KR102018168B1 - 구조화된 입자 - Google Patents
구조화된 입자 Download PDFInfo
- Publication number
- KR102018168B1 KR102018168B1 KR1020147002032A KR20147002032A KR102018168B1 KR 102018168 B1 KR102018168 B1 KR 102018168B1 KR 1020147002032 A KR1020147002032 A KR 1020147002032A KR 20147002032 A KR20147002032 A KR 20147002032A KR 102018168 B1 KR102018168 B1 KR 102018168B1
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- KR
- South Korea
- Prior art keywords
- particles
- powder
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/052—Metallic powder characterised by the size or surface area of the particles characterised by a mixture of particles of different sizes or by the particle size distribution
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/049—Manufacturing of an active layer by chemical means
- H01M4/0492—Chemical attack of the support material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
- H01M4/0428—Chemical vapour deposition
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Silicon Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1110785.1A GB2492167C (en) | 2011-06-24 | 2011-06-24 | Structured particles |
| GB1110785.1 | 2011-06-24 | ||
| PCT/GB2012/051475 WO2012175998A1 (en) | 2011-06-24 | 2012-06-22 | Structured particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140072863A KR20140072863A (ko) | 2014-06-13 |
| KR102018168B1 true KR102018168B1 (ko) | 2019-09-04 |
Family
ID=44485146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147002032A Active KR102018168B1 (ko) | 2011-06-24 | 2012-06-22 | 구조화된 입자 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10077506B2 (enExample) |
| EP (2) | EP3396747B1 (enExample) |
| JP (2) | JP6321539B2 (enExample) |
| KR (1) | KR102018168B1 (enExample) |
| CN (3) | CN103718354B (enExample) |
| GB (3) | GB2492167C (enExample) |
| WO (1) | WO2012175998A1 (enExample) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2492167C (en) | 2011-06-24 | 2018-12-05 | Nexeon Ltd | Structured particles |
| WO2013114095A1 (en) | 2012-01-30 | 2013-08-08 | Nexeon Limited | Composition of si/c electro active material |
| US9337478B2 (en) * | 2012-02-14 | 2016-05-10 | Shailesh Upreti | Composite silicon or composite tin particles |
| GB2499984B (en) | 2012-02-28 | 2014-08-06 | Nexeon Ltd | Composite particles comprising a removable filler |
| GB2502625B (en) | 2012-06-06 | 2015-07-29 | Nexeon Ltd | Method of forming silicon |
| GB2507535B (en) | 2012-11-02 | 2015-07-15 | Nexeon Ltd | Multilayer electrode |
| US9959983B2 (en) | 2013-06-28 | 2018-05-01 | Intel Corporation | Robust porous electrodes for energy storage devices |
| GB2516318B (en) * | 2013-07-19 | 2017-02-15 | Nexeon Ltd | Etched silicon structures, method of forming etched silicon structures and uses thereof |
| EP2919298B1 (en) * | 2014-03-12 | 2017-08-23 | Belenos Clean Power Holding AG | Si/C composite anodes for lithium-ion batteries with a sustained high capacity per unit area |
| US9657723B1 (en) * | 2014-03-26 | 2017-05-23 | Lockheed Martin Corporation | Carbon nanotube-based fluidized bed heat transfer media for concentrating solar power applications |
| KR101567203B1 (ko) | 2014-04-09 | 2015-11-09 | (주)오렌지파워 | 이차 전지용 음극 활물질 및 이의 방법 |
| KR101604352B1 (ko) | 2014-04-22 | 2016-03-18 | (주)오렌지파워 | 음극 활물질 및 이를 포함하는 리튬 이차 전지 |
| JP6252858B2 (ja) * | 2014-04-25 | 2017-12-27 | 株式会社豊田自動織機 | リチウムイオン二次電池用正極及びリチウムイオン二次電池 |
| JP6289995B2 (ja) | 2014-05-13 | 2018-03-07 | 株式会社東芝 | 負極、負極の製造方法、及び非水電解質電池 |
| KR101550781B1 (ko) | 2014-07-23 | 2015-09-08 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자의 제조 방법 |
| GB2529411A (en) * | 2014-08-18 | 2016-02-24 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| GB2529410A (en) * | 2014-08-18 | 2016-02-24 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| EP3208870B1 (en) * | 2014-10-15 | 2020-01-15 | Tokyo University of Science Foundation | Negative electrode for potassium ion secondary batteries, negative electrode for potassium ion capacitors, potassium ion secondary battery, potassium ion capacitor, and binder for negative electrodes of potassium ion secondary batteries or negative electrodes of potassium ion capacitors |
