JP6452292B2 - 低温でのSiNの蒸着用Si前駆体 - Google Patents
低温でのSiNの蒸着用Si前駆体 Download PDFInfo
- Publication number
- JP6452292B2 JP6452292B2 JP2014046638A JP2014046638A JP6452292B2 JP 6452292 B2 JP6452292 B2 JP 6452292B2 JP 2014046638 A JP2014046638 A JP 2014046638A JP 2014046638 A JP2014046638 A JP 2014046638A JP 6452292 B2 JP6452292 B2 JP 6452292B2
- Authority
- JP
- Japan
- Prior art keywords
- less
- silicon
- silicon nitride
- thin film
- precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002243 precursor Substances 0.000 title claims description 125
- 230000008021 deposition Effects 0.000 title description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 188
- 239000000376 reactant Substances 0.000 claims description 144
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 134
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 134
- 239000010408 film Substances 0.000 claims description 126
- 238000000034 method Methods 0.000 claims description 113
- 239000012686 silicon precursor Substances 0.000 claims description 108
- 239000000758 substrate Substances 0.000 claims description 108
- 238000006243 chemical reaction Methods 0.000 claims description 102
- 229910052757 nitrogen Inorganic materials 0.000 claims description 98
- 229910052710 silicon Inorganic materials 0.000 claims description 81
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 80
- 238000000231 atomic layer deposition Methods 0.000 claims description 80
- 239000010703 silicon Substances 0.000 claims description 80
- 239000010409 thin film Substances 0.000 claims description 70
- 229910052740 iodine Inorganic materials 0.000 claims description 67
- 238000000151 deposition Methods 0.000 claims description 64
- 229910052739 hydrogen Inorganic materials 0.000 claims description 62
- 239000001257 hydrogen Substances 0.000 claims description 50
- 229910052794 bromium Inorganic materials 0.000 claims description 49
- 239000003446 ligand Substances 0.000 claims description 48
- 125000000217 alkyl group Chemical group 0.000 claims description 41
- 229910052736 halogen Inorganic materials 0.000 claims description 39
- 150000002367 halogens Chemical class 0.000 claims description 39
- 238000010926 purge Methods 0.000 claims description 38
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 35
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 34
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 239000006227 byproduct Substances 0.000 claims description 29
- 150000003973 alkyl amines Chemical class 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 24
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 23
- 230000000694 effects Effects 0.000 claims description 21
- 238000005530 etching Methods 0.000 claims description 21
- 239000011630 iodine Substances 0.000 claims description 21
- 150000004703 alkoxides Chemical class 0.000 claims description 19
- 238000011068 loading method Methods 0.000 claims description 19
- 239000013110 organic ligand Substances 0.000 claims description 19
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 17
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 17
- 150000002431 hydrogen Chemical class 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 230000007246 mechanism Effects 0.000 claims description 12
- 150000001923 cyclic compounds Chemical class 0.000 claims description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 9
- 239000012808 vapor phase Substances 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 9
- 239000007864 aqueous solution Substances 0.000 claims 8
- 238000007740 vapor deposition Methods 0.000 claims 7
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 238000007736 thin film deposition technique Methods 0.000 claims 1
- 239000012071 phase Substances 0.000 description 48
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 32
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 32
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 32
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 31
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 19
- 229910052786 argon Inorganic materials 0.000 description 16
- 241000894007 species Species 0.000 description 14
- 239000012159 carrier gas Substances 0.000 description 13
- -1 hydrogen radicals Chemical class 0.000 description 12
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 12
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 12
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 12
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 12
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 11
- 229910052734 helium Inorganic materials 0.000 description 11
- 239000012535 impurity Substances 0.000 description 11
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 125000001246 bromo group Chemical group Br* 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 125000006850 spacer group Chemical group 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000445 field-emission scanning electron microscopy Methods 0.000 description 6
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 6
- 239000002052 molecular layer Substances 0.000 description 6
- 229910052756 noble gas Inorganic materials 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 150000003377 silicon compounds Chemical class 0.000 description 6
- 235000012431 wafers Nutrition 0.000 description 6
- VQPFDLRNOCQMSN-UHFFFAOYSA-N bromosilane Chemical class Br[SiH3] VQPFDLRNOCQMSN-UHFFFAOYSA-N 0.000 description 5
- 238000005137 deposition process Methods 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 238000010923 batch production Methods 0.000 description 4
- 238000000349 field-emission scanning electron micrograph Methods 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- IDIOJRGTRFRIJL-UHFFFAOYSA-N iodosilane Chemical class I[SiH3] IDIOJRGTRFRIJL-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 238000006557 surface reaction Methods 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 229910052743 krypton Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052754 neon Inorganic materials 0.000 description 2
- 150000002831 nitrogen free-radicals Chemical class 0.000 description 2
- 150000002835 noble gases Chemical class 0.000 description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 2
- 238000000624 total reflection X-ray fluorescence spectroscopy Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- UGXMKSYKRKUMGY-UHFFFAOYSA-N 1,3,5,2,4,6-triazatrisilinane Chemical class N1[SiH2]N[SiH2]N[SiH2]1 UGXMKSYKRKUMGY-UHFFFAOYSA-N 0.000 description 1
- 229910007991 Si-N Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910006294 Si—N Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000005389 semiconductor device fabrication Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02205—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition
- H01L21/02208—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/0217—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
- C23C16/345—Silicon nitride
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02205—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition
- H01L21/02208—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si
- H01L21/02211—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being characterised by the precursor material for deposition the precursor containing a compound comprising Si the compound being a silane, e.g. disilane, methylsilane or chlorosilane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/02274—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/0228—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE, pulsed CVD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/30604—Chemical etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66787—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
- H01L29/66795—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Formation Of Insulating Films (AREA)
- Chemical Vapour Deposition (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Description
(1)ケイ素前駆体が、基板表面上に吸着されるように、基板をケイ素前駆体と接触させる工程210、
(2)基板を窒素前駆体と接触させる工程220、ならびに
(3)所望の厚さおよび組成物の薄膜を得るために、必要に応じて何回でも工程210および200を繰り返す工程、を含む。
いくつかの実施形態において、プラズマ増幅ALD(PEALD)プロセスは、SiN膜を蒸着するために用いられる。要するに、基板またはワークピースは、反応チャンバーに配置され、交互の繰り返し表面反応を受ける。いくつかの実施形態において、SiN薄膜は、自己制御的なALDサイクルの繰り返しにより形成される。好ましくは、SiN膜を形成するため、各ALDサイクルは、少なくとも2つの異なる相を含む。反応空間からの反応物質の供給および反応空間からの反応物質の除去は、相を考えられてよい。第一相において、ケイ素を含む第一反応物質は、提供され、そして基板表面にわずかに約1つの単層を形成する。この反応物質は、本願明細書において、「ケイ素前駆体」、「ケイ素含有前駆体」、または「ケイ素反応物質」とも称され、例えばH2SiI2であってよい。
いくつかの好適なケイ素前駆体は、現在開示されているPEALDプロセスに用いられうる。少なくともいくつかの好適な前駆体は、以下の一般式であってよい。
上で論じたように本発明のPEALDプロセスにおける第二反応物質は、反応種を含んでよい窒素前駆体を含んでよい。好適なプラズマ組成物は、1つの形態または別の形態において窒素プラズマ、窒素ラジカル、または原子窒素を包含する。1つの形態または別の形態において、水素プラズマ、水素ラジカル、または原子水素も提供される。いくつかの実施形態において、プラズマは、希ガス(He、Ne、Ar、KrおよびXe、好ましくはArまたはHe)をプラズマ形態で、ラジカルとして、または原子形態で含有されてもよい。いくつかの実施形態において、第二反応物質は希ガス(Arなど)由来のいずれの種も含まない。したがって、いくつかの実施形態において、プラズマは、希ガスを含む気体中で発生されない。
(1)ケイ素化合物が基板表面上に吸着するように、基板を蒸発されたケイ素前駆体310と接触する工程、
(2)反応空間320に窒素前駆体を導入する工程、
(3)窒素前駆体330から反応種を生成する工程、および
(4)基板を反応種と接触させる工程340であって、これにより吸着されたケイ素化合物を窒化ケイ素に変換する工程。
(1)三次元構造を含む基板は、反応空間に提供される工程、
(2)ケイ素含有前駆体(SiI2H2など)は、ケイ素含有前駆体が基板の表面に吸着される反応空間に導入される工程、
(3)過剰のケイ素含有前駆体および反応副生成物は、反応空間から除去される工程、
(4)窒素含有前駆体(N2、NH3、N2H4、またはN2およびH2など)は反応空間に導入される工程、
(5)窒素前駆体から反応種を生成する工程、
(6)基板を反応種と接触させる工程、および
(7)過剰の窒素原子、プラズマ、またはラジカルおよび反応副生成物を除去する工程。
本発明で提供される方法は、熱的ALDプロセスにより、基板表面上への窒化ケイ素フィルムの蒸着も可能とする。三次元構造など幾何学的に困難な利用は、これらの熱的プロセスで可能でもある。いくつかの実施形態によれば、熱的原子層堆積(ALD)型プロセスは、集積回路ワークピースなどの基板上に窒化ケイ素フィルムを形成するために用いられる。
いくつかの好適なケイ素前駆体は、現在開示されている熱的プロセス(熱的ALDプロセスなど)に用いられてよい。いくつかの実施形態において、これらの前駆体は、所望の性質(所望のWER、WERR、パターン負荷効果または/およびステップカバレッジ、以下に記載されている機構のうちの少なくとも1つ)をフィルムが蒸着されるプラズマALDプロセスにおいて用いられてもよい。
窒素を含有するいくつかの好適なケイ素前駆体(ヨウ素または臭素置換シラザンなど)または硫黄を含有するいくつかの好適なケイ素前駆体は、現在開示されている熱的かつプラズマALDプロセスにおいて用いられてよい。いくつかの実施形態において、窒素を含有するケイ素前駆体(ヨウ素または臭素置換シラザンなど)は、所望の性質(例えば、所望のWER、WERR、パターン負荷効果または/および以下に記載されている機構のステップカバレッジのうちの少なくとも1つ)を有するフィルムが蒸着されている現在開示されている熱的かつプラズマALDプロセスにおいて用いられてよい。
いくつかの実施形態によれば、熱的ALDプロセスにおける第二反応物質または窒素前駆体はNH3、N2H4、またはNH3、N2H4、またはN−H結合を有する他の好適な窒素化合物の数であってよい。
(1)ケイ素化合物が基板表面上に吸着するように蒸発されたケイ素前駆体410を基板に接触させる工程、
(2)過剰のケイ素反応物質および任意の副生成物420を除去する工程、
(3)基板を窒素前駆体430と接触させる工程、ならびに
(4)過剰の窒素前駆体および反応副生成物440を除去する工程。
(1)反応空間に充填される基板、
(2)ケイ素含有前駆体(H2SiI2など)は、ケイ素含有前駆体が基板の表面に吸着されるように反応空間に導入される、
(3)過剰のケイ素含有前駆体および反応副生成物を除去する工程はパージする工程などにより除去される、
(4)窒素含有前駆体(NH3またはN2H4など)は反応空間に導入され、基板上でケイ素含有前駆体と反応する、
(5)パージするなどにより、過剰の窒素含有前駆体および反応副生成物を除去する工程、および
(6)段階(2)〜(5)が、所望の厚さの窒化ケイ素フィルムが形成されるまで繰り返されてよい。
本願明細書で論じられる実施形態のいくつかにより蒸着される窒化ケイ素薄膜(ケイ素前駆体が臭素またはヨウ素を含有しているかどうかに関わりなく)は、約3at−%未満、好ましくは約1at−%未満、より好ましくは約0.5at−%未満、最も好ましくは、約0.1at−%未満の不純物レベルまたは濃度を達成するかもしれない。ある薄膜において、水素を除く全不純物レベルは約5at−%未満、好ましくは約2at−%未満、より好ましくは約1at−%未満、最も好ましくは、約0.2at−%未満であってよい。そして、ある薄膜において、水素レベルは約30at−%未満、好ましくは約20at−%未満、より好ましくは約15at−%未満、最も好ましくは、約10at−%未満であってよい。
本願明細書に記載される方法および物質は向上した性質を有するフィルムを提供し得、改善されたエッチング特性は、水平ソース/ドレイン(S/D)およびゲート表面を有する伝統的な側部のトランジスタデザインだけでなく、非水平(例えば、垂直)表面および複雑な三次元(3D)構造に用いられるe改善されたSiNフィルムも提供もし得る。ある実施形態において、SiN膜は、集積回路製作中に三次元構造上に開示された方法により蒸着される。三次元トランジスタは、例えば、二重ゲート電界効果トランジスタ(DG FET)、およびFinFETを包含している他の型の多点ゲートFETを包含するかもしれない。例えば、本発明の窒化ケイ素薄膜は、非平面多点ゲートトランジスタ(FinFETなど)において有用であり得、ゲート、ソース、およびドレイン領域の最上部に加えて垂直な壁上にケイ化物を形成するのも望ましいかもしれない。
シラン前駆体としてH2SiI2および窒素前駆体としてH2+N2プラズマを用いるPEALDプロセスによる本願明細書の記載に基づき、窒化ケイ素薄膜を400℃で蒸着した。このフィルムは、ALD反応型(典型的な高品質のPEALD SiN膜)と熱ALDフィルムの等方性のエッチング態様と両方の最高の性質のいくつかの組み合わせを示した。しかしこれらの結果は完全には理解されず、フィルム特性およびエッチング態様は、それにもかかわらず高品質スペーサ層用途のスペックにあった。
