TWI586021B - Solid electrolyte - Google Patents
Solid electrolyte Download PDFInfo
- Publication number
- TWI586021B TWI586021B TW101141356A TW101141356A TWI586021B TW I586021 B TWI586021 B TW I586021B TW 101141356 A TW101141356 A TW 101141356A TW 101141356 A TW101141356 A TW 101141356A TW I586021 B TWI586021 B TW I586021B
- Authority
- TW
- Taiwan
- Prior art keywords
- solid electrolyte
- sulfide
- peak
- lithium
- electrolyte
- Prior art date
Links
- 239000007784 solid electrolyte Substances 0.000 title claims description 330
- 239000003792 electrolyte Substances 0.000 claims description 108
- 238000004519 manufacturing process Methods 0.000 claims description 77
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims description 60
- 229910052736 halogen Inorganic materials 0.000 claims description 55
- 150000002367 halogens Chemical class 0.000 claims description 55
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 49
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 49
- 150000001875 compounds Chemical class 0.000 claims description 47
- 239000002994 raw material Substances 0.000 claims description 45
- 229910052717 sulfur Inorganic materials 0.000 claims description 36
- 229910052794 bromium Inorganic materials 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 32
- 239000011593 sulfur Substances 0.000 claims description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 29
- 229910052783 alkali metal Inorganic materials 0.000 claims description 28
- 229910052744 lithium Inorganic materials 0.000 claims description 28
- 150000001340 alkali metals Chemical class 0.000 claims description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 22
- 239000000470 constituent Substances 0.000 claims description 22
- 229910052698 phosphorus Inorganic materials 0.000 claims description 22
- 229910052801 chlorine Inorganic materials 0.000 claims description 20
- 229910052740 iodine Inorganic materials 0.000 claims description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 230000007062 hydrolysis Effects 0.000 claims description 16
- 238000006460 hydrolysis reaction Methods 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 238000001394 phosphorus-31 nuclear magnetic resonance spectrum Methods 0.000 claims description 14
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical compound S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 claims description 12
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 229910052732 germanium Inorganic materials 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 229910052787 antimony Inorganic materials 0.000 claims description 7
- 229910052785 arsenic Inorganic materials 0.000 claims description 7
- 229910052711 selenium Inorganic materials 0.000 claims description 7
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 10
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 10
- 239000011521 glass Substances 0.000 description 110
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 109
- 238000000034 method Methods 0.000 description 66
- 150000002500 ions Chemical class 0.000 description 60
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 52
- 238000010438 heat treatment Methods 0.000 description 48
- 239000000523 sample Substances 0.000 description 48
- 238000002425 crystallisation Methods 0.000 description 41
- 230000008025 crystallization Effects 0.000 description 41
- 229910018091 Li 2 S Inorganic materials 0.000 description 37
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 33
- 239000000463 material Substances 0.000 description 30
- 238000000634 powder X-ray diffraction Methods 0.000 description 29
