JP2013502371A - 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ - Google Patents
亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ Download PDFInfo
- Publication number
- JP2013502371A JP2013502371A JP2012525732A JP2012525732A JP2013502371A JP 2013502371 A JP2013502371 A JP 2013502371A JP 2012525732 A JP2012525732 A JP 2012525732A JP 2012525732 A JP2012525732 A JP 2012525732A JP 2013502371 A JP2013502371 A JP 2013502371A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- mol
- aluminoborosilicate glass
- aluminoborosilicate
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 155
- 230000003678 scratch resistant effect Effects 0.000 title description 3
- 230000000977 initiatory effect Effects 0.000 claims abstract description 28
- 230000006378 damage Effects 0.000 claims abstract description 12
- 239000005407 aluminoborosilicate glass Substances 0.000 claims description 46
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 43
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 31
- 239000003607 modifier Substances 0.000 claims description 27
- 150000002500 ions Chemical class 0.000 claims description 19
- 229910003460 diamond Inorganic materials 0.000 claims description 11
- 239000010432 diamond Substances 0.000 claims description 11
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 9
- 238000007373 indentation Methods 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 6
- 238000000280 densification Methods 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 239000005358 alkali aluminosilicate glass Substances 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 4
- 239000005361 soda-lime glass Substances 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000005342 ion exchange Methods 0.000 description 36
- 239000000203 mixture Substances 0.000 description 23
- 230000035882 stress Effects 0.000 description 18
- 239000010410 layer Substances 0.000 description 16
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 238000007545 Vickers hardness test Methods 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000005341 toughened glass Substances 0.000 description 7
- 241000282575 Gorilla Species 0.000 description 6
- 229910006404 SnO 2 Inorganic materials 0.000 description 6
- 238000006748 scratching Methods 0.000 description 6
- 230000002393 scratching effect Effects 0.000 description 6
- 239000005368 silicate glass Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 5
- -1 Ag + Chemical class 0.000 description 4
- 241000047703 Nonion Species 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 239000006059 cover glass Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- 229910018068 Li 2 O Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000003280 down draw process Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000005816 glass manufacturing process Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- BXVSAYBZSGIURM-UHFFFAOYSA-N 2-phenoxy-4h-1,3,2$l^{5}-benzodioxaphosphinine 2-oxide Chemical compound O1CC2=CC=CC=C2OP1(=O)OC1=CC=CC=C1 BXVSAYBZSGIURM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000005391 art glass Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001417 caesium ion Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000003286 fusion draw glass process Methods 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003283 slot draw process Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/0222—Scoring using a focussed radiation beam, e.g. laser
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/04—Cutting or splitting in curves, especially for making spectacle lenses
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/09—Severing cooled glass by thermal shock
- C03B33/091—Severing cooled glass by thermal shock using at least one focussed radiation beam, e.g. laser beam
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T225/00—Severing by tearing or breaking
- Y10T225/10—Methods
- Y10T225/12—With preliminary weakening
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24777—Edge feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Toxicology (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23576709P | 2009-08-21 | 2009-08-21 | |
| US61/235,767 | 2009-08-21 | ||
| PCT/US2010/046185 WO2011022661A2 (en) | 2009-08-21 | 2010-08-20 | Crack and scratch resistant glass and enclosures made therefrom |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015133427A Division JP6128401B2 (ja) | 2009-08-21 | 2015-07-02 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2013502371A true JP2013502371A (ja) | 2013-01-24 |
