JP4938446B2 - パイプ反応器を用いるポリエステル化方法 - Google Patents
パイプ反応器を用いるポリエステル化方法 Download PDFInfo
- Publication number
- JP4938446B2 JP4938446B2 JP2006514954A JP2006514954A JP4938446B2 JP 4938446 B2 JP4938446 B2 JP 4938446B2 JP 2006514954 A JP2006514954 A JP 2006514954A JP 2006514954 A JP2006514954 A JP 2006514954A JP 4938446 B2 JP4938446 B2 JP 4938446B2
- Authority
- JP
- Japan
- Prior art keywords
- pipe
- reaction method
- liquid
- dimensionless
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 51
- 229920000728 polyester Polymers 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 239000000376 reactant Substances 0.000 claims description 32
- 238000005886 esterification reaction Methods 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 27
- 230000032050 esterification Effects 0.000 claims description 26
- 238000006068 polycondensation reaction Methods 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 11
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- 150000002009 diols Chemical class 0.000 claims description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 47
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 30
- 238000004088 simulation Methods 0.000 description 14
- 241000183024 Populus tremula Species 0.000 description 12
- 239000000178 monomer Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- -1 aromatic dicarboxylic acids Chemical class 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 4
- QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- LNGAGQAGYITKCW-UHFFFAOYSA-N dimethyl cyclohexane-1,4-dicarboxylate Chemical compound COC(=O)C1CCC(C(=O)OC)CC1 LNGAGQAGYITKCW-UHFFFAOYSA-N 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 235000020030 perry Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- IUYYVMKHUXDWEU-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,1-diol Chemical compound CC(C)CC(C)(C)C(O)O IUYYVMKHUXDWEU-UHFFFAOYSA-N 0.000 description 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 description 1
- ICPXIRMAMWRMAD-UHFFFAOYSA-N 2-[3-[2-[3-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C=CC(OCCO)=CC=1C(C)(C)C1=CC=CC(OCCO)=C1 ICPXIRMAMWRMAD-UHFFFAOYSA-N 0.000 description 1
- CPHURRLSZSRQFS-UHFFFAOYSA-N 3-[4-[2-[4-(3-hydroxypropoxy)phenyl]propan-2-yl]phenoxy]propan-1-ol Chemical compound C=1C=C(OCCCO)C=CC=1C(C)(C)C1=CC=C(OCCCO)C=C1 CPHURRLSZSRQFS-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- KLDXJTOLSGUMSJ-JGWLITMVSA-N Isosorbide Chemical compound O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-JGWLITMVSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- KBWLBXSZWRTHKM-UHFFFAOYSA-N [6-(hydroxymethyl)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-2-yl]methanol Chemical compound C1C(CO)CCC2CC(CO)CCC21 KBWLBXSZWRTHKM-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- XYHMJVZAEWACCS-UHFFFAOYSA-N dimethyl 1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene-2,6-dicarboxylate Chemical compound C1C(C(=O)OC)CCC2CC(C(=O)OC)CCC21 XYHMJVZAEWACCS-UHFFFAOYSA-N 0.000 description 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 1
- GYUVMLBYMPKZAZ-UHFFFAOYSA-N dimethyl naphthalene-2,6-dicarboxylate Chemical compound C1=C(C(=O)OC)C=CC2=CC(C(=O)OC)=CC=C21 GYUVMLBYMPKZAZ-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000012407 engineering method Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229960002479 isosorbide Drugs 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/81—Preparation processes using solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/456,309 | 2003-06-06 | ||
