UA60290C2 - Твердий компонент каталізатора, каталізатор (варіанти) та спосіб полімеризації олефінів - Google Patents
Твердий компонент каталізатора, каталізатор (варіанти) та спосіб полімеризації олефінів Download PDFInfo
- Publication number
- UA60290C2 UA60290C2 UA96020629A UA96020629A UA60290C2 UA 60290 C2 UA60290 C2 UA 60290C2 UA 96020629 A UA96020629 A UA 96020629A UA 96020629 A UA96020629 A UA 96020629A UA 60290 C2 UA60290 C2 UA 60290C2
- Authority
- UA
- Ukraine
- Prior art keywords
- bis
- methoxymethyl
- catalyst
- fact
- catalyst according
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 124
- 238000006116 polymerization reaction Methods 0.000 title claims description 26
- 150000001336 alkenes Chemical class 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 19
- 239000011949 solid catalyst Substances 0.000 title abstract description 6
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 14
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 4
- -1 magnesium halide Chemical class 0.000 claims description 113
- 239000007787 solid Substances 0.000 claims description 65
- 150000001875 compounds Chemical class 0.000 claims description 55
- 150000003254 radicals Chemical class 0.000 claims description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 239000011777 magnesium Substances 0.000 claims description 18
- 229910052749 magnesium Inorganic materials 0.000 claims description 18
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 15
- 229910008484 TiSi Inorganic materials 0.000 claims description 14
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 claims description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 11
- 150000003609 titanium compounds Chemical class 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 125000005842 heteroatom Chemical group 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 150000004820 halides Chemical class 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000012071 phase Substances 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- OTIJMHPVYPMCPU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2,3-dimethylindene Chemical compound C1=CC=C2C(COC)(COC)C(C)=C(C)C2=C1 OTIJMHPVYPMCPU-UHFFFAOYSA-N 0.000 claims description 3
- HHGPZISECHQRLO-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-methyl-4-phenylindene Chemical compound COCC1(COC)C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 HHGPZISECHQRLO-UHFFFAOYSA-N 0.000 claims description 3
- FXWFWIIEIAUQHQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-phenylindene Chemical compound C=1C2=CC=CC=C2C(COC)(COC)C=1C1=CC=CC=C1 FXWFWIIEIAUQHQ-UHFFFAOYSA-N 0.000 claims description 3
- ZZPVNMUQOQQUHU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,7-dimethylindene Chemical compound CC1=CC=C(C)C2=C1C(COC)(COC)C=C2 ZZPVNMUQOQQUHU-UHFFFAOYSA-N 0.000 claims description 3
- JEENAIJBWUBGSW-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(3,3,3-trifluoropropyl)indene Chemical compound C1=CC(CCC(F)(F)F)=C2C(COC)(COC)C=CC2=C1 JEENAIJBWUBGSW-UHFFFAOYSA-N 0.000 claims description 3
- RMXREGKBZYAVSC-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(trifluoromethyl)indene Chemical compound C1=CC(C(F)(F)F)=C2C(COC)(COC)C=CC2=C1 RMXREGKBZYAVSC-UHFFFAOYSA-N 0.000 claims description 3
- ZOIKOBDBSUJRNE-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-methylindene Chemical compound C1=CC(C)=C2C(COC)(COC)C=CC2=C1 ZOIKOBDBSUJRNE-UHFFFAOYSA-N 0.000 claims description 3
- UQGOQZUZKNXSTQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-phenylindene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1=CC=CC=C1 UQGOQZUZKNXSTQ-UHFFFAOYSA-N 0.000 claims description 3