- 239000002243 precursor Substances 0.000 description 27
- 238000005259 measurement Methods 0.000 description 25
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 24
- 238000005481 NMR spectroscopy Methods 0.000 description 22
- 239000002245 particle Substances 0.000 description 22
- 239000002241 glass-ceramic Substances 0.000 description 19
- 239000003960 organic solvent Substances 0.000 description 18
- 239000011734 sodium Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 17
- -1 L iBr Inorganic materials 0.000 description 16
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 14
- 238000011282 treatment Methods 0.000 description 14
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 238000007613 slurry method Methods 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 238000010532 solid phase synthesis reaction Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 150000002366 halogen compounds Chemical class 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 238000007578 melt-quenching technique Methods 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 239000007774 positive electrode material Substances 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical group [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 159000000002 lithium salts Chemical class 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 238000005004 MAS NMR spectroscopy Methods 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- PHSPJQZRQAJPPF-UHFFFAOYSA-N N-alpha-Methylhistamine Chemical compound CNCCC1=CN=CN1 PHSPJQZRQAJPPF-UHFFFAOYSA-N 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 229910004283 SiO 4 Inorganic materials 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- YGLBXEHGQGOHPL-UHFFFAOYSA-M lithium;2-(methylamino)butanoate Chemical compound [Li+].CCC(NC)C([O-])=O YGLBXEHGQGOHPL-UHFFFAOYSA-M 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000012295 chemical reaction liquid Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- 238000003701 mechanical milling Methods 0.000 description 3
- 239000011812 mixed powder Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 102100021202 Desmocollin-1 Human genes 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 101000968043 Homo sapiens Desmocollin-1 Proteins 0.000 description 2
- 101000880960 Homo sapiens Desmocollin-3 Proteins 0.000 description 2
- 239000002227 LISICON Substances 0.000 description 2
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 2
- 229910013716 LiNi Inorganic materials 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910003691 SiBr Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 229910021383 artificial graphite Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 2
- 238000005384 cross polarization magic-angle spinning Methods 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- GQYHUHYESMUTHG-UHFFFAOYSA-N lithium niobate Chemical compound [Li+].[O-][Nb](=O)=O GQYHUHYESMUTHG-UHFFFAOYSA-N 0.000 description 2
- 239000002931 mesocarbon microbead Substances 0.000 description 2
- YQCIWBXEVYWRCW-UHFFFAOYSA-N methane;sulfane Chemical compound C.S YQCIWBXEVYWRCW-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000002203 sulfidic glass Substances 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- UKUVVAMSXXBMRX-UHFFFAOYSA-N 2,4,5-trithia-1,3-diarsabicyclo[1.1.1]pentane Chemical compound S1[As]2S[As]1S2 UKUVVAMSXXBMRX-UHFFFAOYSA-N 0.000 description 1
- 229920003026 Acene Polymers 0.000 description 1
- 229910016569 AlF 3 Inorganic materials 0.000 description 1
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910018871 CoO 2 Inorganic materials 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910005839 GeS 2 Inorganic materials 0.000 description 1
