CA2169401C - Components and catalysts for the polymerization of olefins - Google Patents
Components and catalysts for the polymerization of olefins Download PDFInfo
- Publication number
- CA2169401C CA2169401C CA002169401A CA2169401A CA2169401C CA 2169401 C CA2169401 C CA 2169401C CA 002169401 A CA002169401 A CA 002169401A CA 2169401 A CA2169401 A CA 2169401A CA 2169401 C CA2169401 C CA 2169401C
- Authority
- CA
- Canada
- Prior art keywords
- bis
- methoxymethyl
- radicals
- equal
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003054 catalyst Substances 0.000 title claims abstract description 69
- 238000006116 polymerization reaction Methods 0.000 title claims description 26
- 150000001336 alkenes Chemical class 0.000 title claims description 23
- 239000011949 solid catalyst Substances 0.000 claims abstract description 62
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 37
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 23
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 23
- 125000003367 polycyclic group Chemical group 0.000 claims abstract description 3
- -1 magnesium halide Chemical class 0.000 claims description 141
- 150000001875 compounds Chemical class 0.000 claims description 47
- 150000003254 radicals Chemical class 0.000 claims description 42
- 229910052757 nitrogen Inorganic materials 0.000 claims description 29
- 229910052736 halogen Inorganic materials 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 150000002367 halogens Chemical class 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000011777 magnesium Substances 0.000 claims description 21
- 229910052749 magnesium Inorganic materials 0.000 claims description 18
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 125000005842 heteroatom Chemical group 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 150000003609 titanium compounds Chemical class 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 10
- 150000001721 carbon Chemical group 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical class 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims description 6
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 239000012071 phase Substances 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 125000004434 sulfur atom Chemical group 0.000 claims description 5
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical group CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000005840 aryl radicals Chemical class 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- OTIJMHPVYPMCPU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2,3-dimethylindene Chemical compound C1=CC=C2C(COC)(COC)C(C)=C(C)C2=C1 OTIJMHPVYPMCPU-UHFFFAOYSA-N 0.000 claims description 3
- HHGPZISECHQRLO-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-methyl-4-phenylindene Chemical compound COCC1(COC)C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 HHGPZISECHQRLO-UHFFFAOYSA-N 0.000 claims description 3
- FXWFWIIEIAUQHQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-phenylindene Chemical compound C=1C2=CC=CC=C2C(COC)(COC)C=1C1=CC=CC=C1 FXWFWIIEIAUQHQ-UHFFFAOYSA-N 0.000 claims description 3
- ZZPVNMUQOQQUHU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,7-dimethylindene Chemical compound CC1=CC=C(C)C2=C1C(COC)(COC)C=C2 ZZPVNMUQOQQUHU-UHFFFAOYSA-N 0.000 claims description 3