改善されたエッチング特性および不純物含有量を含む窒化ケイ素薄膜(実施例1との比較)を、直流プラズマALDシャワーヘッド反応器中、本発明のPEALDプロセスにより蒸着した。200℃および400℃のサセプタ温度を用いた。H2SiI2をケイ素前駆体として用い、H2+N2プラズマを窒素前駆体として用いた。プラズマ出力は約200W〜約220Wであり、シャワーヘッドプレートおよびサセプタの間の空間(すなわち、プラズマが発生する空間)は、10mmだった。プラズマはArを含有していなかった。窒素をキャリアガスとして用い、蒸着プロセスの全体にわたって流した。H2SiI2消費は約9.0mg/サイクルだった。
Claims (36)
- (a)ケイ素前駆体が基板の表面に吸着されるように反応空間に気相のケイ素反応物質を導入する工程、
(b)過剰のケイ素反応物質および反応副生成物を除去する工程、
(c)吸着された前記ケイ素前駆体を窒素前駆体からのプラズマにより生成される反応種と接触させる工程、
(d)過剰の反応種および反応副生成物を除去する工程、
を含み、
ここで、工程(a)〜(d)が所望の厚さの窒化ケイ素フィルムが形成されるまで繰り返され、前記ケイ素反応物質がヨウ素または臭素を含み、
三次元機構の上面における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度に対する三次元機構の側壁における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度の割合が4未満である、
反応空間における基板上への窒化ケイ素薄膜の蒸着方法。 - 前記ケイ素反応物質が、式(1)〜式(8)の1つの式を有する前駆体を含む、請求項1に記載の蒸着方法。
式(1) H 2n+2−y−z Si n X y A z
(式中、nは1以上10以下、yは1以上(2n+2−z)以下、zは0以上(2n+2−y)以下、XはIまたはBr、AはX以外のハロゲンである。)
式(2) H 2n−y−z Si n X y A z
(式中、式(2)の化合物は環状化合物であり、nは3以上10以下、yは1以上(2n−z)以下、zは0以上(2n−y)以下、XはIまたはBr、AはX以外のハロゲンである。)
式(3) H 2n+2−y−z Si n I y A z
(式中、nは1以上10以下、yは1以上(2n+2−z)以下、zは0以上(2n+2−y)以下、AはI以外のハロゲンである。)
式(4) H 2n−y−z Si n I y A z
(式中、式(4)の化合物は環状化合物であり、nは3以上10以下、yは1以上(2n−z)以下、zは0以上(2n−y)以下、AはI以外のハロゲンである。)
式(5) H 2n+2−y−z Si n Br y A z
(式中、nは1以上10以下、yは1以上(2n+2−z)以下、zは0以上(2n+2−y)以下、AはBr以外のハロゲンである。)
式(6) H 2n−y−z Si n Br y A z
(式中、式(6)の化合物は環状化合物であり、nは3以上10以下、yは1以上(2n−z)以下、zは0以上(2n−y)以下、AはBr以外のハロゲンである。)
式(7) H 2n+2−y Si n I y
(式中、nは1以上5以下、yは1以上(2n+2)以下である。)
式(8) H 2n+2−y Si n Br y
(式中、nは1以上5以下、yは1以上(2n+2)以下である。) - 前記反応種が、水素、水素原子、水素プラズマ、水素ラジカル、N*ラジカル、NH*ラジカルまたはNH2*ラジカルを含む、請求項1に記載の蒸着方法。
- 前記反応種が前記基板上に直接発生される、請求項1に記載の蒸着方法。
- 前記反応種が前記基板から離れて発生される、請求項1に記載の蒸着方法。
- 遠隔プラズマ発生器が、前記反応種を発生するために用いられる、請求項5に記載の蒸着方法。
- 前記ケイ素反応物質が、HSiI3、H2SiI2、H3SiI、H2Si2I4、H4Si2I2、およびH5Si2Iからなる群から選択される、請求項1に記載の蒸着方法。
- 前記ケイ素反応物質がH2SiI2である、請求項7に記載の蒸着方法。
- 300℃〜400℃の温度で行われる、請求項1に記載の蒸着方法。
- 前記窒素前駆体が、NH3、N2H4、N2/H2の混合物、N2、およびこれらの任意の混合物からなる群から選択される、請求項1に記載の蒸着方法。
- 前記窒化ケイ素薄膜が、少なくとも80%のステップカバレッジおよびパターン負荷効果を示す、請求項1に記載の蒸着方法。
- 前記窒化ケイ素薄膜が三次元構造上に形成される、請求項1に記載の蒸着方法。
- 前記上面における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度に対する少なくとも1つの三次元機構の側壁における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度の割合が3未満である、請求項1に記載の蒸着方法。
- 前記窒化ケイ素薄膜のエッチング速度が0.5%のHF水溶液中4nm/分未満である、請求項1に記載の蒸着方法。
- 前記窒化ケイ素薄膜がFinFETの成形の間に蒸着される、請求項1に記載の蒸着方法。
- 前記吸着されたケイ素前駆体がArのプラズマにより発生した反応種と接触しない、請求項1に記載の蒸着方法。
- 前記反応空間がシャワーヘッド反応器の部分であり、シャワーヘッドおよびサセプタを含む、請求項1に記載の蒸着方法。
- 前記シャワーヘッドおよびサセプタの間に0.5cm〜5cmの隙間がある、請求項17に記載の蒸着方法。
- (a)少なくとも1つの三次元機構を有する基板を反応空間に充填する工程、
(b)ケイ素前駆体が、前記基板の表面に吸着されるように前記ケイ素前駆体を前記反応空間に導入する工程、
(c)前記反応空間の過剰のケイ素含有前駆体および反応副生成物をパージする工程、
(d)窒素前駆体を前記反応空間に導入する工程、
(e)前記反応空間の過剰の窒素前駆体および反応副生成物をパージする工程、
を含む窒化ケイ素薄膜の蒸着方法であって、
所望の厚さの窒化ケイ素薄膜が形成されるまで段階(b)〜(e)を繰り返し、
前記ケイ素含有前駆体が、ヨウ素または臭素を含み、
前記窒化ケイ素薄膜が、前記少なくとも1つの三次元機構に50%超のステップカバレッジを有し、
前記窒化ケイ素薄膜のエッチング速度が0.5%のHF水溶液中5nm/分未満であり、
前記少なくとも1つの三次元機構の上面における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度に対する前記少なくとも1つの三次元機構の側壁における前記窒化ケイ素薄膜のエッチング速度の割合が4未満である、窒化ケイ素薄膜の蒸着方法。 - 前記窒化ケイ素薄膜が、80%超のステップカバレッジを有する、請求項19に記載の蒸着方法。
- 前記窒化ケイ素薄膜が、90%超のステップカバレッジを有する、請求項19に記載の蒸着方法。
- 前記プロセスが熱的原子層堆積プロセスである、請求項19に記載の蒸着方法。
- 前記プロセスがプラズマで増幅された原子層堆積プロセスである、請求項19に記載の蒸着方法。
- 前記ケイ素含有前駆体が、式(9)〜式(20)の1つの一般式を有する、請求項19に記載の蒸着方法。
式(9) H 2n+2−y−zーw Si n X y A z R w
(式中、nは1以上10以下、yは1以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは0以上(2n+2−y−z)以下、XはIまたはBr、AはX以外のハロゲン、Rは有機リガンドであり、およびアルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(10) H 2n−y−zーw Si n X y A z R w
(式中、nは3以上10以下、yは1以上(2n−z−w)以下、zは0以上(2n−y−w)以下、wは0以上(2n−y−z)以下、XはIまたはBr、AはX以外のハロゲン、Rは有機リガンドであり、アルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(11) H 2n+2−y−zーw Si n I y A z R w
(式中、nは1以上10以下、yは1以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは0以上(2n+2−y−z)以下、AはI以外のハロゲン、Rは有機リガンドであり、アルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(12) H 2n−y−zーw Si n I y A z R w
(式中、nは3以上10以下、yは1以上(2n−z−w以下)、zは0以上(2n−y−w以下)、wは0以上(2n−y−z)以下、AはI以外のハロゲン、Rは有機リガンドであり、アルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(13) H 2n+2−y−zーw Si n Br y A z R w
(式中、nは1以上10以下、yは1以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは0以上(2n+2−y−z)以下、AはBr以外のハロゲン、Rは有機リガンドであり、アルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(14) H 2n−y−zーw Si n Br y A z R w
(式中、nは3以上10以下、yは1以上(2n−z−w)以下、zは0以上(2n−y−w)以下、wは0以上(2n−y−z)以下、AはBr以外のハロゲン、Rは有機リガンドであり、アルコキシド、アルキルシリル、アルキル、置換アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(15) H 2n+2−y−zーw Si n X y A z R II w
(式中、nは1以上10以下、yは0以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは1以上(n+2−y−z)以下、XはIまたはBr、AはX以外のハロゲン、R II はIまたはBrを含有する有機リガンドであって、IまたはBrで置換されたアルコキシド、アルキルシリル、アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(16) H 2n−y−zーw Si n X y A z R II w
(式中、nは3以上10以下、yは0以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは1以上(n+2−y−z)以下、XはIまたはBr、AはX以外のハロゲンであり、R II はIまたはBrを含有する有機リガンドであり、IまたはBrで置換されるアルコキシド、アルキルシリル、アルキル、アルキルアミンおよび不飽和炭化水素からなる群から独立に選択される。)
式(17) H 2n+2−y−zーw Si n X y A z (NR 1 R 2 ) w
(式中、nは1以上10以下、yは1以上(2n+2−z−w)以下、zは0以上(2n+2−y−w)以下、wは1以上(n+2−y−z)以下、XはIまたはBr、AはX以外のハロゲン、Nは窒素、R 1 およびR 2 は独立に水素、アルキル、置換アルキル、シリル、アルキルシリルおよび不飽和炭化水素からなる群から選択される。(NR 1 R 2 ) w リガンドは、それぞれ互いに独立に選択され得る。)
式(18) H 3−y−zーw X y A z ((NR 1 R 2 ) w Si) 3 −N
(式中、yは1以上(3−z−w)以下、z=0以上(3−y−w)以下、wは1以上(3−y−z)以下、XはIまたはB、AはX以外のハロゲン、Nは窒素、R 1 およびR 2 は、水素、アルキル、置換アルキル、シリル、アルキルシリル、および不飽和炭化水素からなる群から独立に選択される。(NR 1 R 2 ) w リガンドは、それぞれ互いに独立に選択され得る。3つのH 3−y−z−w X y A z (NR 1 R 2 ) w Siリガンドは、互いに独立に選択され得る。)
式(19) H 2n+2−yーw Si n I y (NR 1 R 2 ) w
(式中、nは1以上10以下、yは1以上(2n+2−w)以下、wは1以上(2n+2−y)以下、Nは窒素、R 1 およびR 2 は独立に水素、アルキル、置換アルキル、シリル、アルキルシリル、および不飽和炭化水素からなる群から選択される。(NR 1 R 2 ) w リガンドのそれぞれは互いに独立に選択され得る。)
式(20) H 3−yーw I y ((NR 1 R 2 ) w Si) 3 −N
(式中、yは1以上(3−w)以下、wは1以上(3−y)以下、Nは窒素であり、R 1 およびR 2 は水素、アルキル、置換アルキル、シリル、アルキルシリル、および不飽和炭化水素からなる群から独立に選択される。3つのH 3−y−w I y (NR 1 R 2 ) w Siリガンドは、それぞれ互いに独立に選択され得る。) - 前記ケイ素含有前駆体が、HSiI3、H2SiI2、H3SiI、H2Si2I4、H4Si2I2、H5Si2I、MeSiI3、Me2SiI2、Me3SiI、Me2Si2I4、Me4Si2I2、HMeSiI2、H2Me2Si2I2、EtSiI3、Et2SiI2、Et3SiI、Et2Si2I4、Et4Si2I2、およびHEtSiI2からなる群から選択される、請求項19に記載の蒸着方法。
- 前記ケイ素含有前駆体がH2SiI2である、請求項25に記載の蒸着方法。
- 前記方法が、300℃〜400℃の温度で行われる、請求項19に記載の蒸着方法。
- 前記窒化ケイ素薄膜が、少なくとも80%のステップカバレッジおよびパターン負荷効果を示す、請求項19に記載の蒸着方法。
- 前記少なくとも1つの三次元機構の上面における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度に対する前記少なくとも1つの三次元機構の側壁における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度が3未満である、請求項19に記載の蒸着方法。
- 前記少なくとも1つの三次元機構の上面における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度に対する前記少なくとも1つの三次元機構の側壁における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度が、1である、請求項19に記載の蒸着方法。
- 前記エッチング速度が、3nm/分未満である、請求項19に記載の蒸着方法。
- (a)ケイ素前駆体が基板の表面に吸着されるように、前記基板を気相のケイ素前駆体に曝す工程、
(b)前記基板をパージガスおよび/または真空に曝して、前記基板表面から過剰のケイ素前駆体および反応副生成物を除去する工程、
(c)前記吸着されたケイ素前駆体を窒素含有プラズマにより生成された種と接触させる工程、ならびに
(d)前記基板をパージガスおよび/または真空に曝して、前記基板表面および前記基板表面付近から窒素含有プラズマの種および反応副生成物を除去する工程、
を含む基板上への窒化ケイ素薄膜の蒸着方法であって、
工程(a)〜(d)が所望の厚さの窒化ケイ素フィルムが形成されるまで繰り返され、
ケイ素反応物質がヨウ素または臭素を含み、
三次元機構の上面における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度に対する三次元機構の側壁における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度の割合が4未満である、
窒化ケイ素薄膜の蒸着方法。 - (a)ケイ素反応物質が基板表面に吸着されるように、前記基板を気相ケイ素反応物質に曝す工程、
(b)前記基板をパージガスおよび/または真空に曝して、前記基板表面から過剰のケイ素反応物質および反応副生成物を除去する工程、
(c)前記吸着されたケイ素反応物質を窒素前駆体と接触させる工程、
(d)前記基板をパージガスおよび/または真空に曝して、前記基板表面および前記基板表面付近から過剰の窒素前駆体を除去する工程、
を含む、少なくとも1つの三次元機構を含む基板上への窒化ケイ素薄膜の蒸着方法であって、
所望の厚さの窒化ケイ素薄膜が形成されるまで段階(a)〜(d)を繰り返し、
ここで、ケイ素含有前駆体がヨウ素または臭素を含有し、
前記窒化ケイ素薄膜が、50%超のステップカバレッジを有し、
前記窒化ケイ素薄膜のエッチング速度が0.5%のHF水溶液中5nm/分未満であり、ならびに
前記少なくとも1つの三次元機構の上面における前記窒化ケイ素薄膜のエッチング速度に対する前記少なくとも1つの三次元機構の側壁における0.5%のHF水溶液中の前記窒化ケイ素薄膜のエッチング速度の割合は4未満である、窒化ケイ素薄膜の蒸着方法。 - 窒化ケイ素薄膜を形成する原子層堆積(ALD)方法であって、前記方法は、複数のサイクルを含み、各サイクルは、反応空間中の基板をケイ素反応物質と第二反応物質との気相パルスと交互にかつ連続的に接触させる工程を含み、
ここで、過剰のケイ素反応物質は、前記ケイ素反応物質の気相パルスへの前記基板の接触と、前記第二反応物質の気相パルスへの前記基板の接触との間に、前記反応空間から取り除かれ、また、
ここで、前記ケイ素反応物質は、以下の式を有する前駆体を含む、原子層堆積(ALD)方法。
H2n+2−y−wSinIy(NR1R2)w
(式中、n=1〜10、y=1またはそれ以上(最大2n+2−w)、w=1またはそれ以上(最大2n+2−y)、Nは窒素、ならびにR1およびR2は、独立に水素、アルキル、置換アルキル、シリル、アルキルシリル、および不飽和炭化水素からなる群から選択され、
少なくとも1つの三次元機構の上面における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度に対する少なくとも1つの三次元機構の側壁における0.5%のHF水溶液中の窒化ケイ素薄膜のエッチング速度の割合が4未満である。) - 前記第二反応物質が窒素前駆体を含む、請求項34に記載の方法。
- 前記窒素前駆体が、窒素含有プラズマ由来の反応種を含む、請求項35に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/830,084 | 2013-03-14 | ||
US13/830,084 US9824881B2 (en) | 2013-03-14 | 2013-03-14 | Si precursors for deposition of SiN at low temperatures |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018231362A Division JP2019062225A (ja) | 2013-03-14 | 2018-12-11 | 低温でのSiNの蒸着用Si前駆体 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014179607A JP2014179607A (ja) | 2014-09-25 |
JP2014179607A5 JP2014179607A5 (ja) | 2017-04-06 |
JP6452292B2 true JP6452292B2 (ja) | 2019-01-16 |
Family
ID=51500341
Family Applications (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014046638A Active JP6452292B2 (ja) | 2013-03-14 | 2014-03-10 | 低温でのSiNの蒸着用Si前駆体 |
JP2018231362A Pending JP2019062225A (ja) | 2013-03-14 | 2018-12-11 | 低温でのSiNの蒸着用Si前駆体 |
JP2020087411A Active JP7219738B2 (ja) | 2013-03-14 | 2020-05-19 | 低温でのSiNの蒸着用Si前駆体 |
JP2020206502A Active JP7123115B2 (ja) | 2013-03-14 | 2020-12-14 | 低温でのSiNの蒸着用Si前駆体 |
JP2022181645A Active JP7383106B2 (ja) | 2013-03-14 | 2022-11-14 | 低温でのSiNの堆積用Si前駆体 |
JP2023188399A Pending JP2024023223A (ja) | 2013-03-14 | 2023-11-02 | 低温でのSiNの堆積用Si前駆体 |
Family Applications After (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018231362A Pending JP2019062225A (ja) | 2013-03-14 | 2018-12-11 | 低温でのSiNの蒸着用Si前駆体 |
JP2020087411A Active JP7219738B2 (ja) | 2013-03-14 | 2020-05-19 | 低温でのSiNの蒸着用Si前駆体 |
JP2020206502A Active JP7123115B2 (ja) | 2013-03-14 | 2020-12-14 | 低温でのSiNの蒸着用Si前駆体 |
JP2022181645A Active JP7383106B2 (ja) | 2013-03-14 | 2022-11-14 | 低温でのSiNの堆積用Si前駆体 |
JP2023188399A Pending JP2024023223A (ja) | 2013-03-14 | 2023-11-02 | 低温でのSiNの堆積用Si前駆体 |
Country Status (5)
Country | Link |
---|---|
US (3) | US9824881B2 (ja) |
JP (6) | JP6452292B2 (ja) |
KR (5) | KR102039035B1 (ja) |
CN (2) | CN109252145B (ja) |
TW (9) | TWI680202B (ja) |
Families Citing this family (394)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10378106B2 (en) | 2008-11-14 | 2019-08-13 | Asm Ip Holding B.V. | Method of forming insulation film by modified PEALD |
US9394608B2 (en) | 2009-04-06 | 2016-07-19 | Asm America, Inc. | Semiconductor processing reactor and components thereof |
US8802201B2 (en) | 2009-08-14 | 2014-08-12 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species |
US8637411B2 (en) | 2010-04-15 | 2014-01-28 | Novellus Systems, Inc. | Plasma activated conformal dielectric film deposition |
US9257274B2 (en) | 2010-04-15 | 2016-02-09 | Lam Research Corporation | Gapfill of variable aspect ratio features with a composite PEALD and PECVD method |
US9287113B2 (en) | 2012-11-08 | 2016-03-15 | Novellus Systems, Inc. | Methods for depositing films on sensitive substrates |
US9312155B2 (en) | 2011-06-06 | 2016-04-12 | Asm Japan K.K. | High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules |
US10364496B2 (en) | 2011-06-27 | 2019-07-30 | Asm Ip Holding B.V. | Dual section module having shared and unshared mass flow controllers |
US10854498B2 (en) | 2011-07-15 | 2020-12-01 | Asm Ip Holding B.V. | Wafer-supporting device and method for producing same |
US20130023129A1 (en) | 2011-07-20 | 2013-01-24 | Asm America, Inc. | Pressure transmitter for a semiconductor processing environment |
US9017481B1 (en) | 2011-10-28 | 2015-04-28 | Asm America, Inc. | Process feed management for semiconductor substrate processing |
US8592328B2 (en) | 2012-01-20 | 2013-11-26 | Novellus Systems, Inc. | Method for depositing a chlorine-free conformal sin film |
US9659799B2 (en) | 2012-08-28 | 2017-05-23 | Asm Ip Holding B.V. | Systems and methods for dynamic semiconductor process scheduling |
