TW593357B - Oxime ester photoinitiators having a combined structure - Google Patents

Info

Publication number

TW593357B

TW593357B TW091112531A TW91112531A TW593357B TW 593357 B TW593357 B TW 593357B TW 091112531 A TW091112531 A TW 091112531A TW 91112531 A TW91112531 A TW 91112531A TW 593357 B TW593357 B TW 593357B

Authority

TW

Taiwan

Prior art keywords

alkyl

phenyl

substituted

nr5r6

halogen

Prior art date

2001-06-11

Links

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• Global Dossier
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• -1 Oxime ester Chemical class 0.000 title claims description 257
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 215
• 150000001875 compounds Chemical class 0.000 claims abstract description 82
• 239000001257 hydrogen Substances 0.000 claims abstract description 56
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 56
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims abstract description 18
• 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims abstract description 12
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
• 229910052727 yttrium Inorganic materials 0.000 claims abstract description 8
• 125000000217 alkyl group Chemical group 0.000 claims description 232
• 239000000203 mixture Substances 0.000 claims description 155
• 229910052736 halogen Inorganic materials 0.000 claims description 99
• 150000002367 halogens Chemical group 0.000 claims description 98
• 238000011049 filling Methods 0.000 claims description 89
• 125000001624 naphthyl group Chemical group 0.000 claims description 89
• 239000000758 substrate Substances 0.000 claims description 79
• 238000000576 coating method Methods 0.000 claims description 60
• 239000000463 material Substances 0.000 claims description 57
• 238000000034 method Methods 0.000 claims description 52
• UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 42
• 125000001424 substituent group Chemical group 0.000 claims description 42
• 239000003086 colorant Substances 0.000 claims description 40
• 229920005989 resin Polymers 0.000 claims description 38
• 239000011347 resin Substances 0.000 claims description 38
• 238000006467 substitution reaction Methods 0.000 claims description 33
• 125000003545 alkoxy group Chemical group 0.000 claims description 32
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 31
• 239000000178 monomer Substances 0.000 claims description 27
• 239000000126 substance Substances 0.000 claims description 27
• 125000002947 alkylene group Chemical group 0.000 claims description 24
• 125000004432 carbon atom Chemical group C* 0.000 claims description 23
• 230000001070 adhesive effect Effects 0.000 claims description 20
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 20
• 230000003287 optical effect Effects 0.000 claims description 20
• 239000000853 adhesive Substances 0.000 claims description 19
• 238000004519 manufacturing process Methods 0.000 claims description 19
• 239000000843 powder Substances 0.000 claims description 19
• 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 17
• 229920002120 photoresistant polymer Polymers 0.000 claims description 17
• 239000011159 matrix material Substances 0.000 claims description 16
• 125000003342 alkenyl group Chemical group 0.000 claims description 15
• 238000005516 engineering process Methods 0.000 claims description 14
• 238000007639 printing Methods 0.000 claims description 13
• 101100533888 Hypocrea jecorina (strain QM6a) sor4 gene Proteins 0.000 claims description 12
• 101100533877 Hypocrea jecorina (strain QM6a) sor8 gene Proteins 0.000 claims description 12
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
• 239000001301 oxygen Substances 0.000 claims description 12
• 229910052760 oxygen Inorganic materials 0.000 claims description 12
• 150000003254 radicals Chemical class 0.000 claims description 12
• XHTUOWXUBNMVEU-UHFFFAOYSA-N 1-benzoyl-5-ethyl-5-(3-methylbutyl)-1,3-diazinane-2,4,6-trione Chemical group O=C1C(CC)(CCC(C)C)C(=O)NC(=O)N1C(=O)C1=CC=CC=C1 XHTUOWXUBNMVEU-UHFFFAOYSA-N 0.000 claims description 11
• 239000000654 additive Substances 0.000 claims description 11
• PXXJHWLDUBFPOL-UHFFFAOYSA-N benzamidine Chemical compound NC(=N)C1=CC=CC=C1 PXXJHWLDUBFPOL-UHFFFAOYSA-N 0.000 claims description 11
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
• 239000007788 liquid Substances 0.000 claims description 11
• 235000010290 biphenyl Nutrition 0.000 claims description 10
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 10
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
• 125000004414 alkyl thio group Chemical group 0.000 claims description 9
• 239000000976 ink Substances 0.000 claims description 9
• 239000004305 biphenyl Substances 0.000 claims description 8
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
• 229910000679 solder Inorganic materials 0.000 claims description 8
