & Gamble | Articulos fibrosos solidos disolubles que contienen surfactantes anionicos. |
USD903152S1 (en) | 2019-07-01 | 2020-11-24 | Shanghai Mebania Industry Co., Ltd. | Tile |
CN114025738A (zh) | 2019-07-03 | 2022-02-08 | 宝洁公司 | 包含阳离子表面活性剂和可溶性酸的纤维结构 |
US20210094744A1 (en) | 2019-10-01 | 2021-04-01 | The Procter & Gamble Company | Primary package containing personal care article |
MX2022002875A (es) | 2019-10-14 | 2022-03-25 | Procter & Gamble | Bolsita biodegradable y/o para compost domestico que contiene un articulo solido. |
KR20220069997A (ko) | 2019-10-24 | 2022-05-27 | 더 프록터 앤드 갬블 캄파니 | 코팅 조성물을 함유하는 다층 용해성 고체 물품 및 이의 제조 방법 |
MX2022003979A (es) | 2019-11-20 | 2022-04-26 | Procter & Gamble | Estructura solida soluble porosa. |
USD921166S1 (en) | 2020-01-28 | 2021-06-01 | Ebbe America, Lc | Drain cover |
JP2023518022A (ja) | 2020-04-10 | 2023-04-27 | ザ プロクター アンド ギャンブル カンパニー | 剃毛に使用するための流動性固体組成物 |
JP7448690B2 (ja) | 2020-06-26 | 2024-03-12 | ザ プロクター アンド ギャンブル カンパニー | アニオン性界面活性剤を含有する溶解性固体繊維性物品 |
CA3189776A1 (en) | 2020-08-19 | 2022-02-24 | The Procter & Gamble Company | Flexible, porous, dissolvable solid sheet article containing direct-added microcapsules and process for making same |
CN118541127A (zh) | 2021-12-17 | 2024-08-23 | 宝洁公司 | 含有盐的可溶性固体纤维洗发剂制品 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1658831A (zh) * | 2002-06-07 | 2005-08-24 | 宝洁公司 | 用于皮肤或毛发的清洁制品 |
US20090041820A1 (en) * | 2007-08-07 | 2009-02-12 | Wu Margaret M | Functional polymer compositions |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109563446A (zh) * | 2016-08-15 | 2019-04-02 | 雷克特本克斯尔菲尼施公司 | 用于机器餐具洗涤机的组合物 |
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