US9021985B2 (en) | 2012-09-12 | 2015-05-05 | Asm Ip Holdings B.V. | Process gas management for an inductively-coupled plasma deposition reactor |
US10714315B2 (en) | 2012-10-12 | 2020-07-14 | Asm Ip Holdings B.V. | Semiconductor reaction chamber showerhead |
US20160376700A1 (en) | 2013-02-01 | 2016-12-29 | Asm Ip Holding B.V. | System for treatment of deposition reactor |
US9484191B2 (en) | 2013-03-08 | 2016-11-01 | Asm Ip Holding B.V. | Pulsed remote plasma method and system |
US9589770B2 (en) | 2013-03-08 | 2017-03-07 | Asm Ip Holding B.V. | Method and systems for in-situ formation of intermediate reactive species |
US9824881B2 (en) | 2013-03-14 | 2017-11-21 | Asm Ip Holding B.V. | Si precursors for deposition of SiN at low temperatures |
US9564309B2 (en) | 2013-03-14 | 2017-02-07 | Asm Ip Holding B.V. | Si precursors for deposition of SiN at low temperatures |
TW201441408A (zh) * | 2013-03-15 | 2014-11-01 | Applied Materials Inc | 包含氮化矽之膜的電漿輔助原子層沉積 |
US9240412B2 (en) | 2013-09-27 | 2016-01-19 | Asm Ip Holding B.V. | Semiconductor structure and device and methods of forming same using selective epitaxial process |
US9576790B2 (en) | 2013-10-16 | 2017-02-21 | Asm Ip Holding B.V. | Deposition of boron and carbon containing materials |
US9362109B2 (en) | 2013-10-16 | 2016-06-07 | Asm Ip Holding B.V. | Deposition of boron and carbon containing materials |
US10023958B2 (en) | 2013-11-22 | 2018-07-17 | Applied Materials, Inc. | Atomic layer deposition of films comprising silicon, carbon and nitrogen using halogenated silicon precursors |
US11549181B2 (en) | 2013-11-22 | 2023-01-10 | Applied Materials, Inc. | Methods for atomic layer deposition of SiCO(N) using halogenated silylamides |
US9401273B2 (en) | 2013-12-11 | 2016-07-26 | Asm Ip Holding B.V. | Atomic layer deposition of silicon carbon nitride based materials |
US10683571B2 (en) | 2014-02-25 | 2020-06-16 | Asm Ip Holding B.V. | Gas supply manifold and method of supplying gases to chamber using same |
US10167557B2 (en) | 2014-03-18 | 2019-01-01 | Asm Ip Holding B.V. | Gas distribution system, reactor including the system, and methods of using the same |
US11015245B2 (en) | 2014-03-19 | 2021-05-25 | Asm Ip Holding B.V. | Gas-phase reactor and system having exhaust plenum and components thereof |
US10858737B2 (en) | 2014-07-28 | 2020-12-08 | Asm Ip Holding B.V. | Showerhead assembly and components thereof |
US9890456B2 (en) | 2014-08-21 | 2018-02-13 | Asm Ip Holding B.V. | Method and system for in situ formation of gas-phase compounds |
US9576792B2 (en) | 2014-09-17 | 2017-02-21 | Asm Ip Holding B.V. | Deposition of SiN |
US9214333B1 (en) * | 2014-09-24 | 2015-12-15 | Lam Research Corporation | Methods and apparatuses for uniform reduction of the in-feature wet etch rate of a silicon nitride film formed by ALD |
US9657845B2 (en) | 2014-10-07 | 2017-05-23 | Asm Ip Holding B.V. | Variable conductance gas distribution apparatus and method |
US10941490B2 (en) | 2014-10-07 | 2021-03-09 | Asm Ip Holding B.V. | Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same |
KR102300403B1 (ko) | 2014-11-19 | 2021-09-09 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 |
US9589790B2 (en) * | 2014-11-24 | 2017-03-07 | Lam Research Corporation | Method of depositing ammonia free and chlorine free conformal silicon nitride film |
US9564312B2 (en) | 2014-11-24 | 2017-02-07 | Lam Research Corporation | Selective inhibition in atomic layer deposition of silicon-containing films |
KR102263121B1 (ko) | 2014-12-22 | 2021-06-09 | 에이에스엠 아이피 홀딩 비.브이. | 반도체 소자 및 그 제조 방법 |
US10529542B2 (en) | 2015-03-11 | 2020-01-07 | Asm Ip Holdings B.V. | Cross-flow reactor and method |
US10276355B2 (en) | 2015-03-12 | 2019-04-30 | Asm Ip Holding B.V. | Multi-zone reactor, system including the reactor, and method of using the same |
US10246772B2 (en) | 2015-04-01 | 2019-04-02 | Applied Materials, Inc. | Plasma enhanced chemical vapor deposition of films for improved vertical etch performance in 3D NAND memory devices |
US9502238B2 (en) | 2015-04-03 | 2016-11-22 | Lam Research Corporation | Deposition of conformal films by atomic layer deposition and atomic layer etch |
WO2016205196A2 (en) * | 2015-06-16 | 2016-12-22 | Air Products And Chemicals, Inc. | Halidosilane compounds and compositions and processes for depositing silicon-containing films using same |
KR102410146B1 (ko) | 2015-06-26 | 2022-06-16 | 삼성전자주식회사 | 반도체 장치의 제조 방법 |
US10458018B2 (en) | 2015-06-26 | 2019-10-29 | Asm Ip Holding B.V. | Structures including metal carbide material, devices including the structures, and methods of forming same |
US10600673B2 (en) | 2015-07-07 | 2020-03-24 | Asm Ip Holding B.V. | Magnetic susceptor to baseplate seal |
US10043661B2 (en) | 2015-07-13 | 2018-08-07 | Asm Ip Holding B.V. | Method for protecting layer by forming hydrocarbon-based extremely thin film |
KR102505242B1 (ko) | 2015-07-21 | 2023-03-06 | 삼성전자주식회사 | 반도체 장치 및 그 제조 방법 |
US10083836B2 (en) | 2015-07-24 | 2018-09-25 | Asm Ip Holding B.V. | Formation of boron-doped titanium metal films with high work function |
KR20180032678A (ko) * | 2015-08-21 | 2018-03-30 | 어플라이드 머티어리얼스, 인코포레이티드 | 고온 열적 ald 실리콘 질화물 막들 |
US10410857B2 (en) * | 2015-08-24 | 2019-09-10 | Asm Ip Holding B.V. | Formation of SiN thin films |
US9601693B1 (en) | 2015-09-24 | 2017-03-21 | Lam Research Corporation | Method for encapsulating a chalcogenide material |
US9960072B2 (en) | 2015-09-29 | 2018-05-01 | Asm Ip Holding B.V. | Variable adjustment for precise matching of multiple chamber cavity housings |
US10211308B2 (en) | 2015-10-21 | 2019-02-19 | Asm Ip Holding B.V. | NbMC layers |
US10322384B2 (en) | 2015-11-09 | 2019-06-18 | Asm Ip Holding B.V. | Counter flow mixer for process chamber |
US9786492B2 (en) * | 2015-11-12 | 2017-10-10 | Asm Ip Holding B.V. | Formation of SiOCN thin films |
US9786491B2 (en) | 2015-11-12 | 2017-10-10 | Asm Ip Holding B.V. | Formation of SiOCN thin films |
US11139308B2 (en) | 2015-12-29 | 2021-10-05 | Asm Ip Holding B.V. | Atomic layer deposition of III-V compounds to form V-NAND devices |
US10053775B2 (en) | 2015-12-30 | 2018-08-21 | L'air Liquide, Societé Anonyme Pour L'etude Et L'exploitation Des Procédés Georges Claude | Methods of using amino(bromo)silane precursors for ALD/CVD silicon-containing film applications |
US9701695B1 (en) | 2015-12-30 | 2017-07-11 | American Air Liquide, Inc. | Synthesis methods for amino(halo)silanes |
US9777373B2 (en) | 2015-12-30 | 2017-10-03 | American Air Liquide, Inc. | Amino(iodo)silane precursors for ALD/CVD silicon-containing film applications and methods of using the same |
US10699897B2 (en) * | 2016-01-24 | 2020-06-30 | Applied Materials, Inc. | Acetylide-based silicon precursors and their use as ALD/CVD precursors |
US9754779B1 (en) * | 2016-02-19 | 2017-09-05 | Asm Ip Holding B.V. | Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches |
US10529554B2 (en) | 2016-02-19 | 2020-01-07 | Asm Ip Holding B.V. | Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches |
US10468251B2 (en) | 2016-02-19 | 2019-11-05 | Asm Ip Holding B.V. | Method for forming spacers using silicon nitride film for spacer-defined multiple patterning |
US10501866B2 (en) | 2016-03-09 | 2019-12-10 | Asm Ip Holding B.V. | Gas distribution apparatus for improved film uniformity in an epitaxial system |
JP6946320B2 (ja) * | 2016-03-13 | 2021-10-06 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | スペーサ用の窒化ケイ素膜の選択的堆積 |
US10343920B2 (en) | 2016-03-18 | 2019-07-09 | Asm Ip Holding B.V. | Aligned carbon nanotubes |
US9892913B2 (en) | 2016-03-24 | 2018-02-13 | Asm Ip Holding B.V. | Radial and thickness control via biased multi-port injection settings |
US10087522B2 (en) | 2016-04-21 | 2018-10-02 | Asm Ip Holding B.V. | Deposition of metal borides |
US10865475B2 (en) | 2016-04-21 | 2020-12-15 | Asm Ip Holding B.V. | Deposition of metal borides and silicides |
US10190213B2 (en) | 2016-04-21 | 2019-01-29 | Asm Ip Holding B.V. | Deposition of metal borides |
US10032628B2 (en) | 2016-05-02 | 2018-07-24 | Asm Ip Holding B.V. | Source/drain performance through conformal solid state doping |
US10367080B2 (en) | 2016-05-02 | 2019-07-30 | Asm Ip Holding B.V. | Method of forming a germanium oxynitride film |
KR102378021B1 (ko) | 2016-05-06 | 2022-03-23 | 에이에스엠 아이피 홀딩 비.브이. | SiOC 박막의 형성 |
KR102592471B1 (ko) | 2016-05-17 | 2023-10-20 | 에이에스엠 아이피 홀딩 비.브이. | 금속 배선 형성 방법 및 이를 이용한 반도체 장치의 제조 방법 |
US11453943B2 (en) | 2016-05-25 | 2022-09-27 | Asm Ip Holding B.V. | Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor |
US10388509B2 (en) | 2016-06-28 | 2019-08-20 | Asm Ip Holding B.V. | Formation of epitaxial layers via dislocation filtering |
US9773643B1 (en) | 2016-06-30 | 2017-09-26 | Lam Research Corporation | Apparatus and method for deposition and etch in gap fill |
US10062563B2 (en) | 2016-07-01 | 2018-08-28 | Lam Research Corporation | Selective atomic layer deposition with post-dose treatment |
US9812319B1 (en) * | 2016-07-06 | 2017-11-07 | Asm Ip Holding B.V. | Method for forming film filled in trench without seam or void |
US10612137B2 (en) | 2016-07-08 | 2020-04-07 | Asm Ip Holdings B.V. | Organic reactants for atomic layer deposition |
US9859151B1 (en) | 2016-07-08 | 2018-01-02 | Asm Ip Holding B.V. | Selective film deposition method to form air gaps |
US9793135B1 (en) | 2016-07-14 | 2017-10-17 | ASM IP Holding B.V | Method of cyclic dry etching using etchant film |
US10714385B2 (en) | 2016-07-19 | 2020-07-14 | Asm Ip Holding B.V. | Selective deposition of tungsten |
US9929006B2 (en) * | 2016-07-20 | 2018-03-27 | Micron Technology, Inc. | Silicon chalcogenate precursors, methods of forming the silicon chalcogenate precursors, and related methods of forming silicon nitride and semiconductor structures |
KR102354490B1 (ko) | 2016-07-27 | 2022-01-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 |
US9812320B1 (en) | 2016-07-28 | 2017-11-07 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US10177025B2 (en) | 2016-07-28 | 2019-01-08 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US9887082B1 (en) | 2016-07-28 | 2018-02-06 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
KR102532607B1 (ko) | 2016-07-28 | 2023-05-15 | 에이에스엠 아이피 홀딩 비.브이. | 기판 가공 장치 및 그 동작 방법 |
US10395919B2 (en) | 2016-07-28 | 2019-08-27 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US10629435B2 (en) | 2016-07-29 | 2020-04-21 | Lam Research Corporation | Doped ALD films for semiconductor patterning applications |
US9865456B1 (en) * | 2016-08-12 | 2018-01-09 | Micron Technology, Inc. | Methods of forming silicon nitride by atomic layer deposition and methods of forming semiconductor structures |
US10074543B2 (en) | 2016-08-31 | 2018-09-11 | Lam Research Corporation | High dry etch rate materials for semiconductor patterning applications |
US10037884B2 (en) | 2016-08-31 | 2018-07-31 | Lam Research Corporation | Selective atomic layer deposition for gapfill using sacrificial underlayer |
US10090316B2 (en) | 2016-09-01 | 2018-10-02 | Asm Ip Holding B.V. | 3D stacked multilayer semiconductor memory using doped select transistor channel |
US9865455B1 (en) * | 2016-09-07 | 2018-01-09 | Lam Research Corporation | Nitride film formed by plasma-enhanced and thermal atomic layer deposition process |
KR20180034798A (ko) * | 2016-09-28 | 2018-04-05 | 삼성전자주식회사 | 유전막 형성 방법 및 반도체 장치의 제조 방법 |
US10410943B2 (en) | 2016-10-13 | 2019-09-10 | Asm Ip Holding B.V. | Method for passivating a surface of a semiconductor and related systems |
US10643826B2 (en) | 2016-10-26 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for thermally calibrating reaction chambers |