- 229910019271 La0.55Li0.35TiO3 Inorganic materials 0.000 description 1
- 229910010093 LiAlO Inorganic materials 0.000 description 1
- 229910013184 LiBO Inorganic materials 0.000 description 1
- 229910013733 LiCo Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910011281 LiCoPO 4 Inorganic materials 0.000 description 1
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910015645 LiMn Inorganic materials 0.000 description 1
- 229910015644 LiMn 2 - z Ni Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- 229910012465 LiTi Inorganic materials 0.000 description 1
- 229910016485 Mn1/3Ni1/3Co1/3 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000002228 NASICON Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910018287 SbF 5 Inorganic materials 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229910020346 SiS 2 Inorganic materials 0.000 description 1
- 229910008449 SnF 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- DUDJJJCZFBPZKW-UHFFFAOYSA-N [Ru]=S Chemical compound [Ru]=S DUDJJJCZFBPZKW-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- COOGPNLGKIHLSK-UHFFFAOYSA-N aluminium sulfide Chemical compound [Al+3].[Al+3].[S-2].[S-2].[S-2] COOGPNLGKIHLSK-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229940052288 arsenic trisulfide Drugs 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 210000001268 chyle Anatomy 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000004807 desolvation Methods 0.000 description 1
- GMKDNCQTOAHUQG-UHFFFAOYSA-L dilithium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=S GMKDNCQTOAHUQG-UHFFFAOYSA-L 0.000 description 1
- FOBPTJZYDGNHLR-UHFFFAOYSA-N diphosphorus Chemical compound P#P FOBPTJZYDGNHLR-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002795 fluorescence method Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
- HZRMTWQRDMYLNW-UHFFFAOYSA-N lithium metaborate Chemical compound [Li+].[O-]B=O HZRMTWQRDMYLNW-UHFFFAOYSA-N 0.000 description 1
- MUERZYSPGYLGBT-UHFFFAOYSA-N lithium;molecular hydrogen Chemical compound [Li].[H][H] MUERZYSPGYLGBT-UHFFFAOYSA-N 0.000 description 1
- HXQGSILMFTUKHI-UHFFFAOYSA-M lithium;sulfanide Chemical compound S[Li] HXQGSILMFTUKHI-UHFFFAOYSA-M 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910021470 non-graphitizable carbon Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
- IPNPIHIZVLFAFP-UHFFFAOYSA-N phosphorus tribromide Chemical compound BrP(Br)Br IPNPIHIZVLFAFP-UHFFFAOYSA-N 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 229920005608 sulfonated EPDM Polymers 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- YTZVWGRNMGHDJE-UHFFFAOYSA-N tetralithium;silicate Chemical compound [Li+].[Li+].[Li+].[Li+].[O-][Si]([O-])([O-])[O-] YTZVWGRNMGHDJE-UHFFFAOYSA-N 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/16—Halogen containing crystalline phase
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/008—Halides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Chemistry (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Glass Compositions (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011243459 | 2011-11-07 | ||
| JP2012002228 | 2012-01-10 | ||
| JP2012034890 | 2012-02-21 | ||
| JP2012147050A JP6234665B2 (ja) | 2011-11-07 | 2012-06-29 | 固体電解質 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201336149A TW201336149A (zh) | 2013-09-01 |
| TWI586021B true TWI586021B (zh) | 2017-06-01 |
Family
ID=48289338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101141356A TWI586021B (zh) | 2011-11-07 | 2012-11-07 | Solid electrolyte |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9620811B2 (enExample) |
