JP5695081B2 - 膜用ポリオレフィン組成物 - Google Patents
膜用ポリオレフィン組成物 Download PDFInfo
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- JP5695081B2 JP5695081B2 JP2012545246A JP2012545246A JP5695081B2 JP 5695081 B2 JP5695081 B2 JP 5695081B2 JP 2012545246 A JP2012545246 A JP 2012545246A JP 2012545246 A JP2012545246 A JP 2012545246A JP 5695081 B2 JP5695081 B2 JP 5695081B2
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- 150000003609 titanium compounds Chemical class 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(I)
a)10〜40重量%、好ましくは20〜40重量%、より好ましくは25〜38重量%のプロピレンホモポリマー、またはプロピレンとエチレンもしくはCH2=CHRα−オレフィン(式中、Rは、C2−C8アルキル基である。)とのコポリマー、またはプロピレンとエチレンおよび前記CH2=CHRα−オレフィンとのコポリマー(前記コポリマーは、85重量%超のプロピレンを含有し、80重量%超の室温キシレン中不溶性フラクションを有する。);ならびに
b)(b1)エチレンとプロピレンまたはCH2=CHRα−オレフィン(式中、Rは、C2−C8アルキル基である。)、および場合により少量のジエンとのコポリマー、ならびに(b2)エチレンとプロピレンおよび前記α−オレフィン、および場合により少量のジエンとのコポリマーから選択される、60〜90重量%、好ましくは60〜80重量%、より好ましくは62〜75重量%の1種以上のコポリマー(前記コポリマーは、40重量%未満、好ましくは20から38重量%の量のエチレンを含有し、70重量%超、好ましくは80重量%超の室温キシレン中溶解度を有する。)
を含む組成物;
((a)および(b)の量は、(a)および(b)の全重量に対するものである。);ならびに
(II)
(i)1種以上の有機ホスファイトおよび/またはホスホナイト;
(ii)ヒンダードフェノール化合物からなる1種以上のフェノール性酸化防止剤;
(iii)1種以上のHALS(ヒンダードアミン光安定剤);
ならびに場合により
(iv)1種以上のエポキシ化脂肪酸エステル
を含む添加剤パッケージ(安定化組成物)
(比(iii)/(ii)、すなわち、HALS(iii)の量とフェノール性酸化防止剤(ii)の量との比は、1以下であり;添加剤パッケージ(II)の重量は、該ポリオレフィン組成物の重量に対して0.5から2重量%である。)
を含む組成物を提供する。
(i)0.05から0.6重量%、好ましくは0.1から0.3重量%
(ii)0.50〜1重量%、好ましくは0.55〜1重量%
(iii)0.10から1重量%、好ましくは0.30から1重量%および存在する場合、
(iv)は、0.02〜0.6重量%、好ましくは0.05から0.5重量%、より好ましくは0.1から0.3重量%である。
(VI)Ciba Specialty Chemicalsにより以下の商標名Irganox 3114;Irganox 1330で販売されている1,3,5−トリメチル−2,4,6−トリス(3,5−ジ−ter−ブチル−4−ヒドロキシベンジル)ベンゼン、1,3,5−トリス(3,5−ジ−ter−ブチル−4−ヒドロキシベンジル)−s−トリアジン−2,4,6(1H,3H,5H)トリオン;
(VII)インペリアル・ケミカル・インダストリーズ(Imperial Chemical Industries Limited)により製造され、シール・サンズ・ケミカルズ(Seal Sands Chemical)により商標名Topanol CAで販売されている4−[4,4−ビス(4−ヒドロキシ−2−メチル−5−tert−ブチル−フェニル)ブタン−2−イル]−5−メチル−2−tert−ブチル−フェノール;
(VIII)Ciba specialty Chemicalsにより商標名Irganox 1010で販売されているペンタエリスリチル−テトラキス[3(3,5−ジ−ter−ブチル−4−ヒドロキシフェニル)プロピオネート];
(IX)Ciba Specialty Chemicalsにより、商標名Irganox MD 1024で販売されている2’,3−[[3−[3,5−ジ−tert−ブチル−4−ヒドロキシフェニル]プロピオニル]]プロピオノヒドラジド;
(X)Ciba Specialty Chemicalsにより商標名Irganox 1076で販売されているオクタデシル−3−(3,5−tert.ブチル−4−ヒドロキシフェニル)−プロピオネートである。
Heco−1は、実施例において膜を調製するために使用される異相組成物(I)である。Heco−1は、約0.6g/10分のMFR値、20MPaの曲げ弾性率および室温キシレン中可溶性フラクションの76重量%の含有率を有し、プロピレンと3.3重量%のエチレンとの(重量パーセント)17重量%の結晶性コポリマー(A);および90重量%の室温キシレン中溶解度を有する32重量%のエチレンを含有するプロピレンとエチレンとの83重量%のコポリマー(B)を含む異相ポリオレフィン組成物である。
表1に規定された安定化添加剤パッケージを含有するポリオレフィン組成物を、Leistritz Micro 27 2軸スクリュー押出機(サイズ=27mm;L/D=40;最大RPM=500;容量=5〜40Kg/時、供給:3個のポート(メインフィーダ+2機のサイドフィーダ);4機のロスインウェイトフィーダ)中で調製した。押出条件は以下の通りであった:
200rpmの回転速度
237℃の溶融温度
処理量6〜8Kg/時
回転速度150rpm
溶融温度245℃
頭部圧力40bar
120×150mmの試験片を各膜試料から切り取り、85±1℃において水中浸漬により6週間老化させて添加剤の枯渇を加速した。水中浸漬老化後、120℃においてオーブン老化を行って酸化効果を加速した。各膜組成物についての試験片を取り出し、試験が不合格になるまで毎週試験した。
引張特性を、ISO527−5Aに従って500mm/分の変形速度において計測した。試料を老化させてから85±1℃において10週間水中浸漬し、次いで120℃においてオーブン老化させることにより引張特性を試験した。試料をオーブンから取り出し、試料が不合格になるまで2週間毎に試験した。試料が50%未満の保持特性を有した場合、不合格とみなした。
Claims (4)
- ポリオレフィン組成物であって、
(I)
a)10〜40重量%のプロピレンホモポリマー、またはプロピレンとエチレンもしくはCH2=CHRα−オレフィン(式中、Rは、C2−C8アルキル基である。)とのコポリマー、またはプロピレンとエチレンおよび前記CH2=CHRα−オレフィンとのコポリマー(前記コポリマーは、85重量%超のプロピレンを含有し、80重量%超の室温キシレン中不溶性フラクションを有する。);ならびに
b)(b1)エチレンとプロピレンまたはCH2=CHRα−オレフィン(式中、Rは、C2−C8アルキル基である。)とのコポリマー、ならびに(b2)エチレンとプロピレンおよび前記α−オレフィンとのコポリマーから選択される、60〜90重量%の1種以上のコポリマー(前記コポリマーは、40重量%未満の量のエチレンを含有し、70重量%超の室温キシレン中溶解度を有する。)
を含む組成物;
((a)および(b)の量は、(a)および(b)の全重量に対するものである。);ならびに
(II)
(i)1種以上の有機ホスファイトおよび/またはホスホナイト;
(ii)ヒンダードフェノール化合物からなる1種以上のフェノール性酸化防止剤;
(iii)2種以上のヒンダードアミン光安定剤(HALS);
ならびに場合により
(iv)1種以上のエポキシ化脂肪酸エステル
を含む添加剤パッケージ
(重量比(iii)/(ii)は、1以下であり;添加剤パッケージ(II)の重量は、該ポリオレフィン組成物の重量に対して0.5から2重量%である。)
を含み、該添加剤パッケージ(II)が0.01重量%以下の水中溶解度を示す成分を含むことを特徴とする組成物。 - 異相組成物(I)が、150MPa以下の曲げ弾性率を有する、請求項1に記載のポリオレフィン組成物。
- 請求項1に記載のポリオレフィン組成物を含む膜。
- ジオメンブレンとして使用される、請求項3に記載の膜。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09180427.8 | 2009-12-22 | ||
EP09180427 | 2009-12-22 | ||
US33562210P | 2010-01-08 | 2010-01-08 | |
US61/335,622 | 2010-01-08 | ||
PCT/EP2010/069930 WO2011076664A1 (en) | 2009-12-22 | 2010-12-16 | Polyolefin composition for membranes |
Publications (2)
Publication Number | Publication Date |
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JP2013515117A JP2013515117A (ja) | 2013-05-02 |
JP5695081B2 true JP5695081B2 (ja) | 2015-04-01 |
Family
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JP2012545246A Active JP5695081B2 (ja) | 2009-12-22 | 2010-12-16 | 膜用ポリオレフィン組成物 |
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Country | Link |
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US (1) | US20120245260A1 (ja) |
EP (1) | EP2516545B1 (ja) |
JP (1) | JP5695081B2 (ja) |
KR (1) | KR101825350B1 (ja) |
CN (1) | CN102686662B (ja) |
WO (1) | WO2011076664A1 (ja) |
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US9518176B2 (en) * | 2013-06-05 | 2016-12-13 | Gse Environmental, Llc | High temperature geomembrane liners and master batch compositions |
CN108290338B (zh) * | 2015-11-24 | 2019-08-30 | 巴塞尔聚烯烃股份有限公司 | 聚烯烃组合物及其制造的制品 |
EP4185463A1 (en) * | 2020-07-24 | 2023-05-31 | Basell Poliolefine Italia S.r.l. | Polyolefin composition for roofing applications |