Family
ID=43033185
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012525732A Pending JP2013502371A (ja) | 2009-08-21 | 2010-08-20 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2015133427A Active JP6128401B2 (ja) | 2009-08-21 | 2015-07-02 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2016218026A Active JP6851783B2 (ja) | 2009-08-21 | 2016-11-08 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2019072670A Pending JP2019108272A (ja) | 2009-08-21 | 2019-04-05 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2022048061A Pending JP2022075932A (ja) | 2009-08-21 | 2022-03-24 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
Family Applications After (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015133427A Active JP6128401B2 (ja) | 2009-08-21 | 2015-07-02 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2016218026A Active JP6851783B2 (ja) | 2009-08-21 | 2016-11-08 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2019072670A Pending JP2019108272A (ja) | 2009-08-21 | 2019-04-05 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
| JP2022048061A Pending JP2022075932A (ja) | 2009-08-21 | 2022-03-24 | 亀裂および引っ掻き抵抗性のガラスおよびそれから製造されたエンクロージャ |
Country Status (8)
| Country | Link |
|---|---|
| US (5) | US8341976B2 (enExample) |
| EP (2) | EP3868725A1 (enExample) |
| JP (5) | JP2013502371A (enExample) |
| KR (4) | KR102212371B1 (enExample) |
| CN (2) | CN102762508B (enExample) |
| IN (1) | IN2012DN01533A (enExample) |
| TW (1) | TWI576324B (enExample) |
| WO (1) | WO2011022661A2 (enExample) |
Cited By (23)
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|---|---|---|---|---|
| JP2015505157A (ja) * | 2011-12-06 | 2015-02-16 | コーニング インコーポレイテッド | イオン交換ガラス基板を備える有機薄膜トランジスタ |
| JP2015042607A (ja) * | 2013-07-24 | 2015-03-05 | 日本電気硝子株式会社 | 強化ガラス及び強化用ガラス |
| KR20150113031A (ko) * | 2013-01-31 | 2015-10-07 | 코닝 인코포레이티드 | 가상 유리 및 이의 제조방법 |
| KR20160090370A (ko) * | 2013-11-26 | 2016-07-29 | 코닝 인코포레이티드 | 높은 압입 임계값을 갖는 빠른 이온 교환 가능한 유리 |
| JP2016534019A (ja) * | 2013-09-13 | 2016-11-04 | コーニング インコーポレイテッド | 亀裂発生閾値が高いイオン交換可能なガラス |
| KR20170018959A (ko) * | 2014-06-19 | 2017-02-20 | 코닝 인코포레이티드 | 비-취약성 응력 프로파일을 갖는 유리 |
| JP2018528923A (ja) * | 2015-08-26 | 2018-10-04 | コーナーストーン・マテリアルズ・テクノロジー・カンパニー・リミテッドKornerstone Materials Technology Company, Ltd. | 化学的に強化されたアルカリアルミノシリケートガラス用のガラス組成物及びそのイオン交換時間の短縮を伴う製造方法 |
| JP2018536613A (ja) * | 2015-11-19 | 2018-12-13 | コーニング インコーポレイテッド | 表示画面プロテクタ |
| JP2020040881A (ja) * | 2013-11-20 | 2020-03-19 | コーニング インコーポレイテッド | 耐スクラッチアルミノホウケイ酸ガラス |
| JP2021014402A (ja) * | 2013-10-14 | 2021-02-12 | コーニング インコーポレイテッド | イオン交換プロセスおよびそれにより得られる化学強化されたガラス基材 |
| JP2021075426A (ja) * | 2019-11-11 | 2021-05-20 | 石塚硝子株式会社 | 化学強化用アルミノボロシケートガラス及び化学強化ガラス品 |
| US11021393B2 (en) | 2014-11-04 | 2021-06-01 | Corning Incorporated | Deep non-frangible stress profiles and methods of making |
| US11084756B2 (en) | 2014-10-31 | 2021-08-10 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
| US11174197B2 (en) | 2016-04-08 | 2021-11-16 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
| JP2022000410A (ja) * | 2016-05-06 | 2022-01-04 | コーニング インコーポレイテッド | 透明基板からの、輪郭設定された形状のレーザ切断及び取り外し |
| US11220456B2 (en) | 2014-10-08 | 2022-01-11 | Corning Incorporated | Glasses and glass ceramics including a metal oxide concentration gradient |
| US11267228B2 (en) | 2015-07-21 | 2022-03-08 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US11472734B2 (en) | 2015-12-11 | 2022-10-18 | Corning Incorporated | Fusion-formable glass-based articles including a metal oxide concentration gradient |
| US11492291B2 (en) | 2012-02-29 | 2022-11-08 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US11634359B2 (en) | 2014-02-24 | 2023-04-25 | Corning Incorporated | Strengthened glass with deep depth of compression |
| US11926564B2 (en) | 2013-01-31 | 2024-03-12 | Corning Incorporated | Transition metal-containing, ion exchangeable colored glasses |
| US11963320B2 (en) | 2016-04-08 | 2024-04-16 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions |
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| KR20120073249A (ko) | 2009-08-28 | 2012-07-04 | 코닝 인코포레이티드 | 화학적으로 강화된 유리 기판으로부터 제품을 레이저 절단하기 위한 방법 |
| US8946590B2 (en) | 2009-11-30 | 2015-02-03 | Corning Incorporated | Methods for laser scribing and separating glass substrates |
| US20110265516A1 (en) * | 2010-04-29 | 2011-11-03 | Douglas Clippinger Allan | Compositional control of fast relaxation in display glasses |
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