| US10/456,309 US7135541B2 (en) | 2003-06-06 | 2003-06-06 | Polyester process using a pipe reactor |
| PCT/US2004/016465 WO2005000461A1 (en) | 2003-06-06 | 2004-05-26 | Polyester process using a pipe reactor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006527279A JP2006527279A (ja) | 2006-11-30 |
| JP2006527279A5 JP2006527279A5 (https=) | 2007-05-17 |
| JP4938446B2 true JP4938446B2 (ja) | 2012-05-23 |
Family
ID=33490133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006514954A Expired - Lifetime JP4938446B2 (ja) | 2003-06-06 | 2004-05-26 | パイプ反応器を用いるポリエステル化方法 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US7135541B2 (https=) |
| EP (1) | EP1631379B1 (https=) |
| JP (1) | JP4938446B2 (https=) |
| KR (1) | KR101130871B1 (https=) |
| CN (1) | CN100512948C (https=) |
| AR (1) | AR044620A1 (https=) |
| BR (1) | BRPI0410976B1 (https=) |
| CA (1) | CA2527018C (https=) |
| ES (1) | ES2483899T3 (https=) |
| MX (1) | MXPA05013165A (https=) |
| MY (1) | MY141971A (https=) |
| PL (1) | PL1631379T3 (https=) |
| PT (1) | PT1631379E (https=) |
| RU (1) | RU2342406C2 (https=) |
| SI (1) | SI1631379T1 (https=) |
| TW (1) | TWI351413B (https=) |
| WO (1) | WO2005000461A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6906164B2 (en) | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
| US7332548B2 (en) | 2004-03-04 | 2008-02-19 | Eastman Chemical Company | Process for production of a polyester product from alkylene oxide and carboxylic acid |
| US7943094B2 (en) * | 2006-12-07 | 2011-05-17 | Grupo Petrotemex, S.A. De C.V. | Polyester production system employing horizontally elongated esterification vessel |
| US7649109B2 (en) | 2006-12-07 | 2010-01-19 | Eastman Chemical Company | Polyester production system employing recirculation of hot alcohol to esterification zone |
| US7863477B2 (en) | 2007-03-08 | 2011-01-04 | Eastman Chemical Company | Polyester production system employing hot paste to esterification zone |
| US7829653B2 (en) | 2007-07-12 | 2010-11-09 | Eastman Chemical Company | Horizontal trayed reactor |
| US7872089B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Multi-level tubular reactor with internal tray |
| US7858730B2 (en) | 2007-07-12 | 2010-12-28 | Eastman Chemical Company | Multi-level tubular reactor with dual headers |
| US7842777B2 (en) | 2007-07-12 | 2010-11-30 | Eastman Chemical Company | Sloped tubular reactor with divided flow |
| US7868129B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Sloped tubular reactor with spaced sequential trays |
| US7847053B2 (en) | 2007-07-12 | 2010-12-07 | Eastman Chemical Company | Multi-level tubular reactor with oppositely extending segments |
| US7872090B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Reactor system with optimized heating and phase separation |
| US7868130B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Multi-level tubular reactor with vertically spaced segments |
| DE102009016819B4 (de) * | 2009-04-09 | 2011-12-15 | Carl Zeiss Optronics Gmbh | Verfahren zur Detektion wenigstens eines Objekts und/oder wenigstens einer Objektgruppe, Computerprogramm, Computerprogammprodukt, Stereokameraeinrichtung, aktiv Strahlung aussendendes Bildsensorsystem und Überwachungsvorrichtung |
| CN112023852B (zh) * | 2019-06-03 | 2023-05-09 | 中国石油化工股份有限公司 | 一种苯部分加氢制备环己烯的生产装置 |