EP4192688A1 (en) * | 2020-08-07 | 2023-06-14 | Basell Poliolefine Italia S.r.l. | Soft and flexible polyolefin composition |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1372528A (en) | 1970-10-22 | 1974-10-30 | Sandoz Ltd | Benzene phosphonous acid compounds their production and use as stabilizers for organic materials |
US4187212A (en) | 1975-02-20 | 1980-02-05 | Ciba-Geigy Corporation | Stabilization systems from triarylphosphites and phenols |
CA1078991A (en) | 1975-02-20 | 1980-06-03 | Hans J. Lorenz | Stabilization systems from triarylphosphites and phenols |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
JPS61136533A (ja) * | 1984-12-03 | 1986-06-24 | フイリツプス ペトロリユーム コンパニー | 組成物 |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
IT1243188B (it) | 1990-08-01 | 1994-05-24 | Himont Inc | Composizioni poliolefiniche elastoplastiche |
ES2071888T3 (es) | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
TW438850B (en) | 1995-09-15 | 2001-06-07 | Ciba Sc Holding Ag | Stabilization of polyolefin composition in permanent contact with extracting media |
JP4794724B2 (ja) * | 2000-08-31 | 2011-10-19 | 三井化学株式会社 | パイプ用ポリオレフィン樹脂組成物およびその用途 |
DE60211444T2 (de) * | 2001-03-15 | 2006-11-30 | Mitsui Chemicals, Inc. | Automobilteile aus einer polypropylenharzzusammensetzung |
EP1279699A1 (en) * | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
KR100873719B1 (ko) * | 2001-12-10 | 2008-12-12 | 시바 홀딩 인코포레이티드 | 난연제 조성물 |
CA2472289A1 (en) * | 2002-01-31 | 2003-08-07 | Ciba Specialty Chemicals Holding Inc. | Stabilization of polyolefins in permanent contact with chlorinated water |
MY145338A (en) * | 2003-12-04 | 2012-01-31 | Dow Global Technologies Inc | Stabilized polyethylene material |
CN101903083B (zh) * | 2007-12-18 | 2015-07-22 | 巴塞尔聚烯烃意大利有限责任公司 | 膜 |
CN102046723B (zh) * | 2007-12-19 | 2014-06-04 | 巴塞尔聚烯烃意大利有限责任公司 | 柔性和挠性的聚烯烃组合物 |
-
2010
- 2010-12-16 CN CN201080059158.6A patent/CN102686662B/zh active Active
- 2010-12-16 EP EP10798060.9A patent/EP2516545B1/en active Active
- 2010-12-16 WO PCT/EP2010/069930 patent/WO2011076664A1/en active Application Filing
- 2010-12-16 JP JP2012545246A patent/JP5695081B2/ja active Active
- 2010-12-16 KR KR1020127016122A patent/KR101825350B1/ko active IP Right Grant
- 2010-12-16 US US13/514,971 patent/US20120245260A1/en not_active Abandoned
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EP2516545B1 (en) | 2017-01-25 |
EP2516545A1 (en) | 2012-10-31 |
JP2013515117A (ja) | 2013-05-02 |
WO2011076664A1 (en) | 2011-06-30 |
KR20120097529A (ko) | 2012-09-04 |
CN102686662A (zh) | 2012-09-19 |
US20120245260A1 (en) | 2012-09-27 |
CN102686662B (zh) | 2015-11-25 |
KR101825350B1 (ko) | 2018-02-05 |
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