JP2007514294A - 大量にドープされたエピタキシャルSiGeを選択的に堆積させる方法 - Google Patents
大量にドープされたエピタキシャルSiGeを選択的に堆積させる方法 Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 152
- 238000000151 deposition Methods 0.000 title claims abstract description 86
- 229910000577 Silicon-germanium Inorganic materials 0.000 title claims abstract description 66
- 239000000758 substrate Substances 0.000 claims abstract description 93
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 55
- 239000010703 silicon Substances 0.000 claims abstract description 55
- 230000008021 deposition Effects 0.000 claims abstract description 54
- 239000012159 carrier gas Substances 0.000 claims abstract description 45
- 239000007789 gas Substances 0.000 claims abstract description 42
- 239000002019 doping agent Substances 0.000 claims abstract description 37
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 37
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 37
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
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- 150000001875 compounds Chemical class 0.000 claims description 39
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
- 229910052799 carbon Inorganic materials 0.000 claims description 22
- 229910052796 boron Inorganic materials 0.000 claims description 16
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- 238000005530 etching Methods 0.000 claims description 14
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- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910003902 SiCl 4 Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 3
- 239000011261 inert gas Substances 0.000 abstract description 2
- 150000003377 silicon compounds Chemical class 0.000 description 90
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 35
- 229910000077 silane Inorganic materials 0.000 description 35
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 32
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 32
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 32
- 125000004429 atom Chemical group 0.000 description 19
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 15
- 229910003811 SiGeC Inorganic materials 0.000 description 13
- 239000004065 semiconductor Substances 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 11
- 235000012431 wafers Nutrition 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 238000005229 chemical vapour deposition Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000012686 silicon precursor Substances 0.000 description 10
- 229910000078 germane Inorganic materials 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 7
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- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 6
- 238000000137 annealing Methods 0.000 description 6
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 6
- 229910021332 silicide Inorganic materials 0.000 description 6
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 6