- JEENAIJBWUBGSW-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(3,3,3-trifluoropropyl)indene Chemical compound C1=CC(CCC(F)(F)F)=C2C(COC)(COC)C=CC2=C1 JEENAIJBWUBGSW-UHFFFAOYSA-N 0.000 claims description 3
- RMXREGKBZYAVSC-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(trifluoromethyl)indene Chemical compound C1=CC(C(F)(F)F)=C2C(COC)(COC)C=CC2=C1 RMXREGKBZYAVSC-UHFFFAOYSA-N 0.000 claims description 3
- ZOIKOBDBSUJRNE-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-methylindene Chemical compound C1=CC(C)=C2C(COC)(COC)C=CC2=C1 ZOIKOBDBSUJRNE-UHFFFAOYSA-N 0.000 claims description 3
- UQGOQZUZKNXSTQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-phenylindene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1=CC=CC=C1 UQGOQZUZKNXSTQ-UHFFFAOYSA-N 0.000 claims description 3
- VJTYHGPEEHLNGJ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-propan-2-ylindene Chemical compound C1=CC(C(C)C)=C2C(COC)(COC)C=CC2=C1 VJTYHGPEEHLNGJ-UHFFFAOYSA-N 0.000 claims description 3
- ILXXAZBXJLMEQM-UHFFFAOYSA-N 1,1-bis(methoxymethyl)indene Chemical compound C1=CC=C2C(COC)(COC)C=CC2=C1 ILXXAZBXJLMEQM-UHFFFAOYSA-N 0.000 claims description 3
- SCTKUNIIBPPKNV-UHFFFAOYSA-N 1,8-dichloro-9,9-bis(methoxymethyl)fluorene Chemical compound C12=CC=CC(Cl)=C2C(COC)(COC)C2=C1C=CC=C2Cl SCTKUNIIBPPKNV-UHFFFAOYSA-N 0.000 claims description 3
- PEKQXDFNLCXEIG-UHFFFAOYSA-N 1,8-difluoro-9,9-bis(methoxymethyl)fluorene Chemical compound C12=CC=CC(F)=C2C(COC)(COC)C2=C1C=CC=C2F PEKQXDFNLCXEIG-UHFFFAOYSA-N 0.000 claims description 3
- ZFAIPBMPKVESPU-UHFFFAOYSA-N 2,3,4,5,6,7-hexafluoro-9,9-bis(methoxymethyl)fluorene Chemical compound C1=C(F)C(F)=C(F)C2=C1C(COC)(COC)C1=CC(F)=C(F)C(F)=C12 ZFAIPBMPKVESPU-UHFFFAOYSA-N 0.000 claims description 3
- LDAYPNRUDRHPCA-UHFFFAOYSA-N 2,7-dicyclopentyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=C2C(COC)(COC)C3=CC(C4CCCC4)=CC=C3C2=CC=C1C1CCCC1 LDAYPNRUDRHPCA-UHFFFAOYSA-N 0.000 claims description 3
- UURZCHPNAPLYER-UHFFFAOYSA-N 4-tert-butyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C(C(C)(C)C)C2=C1C(COC)(COC)C1=CC=CC=C12 UURZCHPNAPLYER-UHFFFAOYSA-N 0.000 claims description 3
- NUPABKVXQKZAHY-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-1,2,3,4-tetramethylcyclopenta-1,3-diene Chemical compound COCC1(COC)C(C)=C(C)C(C)=C1C NUPABKVXQKZAHY-UHFFFAOYSA-N 0.000 claims description 3
- DNQBFNSYXQGWEA-UHFFFAOYSA-N 5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C=CC=C1 DNQBFNSYXQGWEA-UHFFFAOYSA-N 0.000 claims description 3
- TYYSEGNSDSKJDW-UHFFFAOYSA-N 7-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCCC1 TYYSEGNSDSKJDW-UHFFFAOYSA-N 0.000 claims description 3
- OQYGKBOREGNKLC-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)-2-methylindene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C(C)=CC2=C1 OQYGKBOREGNKLC-UHFFFAOYSA-N 0.000 claims description 3
- XBHBMIOEDQWGPY-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)indene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C=CC2=C1 XBHBMIOEDQWGPY-UHFFFAOYSA-N 0.000 claims description 3
- UMMOCVFWWKDPNL-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4,5,6,7,8-octahydrofluorene Chemical compound C1CCCC2=C1C(COC)(COC)C1=C2CCCC1 UMMOCVFWWKDPNL-UHFFFAOYSA-N 0.000 claims description 3
- MGQOPBZMDMTUQK-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4-tetrahydrofluorene Chemical compound C12=CC=CC=C2C(COC)(COC)C2=C1CCCC2 MGQOPBZMDMTUQK-UHFFFAOYSA-N 0.000 claims description 3
