US20100290963A1 - Transition metal / zeolite scr catalysts - Google Patents

Transition metal / zeolite scr catalysts Download PDF

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Publication number
US20100290963A1
US20100290963A1 US12/597,707 US59770710A US2010290963A1 US 20100290963 A1 US20100290963 A1 US 20100290963A1 US 59770710 A US59770710 A US 59770710A US 2010290963 A1 US2010290963 A1 US 2010290963A1
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US
United States
Prior art keywords
sapo
zeolite
catalyst
transition metal
zeolites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/597,707
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English (en)
Inventor
Paul Joseph Andersen
Jillian Elaine Bailie
John Leonello Casci
Hai-Ying Chen
Joseph Michael Fedeyko
Rodney Kok Shin Foo
Raj Rao Rajaram
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38814668&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20100290963(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Assigned to JOHNSON MATTHEY PLC reassignment JOHNSON MATTHEY PLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FEDEYKO, JOSEPH, ANDERSEN, PAUL, CASCI, JOHN, CHEN, HAI-YING, BAILIE, JILLIAN, RAJARAM, RAJ
Assigned to JOHNSON MATTHEY PLC reassignment JOHNSON MATTHEY PLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FOO KOK SHIN, RODNEY
Publication of US20100290963A1 publication Critical patent/US20100290963A1/en
Priority to US13/164,150 priority Critical patent/US8603432B2/en
Priority to US13/567,703 priority patent/US20120301380A1/en
Priority to US13/567,698 priority patent/US20120301379A1/en
Priority to US13/567,705 priority patent/US8906820B2/en
Priority to US13/567,692 priority patent/US20120301378A1/en
Priority to US14/552,161 priority patent/US20150078968A1/en
Priority to US14/587,653 priority patent/US20150118121A1/en
Priority to US14/587,613 priority patent/US20150118114A1/en
Priority to US14/587,793 priority patent/US20150110682A1/en
Priority to US14/587,709 priority patent/US20150118115A1/en
Priority to US15/252,376 priority patent/US20160367939A1/en
Priority to US15/991,565 priority patent/US11478748B2/en
Abandoned legal-status Critical Current

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    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the present invention relates to a method of converting nitrogen oxides in a gas, such as an exhaust gas of a vehicular lean-burn internal combustion engine, to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a transition metal-containing zeolite catalyst.
  • SCR Selective catalytic reduction
  • nitrogenous compounds such as ammonia or urea
  • SCR technology was first used in thermal power plants in Japan in the late 1970s, and has seen widespread application in Europe since the mid-1980s.
  • SCR systems were introduced for gas turbines in the 1990s and have been used more recently in coal-fired powerplants.
  • SCR applications include plant and refinery heaters and boilers in the chemical processing industry, furnaces, coke ovens, municipal waste plants and incinerators.
  • NO x reduction systems based on SCR technology are being developed for a number of vehicular (mobile) applications in Europe, Japan, and the USA, e.g. for treating diesel exhaust gas.
  • reaction (1) Several chemical reactions occur in an NH 3 SCR system, all of which represent desirable reactions that reduce NO x to nitrogen. The dominant reaction is represented by reaction (1).
  • reaction (2) Competing, non-selective reactions with oxygen can produce secondary emissions or may unproductively consume Ammonia.
  • One such non-selective reaction is the complete oxidation of ammonia, shown in reaction (2).
  • reaction (3) may lead to undesirable products such as N 2 O, as represented by reaction (3).
  • Aluminosilicate zeolites are used as catalysts for SCR of NO x with NH 3 .
  • One application is to control NO x emissions from vehicular diesel engines, with the reductant obtainable from an ammonia precursor such as urea or by injecting ammonia per se.
  • transition metals are incorporated into the aluminosilicate zeolites.
  • the most commonly tested transition metal zeolites are Cu/ZSM-5, Cu/Beta, Fe/ZSM-5 and Fe/Beta because they have a relatively wide temperature activity window. In general, Cu-based zeolite catalysts show better low temperature NO reduction activity than Fe-based zeolite catalysts.
  • ZSM-5 and Beta zeolites have a number of drawbacks. They are susceptible to dealumination during high temperature hydrothermal ageing resulting in a loss of acidity, especially with Cu/Beta and Cu/ZSM-5 catalysts. Both Beta- and ZSM-5-based catalysts are also affected by hydrocarbons which become adsorbed on the catalysts at relatively low temperatures and are oxidised as the temperature of the catalytic system is raised generating a significant exotherm, which can thermally damage the catalyst. This problem is particularly acute in vehicular diesel applications where significant quantities of hydrocarbon can be adsorbed on the catalyst during cold-start; and Beta and ZSM-5 zeolites are also prone to coking by hydrocarbons.
  • Cu-based zeolite catalysts are less thermally durable, and produce higher levels of N 2 O than Fe-based zeolite catalysts. However, they have a desirable advantage in that they slip less ammonia in use compared with a corresponding Fe-zeolite catalyst.
  • aluminophosphate zeolites that contain transition metals demonstrate enhanced catalytic activity and superior thermal stability than aluminosilicate zeolite catalysts for SCR of NO x with hydrocarbons (also known as lean NO x catalysis or “DeNOx catalysts” (e.g. Ishihara et al., Journal of Catalysis, 169 (1997) 93)).
  • WO 2006/064805 discloses an electrical processing technology for treating diesel engine exhaust gas which utilizes corona discharge.
  • a combination of a device for adding a NO x reducer (hydrocarbon or fuel) and a Cu-SAPO-34 NO x reducing catalyst can be disposed downstream of the electrical processing apparatus.