- 238000000231 atomic layer deposition Methods 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229910021419 crystalline silicon Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- -1 Organosilane compounds Chemical class 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- AXQKVSDUCKWEKE-UHFFFAOYSA-N [C].[Ge].[Si] Chemical compound [C].[Ge].[Si] AXQKVSDUCKWEKE-UHFFFAOYSA-N 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 3
- 238000003877 atomic layer epitaxy Methods 0.000 description 3
- 229910000085 borane Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 239000005001 laminate film Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
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- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 2
- 238000000277 atomic layer chemical vapour deposition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
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- 238000011065 in-situ storage Methods 0.000 description 2
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- 150000004706 metal oxides Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910003465 moissanite Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000002210 silicon-based material Substances 0.000 description 2
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 2
- 238000000038 ultrahigh vacuum chemical vapour deposition Methods 0.000 description 2
- HNEJIUSZPOMSFT-UHFFFAOYSA-N C[GeH2][GeH3] Chemical compound C[GeH2][GeH3] HNEJIUSZPOMSFT-UHFFFAOYSA-N 0.000 description 1
- UFIKLRNUCHZRPW-UHFFFAOYSA-N C[GeH](C)[GeH3] Chemical compound C[GeH](C)[GeH3] UFIKLRNUCHZRPW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
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- BUMGIEFFCMBQDG-UHFFFAOYSA-N dichlorosilicon Chemical compound Cl[Si]Cl BUMGIEFFCMBQDG-UHFFFAOYSA-N 0.000 description 1
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- VZZJVOCVAZHETD-UHFFFAOYSA-N diethylphosphane Chemical compound CCPCC VZZJVOCVAZHETD-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- VXGHASBVNMHGDI-UHFFFAOYSA-N digermane Chemical compound [Ge][Ge] VXGHASBVNMHGDI-UHFFFAOYSA-N 0.000 description 1
- UCMVNBCLTOOHMN-UHFFFAOYSA-N dimethyl(silyl)silane Chemical compound C[SiH](C)[SiH3] UCMVNBCLTOOHMN-UHFFFAOYSA-N 0.000 description 1
- GMLFPSKPTROTFV-UHFFFAOYSA-N dimethylborane Chemical compound CBC GMLFPSKPTROTFV-UHFFFAOYSA-N 0.000 description 1
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- YOTZYFSGUCFUKA-UHFFFAOYSA-N dimethylphosphine Chemical compound CPC YOTZYFSGUCFUKA-UHFFFAOYSA-N 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 description 1
- AIGRXSNSLVJMEA-FQEVSTJZSA-N ethoxy-(4-nitrophenoxy)-phenyl-sulfanylidene-$l^{5}-phosphane Chemical compound O([P@@](=S)(OCC)C=1C=CC=CC=1)C1=CC=C([N+]([O-])=O)C=C1 AIGRXSNSLVJMEA-FQEVSTJZSA-N 0.000 description 1
- SHRMMCOTNQGWJS-UHFFFAOYSA-N ethylgermane Chemical compound CC[GeH3] SHRMMCOTNQGWJS-UHFFFAOYSA-N 0.000 description 1
