JP2007532762A5 - - Google Patents

Info

Publication number

JP2007532762A5

JP2007532762A5 JP2007508539A JP2007508539A JP2007532762A5 JP 2007532762 A5 JP2007532762 A5 JP 2007532762A5 JP 2007508539 A JP2007508539 A JP 2007508539A JP 2007508539 A JP2007508539 A JP 2007508539A JP 2007532762 A5 JP2007532762 A5 JP 2007532762A5

Authority

JP

Japan

Prior art keywords

zrme

rac

activated

indenyl

pentafluorophenyl

Prior art date

2005-04-13

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Links

• Espacenet
• Global Dossier
• Discuss

• -1 methylene (cyclopentadienyl) (3,8-di - tert-butyl - fluorenyl) Chemical group 0.000 claims description 569
• YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 116
• 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 116
• 229910052735 hafnium Inorganic materials 0.000 claims description 69
• 239000003054 catalyst Substances 0.000 claims description 19
• 238000004519 manufacturing process Methods 0.000 claims description 7
• ZOICEQJZAWJHSI-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)boron Chemical compound [B]C1=C(F)C(F)=C(F)C(F)=C1F ZOICEQJZAWJHSI-UHFFFAOYSA-N 0.000 claims 54
• NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 54
• 229910007926 ZrCl Inorganic materials 0.000 claims 43
• 239000012190 activator Substances 0.000 claims 30
• JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 claims 27
• 150000001450 anions Chemical class 0.000 claims 21
• 238000006243 chemical reaction Methods 0.000 claims 11
• 150000001336 alkenes Chemical class 0.000 claims 7
• 125000000129 anionic group Chemical group 0.000 claims 6
• 229920000642 polymer Polymers 0.000 claims 6
• 238000000034 method Methods 0.000 claims 5
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
• 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 2
• 239000012071 phase Substances 0.000 claims 2
• 238000006116 polymerization reaction Methods 0.000 claims 2
• 229920000098 polyolefin Polymers 0.000 claims 2
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 2
• YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 1
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
• 239000005977 Ethylene Substances 0.000 claims 1
• 230000003213 activating effect Effects 0.000 claims 1
• 230000004913 activation Effects 0.000 claims 1
• 125000005626 carbonium group Chemical group 0.000 claims 1
• 239000003795 chemical substances by application Substances 0.000 claims 1
• 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 1
• ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 1
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
• 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
• 239000007791 liquid phase Substances 0.000 claims 1
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
• 239000002002 slurry Substances 0.000 claims 1
• 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
• 239000004711 α-olefin Substances 0.000 claims 1
• 229910052726 zirconium Inorganic materials 0.000 description 163
• VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 158
• KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 63
• 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 60
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 56
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 55
• 239000012968 metallocene catalyst Substances 0.000 description 3
• KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
• 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
• NJYTVNWDHPUNTD-UHFFFAOYSA-N 2-methyl-1-[(2-methyl-4-phenyl-1h-inden-1-yl)methyl]-4-phenyl-1h-indene Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1CC1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NJYTVNWDHPUNTD-UHFFFAOYSA-N 0.000 description 1
• ASGNRCDZSRNHOP-UHFFFAOYSA-N 2-methyl-4-phenyl-1h-indene Chemical compound C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 ASGNRCDZSRNHOP-UHFFFAOYSA-N 0.000 description 1
• MWZISNRLKLPKMO-UHFFFAOYSA-L C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(=C)C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=CC=CC2=C1 Chemical compound C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(=C)C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=CC=CC2=C1 MWZISNRLKLPKMO-UHFFFAOYSA-L 0.000 description 1
• HCDYOWWRPRWLBK-UHFFFAOYSA-L C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)[SiH](C)C)=CC=CC2=C1 Chemical compound C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)[SiH](C)C)=CC=CC2=C1 HCDYOWWRPRWLBK-UHFFFAOYSA-L 0.000 description 1
• OITLQHFSFQHOLH-UHFFFAOYSA-N CC(C(C1=CC=C2)[Hf](C)(C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl Chemical compound CC(C(C1=CC=C2)[Hf](C)(C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl OITLQHFSFQHOLH-UHFFFAOYSA-N 0.000 description 1
• QEEPLEFBPYDQON-UHFFFAOYSA-N CC(C(C1=CC=C2)[Zr](C)(C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl Chemical compound CC(C(C1=CC=C2)[Zr](C)(C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl QEEPLEFBPYDQON-UHFFFAOYSA-N 0.000 description 1
• JSFCROZLEHMLRW-UHFFFAOYSA-N CC(C(C1=CC=C2)[Zr](C)(C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC=C1.Cl.Cl Chemical compound CC(C(C1=CC=C2)[Zr](C)(C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)[SiH2]C3=CC=CC=C3)=CC1=C2C1=CC=CC=C1.Cl.Cl JSFCROZLEHMLRW-UHFFFAOYSA-N 0.000 description 1
• ORLOFKMUOFCWGQ-UHFFFAOYSA-N CC1=C(C(C=C2)[Hf](C)(C3C4=C(C)C=CC(C)=C4C=C3)[SiH2]C3=CC=CC=C3)C2=C(C)C=C1.Cl.Cl Chemical compound CC1=C(C(C=C2)[Hf](C)(C3C4=C(C)C=CC(C)=C4C=C3)[SiH2]C3=CC=CC=C3)C2=C(C)C=C1.Cl.Cl ORLOFKMUOFCWGQ-UHFFFAOYSA-N 0.000 description 1
• UCSPDPQSCVXVHY-UHFFFAOYSA-N CC1=C(C(C=C2)[Zr](C)(C3C4=C(C)C=CC(C)=C4C=C3)[SiH2]C3=CC=CC=C3)C2=C(C)C=C1.Cl.Cl Chemical compound CC1=C(C(C=C2)[Zr](C)(C3C4=C(C)C=CC(C)=C4C=C3)[SiH2]C3=CC=CC=C3)C2=C(C)C=C1.Cl.Cl UCSPDPQSCVXVHY-UHFFFAOYSA-N 0.000 description 1
• WSCXFHUAMAAYAP-UHFFFAOYSA-L CC1=C(C)C(C=C1)[Hf](Cl)(Cl)(=C)C1C=CC(C)=C1C Chemical compound CC1=C(C)C(C=C1)[Hf](Cl)(Cl)(=C)C1C=CC(C)=C1C WSCXFHUAMAAYAP-UHFFFAOYSA-L 0.000 description 1