Family Cites Families (247)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2905707A (en) | 1959-09-22 | Production of bis | ||
| GB115812A (en) | 1915-08-30 | 1919-04-10 | Charles Franklin Kettering | Improvements in Ignition Systems for Internal Combustion Engines. |
| US2361717A (en) | 1940-09-12 | 1944-10-31 | Du Pont | Process for making polyamides |
| US2753249A (en) | 1950-10-06 | 1956-07-03 | Exxon Research Engineering Co | Catalytic polymerization apparatus |
| US2709642A (en) | 1951-12-03 | 1955-05-31 | Exxon Research Engineering Co | Chemical reactor |
| US2973341A (en) | 1956-01-25 | 1961-02-28 | Glanzstoff Ag | Continuous process for production of a polyethylene terephthalate condensate |
| NL108873C (https=) | 1957-01-17 | |||
| US2829153A (en) | 1957-03-04 | 1958-04-01 | Du Pont | Continuous ester interchange process |
| NL96710C (https=) | 1957-09-28 | |||
| US3254965A (en) | 1958-11-28 | 1966-06-07 | Phillips Petroleum Co | Polymerization control apparatus |
| US3113843A (en) | 1959-01-27 | 1963-12-10 | Du Pont | Apparatus for separating a vapor from a viscous material such as molten polymer |
| US3192184A (en) | 1959-03-19 | 1965-06-29 | Du Pont | Prepolymerization process |
| NL255414A (https=) | 1959-08-31 | |||
| US3052711A (en) | 1960-04-20 | 1962-09-04 | Du Pont | Production of di(beta-hydroxyethyl) terephthalate |
| US3110547A (en) | 1961-07-26 | 1963-11-12 | Du Pont | Polymerization process |
| US3161710A (en) | 1961-07-27 | 1964-12-15 | Du Pont | Polymerization process for polyester films |
| GB988548A (en) | 1961-08-30 | 1965-04-07 | Goodyear Tire & Rubber | Method for preparing polyester resins |
| BE634031A (https=) | 1962-06-23 | |||
| NL130338C (https=) | 1963-06-11 | 1900-01-01 | ||
| US3241926A (en) | 1963-11-15 | 1966-03-22 | Monsanto Co | Apparatus for continuously polycondensing polymethylene glycol esters of aromatic dicarboxylic acids |
| NO116966B (https=) | 1964-06-01 | 1969-06-16 | Consanto Co | |
| DE1240286B (de) | 1965-01-02 | 1967-05-11 | Basf Ag | Verfahren zur kontinuierlichen Emulsions-polymerisation olefinisch ungesaettigter Verbindungen |
| NL131998C (https=) | 1965-06-09 | |||
| US3442868A (en) | 1965-07-20 | 1969-05-06 | Teijin Ltd | Novel process for the preparation of polyester |
| CH487345A (de) | 1965-11-11 | 1970-03-15 | Karl Fischer App Und Rohrleitu | Verfahren zur Förderung eines dampfförmigen Stoffes und Anwendung dieses Verfahrens |
| ES337977A1 (es) | 1966-03-23 | 1968-03-16 | Fiber Industries Inc | Un procedimiento para la produccion de polimeros lineales de bajo peso molecular de acido tereftalico y etilenglicol. |
| US3496220A (en) | 1966-04-04 | 1970-02-17 | Mobil Oil Corp | Esterification process |
| GB1111815A (en) | 1966-04-22 | 1968-05-01 | Ici Ltd | Polyester preparation |
| CH465875A (de) | 1966-09-16 | 1968-11-30 | Inventa Ag | Verfahren zur kontinuierlichen Herstellung von Polyestern |
| US3590072A (en) | 1966-11-18 | 1971-06-29 | Monsanto Co | Method for direct esterification of terephthalic acid with ethylene glycol |
| US3639448A (en) | 1966-12-30 | 1972-02-01 | Mitsubishi Chem Ind | Process for producing bis(beta-hydroxyethyl)-terephthalate and/or prepolymer thereof |
| US3487049A (en) | 1967-01-04 | 1969-12-30 | Du Pont | Process for producing polyethylene terephthalate |
| US3522214A (en) | 1967-04-13 | 1970-07-28 | Mobil Oil Corp | Process and apparatus for polymerizing liquids |
| GB1154538A (en) | 1967-04-19 | 1969-06-11 | Mobil Oil Corp | Esterifying Viscous Reaction Mixtures |