  • transition metal-containing aluminophosphate zeolites for SCR of NO x with NH 3 (or urea) reported in any literature to date.
  • WO 00/72965 discloses iron (Fe) exchanged zeolites for the selective catalytic reduction of nitrogen monoxide by ammonia for controlling NO x emissions from fossil-fuel power plants and engines.
  • the Fe-exchanged, and optionally Fe-rare earth-exchanged, e.g. Fe-Ce-exchanged, zeolites suggested include: ZSM-5, mordenite, SAPO, clinoptilolite, chabazite, ZK-4 and ZK-5. No specific SAPO zeolites are identified and no experiment using SAPO zeolites is disclosed.
  • WO '965 teaches that the disclosure has application to zeolites with a range of pore sizes, i.e.
  • U.S. Pat. No. 4,735,927 discloses an extruded-type NH 3 —SCR catalyst with stability to sulfur poisoning comprising a high surface area titania in the form of anatase and a natural or synthetic zeolite.
  • the zeolite must be either in the acid form or thermally convertible to the acid form in the catalytic product.
  • suitable zeolites include mordenite, natural clinoptilolite, erionite, heulandite, ferrierite, natural faujasite or its synthetic counterpart zeolite Y, chabazite and gmelinite.
  • a preferred zeolite is natural clinoptilolite, which may be mixed with another acid stable zeolite such as chabazite.
  • the catalyst may optionally include small amounts (at least 0.1% by elemental weight) of a promoter in the form of precursors of vanadium oxide, copper oxide, molybdenum oxide or combinations thereof (0.2 wt % Cu and up to 1.6 wt % V are exemplified).
  • Extruded-type catalysts are generally less durable, have lower chemical strength, require more catalyst material to achieve the same activity and are more complicated to manufacture than catalyst coatings applied to inert monolith substrates.
  • U.S. Pat. No. 5,417,949 also discloses an extruded-type NH 3 —SCR catalyst comprising a zeolite having a constraint index of up to 12 and a titania binder. Intentionally, no transition metal promoter is present.
  • Constraint Index is a test to determine shape-selective catalytic behaviour in zeolites. It compares the reaction rates for the cracking of n-hexane and its isomer 3-methylpentane under competitive conditions (see V. J. Frillette et al., J Catal. 67 (1991) 218)).
  • U.S. Pat. No. 5,589,147 discloses an ammonia SCR catalyst comprising a molecular sieve and a metal, which catalyst can be coated on a substrate monolith.
  • the molecular sieve useful in the invention is not limited to any particular molecular sieve material and, in general, includes all metallosilicates, metallophosphates, silicoaluminophosphates and layered and pillared layered materials.
  • the metal is typically selected from at least one of the metals of Groups of the Periodic Table IIIA, IB, IIB, VA, VIA, VIIA, VIIIA, and combinations thereof.
  • Examples of these metals include at least one of copper, zinc, vanadium, chromium, manganese, cobalt, iron, nickel, rhodium, palladium, platinum, molybdenum, tungsten, cerium and mixtures thereof.
  • intermediate pore size zeolites e.g. those having pore sizes of from about 5 to less than 7 Angstroms, are preferred in the process of the invention.
  • intermediate pore size zeolites are preferred because they provide constrained access to and egress from the intracrystalline free space: “The intermediate pore size zeolites . . . have an effective pore size such as to freely sorb normal hexane . . .
  • WO 2004/002611 discloses an NH 3 —SCR catalyst comprising a ceria-doped aluminosilicate zeolite.
  • U.S. Pat. No. 6,514,470 discloses a process for catalytically reducing NO x in an exhaust gas stream containing nitrogen oxides and a reductant material.
  • the catalyst comprises an aluminium-silicate material and a metal in an amount of up to about 0.1 weight percent based on the total weight of catalyst. All of the examples use ferrierite.
  • U.S. Pat. No. 4,961,917 discloses an NH 3 —SCR catalyst comprising a zeolite having a silica-to-alumina ratio of at least about 10, and a pore structure which is interconnected in all three crystallographic dimensions by pores having an average kinetic pore diameter of at least about 7 Angstroms and a Cu or Fe promoter.
  • the catalysts are said to have high activity, reduced NH 3 oxidation and reduced sulphur poisoning.
  • Zeolite Beta and zeolite Y are two zeolites that meet the required definition.
  • U.S. Pat. No. 3,895,094 discloses an NH 3 —SCR process using zeolite catalysts of at least 6 Angstrom intercrystalline pore size. No mention is made of exchanging the zeolites with transition metals.
  • U.S. Pat. No. 4,220,632 also discloses an NH 3 —SCR process, this time using 3-10 Angstrom pore size zeolites of Na or H form.
  • WO 02/41991 discloses metal promoted zeolite Beta for NH 3 —SCR, wherein the zeolite is pre-treated so as to provide it with improved hydrothermal stability.
  • the invention provides a method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.
  • zeolite catalyst containing at least one transition metal herein we mean a zeolite structure to which has been added by ion exchange, impregnation or isomorphous substitution etc. one or more metals.
  • Transition metal-containing zeolite catalyst and “zeolite catalyst containing at least one transition metal” and similar terms are used interchangeably herein.
  • zeolites by their Framework Type Codes we intend to include the “Type Material” and any and all isotypic framework materials.
  • the “Type Material” is the species first used to establish the framework type).
  • Table 1 lists a range of illustrative zeolite zeotype framework materials for use in the present invention.