• CCRSBAPACFWDLW-UHFFFAOYSA-L CC1=C(C)C(C=C1)[Hf](Cl)(Cl)(C1C=CC(C)=C1C)[SiH](C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound CC1=C(C)C(C=C1)[Hf](Cl)(Cl)(C1C=CC(C)=C1C)[SiH](C1=CC=CC=C1)C1=CC=CC=C1 CCRSBAPACFWDLW-UHFFFAOYSA-L 0.000 description 1
• CAWJOXPONCTULN-UHFFFAOYSA-L CC1=C(C)C(C=C1)[Zr](Cl)(Cl)(=C)C1C=CC(C)=C1C Chemical compound CC1=C(C)C(C=C1)[Zr](Cl)(Cl)(=C)C1C=CC(C)=C1C CAWJOXPONCTULN-UHFFFAOYSA-L 0.000 description 1
• MHJAPSRCDXSJHN-UHFFFAOYSA-N CC1=C(C)C=CC1[Hf](C)(C1C(C)=C(C)C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound CC1=C(C)C=CC1[Hf](C)(C1C(C)=C(C)C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl MHJAPSRCDXSJHN-UHFFFAOYSA-N 0.000 description 1
• DRJBONPCHLZUKH-UHFFFAOYSA-N CC1=C(C)C=CC1[Zr](C)(C1C(C)=C(C)C=C1)[SiH2]C1=CC=CC=C1.Cl Chemical compound CC1=C(C)C=CC1[Zr](C)(C1C(C)=C(C)C=C1)[SiH2]C1=CC=CC=C1.Cl DRJBONPCHLZUKH-UHFFFAOYSA-N 0.000 description 1
• JGLHDILSBOSJPM-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C4=CC=CC=C4C=CC=3)=C2C1[Zr](Cl)(Cl)(C1C2=C(C(=CC=C2)C=2C3=CC=CC=C3C=CC=2)C=C1C)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C4=CC=CC=C4C=CC=3)=C2C1[Zr](Cl)(Cl)(C1C2=C(C(=CC=C2)C=2C3=CC=CC=C3C=CC=2)C=C1C)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 JGLHDILSBOSJPM-UHFFFAOYSA-L 0.000 description 1
• XLCYGAPESVMMLC-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Hf](Cl)(Cl)([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Hf](Cl)(Cl)([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 XLCYGAPESVMMLC-UHFFFAOYSA-L 0.000 description 1
• BOOHTEYYVQAWMD-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Hf](C)(C1C2=CC=CC=C2C=C1C)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound CC1=CC2=CC=CC=C2C1[Hf](C)(C1C2=CC=CC=C2C=C1C)[SiH2]C1=CC=CC=C1.Cl.Cl BOOHTEYYVQAWMD-UHFFFAOYSA-N 0.000 description 1
• PCEUKHDUMPARIN-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr](C)(C1C2=CC=CC=C2C=C1C)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound CC1=CC2=CC=CC=C2C1[Zr](C)(C1C2=CC=CC=C2C=C1C)[SiH2]C1=CC=CC=C1.Cl.Cl PCEUKHDUMPARIN-UHFFFAOYSA-N 0.000 description 1
• GYZFAUWZGBCUNJ-UHFFFAOYSA-L CC1=Cc2c(cccc2-c2cccc3ccccc23)C1[Hf](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1cccc2ccccc12)[SiH](c1ccccc1)c1ccccc1 Chemical compound CC1=Cc2c(cccc2-c2cccc3ccccc23)C1[Hf](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1cccc2ccccc12)[SiH](c1ccccc1)c1ccccc1 GYZFAUWZGBCUNJ-UHFFFAOYSA-L 0.000 description 1
• XKSFSOKJDSMNPI-UHFFFAOYSA-N C[Hf](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound C[Hf](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl XKSFSOKJDSMNPI-UHFFFAOYSA-N 0.000 description 1
• IJCJZGOYNJFVFH-UHFFFAOYSA-N C[Hf](C1C2=CC=CCC2CC1)(C1C2=CC=CCC2CC1)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound C[Hf](C1C2=CC=CCC2CC1)(C1C2=CC=CCC2CC1)[SiH2]C1=CC=CC=C1.Cl.Cl IJCJZGOYNJFVFH-UHFFFAOYSA-N 0.000 description 1