- BJBJQWLYAGUTIO-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,3,6,7-tetramethylfluorene Chemical compound CC1=C(C)C=C2C(COC)(COC)C3=CC(C)=C(C)C=C3C2=C1 BJBJQWLYAGUTIO-UHFFFAOYSA-N 0.000 claims description 3
- MHOBTJZEFPKMLE-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,3,6,7-tetramethylxanthene Chemical compound CC1=C(C)C=C2C(COC)(COC)C3=CC(C)=C(C)C=C3OC2=C1 MHOBTJZEFPKMLE-UHFFFAOYSA-N 0.000 claims description 3
- PQRUIZPAUUOIPY-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,7-di(propan-2-yl)fluorene Chemical compound C1=C(C(C)C)C=C2C(COC)(COC)C3=CC(C(C)C)=CC=C3C2=C1 PQRUIZPAUUOIPY-UHFFFAOYSA-N 0.000 claims description 3
- UVZNCPVTOYWJAQ-UHFFFAOYSA-N 9,9-bis(methoxymethyl)xanthene Chemical group C1=CC=C2C(COC)(COC)C3=CC=CC=C3OC2=C1 UVZNCPVTOYWJAQ-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- JSDWVMORIKLNNU-UHFFFAOYSA-N [3,3-bis(methoxymethyl)-2,4,5-triphenylcyclopenta-1,4-dien-1-yl]benzene Chemical compound COCC1(COC)C(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 JSDWVMORIKLNNU-UHFFFAOYSA-N 0.000 claims description 3
- DFBNDURJLQVNJX-UHFFFAOYSA-N [3,3-bis(methoxymethyl)inden-4-yl]-trimethylsilane Chemical compound C1=CC([Si](C)(C)C)=C2C(COC)(COC)C=CC2=C1 DFBNDURJLQVNJX-UHFFFAOYSA-N 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 150000003377 silicon compounds Chemical class 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- CQNWWQKMMODDOL-UHFFFAOYSA-N 2,3,6,7-tetrafluoro-9-(1-methoxyethyl)-9-(methoxymethyl)fluorene Chemical compound FC1=C(F)C=C2C(COC)(C(C)OC)C3=CC(F)=C(F)C=C3C2=C1 CQNWWQKMMODDOL-UHFFFAOYSA-N 0.000 claims description 2
- POWUJINVZSHIGY-UHFFFAOYSA-N 2,6-di(propan-2-yl)piperidine Chemical group CC(C)C1CCCC(C(C)C)N1 POWUJINVZSHIGY-UHFFFAOYSA-N 0.000 claims description 2
- WUTBIESYSBKEFV-UHFFFAOYSA-N 5,6-dichloro-1,1-bis(1-methoxyethyl)indene Chemical compound ClC1=C(Cl)C=C2C(C(C)OC)(C(C)OC)C=CC2=C1 WUTBIESYSBKEFV-UHFFFAOYSA-N 0.000 claims description 2
- VOJHJALZRBMLDE-UHFFFAOYSA-N 9,9-bis(1-methoxyethyl)fluorene Chemical compound C1=CC=C2C(C(C)OC)(C(C)OC)C3=CC=CC=C3C2=C1 VOJHJALZRBMLDE-UHFFFAOYSA-N 0.000 claims description 2
- ANGMMFRGIJDWPU-UHFFFAOYSA-N 9-(1-methoxyethyl)-9-(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(C(C)OC)C3=CC=CC=C3C2=C1 ANGMMFRGIJDWPU-UHFFFAOYSA-N 0.000 claims description 2
- FBGWXZDLLURWAM-UHFFFAOYSA-N 9-(ethoxymethyl)-9-(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COCC)(COC)C3=CC=CC=C3C2=C1 FBGWXZDLLURWAM-UHFFFAOYSA-N 0.000 claims description 2
- WFLVIOIMYKVGLP-UHFFFAOYSA-N 9-(methoxymethyl)-9-(pentoxymethyl)fluorene Chemical compound C1=CC=C2C(COCCCCC)(COC)C3=CC=CC=C3C2=C1 WFLVIOIMYKVGLP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002879 Lewis base Substances 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical group 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 150000007527 lewis bases Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims 12
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 2
- OEGBIJMAWUHNFV-UHFFFAOYSA-N 7-cyclopentyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCC1 OEGBIJMAWUHNFV-UHFFFAOYSA-N 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 abstract description 4
- 239000004743 Polypropylene Substances 0.000 description 41
- 229920001155 polypropylene Polymers 0.000 description 41
