ES2178648T3 - Polietileno, composicion de resina termoplastica que lo contiene, y procedimiento de produccion de polietileno. - Google Patents
Polietileno, composicion de resina termoplastica que lo contiene, y procedimiento de produccion de polietileno.Info
- Publication number
- ES2178648T3 ES2178648T3 ES94905848T ES94905848T ES2178648T3 ES 2178648 T3 ES2178648 T3 ES 2178648T3 ES 94905848 T ES94905848 T ES 94905848T ES 94905848 T ES94905848 T ES 94905848T ES 2178648 T3 ES2178648 T3 ES 2178648T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- relationship
- polyethylene
- formula
- ldpe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Abstract
SE PRESENTAN POLIMEROS DERIVADOS DE MONOMERO DE ETILENO, QUE NO CONTIENEN CARBONO CUATERNARIO EN LA CADENA PRINCIPAL Y QUE TIENE UNA ENERGIA DE ACTIVACION (EA) DE FLUJO EN ESTADO FUNDIDO DE 8-20 KCAL/MOL, Y EN DONDE (1) LA CONSTANTE DE HUGGINS (K) Y LA VISCOSIDAD LIMITE [{ET}] SATISFACEN LA RELACION DE LA FORMULA: K >= 0.2 + 0.0743 X [{ET}], O (2) LA RELACION DE MOL DE LOS GRUPOS DE METIL CON RESPECTO A LOS GRUPOS DE METILENO EN LA CADENA MOLECULAR, [CH{SUB, 3}/CH{SUB, 2}], ES ENTRE 0.005 Y 0.1 Y SATISFACE LA RELACION DE LA FORMULA: TM >= 131 - 1340 {CH{SUB, 3}/CH{SUB, 2}], O (3) EL MW Y LA PROPORCION DE ENROSAMIENTO DEL TROQUEL (DR) SATISFACE LA RELACION DE LA FORMULA: DR > 0.5 + 0.125 X LOG MW, O (4) UN PICO DE DISPERSION {BE} ESTA PRESENTE EN UNA BANDA DE TEMPERATURA DE ENTRE 0 (GRADOS) Y 100 (GRADOS) C EN LA MEDIDA DEL MODULO DE PERDIDA. ESTOS POLIETILENOS SON DIFERENTES DE LOS HDPE, L-LDPE Y LDPE ORIDINARIOS, Y SE CARACTERIZAN EN QUE TIENEN UNA EXCELENTE PROCESABILIDAD Y SON CAPACES DECONTROLAR DIFERENTES PROPIEDADES, TALES COMO LA DENSIDAD, EL PUNTO DE FUSION Y LA CRISTALINIDAD, PRINCIPAL POR EL POLIETILENO MISMO.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1897793 | 1993-02-05 | ||
JP3202193 | 1993-02-22 | ||
JP19497293A JP3444430B2 (ja) | 1993-08-05 | 1993-08-05 | エチレン重合体及びそれを含有する熱可塑性樹脂組成物 |
JP22920093A JPH0782322A (ja) | 1993-09-14 | 1993-09-14 | エチレン重合体及びそれを含有する熱可塑性樹脂組成物 |
JP26478993A JPH07118343A (ja) | 1993-10-22 | 1993-10-22 | エチレン重合体及びそれを含有する熱可塑性樹脂組成物 |
PCT/JP1994/000168 WO1994018250A1 (en) | 1993-02-05 | 1994-02-04 | Polyethylene, thermoplastic resin composition containing the same, and process for producing polyethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2178648T3 true ES2178648T3 (es) | 2003-01-01 |
Family
ID=27520096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94905848T Expired - Lifetime ES2178648T3 (es) | 1993-02-05 | 1994-02-04 | Polietileno, composicion de resina termoplastica que lo contiene, y procedimiento de produccion de polietileno. |
Country Status (5)
Country | Link |
---|---|
US (1) | US6121402A (es) |
EP (1) | EP0683184B1 (es) |
DE (1) | DE69430795T2 (es) |
ES (1) | ES2178648T3 (es) |
WO (1) | WO1994018250A1 (es) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6114477A (en) * | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
KR100699623B1 (ko) | 1999-07-26 | 2007-03-23 | 이데미쓰 고산 가부시키가이샤 | 올레핀계 분지상 매크로모노머, 올레핀계 그래프트공중합체 및 올레핀계 수지 조성물 |
US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
US6852809B2 (en) * | 1999-12-27 | 2005-02-08 | Sumitomo Chemical Company, Limited | Catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer |
US6875719B2 (en) * | 2000-04-27 | 2005-04-05 | Industrial Technology Research Institute | Catalyst composition for preparing olefin polymers |
WO2002008304A1 (fr) | 2000-07-24 | 2002-01-31 | Idemitsu Petrochemical Co., Ltd. | Homopolymere de propylene et copolymere de propylene |
US6995229B2 (en) * | 2000-07-26 | 2006-02-07 | Mitsui Chemicals, Inc. | Polymer and process for producing the same |
US6891018B2 (en) | 2000-07-26 | 2005-05-10 | Mitsui Chemicals, Inc. | Ethylene copolymer and uses thereof |
US7531605B2 (en) | 2001-03-12 | 2009-05-12 | Idemitsu Kosan Co., Ltd. | Process for producing polyolefin resin composition and polypropylene composition |