• CBNBXEOXXQZEII-UHFFFAOYSA-L C[SiH](C)[Hf](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)C1C=CC(=C1)[Si](C)(C)C Chemical compound C[SiH](C)[Hf](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)C1C=CC(=C1)[Si](C)(C)C CBNBXEOXXQZEII-UHFFFAOYSA-L 0.000 description 1
• UUWXZXQQDWGCFP-UHFFFAOYSA-L C[SiH](C)[Zr](Cl)(Cl)(C1C=C(C)C(C)=C1)C1C=C(C)C(C)=C1 Chemical compound C[SiH](C)[Zr](Cl)(Cl)(C1C=C(C)C(C)=C1)C1C=C(C)C(C)=C1 UUWXZXQQDWGCFP-UHFFFAOYSA-L 0.000 description 1
• IMNMCKQOOMHUAG-UHFFFAOYSA-L C[SiH](C)[Zr](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)C1C=CC(=C1)[Si](C)(C)C Chemical compound C[SiH](C)[Zr](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)C1C=CC(=C1)[Si](C)(C)C IMNMCKQOOMHUAG-UHFFFAOYSA-L 0.000 description 1
• SAKIGWJZTZKOAW-UHFFFAOYSA-N C[Si](C)(C)C(C=C1)=CC1[Hf](C)(C(C=C1)C=C1[Si](C)(C)C)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound C[Si](C)(C)C(C=C1)=CC1[Hf](C)(C(C=C1)C=C1[Si](C)(C)C)[SiH2]C1=CC=CC=C1.Cl.Cl SAKIGWJZTZKOAW-UHFFFAOYSA-N 0.000 description 1
• YDUGOSCRXWZULO-UHFFFAOYSA-L C[Si](C)(C)C1=CC(C=C1)[Hf](Cl)(Cl)(=C)C1C=CC(=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1=CC(C=C1)[Hf](Cl)(Cl)(=C)C1C=CC(=C1)[Si](C)(C)C YDUGOSCRXWZULO-UHFFFAOYSA-L 0.000 description 1
• VGVYFPUCSRFSOV-UHFFFAOYSA-L C[Si](C)(C)C1=CC(C=C1)[Zr](Cl)(Cl)(=C)C1C=CC(=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1=CC(C=C1)[Zr](Cl)(Cl)(=C)C1C=CC(=C1)[Si](C)(C)C VGVYFPUCSRFSOV-UHFFFAOYSA-L 0.000 description 1
• ZJWSEPWXSAVQPE-UHFFFAOYSA-L C[Si](C)(C)C1=CC(C=C1)[Zr](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)[SiH](C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C[Si](C)(C)C1=CC(C=C1)[Zr](Cl)(Cl)(C1C=CC(=C1)[Si](C)(C)C)[SiH](C1=CC=CC=C1)C1=CC=CC=C1 ZJWSEPWXSAVQPE-UHFFFAOYSA-L 0.000 description 1
• FPUALFQZGDMNAT-UHFFFAOYSA-N C[Zr](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound C[Zr](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH2]C1=CC=CC=C1.Cl.Cl FPUALFQZGDMNAT-UHFFFAOYSA-N 0.000 description 1
• FEMGAXGLTIYWRE-UHFFFAOYSA-N C[Zr](C1C2=CC=CCC2CC1)(C1C2=CC=CCC2CC1)[SiH2]C1=CC=CC=C1.Cl.Cl Chemical compound C[Zr](C1C2=CC=CCC2CC1)(C1C2=CC=CCC2CC1)[SiH2]C1=CC=CC=C1.Cl.Cl FEMGAXGLTIYWRE-UHFFFAOYSA-N 0.000 description 1
• YHYHCGCMYMMXAH-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr+2](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr+2](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12 YHYHCGCMYMMXAH-UHFFFAOYSA-L 0.000 description 1
• GVMCJEXOZRLPKR-UHFFFAOYSA-L [Cl-].[Cl-].C1(CCC2CC=CC=C12)[Hf+2]C1CCC2CC=CC=C12.C=C Chemical compound [Cl-].[Cl-].C1(CCC2CC=CC=C12)[Hf+2]C1CCC2CC=CC=C12.C=C GVMCJEXOZRLPKR-UHFFFAOYSA-L 0.000 description 1
• NFNBXPIIOMPJQE-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Hf+2](=C)C1C(C(C)=CC=C2C)=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Hf+2](=C)C1C(C(C)=CC=C2C)=C2C=C1 NFNBXPIIOMPJQE-UHFFFAOYSA-L 0.000 description 1
• KNRYBQYJVYZOQB-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Zr+2](=C)C1C(C(C)=CC=C2C)=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Zr+2](=C)C1C(C(C)=CC=C2C)=C2C=C1 KNRYBQYJVYZOQB-UHFFFAOYSA-L 0.000 description 1