| US3595846A (en) | 1967-05-02 | 1971-07-27 | Michelin & Cie | Continuous chemical reactions |
| US3497743A (en) | 1967-06-16 | 1970-02-24 | United Aircraft Corp | Annular multiple beam contoured cathode device |
| US3496146A (en) | 1967-08-23 | 1970-02-17 | Du Pont | Preparation of glycol terephthalate linear polyester by direct esterification of terephthalic acid |
| US4020049A (en) | 1967-09-14 | 1977-04-26 | The Goodyear Tire & Rubber Company | Process for preparing polyester resin |
| US3551396A (en) | 1968-01-05 | 1970-12-29 | Gulf Oil Canada Ltd | Continuous vinyl polymerization process |
| NL6809754A (https=) | 1968-04-11 | 1969-10-14 | ||
| US3609125A (en) | 1968-04-24 | 1971-09-28 | Asahi Chemical Ind | Polyesterification process and apparatus |
| FR1583867A (https=) | 1968-05-15 | 1969-12-05 | ||
| US3590070A (en) | 1968-06-03 | 1971-06-29 | Celanese Corp | Recycle of terephthalic acid in the production of a bis(2-hydroxyalkyl) terephthalate |
| US3651125A (en) | 1968-08-12 | 1972-03-21 | Eastman Kodak Co | Continuous method for formation of a liquid monomer for a condensation polymer |
| US3646102A (en) | 1968-08-28 | 1972-02-29 | Idemitsu Kosan Co | Method for continuously preparing polycarbonate oligomer |
| NL160174C (nl) | 1968-12-12 | 1979-10-15 | Snia Viscosa | Inrichting voor het volumetrisch afvoeren van een viskeuze vloeistof uit een ruimte voor het continu behandelen van polymeren. |
| CH521400A (de) | 1969-01-24 | 1972-04-15 | Inventa Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polylactamen |
| US3697579A (en) | 1969-09-18 | 1972-10-10 | Allied Chem | Method of esterifying a polycarboxylic acid with a glycol |
| US3689461A (en) | 1969-09-18 | 1972-09-05 | Allied Chem | Process for the preparation of linear condensation polyesters |
| BE759208A (fr) | 1969-11-22 | 1971-05-21 | Basf Ag | Procede de preparation continue de |
| US3644096A (en) | 1970-03-30 | 1972-02-22 | Eastman Kodak Co | Apparatus for use in a continuous flow reaction for producing a monomer and/or a protopolymer |
| US3684459A (en) | 1970-08-20 | 1972-08-15 | Phillips Fibers Corp | Plug metered evaporative reaction tube |
| NL7016364A (https=) | 1970-10-21 | 1972-04-25 | ||
| GB1380266A (en) | 1971-05-21 | 1975-01-08 | Agfa Gevaert | Process for the semi-continuous preparation of high-molecular weight linear polyesters |
| DE2145761C3 (de) | 1971-09-14 | 1978-06-15 | Davy International Ag, 6000 Frankfurt | Verfahren zur Einführung pulverförmiger Terephthalsäure in ein Reaktionsgemisch aus teilweise mit Diolen veresterter Terephthalsäure |
| US3740267A (en) | 1971-09-22 | 1973-06-19 | Allied Chem | Method of cleaning apparatus used in processing polyethylene terephthalate |
| US3819585A (en) | 1971-09-30 | 1974-06-25 | Monsanto Co | Polyester esterification under two different pressures |
| GB1395551A (en) | 1971-12-29 | 1975-05-29 | Kanebo Ltd | Method of producing polyesters |
| DE2200832A1 (de) | 1972-01-08 | 1973-07-12 | Schwarza Chemiefaser | Verfahren zur kontinuierlichen herstellung von oligomeren des bis - (betahydroxyaethyl) - terephthalates |
| FR2168990A1 (en) | 1972-01-28 | 1973-09-07 | Schwarza Chemiefaser | Bis-(beta-hydroxyethyl) terephthalate oligomers prodn - by continuous reaction in stirred still and flow tube |
| BE780142A (en) | 1972-03-02 | 1972-09-04 | Sandoz Sa | Polyester prepn - by solid phase condensation in heated tubular reactors under vacuum with opt heated transport screws |