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 22
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 20
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 10
- 229910003074 TiCl4 Inorganic materials 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 238000013019 agitation Methods 0.000 description 9
- 150000002170 ethers Chemical class 0.000 description 9
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- 125000002877 alkyl aryl group Chemical group 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
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- 230000015572 biosynthetic process Effects 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 4
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- HBMODDNTUPGVFW-UHFFFAOYSA-N (1,3-dimethoxy-2-phenylpropan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(COC)(COC)C1=CC=CC=C1 HBMODDNTUPGVFW-UHFFFAOYSA-N 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- PQIDFVXMOZQINS-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclohexane Chemical compound COCC(COC)(C(C)C)C1CCCCC1 PQIDFVXMOZQINS-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001033 ether group Chemical group 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
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- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
- YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003987 high-resolution gas chromatography Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000010813 internal standard method Methods 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT95MI000318 IT1274252B (it) | 1995-02-21 | 1995-02-21 | Catalizzatori per la polimerizzazione delle olefine |
| IT95MI000317 IT1274251B (it) | 1995-02-21 | 1995-02-21 | Componenti e catalizzatori per la polimerizzazione delle olefine |
| ITMI95A000318 | 1995-02-21 | ||
| ITMI95A000317 | 1995-02-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2169401A1 CA2169401A1 (en) | 1996-08-22 |
| CA2169401C true CA2169401C (en) | 2007-04-10 |
Family
ID=26331244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002169401A Expired - Fee Related CA2169401C (en) | 1995-02-21 | 1996-02-13 | Components and catalysts for the polymerization of olefins |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP0728769B1 (h) |
| JP (1) | JP3904117B2 (h) |
| KR (1) | KR100424925B1 (h) |
| CN (1) | CN1090194C (h) |
| AR (1) | AR000994A1 (h) |
| AT (1) | ATE169937T1 (h) |
| AU (1) | AU699522B2 (h) |
| BR (1) | BR9600767A (h) |
| CA (1) | CA2169401C (h) |
| DE (1) | DE69600532T2 (h) |
| ES (1) | ES2121446T3 (h) |
| FI (1) | FI119643B (h) |
| HU (1) | HU221228B1 (h) |
| IL (1) | IL117114A (h) |
| IN (1) | IN186169B (h) |
| MY (1) | MY115716A (h) |
| NO (1) | NO309380B1 (h) |
| RU (1) | RU2156260C2 (h) |
| UA (1) | UA60290C2 (h) |
Families Citing this family (347)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1003017C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerd fluoreen. |
| NL1003013C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met cyclische groepen gesubstitueerde cyclopentadieenverbinding. |
| NL1003016C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Gesubstitueerde pentadieenverbinding. |
| US6117811A (en) * | 1996-05-03 | 2000-09-12 | Dsm N.V. | Cyclopentadiene compound substituted with linear groups |
| NL1003008C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
| NL1003018C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde indeen. |
| NL1003004C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding. |
| NL1003007C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding. |
| US6124488A (en) * | 1996-05-03 | 2000-09-26 | Dsm N.V. | Cyclopentadiene compound substituted with branched alkyl groups |
| NL1003011C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
| MY125673A (en) * | 1996-06-10 | 2006-08-30 | Mitsui Chemicals Inc | Solid titanium catalyst component for olefin polymerization,process for preparing the same, olefin plymerization catalyst containing the catalyst component and olefin polymerization process using thecatalyst |
| FI963707A0 (fi) | 1996-09-19 | 1996-09-19 | Borealis Polymers Oy | Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma |
| KR100530978B1 (ko) * | 1998-05-06 | 2005-11-24 | 바셀 테크놀로지 캄파니 비이브이 | 올레핀 중합용 촉매 성분 |
| DE69905231T2 (de) | 1998-07-08 | 2003-11-13 | Basell Poliolefine Italia S.P.A., Mailand/Milano | Verfahren und vorrichtung zur gasphasenpolymerisation |
| US6395831B1 (en) | 1998-08-20 | 2002-05-28 | Baselltech Usa Inc. | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility |
| ATE464365T1 (de) | 1998-12-24 | 2010-04-15 | Basell Poliolefine Srl | Flaschenverschlüsse aus polyolefinen |
| WO2000053646A1 (en) | 1999-03-09 | 2000-09-14 | Basell Technology Company B.V. | Multi-stage process for the (co)polymerization of olefins |
| ID28962A (id) * | 1999-09-14 | 2001-07-19 | Baselltech Usa Inc | Komposisi poliolefin yang tahan benturan |
| CN1137155C (zh) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
| DE60012145T2 (de) | 1999-12-16 | 2005-08-18 | Basell Poliolefine Italia S.P.A. | Statistische propylen/alpha-olefin copolymerzusammensetzung |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| RU2002117429A (ru) | 2000-09-15 | 2003-12-20 | Бэйселлтек Ю Эс Эй Инк. (Us) | Неэкструдированные дисперсии и концентраты добавок в олефиновых полимерах |
| US6586531B2 (en) | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
| JP2002173504A (ja) * | 2000-11-29 | 2002-06-21 | Basell Technology Co Bv | オレフィン重合用触媒およびオレフィン重合方法 |
| AU2002217104A1 (en) | 2000-12-15 | 2002-06-24 | Basell Poliolefine Italia S.P.A. | Continuous process for the preparation of solid catalyst components for the polymerisation of alpha-olefins |
| TWI238169B (en) | 2000-12-22 | 2005-08-21 | Basell Technology Co Bv | Bioriented polypropylene films |
| JP2004516373A (ja) | 2000-12-22 | 2004-06-03 | バセル ポリオレフィン イタリア エス．ピー．エー． | 熱成形用ポリオレフィンシート |
| WO2002096957A1 (en) * | 2001-05-29 | 2002-12-05 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| EP1279699A1 (en) | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
| MY132768A (en) | 2001-10-09 | 2007-10-31 | Basell Poliolefine Italia Spa | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility. |
| JP2005507444A (ja) | 2001-10-30 | 2005-03-17 | バセル ポリオレフィン イタリア エス．ピー．エー． | ポリプロピレン組成物についての管システム |
| ATE324387T1 (de) | 2001-11-27 | 2006-05-15 | Basell Poliolefine Srl | Durchsichtige und flexible polypropenzusammensetzungen |
| TWI268939B (en) | 2001-12-12 | 2006-12-21 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| ES2322047T3 (es) | 2002-03-08 | 2009-06-16 | Basell Poliolefine Italia S.R.L. | Proceso para obtener un componente catalizador basado en un dieter. |
| ATE382641T1 (de) | 2002-03-08 | 2008-01-15 | Basell Poliolefine Srl | Verfahren zur polymerisation von olefinen |
| WO2003076508A1 (en) | 2002-03-12 | 2003-09-18 | Basell Poliolefine Italia S.P.A. | Polyolefin compositions having high fluidity |
| US6743864B2 (en) | 2002-03-12 | 2004-06-01 | Basell Poliolefine Italia S.P.A. | Polyolefin compositions having high tenacity |
| MXPA04012697A (es) | 2002-06-26 | 2005-03-23 | Basell Poliolefine Spa | Composiciones de poliolefina resistentes al impacto. |
| WO2004003073A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A | Impact-resistant polyolefin compositions |
| CN100564399C (zh) | 2002-08-01 | 2009-12-02 | 巴塞尔聚烯烃意大利有限公司 | 性能改进的高度立构有规聚丙烯 |
| US7125924B2 (en) | 2002-09-17 | 2006-10-24 | Basell Poliolefine Italia S.P.A. | Highly filled soft polyolefin compositions |
| CA2510254A1 (en) * | 2002-12-18 | 2004-07-01 | Basell Poliolefine Italia S.P.A. | Magnesium dichloride-based adducts and catalyst components obtained therefrom |
| US7288598B2 (en) | 2003-03-06 | 2007-10-30 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch for preparing impact-resistant polyolefin articles |
| MY136027A (en) | 2003-04-02 | 2008-07-31 | Basell Poliolefine Spa | Polyolefin masterbatch and composition suitable for injection molding |
| TW200427763A (en) | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| CA2534524A1 (en) | 2003-08-05 | 2005-02-17 | Basell Poliolefine Italia S.R.L. | Polyolefin articles |
| TW200505985A (en) | 2003-08-07 | 2005-02-16 | Basell Poliolefine Spa | Polyolefin composition having a high balance of stiffness and impact strength |
| JP2007510771A (ja) * | 2003-11-06 | 2007-04-26 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリプロピレン組成物 |
| CN1894448A (zh) | 2003-12-19 | 2007-01-10 | 巴塞尔聚烯烃意大利有限责任公司 | 由丙烯和1－己烯的共聚物制造的纤维 |
| US7405260B2 (en) | 2004-03-03 | 2008-07-29 | Basell Poliolefine Italia S.R.L. | Method for controlling the polymer flow in a polymerization process |
| KR20070011378A (ko) * | 2004-03-29 | 2007-01-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 염화마그네슘 기재 부가물 및 이로부터 수득된 촉매 성분 |
| JP2007538119A (ja) | 2004-05-21 | 2007-12-27 | バセル ポリオレフィン イタリア エス．アール．エル． | 耐衝撃性ポリオレフィン組成物 |
| ES2296190T3 (es) | 2004-06-08 | 2008-04-16 | Basell Poliolefine Italia S.R.L. | Composicion polilefinica que tiene una alto equilibrio de rigidea, resistencia al impacto y alargamiento en rotura y bajo encogimmiento termico. |
| ES2343070T3 (es) | 2004-06-18 | 2010-07-22 | Basell Poliolefine Italia S.R.L. | Procedimiento para la preparacion de componentes catalizadores para la polimerizacion de olefinas. |
| US8017206B2 (en) | 2004-06-25 | 2011-09-13 | Basell Poliolefine Italia S.R.L. | Pipe systems made from random copolymers of propylene and α-olefins |
| US7772324B2 (en) | 2004-10-04 | 2010-08-10 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| US7652108B2 (en) | 2004-10-14 | 2010-01-26 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization olefins |
| CN100389112C (zh) * | 2004-12-16 | 2008-05-21 | 中国石油化工股份有限公司 | 一类环状缩醛和缩酮化合物及其应用 |
| EP1827825A1 (en) | 2004-12-21 | 2007-09-05 | Basell Poliolefine Italia S.r.l. | Heat-sealable polyolefin films |
| WO2006067023A1 (en) | 2004-12-23 | 2006-06-29 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions having good whitening resistance |
| CN101115797B (zh) | 2005-02-03 | 2011-10-19 | 巴塞尔聚烯烃意大利有限责任公司 | 用于注塑的丙烯聚合物组合物 |