• IGSPQDBOJOXEJJ-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](=C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](=C)C1C2=CC=CC=C2C=C1 IGSPQDBOJOXEJJ-UHFFFAOYSA-L 0.000 description 1
• BWUKAWLFMALYIV-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 BWUKAWLFMALYIV-UHFFFAOYSA-L 0.000 description 1
• SGJOMARGPMMNKC-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 SGJOMARGPMMNKC-UHFFFAOYSA-L 0.000 description 1
• ZUGAYUSVYHLKDE-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C)C1C2=CC=CC=C2C=C1 ZUGAYUSVYHLKDE-UHFFFAOYSA-L 0.000 description 1
• DHOIFLAXQKMNNF-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 DHOIFLAXQKMNNF-UHFFFAOYSA-L 0.000 description 1
• FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
• IPFOHNSBHKSSCX-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Hf+2](=C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Hf+2](=C)C1C2=CC=CCC2CC1 IPFOHNSBHKSSCX-UHFFFAOYSA-L 0.000 description 1
• IGCCPSZEERPJNE-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CCC2CC1 IGCCPSZEERPJNE-UHFFFAOYSA-L 0.000 description 1
• QHHXDHRTYCUORU-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2](=C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2](=C)C1C2=CC=CCC2CC1 QHHXDHRTYCUORU-UHFFFAOYSA-L 0.000 description 1
• RLEZACANRPOGPQ-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 RLEZACANRPOGPQ-UHFFFAOYSA-L 0.000 description 1
• QSZGOMRHQRFORD-UHFFFAOYSA-L [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 QSZGOMRHQRFORD-UHFFFAOYSA-L 0.000 description 1
• RNGXLYVWHJFMBW-UHFFFAOYSA-L [Cl-].[Cl-].C=[Hf+2](C1C(=CC2=C(C=CC=C12)C1=CC=CC2=CC=CC=C12)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC2=CC=CC=C12)C Chemical compound [Cl-].[Cl-].C=[Hf+2](C1C(=CC2=C(C=CC=C12)C1=CC=CC2=CC=CC=C12)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC2=CC=CC=C12)C RNGXLYVWHJFMBW-UHFFFAOYSA-L 0.000 description 1
• AMYIOBGYBIXLFE-UHFFFAOYSA-L [Cl-].[Cl-].CC([SiH](C)[Zr+](C1C=CC2=C(C=CC(=C12)C)C)C1C=CC2=C(C=CC(=C12)C)C)C.C=[Hf](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C.CC(C)[SiH](C)[Zr+](C1C=CC2=C(C=CC(=C12)C)C)C1C=CC2=C(C=CC(=C12)C)C Chemical compound [Cl-].[Cl-].CC([SiH](C)[Zr+](C1C=CC2=C(C=CC(=C12)C)C)C1C=CC2=C(C=CC(=C12)C)C)C.C=[Hf](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C.CC(C)[SiH](C)[Zr+](C1C=CC2=C(C=CC(=C12)C)C)C1C=CC2=C(C=CC(=C12)C)C AMYIOBGYBIXLFE-UHFFFAOYSA-L 0.000 description 1
• OYKIBEVXOHBLAP-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Hf+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C OYKIBEVXOHBLAP-UHFFFAOYSA-L 0.000 description 1
• MOMFNNODEDMKRW-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2](=C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2](=C)C1C2=CC=CC=C2C=C1C MOMFNNODEDMKRW-UHFFFAOYSA-L 0.000 description 1
• LEOYKWIXWJXYQJ-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C LEOYKWIXWJXYQJ-UHFFFAOYSA-L 0.000 description 1