• 229910052799 carbon Inorganic materials 0.000 claims description 7
• 239000003795 chemical substances by application Substances 0.000 claims description 7
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 7
• 125000006678 phenoxycarbonyl group Chemical group 0.000 claims description 7
• 125000006729 (C2-C5) alkenyl group Chemical group 0.000 claims description 6
• 125000003302 alkenyloxy group Chemical group 0.000 claims description 6
• 238000005530 etching Methods 0.000 claims description 6
• 238000003384 imaging method Methods 0.000 claims description 6
• 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 6
• 238000007747 plating Methods 0.000 claims description 6
• 238000007650 screen-printing Methods 0.000 claims description 6
• 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 5
• 238000010894 electron beam technology Methods 0.000 claims description 5
• 229920000620 organic polymer Polymers 0.000 claims description 4
• 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 3
• 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 3
• OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 3
• 238000012795 verification Methods 0.000 claims description 3
• YUALYRLIFVPOHL-VPLUBSIMSA-N 2-[(3r,5r,6s)-5-(3-chlorophenyl)-6-(4-chlorophenyl)-1-[(2s,3s)-2-hydroxypentan-3-yl]-3-methyl-2-oxopiperidin-3-yl]acetic acid Chemical compound C1([C@@H]2[C@H](N(C([C@@](C)(CC(O)=O)C2)=O)[C@H]([C@H](C)O)CC)C=2C=CC(Cl)=CC=2)=CC=CC(Cl)=C1 YUALYRLIFVPOHL-VPLUBSIMSA-N 0.000 claims description 2
• 239000001273 butane Substances 0.000 claims description 2
• 125000000332 coumarinyl group Chemical group O1C(=O)C(=CC2=CC=CC=C12)* 0.000 claims description 2
• 230000005670 electromagnetic radiation Effects 0.000 claims description 2
• 239000011152 fibreglass Substances 0.000 claims description 2
• 238000004377 microelectronic Methods 0.000 claims description 2
• 239000003973 paint Substances 0.000 claims description 2
• 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 claims description 2
• 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
• 230000002079 cooperative effect Effects 0.000 claims 5
• 125000001188 haloalkyl group Chemical group 0.000 claims 2
• PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
• 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
• VKVJIWVUYNTBEZ-UHFFFAOYSA-N 1,3-bis(3,5-dichlorophenyl)urea Chemical compound ClC1=CC(Cl)=CC(NC(=O)NC=2C=C(Cl)C=C(Cl)C=2)=C1 VKVJIWVUYNTBEZ-UHFFFAOYSA-N 0.000 claims 1
• QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims 1
• 241001122767 Theaceae Species 0.000 claims 1
• 125000000392 cycloalkenyl group Chemical group 0.000 claims 1
• 238000005401 electroluminescence Methods 0.000 claims 1
• 239000004922 lacquer Substances 0.000 claims 1
• 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims 1
• IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
• 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 claims 1
• 238000004806 packaging method and process Methods 0.000 claims 1
• 238000012856 packing Methods 0.000 claims 1
• 150000002431 hydrogen Chemical class 0.000 abstract description 29
• 238000006243 chemical reaction Methods 0.000 abstract description 12
• 239000010410 layer Substances 0.000 description 70
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 53
• 239000010408 film Substances 0.000 description 42
• 229920001577 copolymer Polymers 0.000 description 38
• 239000011248 coating agent Substances 0.000 description 36
• 229920000642 polymer Polymers 0.000 description 32
• 239000000123 paper Substances 0.000 description 30
• 239000004973 liquid crystal related substance Substances 0.000 description 28
• 239000002904 solvent Substances 0.000 description 27
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 26
• 239000002253 acid Substances 0.000 description 24
• 239000000243 solution Substances 0.000 description 23
• 239000002585 base Substances 0.000 description 22
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 21
• 239000011342 resin composition Substances 0.000 description 21
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
• 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 18
• 239000007787 solid Substances 0.000 description 18
• 229910052751 metal Inorganic materials 0.000 description 17
• 239000002184 metal Substances 0.000 description 17
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 17
• 239000011521 glass Substances 0.000 description 16
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 15
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 15
• 238000010438 heat treatment Methods 0.000 description 15
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
• 150000001412 amines Chemical class 0.000 description 14
• 238000002360 preparation method Methods 0.000 description 14
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 14
• 238000011161 development Methods 0.000 description 13
• 230000018109 developmental process Effects 0.000 description 13