- VJTYHGPEEHLNGJ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-propan-2-ylindene Chemical compound C1=CC(C(C)C)=C2C(COC)(COC)C=CC2=C1 VJTYHGPEEHLNGJ-UHFFFAOYSA-N 0.000 claims description 3
- ILXXAZBXJLMEQM-UHFFFAOYSA-N 1,1-bis(methoxymethyl)indene Chemical compound C1=CC=C2C(COC)(COC)C=CC2=C1 ILXXAZBXJLMEQM-UHFFFAOYSA-N 0.000 claims description 3
- SCTKUNIIBPPKNV-UHFFFAOYSA-N 1,8-dichloro-9,9-bis(methoxymethyl)fluorene Chemical compound C12=CC=CC(Cl)=C2C(COC)(COC)C2=C1C=CC=C2Cl SCTKUNIIBPPKNV-UHFFFAOYSA-N 0.000 claims description 3
- PEKQXDFNLCXEIG-UHFFFAOYSA-N 1,8-difluoro-9,9-bis(methoxymethyl)fluorene Chemical compound C12=CC=CC(F)=C2C(COC)(COC)C2=C1C=CC=C2F PEKQXDFNLCXEIG-UHFFFAOYSA-N 0.000 claims description 3
- ZFAIPBMPKVESPU-UHFFFAOYSA-N 2,3,4,5,6,7-hexafluoro-9,9-bis(methoxymethyl)fluorene Chemical compound C1=C(F)C(F)=C(F)C2=C1C(COC)(COC)C1=CC(F)=C(F)C(F)=C12 ZFAIPBMPKVESPU-UHFFFAOYSA-N 0.000 claims description 3
- LDAYPNRUDRHPCA-UHFFFAOYSA-N 2,7-dicyclopentyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=C2C(COC)(COC)C3=CC(C4CCCC4)=CC=C3C2=CC=C1C1CCCC1 LDAYPNRUDRHPCA-UHFFFAOYSA-N 0.000 claims description 3
- UURZCHPNAPLYER-UHFFFAOYSA-N 4-tert-butyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C(C(C)(C)C)C2=C1C(COC)(COC)C1=CC=CC=C12 UURZCHPNAPLYER-UHFFFAOYSA-N 0.000 claims description 3
- DNQBFNSYXQGWEA-UHFFFAOYSA-N 5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C=CC=C1 DNQBFNSYXQGWEA-UHFFFAOYSA-N 0.000 claims description 3
- TYYSEGNSDSKJDW-UHFFFAOYSA-N 7-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCCC1 TYYSEGNSDSKJDW-UHFFFAOYSA-N 0.000 claims description 3
- OEGBIJMAWUHNFV-UHFFFAOYSA-N 7-cyclopentyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCC1 OEGBIJMAWUHNFV-UHFFFAOYSA-N 0.000 claims description 3
- OQYGKBOREGNKLC-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)-2-methylindene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C(C)=CC2=C1 OQYGKBOREGNKLC-UHFFFAOYSA-N 0.000 claims description 3
- XBHBMIOEDQWGPY-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)indene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C=CC2=C1 XBHBMIOEDQWGPY-UHFFFAOYSA-N 0.000 claims description 3
- UMMOCVFWWKDPNL-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4,5,6,7,8-octahydrofluorene Chemical compound C1CCCC2=C1C(COC)(COC)C1=C2CCCC1 UMMOCVFWWKDPNL-UHFFFAOYSA-N 0.000 claims description 3
- MGQOPBZMDMTUQK-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4-tetrahydrofluorene Chemical compound C12=CC=CC=C2C(COC)(COC)C2=C1CCCC2 MGQOPBZMDMTUQK-UHFFFAOYSA-N 0.000 claims description 3
- BJBJQWLYAGUTIO-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,3,6,7-tetramethylfluorene Chemical compound CC1=C(C)C=C2C(COC)(COC)C3=CC(C)=C(C)C=C3C2=C1 BJBJQWLYAGUTIO-UHFFFAOYSA-N 0.000 claims description 3
- PQRUIZPAUUOIPY-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,7-di(propan-2-yl)fluorene Chemical compound C1=C(C(C)C)C=C2C(COC)(COC)C3=CC(C(C)C)=CC=C3C2=C1 PQRUIZPAUUOIPY-UHFFFAOYSA-N 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 150000005840 aryl radicals Chemical class 0.000 claims description 3
- 150000003944 halohydrins Chemical class 0.000 claims description 3
- 150000003377 silicon compounds Chemical class 0.000 claims description 3
- MHOBTJZEFPKMLE-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,3,6,7-tetramethylxanthene Chemical compound CC1=C(C)C=C2C(COC)(COC)C3=CC(C)=C(C)C=C3OC2=C1 MHOBTJZEFPKMLE-UHFFFAOYSA-N 0.000 claims description 2