| EP (2) | EP3361545B1 (enExample) |
| JP (1) | JP6234665B2 (enExample) |
| KR (1) | KR101973827B1 (enExample) |
| CN (1) | CN104025363B (enExample) |
| AU (1) | AU2012333924A1 (enExample) |
| CA (1) | CA2854596C (enExample) |
| TW (1) | TWI586021B (enExample) |
| WO (1) | WO2013069243A1 (enExample) |
Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6243103B2 (ja) * | 2012-06-29 | 2017-12-06 | 出光興産株式会社 | 正極合材 |
| WO2014073197A1 (ja) | 2012-11-06 | 2014-05-15 | 出光興産株式会社 | 固体電解質 |
| JP6073107B2 (ja) * | 2012-11-06 | 2017-02-01 | 出光興産株式会社 | 固体電解質 |
| JP6088797B2 (ja) * | 2012-11-06 | 2017-03-01 | 出光興産株式会社 | 固体電解質 |
| CN105518906B (zh) | 2013-05-15 | 2019-04-16 | 量子世界公司 | 用于使用LiAMPBSC的电池的固态阴极电解质或电解质(M=Si、Ge和/或Sn) |
| WO2014192309A1 (ja) | 2013-05-31 | 2014-12-04 | 出光興産株式会社 | 固体電解質の製造方法 |
| JP6122708B2 (ja) * | 2013-06-19 | 2017-04-26 | 出光興産株式会社 | 硫化物系固体電解質の製造方法 |
| CN105210154B (zh) * | 2013-07-04 | 2017-07-14 | 三井金属矿业株式会社 | 结晶性固体电解质及其制造方法 |
| JP6070468B2 (ja) * | 2013-08-02 | 2017-02-01 | トヨタ自動車株式会社 | 硫化物固体電解質材料 |
| JP2015041572A (ja) * | 2013-08-23 | 2015-03-02 | 株式会社豊田中央研究所 | 無機マグネシウム固体電解質、マグネシウム電池、電気化学デバイス及び無機マグネシウム固体電解質の製造方法 |
| JP2015088226A (ja) * | 2013-10-28 | 2015-05-07 | トヨタ自動車株式会社 | 硫化物固体電解質の製造方法 |
| JP2015137218A (ja) * | 2014-01-24 | 2015-07-30 | トヨタ自動車株式会社 | 硫化物固体電解質の製造方法 |
| JP6310713B2 (ja) * | 2014-02-03 | 2018-04-11 | 古河機械金属株式会社 | 固体電解質材料、リチウムイオン電池および固体電解質材料の製造方法 |
| JP6044588B2 (ja) * | 2014-05-15 | 2016-12-14 | トヨタ自動車株式会社 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
| JP6044587B2 (ja) * | 2014-05-15 | 2016-12-14 | トヨタ自動車株式会社 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
| JP6288716B2 (ja) | 2014-06-25 | 2018-03-07 | 国立大学法人東京工業大学 | 硫化物固体電解質材料の製造方法 |
| JP5873533B2 (ja) * | 2014-07-16 | 2016-03-01 | 三井金属鉱業株式会社 | リチウムイオン電池用硫化物系固体電解質 |
| JP5975071B2 (ja) * | 2014-07-22 | 2016-08-23 | トヨタ自動車株式会社 | 硫化物固体電解質材料、電池および硫化物固体電解質材料の製造方法 |
| CN107108328A (zh) * | 2014-10-31 | 2017-08-29 | 出光兴产株式会社 | 硫化物玻璃和结晶性固体电解质的制造方法、结晶性固体电解质、硫化物玻璃和固体电池 |
| US9899702B2 (en) | 2014-12-26 | 2018-02-20 | Mitsui Mining & Smelting Co., Ltd. | Sulfide-based solid electrolyte for lithium ion cell, and solid electrolyte compound |
| JP6415008B2 (ja) * | 2015-02-20 | 2018-10-31 | 富士フイルム株式会社 | 固体電解質組成物、これを用いた電池用電極シートおよび全固体二次電池、ならびに電池用電極シートおよび全固体二次電池の製造方法 |
| JP6577222B2 (ja) | 2015-04-17 | 2019-09-18 | トヨタ自動車株式会社 | 硫化物固体電解質の製造方法及び硫黄系材料 |
| KR101684130B1 (ko) * | 2015-06-16 | 2016-12-07 | 현대자동차주식회사 | 리튬 이온 전도성 황화물의 제조방법, 이에 의하여 제조된 리튬 이온 전도성 황화물, 및 이를 포함하는 고체전해질, 전고체 배터리 |
| JP6956641B2 (ja) * | 2015-06-24 | 2021-11-02 | クアンタムスケイプ バテリー， インク． | 複合電解質 |
| JP6380263B2 (ja) | 2015-06-29 | 2018-08-29 | トヨタ自動車株式会社 | 硫化物固体電解質の製造方法 |
| JP6877084B2 (ja) | 2015-07-31 | 2021-05-26 | 国立大学法人東京工業大学 | α−リチウム固体電解質 |
| JP2017045613A (ja) * | 2015-08-26 | 2017-03-02 | 出光興産株式会社 | 硫化物固体電解質及びその製造方法 |
| JP2017091810A (ja) * | 2015-11-10 | 2017-05-25 | トヨタ自動車株式会社 | 正極合材の製造方法 |
| CN109075388A (zh) | 2015-11-24 | 2018-12-21 | 锡安能量公司 | 离子传导化合物及其相关用途 |
| JP6320983B2 (ja) * | 2015-12-01 | 2018-05-09 | 出光興産株式会社 | 硫化物ガラスセラミックスの製造方法 |
| CN114512709A (zh) * | 2015-12-04 | 2022-05-17 | 昆腾斯科普电池公司 | 含锂、磷、硫、碘的电解质和阴极电解液组成 |
| WO2017106563A1 (en) | 2015-12-15 | 2017-06-22 | Sila Nanotechnologies Inc. | Solid state electrolytes for safe metal and metal-ion batteries |
| JP2017117635A (ja) * | 2015-12-24 | 2017-06-29 | 出光興産株式会社 | 硫化物固体電解質、硫化物ガラス、電極合材及びリチウムイオン電池 |
| US11245131B2 (en) | 2015-12-25 | 2022-02-08 | Samsung Electronics Co., Ltd. | Solid electrolyte and lithium battery including the same |
| JP6750836B2 (ja) | 2016-03-14 | 2020-09-02 | 出光興産株式会社 | ハロゲン化アルカリ金属の製造方法、及び硫化物系固体電解質の製造方法 |
