TWI576324B - 防裂縫及刮損玻璃及製造外殼 - Google Patents
防裂縫及刮損玻璃及製造外殼 Download PDFInfo
- Publication number
- TWI576324B TWI576324B TW099127636A TW99127636A TWI576324B TW I576324 B TWI576324 B TW I576324B TW 099127636 A TW099127636 A TW 099127636A TW 99127636 A TW99127636 A TW 99127636A TW I576324 B TWI576324 B TW I576324B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- aluminoborosilicate glass
- mol
- aluminoborosilicate
- ion
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims description 162
- 230000003678 scratch resistant effect Effects 0.000 title 1
- 239000005407 aluminoborosilicate glass Substances 0.000 claims description 98
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 44
- 238000005342 ion exchange Methods 0.000 claims description 41
- 238000007373 indentation Methods 0.000 claims description 32
- 230000000977 initiatory effect Effects 0.000 claims description 30
- 239000003607 modifier Substances 0.000 claims description 26
- 150000002500 ions Chemical class 0.000 claims description 20
- 239000010432 diamond Substances 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 229910003460 diamond Inorganic materials 0.000 claims description 11
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 10
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 9
- 239000005341 toughened glass Substances 0.000 claims description 9
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000005388 borosilicate glass Substances 0.000 claims description 7
- 150000002923 oximes Chemical class 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000012634 fragment Substances 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 2
- 239000006058 strengthened glass Substances 0.000 claims 2
- USKDPFQTJZBDFB-UHFFFAOYSA-N [B+3].B([O-])([O-])[O-].[Al+3].B([O-])([O-])[O-] Chemical compound [B+3].B([O-])([O-])[O-].[Al+3].B([O-])([O-])[O-] USKDPFQTJZBDFB-UHFFFAOYSA-N 0.000 claims 1
- DJPURDPSZFLWGC-UHFFFAOYSA-N alumanylidyneborane Chemical compound [Al]#B DJPURDPSZFLWGC-UHFFFAOYSA-N 0.000 claims 1
- 230000003746 surface roughness Effects 0.000 claims 1
- SITVSCPRJNYAGV-UHFFFAOYSA-L tellurite Chemical compound [O-][Te]([O-])=O SITVSCPRJNYAGV-UHFFFAOYSA-L 0.000 claims 1
- 230000035882 stress Effects 0.000 description 17
- 239000010410 layer Substances 0.000 description 16
- 230000007547 defect Effects 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 239000005354 aluminosilicate glass Substances 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 7
- 229910006404 SnO 2 Inorganic materials 0.000 description 6
- 239000006059 cover glass Substances 0.000 description 6
- 239000005400 gorilla glass Substances 0.000 description 6
- -1 Ag + Chemical class 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 201000000724 Chronic recurrent multifocal osteomyelitis Diseases 0.000 description 4
- 239000005368 silicate glass Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- BXVSAYBZSGIURM-UHFFFAOYSA-N 2-phenoxy-4h-1,3,2$l^{5}-benzodioxaphosphinine 2-oxide Chemical compound O1CC2=CC=CC=C2OP1(=O)OC1=CC=CC=C1 BXVSAYBZSGIURM-UHFFFAOYSA-N 0.000 description 1
- 241000282575 Gorilla Species 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000005358 alkali aluminosilicate glass Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000005345 chemically strengthened glass Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000006066 glass batch Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/0222—Scoring using a focussed radiation beam, e.g. laser
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/04—Cutting or splitting in curves, especially for making spectacle lenses
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/09—Severing cooled glass by thermal shock
- C03B33/091—Severing cooled glass by thermal shock using at least one focussed radiation beam, e.g. laser beam
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T225/00—Severing by tearing or breaking
- Y10T225/10—Methods
- Y10T225/12—With preliminary weakening
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24777—Edge feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23576709P | 2009-08-21 | 2009-08-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201127771A TW201127771A (en) | 2011-08-16 |
| TWI576324B true TWI576324B (zh) | 2017-04-01 |
Family
ID=43033185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW099127636A TWI576324B (zh) | 2009-08-21 | 2010-08-19 | 防裂縫及刮損玻璃及製造外殼 |
Country Status (8)
| Country | Link |
|---|---|
| US (5) | US8341976B2 (enExample) |
| EP (2) | EP2467340B1 (enExample) |
| JP (5) | JP2013502371A (enExample) |
| KR (4) | KR101823163B1 (enExample) |
| CN (2) | CN102762508B (enExample) |
| IN (1) | IN2012DN01533A (enExample) |
| TW (1) | TWI576324B (enExample) |
| WO (1) | WO2011022661A2 (enExample) |
Families Citing this family (247)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2227444B1 (en) | 2007-11-29 | 2019-02-20 | Corning Incorporated | Glasses having improved toughness and scratch resistance |
| US8341976B2 (en) * | 2009-02-19 | 2013-01-01 | Corning Incorporated | Method of separating strengthened glass |
| WO2011025908A1 (en) | 2009-08-28 | 2011-03-03 | Corning Incorporated | Methods for laser cutting articles from chemically strengthened glass substrates |
| US8946590B2 (en) | 2009-11-30 | 2015-02-03 | Corning Incorporated | Methods for laser scribing and separating glass substrates |
| US20110265516A1 (en) * | 2010-04-29 | 2011-11-03 | Douglas Clippinger Allan | Compositional control of fast relaxation in display glasses |
| US8759238B2 (en) | 2010-05-27 | 2014-06-24 | Corning Incorporated | Ion exchangeable glasses |
| US8778820B2 (en) * | 2010-05-27 | 2014-07-15 | Corning Incorporated | Glasses having low softening temperatures and high toughness |
| US9540278B2 (en) | 2010-05-27 | 2017-01-10 | Corning Incorporated | Ion exchangeable glasses |
| TWI398423B (zh) * | 2010-05-28 | 2013-06-11 | Wintek Corp | 玻璃強化方法及應用其之玻璃 |
| US20130059157A1 (en) * | 2010-05-28 | 2013-03-07 | Dana Craig Bookbinder | Transparent laminates comprising intermediate or anomalous glass |
| US20120052271A1 (en) * | 2010-08-26 | 2012-03-01 | Sinue Gomez | Two-step method for strengthening glass |
| FR2964655B1 (fr) * | 2010-09-13 | 2017-05-19 | Saint Gobain | Feuille de verre |
| US9346703B2 (en) | 2010-11-30 | 2016-05-24 | Corning Incorporated | Ion exchangable glass with deep compressive layer and high damage threshold |
| KR101757927B1 (ko) | 2010-12-06 | 2017-07-17 | 엘지디스플레이 주식회사 | 윈도우 패널 및 그 제조방법과, 윈도우 패널 일체형 터치 스크린 패널 및 그 제조방법 |
| JP5612233B1 (ja) * | 2010-12-24 | 2014-10-22 | 旭硝子株式会社 | 化学強化用ガラス |
| US8539794B2 (en) | 2011-02-01 | 2013-09-24 | Corning Incorporated | Strengthened glass substrate sheets and methods for fabricating glass panels from glass substrate sheets |
| US8889575B2 (en) | 2011-05-31 | 2014-11-18 | Corning Incorporated | Ion exchangeable alkali aluminosilicate glass articles |
| US9616641B2 (en) | 2011-06-24 | 2017-04-11 | Corning Incorporated | Light-weight hybrid glass laminates |
| US9783452B2 (en) | 2011-07-01 | 2017-10-10 | Corning Incorporated | Ion-exchanged glass of high surface compression and shallow depth of layer with high resistance to radial crack formation from vickers indentation |
| TWI591039B (zh) * | 2011-07-01 | 2017-07-11 | 康寧公司 | 具高壓縮應力的離子可交換玻璃 |
| US10280112B2 (en) | 2011-08-19 | 2019-05-07 | Corning Incorporated | Ion exchanged glass with high resistance to sharp contact failure and articles made therefrom |
| JPWO2013031547A1 (ja) * | 2011-08-29 | 2015-03-23 | 旭硝子株式会社 | ガラス板、およびガラス板の製造方法 |
| EP2759522A4 (en) * | 2011-09-22 | 2015-05-20 | Asahi Glass Co Ltd | GLASS PLATE TO TEMPERN |
| KR102306087B1 (ko) * | 2011-11-16 | 2021-09-29 | 코닝 인코포레이티드 | 높은 균열 개시 임계값을 갖는 이온 교환가능한 유리 |
| US20130129947A1 (en) * | 2011-11-18 | 2013-05-23 | Daniel Ralph Harvey | Glass article having high damage resistance |
| US20130136909A1 (en) * | 2011-11-30 | 2013-05-30 | John Christopher Mauro | Colored alkali aluminosilicate glass articles |
| US8901544B2 (en) * | 2011-12-06 | 2014-12-02 | Corning Incorporated | Organic thin film transistor with ion exchanged glass substrate |
| WO2013116420A1 (en) * | 2012-02-01 | 2013-08-08 | Corning Incorporated | Method of producing constancy of compressive stress in glass in an ion-exchange process |
| US9828278B2 (en) | 2012-02-28 | 2017-11-28 | Electro Scientific Industries, Inc. | Method and apparatus for separation of strengthened glass and articles produced thereby |
| CN104136967B (zh) | 2012-02-28 | 2018-02-16 | 伊雷克托科学工业股份有限公司 | 用于分离增强玻璃的方法及装置及由该增强玻璃生产的物品 |
| US10357850B2 (en) | 2012-09-24 | 2019-07-23 | Electro Scientific Industries, Inc. | Method and apparatus for machining a workpiece |
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| WO2013130608A1 (en) | 2012-02-29 | 2013-09-06 | Electro Scientific Industries, Inc. | Methods and apparatus for machining strengthened glass and articles produced thereby |
| US9701580B2 (en) * | 2012-02-29 | 2017-07-11 | Corning Incorporated | Aluminosilicate glasses for ion exchange |
| US8720226B2 (en) | 2012-03-12 | 2014-05-13 | Corning Incorporated | Methods for producing ion-exchangeable glasses |
| JP5888158B2 (ja) * | 2012-04-05 | 2016-03-16 | 日本電気硝子株式会社 | ガラスフィルムの割断方法 |
| US9938186B2 (en) | 2012-04-13 | 2018-04-10 | Corning Incorporated | Strengthened glass articles having etched features and methods of forming the same |
| TWI593644B (zh) | 2012-05-09 | 2017-08-01 | 康寧公司 | 製造覆蓋玻璃的方法 |
| EP2855384B1 (en) | 2012-05-29 | 2020-12-09 | Corning Incorporated | Method for texturing a glass surface |
| US9512029B2 (en) | 2012-05-31 | 2016-12-06 | Corning Incorporated | Cover glass article |
| US9145333B1 (en) * | 2012-05-31 | 2015-09-29 | Corning Incorporated | Chemically-strengthened borosilicate glass articles |
| US10898933B2 (en) | 2012-05-31 | 2021-01-26 | Corning Incorporated | Oleophobic glass articles |
| KR102462318B1 (ko) * | 2012-05-31 | 2022-11-03 | 코닝 인코포레이티드 | 높은 내손상성을 갖는 지르콘 호환가능한, 이온 교환가능한 유리 |
| US9517967B2 (en) * | 2012-05-31 | 2016-12-13 | Corning Incorporated | Ion exchangeable glass with high damage resistance |
| JP6173444B2 (ja) * | 2012-05-31 | 2017-08-02 | コーニング インコーポレイテッド | イオン交換可能な遷移金属含有ガラス |
| US9938180B2 (en) * | 2012-06-05 | 2018-04-10 | Corning Incorporated | Methods of cutting glass using a laser |
| CN104125935A (zh) * | 2012-06-08 | 2014-10-29 | 日本电气硝子株式会社 | 强化玻璃、强化玻璃板以及强化用玻璃 |
| JP2015523310A (ja) | 2012-06-08 | 2015-08-13 | コーニング インコーポレイテッド | 強化ガラス物品と製造方法 |
| JP6168288B2 (ja) * | 2012-06-13 | 2017-07-26 | 日本電気硝子株式会社 | 強化ガラス及び強化ガラス板 |
| US10696022B2 (en) * | 2012-06-27 | 2020-06-30 | Tosoh Corporation | Composite plate and production method therefor |
| WO2014010533A1 (ja) * | 2012-07-09 | 2014-01-16 | 日本電気硝子株式会社 | 強化ガラス及び強化ガラス板 |
| JP2014031305A (ja) * | 2012-07-11 | 2014-02-20 | Asahi Glass Co Ltd | 化学強化用ガラス、化学強化ガラス |
| CN104781201A (zh) * | 2012-08-17 | 2015-07-15 | 康宁股份有限公司 | 超薄强化玻璃 |
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2010
- 2010-07-28 US US12/845,066 patent/US8341976B2/en active Active
- 2010-08-18 US US12/858,490 patent/US8586492B2/en active Active
- 2010-08-19 TW TW099127636A patent/TWI576324B/zh active
- 2010-08-20 IN IN1533DEN2012 patent/IN2012DN01533A/en unknown
- 2010-08-20 KR KR1020127007360A patent/KR101823163B1/ko active Active
- 2010-08-20 KR KR1020217002995A patent/KR102392737B1/ko active Active
- 2010-08-20 WO PCT/US2010/046185 patent/WO2011022661A2/en not_active Ceased
- 2010-08-20 EP EP10748028.7A patent/EP2467340B1/en active Active
- 2010-08-20 KR KR1020187001976A patent/KR102025267B1/ko active Active
- 2010-08-20 EP EP21168270.3A patent/EP3868725A1/en not_active Withdrawn
- 2010-08-20 CN CN201080043021.1A patent/CN102762508B/zh active Active
- 2010-08-20 JP JP2012525732A patent/JP2013502371A/ja active Pending
- 2010-08-20 CN CN201710321273.XA patent/CN107032605B/zh active Active
- 2010-08-20 KR KR1020197027337A patent/KR102212371B1/ko active Active
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2013
- 2013-11-18 US US14/082,847 patent/US9290407B2/en not_active Ceased
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2015
- 2015-07-02 JP JP2015133427A patent/JP6128401B2/ja active Active
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2016
- 2016-11-08 JP JP2016218026A patent/JP6851783B2/ja not_active Expired - Fee Related
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2018
- 2018-01-04 US US15/862,353 patent/USRE47837E1/en active Active
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2019
- 2019-04-05 JP JP2019072670A patent/JP2019108272A/ja active Pending
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2020
- 2020-01-17 US US16/746,545 patent/USRE49530E1/en active Active
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2022
- 2022-03-24 JP JP2022048061A patent/JP2022075932A/ja active Pending
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| US5674790A (en) * | 1995-12-15 | 1997-10-07 | Corning Incorporated | Strengthening glass by ion exchange |
| US20090142568A1 (en) * | 2007-11-29 | 2009-06-04 | Matthew John Dejneka | Glasses having improved toughness and scratch resistance |
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