EP1391498B1 (en) * | 2001-05-08 | 2016-09-07 | Sanyo Chemical Industries, Ltd. | Fluidity improver and fuel oil composition |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
JP4903357B2 (ja) * | 2003-03-28 | 2012-03-28 | 住友化学株式会社 | エチレン重合体 |
US7863379B2 (en) * | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
US7662881B2 (en) * | 2004-03-17 | 2010-02-16 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
US7803728B2 (en) * | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
US7582716B2 (en) * | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
US7579408B2 (en) * | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
US7795321B2 (en) * | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
US7666918B2 (en) * | 2004-03-17 | 2010-02-23 | Dow Global Technologies, Inc. | Foams made from interpolymers of ethylene/α-olefins |
US8273838B2 (en) * | 2004-03-17 | 2012-09-25 | Dow Global Technologies Llc | Propylene/α-olefins block interpolymers |
US7671106B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
AR053693A1 (es) | 2004-03-17 | 2007-05-16 | Dow Global Technologies Inc | Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas |
US7355089B2 (en) * | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7671131B2 (en) * | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
US7622529B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
US7741397B2 (en) * | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
US7622179B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof |
US7687442B2 (en) * | 2004-03-17 | 2010-03-30 | Dow Global Technologies Inc. | Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils |
SG151302A1 (en) * | 2004-03-17 | 2009-04-30 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi- block copolymer formation |
US7897689B2 (en) * | 2004-03-17 | 2011-03-01 | Dow Global Technologies Inc. | Functionalized ethylene/α-olefin interpolymer compositions |
US7608668B2 (en) * | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
WO2005090427A2 (en) | 2004-03-17 | 2005-09-29 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
JP4655509B2 (ja) | 2004-05-13 | 2011-03-23 | 住友化学株式会社 | 接触処理物、付加重合用触媒成分、付加重合用触媒および付加重合体の製造方法 |
BRPI0609851B1 (pt) * | 2005-03-17 | 2016-12-13 | Dow Global Technologies Inc | fibra obtenível de ou compreendendo um interpolímero de etileno/(alfa)-olefina, fibra obtenível de ou compreendendo pelo menos um interpolímero de etileno e uma (alfa)-olefina de c3-c20, pano, fio e método para fabricar uma fibra ou pano |
CN101287772B (zh) | 2005-03-17 | 2014-09-24 | 陶氏环球技术有限责任公司 | 用于弹性膜和层压材料的乙烯/α-烯烃多嵌段共聚体的组合物 |
US8084537B2 (en) * | 2005-03-17 | 2011-12-27 | Dow Global Technologies Llc | Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility |
WO2006102150A2 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins |
BRPI0617041B1 (pt) | 2005-09-15 | 2018-01-30 | Dow Global Technologies Inc. | PROCESSO PARA PREPARAR UM POLÍMERO DIFUNCIONAL EM a, ?" |
ES2526056T3 (es) * | 2005-09-15 | 2015-01-05 | Dow Global Technologies Llc | Copolímeros de bloque de olefinas catalíticos por medio de agente de transporte polimerizable |
KR20080060289A (ko) * | 2005-10-26 | 2008-07-01 | 다우 글로벌 테크놀로지스 인크. | 다층 탄성 물품 |
US8153243B2 (en) * | 2005-12-09 | 2012-04-10 | Dow Global Technologies Llc | Interpolymers suitable for multilayer films |
AR058852A1 (es) * | 2005-12-09 | 2008-02-27 | Dow Global Technologies Inc | Procesos para controlar la distribucion del peso molecular en las composiciones de etileno/alfa olefina |
TW200829745A (en) * | 2006-09-06 | 2008-07-16 | Dow Global Technologies Inc | Fibers and knit fabrics comprising olefin block interpolymers |
AU2007325015A1 (en) * | 2006-11-30 | 2008-06-05 | Dow Global Technologies Inc. | Fabric comprising elastic fibres of cross-linked ethylene polymer |
BRPI0717718A2 (pt) | 2006-11-30 | 2013-10-22 | Dow Global Technologies Inc | "tecido estirável capaz de ser submetido a um tratamento antienrugamento e peça de vestuario" |
EP2084313A1 (en) * | 2006-11-30 | 2009-08-05 | Dow Global Technologies Inc. | Olefin block compositions for heavy weight stretch fabrics |