- KCWYOFZQRFCIIE-UHFFFAOYSA-N ethylsilane Chemical compound CC[SiH3] KCWYOFZQRFCIIE-UHFFFAOYSA-N 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- NEXSMEBSBIABKL-UHFFFAOYSA-N hexamethyldisilane Chemical compound C[Si](C)(C)[Si](C)(C)C NEXSMEBSBIABKL-UHFFFAOYSA-N 0.000 description 1
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- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- IQCYANORSDPPDT-UHFFFAOYSA-N methyl(silyl)silane Chemical compound C[SiH2][SiH3] IQCYANORSDPPDT-UHFFFAOYSA-N 0.000 description 1
- FOTXTBSEOHNRCB-UHFFFAOYSA-N methylgermane Chemical compound [GeH3]C FOTXTBSEOHNRCB-UHFFFAOYSA-N 0.000 description 1
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
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- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
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- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02524—Group 14 semiconducting materials
- H01L21/02532—Silicon, silicon germanium, germanium
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7842—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate
- H01L29/7848—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate the means being located in the source/drain region, e.g. SiGe source and drain
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
Abstract
【選択図】 図2C
Description
[0001]本発明の実施形態は、一般的には、半導体製造プロセスとデバイスの分野、特に、半導体デバイスを形成するシリコン含有膜を堆積させる方法に関する。
[0002]より小さなトランジスタが製造されるにつれて、極端に浅いソース/ドレイン接合が製造の意欲をかりたてている。国際半導体技術ロードマップ(ITRS)によると、100nm未満のCMOS(相補型金属酸化物半導体)デバイスの場合、接合の深さは30nm未満であることが必要とされる。接合の深さが10nmに近づくにつれて、注入やアニールによる従来のドーピングが効果的でなくなる。注入によるドーピングは、ドーパントを活性化させるためにポストアニールプロセスを必要とし、ポストアニールが層へのドーパント拡散を増強させる。
Claims (42)
- 基板上にシリコンゲルマニウム膜を堆積させる方法であって、
該基板をプロセスチャンバ内に配置するステップと、
該基板を約500℃〜約900℃の範囲の温度に加熱するステップと、
圧力を約0.1トール〜約200トールの範囲に維持するステップと、
SiH4、GeH4、HCl、キャリヤガス、少なくとも1つのドーパントガスを含む堆積ガスを供給するステップと、
該シリコンゲルマニウム膜を該基板上にエピタキシャル的に堆積させるステップと、
を含む、前記方法。 - 該少なくとも1つのドーパントガスが、BH3、B2H6、B3H8、Me3B、Et3B、それらの複合物及びそれらの誘導体又はそれらの組合わせからなる群より選ばれるホウ素含有化合物である、請求項1記載の方法。
- 該シリコンゲルマニウム膜が、約1×1020原子/cm3〜約2.5×1021原子/cm3の範囲のホウ素濃度で堆積する、請求項2記載の方法。
- 該少なくとも1つのドーパントガスが、ヒ素含有化合物又はリン含有化合物を含んでいる、請求項1記載の方法。
- 該キャリヤガスが、H2、Ar、N2、He又はそれらの組合わせからなる群より選ばれる、請求項1記載の方法。
- 該堆積ガスが、更に、炭素源、Cl2SiH2又はそれらの組合わせからなる群より選ばれる1種を含んでいる、請求項5記載の方法。
- 該温度が、約600℃〜約750℃の範囲にある、請求項6記載の方法。
- 該シリコンゲルマニウム膜が、約100オングストローム〜約3,000オングストロームの範囲の厚さに成長する、請求項7記載の方法。
- 該シリコンゲルマニウム膜が、CMOS、バイポーラ又はBiCMOS用途に用いられる電子デバイス内で堆積する、請求項8記載の方法。
- 製造ステップが、コンタクトプラグ、ソース/ドレイン伸長部、高ソース/ドレイン及びバイポーラトランジスタからなる群より選ばれる、請求項9記載の方法。
- 該シリコンゲルマニウム膜が第1厚さに堆積し、その中でSiH4がCl2SiH2で置き換えられ、第2シリコンゲルマニウム膜が該シリコンゲルマニウム膜上に第2厚さに堆積する、請求項1記載の方法。
- シリコン含有膜が、該シリコンゲルマニウム膜の前に該基板上に堆積する、請求項1記載の方法。
- 該シリコン含有膜が、Cl2SiH2を含むプロセスガスから堆積される、請求項12記載の方法。
- 基板上にシリコンゲルマニウム膜を成長させるための選択的エピタキシャル方法であって、
該基板をプロセスチャンバ内に約0.1トール〜約200トールの範囲の圧力で配置するステップと、
該基板を約500℃〜約900℃の範囲の温度に加熱するステップと、
SiH4、ゲルマニウム源、エッチング源、キャリヤガス、少なくとも1つのドーパントガスを含む堆積ガスを供給するステップと、
約1×1020原子/cm3〜約2.5×1021原子/cm3の範囲のドーパント濃度で該シリコンゲルマニウム膜を選択的に成長させるステップと、