| US11038198B2 (en) | 2016-03-14 | 2021-06-15 | Idemitsu Kosan Co., Ltd. | Solid electrolyte and method for producing solid electrolyte |
| KR101842556B1 (ko) * | 2016-03-30 | 2018-05-14 | 울산과학기술원 | 고체 전해질, 이의 제조방법, 및 이를 포함하는 전고체 전지 |
| WO2018044952A1 (en) | 2016-08-29 | 2018-03-08 | Quantumscape Corporation | Catholytes for solid state rechargeable batteries, battery architectures suitable for use with these catholytes, and methods of making and using the same |
| CN109690696B (zh) * | 2016-09-12 | 2020-10-20 | 出光兴产株式会社 | 硫化物固体电解质 |
| CN115458802A (zh) * | 2016-11-16 | 2022-12-09 | 出光兴产株式会社 | 硫化物固体电解质 |
| KR102417513B1 (ko) | 2016-11-22 | 2022-07-05 | 현대자동차주식회사 | 광범위한 결정화 온도 범위에서 고이온전도도를 갖는 황화물계 고체전해질 및 이의 제조방법 |
| JP7113513B2 (ja) * | 2016-11-28 | 2022-08-05 | 国立研究開発法人産業技術総合研究所 | 無機硫化物及びその製造方法 |
| JP6936251B2 (ja) | 2016-12-14 | 2021-09-15 | 出光興産株式会社 | 硫化物固体電解質の製造方法 |
| KR101867555B1 (ko) * | 2017-01-04 | 2018-06-14 | 울산과학기술원 | 전극 활물질-고체 전해질 복합체, 이의 제조 방법, 이를 포함하는 전고체 전지 |
| TW201841168A (zh) * | 2017-01-30 | 2018-11-16 | 日商三菱瓦斯化學股份有限公司 | 離子傳導體及其製造方法 |
| JP6763808B2 (ja) | 2017-03-14 | 2020-09-30 | 出光興産株式会社 | 固体電解質の製造方法 |
| CN106972195A (zh) * | 2017-04-17 | 2017-07-21 | 哈尔滨工业大学无锡新材料研究院 | 一种无机硫化物电解质及其制备方法 |
| US11251501B2 (en) | 2017-05-24 | 2022-02-15 | Sion Power Corporation | Lithium metal sulfide and lithium metal sulfide argyrodite ionically conductive compounds and related uses |
| DE112018002679T5 (de) | 2017-05-24 | 2020-03-05 | Idemitsu Kosan Co., Ltd. | Sulfid-festelektrolyt |
| JP7369988B2 (ja) * | 2017-06-14 | 2023-10-27 | パナソニックＩｐマネジメント株式会社 | 硫化物固体電解質材料を用いた電池 |
| WO2019003986A1 (ja) | 2017-06-29 | 2019-01-03 | 出光興産株式会社 | 硫化物固体電解質 |
| JP7236648B2 (ja) | 2017-09-08 | 2023-03-10 | パナソニックＩｐマネジメント株式会社 | 硫化物固体電解質材料及びそれを用いた電池 |
| US10811726B2 (en) | 2017-11-14 | 2020-10-20 | Samsung Electronics Co., Ltd. | Solid electrolyte for all-solid lithium secondary battery, all-solid lithium secondary battery, and method of preparing the solid electrolyte |
| DE112018005830T5 (de) | 2017-11-14 | 2020-09-03 | lDEMITSU KOSAN CO., LTD. | Metallelement enthaltender Sulfidtyp-Festelektrolyt und Verfahren zur Herstellung desselben |
| JP2019096610A (ja) | 2017-11-21 | 2019-06-20 | 三星電子株式会社Ｓａｍｓｕｎｇ Ｅｌｅｃｔｒｏｎｉｃｓ Ｃｏ．，Ｌｔｄ． | 全固体二次電池およびその充電方法 |
| CN109818050B (zh) * | 2017-11-22 | 2021-04-09 | 中国科学院物理研究所 | Nasicon结构钠离子固体电解质/卤化钠复合材料及其制备方法和应用 |
| KR20190066792A (ko) * | 2017-12-06 | 2019-06-14 | 현대자동차주식회사 | 아지로다이트형 결정구조를 갖는 전고체 전지용 황화물계 고체 전해질의 제조 방법 |
| CN109935900B (zh) * | 2017-12-19 | 2021-10-19 | 成都大超科技有限公司 | 固态电解质及其锂电池、锂电池电芯及其制备方法 |
| US11437643B2 (en) | 2018-02-20 | 2022-09-06 | Samsung Electronics Co., Ltd. | All-solid-state secondary battery |
| EP3726635B1 (en) * | 2018-03-12 | 2022-10-19 | Mitsui Mining & Smelting Co., Ltd. | Sulfide-based solid electrolyte particles |
| JP6595031B2 (ja) * | 2018-03-19 | 2019-10-23 | 古河機械金属株式会社 | 固体電解質材料、リチウムイオン電池および固体電解質材料の製造方法 |
| CN108598475B (zh) * | 2018-04-25 | 2021-03-26 | 广东工业大学 | 离子电池用成分结构可调控的磷硫硒系列负极材料 |
| JP2019200851A (ja) * | 2018-05-14 | 2019-11-21 | トヨタ自動車株式会社 | 固体電解質、全固体電池および固体電解質の製造方法 |
| US11127974B2 (en) | 2018-05-14 | 2021-09-21 | Samsung Electronics Co., Ltd. | Method of preparing sulfide-based solid electrolyte, sulfide-based solid electrolyte prepared therefrom, and solid secondary battery including the sulfide electrolyte |
| JP7077766B2 (ja) * | 2018-05-18 | 2022-05-31 | トヨタ自動車株式会社 | 硫化物系固体電解質、当該硫化物系固体電解質の製造方法、及び、全固体電池の製造方法 |
| PL3809425T3 (pl) * | 2018-06-13 | 2022-11-21 | Mitsubishi Gas Chemical Company, Inc. | Stały elektrolit na bazie LGPS i sposób jego wytwarzania |
| US12107214B2 (en) * | 2018-06-15 | 2024-10-01 | Georgia Tech Research Corporation | Solid electrolyte materials and methods of making the same |
| KR102063159B1 (ko) * | 2018-07-17 | 2020-01-08 | 한국과학기술연구원 | 셀레늄을 포함하는 리튬 이온 전도성 황화물계 고체전해질 및 이의 제조방법 |
| KR102728661B1 (ko) | 2018-09-06 | 2024-11-11 | 삼성전자주식회사 | 고체 전해질, 그 제조방법 및 이를 포함하는 이차전지 |
| WO2020058529A1 (en) | 2018-09-21 | 2020-03-26 | Philipps-Universität Marburg | Amorphous solid li+ electrolyte, process for production of the amorphous solid electrolyte and usage of the amorphous solid electrolyte |
| JP7119902B2 (ja) * | 2018-10-29 | 2022-08-17 | トヨタ自動車株式会社 | 硫化物系固体電解質 |
| KR20200053099A (ko) * | 2018-11-08 | 2020-05-18 | 현대자동차주식회사 | 습식법으로 합성된 황화물계 고체전해질, 이의 제조용 조성물 및 이의 제조방법 |
| US11387487B2 (en) | 2018-11-08 | 2022-07-12 | Mitsui Mining & Smelting Co., Ltd. | Sulfur-containing compound, solid electrolyte, and battery |
| KR102650658B1 (ko) | 2018-11-15 | 2024-03-25 | 삼성전자주식회사 | 헤테로고리 방향족 구조의 음이온을 포함하는 금속염 및 그 제조방법, 그리고 상기 금속염을 포함하는 전해질 및 전기화학소자 |
| CN111293352A (zh) | 2018-12-06 | 2020-06-16 | 三星电子株式会社 | 全固态二次电池和制造全固态二次电池的方法 |
| CN109712823A (zh) * | 2018-12-27 | 2019-05-03 | 上海奥威科技开发有限公司 | 固态玻璃电解质及其复合电极材料、膜片、电极片和全固态超级电容器 |
| KR102831128B1 (ko) * | 2019-03-07 | 2025-07-04 | 삼성전자주식회사 | 황화물계 고체 전해질, 이를 포함하는 전고체 이차전지 및 황화물계 고체 전해질의 제조방법 |
| EP3716389B1 (en) * | 2019-03-28 | 2025-04-09 | Toyota Jidosha Kabushiki Kaisha | Sulfide solid electrolyte, precursor of sulfide solid electrolyte, all solid state battery and method for producing sulfide solid electrolyte |
| WO2020203045A1 (ja) | 2019-03-29 | 2020-10-08 | 古河機械金属株式会社 | 硫化物系無機固体電解質材料用の五硫化二リン組成物 |
| CN109970347A (zh) * | 2019-04-29 | 2019-07-05 | 齐鲁工业大学 | 一种提高锂离子电池性能的TeO2-V2O5-CuO微晶玻璃负极材料 |
| US11264602B2 (en) | 2019-05-08 | 2022-03-01 | Samsung Electronics Co., Ltd. | Sulfide glass-ceramic lithium-ion solid-state conductor |
| US11824155B2 (en) | 2019-05-21 | 2023-11-21 | Samsung Electronics Co., Ltd. | All-solid lithium secondary battery and method of charging the same |
| US11799126B2 (en) | 2019-05-31 | 2023-10-24 | Samsung Electronics Co., Ltd. | Method of preparing solid electrolyte and all-solid battery including solid electrolyte prepared by the method |
| JP7151658B2 (ja) * | 2019-08-01 | 2022-10-12 | トヨタ自動車株式会社 | 正極合材 |
| US11702337B2 (en) | 2019-09-27 | 2023-07-18 | Samsung Sdi Co., Ltd. | Solid ion conductor, solid electrolyte including the solid ion conductor, electrochemical cell including the solid ion conductor, and preparation method of the same |
| KR102292161B1 (ko) * | 2019-10-22 | 2021-08-24 | 한국과학기술연구원 | 다중 칼코겐 원소가 도입된 황화물계 리튬-아지로다이트 이온 초전도체 및 이의 제조방법 |
| CN110808407B (zh) * | 2019-11-01 | 2020-11-20 | 宁德新能源科技有限公司 | 一种不含磷的硫化物固态电解质 |
| JP7143834B2 (ja) * | 2019-11-14 | 2022-09-29 | トヨタ自動車株式会社 | 電極の製造方法、電極、および全固体電池 |
| EP4075450A4 (en) * | 2019-12-11 | 2023-06-14 | Mitsui Mining & Smelting Co., Ltd. | SULPHIDE SOLID ELECTROLYTE |
| US20230037508A1 (en) * | 2019-12-27 | 2023-02-09 | Mitsui Mining & Smelting Co., Ltd. | Sulfide solid electrolyte and method for producing the same |
| JP7035281B2 (ja) * | 2019-12-27 | 2022-03-14 | 昭和電工株式会社 | リチウムイオン伝導性酸化物およびその用途 |
| US20230084324A1 (en) * | 2020-02-07 | 2023-03-16 | Samsung Sdi Co., Ltd. | Solid ion conductor compound, solid electrolyte comprising same, electrochemical cell comprising same, and manufacturing method thereof |
| TWI829867B (zh) * | 2020-02-19 | 2024-01-21 | 日商三井金屬鑛業股份有限公司 | 含硫化合物、固體電解質及電池 |
| JP7754083B2 (ja) * | 2020-02-28 | 2025-10-15 | 株式会社Ｇｓユアサ | 固体電解質、固体電解質の製造方法及び蓄電素子 |
| US11923503B2 (en) * | 2020-03-16 | 2024-03-05 | Solid Power Operating, Inc. | Bromine and iodine lithium phosphorous sulfide solid electrolyte and solid-state battery including the same |
| CN115023770A (zh) * | 2020-03-23 | 2022-09-06 | 三井金属矿业株式会社 | 硫化物固体电解质和使用其的电极复合材料、固体电解质层以及电池 |
| US11978848B2 (en) * | 2020-05-27 | 2024-05-07 | Idemitsu Kosan Co., Ltd. | Method for producing solid electrolyte |
| WO2022009810A1 (ja) * | 2020-07-09 | 2022-01-13 | 三井金属鉱業株式会社 | 硫化リチウムの製造方法 |
| JP7563033B2 (ja) * | 2020-08-06 | 2024-10-08 | 株式会社Ｇｓユアサ | 硫化物固体電解質、蓄電素子及び硫化物固体電解質の製造方法 |
| KR20220039386A (ko) * | 2020-09-22 | 2022-03-29 | 삼성에스디아이 주식회사 | 고체이온전도체 화합물, 이를 포함하는 고체전해질, 이를 포함하는 전기화학 셀, 및 이의 제조방법 |
| JP2022059592A (ja) * | 2020-10-01 | 2022-04-13 | 国立大学法人東京工業大学 | 全固体電池の充放電方法およびそれに用いることができる固体電解質材 |
| KR102406069B1 (ko) * | 2020-11-25 | 2022-06-13 | 한국과학기술연구원 | 할로겐의 완전 점유형 구조가 도입된 리튬-아지로다이트 기반 이온 초전도체 및 이의 제조방법 |
| CN114122508B (zh) * | 2021-11-26 | 2024-02-23 | 湖州昆仑先端固态电池科技有限公司 | 一种硫化物固体电解质及其制备方法和应用 |
| KR102773821B1 (ko) * | 2022-05-16 | 2025-02-27 | 울산대학교 산학협력단 | 황화물계 고체 전해질, 이를 포함하는 전고체 리튬 전지 및 이의 제조 방법 |
| KR20250038875A (ko) * | 2023-09-12 | 2025-03-20 | 삼성에스디아이 주식회사 | 고체 이차전지용 양극 및 이를 포함하는 고체 이차전지 |
| US20250192225A1 (en) * | 2023-12-08 | 2025-06-12 | Solid Power Operating, Inc. | Solid electrolyte materials and methods for making the same |
| CN120824408A (zh) * | 2024-04-11 | 2025-10-21 | 宁德时代新能源科技股份有限公司 | 硫化物固体电解质及其制备方法、固体电解质膜、电极极片、固态电池和用电装置 |
| CN120824407A (zh) * | 2024-04-11 | 2025-10-21 | 宁德时代新能源科技股份有限公司 | 硫化物固体电解质及其制备方法、固体电解质膜、电极极片、固态电池和用电装置 |
| WO2025244481A1 (ko) * | 2024-05-24 | 2025-11-27 | 주식회사 솔리비스 | 황화물계 고체전해질의 제조방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011124081A (ja) * | 2009-12-10 | 2011-06-23 | Idemitsu Kosan Co Ltd | リチウムイオン伝導性硫化物ガラス及びそれを用いたリチウムイオン電池 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3151925B2 (ja) * | 1992-05-07 | 2001-04-03 | 松下電器産業株式会社 | 非晶質リチウムイオン伝導性固体電解質並びにその合成法 |
| JP3343934B2 (ja) * | 1992-05-07 | 2002-11-11 | 松下電器産業株式会社 | 非晶質リチウムイオン伝導性固体電解質並びにその合成法 |
| JP3125506B2 (ja) | 1993-03-26 | 2001-01-22 | 松下電器産業株式会社 | 硫化物系リチウムイオン導電性固体電解質及びその合成法 |
| JP3528866B2 (ja) | 1994-06-03 | 2004-05-24 | 出光石油化学株式会社 | 硫化リチウムの製造方法 |
| JP3510420B2 (ja) | 1996-04-16 | 2004-03-29 | 松下電器産業株式会社 | リチウムイオン伝導性固体電解質およびその製造方法 |
| JPH10321256A (ja) * | 1997-05-19 | 1998-12-04 | Matsushita Electric Ind Co Ltd | 固体電解質あるいは電極の加工方法及びリチウム電池の製造方法 |
| JP3233345B2 (ja) | 1997-10-31 | 2001-11-26 | 大阪府 | 全固体型電池用イオン伝導性硫化物ガラス微粉末の製造方法、全固体型電池用イオン伝導性硫化物ガラス微粉末、固体型電解質及び全固体型二次電池 |
| JP2003346896A (ja) * | 2002-05-30 | 2003-12-05 | Fujitsu Ltd | 固体電解質の製造方法、固体電解質、およびリチウム電池 |
| WO2004093099A1 (ja) | 2003-04-15 | 2004-10-28 | Idemitsu Kosan Co., Ltd. | リチウムイオン導電性固体電解質の製造方法及びそれを用いた全固体型二次電池 |
| JP4580149B2 (ja) | 2003-04-24 | 2010-11-10 | 出光興産株式会社 | リチウムイオン伝導性硫化物ガラスの製造方法及びリチウムイオン伝導性硫化物ガラスセラミックスの製造方法 |
| JP4498688B2 (ja) | 2003-04-24 | 2010-07-07 | 出光興産株式会社 | リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法 |
| US8084160B2 (en) | 2003-10-23 | 2011-12-27 | Idemitsu Kosan Co., Ltd. | Method for purifying lithium sulfide |
| JP4813767B2 (ja) | 2004-02-12 | 2011-11-09 | 出光興産株式会社 | リチウムイオン伝導性硫化物系結晶化ガラス及びその製造方法 |
| CA2555751A1 (en) | 2004-03-31 | 2005-11-03 | Exxonmobil Upstream Research Company | Method for constructing a geologic model of a subsurface reservoir |
| US20070248888A1 (en) | 2004-06-04 | 2007-10-25 | Idemitsu Kosan Co., Ltd. | High-Performance All-Solid Lithium Battery |
| WO2007066539A1 (ja) | 2005-12-09 | 2007-06-14 | Idemitsu Kosan Co., Ltd. | リチウムイオン伝導性硫化物系固体電解質及びそれを用いた全固体リチウム電池 |
| DE102007048289A1 (de) | 2007-10-08 | 2009-04-09 | Universität Siegen | Lithium-Argyrodite |
| JP5396033B2 (ja) | 2007-10-11 | 2014-01-22 | 出光興産株式会社 | 硫化物系固体電解質の製造方法、全固体リチウム二次電池、全固体リチウム一次電池及びこれらを備えた装置 |
| EP2211415B1 (en) | 2007-10-11 | 2013-11-06 | Idemitsu Kosan Co., Ltd. | Method for producing lithium ion conductive solid electrolyte |