• 150000002148 esters Chemical class 0.000 description 13
• 235000019441 ethanol Nutrition 0.000 description 13
• 229910052757 nitrogen Inorganic materials 0.000 description 13
• 239000011241 protective layer Substances 0.000 description 13
• 229920002554 vinyl polymer Polymers 0.000 description 13
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 12
• 239000010949 copper Substances 0.000 description 12
• 239000006185 dispersion Substances 0.000 description 12
• 239000003999 initiator Substances 0.000 description 12
• 239000003960 organic solvent Substances 0.000 description 12
• TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 11
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 11
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
• 230000005855 radiation Effects 0.000 description 11
• 238000012360 testing method Methods 0.000 description 11
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
• 125000003118 aryl group Chemical group 0.000 description 10
• ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 10
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
• BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 10
• 239000000975 dye Substances 0.000 description 10
• OKKJLVBELUTLKV-UHFFFAOYSA-N methyl alcohol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 10
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
• 229920005862 polyol Polymers 0.000 description 10
• 230000035945 sensitivity Effects 0.000 description 10
• 229920003002 synthetic resin Polymers 0.000 description 10
• 239000000057 synthetic resin Substances 0.000 description 10
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
• 239000007864 aqueous solution Substances 0.000 description 9
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 9
• 239000012964 benzotriazole Substances 0.000 description 9
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
• 239000007789 gas Substances 0.000 description 9
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 9
• 239000005977 Ethylene Substances 0.000 description 8
• 239000004642 Polyimide Substances 0.000 description 8
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
• 230000000694 effects Effects 0.000 description 8
• LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 8
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 8
• 239000011229 interlayer Substances 0.000 description 8
• 239000011976 maleic acid Substances 0.000 description 8
• XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 8
• 238000000206 photolithography Methods 0.000 description 8
• 229920001721 polyimide Polymers 0.000 description 8
• 238000006116 polymerization reaction Methods 0.000 description 8
• 150000003077 polyols Chemical class 0.000 description 8
• 239000000047 product Substances 0.000 description 8
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
• 101100258315 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) crc-1 gene Proteins 0.000 description 7
• 239000003513 alkali Substances 0.000 description 7
• 230000004888 barrier function Effects 0.000 description 7
• AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 7
• 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
• FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 7
• BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 7
• 150000003839 salts Chemical class 0.000 description 7
• 239000000600 sorbitol Substances 0.000 description 7
• 125000006850 spacer group Chemical group 0.000 description 7
• 239000001060 yellow colorant Substances 0.000 description 7
• GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 6
• YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 6
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 6
• CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 6
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
• 239000007983 Tris buffer Substances 0.000 description 6
• MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 6
• 239000002671 adjuvant Substances 0.000 description 6
• DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 6
• 235000001671 coumarin Nutrition 0.000 description 6
• 229960000956 coumarin Drugs 0.000 description 6
• 238000001723 curing Methods 0.000 description 6
• SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 6
• 238000001035 drying Methods 0.000 description 6
• JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
• 229920003986 novolac Polymers 0.000 description 6
• 238000007645 offset printing Methods 0.000 description 6
• YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 6
• 239000000049 pigment Substances 0.000 description 6
• LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 6
• JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
• 239000011541 reaction mixture Substances 0.000 description 6
• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
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