| JPS4894795A (https=) | 1972-03-18 | 1973-12-06 | ||
| DE2227091A1 (de) | 1972-06-03 | 1973-12-13 | Davy Ashmore Ag | Verfahren zur herstellung von hochpolymeren, insbesondere spinnfaehigen, polyestermassen |
| JPS5534822B2 (https=) | 1972-07-14 | 1980-09-09 | ||
| ZA734645B (en) * | 1972-07-21 | 1974-04-24 | Ici Ltd | Manufacture of polyesters |
| JPS537477B2 (https=) | 1972-07-31 | 1978-03-17 | ||
| US4100142A (en) | 1972-09-13 | 1978-07-11 | Fiber Industries, Inc. | Polyester process and product |
| JPS49105893A (https=) | 1973-02-07 | 1974-10-07 | ||
| GB1474524A (https=) | 1973-07-06 | 1977-05-25 | ||
| US3927983A (en) | 1973-09-19 | 1975-12-23 | Monsanto Co | Continuous staged isobaric stirred polymerization apparatus |
| GB1486409A (en) | 1973-11-06 | 1977-09-21 | Agfa Gevaert | Process for the preparation of high-molecular weight polyesters |
| JPS5082197A (https=) | 1973-11-21 | 1975-07-03 | ||
| CA1024294A (en) | 1974-02-27 | 1978-01-10 | Du Pont Of Canada Limited | Control in preparing polyamides by continuous polymerization |
| US4077945A (en) | 1974-03-23 | 1978-03-07 | Zimmer Aktiengesellschaft | Process for making linear polyesters from ethylene glycol and terephthalic acid |
| JPS5129460A (en) | 1974-09-02 | 1976-03-12 | Asahi Chemical Ind | Esuterukahoho narabini sochi |
| DE2443566A1 (de) | 1974-09-12 | 1976-04-01 | Basf Ag | Verfahren zum kontinuierlichen herstellen von polyamiden |
| DE2504258A1 (de) | 1975-02-01 | 1976-08-05 | Dynamit Nobel Ag | Verfahren und apparatur zur herstellung von oligomeren alkylenterephthalaten |
| JPS51100036A (ja) | 1975-03-03 | 1976-09-03 | Mitsubishi Rayon Co | Esuterukahoho |
| FR2302778A1 (fr) | 1975-03-05 | 1976-10-01 | Rhone Poulenc Ind | Appareil et procede de preparation de polyesters |
| DE2514116C3 (de) | 1975-03-29 | 1983-03-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen Herstellung von linearen, hochmolekularen Polybutylenterephthalaten |
| JPS51127031A (en) | 1975-04-23 | 1976-11-05 | Fuji Photo Film Co Ltd | Preparation of polyethylene terephthalate |
| JPS51136788A (en) | 1975-05-21 | 1976-11-26 | Kuraray Co Ltd | Continuo us process for preparing polyester using terephthalic acid |
| JPS51136789A (en) | 1975-05-21 | 1976-11-26 | Kuraray Co Ltd | Continuous process for preparing polyest er using terephthalic acid |
| US4028307A (en) | 1975-05-30 | 1977-06-07 | Fiber Industries, Inc. | Preparation of polyesters using salts of substituted quaternary ammonium bases |
| JPS5251495A (en) | 1975-10-23 | 1977-04-25 | Mitsubishi Chem Ind Ltd | A continuous process for preparing polyester |
| US4118582A (en) | 1975-10-28 | 1978-10-03 | E. I. Du Pont De Nemours And Company | Purification of spent ethylene glycol |
| JPS5271432A (en) | 1975-12-09 | 1977-06-14 | Teijin Ltd | Cntinuus feeding of terephthalic acid and alkylene gylcol |
| JPS5278845A (en) | 1975-12-24 | 1977-07-02 | Mitsubishi Rayon Co Ltd | Esterification |
| JPS5827782B2 (ja) | 1975-12-30 | 1983-06-11 | 東レ株式会社 | エステルカホウホウ |
| DE2559290B2 (de) | 1975-12-31 | 1979-08-02 | Davy International Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von hochmolekularem PoIyäthylenterephthalat |
| JPS5833855B2 (ja) | 1976-01-12 | 1983-07-22 | 東レ株式会社 | エステル化方法 |
| US4079046A (en) | 1976-06-03 | 1978-03-14 | Monsanto Company, St. Louis, Missouri | Multiple polyesterification process |