  • chabazite is to the zeolite material per se (in this example the naturally occurring type material chabazite) and not to any other material designated by the Framework Type Code to which the individual zeolite may belong, e.g. some other isotypic framework material.
  • zeolite type materials such as naturally occurring (i.e. mineral) chabazite
  • isotypes within the same Framework Type Code is not merely arbitrary, but reflects differences in the properties between the materials, which may in turn lead to differences in activity in the method of the present invention.
  • chabazite naturally occurring (i.e. mineral) chabazite
  • isotypes within the same Framework Type Code is not merely arbitrary, but reflects differences in the properties between the materials, which may in turn lead to differences in activity in the method of the present invention.
  • the naturally occurring chabazite has a lower silica-to-alumina ratio than aluminosilicate isotypes such as SSZ-13, the naturally occurring chabazite has lower acidity than aluminosilicate isotypes such as SSZ-13 and the activity of the material in the method of the present invention is relatively low (see the comparison of Cu/naturally occurring chabazite with Cu/SAPO-34 in Example 13).
  • the zeolite catalysts for use in the present invention can be coated on a suitable substrate monolith or can be formed as extruded-type catalysts, but are preferably used in a catalyst coating.
  • the zeolite catalyst is not one of Co, Ga, Mn, In or Zn or any combination of two or more thereof/epistilbite (see U.S. Pat. No. 6,514,470).
  • the transition metal-containing small pore zeolite is not Cu/chabazite, Mo/chabazite, Cu-Mo/chabazite, Cu/erionite, Mo/erionite or Cu-Mo/erionite (see U.S. Pat. No. 4,735,927).
  • the transition metal-containing small pore zeolite is not Ce/erionite (see WO 2004/002611).
  • the transition metal-containing small pore zeolite is not Fe/chabazite, Fe/ZK-5, Fe/ZK-4, Fe-rare-earth/chabazite, Fe-rare-earth/ZK-5 or Fe-rare-earth/ZK-4 (see WO 00/72965).
  • WO 00/72965 discloses the use of Ce/SAPO zeolites and Ce-rare-earth/SAPO zeolites in general, it does not disclose any particular small pore SAPO zeolites with application in the present invention, such as SAPO-17, SAPO-18, SAPO-34, SAPO-35, SAPO-39, SAPO-43 and SAPO-56.
  • the transition metal-containing small pore zeolite is not Fe/chabazite, (see Long et al. Journal of Catalysis 207 (2002) 274-285). Whilst, for the reasons given hereinabove, we do not believe that U.S. Pat. No.
  • the zeolite catalyst is not any one of copper, zinc, chromium, manganese, cobalt, iron, nickel, rhodium, palladium, platinum, molybdenum, cerium or mixtures thereof/any one of aluminosilicate chabazite, aluminosilicate erionite, aluminosilicate ZSM-34 and SAPO-34.
  • the transition metal-containing zeolite catalyst is not LTA or Fe/CHA.
  • chabazite is a small pore zeolite according to the definition adopted herein and that the Long et al. paper mentioned above reports that Fe/chabazite has the poorest activity of any of the catalysts tested. Without wishing to be bound by any theory, we believe that the poor performance of the Fe/chabazite in this study is due to two principal reasons. Firstly, natural chabazite can contain basic metal cations including potassium, sodium, strontium and calcium. To obtain an active material the basic metal cations need to be exchanged for e.g. iron cations because basic metals are a known poison of zeolite acid sites.
  • iron ions can form metal complexes (coordination compounds) with suitable ligands in the ionic exchange medium.
  • coordination compounds metal complexes
  • suitable ligands in the ionic exchange medium.
  • Long et al. use an aqueous FeCl 2 solution for ion exchange. Since the zeolite pores are relatively small, it is possible that a bulky co-ordination compound may not be able to gain access to the active sites located in the pores.
  • Suitable substituent metals include one or more of, without limitation, As, B, Be, Co, Fe, Ga, Ge, Li, Mg, Mn, Zn and Zr.
  • the small pore zeolites for use in the present invention can be selected from the group consisting of aluminosilicate zeolites, metal-substituted aluminosilicate zeolites and aluminophosphate zeolites.
  • Aluminophosphate zeolites with application in the present invention include aluminophosphate (A1PO) zeolites, metal substituted zeolites (MeA1PO) zeolites, silico-aluminophosphate (SAPO) zeolites and metal substituted silico-aluminophosphate (MeAPSO) zeolites.
  • A1PO aluminophosphate
  • MeA1PO metal substituted zeolites
  • SAPO silico-aluminophosphate
  • MeAPSO metal substituted silico-aluminophosphate
  • the invention extends to catalyst coatings and extruded-type substrate monoliths comprising both transition metal-containing small pore zeolites according to the invention and non-small pore zeolites (whether metallised or not) such as medium-, large- and meso-pore zeolites (whether containing transition metal(s) or not) because such a combination also obtains the advantages of using small pore zeolites per se.
  • the catalyst coatings and extruded-type substrate monoliths for use in the invention can comprise combinations of two or more transition metal-containing small pore zeolites.
  • each small pore zeolite in such a combination can contain one or more transition metals, each being ° selected from the group defined hereinabove, e.g. a first small pore zeolite can contain both Cu and Fe and a second small pore zeolite in combination with the first small pore zeolite can contain Ce.
  • transition metal-containing small pore zeolites are advantageous catalysts for SCR of NO x with NH 3 .
  • transition metal-containing small pore zeolite catalysts demonstrate significantly improved NO x reduction activity, especially at low temperatures. They also exhibit high selectivity to N 2 (e.g. low N 2 O formation) and good hydrothermal stability.