BRPI0806194A2 (pt) * | 2007-01-16 | 2011-08-30 | Dow Global Technologies Inc | fio tingido em cone |
JP2010516908A (ja) * | 2007-01-16 | 2010-05-20 | ダウ グローバル テクノロジーズ インコーポレイティド | オレフィンブロックポリマーの伸縮性布帛および衣類 |
US20080184498A1 (en) * | 2007-01-16 | 2008-08-07 | Dow Global Technologies Inc. | Colorfast fabrics and garments of olefin block compositions |
WO2009012073A2 (en) * | 2007-07-09 | 2009-01-22 | Dow Global Technologies Inc. | Olefin block interpolymer composition suitable for fibers |
CN101878265A (zh) * | 2007-09-28 | 2010-11-03 | 陶氏环球技术公司 | 具有改善热变形温度的热塑性烯烃组合物 |
EP2799235A1 (en) * | 2007-10-22 | 2014-11-05 | Dow Global Technologies LLC | Multilayer films |
JP5807325B2 (ja) | 2009-09-30 | 2015-11-10 | 住友化学株式会社 | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、1−ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
JP2012214457A (ja) | 2011-03-29 | 2012-11-08 | Sumitomo Chemical Co Ltd | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、1−ヘキセンの製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
JP5900089B2 (ja) | 2011-03-29 | 2016-04-06 | 住友化学株式会社 | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、1−ヘキセンの製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
WO2014157583A1 (ja) * | 2013-03-27 | 2014-10-02 | 日本ポリエチレン株式会社 | 極性基含有オレフィン共重合体、多元系極性基含有オレフィン共重合体及びオレフィン系樹脂組成物並びにそれを利用する接着剤、積層体 |
US11718737B2 (en) | 2018-05-04 | 2023-08-08 | Lg Chem, Ltd. | Ethylene/alpha-olefin copolymer and method for preparing the same |
US11505631B2 (en) | 2018-05-04 | 2022-11-22 | Lg Chem, Ltd. | Ethylene/alpha-olefin copolymer and method for preparing the same |
CN111902438B (zh) | 2018-05-04 | 2023-01-10 | Lg化学株式会社 | 乙烯/α-烯烃共聚物及其制备方法 |
ES2947462T3 (es) | 2018-05-04 | 2023-08-09 | Lg Chemical Ltd | Composición de adhesivo que incluye un copolímero de etileno/alfa-olefina |
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US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4935474A (en) * | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US5155186A (en) * | 1984-12-24 | 1992-10-13 | Phillips Petroleum Company | Ethylene homopolymer and copolymer polymerization process and the products produced therefrom |
US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5028665A (en) * | 1989-01-09 | 1991-07-02 | The Dow Chemical Company | Polymer hydrogenation catalysts |
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
MY107639A (en) * | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
WO1992009640A1 (en) * | 1990-11-30 | 1992-06-11 | Idemitsu Kosan Co., Ltd. | Process for producing olefinic polymer |
US5444134A (en) * | 1991-07-11 | 1995-08-22 | Idemitsu Kosan Co., Ltd. | Process for producing olefin based polymers and olefin polymerization catalyst |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
WO1994007930A1 (en) * | 1992-09-29 | 1994-04-14 | Exxon Chemical Patents Inc. | Long chain branched polymers and a process to make long chain branched polymers |
DE69430910T2 (de) * | 1993-02-22 | 2002-12-12 | Idemitsu Kosan Co | Ethylencopolymer, dieses enthaltende thermoplastische harzzusammensetzung und verfahren zu seiner herstellung |
ATE147748T1 (de) * | 1993-06-24 | 1997-02-15 | Dow Chemical Co | Titan-und zirkoniumkomplexe und diese enthaltende polymerisationskatalysatoren |
-
1994
- 1994-02-04 ES ES94905848T patent/ES2178648T3/es not_active Expired - Lifetime
- 1994-02-04 DE DE69430795T patent/DE69430795T2/de not_active Expired - Fee Related
- 1994-02-04 WO PCT/JP1994/000168 patent/WO1994018250A1/ja active IP Right Grant
- 1994-02-04 EP EP94905848A patent/EP0683184B1/en not_active Expired - Lifetime
-
1998
- 1998-03-23 US US09/045,913 patent/US6121402A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0683184A1 (en) | 1995-11-22 |
WO1994018250A1 (en) | 1994-08-18 |
DE69430795D1 (de) | 2002-07-18 |
DE69430795T2 (de) | 2002-11-28 |
US6121402A (en) | 2000-09-19 |
EP0683184B1 (en) | 2002-06-12 |
EP0683184A4 (en) | 1997-08-20 |
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