US11532757B2 (en) | 2016-10-27 | 2022-12-20 | Asm Ip Holding B.V. | Deposition of charge trapping layers |
US10714350B2 (en) | 2016-11-01 | 2020-07-14 | ASM IP Holdings, B.V. | Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10435790B2 (en) | 2016-11-01 | 2019-10-08 | Asm Ip Holding B.V. | Method of subatmospheric plasma-enhanced ALD using capacitively coupled electrodes with narrow gap |
US10643904B2 (en) | 2016-11-01 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for forming a semiconductor device and related semiconductor device structures |
US10229833B2 (en) | 2016-11-01 | 2019-03-12 | Asm Ip Holding B.V. | Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10134757B2 (en) | 2016-11-07 | 2018-11-20 | Asm Ip Holding B.V. | Method of processing a substrate and a device manufactured by using the method |
US10454029B2 (en) | 2016-11-11 | 2019-10-22 | Lam Research Corporation | Method for reducing the wet etch rate of a sin film without damaging the underlying substrate |
US10832908B2 (en) | 2016-11-11 | 2020-11-10 | Lam Research Corporation | Self-aligned multi-patterning process flow with ALD gapfill spacer mask |
US10134579B2 (en) | 2016-11-14 | 2018-11-20 | Lam Research Corporation | Method for high modulus ALD SiO2 spacer |
KR102546317B1 (ko) | 2016-11-15 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | 기체 공급 유닛 및 이를 포함하는 기판 처리 장치 |
US10340135B2 (en) | 2016-11-28 | 2019-07-02 | Asm Ip Holding B.V. | Method of topologically restricted plasma-enhanced cyclic deposition of silicon or metal nitride |
KR20180068582A (ko) | 2016-12-14 | 2018-06-22 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
USD834686S1 (en) | 2016-12-15 | 2018-11-27 | Asm Ip Holding B.V. | Shower plate |
US11447861B2 (en) | 2016-12-15 | 2022-09-20 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus and a method of forming a patterned structure |
US9916980B1 (en) | 2016-12-15 | 2018-03-13 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US11581186B2 (en) | 2016-12-15 | 2023-02-14 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus |
US10801106B2 (en) | 2016-12-15 | 2020-10-13 | Asm Ip Holding B.V. | Shower plate structure for exhausting deposition inhibiting gas |
US10153156B2 (en) * | 2016-12-15 | 2018-12-11 | Taiwan Semiconductor Manufacturing Co., Ltd. | Plasma enhanced atomic layer deposition |
KR20180070971A (ko) | 2016-12-19 | 2018-06-27 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
JP2020514529A (ja) * | 2016-12-21 | 2020-05-21 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | Cvdによる共形密封膜堆積 |
US10269558B2 (en) | 2016-12-22 | 2019-04-23 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US10867788B2 (en) | 2016-12-28 | 2020-12-15 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US11390950B2 (en) | 2017-01-10 | 2022-07-19 | Asm Ip Holding B.V. | Reactor system and method to reduce residue buildup during a film deposition process |
WO2018132568A1 (en) * | 2017-01-13 | 2018-07-19 | Applied Materials, Inc. | Methods and apparatus for low temperature silicon nitride films |
US10655221B2 (en) | 2017-02-09 | 2020-05-19 | Asm Ip Holding B.V. | Method for depositing oxide film by thermal ALD and PEALD |
JP6963264B2 (ja) | 2017-02-14 | 2021-11-05 | 東芝三菱電機産業システム株式会社 | 窒化膜成膜方法 |
US10468261B2 (en) | 2017-02-15 | 2019-11-05 | Asm Ip Holding B.V. | Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures |
US9911595B1 (en) * | 2017-03-17 | 2018-03-06 | Lam Research Corporation | Selective growth of silicon nitride |
US10529563B2 (en) | 2017-03-29 | 2020-01-07 | Asm Ip Holdings B.V. | Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures |
US10283353B2 (en) | 2017-03-29 | 2019-05-07 | Asm Ip Holding B.V. | Method of reforming insulating film deposited on substrate with recess pattern |
US10103040B1 (en) | 2017-03-31 | 2018-10-16 | Asm Ip Holding B.V. | Apparatus and method for manufacturing a semiconductor device |
WO2018187429A1 (en) * | 2017-04-04 | 2018-10-11 | Applied Materials, Inc. | Two-step process for silicon gapfill |
USD830981S1 (en) | 2017-04-07 | 2018-10-16 | Asm Ip Holding B.V. | Susceptor for semiconductor substrate processing apparatus |
US10847529B2 (en) | 2017-04-13 | 2020-11-24 | Asm Ip Holding B.V. | Substrate processing method and device manufactured by the same |
KR102457289B1 (ko) | 2017-04-25 | 2022-10-21 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 및 반도체 장치의 제조 방법 |
US11158500B2 (en) | 2017-05-05 | 2021-10-26 | Asm Ip Holding B.V. | Plasma enhanced deposition processes for controlled formation of oxygen containing thin films |
US11501965B2 (en) | 2017-05-05 | 2022-11-15 | Asm Ip Holding B.V. | Plasma enhanced deposition processes for controlled formation of metal oxide thin films |
US10770286B2 (en) | 2017-05-08 | 2020-09-08 | Asm Ip Holdings B.V. | Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures |
US10446393B2 (en) | 2017-05-08 | 2019-10-15 | Asm Ip Holding B.V. | Methods for forming silicon-containing epitaxial layers and related semiconductor device structures |
US10892156B2 (en) * | 2017-05-08 | 2021-01-12 | Asm Ip Holding B.V. | Methods for forming a silicon nitride film on a substrate and related semiconductor device structures |
JP6807278B2 (ja) * | 2017-05-24 | 2021-01-06 | 東京エレクトロン株式会社 | シリコン窒化膜の成膜方法および成膜装置 |
US10950498B2 (en) | 2017-05-31 | 2021-03-16 | Applied Materials, Inc. | Selective and self-limiting tungsten etch process |
US10504742B2 (en) | 2017-05-31 | 2019-12-10 | Asm Ip Holding B.V. | Method of atomic layer etching using hydrogen plasma |
US11056353B2 (en) | 2017-06-01 | 2021-07-06 | Asm Ip Holding B.V. | Method and structure for wet etch utilizing etch protection layer comprising boron and carbon |
US10886123B2 (en) | 2017-06-02 | 2021-01-05 | Asm Ip Holding B.V. | Methods for forming low temperature semiconductor layers and related semiconductor device structures |
US11306395B2 (en) | 2017-06-28 | 2022-04-19 | Asm Ip Holding B.V. | Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus |
US10685834B2 (en) | 2017-07-05 | 2020-06-16 | Asm Ip Holdings B.V. | Methods for forming a silicon germanium tin layer and related semiconductor device structures |
KR20190009245A (ko) | 2017-07-18 | 2019-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 반도체 소자 구조물 형성 방법 및 관련된 반도체 소자 구조물 |
US10541333B2 (en) | 2017-07-19 | 2020-01-21 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US11018002B2 (en) | 2017-07-19 | 2021-05-25 | Asm Ip Holding B.V. | Method for selectively depositing a Group IV semiconductor and related semiconductor device structures |
US11374112B2 (en) | 2017-07-19 | 2022-06-28 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US10605530B2 (en) | 2017-07-26 | 2020-03-31 | Asm Ip Holding B.V. | Assembly of a liner and a flange for a vertical furnace as well as the liner and the vertical furnace |
US10312055B2 (en) | 2017-07-26 | 2019-06-04 | Asm Ip Holding B.V. | Method of depositing film by PEALD using negative bias |
US10590535B2 (en) | 2017-07-26 | 2020-03-17 | Asm Ip Holdings B.V. | Chemical treatment, deposition and/or infiltration apparatus and method for using the same |
US10692741B2 (en) | 2017-08-08 | 2020-06-23 | Asm Ip Holdings B.V. | Radiation shield |
US10770336B2 (en) | 2017-08-08 | 2020-09-08 | Asm Ip Holding B.V. | Substrate lift mechanism and reactor including same |
US10249524B2 (en) | 2017-08-09 | 2019-04-02 | Asm Ip Holding B.V. | Cassette holder assembly for a substrate cassette and holding member for use in such assembly |
US11769682B2 (en) | 2017-08-09 | 2023-09-26 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US11139191B2 (en) | 2017-08-09 | 2021-10-05 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US10236177B1 (en) | 2017-08-22 | 2019-03-19 | ASM IP Holding B.V.. | Methods for depositing a doped germanium tin semiconductor and related semiconductor device structures |
USD900036S1 (en) | 2017-08-24 | 2020-10-27 | Asm Ip Holding B.V. | Heater electrical connector and adapter |
US11830730B2 (en) | 2017-08-29 | 2023-11-28 | Asm Ip Holding B.V. | Layer forming method and apparatus |
US11056344B2 (en) | 2017-08-30 | 2021-07-06 | Asm Ip Holding B.V. | Layer forming method |
KR102491945B1 (ko) | 2017-08-30 | 2023-01-26 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11295980B2 (en) | 2017-08-30 | 2022-04-05 | Asm Ip Holding B.V. | Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures |
KR102401446B1 (ko) | 2017-08-31 | 2022-05-24 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US10269559B2 (en) | 2017-09-13 | 2019-04-23 | Lam Research Corporation | Dielectric gapfill of high aspect ratio features utilizing a sacrificial etch cap layer |
US10607895B2 (en) | 2017-09-18 | 2020-03-31 | Asm Ip Holdings B.V. | Method for forming a semiconductor device structure comprising a gate fill metal |
KR102630301B1 (ko) | 2017-09-21 | 2024-01-29 | 에이에스엠 아이피 홀딩 비.브이. | 침투성 재료의 순차 침투 합성 방법 처리 및 이를 이용하여 형성된 구조물 및 장치 |
US10844484B2 (en) | 2017-09-22 | 2020-11-24 | Asm Ip Holding B.V. | Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
US10658205B2 (en) | 2017-09-28 | 2020-05-19 | Asm Ip Holdings B.V. | Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber |
US10403504B2 (en) | 2017-10-05 | 2019-09-03 | Asm Ip Holding B.V. | Method for selectively depositing a metallic film on a substrate |
US10319588B2 (en) | 2017-10-10 | 2019-06-11 | Asm Ip Holding B.V. | Method for depositing a metal chalcogenide on a substrate by cyclical deposition |
US10923344B2 (en) | 2017-10-30 | 2021-02-16 | Asm Ip Holding B.V. | Methods for forming a semiconductor structure and related semiconductor structures |
US10910262B2 (en) | 2017-11-16 | 2021-02-02 | Asm Ip Holding B.V. | Method of selectively depositing a capping layer structure on a semiconductor device structure |
KR102443047B1 (ko) | 2017-11-16 | 2022-09-14 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 방법 및 그에 의해 제조된 장치 |
US11022879B2 (en) | 2017-11-24 | 2021-06-01 | Asm Ip Holding B.V. | Method of forming an enhanced unexposed photoresist layer |
US11127617B2 (en) | 2017-11-27 | 2021-09-21 | Asm Ip Holding B.V. | Storage device for storing wafer cassettes for use with a batch furnace |
CN111344522B (zh) | 2017-11-27 | 2022-04-12 | 阿斯莫Ip控股公司 | 包括洁净迷你环境的装置 |
TWI761636B (zh) | 2017-12-04 | 2022-04-21 | 荷蘭商Asm Ip控股公司 | 電漿增強型原子層沉積製程及沉積碳氧化矽薄膜的方法 |
US10290508B1 (en) | 2017-12-05 | 2019-05-14 | Asm Ip Holding B.V. | Method for forming vertical spacers for spacer-defined patterning |
US10872771B2 (en) | 2018-01-16 | 2020-12-22 | Asm Ip Holding B. V. | Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures |
TWI799494B (zh) | 2018-01-19 | 2023-04-21 | 荷蘭商Asm 智慧財產控股公司 | 沈積方法 |
CN111630203A (zh) | 2018-01-19 | 2020-09-04 | Asm Ip私人控股有限公司 | 通过等离子体辅助沉积来沉积间隙填充层的方法 |
USD903477S1 (en) | 2018-01-24 | 2020-12-01 | Asm Ip Holdings B.V. | Metal clamp |
US11018047B2 (en) | 2018-01-25 | 2021-05-25 | Asm Ip Holding B.V. | Hybrid lift pin |
USD880437S1 (en) | 2018-02-01 | 2020-04-07 | Asm Ip Holding B.V. | Gas supply plate for semiconductor manufacturing apparatus |
US10535516B2 (en) | 2018-02-01 | 2020-01-14 | Asm Ip Holdings B.V. | Method for depositing a semiconductor structure on a surface of a substrate and related semiconductor structures |
US11081345B2 (en) | 2018-02-06 | 2021-08-03 | Asm Ip Holding B.V. | Method of post-deposition treatment for silicon oxide film |
US10896820B2 (en) | 2018-02-14 | 2021-01-19 | Asm Ip Holding B.V. | Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US11685991B2 (en) | 2018-02-14 | 2023-06-27 | Asm Ip Holding B.V. | Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US10731249B2 (en) | 2018-02-15 | 2020-08-04 | Asm Ip Holding B.V. | Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus |
KR102636427B1 (ko) | 2018-02-20 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 및 장치 |
US10658181B2 (en) | 2018-02-20 | 2020-05-19 | Asm Ip Holding B.V. | Method of spacer-defined direct patterning in semiconductor fabrication |
US10975470B2 (en) | 2018-02-23 | 2021-04-13 | Asm Ip Holding B.V. | Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment |
US11473195B2 (en) | 2018-03-01 | 2022-10-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus and a method for processing a substrate |
KR20200118504A (ko) | 2018-03-02 | 2020-10-15 | 램 리써치 코포레이션 | 가수분해를 사용한 선택적인 증착 |
US11629406B2 (en) | 2018-03-09 | 2023-04-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate |
US11114283B2 (en) | 2018-03-16 | 2021-09-07 | Asm Ip Holding B.V. | Reactor, system including the reactor, and methods of manufacturing and using same |
KR102646467B1 (ko) | 2018-03-27 | 2024-03-11 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상에 전극을 형성하는 방법 및 전극을 포함하는 반도체 소자 구조 |
US11088002B2 (en) | 2018-03-29 | 2021-08-10 | Asm Ip Holding B.V. | Substrate rack and a substrate processing system and method |
US11230766B2 (en) | 2018-03-29 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
US10510536B2 (en) | 2018-03-29 | 2019-12-17 | Asm Ip Holding B.V. | Method of depositing a co-doped polysilicon film on a surface of a substrate within a reaction chamber |
KR102501472B1 (ko) | 2018-03-30 | 2023-02-20 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 |
US10580645B2 (en) * | 2018-04-30 | 2020-03-03 | Asm Ip Holding B.V. | Plasma enhanced atomic layer deposition (PEALD) of SiN using silicon-hydrohalide precursors |
KR20190128558A (ko) | 2018-05-08 | 2019-11-18 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상에 산화물 막을 주기적 증착 공정에 의해 증착하기 위한 방법 및 관련 소자 구조 |
KR20190129718A (ko) | 2018-05-11 | 2019-11-20 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상에 피도핑 금속 탄화물 막을 형성하는 방법 및 관련 반도체 소자 구조 |
US11393674B2 (en) | 2018-05-18 | 2022-07-19 | Taiwan Semiconductor Manufacturing Company, Ltd. | Forming low-stress silicon nitride layer through hydrogen treatment |
KR102596988B1 (ko) | 2018-05-28 | 2023-10-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 및 그에 의해 제조된 장치 |
US11718913B2 (en) | 2018-06-04 | 2023-08-08 | Asm Ip Holding B.V. | Gas distribution system and reactor system including same |
US11270899B2 (en) | 2018-06-04 | 2022-03-08 | Asm Ip Holding B.V. | Wafer handling chamber with moisture reduction |
US11286562B2 (en) | 2018-06-08 | 2022-03-29 | Asm Ip Holding B.V. | Gas-phase chemical reactor and method of using same |
KR102568797B1 (ko) | 2018-06-21 | 2023-08-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 시스템 |
US10797133B2 (en) | 2018-06-21 | 2020-10-06 | Asm Ip Holding B.V. | Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures |
WO2020003000A1 (en) | 2018-06-27 | 2020-01-02 | Asm Ip Holding B.V. | Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material |
JP2021529254A (ja) | 2018-06-27 | 2021-10-28 | エーエスエム・アイピー・ホールディング・ベー・フェー | 金属含有材料ならびに金属含有材料を含む膜および構造体を形成するための周期的堆積方法 |
US10720526B2 (en) | 2018-06-29 | 2020-07-21 | Taiwan Semiconductor Manufacturing Company, Ltd. | Stress modulation for dielectric layers |
KR20200002519A (ko) | 2018-06-29 | 2020-01-08 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 및 반도체 장치의 제조 방법 |
US10612136B2 (en) | 2018-06-29 | 2020-04-07 | ASM IP Holding, B.V. | Temperature-controlled flange and reactor system including same |
US10755922B2 (en) * | 2018-07-03 | 2020-08-25 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10388513B1 (en) * | 2018-07-03 | 2019-08-20 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10767789B2 (en) | 2018-07-16 | 2020-09-08 | Asm Ip Holding B.V. | Diaphragm valves, valve components, and methods for forming valve components |
US10483099B1 (en) | 2018-07-26 | 2019-11-19 | Asm Ip Holding B.V. | Method for forming thermally stable organosilicon polymer film |
US11600530B2 (en) * | 2018-07-31 | 2023-03-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device and method of manufacture |
US11053591B2 (en) | 2018-08-06 | 2021-07-06 | Asm Ip Holding B.V. | Multi-port gas injection system and reactor system including same |
US10883175B2 (en) | 2018-08-09 | 2021-01-05 | Asm Ip Holding B.V. | Vertical furnace for processing substrates and a liner for use therein |
US10829852B2 (en) | 2018-08-16 | 2020-11-10 | Asm Ip Holding B.V. | Gas distribution device for a wafer processing apparatus |
US11430674B2 (en) | 2018-08-22 | 2022-08-30 | Asm Ip Holding B.V. | Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
US11239420B2 (en) | 2018-08-24 | 2022-02-01 | Lam Research Corporation | Conformal damage-free encapsulation of chalcogenide materials |
KR20200030162A (ko) | 2018-09-11 | 2020-03-20 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 |
US11024523B2 (en) | 2018-09-11 | 2021-06-01 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
US11049751B2 (en) | 2018-09-14 | 2021-06-29 | Asm Ip Holding B.V. | Cassette supply system to store and handle cassettes and processing apparatus equipped therewith |
CN110970344A (zh) | 2018-10-01 | 2020-04-07 | Asm Ip控股有限公司 | 衬底保持设备、包含所述设备的系统及其使用方法 |
US11232963B2 (en) | 2018-10-03 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
KR102592699B1 (ko) | 2018-10-08 | 2023-10-23 | 에이에스엠 아이피 홀딩 비.브이. | 기판 지지 유닛 및 이를 포함하는 박막 증착 장치와 기판 처리 장치 |
US10847365B2 (en) | 2018-10-11 | 2020-11-24 | Asm Ip Holding B.V. | Method of forming conformal silicon carbide film by cyclic CVD |
US10811256B2 (en) | 2018-10-16 | 2020-10-20 | Asm Ip Holding B.V. | Method for etching a carbon-containing feature |
KR102546322B1 (ko) | 2018-10-19 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 및 기판 처리 방법 |
KR102605121B1 (ko) | 2018-10-19 | 2023-11-23 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 및 기판 처리 방법 |
USD948463S1 (en) | 2018-10-24 | 2022-04-12 | Asm Ip Holding B.V. | Susceptor for semiconductor substrate supporting apparatus |
US10381219B1 (en) | 2018-10-25 | 2019-08-13 | Asm Ip Holding B.V. | Methods for forming a silicon nitride film |
US11087997B2 (en) | 2018-10-31 | 2021-08-10 | Asm Ip Holding B.V. | Substrate processing apparatus for processing substrates |
KR20200051105A (ko) | 2018-11-02 | 2020-05-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 지지 유닛 및 이를 포함하는 기판 처리 장치 |
US11572620B2 (en) | 2018-11-06 | 2023-02-07 | Asm Ip Holding B.V. | Methods for selectively depositing an amorphous silicon film on a substrate |
US11031242B2 (en) | 2018-11-07 | 2021-06-08 | Asm Ip Holding B.V. | Methods for depositing a boron doped silicon germanium film |
US10818758B2 (en) | 2018-11-16 | 2020-10-27 | Asm Ip Holding B.V. | Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures |
US10847366B2 (en) | 2018-11-16 | 2020-11-24 | Asm Ip Holding B.V. | Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process |
US10559458B1 (en) | 2018-11-26 | 2020-02-11 | Asm Ip Holding B.V. | Method of forming oxynitride film |
US11217444B2 (en) | 2018-11-30 | 2022-01-04 | Asm Ip Holding B.V. | Method for forming an ultraviolet radiation responsive metal oxide-containing film |
KR102157137B1 (ko) | 2018-11-30 | 2020-09-17 | 주식회사 한솔케미칼 | 실리콘 전구체 및 이를 이용한 실리콘 함유 박막의 제조방법 |
WO2020111405A1 (ko) * | 2018-11-30 | 2020-06-04 | 주식회사 한솔케미칼 | 실리콘 전구체 및 이를 이용한 실리콘 함유 박막의 제조방법 |
KR102636428B1 (ko) | 2018-12-04 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치를 세정하는 방법 |
US11158513B2 (en) | 2018-12-13 | 2021-10-26 | Asm Ip Holding B.V. | Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures |
TW202037745A (zh) | 2018-12-14 | 2020-10-16 | 荷蘭商Asm Ip私人控股有限公司 | 形成裝置結構之方法、其所形成之結構及施行其之系統 |
TWI819180B (zh) | 2019-01-17 | 2023-10-21 | 荷蘭商Asm 智慧財產控股公司 | 藉由循環沈積製程於基板上形成含過渡金屬膜之方法 |
KR20200091543A (ko) | 2019-01-22 | 2020-07-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
CN111524788B (zh) | 2019-02-01 | 2023-11-24 | Asm Ip私人控股有限公司 | 氧化硅的拓扑选择性膜形成的方法 |
CN117265500A (zh) * | 2019-02-14 | 2023-12-22 | 恩特格里斯公司 | 氮化硅的选择性沉积 |
KR102638425B1 (ko) | 2019-02-20 | 2024-02-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 표면 내에 형성된 오목부를 충진하기 위한 방법 및 장치 |
JP2020136677A (ja) | 2019-02-20 | 2020-08-31 | エーエスエム・アイピー・ホールディング・ベー・フェー | 基材表面内に形成された凹部を充填するための周期的堆積方法および装置 |
KR20200102357A (ko) | 2019-02-20 | 2020-08-31 | 에이에스엠 아이피 홀딩 비.브이. | 3-d nand 응용의 플러그 충진체 증착용 장치 및 방법 |
KR102626263B1 (ko) | 2019-02-20 | 2024-01-16 | 에이에스엠 아이피 홀딩 비.브이. | 처리 단계를 포함하는 주기적 증착 방법 및 이를 위한 장치 |
JP2020133004A (ja) | 2019-02-22 | 2020-08-31 | エーエスエム・アイピー・ホールディング・ベー・フェー | 基材を処理するための基材処理装置および方法 |
KR20200108242A (ko) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 질화물 층을 선택적으로 증착하는 방법, 및 선택적으로 증착된 실리콘 질화물 층을 포함하는 구조체 |
KR20200108243A (ko) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | SiOC 층을 포함한 구조체 및 이의 형성 방법 |
US11742198B2 (en) | 2019-03-08 | 2023-08-29 | Asm Ip Holding B.V. | Structure including SiOCN layer and method of forming same |
JP2020167398A (ja) | 2019-03-28 | 2020-10-08 | エーエスエム・アイピー・ホールディング・ベー・フェー | ドアオープナーおよびドアオープナーが提供される基材処理装置 |
KR20200116855A (ko) | 2019-04-01 | 2020-10-13 | 에이에스엠 아이피 홀딩 비.브이. | 반도체 소자를 제조하는 방법 |
KR20200123380A (ko) | 2019-04-19 | 2020-10-29 | 에이에스엠 아이피 홀딩 비.브이. | 층 형성 방법 및 장치 |
KR20200125453A (ko) | 2019-04-24 | 2020-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 기상 반응기 시스템 및 이를 사용하는 방법 |
KR20200130121A (ko) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | 딥 튜브가 있는 화학물질 공급원 용기 |
KR20200130118A (ko) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | 비정질 탄소 중합체 막을 개질하는 방법 |
KR20200130652A (ko) | 2019-05-10 | 2020-11-19 | 에이에스엠 아이피 홀딩 비.브이. | 표면 상에 재료를 증착하는 방법 및 본 방법에 따라 형성된 구조 |
JP2020188255A (ja) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | ウェハボートハンドリング装置、縦型バッチ炉および方法 |
JP2020188254A (ja) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | ウェハボートハンドリング装置、縦型バッチ炉および方法 |
USD947913S1 (en) | 2019-05-17 | 2022-04-05 | Asm Ip Holding B.V. | Susceptor shaft |
USD975665S1 (en) | 2019-05-17 | 2023-01-17 | Asm Ip Holding B.V. | Susceptor shaft |
USD935572S1 (en) | 2019-05-24 | 2021-11-09 | Asm Ip Holding B.V. | Gas channel plate |
USD922229S1 (en) | 2019-06-05 | 2021-06-15 | Asm Ip Holding B.V. | Device for controlling a temperature of a gas supply unit |
KR20200141002A (ko) | 2019-06-06 | 2020-12-17 | 에이에스엠 아이피 홀딩 비.브이. | 배기 가스 분석을 포함한 기상 반응기 시스템을 사용하는 방법 |
KR20200143254A (ko) | 2019-06-11 | 2020-12-23 | 에이에스엠 아이피 홀딩 비.브이. | 개질 가스를 사용하여 전자 구조를 형성하는 방법, 상기 방법을 수행하기 위한 시스템, 및 상기 방법을 사용하여 형성되는 구조 |
USD944946S1 (en) | 2019-06-14 | 2022-03-01 | Asm Ip Holding B.V. | Shower plate |
USD931978S1 (en) | 2019-06-27 | 2021-09-28 | Asm Ip Holding B.V. | Showerhead vacuum transport |
KR20210005515A (ko) | 2019-07-03 | 2021-01-14 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치용 온도 제어 조립체 및 이를 사용하는 방법 |
JP2021015791A (ja) | 2019-07-09 | 2021-02-12 | エーエスエム アイピー ホールディング ビー.ブイ. | 同軸導波管を用いたプラズマ装置、基板処理方法 |
CN112216646A (zh) | 2019-07-10 | 2021-01-12 | Asm Ip私人控股有限公司 | 基板支撑组件及包括其的基板处理装置 |
KR20210010307A (ko) | 2019-07-16 | 2021-01-27 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
KR20210010816A (ko) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 라디칼 보조 점화 플라즈마 시스템 및 방법 |
KR20210010820A (ko) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 게르마늄 구조를 형성하는 방법 |
US11643724B2 (en) | 2019-07-18 | 2023-05-09 | Asm Ip Holding B.V. | Method of forming structures using a neutral beam |
CN112242296A (zh) | 2019-07-19 | 2021-01-19 | Asm Ip私人控股有限公司 | 形成拓扑受控的无定形碳聚合物膜的方法 |