  • small pore zeolites containing at least one transition metal are more resistant to hydrocarbon inhibition than larger pore zeolites, e.g.
  • a medium pore zeolite such as ZSM-5
  • a large pore zeolite a zeolite having a maximum ring size of 12
  • Beta a medium pore zeolite
  • Small pore aluminophosphate zeolites for, use in the present invention include SAPO-17, SAPO-18, SAPO-34, SAPO-35, SAPO-39, SAPO-43 and SAPO-56.
  • the small pore zeolite is selected from the group of Framework Type Codes consisting of: ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, CHA, DDR, DFT, EAB, EDI, EPI, ERI, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, RTH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG and ZON.
  • Framework Type Codes consisting of: ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, CHA, DDR, DFT, EAB, EDI, EPI, ERI, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON,
  • Zeolites with application in the present invention can include those that have been treated to improve hydrothermal stability.
  • Illustrative methods of improving hydrothermal stability include:
  • small pore zeolites may minimise the detrimental effect of hydrocarbons by means of a molecular sieving effect, whereby the small pore zeolite allows NO and NH 3 to diffuse, to the active sites inside the pores but that the diffusion of hydrocarbon molecules is restricted.
  • the kinetic diameter of both NO (3.16 ⁇ ) and NH 3 (2.6 ⁇ ) is smaller than those of the typical hydrocarbons (C 3 H 6 ⁇ 4.5 ⁇ , n-C 8 H 18 ⁇ 4.30 ⁇ and C 7 H 8 ⁇ 6.0 ⁇ ) present in, for example, diesel engine exhaust.
  • the small pore zeolite catalysts for use in the present invention have a pore size in at least one dimension of less than 4.3 ⁇ .
  • Illustrative examples of suitable small pore zeolites are set out in Table 1.
  • Small pore zeolites with particular application for treating NO x in exhaust gases of lean-burn internal combustion engines, e.g. vehicular exhaust gases are set out in Table 2.
  • Small pore aluminosilicate zeolites for use in the present invention can have a silica-to-alumina ratio (SAR) of from 2 to 300, optionally 4 to 200 and preferably 8 to 150. It will be appreciated that higher SAR ratios are preferred to improve thermal stability but this may negatively affect transition metal exchange. Therefore, in selecting preferred materials consideration can be given to SAR so that a balance may be struck between these two properties.
  • SAR silica-to-alumina ratio
  • the gas containing the nitrogen oxides can, contact the zeolite catalyst at a gas hourly space velocity of from 5,000 hr ⁇ 1 to 500,000 hr ⁇ 1 , optionally from 10,000 hr ⁇ 1 to 200,000 hr ⁇ 1 .
  • the small pore zeolites for use in the present invention do not include aluminophosphate zeolites as defined herein.
  • the small pore zeolites (as defined herein) for use in the present invention are restricted to aluminophosphate zeolites (as defined herein).
  • small pore zeolites for use in the present invention are aluminosilicate zeolites and metal substituted aluminosilicate zeolites (and not aluminophosphate zeolites as defined herein).
  • Small pore zeolites for use in the invention can have three-dimensional dimensionality, i.e. a pore structure which is interconnected in all three crystallographic dimensions, or two-dimensional dimensionality.
  • the small pore zeolites for use in the present invention consist of zeolites having three-dimensional dimensionality.
  • the small pore zeolites for use in the present invention consist of zeolites having two-dimensional dimensionality.
  • the at least one transition metal is selected from the group consisting of Cr, Ce, Mn, Fe, Co, Ni and Cu. In a preferred embodiment, the at least one transition metal is selected from the group consisting of Cu, Fe and Ce. In a particular embodiment, the at least one transition metal consists of Cu. In another particular embodiment, the at least one transition metal consists of Fe. In a further particular embodiment, the at least one transition metal is Cu and/or Fe.
  • the total of the at least one transition metal that can be included in the at least one transition metal-containing zeolite can be from 0.01 to 20 wt %, based on the total weight of the zeolite catalyst containing at least one transition metal. In one embodiment, the total of the at least one transition metal that can be included can be from 0.1 to 10 wt %. In a particular embodiment, the total of the at least one transition metal that can be included is from 0.5 to 5 wt %.
  • a preferred transition metal-containing two dimensional small pore zeolite for use in the present invention consists of Cu/LEV, such as Cu/Nu-3, whereas a preferred transition metal-containing three dimensional small pore zeolite/aluminophosphate zeolite for use in the present invention consists of Cu/CHA, such as Cu/SAPO-34 or Cu/SSZ-13.
  • Fe-containing zeolite catalysts are preferred, such as Fe-CHA, e.g. Fe/SAPO-34 or Fe/SSZ-13.
  • the at least one transition metal can be included in the zeolite by any feasible method. For example, it can be added after the zeolite has been synthesised, e.g. by incipient wetness or exchange process; or the at least one metal can be added during zeolite synthesis.
  • the zeolite catalyst for use in the present invention can be coated, e.g. as a washcoat component, on a suitable monolith substrate, such as a metal or ceramic flow through monolith substrate or a filtering substrate, such as a wall-flow filter or sintered metal or partial filter (such as is disclosed in WO 01/80978 or EP 1057519, the latter document describing a substrate comprising convoluted flow paths that at least slows the passage of soot therethrough).
  • a suitable monolith substrate such as a metal or ceramic flow through monolith substrate or a filtering substrate, such as a wall-flow filter or sintered metal or partial filter (such as is disclosed in WO 01/80978 or EP 1057519, the latter document describing a substrate comprising convoluted flow paths that at least slows the passage of soot therethrough).