• IVZHJEOMGNUPTC-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Hf++](=C)C1C(C)=Cc2c1cccc2-c1ccccc1 Chemical compound [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Hf++](=C)C1C(C)=Cc2c1cccc2-c1ccccc1 IVZHJEOMGNUPTC-UHFFFAOYSA-L 0.000 description 1
• KLOBHLFYIOQEOF-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Hf++](C1C(C)=Cc2c1cccc2-c1ccccc1)[SiH](c1ccccc1)c1ccccc1 Chemical compound [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Hf++](C1C(C)=Cc2c1cccc2-c1ccccc1)[SiH](c1ccccc1)c1ccccc1 KLOBHLFYIOQEOF-UHFFFAOYSA-L 0.000 description 1
• WKWATPQNSRSHDL-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2ccccc2C1[Hf++](=C)C1C(C)=Cc2ccccc12 Chemical compound [Cl-].[Cl-].CC1=Cc2ccccc2C1[Hf++](=C)C1C(C)=Cc2ccccc12 WKWATPQNSRSHDL-UHFFFAOYSA-L 0.000 description 1
• YXIARWMBTNXPAN-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(=C(C=CC1)[SiH](C1=CC=CC=C1)[Hf+](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12)C.C[SiH](C)[Hf+](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12 Chemical compound [Cl-].[Cl-].CC=1C(=C(C=CC1)[SiH](C1=CC=CC=C1)[Hf+](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12)C.C[SiH](C)[Hf+](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12 YXIARWMBTNXPAN-UHFFFAOYSA-L 0.000 description 1
• HMAVCOLCFIQXFY-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C=CC1C)[Hf+2]C1C(=C(C=C1)C)C.C=C Chemical compound [Cl-].[Cl-].CC=1C(C=CC1C)[Hf+2]C1C(=C(C=C1)C)C.C=C HMAVCOLCFIQXFY-UHFFFAOYSA-L 0.000 description 1
• HWESFSSIAPADSJ-UHFFFAOYSA-L [Cl-].[Cl-].C[SiH](C)[Hf++](C1C=Cc2c1c(C)ccc2C)C1C=Cc2c1c(C)ccc2C Chemical compound [Cl-].[Cl-].C[SiH](C)[Hf++](C1C=Cc2c1c(C)ccc2C)C1C=Cc2c1c(C)ccc2C HWESFSSIAPADSJ-UHFFFAOYSA-L 0.000 description 1
• VOESPWUATJENDM-UHFFFAOYSA-L [Cl-].[Cl-].C[SiH](C)[Hf+2](C1(C(=CC=C1)C)C)C1(C(=CC=C1)C)C Chemical compound [Cl-].[Cl-].C[SiH](C)[Hf+2](C1(C(=CC=C1)C)C)C1(C(=CC=C1)C)C VOESPWUATJENDM-UHFFFAOYSA-L 0.000 description 1
• TYGPYZGVLXKYCG-UHFFFAOYSA-L [Cl-].[Cl-].Cc1ccc(C)c2C(C=Cc12)[Hf++](C1C=Cc2c1c(C)ccc2C)[SiH](c1ccccc1)c1ccccc1 Chemical compound [Cl-].[Cl-].Cc1ccc(C)c2C(C=Cc12)[Hf++](C1C=Cc2c1c(C)ccc2C)[SiH](c1ccccc1)c1ccccc1 TYGPYZGVLXKYCG-UHFFFAOYSA-L 0.000 description 1
• PCRVPTVYRLHWKZ-UHFFFAOYSA-L [Cl-].[Cl-].Cc1ccc(C)c2C(C=Cc12)[Zr++](C1C=Cc2c1c(C)ccc2C)[SiH](c1ccccc1)c1ccccc1 Chemical compound [Cl-].[Cl-].Cc1ccc(C)c2C(C=Cc12)[Zr++](C1C=Cc2c1c(C)ccc2C)[SiH](c1ccccc1)c1ccccc1 PCRVPTVYRLHWKZ-UHFFFAOYSA-L 0.000 description 1
• LNKNUAVVTPSYIK-UHFFFAOYSA-N [Cl].[Cl].[Zr] Chemical compound [Cl].[Cl].[Zr] LNKNUAVVTPSYIK-UHFFFAOYSA-N 0.000 description 1
• ZHFFGBNOSGNGDM-UHFFFAOYSA-N carbanide hafnium(4+) inden-3a-id-1-yl-inden-1-id-1-yl-dimethylsilane Chemical group [CH3-].[CH3-].[Hf+4].C[Si](C)([c-]1ccc2ccccc12)[c-]1ccc2ccccc12 ZHFFGBNOSGNGDM-UHFFFAOYSA-N 0.000 description 1
• 150000001875 compounds Chemical class 0.000 description 1
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
• 229920013639 polyalphaolefin Polymers 0.000 description 1
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
• 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1