| JPS52150496A (en) | 1976-06-09 | 1977-12-14 | Mitsubishi Gas Chem Co Inc | Preparation of polycaronate oligomers |
| US4046718A (en) | 1976-06-17 | 1977-09-06 | The Dow Chemical Company | Polymerization method employing tubular reactor |
| US4089888A (en) | 1976-07-12 | 1978-05-16 | Idemitsu Petrochemical Co. Ltd. | Method for producing a polycarbonate oligomer |
| JPS5331793A (en) | 1976-09-06 | 1978-03-25 | Toray Ind Inc | Preparation of particle-containing polyester |
| JPS5334894A (en) | 1976-09-14 | 1978-03-31 | Toray Ind Inc | Preparation of polyester |
| US4097468A (en) | 1977-03-15 | 1978-06-27 | Allied Chemical Corporation | Process for preparing polyesters |
| US4146729A (en) | 1977-04-07 | 1979-03-27 | E. I. Du Pont De Nemours And Company | Process for preparing poly(ethylene terephthalate) |
| US4110316A (en) | 1977-04-14 | 1978-08-29 | E. I. Du Pont De Nemours And Company | Improved process for preparing poly(ethylene terephthalate) |
| DE2719967A1 (de) | 1977-05-04 | 1978-11-09 | Bayer Ag | Kontinuierliches verfahren zur durchfuehrung von stofftransportbedingten reaktionen |
| GB1558910A (en) | 1977-05-04 | 1980-01-09 | Bayer Ag | Continuous process for the production of polybutylene terephthalates |
| IT1097584B (it) | 1977-08-24 | 1985-08-31 | Basf Ag | Processo ed apparecchio per la preparazione di poliesteri macronolecolari linerai |
| JPS5441833A (en) | 1977-09-02 | 1979-04-03 | Toray Ind Inc | Method of esterification |
| JPS5476535A (en) | 1977-11-22 | 1979-06-19 | Toray Ind Inc | Esterification |
| JPS5479242A (en) | 1977-12-05 | 1979-06-25 | Teijin Ltd | Method of esterification |
| US4365078A (en) | 1977-12-16 | 1982-12-21 | The Goodyear Tire & Rubber Company | Process for charging dry terephthalic acid into a reactor |
| CA1115446A (en) | 1977-12-16 | 1981-12-29 | Lawrence E. Shelley | Process |
| JPS6017291B2 (ja) | 1978-01-25 | 1985-05-02 | 東レ株式会社 | ポリエステルの製造方法 |
| JPS54157536A (en) | 1978-05-29 | 1979-12-12 | Toray Ind Inc | Esterification process |
| JPS5543128A (en) | 1978-09-22 | 1980-03-26 | Toray Ind Inc | Production of polyester film with high transparency |
| JPS55108422A (en) | 1979-02-15 | 1980-08-20 | Toray Ind Inc | Batch-wise esterification |
| US4230818A (en) | 1979-03-01 | 1980-10-28 | The Goodyear Tire & Rubber Company | Reduction of glycol ethers in polyesters |
| US4254246A (en) | 1979-03-26 | 1981-03-03 | Davy International Ag | Column system process for polyester plants |
| JPS55135133A (en) | 1979-04-10 | 1980-10-21 | Mitsubishi Chem Ind Ltd | Continuous production of polyester |
| PL127634B1 (en) | 1979-05-23 | 1983-11-30 | Inst Chemii Przemyslowej | Continuous process for manufacturing polyesters and apparatus therefor |
| US4238593B1 (en) | 1979-06-12 | 1994-03-22 | Goodyear Tire & Rubber | Method for production of a high molecular weight polyester prepared from a prepolymer polyester having an optional carboxyl content |
| US4223124A (en) | 1979-06-22 | 1980-09-16 | The Goodyear Tire & Rubber Company | Method for producing polyesters containing low amounts of ether by-products |
| JPS5645704A (en) | 1979-09-21 | 1981-04-25 | Hitachi Ltd | Method and apparatus for removal of volatile substances from high-viscous substance |
| BR7906279A (pt) | 1979-10-01 | 1981-04-07 | Nippon Ester Co Ltd | Apereicoamento em processo continuo para produzir poliester e em processo para produzir uma fibra fiada a partir de polimero de poli(tereftalato de etileno) |