  • the zeolites for use in the present invention can be synthesized directly onto the substrate.
  • the zeolite catalysts according to the invention can be formed into an extruded-type flow through catalyst.
  • washcoat compositions containing the zeolites for use in the present invention for coating onto the monolith substrate for manufacturing extruded type substrate monoliths can comprise a binder selected from the group consisting of alumina, silica, (non zeolite) silica-alumina, naturally occurring clays, TiO 2 , ZrO 2 , and SnO 2 .
  • the nitrogen oxides are reduced with the reducing agent at a temperature of at least 100° C. In another embodiment, the nitrogen oxides are reduced with the reducing agent at a temperature from about 150° C. to 750° C.
  • the latter embodiment is particularly useful for treating exhaust gases from heavy and light duty diesel engines, particularly engines comprising exhaust systems comprising (optionally catalysed) diesel particulate filters which are regenerated actively, e.g. by injecting hydrocarbon into the exhaust system upstream of the filter, wherein the zeolite catalyst for use in the present invention is located downstream of the filter.
  • the temperature range is from 175 to 550° C. In another embodiment, the temperature range is from 175 to 400° C.
  • the nitrogen oxides reduction is carried out in the presence of oxygen. In an alternative embodiment, the nitrogen oxides reduction is carried out in the absence of oxygen.
  • Zeolites for use in the present application include natural and synthetic zeolites, preferably synthetic zeolites because the zeolites can have a more uniform: silica-to-alumina ratio (SAR), crystallite size, crystallite morphology, and the absence of impurities (e.g. alkaline earth metals).
  • SAR silica-to-alumina ratio
  • crystallite size crystallite size
  • crystallite morphology crystallite morphology
  • impurities e.g. alkaline earth metals
  • the source of nitrogenous reductant can be ammonia per se, hydrazine or any suitable ammonia precursor, such as urea ((NH 2 ) 2 CO), ammonium carbonate, ammonium carbamate, ammonium hydrogen carbonate or ammonium formate.
  • urea (NH 2 ) 2 CO)
  • ammonium carbonate ammonium carbamate
  • ammonium hydrogen carbonate or ammonium formate.
  • the method can be performed on a gas derived from a combustion process, such as from an internal combustion engine (whether mobile or stationary), a gas turbine and coal or oil fired power plants.
  • a gas derived from a combustion process such as from an internal combustion engine (whether mobile or stationary), a gas turbine and coal or oil fired power plants.
  • the method may also be used to treat gas from industrial processes such as refining, from refinery heaters and boilers, furnaces, the chemical processing industry, coke ovens, municipal waste plants and incinerators, coffee roasting plants etc.
  • the method is used for treating exhaust gas from a vehicular lean burn internal combustion engine, such as a diesel engine, a lean-burn gasoline engine or an engine powered by liquid petroleum gas or natural gas.
  • a vehicular lean burn internal combustion engine such as a diesel engine, a lean-burn gasoline engine or an engine powered by liquid petroleum gas or natural gas.
  • the invention provides an exhaust system for a vehicular lean burn internal combustion engine, which system comprising a conduit for carrying a flowing exhaust gas, a source of nitrogenous reductant, a zeolite catalyst containing at least one transition metal disposed in a flow path of the exhaust gas and means for metering nitrogenous reductant into a flowing exhaust gas upstream of the zeolite catalyst, wherein the zeolite catalyst is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.
  • the small pore transition metal-containing zeolites for use in the exhaust system aspect of the present invention include any for use in the method according to the invention as described hereinabove.
  • the zeolite catalyst is coated on a flow-through monolith substrate (i.e. a honeycomb monolithic catalyst support structure with many small, parallel channels running axially through the entire part) or filter monolith substrate such as a wall-flow filter etc., as described hereinabove.
  • a flow-through monolith substrate i.e. a honeycomb monolithic catalyst support structure with many small, parallel channels running axially through the entire part
  • filter monolith substrate such as a wall-flow filter etc., as described hereinabove.
  • the zeolite catalyst is formed into an extruded-type catalyst.
  • the system can include means, when in use, for controlling the metering means so that nitrogenous reductant is metered into the flowing exhaust gas only when it is determined that the zeolite catalyst is capable of catalysing NO x reduction at or above a desired efficiency, such as at above 100° C., above 150° C. or above 175° C.
  • the determination by the control means can be assisted by one or more suitable sensor inputs indicative of a condition of the engine selected from the group consisting of: exhaust gas temperature, catalyst bed temperature, accelerator position, mass flow of exhaust gas in the system, manifold vacuum, ignition timing, engine speed, lambda value of the exhaust gas, the quantity of fuel injected in the engine, the position of the exhaust gas recirculation (EGR) valve and thereby the amount of EGR and boost pressure.
  • suitable sensor inputs indicative of a condition of the engine selected from the group consisting of: exhaust gas temperature, catalyst bed temperature, accelerator position, mass flow of exhaust gas in the system, manifold vacuum, ignition timing, engine speed, lambda value of the exhaust gas, the quantity of fuel injected in the engine, the position of the exhaust gas recirculation (EGR) valve and thereby the amount of EGR and boost pressure.
  • metering is controlled in response to the quantity of nitrogen oxides in the exhaust gas determined either directly (using a suitable NO x sensor) or indirectly, such as using pre-correlated look-up tables or maps—stored in the control means—correlating any one or more of the abovementioned inputs indicative of a condition of the engine with predicted NO x content of the exhaust gas.
  • the control means can comprise a pre-programmed processor such as an electronic control unit (ECU).