CN112309843A (zh) | 2019-07-29 | 2021-02-02 | Asm Ip私人控股有限公司 | 实现高掺杂剂掺入的选择性沉积方法 |
TW202111825A (zh) | 2019-07-29 | 2021-03-16 | 美商應用材料股份有限公司 | 原子層沉積之多層封裝堆疊 |
CN112309900A (zh) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | 基板处理设备 |
CN112309899A (zh) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | 基板处理设备 |
US11587815B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11227782B2 (en) | 2019-07-31 | 2022-01-18 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11587814B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
CN112323048B (zh) | 2019-08-05 | 2024-02-09 | Asm Ip私人控股有限公司 | 用于化学源容器的液位传感器 |
USD965524S1 (en) | 2019-08-19 | 2022-10-04 | Asm Ip Holding B.V. | Susceptor support |
USD965044S1 (en) | 2019-08-19 | 2022-09-27 | Asm Ip Holding B.V. | Susceptor shaft |
JP2021031769A (ja) | 2019-08-21 | 2021-03-01 | エーエスエム アイピー ホールディング ビー.ブイ. | 成膜原料混合ガス生成装置及び成膜装置 |
USD979506S1 (en) | 2019-08-22 | 2023-02-28 | Asm Ip Holding B.V. | Insulator |
USD940837S1 (en) | 2019-08-22 | 2022-01-11 | Asm Ip Holding B.V. | Electrode |
USD930782S1 (en) | 2019-08-22 | 2021-09-14 | Asm Ip Holding B.V. | Gas distributor |
USD949319S1 (en) | 2019-08-22 | 2022-04-19 | Asm Ip Holding B.V. | Exhaust duct |
KR20210024423A (ko) | 2019-08-22 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | 홀을 구비한 구조체를 형성하기 위한 방법 |
US11286558B2 (en) | 2019-08-23 | 2022-03-29 | Asm Ip Holding B.V. | Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film |
KR20210024420A (ko) | 2019-08-23 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | 비스(디에틸아미노)실란을 사용하여 peald에 의해 개선된 품질을 갖는 실리콘 산화물 막을 증착하기 위한 방법 |
KR20210029090A (ko) | 2019-09-04 | 2021-03-15 | 에이에스엠 아이피 홀딩 비.브이. | 희생 캡핑 층을 이용한 선택적 증착 방법 |
KR20210029663A (ko) | 2019-09-05 | 2021-03-16 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11562901B2 (en) | 2019-09-25 | 2023-01-24 | Asm Ip Holding B.V. | Substrate processing method |
CN112593212B (zh) | 2019-10-02 | 2023-12-22 | Asm Ip私人控股有限公司 | 通过循环等离子体增强沉积工艺形成拓扑选择性氧化硅膜的方法 |
US10988490B1 (en) * | 2019-10-03 | 2021-04-27 | Entegris, Inc. | Triiodosilylamine precursor compounds |
TW202129060A (zh) | 2019-10-08 | 2021-08-01 | 荷蘭商Asm Ip控股公司 | 基板處理裝置、及基板處理方法 |
KR20210043460A (ko) | 2019-10-10 | 2021-04-21 | 에이에스엠 아이피 홀딩 비.브이. | 포토레지스트 하부층을 형성하기 위한 방법 및 이를 포함한 구조체 |
KR20210045930A (ko) | 2019-10-16 | 2021-04-27 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 산화물의 토폴로지-선택적 막의 형성 방법 |
US11637014B2 (en) | 2019-10-17 | 2023-04-25 | Asm Ip Holding B.V. | Methods for selective deposition of doped semiconductor material |
KR20210047808A (ko) | 2019-10-21 | 2021-04-30 | 에이에스엠 아이피 홀딩 비.브이. | 막을 선택적으로 에칭하기 위한 장치 및 방법 |
KR20210050453A (ko) | 2019-10-25 | 2021-05-07 | 에이에스엠 아이피 홀딩 비.브이. | 기판 표면 상의 갭 피처를 충진하는 방법 및 이와 관련된 반도체 소자 구조 |
US11646205B2 (en) | 2019-10-29 | 2023-05-09 | Asm Ip Holding B.V. | Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same |
KR20210054983A (ko) | 2019-11-05 | 2021-05-14 | 에이에스엠 아이피 홀딩 비.브이. | 도핑된 반도체 층을 갖는 구조체 및 이를 형성하기 위한 방법 및 시스템 |
US11501968B2 (en) | 2019-11-15 | 2022-11-15 | Asm Ip Holding B.V. | Method for providing a semiconductor device with silicon filled gaps |
KR20210062561A (ko) | 2019-11-20 | 2021-05-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판의 표면 상에 탄소 함유 물질을 증착하는 방법, 상기 방법을 사용하여 형성된 구조물, 및 상기 구조물을 형성하기 위한 시스템 |
CN112951697A (zh) | 2019-11-26 | 2021-06-11 | Asm Ip私人控股有限公司 | 基板处理设备 |
KR20210065848A (ko) | 2019-11-26 | 2021-06-04 | 에이에스엠 아이피 홀딩 비.브이. | 제1 유전체 표면과 제2 금속성 표면을 포함한 기판 상에 타겟 막을 선택적으로 형성하기 위한 방법 |
CN112885693A (zh) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | 基板处理设备 |
CN112885692A (zh) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | 基板处理设备 |
JP2021090042A (ja) | 2019-12-02 | 2021-06-10 | エーエスエム アイピー ホールディング ビー.ブイ. | 基板処理装置、基板処理方法 |
CN112908846A (zh) * | 2019-12-02 | 2021-06-04 | 财团法人金属工业研究发展中心 | 形成半导体结构的方法及半导体结构 |
KR20210070898A (ko) | 2019-12-04 | 2021-06-15 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11885013B2 (en) | 2019-12-17 | 2024-01-30 | Asm Ip Holding B.V. | Method of forming vanadium nitride layer and structure including the vanadium nitride layer |
US11527403B2 (en) | 2019-12-19 | 2022-12-13 | Asm Ip Holding B.V. | Methods for filling a gap feature on a substrate surface and related semiconductor structures |
JP2021109175A (ja) | 2020-01-06 | 2021-08-02 | エーエスエム・アイピー・ホールディング・ベー・フェー | ガス供給アセンブリ、その構成要素、およびこれを含む反応器システム |
US11993847B2 (en) | 2020-01-08 | 2024-05-28 | Asm Ip Holding B.V. | Injector |
US20210225634A1 (en) * | 2020-01-17 | 2021-07-22 | Asm Ip Holding B.V. | FORMATION OF SiCN THIN FILMS |
KR20210094462A (ko) * | 2020-01-20 | 2021-07-29 | 에이에스엠 아이피 홀딩 비.브이. | 전처리를 사용하여 실리콘 질화물 층을 증착하는 방법, 상기 방법을 사용하여 형성된 구조체, 및 상기 방법을 수행하기 위한 시스템 |
KR20210095050A (ko) | 2020-01-20 | 2021-07-30 | 에이에스엠 아이피 홀딩 비.브이. | 박막 형성 방법 및 박막 표면 개질 방법 |
TW202130846A (zh) | 2020-02-03 | 2021-08-16 | 荷蘭商Asm Ip私人控股有限公司 | 形成包括釩或銦層的結構之方法 |
KR20210100010A (ko) | 2020-02-04 | 2021-08-13 | 에이에스엠 아이피 홀딩 비.브이. | 대형 물품의 투과율 측정을 위한 방법 및 장치 |
US11776846B2 (en) | 2020-02-07 | 2023-10-03 | Asm Ip Holding B.V. | Methods for depositing gap filling fluids and related systems and devices |
TW202146715A (zh) | 2020-02-17 | 2021-12-16 | 荷蘭商Asm Ip私人控股有限公司 | 用於生長磷摻雜矽層之方法及其系統 |
TW202203344A (zh) | 2020-02-28 | 2022-01-16 | 荷蘭商Asm Ip控股公司 | 專用於零件清潔的系統 |
KR20210116240A (ko) | 2020-03-11 | 2021-09-27 | 에이에스엠 아이피 홀딩 비.브이. | 조절성 접합부를 갖는 기판 핸들링 장치 |
US11876356B2 (en) | 2020-03-11 | 2024-01-16 | Asm Ip Holding B.V. | Lockout tagout assembly and system and method of using same |
KR20210117157A (ko) | 2020-03-12 | 2021-09-28 | 에이에스엠 아이피 홀딩 비.브이. | 타겟 토폴로지 프로파일을 갖는 층 구조를 제조하기 위한 방법 |
KR20210124042A (ko) | 2020-04-02 | 2021-10-14 | 에이에스엠 아이피 홀딩 비.브이. | 박막 형성 방법 |
TW202146689A (zh) | 2020-04-03 | 2021-12-16 | 荷蘭商Asm Ip控股公司 | 阻障層形成方法及半導體裝置的製造方法 |
TW202145344A (zh) | 2020-04-08 | 2021-12-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於選擇性蝕刻氧化矽膜之設備及方法 |
US11821078B2 (en) | 2020-04-15 | 2023-11-21 | Asm Ip Holding B.V. | Method for forming precoat film and method for forming silicon-containing film |
US11996289B2 (en) | 2020-04-16 | 2024-05-28 | Asm Ip Holding B.V. | Methods of forming structures including silicon germanium and silicon layers, devices formed using the methods, and systems for performing the methods |
KR20210132605A (ko) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 냉각 가스 공급부를 포함한 수직형 배치 퍼니스 어셈블리 |
JP2021172884A (ja) | 2020-04-24 | 2021-11-01 | エーエスエム・アイピー・ホールディング・ベー・フェー | 窒化バナジウム含有層を形成する方法および窒化バナジウム含有層を含む構造体 |
KR20210132600A (ko) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 바나듐, 질소 및 추가 원소를 포함한 층을 증착하기 위한 방법 및 시스템 |
KR20210134226A (ko) | 2020-04-29 | 2021-11-09 | 에이에스엠 아이피 홀딩 비.브이. | 고체 소스 전구체 용기 |
KR20210134869A (ko) | 2020-05-01 | 2021-11-11 | 에이에스엠 아이피 홀딩 비.브이. | Foup 핸들러를 이용한 foup의 빠른 교환 |
KR102364476B1 (ko) * | 2020-05-08 | 2022-02-18 | 주식회사 한솔케미칼 | 실리콘 전구체 및 이를 이용한 실리콘 함유 박막의 제조방법 |
KR20210141379A (ko) | 2020-05-13 | 2021-11-23 | 에이에스엠 아이피 홀딩 비.브이. | 반응기 시스템용 레이저 정렬 고정구 |
KR20210143653A (ko) | 2020-05-19 | 2021-11-29 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
KR20210145078A (ko) | 2020-05-21 | 2021-12-01 | 에이에스엠 아이피 홀딩 비.브이. | 다수의 탄소 층을 포함한 구조체 및 이를 형성하고 사용하는 방법 |
TW202200837A (zh) | 2020-05-22 | 2022-01-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於在基材上形成薄膜之反應系統 |
TW202201602A (zh) | 2020-05-29 | 2022-01-01 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理方法 |
TW202218133A (zh) | 2020-06-24 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成含矽層之方法 |
TW202217953A (zh) | 2020-06-30 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理方法 |
KR20220010438A (ko) | 2020-07-17 | 2022-01-25 | 에이에스엠 아이피 홀딩 비.브이. | 포토리소그래피에 사용하기 위한 구조체 및 방법 |
TW202204662A (zh) | 2020-07-20 | 2022-02-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於沉積鉬層之方法及系統 |
TW202212623A (zh) | 2020-08-26 | 2022-04-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成金屬氧化矽層及金屬氮氧化矽層的方法、半導體結構、及系統 |
USD990534S1 (en) | 2020-09-11 | 2023-06-27 | Asm Ip Holding B.V. | Weighted lift pin |
USD1012873S1 (en) | 2020-09-24 | 2024-01-30 | Asm Ip Holding B.V. | Electrode for semiconductor processing apparatus |
US11979171B2 (en) | 2020-10-13 | 2024-05-07 | Microchip Technology Incorporated | Reduced complexity encoders and related systems, methods, and devices |
TW202229613A (zh) | 2020-10-14 | 2022-08-01 | 荷蘭商Asm Ip私人控股有限公司 | 於階梯式結構上沉積材料的方法 |
KR20220053482A (ko) | 2020-10-22 | 2022-04-29 | 에이에스엠 아이피 홀딩 비.브이. | 바나듐 금속을 증착하는 방법, 구조체, 소자 및 증착 어셈블리 |
TW202223136A (zh) | 2020-10-28 | 2022-06-16 | 荷蘭商Asm Ip私人控股有限公司 | 用於在基板上形成層之方法、及半導體處理系統 |
US11447865B2 (en) | 2020-11-17 | 2022-09-20 | Applied Materials, Inc. | Deposition of low-κ films |
TW202235675A (zh) | 2020-11-30 | 2022-09-16 | 荷蘭商Asm Ip私人控股有限公司 | 注入器、及基板處理設備 |
KR20220081905A (ko) | 2020-12-09 | 2022-06-16 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 질화물 증착용 실리콘 전구체 |
US11946137B2 (en) | 2020-12-16 | 2024-04-02 | Asm Ip Holding B.V. | Runout and wobble measurement fixtures |
TW202231903A (zh) | 2020-12-22 | 2022-08-16 | 荷蘭商Asm Ip私人控股有限公司 | 過渡金屬沉積方法、過渡金屬層、用於沉積過渡金屬於基板上的沉積總成 |
US11658025B2 (en) * | 2021-01-18 | 2023-05-23 | Applied Materials, Inc. | Chalcogen precursors for deposition of silicon nitride |
US11551926B2 (en) | 2021-01-22 | 2023-01-10 | Micron Technology, Inc. | Methods of forming a microelectronic device, and related systems and additional methods |
JP2022113560A (ja) * | 2021-01-25 | 2022-08-04 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
US11800824B2 (en) | 2021-03-24 | 2023-10-24 | Applied Materials, Inc. | Low temperature silicon nitride/silicon oxynitride stack film with tunable dielectric constant |
USD980814S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas distributor for substrate processing apparatus |
USD981973S1 (en) | 2021-05-11 | 2023-03-28 | Asm Ip Holding B.V. | Reactor wall for substrate processing apparatus |
USD1023959S1 (en) | 2021-05-11 | 2024-04-23 | Asm Ip Holding B.V. | Electrode for substrate processing apparatus |
USD980813S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas flow control plate for substrate processing apparatus |
USD990441S1 (en) | 2021-09-07 | 2023-06-27 | Asm Ip Holding B.V. | Gas flow control plate |
KR20240057450A (ko) * | 2021-09-23 | 2024-05-02 | 램 리써치 코포레이션 | 정전 클램핑을 사용한 리모트 플라즈마 증착 |
US20230132200A1 (en) | 2021-10-27 | 2023-04-27 | Applied Materials, Inc. | Selective blocking of metal surfaces using bifunctional self-assembled monolayers |
US20230369031A1 (en) * | 2022-05-12 | 2023-11-16 | Applied Materials, Inc. | Integrated method and tool for high quality selective silicon nitride deposition |
CN117219506B (zh) * | 2023-11-09 | 2024-03-12 | 深圳基本半导体有限公司 | 一种消除刻蚀负载效应的方法 |
Family Cites Families (172)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6482262B1 (en) | 1959-10-10 | 2002-11-19 | Asm Microchemistry Oy | Deposition of transition metal carbides |
US4683147A (en) * | 1984-04-16 | 1987-07-28 | Canon Kabushiki Kaisha | Method of forming deposition film |
US4668365A (en) | 1984-10-25 | 1987-05-26 | Applied Materials, Inc. | Apparatus and method for magnetron-enhanced plasma-assisted chemical vapor deposition |
JPS61252932A (ja) | 1985-04-30 | 1986-11-10 | Mitsubishi Heavy Ind Ltd | ワイヤチエ−ンコネクタ |
US4696834A (en) * | 1986-02-28 | 1987-09-29 | Dow Corning Corporation | Silicon-containing coatings and a method for their preparation |
JPH01103844A (ja) * | 1987-10-16 | 1989-04-20 | Matsushita Electric Ind Co Ltd | 絶縁体薄膜の製造方法 |
US5024716A (en) * | 1988-01-20 | 1991-06-18 | Canon Kabushiki Kaisha | Plasma processing apparatus for etching, ashing and film-formation |