| GB2533161C (en) | 2014-12-12 | 2019-07-24 | Nexeon Ltd | Electrodes for metal-ion batteries |
| KR101614016B1 (ko) | 2014-12-31 | 2016-04-20 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
| JP6407771B2 (ja) * | 2015-03-10 | 2018-10-17 | 大阪瓦斯株式会社 | 振動吸収材及びその製造方法 |
| KR101726037B1 (ko) | 2015-03-26 | 2017-04-11 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
| WO2016160703A1 (en) | 2015-03-27 | 2016-10-06 | Harrup Mason K | All-inorganic solvents for electrolytes |
| US9601763B2 (en) | 2015-03-27 | 2017-03-21 | Nanotek Instruments, Inc. | Process for mass-producing silicon nanowires and silicon nanowire-graphene hybrid particulates |
| CN104792679B (zh) * | 2015-04-08 | 2017-10-27 | 东华大学 | 一种中空微球复合材料孔隙率检测标块及其制备方法 |
| DE102015215415A1 (de) * | 2015-08-12 | 2017-02-16 | Wacker Chemie Ag | Siliciumpartikel enthaltende Anodenmaterialien für Lithium-Ionen-Batterien |
| US10319987B2 (en) * | 2015-12-21 | 2019-06-11 | Nissan North America, Inc. | Active material with expansion structure for use in lithium ion batteries |
| US10535873B2 (en) * | 2016-03-04 | 2020-01-14 | Lg Chem, Ltd. | Positive electrode active material for secondary battery, method of preparing the same and secondary battery including the same |
| ES2993278T3 (en) | 2016-06-14 | 2024-12-26 | Nexeon Ltd | Electrodes for metal-ion batteries |
| KR101773719B1 (ko) | 2016-08-23 | 2017-09-01 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자 및 이의 제조 방법 |
| KR101918815B1 (ko) | 2016-08-23 | 2018-11-15 | 넥시온 엘티디. | 이차 전지용 음극 활물질 및 이의 제조 방법 |
| WO2018056204A1 (ja) * | 2016-09-23 | 2018-03-29 | 株式会社豊田自動織機 | Si粒子結合体及びその製造方法 |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| GB2563455B (en) | 2017-06-16 | 2019-06-19 | Nexeon Ltd | Particulate electroactive materials for use in metal-ion batteries |
| FR3069461B1 (fr) | 2017-07-28 | 2021-12-24 | Enwires | Materiau nanostructure et son procede de preparation |
| GB201803983D0 (en) | 2017-09-13 | 2018-04-25 | Unifrax I Llc | Materials |
| US12218341B2 (en) * | 2018-11-08 | 2025-02-04 | Nexeon Limited | Electroactive materials for metal-ion batteries |
| GB201818235D0 (en) * | 2018-11-08 | 2018-12-26 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| US12106968B2 (en) * | 2019-08-01 | 2024-10-01 | Ram Nanotech, Incorporated | Injection metal assisted catalytic etching |
| KR20210099434A (ko) * | 2020-02-04 | 2021-08-12 | 삼성전자주식회사 | 양극, 이를 포함하는 리튬-공기 전지 및 이의 제조 방법 |
| KR20210099433A (ko) | 2020-02-04 | 2021-08-12 | 삼성전자주식회사 | 양극, 이를 포함하는 리튬-공기 전지 및 이의 제조 방법 |
| WO2021182617A1 (ja) * | 2020-03-13 | 2021-09-16 | 積水化学工業株式会社 | 導電性粒子、導電材料及び接続構造体 |
| CN120933338A (zh) * | 2020-08-03 | 2025-11-11 | 奈克松有限公司 | 用于金属离子电池的电活性材料 |
| KR102411717B1 (ko) * | 2021-05-12 | 2022-06-22 | 아주대학교산학협력단 | 구리 복합 구조체의 제조방법 및 이에 의해 제조된 구리 복합 구조체를 포함하는 에너지 저장 장치 및 라만 분광 기판 구조물 |
| EP4440987A1 (de) * | 2021-12-02 | 2024-10-09 | Wacker Chemie AG | Verfahren zur herstellung von silicium enthaltenden materialien |
| US20230216032A1 (en) * | 2022-01-04 | 2023-07-06 | Prologium Technology Co., Ltd. | Composite negative active material ball |
| JP2024122207A (ja) * | 2023-02-28 | 2024-09-09 | Tdk株式会社 | リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
| JP7696640B2 (ja) * | 2023-07-28 | 2025-06-23 | 学校法人東京電機大学 | リチウムイオン二次電池用負極材料、リチウムイオン二次電池用負極及びリチウムイオン二次電池、並びにこれらの製法方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010533637A (ja) * | 2007-07-17 | 2010-10-28 | ネグゼオン・リミテッド | シリコン又はシリコンベースの材料で構成される構造化粒子の製造方法及びリチウム蓄電池におけるそれらの使用 |
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| US4002541A (en) | 1972-11-03 | 1977-01-11 | Design Systems, Inc. | Solar energy absorbing article and method of making same |
| SU471402A1 (ru) | 1973-03-02 | 1975-05-25 | Предприятие П/Я Г-4671 | Травильный раствор |
| SU544019A1 (ru) | 1975-07-22 | 1977-01-25 | Одесский Ордена Трудового Красного Знамени Государственный Университет Им.И.И.Мечникова | Травитель дл полупроводниковых материалов |
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