を含む、前記方法。 - 該ゲルマニウム源が、GeH4、Ge2H6、Ge3H8、Ge4H10、それらの誘導体又はそれらの組合わせからなる群より選ばれる、請求項14記載の方法。
- 該キャリヤガスが、H2、Ar、N2、He又はそれらの組合わせからなる群より選ばれる、請求項15記載の方法。
- 該温度が、約600℃〜約750℃の範囲にある、請求項16記載の方法。
- 該エッチング剤源が、HCl、SiCl4、CCl4、H2CCl2、Cl2、それらの誘導体又はそれらの組合わせからなる群より選ばれる、請求項17記載の方法。
- 該少なくとも1つのドーパントガスが、BH3、B2H6、B3H8、Me3B、Et3B、それらの複合物、及びそれらの誘導体又はそれらの組合わせからなる群より選ばれるホウ素含有化合物である、請求項14記載の方法。
- 該少なくとも1つのドーパントガスが、ヒ素含有化合物又はリン含有化合物からなる群より選ばれる、請求項14記載の方法。
- 該堆積ガスが、更に、炭素源、Cl2SiH2又はそれらの組合わせからなる群より選ばれる1種を含んでいる、請求項14記載の方法。
- 該シリコンゲルマニウム膜が、約100オングストローム〜約3,000オングストロームの範囲の厚さに成長する、請求項17記載の方法。
- 該シリコンゲルマニウム膜が、CMOS、バイポーラ又はBiCMOS用途に用いられる電子デバイス内で堆積する、請求項22記載の方法。
- 製造ステップが、コンタクトプラグ、ソース/ドレイン伸長部、高ソース/ドレイン又はバイポーラトランジスタからなる群より選ばれる、請求項23記載の方法。
- 該シリコンゲルマニウム膜が第1厚さに成長し、その中でSiH4がCl2SiH2で置き換えられ、第2シリコンゲルマニウム膜が該シリコンゲルマニウム膜上に第2厚さに堆積する、請求項14記載の方法。
- シリコン含有膜が、該シリコンゲルマニウム膜の前に該基板上に堆積する、請求項14記載の方法。
- 該シリコン含有膜が、Cl2SiH2を含むプロセスガスから堆積される、請求項26記載の方法。
- 基板上にシリコン含有膜を成長させるための選択的エピタキシャル方法であって、
該基板をプロセスチャンバ内に約0.1トール〜約200トールの範囲の圧力で配置するステップと、
該基板を約500℃〜約900℃の範囲の温度に加熱するステップと、
SiH4、HCl、キャリヤガスを含む堆積ガスを供給するステップと、
該シリコン含有膜を約50オングストローム/分〜約600オングストローム/分の速度で成長させるステップと、
を含む、前記方法。 - 該堆積ガスが、更に、少なくとも1つのドーパントガスを含んでいる、請求項28記載の方法。
- 該少なくとも1つのドーパントガスが、BH3、B2H6、B3H8、Me3B、Et3B、それらの複合物、及びそれらの誘導体又はそれらの組合わせからなる群より選ばれるホウ素含有化合物である、請求項29記載の方法。
- 該シリコン含有膜が、約1×1020原子/cm3〜約2.5×1021原子/cm3の範囲のホウ素濃度で堆積する、請求項30記載の方法。
- 該少なくとも1つのドーパントガスが、ヒ素含有化合物又はリン含有化合物を含んでいる、請求項28記載の方法。
- 該キャリヤガスが、H2、Ar、N2、He又はそれらの組合わせからなる群より選ばれる、請求項28記載の方法。
- 該温度が約650℃〜約800℃の範囲にある、請求項33記載の方法。
- 該堆積ガスが、更に、炭素源、Cl2SiH2又はそれらの組合わせからなる群より選ばれる1種を含んでいる、請求項28記載の方法。
- 該シリコン含有膜が、CMOS、バイポーラ又はBiCMOS用途に用いられる電子デバイス内で堆積する、請求項28記載の方法。
- 製造ステップが、コンタクトプラグ、ソース/ドレイン伸長部、高ソース/ドレイン及びバイポーラトランジスタからなる群より選ばれる、請求項36記載の方法。
- 該シリコン含有膜が第1厚さに成長し、その中でSiH4がCl2SiH2で置き換えられ、第2シリコン含有膜が該シリコン含有膜上に第2厚さに堆積する、請求項28記載の方法。
- 第2シリコン含有膜が、該シリコンゲルマニウム膜の前に該基板上に堆積する、請求項28記載の方法。
- 該シリコン含有膜が、Cl2SiH2を含むプロセスガスから堆積される、請求項39記載の方法。
- 基板上にシリコン含有膜を成長させるための選択的エピタキシャル方法であって、
該基板をプロセスチャンバ内に約0.1トール〜約200トールの範囲の圧力で配置させるステップと、
該基板を約500℃〜約900℃の範囲の温度に加熱するステップと、
Cl2SiH2、HCl、キャリヤガスを含む堆積ガスを供給するステップと、
該基板上にシリコン含有層を堆積させるステップと、
SiH4と、HClと、第2キャリヤガスとを含む第2堆積ガスを供給するステップと、
該シリコン含有層上に第2シリコン含有層を堆積させるステップと、
を含む、前記方法。 - 基板上にシリコン含有膜を堆積させる方法であって、
該基板をプロセスチャンバ内に配置させるステップと、
該基板を約500℃〜約900℃の範囲の温度に加熱するステップと、
約0.1トール〜約200トールの範囲の圧力を維持するステップと、
SiH4、ゲルマニウム源、HCl、少なくとも1つのドーパントガス、N2、Ar、He及びそれらの組合わせからなる群より選ばれるキャリヤガスを含む堆積ガスを供給するステップと、
該基板上にエピタキシャル的に該シリコン含有膜を選択的に堆積させるステップと、
を含む、前記方法。
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KR20060110291A (ko) | 2006-10-24 |
CN101483136A (zh) | 2009-07-15 |
CN1875461A (zh) | 2006-12-06 |
US7517775B2 (en) | 2009-04-14 |
US20060234488A1 (en) | 2006-10-19 |
WO2005038890A1 (en) | 2005-04-28 |
EP1680808A1 (en) | 2006-07-19 |
JP4969244B2 (ja) | 2012-07-04 |
US7737007B2 (en) | 2010-06-15 |
CN101483136B (zh) | 2012-02-29 |
CN100468625C (zh) | 2009-03-11 |
US7166528B2 (en) | 2007-01-23 |
US20050079691A1 (en) | 2005-04-14 |
US20090011578A1 (en) | 2009-01-08 |
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