JPH0570957A (ja) * | 1991-09-19 | 1993-03-23 | Nec Corp | プラズマ気相成長装置 |
US5939333A (en) | 1996-05-30 | 1999-08-17 | Micron Technology, Inc. | Silicon nitride deposition method |
KR100385946B1 (ko) | 1999-12-08 | 2003-06-02 | 삼성전자주식회사 | 원자층 증착법을 이용한 금속층 형성방법 및 그 금속층을장벽금속층, 커패시터의 상부전극, 또는 하부전극으로구비한 반도체 소자 |
JP3063840B2 (ja) * | 1997-11-19 | 2000-07-12 | 日本電気株式会社 | 半導体装置およびその製造方法 |
KR20010032764A (ko) * | 1997-12-02 | 2001-04-25 | 베리 아이클스 | 아이오도사일렌 전구체로부터 형성된 실리콘계 필름과 그제조방법 |
KR20010074387A (ko) * | 2000-01-25 | 2001-08-04 | 황 철 주 | 실리콘질화막 형성방법 |
JP3420205B2 (ja) * | 2000-11-20 | 2003-06-23 | Necエレクトロニクス株式会社 | 半導体装置の製造方法 |
KR100385947B1 (ko) | 2000-12-06 | 2003-06-02 | 삼성전자주식회사 | 원자층 증착 방법에 의한 박막 형성 방법 |
JP5068402B2 (ja) | 2000-12-28 | 2012-11-07 | 公益財団法人国際科学振興財団 | 誘電体膜およびその形成方法、半導体装置、不揮発性半導体メモリ装置、および半導体装置の製造方法 |
JP2002308643A (ja) * | 2001-02-01 | 2002-10-23 | Nippon Electric Glass Co Ltd | 無アルカリガラス及びディスプレイ用ガラス基板 |
US7005392B2 (en) | 2001-03-30 | 2006-02-28 | Advanced Technology Materials, Inc. | Source reagent compositions for CVD formation of gate dielectric thin films using amide precursors and method of using same |
US7084080B2 (en) * | 2001-03-30 | 2006-08-01 | Advanced Technology Materials, Inc. | Silicon source reagent compositions, and method of making and using same for microelectronic device structure |
GB0113751D0 (en) | 2001-06-06 | 2001-07-25 | Dow Corning | Surface treatment |
US6391803B1 (en) | 2001-06-20 | 2002-05-21 | Samsung Electronics Co., Ltd. | Method of forming silicon containing thin films by atomic layer deposition utilizing trisdimethylaminosilane |
US9708707B2 (en) | 2001-09-10 | 2017-07-18 | Asm International N.V. | Nanolayer deposition using bias power treatment |
US6756318B2 (en) | 2001-09-10 | 2004-06-29 | Tegal Corporation | Nanolayer thick film processing system and method |
US6929831B2 (en) | 2001-09-15 | 2005-08-16 | Trikon Holdings Limited | Methods of forming nitride films |
JP4121269B2 (ja) * | 2001-11-27 | 2008-07-23 | 日本エー・エス・エム株式会社 | セルフクリーニングを実行するプラズマcvd装置及び方法 |
US20030215570A1 (en) * | 2002-05-16 | 2003-11-20 | Applied Materials, Inc. | Deposition of silicon nitride |
KR100469126B1 (ko) * | 2002-06-05 | 2005-01-29 | 삼성전자주식회사 | 수소 함유량이 적은 박막 형성방법 |
US7297641B2 (en) * | 2002-07-19 | 2007-11-20 | Asm America, Inc. | Method to form ultra high quality silicon-containing compound layers |
CN100471991C (zh) * | 2002-10-18 | 2009-03-25 | 应用材料有限公司 | 采用硅化合物进行的含硅层沉积 |
US7540920B2 (en) | 2002-10-18 | 2009-06-02 | Applied Materials, Inc. | Silicon-containing layer deposition with silicon compounds |
US7446217B2 (en) * | 2002-11-14 | 2008-11-04 | Advanced Technology Materials, Inc. | Composition and method for low temperature deposition of silicon-containing films |
US7531679B2 (en) | 2002-11-14 | 2009-05-12 | Advanced Technology Materials, Inc. | Composition and method for low temperature deposition of silicon-containing films such as films including silicon nitride, silicon dioxide and/or silicon-oxynitride |
KR100496265B1 (ko) * | 2002-11-29 | 2005-06-17 | 한국전자통신연구원 | 반도체 소자의 박막 형성방법 |
US7172792B2 (en) * | 2002-12-20 | 2007-02-06 | Applied Materials, Inc. | Method for forming a high quality low temperature silicon nitride film |
US7122222B2 (en) | 2003-01-23 | 2006-10-17 | Air Products And Chemicals, Inc. | Precursors for depositing silicon containing films and processes thereof |
US9121098B2 (en) | 2003-02-04 | 2015-09-01 | Asm International N.V. | NanoLayer Deposition process for composite films |
US7713592B2 (en) | 2003-02-04 | 2010-05-11 | Tegal Corporation | Nanolayer deposition process |
KR100965758B1 (ko) * | 2003-05-22 | 2010-06-24 | 주성엔지니어링(주) | 액정표시장치용 플라즈마 강화 화학기상증착 장치의샤워헤드 어셈블리 |
US7125582B2 (en) * | 2003-07-30 | 2006-10-24 | Intel Corporation | Low-temperature silicon nitride deposition |
US20050145177A1 (en) * | 2003-12-30 | 2005-07-07 | Mcswiney Michael | Method and apparatus for low temperature silicon nitride deposition |
KR100560654B1 (ko) * | 2004-01-08 | 2006-03-16 | 삼성전자주식회사 | 질화실리콘막을 형성을 위한 질소화합물 및 이를 이용한질화실리콘 막의 형성방법 |
US20050181633A1 (en) * | 2004-02-17 | 2005-08-18 | Hochberg Arthur K. | Precursors for depositing silicon-containing films and processes thereof |
TW200603287A (en) * | 2004-03-26 | 2006-01-16 | Ulvac Inc | Unit layer posttreating catalytic chemical vapor deposition apparatus and method of film formation therewith |
KR101082921B1 (ko) | 2004-06-03 | 2011-11-11 | 삼성전자주식회사 | 반도체 소자의 실리콘 산화막 형성 방법 |
US20050282350A1 (en) | 2004-06-22 | 2005-12-22 | You-Hua Chou | Atomic layer deposition for filling a gap between devices |
US20060019032A1 (en) | 2004-07-23 | 2006-01-26 | Yaxin Wang | Low thermal budget silicon nitride formation for advance transistor fabrication |
JP4669679B2 (ja) * | 2004-07-29 | 2011-04-13 | 東京エレクトロン株式会社 | 窒化珪素膜の製造方法及び半導体装置の製造方法 |
US7629270B2 (en) | 2004-08-27 | 2009-12-08 | Asm America, Inc. | Remote plasma activated nitridation |
US20060084283A1 (en) * | 2004-10-20 | 2006-04-20 | Paranjpe Ajit P | Low temperature sin deposition methods |
US20060255315A1 (en) * | 2004-11-19 | 2006-11-16 | Yellowaga Deborah L | Selective removal chemistries for semiconductor applications, methods of production and uses thereof |
JP2006190770A (ja) | 2005-01-05 | 2006-07-20 | Hitachi Kokusai Electric Inc | 基板処理装置 |
KR100924055B1 (ko) * | 2005-02-17 | 2009-10-27 | 가부시키가이샤 히다치 고쿠사이 덴키 | 반도체 디바이스의 제조 방법 및 기판 처리 장치 |
US7608549B2 (en) | 2005-03-15 | 2009-10-27 | Asm America, Inc. | Method of forming non-conformal layers |
US20060213437A1 (en) | 2005-03-28 | 2006-09-28 | Tokyo Electron Limited | Plasma enhanced atomic layer deposition system |
JP4607637B2 (ja) | 2005-03-28 | 2011-01-05 | 東京エレクトロン株式会社 | シリコン窒化膜の形成方法、シリコン窒化膜の形成装置及びプログラム |
US8138104B2 (en) * | 2005-05-26 | 2012-03-20 | Applied Materials, Inc. | Method to increase silicon nitride tensile stress using nitrogen plasma in-situ treatment and ex-situ UV cure |
US7473655B2 (en) * | 2005-06-17 | 2009-01-06 | Applied Materials, Inc. | Method for silicon based dielectric chemical vapor deposition |
US7651955B2 (en) | 2005-06-21 | 2010-01-26 | Applied Materials, Inc. | Method for forming silicon-containing materials during a photoexcitation deposition process |
US7429538B2 (en) | 2005-06-27 | 2008-09-30 | Applied Materials, Inc. | Manufacturing method for two-step post nitridation annealing of plasma nitrided gate dielectric |
US7402534B2 (en) | 2005-08-26 | 2008-07-22 | Applied Materials, Inc. | Pretreatment processes within a batch ALD reactor |
US7785658B2 (en) | 2005-10-07 | 2010-08-31 | Asm Japan K.K. | Method for forming metal wiring structure |
US20070116888A1 (en) | 2005-11-18 | 2007-05-24 | Tokyo Electron Limited | Method and system for performing different deposition processes within a single chamber |
US7780865B2 (en) * | 2006-03-31 | 2010-08-24 | Applied Materials, Inc. | Method to improve the step coverage and pattern loading for dielectric films |
FR2900276B1 (fr) | 2006-04-25 | 2008-09-12 | St Microelectronics Sa | Depot peald d'un materiau a base de silicium |
US7795160B2 (en) * | 2006-07-21 | 2010-09-14 | Asm America Inc. | ALD of metal silicate films |
KR100752190B1 (ko) | 2006-09-04 | 2007-08-27 | 동부일렉트로닉스 주식회사 | 반도체 소자의 갭필 방법 |
US7531452B2 (en) | 2007-03-30 | 2009-05-12 | Tokyo Electron Limited | Strained metal silicon nitride films and method of forming |
US7651961B2 (en) * | 2007-03-30 | 2010-01-26 | Tokyo Electron Limited | Method for forming strained silicon nitride films and a device containing such films |
US7713874B2 (en) | 2007-05-02 | 2010-05-11 | Asm America, Inc. | Periodic plasma annealing in an ALD-type process |
US8084105B2 (en) | 2007-05-23 | 2011-12-27 | Applied Materials, Inc. | Method of depositing boron nitride and boron nitride-derived materials |
JP5151260B2 (ja) * | 2007-06-11 | 2013-02-27 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
CN100590803C (zh) * | 2007-06-22 | 2010-02-17 | 中芯国际集成电路制造(上海)有限公司 | 原子层沉积方法以及形成的半导体器件 |
US20090041952A1 (en) * | 2007-08-10 | 2009-02-12 | Asm Genitech Korea Ltd. | Method of depositing silicon oxide films |
US7867923B2 (en) * | 2007-10-22 | 2011-01-11 | Applied Materials, Inc. | High quality silicon oxide films by remote plasma CVD from disilane precursors |
US20090155606A1 (en) | 2007-12-13 | 2009-06-18 | Asm Genitech Korea Ltd. | Methods of depositing a silicon nitride film |
US7678715B2 (en) * | 2007-12-21 | 2010-03-16 | Applied Materials, Inc. | Low wet etch rate silicon nitride film |
JP4935684B2 (ja) | 2008-01-12 | 2012-05-23 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
US8129288B2 (en) * | 2008-05-02 | 2012-03-06 | Intermolecular, Inc. | Combinatorial plasma enhanced deposition techniques |
JP4935687B2 (ja) | 2008-01-19 | 2012-05-23 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
US7871942B2 (en) * | 2008-03-27 | 2011-01-18 | Applied Materials, Inc. | Methods for manufacturing high dielectric constant film |
US8148269B2 (en) * | 2008-04-04 | 2012-04-03 | Applied Materials, Inc. | Boron nitride and boron-nitride derived materials deposition method |
US8383525B2 (en) | 2008-04-25 | 2013-02-26 | Asm America, Inc. | Plasma-enhanced deposition process for forming a metal oxide thin film and related structures |
US8298628B2 (en) * | 2008-06-02 | 2012-10-30 | Air Products And Chemicals, Inc. | Low temperature deposition of silicon-containing films |
CN102047386B (zh) | 2008-06-03 | 2013-06-19 | 气体产品与化学公司 | 含硅薄膜的低温沉积 |
US8129555B2 (en) | 2008-08-12 | 2012-03-06 | Air Products And Chemicals, Inc. | Precursors for depositing silicon-containing films and methods for making and using same |
US8726838B2 (en) | 2010-03-31 | 2014-05-20 | Intermolecular, Inc. | Combinatorial plasma enhanced deposition and etch techniques |
JP2010103484A (ja) * | 2008-09-29 | 2010-05-06 | Adeka Corp | 半導体デバイス、その製造装置及び製造方法 |
US20120153442A1 (en) * | 2008-09-30 | 2012-06-21 | Tokyo Electron Limited | Silicon nitride film and process for production thereof, computer-readable storage medium, and plasma cvd device |
KR101491726B1 (ko) | 2008-10-08 | 2015-02-17 | 주성엔지니어링(주) | 반도체 소자의 갭필 방법 |
US10378106B2 (en) | 2008-11-14 | 2019-08-13 | Asm Ip Holding B.V. | Method of forming insulation film by modified PEALD |
US7919416B2 (en) | 2009-01-21 | 2011-04-05 | Asm Japan K.K. | Method of forming conformal dielectric film having Si-N bonds by PECVD |
JP5547418B2 (ja) * | 2009-03-19 | 2014-07-16 | 株式会社Adeka | 化学気相成長用原料及びこれを用いたシリコン含有薄膜形成方法 |
JP2011023718A (ja) | 2009-07-15 | 2011-02-03 | Asm Japan Kk | PEALDによってSi−N結合を有するストレス調節された誘電体膜を形成する方法 |
US8173554B2 (en) * | 2009-10-14 | 2012-05-08 | Asm Japan K.K. | Method of depositing dielectric film having Si-N bonds by modified peald method |
US8415259B2 (en) | 2009-10-14 | 2013-04-09 | Asm Japan K.K. | Method of depositing dielectric film by modified PEALD method |
US20110136347A1 (en) * | 2009-10-21 | 2011-06-09 | Applied Materials, Inc. | Point-of-use silylamine generation |
JP5346904B2 (ja) * | 2009-11-27 | 2013-11-20 | 東京エレクトロン株式会社 | 縦型成膜装置およびその使用方法 |
US8114761B2 (en) | 2009-11-30 | 2012-02-14 | Applied Materials, Inc. | Method for doping non-planar transistors |
US20110151677A1 (en) | 2009-12-21 | 2011-06-23 | Applied Materials, Inc. | Wet oxidation process performed on a dielectric material formed from a flowable cvd process |
US8937353B2 (en) | 2010-03-01 | 2015-01-20 | Taiwan Semiconductor Manufacturing Co., Ltd. | Dual epitaxial process for a finFET device |
US20130157466A1 (en) | 2010-03-25 | 2013-06-20 | Keith Fox | Silicon nitride films for semiconductor device applications |