  • ECU electronice control unit
  • the metering of the nitrogenous reductant can be arranged such that 60% to 200% of theoretical ammonia is present in exhaust gas entering the SCR catalyst calculated at 1:1 NH 3 /NO and 4:3 NH 3 /NO 2 .
  • an oxidation catalyst for oxidising nitrogen monoxide in the exhaust gas to nitrogen dioxide can be located upstream of a point of metering the nitrogenous reductant into the exhaust gas.
  • the oxidation catalyst is adapted to yield a gas stream entering the SCR zeolite catalyst having a ratio of NO to NO 2 of from about 4:1 to about 1:3 by volume, e.g. at an exhaust gas temperature at oxidation catalyst inlet of 250° C. to 450° C.
  • the oxidation catalyst can include at least one platinum group metal (or some combination of these), such as platinum, palladium, or rhodium, coated on a flow-through monolith substrate.
  • the at least one platinum group metal is platinum, palladium or a combination of both platinum and palladium.
  • the platinum group metal can be supported on a high surface area washcoat component such as alumina, a zeolite such as an aluminosilicate zeolite, silica, non-zeolite silica alumina, ceria, zirconia, titania or a mixed or composite oxide containing both ceria and zirconia.
  • a suitable filter substrate is located between the oxidation catalyst and the zeolite catalyst.
  • Filter substrates can be selected from any of those mentioned above, e.g. wall flow filters.
  • the filter is catalysed, e.g. with an oxidation catalyst of the kind discussed above, preferably the point of metering nitrogenous reductant is located between the filter and the zeolite catalyst.
  • the means for metering nitrogenous reductant can be located between the oxidation catalyst and the filter. It will be appreciated that this arrangement is disclosed in WO 99/39809.
  • the zeolite catalyst for use in the present invention is coated on a filter located downstream of the oxidation catalyst.
  • the filter includes the zeolite catalyst for use in the present invention
  • the point of metering the nitrogenous reductant is preferably located between the oxidation catalyst and the filter.
  • control means meters nitrogenous reductant into the flowing exhaust gas, only when the exhaust gas temperature is at least 100° C., for example only when the exhaust gas temperature is from 150° C. to 750° C.
  • a vehicular lean-burn engine comprising an exhaust system according to the present invention.
  • the vehicular lean burn internal combustion engine can be a diesel engine, a lean-burn gasoline engine or an engine powered by liquid petroleum gas or natural gas.
  • FIG. 1 is a graph showing NO x conversion (at a gas hourly space velocity of 30,000 hr ⁇ 1 ) comparing transition metal-containing aluminosilicate catalysts with a transition metal-containing aluminophosphate/small pore zeolite catalyst after relatively moderate lean hydrothermal ageing performed on a laboratory reactor;
  • FIG. 2 is a graph showing N 2 O formation in the test shown in FIG. 1 ;
  • FIG. 3 is a graph showing NO x conversion (at a gas hourly space velocity of 100,000 hr ⁇ 1 ) comparing Cu/Beta zeolite and Cu/SAPO-34 catalysts with a transition metal-containing aluminophosphate/small pore zeolite catalyst after relatively moderate lean hydrothermal ageing performed on a laboratory reactor;
  • FIG. 4 is a graph showing NO x conversion (at a gas hourly space velocity of 30,000 hr ⁇ 1 ) comparing transition metal-containing aluminosilicate catalysts with a transition metal-containing aluminophosphate/small pore zeolite catalyst after relatively severe lean hydrothermal ageing performed on a laboratory reactor;
  • FIG. 5 is a graph showing NO conversion for fresh Cu/Zeolite catalysts
  • FIG. 6 is a graph showing NO conversion for aged Cu/Zeolite catalysts
  • FIG. 7 is a graph showing N 2 O formation for fresh Cu/Zeolite catalysts of FIG. 5 ;
  • FIG. 8 is a graph showing N 2 O formation for aged Cu/Zeolite catalysts of FIG. 6 ;
  • FIG. 9 is a graph showing the effect of adding HC species to Cu/zeolite catalysts during NH 3 SCR at 300° C.
  • FIG. 10 is a graph showing hydrocarbon breakthrough following addition of hydrocarbon species to Cu/zeolite catalysts during NH 3 SCR at 300° C.;
  • FIG. 11 is a graph showing the adsorption profiles of n-octane at 150° C. flowing through the Cu zeolite catalysts;
  • FIG. 12 is a graph of the temperature programmed desorption (TPD) of HC species to Cu/zeolite catalysts after HC adsorption at 150° C.;
  • FIG. 13 is a graph similar to FIG. 6 comparing NO x conversion activity for aged Cu/Sigma-1, Cu-SAPO-34, Cu/SSZ-13 and Cu/Beta;
  • FIG. 14 is a graph similar to FIG. 8 comparing N 2 O formation for the aged Cu/zeolite catalysts of FIG. 13 ;
  • FIG. 15 is a graph similar to FIG. 13 comparing NO x conversion activity for aged Cu/ZSM-34, Cu/SAPO-34, Cu/SSZ-13 and Cu/Beta catalysts;
  • FIG. 16 is a graph comparing the NO x conversion activity of fresh and aged Cu-SAPO-34 and Cu/SSZ-13 catalysts
  • FIG. 17 is a graph comparing the NO x conversion activity of fresh samples of Cu/SAPO-34 with a Cu/naturally occurring chabazite type material
  • FIG. 18 is a bar chart comparing the NO x conversion activity of fresh Cu/SAPO-34 with that of two fresh Cu/naturally occurring chabazite type materials at two temperature data points;
  • FIG. 19 is a bar chart comparing the NO conversion activity of aged Cu/Beta, Cu/SAPO-34, Fe/SAPO-34 and Fe/SSZ-13 catalysts at two temperature data points;
  • FIG. 20 is a bar chart comparing the hydrocarbon inhibition effect of introducing n-octane into a feed gas for fresh Fe/Beta and Fe/SSZ-13 catalysts;
  • FIG. 21 is a graph showing hydrocarbon breakthrough following the introduction of n-octane in the experiment of FIG. 20 ;
  • FIG. 22 is a bar chart comparing the effect on NO x conversion activity for a fresh Fe/SSZ-13 catalyst of using 100% NO as a component of the feed gas with using 1:1 NO:NO 2 ;
  • FIG. 23 is a schematic diagram of an embodiment of an exhaust system according to the present invention.
  • FIG. 23 is a schematic diagram of an embodiment of an exhaust system according to the present invention, wherein diesel engine 12 comprises an exhaust system 10 according to the present invention comprising an exhaust line 14 for conveying an exhaust gas from the engine to atmosphere via tailpipe 15 .
  • an exhaust line 14 for conveying an exhaust gas from the engine to atmosphere via tailpipe 15 .
  • a platinum or platinum/palladium NO oxidation catalyst 16 coated on a ceramic flow-through substrate monolith.
  • a ceramic wall-flow filter 18 Located downstream of oxidation catalyst 16 in the exhaust system is .
  • An iron/small pore zeolite SCR catalyst 20 also coated on a ceramic flow-through substrate monolith is disposed downstream of the wall-flow filter 18 .
  • An NH 3 oxidation clean-up or slip catalyst 21 is coated on a downstream end of the SCR catalyst monolith substrate.
  • the NH 3 slip catalyst can be coated on a separate substrate located downstream of the SCR catalyst.
  • Means (injector 22 ) is provided for introducing nitrogenous reductant fluid (urea 26 ) from reservoir 24 into exhaust gas carried in the exhaust line 14 .
  • Injector 22 is controlled using valve 28 , which valve is in turn controlled by electronic control unit 30 (valve control represented by dotted line).
  • Electronic control unit 30 receives closed loop feedback control input from a NO x sensor 32 located downstream of the SCR catalyst:
  • the oxidation catalyst 16 passively oxidises NO to NO 2 , particulate matter is trapped on filter 18 and is combusted in NO 2 .
  • NO x emitted from the filter is reduced on the SCR catalyst 20 in the presence of ammonia derived from urea injected via injector 22 . It is also understood that mixtures of NO and NO 2 in the total NO x content of the exhaust gas entering the SCR catalyst (about 1:1) are desirable for NO x reduction on a SCR catalyst as they are more readily reduced to N 2 .
  • the NH 3 slip catalyst 21 oxidises NH 3 that would otherwise be exhausted to atmosphere. A similar arrangement is described in WO 99/39809.
  • Beta zeolite, SAPO-34 or SSZ-13 was NH 4 + ion exchanged in a solution of NH 4 NO 3 , then filtered. The resulting material was added to an aqueous solution of Fe(NO 3 ) 3 with stirring. The slurry was filtered, then washed and dried. The procedure can be repeated to achieve a desired metal loading. The final product was calcined.
  • SAPO-34, SSZ-13, Sigma-1, ZSM-34, Nu-3, ZSM-5 and Beta zeolites were NH 4 + ion exchanged in a solution of NH 4 NO 3 , then filtered. The resulting materials were added to an aqueous solution of Cu(NO 3 ) 2 with stirring. The slurry was filtered, then washed and dried. The procedure can be repeated to achieve a desired metal loading. The final product was calcined.
  • the catalysts obtained by means of Examples 1 and 2 were lean hydrothermally aged at 750° C. for 24 hours in 4.5% H 2 O/air mixture.
  • the catalysts obtained by means of Examples 1 and 2 were severely lean hydrothermally aged at 900° C. for 1 hour in 4.5% H 2 O/air mixture.
  • the catalysts obtained by means of Examples 1 and 2 were severely lean hydrothermally aged at 900° C. for a period of 3 hours in 4.5% H 2 O/air mixture.
  • FIG. 1 compares the NQ reduction efficiencies of a Cu/SAPO-34 catalyst against a series of aluminosilicate zeolite supported transition metal catalysts (Cu/ZSM-5, Cu/Beta and Fe/Beta) after a mild aging. The result clearly demonstrates that Cu/SAPO-34 has improved low temperature activity for SCR of NO x with NH 3 .
  • FIG. 2 compares the N 2 O formation over the catalysts. It is clear that the Cu/SAPO-34 catalyst produced lower levels of N 2 O compared to the other two Cu-containing catalysts.
  • the Fe-containing catalyst also exhibits low N 2 O formation, but as shown in FIG. 1 , the Fe catalyst is less active at lower temperatures.
  • FIG. 3 compares the NO x reduction efficiencies of a Cu/SAPO-34 catalyst against a Cu/Beta catalyst tested at a higher gas hourly space velocity.
  • the Cu/SAPO-34 catalyst is significantly more active than the Cu-Beta catalyst at low reaction temperatures.
  • FIG. 4 shows the NO x reduction efficiencies of a Cu/SAPO-34 catalyst and a series of aluminosilicate zeolite supported transition metal catalysts (Cu/ZSM-5, Cu/Beta, and Fe/Beta) after severe lean hydrothermal aging.
  • Cu/SAPO-34 catalyst has superior hydrothermal stability.
  • N 2 O formation measured for the fresh and aged catalysts is shown in FIGS. 7 and 8 , respectively.
  • FIG. 9 compares the effect of HC on Cu/zeolite catalysts where SAPO-34 and Nu-3 are used as examples of small pore zeolite materials.
  • ZSM-5 and Beta zeolite are used as examples of a medium and large pore zeolite, respectively.
  • Samples were exposed to different HC species (propene, n-octane and toluene) during NH 3 SCR reaction at 300° C.
  • FIG. 10 shows the corresponding HC breakthrough following HC addition.
  • FIG. 11 shows the adsorption profiles of n-octane at 150° C. flowing through different Cu/zeolite catalysts. HC breakthrough is observed almost immediately with Cu supported on the small pore zeolites SAPO-34 and Nu-3, whereas significant HC uptake is observed with Cu on Beta zeolite and ZSM-5.
  • FIG. 12 shows the subsequent HC desorption profile as a function of increasing temperature and confirms that large amounts of HC are stored when Cu is supported on the larger pore zeolites, whereas very little HC is stored when small pore zeolites are employed.
  • Cu/SSZ-13, Cu/SAPO-34, Cu/Sigma-1 and Cu/Beta prepared according to Example 2 were aged in the manner described in Example 4 and tested according to Example 6.
  • the results are shown in FIG. 13 , from which it can be seen that the NO x conversion activity of each of the severely lean hydrothermally aged Cu/SSZ-13, Cu/SAPO-34 and Cu/Sigma-1 samples is significantly better than that of the corresponding large-pore zeolite, Cu/Beta.
  • FIG. 14 it can be seen that Cu/Beta generates significantly more N 2 O than the Cu/small-pore zeolite catalysts.
  • Cu/ZSM-34, Cu/SAPO-34, Cu/SSZ-13 and Cu/Beta prepared according to Example 2 were aged in the manner described in Example 3 and tested according to Example 6. The results are shown in FIG. 15 , from which it can be seen that the NO x conversion activity of each of the lean hydrothermally aged Cu/SSZ-13, Cu/SAPO-34 and Cu/ZSM-34 samples is significantly better than that of the corresponding large-pore zeolite, Cu/Beta.
  • FIG. 17 is a bar chart comparing the NO x conversion activity of two fresh Cu/naturally occurring chabazite type materials prepared according to Example 2 at two temperature data points (200° C. and 300° C.), a first chabazite material having a SAR of about 4 and a second chabazite material of SAR about 7.
  • Cu/SAPO-34 and Cu/Beta were prepared according to Example 2.
  • Fe/SAPO-34 and Fe/SSZ-13 were prepared according to Example 1. The samples were aged according to Example 4 and the aged samples were tested according to Example 6. The NO x activity at the 350° C. and 450° C. data points is shown in FIG. 19 , from which it can be seen that the Cu/SAPO-34, Fe/SAPO-34 and Fe/SSZ-13 samples exhibit comparable or better performance than the Cu/Beta reference.
  • Fe/SSZ-13 and Fe/Beta prepared according to Example 1 were tested fresh as described in Example 7, wherein n-octane (to replicate the effects of unburned diesel fuel in a exhaust gas) was introduced at 8 minutes into the test.
  • the results shown in FIG. 20 compare the NOx conversion activity at 8 minutes into the test, but before n-octane was introduced into the feed gas (HC ⁇ ) and 8 minutes after n-octane was introduced into the feed gas (HC+). It can be seen that the Fe/Beta activity dramatically reduces following n-octane introduction compared with Fe/SSZ-13. We believe that this effect results from coking of the catalyst.
  • Fe/SSZ-13 prepared according to Example 1 was tested fresh, i.e. without ageing, in the manner described in Example 6. The test was then repeated using identical conditions, except in that the 350 ppm NO was replaced with a mixture of 175 ppm NO and 175 ppm NO 2 , i.e. 350 ppm total NO x . The results from both tests are shown in FIG. 22 , from which the significant improvement obtainable from increasing the NO 2 content of NO x in the feed gas to 1:1 can be seen.
  • the NO:NO 2 ratio can be adjusted by oxidising NO in an exhaust gas, e.g. of a diesel engine, using a suitable oxidation catalyst located upstream of the NH 3 —SCR catalyst.

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US13/164,150 US8603432B2 (en) 2007-04-26 2011-06-20 Transition metal/zeolite SCR catalysts
US13/567,703 US20120301380A1 (en) 2007-04-26 2012-08-06 Transition metal/zeolite scr catalysts
US13/567,698 US20120301379A1 (en) 2007-04-26 2012-08-06 Transition metal/zeolite scr catalysts
US13/567,705 US8906820B2 (en) 2007-04-26 2012-08-06 Transition metal/zeolite SCR catalysts
US13/567,692 US20120301378A1 (en) 2007-04-26 2012-08-06 Transition metal/zeolite scr catalysts
US14/552,161 US20150078968A1 (en) 2007-04-26 2014-11-24 Transition metal/zeolite scr catalysts
US14/587,709 US20150118115A1 (en) 2007-04-26 2014-12-31 Transition metal/zeolite scr catalysts
US14/587,653 US20150118121A1 (en) 2007-04-26 2014-12-31 Transition metal/zeolite scr catalysts
US14/587,793 US20150110682A1 (en) 2007-04-26 2014-12-31 Transition metal/zeolite scr catalysts
US14/587,613 US20150118114A1 (en) 2007-04-26 2014-12-31 Transition metal/zeolite scr catalysts
US15/252,376 US20160367939A1 (en) 2007-04-26 2016-08-31 Transition metal/zeolite scr catalysts
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