| US4452956A (en) | 1979-11-09 | 1984-06-05 | Union Carbide Corporation | Discrete spiral flow imparting device |
| SU973552A1 (ru) | 1980-02-12 | 1982-11-15 | Всесоюзный научно-исследовательский институт синтетических волокон | Непрерывный способ получени полиэтилентерефталата |
| US4289871A (en) | 1980-03-27 | 1981-09-15 | Allied Chemical Corporation | Method to increase reactor capacity for polycondensation of polyesters |
| JPS57101A (en) | 1980-06-04 | 1982-01-05 | Mitsui Petrochem Ind Ltd | Method and apparatus for polymerization |
| DE3025574A1 (de) | 1980-07-05 | 1982-02-04 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polyestern |
| DE3047474C2 (de) * | 1980-12-17 | 1983-05-11 | Didier Engineering Gmbh, 4300 Essen | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polyestern |
| US4499226A (en) | 1981-03-20 | 1985-02-12 | The Goodyear Tire & Rubber Company | High clarity colorless polyesters |
| US4346193A (en) | 1981-05-04 | 1982-08-24 | Atlantic Richfield Company | Continuous process for making star-block copolymers |
| JPS5823829A (ja) | 1981-07-17 | 1983-02-12 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | 合成重合体仕上げ装置 |
| US4397343A (en) | 1981-08-31 | 1983-08-09 | The Coe Manufacturing Co. | Log scanning in veneer lathe to determine optimum yield axis |
| US4410750A (en) | 1981-12-14 | 1983-10-18 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| JPS58129020A (ja) | 1982-01-27 | 1983-08-01 | Toray Ind Inc | ポリエステルの製造方法 |
| PL136188B1 (en) | 1982-04-16 | 1986-02-28 | Inst Chemii Przemyslowej | Continuous process for manufacturing polyesters and apparatus therefor |
| JPS5947226A (ja) | 1982-09-09 | 1984-03-16 | Toyobo Co Ltd | ポリエステルの製造法 |
| JPS5953530A (ja) | 1982-09-22 | 1984-03-28 | Toyobo Co Ltd | ポリエステルの製造方法 |
| US4548788A (en) | 1982-09-24 | 1985-10-22 | Cosden Technology, Inc. | Apparatus for producing styrenic/alkenylnitrile copolymers |
| US4542196A (en) | 1982-09-24 | 1985-09-17 | Cosden Technology, Inc. | Process for producing styrenic/alkenylnitrile copolymers |
| US4550149A (en) | 1982-09-24 | 1985-10-29 | Cosden Technology, Inc. | Process for producing styrenic/alkenylnitrile copolymers |
| US4551309A (en) | 1982-09-24 | 1985-11-05 | Cosden Technology, Inc. | Apparatus for producing styrenic/alkenylnitrile copolymers |
| US4551510A (en) | 1982-09-24 | 1985-11-05 | Cosden Technology, Inc. | Process for producing styrenic/alkenylnitrile copolymers |
| US4555384A (en) | 1982-09-24 | 1985-11-26 | Cosden Technology, Inc. | Apparatus for producing styrenic/alkenylnitrile copolymers |
| US4440924A (en) | 1982-10-05 | 1984-04-03 | Toyo Boseki Kabushiki Kaisha | Process for production of polyester |
| JPS5968326A (ja) | 1982-10-13 | 1984-04-18 | Toyobo Co Ltd | ポリエステルの製造法 |
| JPS5971326A (ja) | 1982-10-15 | 1984-04-23 | Toyobo Co Ltd | ポリエステルの製造法 |
| US4831108A (en) | 1983-02-16 | 1989-05-16 | Amoco Corporation | Polycondensation process with mean dispersion residence time |
| JPS6015421A (ja) | 1983-07-06 | 1985-01-26 | Nippon Ester Co Ltd | ポリエステルの製造方法 |
| JPS6072845A (ja) | 1983-09-28 | 1985-04-24 | Nippon Ester Co Ltd | テレフタル酸グリコ−ルエステルの連続製造法 |
| JPS60115551A (ja) | 1983-11-25 | 1985-06-22 | Nippon Ester Co Ltd | エステル化方法 |
| JPS60120839A (ja) | 1983-12-02 | 1985-06-28 | Nippon Ester Co Ltd | テレフタル酸とエチレングリコ−ルとのスラリ−の連続供給法 |
| JPS60163918A (ja) | 1984-02-06 | 1985-08-26 | Toyobo Co Ltd | ポリエステルの連続製造方法 |
| JPS60226846A (ja) | 1984-04-26 | 1985-11-12 | Nippon Ester Co Ltd | エステル化方法 |