US9076646B2 (en) * | 2010-04-15 | 2015-07-07 | Lam Research Corporation | Plasma enhanced atomic layer deposition with pulsed plasma exposure |
US8728956B2 (en) * | 2010-04-15 | 2014-05-20 | Novellus Systems, Inc. | Plasma activated conformal film deposition |
US8993460B2 (en) | 2013-01-10 | 2015-03-31 | Novellus Systems, Inc. | Apparatuses and methods for depositing SiC/SiCN films via cross-metathesis reactions with organometallic co-reactants |
US9611544B2 (en) * | 2010-04-15 | 2017-04-04 | Novellus Systems, Inc. | Plasma activated conformal dielectric film deposition |
US8637411B2 (en) * | 2010-04-15 | 2014-01-28 | Novellus Systems, Inc. | Plasma activated conformal dielectric film deposition |
US8956983B2 (en) * | 2010-04-15 | 2015-02-17 | Novellus Systems, Inc. | Conformal doping via plasma activated atomic layer deposition and conformal film deposition |
WO2011140355A2 (en) | 2010-05-07 | 2011-11-10 | Applied Materials, Inc. | Oxide nitride stack for backside reflector of solar cell |
WO2011162136A1 (en) * | 2010-06-23 | 2011-12-29 | Tokyo Electron Limited | Film formation method, semiconductor-device fabrication method, insulating film and semiconductor device |
US20130115374A1 (en) * | 2010-07-19 | 2013-05-09 | Krishnakumar M. Jayakar | Polycrystalline silicon production |
US8669185B2 (en) | 2010-07-30 | 2014-03-11 | Asm Japan K.K. | Method of tailoring conformality of Si-containing film |
US20120213940A1 (en) * | 2010-10-04 | 2012-08-23 | Applied Materials, Inc. | Atomic layer deposition of silicon nitride using dual-source precursor and interleaved plasma |
US20120149213A1 (en) | 2010-12-09 | 2012-06-14 | Lakshminarayana Nittala | Bottom up fill in high aspect ratio trenches |
JP5689398B2 (ja) | 2010-12-21 | 2015-03-25 | 東京エレクトロン株式会社 | 窒化シリコン膜の成膜方法及び成膜装置 |
JP2012142386A (ja) * | 2010-12-28 | 2012-07-26 | Elpida Memory Inc | 窒化膜の形成方法 |
US8465811B2 (en) | 2011-01-28 | 2013-06-18 | Asm Japan K.K. | Method of depositing film by atomic layer deposition with pulse-time-modulated plasma |
US8329599B2 (en) | 2011-02-18 | 2012-12-11 | Asm Japan K.K. | Method of depositing dielectric film by ALD using precursor containing silicon, hydrocarbon, and halogen |
US8563443B2 (en) | 2011-02-18 | 2013-10-22 | Asm Japan K.K. | Method of depositing dielectric film by ALD using precursor containing silicon, hydrocarbon, and halogen |
JP2012216631A (ja) | 2011-03-31 | 2012-11-08 | Tokyo Electron Ltd | プラズマ窒化処理方法 |
US8580664B2 (en) | 2011-03-31 | 2013-11-12 | Tokyo Electron Limited | Method for forming ultra-shallow boron doping regions by solid phase diffusion |
TW201306082A (zh) * | 2011-04-18 | 2013-02-01 | Tokyo Electron Ltd | 電漿評估方法、電漿處理方法及電漿處理裝置 |
KR101657341B1 (ko) | 2011-04-25 | 2016-09-13 | 도쿄엘렉트론가부시키가이샤 | 성막 방법 |
KR101659463B1 (ko) * | 2011-06-03 | 2016-09-23 | 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 | 탄소-도핑된 규소-함유 막을 증착시키기 위한 조성물 및 방법 |
KR101514231B1 (ko) | 2011-08-25 | 2015-04-22 | 가부시키가이샤 히다치 고쿠사이 덴키 | 반도체 장치의 제조 방법, 기판 처리 방법, 기판 처리 장치 및 기록 매체 |
US8476743B2 (en) | 2011-09-09 | 2013-07-02 | International Business Machines Corporation | C-rich carbon boron nitride dielectric films for use in electronic devices |
US8557666B2 (en) | 2011-09-13 | 2013-10-15 | GlobalFoundries, Inc. | Methods for fabricating integrated circuits |
US8993072B2 (en) * | 2011-09-27 | 2015-03-31 | Air Products And Chemicals, Inc. | Halogenated organoaminosilane precursors and methods for depositing films comprising same |
US8569184B2 (en) | 2011-09-30 | 2013-10-29 | Asm Japan K.K. | Method for forming single-phase multi-element film by PEALD |
JP6088178B2 (ja) | 2011-10-07 | 2017-03-01 | 株式会社日立国際電気 | 半導体装置の製造方法、基板処理装置およびプログラム |
JP6202798B2 (ja) | 2011-10-12 | 2017-09-27 | エーエスエム インターナショナル エヌ.ヴェー.Asm International N.V. | 酸化アンチモン膜の原子層堆積 |
TWI606136B (zh) * | 2011-11-04 | 2017-11-21 | Asm國際股份有限公司 | 沉積摻雜氧化矽的方法以及用於沉積摻雜氧化矽至基板上的原子層沉積製程 |
JP2013125762A (ja) | 2011-12-13 | 2013-06-24 | Tokyo Electron Ltd | 成膜装置、および成膜方法 |
US8698199B2 (en) * | 2012-01-11 | 2014-04-15 | United Microelectronics Corp. | FinFET structure |
US8586487B2 (en) * | 2012-01-18 | 2013-11-19 | Applied Materials, Inc. | Low temperature plasma enhanced chemical vapor deposition of conformal silicon carbon nitride and silicon nitride films |
US8592328B2 (en) | 2012-01-20 | 2013-11-26 | Novellus Systems, Inc. | Method for depositing a chlorine-free conformal sin film |
JP5912637B2 (ja) | 2012-02-17 | 2016-04-27 | 東京エレクトロン株式会社 | 半導体装置の製造方法 |
US20130224964A1 (en) | 2012-02-28 | 2013-08-29 | Asm Ip Holding B.V. | Method for Forming Dielectric Film Containing Si-C bonds by Atomic Layer Deposition Using Precursor Containing Si-C-Si bond |
US8912101B2 (en) * | 2012-03-15 | 2014-12-16 | Asm Ip Holding B.V. | Method for forming Si-containing film using two precursors by ALD |
JPWO2013137115A1 (ja) | 2012-03-15 | 2015-08-03 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
JP6105967B2 (ja) | 2012-03-21 | 2017-03-29 | 株式会社日立国際電気 | 半導体装置の製造方法、基板処理方法、基板処理装置およびプログラム |
JP5208294B2 (ja) * | 2012-04-23 | 2013-06-12 | 株式会社日立国際電気 | 半導体装置の製造方法、基板処理方法及び基板処理装置 |
US9337018B2 (en) * | 2012-06-01 | 2016-05-10 | Air Products And Chemicals, Inc. | Methods for depositing films with organoaminodisilane precursors |
US8722546B2 (en) | 2012-06-11 | 2014-05-13 | Asm Ip Holding B.V. | Method for forming silicon-containing dielectric film by cyclic deposition with side wall coverage control |
WO2014015237A1 (en) * | 2012-07-20 | 2014-01-23 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Organosilane precursors for ald/cvd silicon-containing film applications |
US20140023794A1 (en) | 2012-07-23 | 2014-01-23 | Maitreyee Mahajani | Method And Apparatus For Low Temperature ALD Deposition |
US20140030444A1 (en) | 2012-07-30 | 2014-01-30 | Novellus Systems, Inc. | High pressure, high power plasma activated conformal film deposition |
JP2014060378A (ja) | 2012-08-23 | 2014-04-03 | Tokyo Electron Ltd | シリコン窒化膜の成膜方法、有機電子デバイスの製造方法及びシリコン窒化膜の成膜装置 |
US8742668B2 (en) * | 2012-09-05 | 2014-06-03 | Asm Ip Holdings B.V. | Method for stabilizing plasma ignition |
US8889566B2 (en) * | 2012-09-11 | 2014-11-18 | Applied Materials, Inc. | Low cost flowable dielectric films |
US8772101B2 (en) * | 2012-11-08 | 2014-07-08 | Globalfoundries Inc. | Methods of forming replacement gate structures on semiconductor devices and the resulting device |
US8784951B2 (en) | 2012-11-16 | 2014-07-22 | Asm Ip Holding B.V. | Method for forming insulation film using non-halide precursor having four or more silicons |
JP2016509662A (ja) * | 2012-12-21 | 2016-03-31 | アールイーシー シリコン インコーポレイテッド | 流動床反応器のための高温グレードの鋼 |
CN103915341B (zh) * | 2013-01-08 | 2016-12-28 | 中芯国际集成电路制造(上海)有限公司 | 晶体管及其形成方法 |
US20140273526A1 (en) * | 2013-03-12 | 2014-09-18 | David Thompson | Atomic Layer Deposition Of Films Comprising Si(C)N Using Hydrazine, Azide And/Or Silyl Amine Derivatives |
US10573511B2 (en) | 2013-03-13 | 2020-02-25 | Asm Ip Holding B.V. | Methods for forming silicon nitride thin films |
US20140273531A1 (en) | 2013-03-14 | 2014-09-18 | Asm Ip Holding B.V. | Si PRECURSORS FOR DEPOSITION OF SiN AT LOW TEMPERATURES |
US9824881B2 (en) | 2013-03-14 | 2017-11-21 | Asm Ip Holding B.V. | Si precursors for deposition of SiN at low temperatures |
US9564309B2 (en) * | 2013-03-14 | 2017-02-07 | Asm Ip Holding B.V. | Si precursors for deposition of SiN at low temperatures |
TW201441408A (zh) | 2013-03-15 | 2014-11-01 | Applied Materials Inc | 包含氮化矽之膜的電漿輔助原子層沉積 |
US20140273530A1 (en) | 2013-03-15 | 2014-09-18 | Victor Nguyen | Post-Deposition Treatment Methods For Silicon Nitride |
US8828866B1 (en) | 2013-06-26 | 2014-09-09 | Applied Materials, Inc. | Methods for depositing a tantalum silicon nitride film |
US9576790B2 (en) | 2013-10-16 | 2017-02-21 | Asm Ip Holding B.V. | Deposition of boron and carbon containing materials |
US9362109B2 (en) | 2013-10-16 | 2016-06-07 | Asm Ip Holding B.V. | Deposition of boron and carbon containing materials |
US20150125628A1 (en) | 2013-11-06 | 2015-05-07 | Asm Ip Holding B.V. | Method of depositing thin film |
US9401273B2 (en) | 2013-12-11 | 2016-07-26 | Asm Ip Holding B.V. | Atomic layer deposition of silicon carbon nitride based materials |
US20150255324A1 (en) | 2014-03-06 | 2015-09-10 | Applied Materials, Inc. | Seamless gap-fill with spatial atomic layer deposition |
US9576792B2 (en) * | 2014-09-17 | 2017-02-21 | Asm Ip Holding B.V. | Deposition of SiN |
US10410857B2 (en) * | 2015-08-24 | 2019-09-10 | Asm Ip Holding B.V. | Formation of SiN thin films |
US9455138B1 (en) | 2015-11-10 | 2016-09-27 | Asm Ip Holding B.V. | Method for forming dielectric film in trenches by PEALD using H-containing gas |
US10269558B2 (en) * | 2016-12-22 | 2019-04-23 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US10867788B2 (en) | 2016-12-28 | 2020-12-15 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US10580645B2 (en) * | 2018-04-30 | 2020-03-03 | Asm Ip Holding B.V. | Plasma enhanced atomic layer deposition (PEALD) of SiN using silicon-hydrohalide precursors |
-
2013
- 2013-03-14 US US13/830,084 patent/US9824881B2/en active Active
-
2014
- 2014-03-07 TW TW108122575A patent/TWI680202B/zh active
- 2014-03-07 TW TW109115498A patent/TWI714504B/zh active
- 2014-03-07 TW TW103107945A patent/TWI652276B/zh active
- 2014-03-07 TW TW108109981A patent/TWI668325B/zh active
- 2014-03-07 TW TW108102215A patent/TWI660067B/zh active
- 2014-03-07 TW TW109143639A patent/TWI748792B/zh active
- 2014-03-07 TW TW108140178A patent/TWI695905B/zh active
- 2014-03-07 TW TW110140665A patent/TWI773572B/zh active
- 2014-03-07 TW TW109140926A patent/TWI748762B/zh active
- 2014-03-10 JP JP2014046638A patent/JP6452292B2/ja active Active
- 2014-03-13 CN CN201811364487.6A patent/CN109252145B/zh active Active
- 2014-03-13 KR KR1020140029846A patent/KR102039035B1/ko active IP Right Grant
- 2014-03-13 CN CN201410092569.5A patent/CN104046955B/zh active Active
-
2017
- 2017-09-13 US US15/703,241 patent/US10424477B2/en active Active
-
2018
- 2018-12-11 JP JP2018231362A patent/JP2019062225A/ja active Pending
-
2019
- 2019-09-18 US US16/574,542 patent/US11289327B2/en active Active
- 2019-10-25 KR KR1020190133724A patent/KR102176030B1/ko active IP Right Grant
-
2020
- 2020-05-19 JP JP2020087411A patent/JP7219738B2/ja active Active
- 2020-11-02 KR KR1020200144734A patent/KR102319525B1/ko active IP Right Grant
- 2020-12-10 KR KR1020200172141A patent/KR102514553B1/ko active IP Right Grant
- 2020-12-14 JP JP2020206502A patent/JP7123115B2/ja active Active
-
2022
- 2022-11-14 JP JP2022181645A patent/JP7383106B2/ja active Active
-
2023
- 2023-03-22 KR KR1020230037451A patent/KR20230043095A/ko active IP Right Grant
- 2023-11-02 JP JP2023188399A patent/JP2024023223A/ja active Pending
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7123115B2 (ja) | 低温でのSiNの蒸着用Si前駆体 | |
US11587783B2 (en) | Si precursors for deposition of SiN at low temperatures | |
US20140273531A1 (en) | Si PRECURSORS FOR DEPOSITION OF SiN AT LOW TEMPERATURES |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170302 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170302 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180125 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180130 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180925 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181026 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20181113 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20181211 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6452292 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |