JP6321539B2 - 構造化粒子 - Google Patents
構造化粒子 Download PDFInfo
- Publication number
- JP6321539B2 JP6321539B2 JP2014516447A JP2014516447A JP6321539B2 JP 6321539 B2 JP6321539 B2 JP 6321539B2 JP 2014516447 A JP2014516447 A JP 2014516447A JP 2014516447 A JP2014516447 A JP 2014516447A JP 6321539 B2 JP6321539 B2 JP 6321539B2
- Authority
- JP
- Japan
- Prior art keywords
- particles
- pillared
- powder
- pillar
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/052—Metallic powder characterised by the size or surface area of the particles characterised by a mixture of particles of different sizes or by the particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/049—Manufacturing of an active layer by chemical means
- H01M4/0492—Chemical attack of the support material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
- H01M4/0428—Chemical vapour deposition
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Silicon Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1110785.1 | 2011-06-24 | ||
| GB1110785.1A GB2492167C (en) | 2011-06-24 | 2011-06-24 | Structured particles |
| PCT/GB2012/051475 WO2012175998A1 (en) | 2011-06-24 | 2012-06-22 | Structured particles |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018072859A Division JP6568973B2 (ja) | 2011-06-24 | 2018-04-05 | 構造化粒子 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014523066A JP2014523066A (ja) | 2014-09-08 |
| JP2014523066A5 JP2014523066A5 (https=) | 2017-08-24 |
| JP6321539B2 true JP6321539B2 (ja) | 2018-05-09 |
Family
ID=44485146
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014516447A Expired - Fee Related JP6321539B2 (ja) | 2011-06-24 | 2012-06-22 | 構造化粒子 |
| JP2018072859A Active JP6568973B2 (ja) | 2011-06-24 | 2018-04-05 | 構造化粒子 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018072859A Active JP6568973B2 (ja) | 2011-06-24 | 2018-04-05 | 構造化粒子 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10077506B2 (https=) |
| EP (2) | EP2724404B1 (https=) |
| JP (2) | JP6321539B2 (https=) |
| KR (1) | KR102018168B1 (https=) |
| CN (3) | CN103718354B (https=) |
| GB (3) | GB2492167C (https=) |
| WO (1) | WO2012175998A1 (https=) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2492167C (en) | 2011-06-24 | 2018-12-05 | Nexeon Ltd | Structured particles |
| JP2015510666A (ja) | 2012-01-30 | 2015-04-09 | ネクソン リミテッドNexeon Limited | Si/C電気活性材料組成物 |
| US9337478B2 (en) * | 2012-02-14 | 2016-05-10 | Shailesh Upreti | Composite silicon or composite tin particles |
| GB2499984B (en) | 2012-02-28 | 2014-08-06 | Nexeon Ltd | Composite particles comprising a removable filler |
| GB2502625B (en) | 2012-06-06 | 2015-07-29 | Nexeon Ltd | Method of forming silicon |
| GB2507535B (en) | 2012-11-02 | 2015-07-15 | Nexeon Ltd | Multilayer electrode |
| US9959983B2 (en) | 2013-06-28 | 2018-05-01 | Intel Corporation | Robust porous electrodes for energy storage devices |
| GB2516318B (en) * | 2013-07-19 | 2017-02-15 | Nexeon Ltd | Etched silicon structures, method of forming etched silicon structures and uses thereof |
| EP2919298B1 (en) * | 2014-03-12 | 2017-08-23 | Belenos Clean Power Holding AG | Si/C composite anodes for lithium-ion batteries with a sustained high capacity per unit area |
| US9657723B1 (en) * | 2014-03-26 | 2017-05-23 | Lockheed Martin Corporation | Carbon nanotube-based fluidized bed heat transfer media for concentrating solar power applications |
| KR101567203B1 (ko) | 2014-04-09 | 2015-11-09 | (주)오렌지파워 | 이차 전지용 음극 활물질 및 이의 방법 |
| KR101604352B1 (ko) | 2014-04-22 | 2016-03-18 | (주)오렌지파워 | 음극 활물질 및 이를 포함하는 리튬 이차 전지 |
| JP6252858B2 (ja) * | 2014-04-25 | 2017-12-27 | 株式会社豊田自動織機 | リチウムイオン二次電池用正極及びリチウムイオン二次電池 |
| JP6289995B2 (ja) * | 2014-05-13 | 2018-03-07 | 株式会社東芝 | 負極、負極の製造方法、及び非水電解質電池 |
| KR101550781B1 (ko) | 2014-07-23 | 2015-09-08 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자의 제조 방법 |
| GB2529411A (en) * | 2014-08-18 | 2016-02-24 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| GB2529410A (en) * | 2014-08-18 | 2016-02-24 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| CN106797022B (zh) | 2014-10-15 | 2020-09-08 | 学校法人东京理科大学 | 钾离子二次电池或钾离子电容器 |
| GB2533161C (en) | 2014-12-12 | 2019-07-24 | Nexeon Ltd | Electrodes for metal-ion batteries |
| KR101614016B1 (ko) | 2014-12-31 | 2016-04-20 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
| JP6407771B2 (ja) * | 2015-03-10 | 2018-10-17 | 大阪瓦斯株式会社 | 振動吸収材及びその製造方法 |
| KR101726037B1 (ko) | 2015-03-26 | 2017-04-11 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
| US9601763B2 (en) * | 2015-03-27 | 2017-03-21 | Nanotek Instruments, Inc. | Process for mass-producing silicon nanowires and silicon nanowire-graphene hybrid particulates |
| EP3353844B1 (en) | 2015-03-27 | 2022-05-11 | Mason K. Harrup | All-inorganic solvents for electrolytes |
| CN104792679B (zh) * | 2015-04-08 | 2017-10-27 | 东华大学 | 一种中空微球复合材料孔隙率检测标块及其制备方法 |
| DE102015215415A1 (de) * | 2015-08-12 | 2017-02-16 | Wacker Chemie Ag | Siliciumpartikel enthaltende Anodenmaterialien für Lithium-Ionen-Batterien |
| US10319987B2 (en) * | 2015-12-21 | 2019-06-11 | Nissan North America, Inc. | Active material with expansion structure for use in lithium ion batteries |
| JP6723545B2 (ja) * | 2016-03-04 | 2020-07-15 | エルジー・ケム・リミテッド | 二次電池用正極活物質、その製造方法およびこれを含む二次電池 |
| EP3469644B1 (en) | 2016-06-14 | 2022-11-09 | Nexeon Limited | Electrodes for metal-ion batteries |
| KR101918815B1 (ko) | 2016-08-23 | 2018-11-15 | 넥시온 엘티디. | 이차 전지용 음극 활물질 및 이의 제조 방법 |
| KR101773719B1 (ko) | 2016-08-23 | 2017-09-01 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자 및 이의 제조 방법 |
| JP6743159B2 (ja) * | 2016-09-23 | 2020-08-19 | 株式会社豊田自動織機 | Si粒子結合体及びその製造方法 |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| GB2563455B (en) | 2017-06-16 | 2019-06-19 | Nexeon Ltd | Particulate electroactive materials for use in metal-ion batteries |
| FR3069461B1 (fr) | 2017-07-28 | 2021-12-24 | Enwires | Materiau nanostructure et son procede de preparation |
| GB201803983D0 (en) | 2017-09-13 | 2018-04-25 | Unifrax I Llc | Materials |
| GB201818235D0 (en) * | 2018-11-08 | 2018-12-26 | Nexeon Ltd | Electroactive materials for metal-ion batteries |
| US12218341B2 (en) * | 2018-11-08 | 2025-02-04 | Nexeon Limited | Electroactive materials for metal-ion batteries |
| US12106968B2 (en) * | 2019-08-01 | 2024-10-01 | Ram Nanotech, Incorporated | Injection metal assisted catalytic etching |
| KR20210099433A (ko) | 2020-02-04 | 2021-08-12 | 삼성전자주식회사 | 양극, 이를 포함하는 리튬-공기 전지 및 이의 제조 방법 |
| KR102935447B1 (ko) * | 2020-02-04 | 2026-03-05 | 삼성전자주식회사 | 양극, 이를 포함하는 리튬-공기 전지 및 이의 제조 방법 |
| WO2021182617A1 (ja) * | 2020-03-13 | 2021-09-16 | 積水化学工業株式会社 | 導電性粒子、導電材料及び接続構造体 |
| CN120933339A (zh) * | 2020-08-03 | 2025-11-11 | 奈克松有限公司 | 用于金属离子电池的电活性材料 |
| KR102411717B1 (ko) * | 2021-05-12 | 2022-06-22 | 아주대학교산학협력단 | 구리 복합 구조체의 제조방법 및 이에 의해 제조된 구리 복합 구조체를 포함하는 에너지 저장 장치 및 라만 분광 기판 구조물 |
| US20250015259A1 (en) * | 2021-12-02 | 2025-01-09 | Wacker Chemie Ag | Process for producing silicon-containing materials |
| US20230216032A1 (en) * | 2022-01-04 | 2023-07-06 | Prologium Technology Co., Ltd. | Composite negative active material ball |
| JP2024122207A (ja) * | 2023-02-28 | 2024-09-09 | Tdk株式会社 | リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
| JP7696640B2 (ja) * | 2023-07-28 | 2025-06-23 | 学校法人東京電機大学 | リチウムイオン二次電池用負極材料、リチウムイオン二次電池用負極及びリチウムイオン二次電池、並びにこれらの製法方法 |
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| SU471402A1 (ru) | 1973-03-02 | 1975-05-25 | Предприятие П/Я Г-4671 | Травильный раствор |
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| CN107104234B (zh) | 2019-11-08 |
| GB201110785D0 (en) | 2011-08-10 |
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| US10822713B2 (en) | 2020-11-03 |
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| GB2492167C (en) | 2018-12-05 |
| CN103718354B (zh) | 2017-05-24 |
| GB201316571D0 (en) | 2013-10-30 |
| GB201211164D0 (en) | 2012-08-08 |
| EP2724404A1 (en) | 2014-04-30 |
| WO2012175998A1 (en) | 2012-12-27 |
| US10077506B2 (en) | 2018-09-18 |
| CN107104234A (zh) | 2017-08-29 |
| JP6568973B2 (ja) | 2019-08-28 |
| EP2724404B1 (en) | 2018-04-18 |
| KR102018168B1 (ko) | 2019-09-04 |
| CN106935795A (zh) | 2017-07-07 |
| GB2502500B (en) | 2018-12-12 |
| US20140162131A1 (en) | 2014-06-12 |
| CN106935795B (zh) | 2019-09-24 |
| JP2014523066A (ja) | 2014-09-08 |
| CN103718354A (zh) | 2014-04-09 |
| US20190119826A1 (en) | 2019-04-25 |
| KR20140072863A (ko) | 2014-06-13 |
| JP2018152346A (ja) | 2018-09-27 |
| EP3396747B1 (en) | 2021-09-22 |
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