| WO2006114358A2 (en) | 2005-04-28 | 2006-11-02 | Basell Poliolefine Italia S.R.L. | Reinforced polypropylene pipe |
| EP1879931B2 (en) * | 2005-05-12 | 2024-07-17 | Basell Poliolefine Italia S.r.l. | Propylene-ethylene copolymers and process for their preparation |
| WO2006120187A1 (en) | 2005-05-13 | 2006-11-16 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| JP5175180B2 (ja) | 2005-05-27 | 2013-04-03 | サンアロマー株式会社 | 良好な白化抵抗を有するポリオレフィン性組成物 |
| BRPI0615488B1 (pt) | 2005-07-01 | 2017-07-04 | Basell Poliolefine Italia S.R.L | Polymers of propylene having a large distribution of molecular weight |
| KR100639696B1 (ko) * | 2005-07-01 | 2006-10-30 | 에스케이 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용아릴페녹시 촉매계 |
| US7794845B2 (en) | 2005-07-11 | 2010-09-14 | Basell Poliolefine Italia S.R.L. | Metallized propylene polymer film with good barrier retention properties |
| AU2006316650A1 (en) | 2005-11-22 | 2007-05-31 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions having low gloss |
| US7872074B2 (en) | 2005-11-22 | 2011-01-18 | Basell Poliolefine Italia S.R.L. | Impact resistant polyolefin compositions |
| WO2007071622A1 (en) | 2005-12-20 | 2007-06-28 | Basell Poliolefine Italia S.R.L. | Polypropylene compositions for stretched articles |
| US8343602B2 (en) | 2006-02-23 | 2013-01-01 | Basell Poliolefine Italia, s.r.l. | Propylene polymers for injection molding applications |
| EP1845112A1 (en) | 2006-04-12 | 2007-10-17 | Total Petrochemicals Research Feluy | Controlled distribution of active sites in Ziegler-Natta catalysts systems |
| JP2009541545A (ja) | 2006-06-23 | 2009-11-26 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | マグネシウムクロロアルコレートをベースとする触媒前駆体 |
| TWI496762B (zh) | 2006-07-24 | 2015-08-21 | 製備（１ｒ，２ｒ）-３-（３-二甲胺基-１-乙基-２-甲基-丙基）-酚之方法 | |
| EP2046845B1 (en) | 2006-07-28 | 2012-06-06 | Basell Poliolefine Italia S.r.l. | Propylene polymers |
| EP2084223B1 (en) | 2006-11-23 | 2010-07-28 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| EP2089469B1 (en) | 2006-12-07 | 2011-08-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions having low hardness and low gloss |
| US8071686B2 (en) | 2006-12-07 | 2011-12-06 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions having low hardness and low gloss |
| EP2099834B1 (en) | 2006-12-21 | 2010-03-03 | Basell Poliolefine Italia S.R.L. | High shrink polypropylene films |
| JP5583973B2 (ja) | 2006-12-22 | 2014-09-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用の触媒成分及びそれから得られる触媒 |
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| EP2070956A1 (en) | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a bimodal polypropylene having low ash content |
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| JP5518698B2 (ja) | 2007-05-22 | 2014-06-11 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 軟質プロピレンポリマー組成物の製造方法 |
| CN101323650B (zh) | 2007-06-13 | 2010-11-03 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂及其制备方法和应用 |
| BRPI0813543B1 (pt) * | 2007-08-03 | 2019-10-08 | Basell Poliolefine Italia S.R.L. | Terpolímero de propileno, processo para sua produção e película compreendendo o mesmo |
| US8779058B2 (en) | 2007-08-24 | 2014-07-15 | William G. Sheard | High melt flow propylene impact copolymer and method |