| JP5403925B2 (ja) | 2008-03-04 | 2014-01-29 | 出光興産株式会社 | 固体電解質及びその製造方法 |
| JP5388468B2 (ja) | 2008-03-26 | 2014-01-15 | 京セラ株式会社 | 支持用キャリア |
| JP5431809B2 (ja) | 2008-07-01 | 2014-03-05 | 出光興産株式会社 | リチウムイオン伝導性硫化物ガラスの製造方法、リチウムイオン伝導性硫化物ガラスセラミックスの製造方法及び硫化物ガラス製造用のメカニカルミリング処理装置 |
| JP5577028B2 (ja) | 2008-10-09 | 2014-08-20 | 出光興産株式会社 | 硫化物系固体電解質の製造方法 |
| JP5396239B2 (ja) | 2008-11-17 | 2014-01-22 | 出光興産株式会社 | 固体電解質の製造装置及び製造方法 |
| JP5460283B2 (ja) | 2008-12-15 | 2014-04-02 | 出光興産株式会社 | 硫化リチウムの製造方法 |
| JP5485716B2 (ja) | 2009-01-15 | 2014-05-07 | 出光興産株式会社 | リチウムイオン伝導性固体電解質の製造方法 |
| JP5448038B2 (ja) | 2009-02-27 | 2014-03-19 | 公立大学法人大阪府立大学 | 硫化物固体電解質材料 |
| JP5313761B2 (ja) | 2009-05-08 | 2013-10-09 | パナソニック株式会社 | リチウムイオン電池 |
| JP2010270191A (ja) | 2009-05-20 | 2010-12-02 | Tokuyama Corp | コーティング組成物および光学物品 |
| JP2011096630A (ja) * | 2009-10-02 | 2011-05-12 | Sanyo Electric Co Ltd | 固体リチウム二次電池及びその製造方法 |
| JP2011113796A (ja) | 2009-11-26 | 2011-06-09 | Nippon Chem Ind Co Ltd | リチウム二次電池用活物質およびこれを用いたリチウム二次電池 |
| JP5349427B2 (ja) | 2010-08-26 | 2013-11-20 | トヨタ自動車株式会社 | 硫化物固体電解質材料、正極体およびリチウム固体電池 |
| JP5521899B2 (ja) | 2010-08-26 | 2014-06-18 | トヨタ自動車株式会社 | 硫化物固体電解質材料およびリチウム固体電池 |
| JP5553004B2 (ja) * | 2010-11-08 | 2014-07-16 | トヨタ自動車株式会社 | 硫化物固体電解質材料、リチウム固体電池、および硫化物固体電解質材料の製造方法 |
| JP5443445B2 (ja) * | 2011-07-06 | 2014-03-19 | トヨタ自動車株式会社 | 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法 |
-
2012
- 2012-06-29 JP JP2012147050A patent/JP6234665B2/ja active Active
- 2012-11-02 WO PCT/JP2012/007053 patent/WO2013069243A1/ja not_active Ceased
- 2012-11-02 CN CN201280054657.5A patent/CN104025363B/zh active Active
- 2012-11-02 US US14/355,715 patent/US9620811B2/en active Active
- 2012-11-02 KR KR1020147011569A patent/KR101973827B1/ko active Active
- 2012-11-02 AU AU2012333924A patent/AU2012333924A1/en not_active Abandoned
- 2012-11-02 EP EP18158213.1A patent/EP3361545B1/en active Active
- 2012-11-02 CA CA2854596A patent/CA2854596C/en active Active
- 2012-11-02 EP EP12846932.7A patent/EP2779298B1/en active Active
- 2012-11-07 TW TW101141356A patent/TWI586021B/zh active
-
2017
- 2017-02-27 US US15/442,800 patent/US9806373B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011124081A (ja) * | 2009-12-10 | 2011-06-23 | Idemitsu Kosan Co Ltd | リチウムイオン伝導性硫化物ガラス及びそれを用いたリチウムイオン電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104025363B (zh) | 2017-08-25 |
| EP2779298A4 (en) | 2015-09-30 |
| CA2854596C (en) | 2019-12-31 |
| US20170194662A1 (en) | 2017-07-06 |
| EP2779298B1 (en) | 2018-04-11 |
| CA2854596A1 (en) | 2013-05-16 |
| AU2012333924A1 (en) | 2014-05-22 |
| US9806373B2 (en) | 2017-10-31 |
| KR20140096273A (ko) | 2014-08-05 |
| WO2013069243A1 (ja) | 2013-05-16 |
| US9620811B2 (en) | 2017-04-11 |
| JP6234665B2 (ja) | 2017-11-22 |
| US20140302382A1 (en) | 2014-10-09 |
| EP3361545B1 (en) | 2020-06-24 |
| EP3361545A1 (en) | 2018-08-15 |
| CN104025363A (zh) | 2014-09-03 |
| EP2779298A1 (en) | 2014-09-17 |
| KR101973827B1 (ko) | 2019-04-29 |
| JP2013201110A (ja) | 2013-10-03 |
| TW201336149A (zh) | 2013-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI586021B (zh) | Solid electrolyte | |
| US10090558B2 (en) | Solid electrolyte | |
| JP6077740B2 (ja) | 固体電解質 | |
| TWI591886B (zh) | Positive mix | |
| JP6073107B2 (ja) | 固体電解質 | |
| JP6139864B2 (ja) | 固体電解質成形体及びその製造方法、並びに全固体電池 | |
| JP6088797B2 (ja) | 固体電解質 | |
| JP6518745B2 (ja) | 結晶化固体電解質 | |
| KR20230060541A (ko) | 황화물 고체 전해질 | |
| JP2014093263A (ja) | 固体電解質及びリチウム電池 | |
| CN107710347A (zh) | 固体电解质的制造方法 | |
| JP2014192093A (ja) | 負極合材 | |
| JP6373417B2 (ja) | 固体電解質 | |
| JP2014091664A (ja) | 固体電解質ガラス粒子及びリチウムイオン電池 |