- UVZNCPVTOYWJAQ-UHFFFAOYSA-N 9,9-bis(methoxymethyl)xanthene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3OC2=C1 UVZNCPVTOYWJAQ-UHFFFAOYSA-N 0.000 claims description 2
- ANGMMFRGIJDWPU-UHFFFAOYSA-N 9-(1-methoxyethyl)-9-(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(C(C)OC)C3=CC=CC=C3C2=C1 ANGMMFRGIJDWPU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002879 Lewis base Substances 0.000 claims description 2
- JSDWVMORIKLNNU-UHFFFAOYSA-N [3,3-bis(methoxymethyl)-2,4,5-triphenylcyclopenta-1,4-dien-1-yl]benzene Chemical compound COCC1(COC)C(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 JSDWVMORIKLNNU-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 150000007527 lewis bases Chemical group 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004354 sulfur functional group Chemical group 0.000 claims description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
- NUPABKVXQKZAHY-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-1,2,3,4-tetramethylcyclopenta-1,3-diene Chemical compound COCC1(COC)C(C)=C(C)C(C)=C1C NUPABKVXQKZAHY-UHFFFAOYSA-N 0.000 claims 2
- DFBNDURJLQVNJX-UHFFFAOYSA-N [3,3-bis(methoxymethyl)inden-4-yl]-trimethylsilane Chemical compound C1=CC([Si](C)(C)C)=C2C(COC)(COC)C=CC2=C1 DFBNDURJLQVNJX-UHFFFAOYSA-N 0.000 claims 2
- CQNWWQKMMODDOL-UHFFFAOYSA-N 2,3,6,7-tetrafluoro-9-(1-methoxyethyl)-9-(methoxymethyl)fluorene Chemical compound FC1=C(F)C=C2C(COC)(C(C)OC)C3=CC(F)=C(F)C=C3C2=C1 CQNWWQKMMODDOL-UHFFFAOYSA-N 0.000 claims 1
- WFLVIOIMYKVGLP-UHFFFAOYSA-N 9-(methoxymethyl)-9-(pentoxymethyl)fluorene Chemical compound C1=CC=C2C(COCCCCC)(COC)C3=CC=CC=C3C2=C1 WFLVIOIMYKVGLP-UHFFFAOYSA-N 0.000 claims 1
- 125000003262 carboxylic acid ester group Chemical class [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims 1
- FSDZFXDDKLLPRB-UHFFFAOYSA-N phthalic acid;sulfuric acid Chemical group OS(O)(=O)=O.OC(=O)C1=CC=CC=C1C(O)=O FSDZFXDDKLLPRB-UHFFFAOYSA-N 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 238000012876 topography Methods 0.000 claims 1
- 125000003367 polycyclic group Chemical group 0.000 abstract description 2
- 239000004743 Polypropylene Substances 0.000 description 40
- 229920001155 polypropylene Polymers 0.000 description 40
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 22
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 17
- 230000003993 interaction Effects 0.000 description 15
- 239000000155 melt Substances 0.000 description 15
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 6
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 5
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 description 5
- 239000012265 solid product Substances 0.000 description 5
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- HBMODDNTUPGVFW-UHFFFAOYSA-N (1,3-dimethoxy-2-phenylpropan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(COC)(COC)C1=CC=CC=C1 HBMODDNTUPGVFW-UHFFFAOYSA-N 0.000 description 3
- 125000006651 (C3-C20) cycloalkyl group Chemical group 0.000 description 3
- SBWACGDKPKXCRS-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,2,4,4-tetramethylpentane Chemical compound COCC(C(C)(C)C)(C(C)(C)C)COC SBWACGDKPKXCRS-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910016006 MoSi Inorganic materials 0.000 description 3
- RHBLISBUFROBBC-UHFFFAOYSA-N [9-(hydroxymethyl)fluoren-9-yl]methanol Chemical compound C1=CC=C2C(CO)(CO)C3=CC=CC=C3C2=C1 RHBLISBUFROBBC-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 125000004135 2-norbornyl group Chemical group [H]C1([H])C([H])([H])C2([H])C([H])([H])C1([H])C([H])([H])C2([H])* 0.000 description 2
- RGHIYOCUMCUWAQ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,5-dimethylhexane Chemical compound COCC(COC)(CC(C)C)C(C)C RGHIYOCUMCUWAQ-UHFFFAOYSA-N 0.000 description 2