| US10647788B2 (en) | 2007-08-24 | 2020-05-12 | W. R. Grace & Co-.Conn. | Self-limiting catalyst system with controlled aluminum to SCA ratio and method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1227259B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Catalizzatori per la polimerizzazione di olefine. |
| IT1237812B (it) * | 1989-12-22 | 1993-06-17 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1241093B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| DE69127220T2 (de) * | 1990-04-13 | 1998-01-02 | Mitsui Petrochemical Ind | Festes Titan enthaltendes Katalysatorbestandteil und Katalysator für Olefinpolymerisation, vorpolymerisierte Olefinpolymerisationskatalysator und Verfahren für Olefinpolymerisation |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
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1996
- 1996-02-12 IL IL11711496A patent/IL117114A/xx not_active IP Right Cessation
- 1996-02-13 CA CA002169401A patent/CA2169401C/en not_active Expired - Fee Related
- 1996-02-13 MY MYPI96000538A patent/MY115716A/en unknown
- 1996-02-16 AU AU45594/96A patent/AU699522B2/en not_active Ceased
- 1996-02-16 BR BR9600767A patent/BR9600767A/pt not_active IP Right Cessation
- 1996-02-18 CN CN96107325A patent/CN1090194C/zh not_active Expired - Fee Related
- 1996-02-20 UA UA96020629A patent/UA60290C2/uk unknown
- 1996-02-20 HU HU9600390A patent/HU221228B1/hu not_active IP Right Cessation
- 1996-02-20 NO NO960669A patent/NO309380B1/no not_active IP Right Cessation
- 1996-02-20 RU RU96103154/04A patent/RU2156260C2/ru active
- 1996-02-20 IN IN316CA1996 patent/IN186169B/en unknown
- 1996-02-21 AR ARP960101455A patent/AR000994A1/es unknown
- 1996-02-21 FI FI960786A patent/FI119643B/fi not_active IP Right Cessation
- 1996-02-21 KR KR1019960004091A patent/KR100424925B1/ko not_active Expired - Fee Related
- 1996-02-21 JP JP03409196A patent/JP3904117B2/ja not_active Expired - Fee Related
- 1996-02-21 DE DE69600532T patent/DE69600532T2/de not_active Expired - Lifetime
- 1996-02-21 ES ES96102584T patent/ES2121446T3/es not_active Expired - Lifetime
- 1996-02-21 AT AT96102584T patent/ATE169937T1/de active
- 1996-02-21 EP EP96102584A patent/EP0728769B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69600532D1 (de) | 1998-09-24 |
| CN1143651A (zh) | 1997-02-26 |
| DE69600532T2 (de) | 1999-03-18 |
| HU9600390D0 (en) | 1996-04-29 |
| ES2121446T3 (es) | 1998-11-16 |
| HUP9600390A2 (en) | 1997-04-28 |
| AR000994A1 (es) | 1997-08-27 |
| CN1090194C (zh) | 2002-09-04 |
| IL117114A0 (en) | 1996-07-23 |
| KR960031489A (ko) | 1996-09-17 |
| AU4559496A (en) | 1996-08-29 |
| MY115716A (en) | 2003-08-30 |
| JPH0920803A (ja) | 1997-01-21 |
| AU699522B2 (en) | 1998-12-03 |
| FI119643B (fi) | 2009-01-30 |
| BR9600767A (pt) | 1997-12-23 |
| NO960669D0 (no) | 1996-02-20 |
| FI960786A0 (fi) | 1996-02-21 |
| RU2156260C2 (ru) | 2000-09-20 |
| NO309380B1 (no) | 2001-01-22 |
| HUP9600390A3 (en) | 2000-03-28 |
| CA2169401A1 (en) | 1996-08-22 |
| MX9600627A (es) | 1997-07-31 |
| UA60290C2 (uk) | 2003-10-15 |
| ATE169937T1 (de) | 1998-09-15 |
| FI960786L (fi) | 1996-08-22 |
| HK1010379A1 (en) | 1999-06-17 |
| KR100424925B1 (ko) | 2004-06-26 |
| EP0728769B1 (en) | 1998-08-19 |
| IN186169B (h) | 2001-06-30 |
| EP0728769A1 (en) | 1996-08-28 |
| NO960669L (no) | 1996-08-22 |
| JP3904117B2 (ja) | 2007-04-11 |
| HU221228B1 (en) | 2002-08-28 |
| IL117114A (en) | 2000-02-17 |
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