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- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000005817 fluorobutyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950317 IT1274251B (it) | 1995-02-21 | 1995-02-21 | Componenti e catalizzatori per la polimerizzazione delle olefine |
| IT95MI000318 IT1274252B (it) | 1995-02-21 | 1995-02-21 | Catalizzatori per la polimerizzazione delle olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA60290C2 true UA60290C2 (uk) | 2003-10-15 |
Family
ID=26331244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA96020629A UA60290C2 (uk) | 1995-02-21 | 1996-02-20 | Твердий компонент каталізатора, каталізатор (варіанти) та спосіб полімеризації олефінів |
Country Status (19)
Families Citing this family (347)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1003016C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Gesubstitueerde pentadieenverbinding. |
| NL1003018C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde indeen. |
| NL1003004C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding. |
| US6117811A (en) * | 1996-05-03 | 2000-09-12 | Dsm N.V. | Cyclopentadiene compound substituted with linear groups |
| NL1003008C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
| NL1003013C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met cyclische groepen gesubstitueerde cyclopentadieenverbinding. |
| US6124488A (en) * | 1996-05-03 | 2000-09-26 | Dsm N.V. | Cyclopentadiene compound substituted with branched alkyl groups |
| NL1003017C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerd fluoreen. |
| NL1003007C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding. |
| NL1003011C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
| MY125673A (en) * | 1996-06-10 | 2006-08-30 | Mitsui Chemicals Inc | Solid titanium catalyst component for olefin polymerization,process for preparing the same, olefin plymerization catalyst containing the catalyst component and olefin polymerization process using thecatalyst |
| FI963707A0 (fi) | 1996-09-19 | 1996-09-19 | Borealis Polymers Oy | Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma |
| WO1999057160A1 (en) * | 1998-05-06 | 1999-11-11 | Montell Technology Company B.V. | Catalyst components for the polymerization of olefins |
| TR200000617T1 (tr) | 1998-07-08 | 2000-10-23 | Montell Tecnology Company Bv | Gazı-fazı polimerizasyonu için işlem ve aygıt. |
| US6395831B1 (en) | 1998-08-20 | 2002-05-28 | Baselltech Usa Inc. | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility |
| WO2000039238A1 (en) | 1998-12-24 | 2000-07-06 | Montell Technology Company B.V. | Bottle closures made of polyolefins |
| ATE252605T1 (de) | 1999-03-09 | 2003-11-15 | Basell Polyolefine Gmbh | Mehrstufiges verfahren zur (co)polymersation von olefinen |
| EP1135440B1 (en) | 1999-09-14 | 2004-08-11 | Basell Poliolefine Italia S.P.A. | Impact-resitant polyolefin compositions |
| CN1137155C (zh) | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
| BR0009968A (pt) | 1999-12-16 | 2002-01-22 | Baselltech Usa Inc | Composições poliolefìnicas semicristalinas, processo para a sua preparação e artigos laminados obtidos a partir delas |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| US6723792B2 (en) | 2000-09-15 | 2004-04-20 | Basell Poliolefine Italia S.P.A. | Nonextruded dispersions and concentrates of additives on olefin polymers |
| US6586531B2 (en) | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
| JP2002173504A (ja) * | 2000-11-29 | 2002-06-21 | Basell Technology Co Bv | オレフィン重合用触媒およびオレフィン重合方法 |
| KR100845454B1 (ko) | 2000-12-15 | 2008-07-10 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 알파-올레핀의 중합을 위한 고체 촉매 성분의 연속적 제조방법 |
| US6800710B2 (en) | 2000-12-22 | 2004-10-05 | Basell Poliolefine Italia S.P.A. | Polyolefin sheets for thermoforming |
| TWI238169B (en) | 2000-12-22 | 2005-08-21 | Basell Technology Co Bv | Bioriented polypropylene films |
| CN100564400C (zh) * | 2001-05-29 | 2009-12-02 | 联合碳化化学及塑料技术有限责任公司 | 烯烃聚合催化剂组合物和制备方法 |
| EP1279699A1 (en) | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
| MY132768A (en) | 2001-10-09 | 2007-10-31 | Basell Poliolefine Italia Spa | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility. |
| US7595103B2 (en) | 2001-10-30 | 2009-09-29 | Basell Poliolefine Italia S.P.A. | Pipe systems of polypropylene compositions |
| PL368462A1 (en) | 2001-11-27 | 2005-03-21 | Basell Poliolefine Italia S.P.A. | Clear and flexible propylene polymer compositions |
| TWI268939B (en) | 2001-12-12 | 2006-12-21 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| DE60326212D1 (de) * | 2002-03-08 | 2009-04-02 | Basell Poliolefine Srl | Verfahren zur herstellung einer katalysatorkomponente basierend auf einem diether |
| US7098164B2 (en) | 2002-03-08 | 2006-08-29 | Basell Poliolefine Italia S.P.A. | Process for the polymerization of olefins |
| US6743864B2 (en) | 2002-03-12 | 2004-06-01 | Basell Poliolefine Italia S.P.A. | Polyolefin compositions having high tenacity |
| JP4170229B2 (ja) | 2002-03-12 | 2008-10-22 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 高流動性を有するポリオレフィン組成物 |
| BR0305248A (pt) | 2002-06-26 | 2004-09-21 | Basell Poliolefine Spa | Composições de poliolefinas resistentes ao impacto |
| MXPA04012699A (es) | 2002-06-26 | 2005-03-23 | Basell Poliolefine Spa | Composiciones de poliolefina resistentes a impactos. |
| CA2492939A1 (en) | 2002-08-01 | 2004-02-12 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| US7125924B2 (en) | 2002-09-17 | 2006-10-24 | Basell Poliolefine Italia S.P.A. | Highly filled soft polyolefin compositions |
| JP5069414B2 (ja) * | 2002-12-18 | 2012-11-07 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 二塩化マグネシウムベースの付加物およびそれから得られる触媒成分 |
| US7288598B2 (en) | 2003-03-06 | 2007-10-30 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch for preparing impact-resistant polyolefin articles |
| MY136027A (en) | 2003-04-02 | 2008-07-31 | Basell Poliolefine Spa | Polyolefin masterbatch and composition suitable for injection molding |
| TW200427763A (en) | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| RU2342411C2 (ru) | 2003-08-05 | 2008-12-27 | Базелль Полиолефин Италия С.Р.Л. | Полиолефиновые изделия |
| TW200505985A (en) | 2003-08-07 | 2005-02-16 | Basell Poliolefine Spa | Polyolefin composition having a high balance of stiffness and impact strength |
| AU2004287638A1 (en) * | 2003-11-06 | 2005-05-19 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| JP2007514874A (ja) | 2003-12-19 | 2007-06-07 | バセル ポリオレフィン イタリア エス．アール．エル． | プロピレンとヘキセン−１とのコポリマーからつくられる繊維 |
| ATE426621T1 (de) | 2004-03-03 | 2009-04-15 | Basell Poliolefine Srl | Verfahren zur steuerung des polymerflusses in einem polymerisationsprozess |
| JP2007530747A (ja) * | 2004-03-29 | 2007-11-01 | バセル ポリオレフィン イタリア エス．アール．エル． | 塩化マグネシウムに基づく付加物およびそれから得られる触媒成分 |
| JP2007538119A (ja) | 2004-05-21 | 2007-12-27 | バセル ポリオレフィン イタリア エス．アール．エル． | 耐衝撃性ポリオレフィン組成物 |
| CA2569656A1 (en) | 2004-06-08 | 2005-12-22 | Basell Poliolefine Italia S.R.L. | Polyolefin composition having a high balance of stiffness, impact strength and elongation at break and low thermal shrinkage |
| JP4885130B2 (ja) | 2004-06-18 | 2012-02-29 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用触媒成分の製造方法 |
| RU2377461C2 (ru) | 2004-06-25 | 2009-12-27 | Базелль Полиолефин Италия С.Р.Л. | Трубопроводные сети, изготовленные из статистических сополимеров пропилена и альфа-олефинов |
| US7772324B2 (en) | 2004-10-04 | 2010-08-10 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| US7652108B2 (en) | 2004-10-14 | 2010-01-26 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization olefins |
| CN100389112C (zh) * | 2004-12-16 | 2008-05-21 | 中国石油化工股份有限公司 | 一类环状缩醛和缩酮化合物及其应用 |
| JP2008524414A (ja) | 2004-12-21 | 2008-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシール可能なポリオレフィンフィルム |
| US7795352B2 (en) | 2004-12-23 | 2010-09-14 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions having good whitening resistance |
| ATE446987T1 (de) | 2005-02-03 | 2009-11-15 | Basell Poliolefine Srl | Propylen-polymer-zusammensetzung zum spritzgiessen |
| KR20080005988A (ko) | 2005-04-28 | 2008-01-15 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 강화 폴리프로필렌 파이프 |
| AU2006245784A1 (en) * | 2005-05-12 | 2006-11-16 | Basell Poliolefine Italia S.R.L. | Propylene-ethylene copolymers and process for their preparation |
| CN101175775B (zh) | 2005-05-13 | 2010-12-08 | 巴塞尔聚烯烃意大利有限责任公司 | 烯烃气相聚合方法 |
| ATE450573T1 (de) | 2005-05-27 | 2009-12-15 | Basell Poliolefine Srl | Polyolefinische zusammensetzungen mit hoher bleichungsresistenz |
| AU2006265203A1 (en) | 2005-07-01 | 2007-01-11 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
| KR100639696B1 (ko) * | 2005-07-01 | 2006-10-30 | 에스케이 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용아릴페녹시 촉매계 |
| EP1901922A1 (en) | 2005-07-11 | 2008-03-26 | Basell Poliolefine Italia S.r.l. | Metallized propylene polymer film with good barrier retention properties |
| BRPI0620531B1 (pt) | 2005-11-22 | 2018-01-30 | Basell Poliolefine Italia S.R.L. | Composições poliolefínicas resistentes a impacto |
| JP5300486B2 (ja) | 2005-11-22 | 2013-09-25 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 低い光沢を有するポリオレフィン組成物 |
| JP2009520093A (ja) | 2005-12-20 | 2009-05-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 延伸される物品用のポリプロピレン組成物 |
| US8343602B2 (en) | 2006-02-23 | 2013-01-01 | Basell Poliolefine Italia, s.r.l. | Propylene polymers for injection molding applications |
| EP1845112A1 (en) | 2006-04-12 | 2007-10-17 | Total Petrochemicals Research Feluy | Controlled distribution of active sites in Ziegler-Natta catalysts systems |
| KR20090034350A (ko) | 2006-06-23 | 2009-04-07 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 마그네슘 클로로알콜레이트계 촉매 전구체 |
| TWI496762B (zh) | 2006-07-24 | 2015-08-21 | 製備（１ｒ，２ｒ）-３-（３-二甲胺基-１-乙基-２-甲基-丙基）-酚之方法 | |
| EP2046845B1 (en) | 2006-07-28 | 2012-06-06 | Basell Poliolefine Italia S.r.l. | Propylene polymers |
| WO2008061843A1 (en) | 2006-11-23 | 2008-05-29 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions |
| EP2089470B1 (en) | 2006-12-07 | 2011-06-01 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions having low hardness and low gloss |
| JP5237960B2 (ja) | 2006-12-07 | 2013-07-17 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 低硬度及び低光沢性のポリオレフィン組成物 |
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| WO2008077770A1 (en) | 2006-12-22 | 2008-07-03 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| WO2008077773A1 (en) | 2006-12-22 | 2008-07-03 | Basell Poliolefine Italia S.R.L. | Polyolefin composition for pipe systems and sheets |
| EP2070956A1 (en) | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a bimodal polypropylene having low ash content |
| EP2147026B1 (en) | 2007-05-22 | 2010-10-20 | Basell Poliolefine Italia S.r.l. | Soft propylene polymer compositions |
| EP2158234B1 (en) | 2007-05-22 | 2011-09-21 | Basell Poliolefine Italia S.r.l. | Process for the preparation of soft propylene polymer compositions |
| CN101323650B (zh) | 2007-06-13 | 2010-11-03 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂及其制备方法和应用 |
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| US8324327B2 (en) | 2007-08-24 | 2012-12-04 | Dow Global Technologies Llc | Gas-phase polymerization process |
| US10322394B2 (en) | 2007-08-24 | 2019-06-18 | W. R. Grace & Co.-Conn. | Catalyst composition with mixed selectivity control agent and method |
| US8080616B2 (en) | 2007-10-17 | 2011-12-20 | Basell Poliolefine Italia S.R.L. | Heterophasic polyolefin compositions having improved tensile properties |
| JP5580743B2 (ja) | 2007-11-27 | 2014-08-27 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ビチューメンとポリマー組成物との混合物 |
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| JP2025521958A (ja) | 2022-08-03 | 2025-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシールフィルム用ポリプロピレン組成物 |
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| WO2024223264A1 (en) | 2023-04-26 | 2024-10-31 | Basell Poliolefine Italia S.R.L. | Propylene-based copolymer compositon |
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| WO2025162707A1 (en) | 2024-01-29 | 2025-08-07 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
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Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1227259B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Catalizzatori per la polimerizzazione di olefine. |
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1237812B (it) * | 1989-12-22 | 1993-06-17 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1241093B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| DE69127220T2 (de) * | 1990-04-13 | 1998-01-02 | Mitsui Petrochemical Ind | Festes Titan enthaltendes Katalysatorbestandteil und Katalysator für Olefinpolymerisation, vorpolymerisierte Olefinpolymerisationskatalysator und Verfahren für Olefinpolymerisation |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1996
- 1996-02-12 IL IL11711496A patent/IL117114A/xx not_active IP Right Cessation
- 1996-02-13 MY MYPI96000538A patent/MY115716A/en unknown
- 1996-02-13 CA CA002169401A patent/CA2169401C/en not_active Expired - Fee Related
- 1996-02-16 BR BR9600767A patent/BR9600767A/pt not_active IP Right Cessation
- 1996-02-16 AU AU45594/96A patent/AU699522B2/en not_active Ceased
- 1996-02-18 CN CN96107325A patent/CN1090194C/zh not_active Expired - Fee Related
- 1996-02-20 IN IN316CA1996 patent/IN186169B/en unknown
- 1996-02-20 NO NO960669A patent/NO309380B1/no not_active IP Right Cessation
- 1996-02-20 UA UA96020629A patent/UA60290C2/uk unknown
- 1996-02-20 RU RU96103154/04A patent/RU2156260C2/ru active
- 1996-02-20 HU HU9600390A patent/HU221228B1/hu not_active IP Right Cessation
- 1996-02-21 EP EP96102584A patent/EP0728769B1/en not_active Expired - Lifetime
- 1996-02-21 AT AT96102584T patent/ATE169937T1/de active
- 1996-02-21 KR KR1019960004091A patent/KR100424925B1/ko not_active Expired - Fee Related
- 1996-02-21 ES ES96102584T patent/ES2121446T3/es not_active Expired - Lifetime
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- 1996-02-21 DE DE69600532T patent/DE69600532T2/de not_active Expired - Lifetime
- 1996-02-21 JP JP03409196A patent/JP3904117B2/ja not_active Expired - Fee Related
- 1996-02-21 FI FI960786A patent/FI119643B/fi not_active IP Right Cessation
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