| JPH0641513B2 (ja) | 1984-11-20 | 1994-06-01 | 三菱レイヨン株式会社 | ポリエステルの製造法 |
| US4554343A (en) | 1984-11-23 | 1985-11-19 | Eastman Kodak Company | Process for the production of high molecular weight polyester |
| US4675377A (en) | 1985-03-11 | 1987-06-23 | General Electric Company | Process for continuous preparation of polyphenylene oxide in agitated reaction zones |
| DE3544551C2 (de) | 1985-12-17 | 2002-02-28 | Zimmer Ag | Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polybutylenterephthalat |
| JPH06104718B2 (ja) | 1986-03-07 | 1994-12-21 | コニカ株式会社 | ポリエステルの製造方法 |
| US4670580A (en) | 1986-03-31 | 1987-06-02 | Celanese Corporation | Process for preparing oligomeric glycol esters of dicarboxylic acids |
| US4721575A (en) | 1986-04-03 | 1988-01-26 | Vertech Treatment Systems, Inc. | Method and apparatus for controlled chemical reactions |
| JPS62292831A (ja) | 1986-06-12 | 1987-12-19 | Teijin Ltd | ポリエステルの連続重合法 |
| EP0254304B1 (en) | 1986-07-25 | 1994-09-21 | Dainippon Ink And Chemicals, Inc. | Process for producing high impact styrene resin by continuous bulk polymerization |
| JP2512491B2 (ja) | 1987-08-27 | 1996-07-03 | 旭化成工業株式会社 | ポリエステルの連続重合方法 |
| JPH0813786B2 (ja) | 1987-10-15 | 1996-02-14 | 日本エステル株式会社 | エステル化方法 |
| DE3820362A1 (de) | 1988-06-15 | 1990-03-15 | Basf Ag | Verfahren zur kontinuierlichen herstellung von linearen thermoplastischen polyestern |
| US5041525A (en) | 1988-09-30 | 1991-08-20 | E. I. Du Pont De Nemours And Company | Process for manufacture of shaped polyethylene terephthalate structures in the presence of molecular sieve catalyst |
| US5413861A (en) | 1988-10-17 | 1995-05-09 | Dextor Corporation | Semiconductor device encapsulated with a flame retardant epoxy molding compound |
| US5194525A (en) | 1988-12-12 | 1993-03-16 | Dainippon Ink And Chemicals, Inc. | Continuous mass polymerization process for making styrene copolymers |
| US5162488A (en) | 1989-05-22 | 1992-11-10 | Hoechst Celanese Corporation | Catalyst system and process for preparing polyethylene terephthalate |
| JPH03192118A (ja) | 1989-12-21 | 1991-08-22 | Toray Ind Inc | ポリエステルの製造方法 |
| FR2660663B1 (fr) | 1990-04-05 | 1993-05-21 | Rhone Poulenc Fibres | Procede pour l'obtention de polyterephtalate d'ethylene modifie, fibres exemptes de boulochage issues du polymere ainsi modifie. |
| JPH03292323A (ja) | 1990-04-10 | 1991-12-24 | Fuji Photo Film Co Ltd | ポリエステルの製造方法 |
| US5064935A (en) | 1990-08-01 | 1991-11-12 | E. I. Dupont De Nemours And Company | Continuous process for preparing poly(butylene terephthalate) oligomer or poly(butylene isophthalate) oligomer |
| KR940009419B1 (ko) | 1991-02-07 | 1994-10-13 | 한국과학기술연구원 | 색조가 우수한 폴리에스테르의 제조방법 |
| EP0501543B1 (en) | 1991-02-28 | 1998-05-20 | Agfa-Gevaert N.V. | Process for the production of polyesters with increased electroconductivity |
| DE69214686T2 (de) | 1991-02-28 | 1997-06-05 | Agfa Gevaert Nv | Verfahren zur Herstellung von Polyestern mit verbesserter thermooxydativer Stabilität |
| JPH05222180A (ja) | 1992-02-17 | 1993-08-31 | Fuji Photo Film Co Ltd | ポリエステルの製造法 |
| DE4235785A1 (de) | 1992-10-23 | 1994-05-11 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Polymerisation |
| DE4240588A1 (de) | 1992-12-03 | 1994-06-09 | Bayer Ag | Verfahren zur Herstellung von Polycarbonaten |
| US5650536A (en) | 1992-12-17 | 1997-07-22 | Exxon Chemical Patents Inc. | Continuous process for production of functionalized olefins |
| JP3336658B2 (ja) | 1993-02-26 | 2002-10-21 | 三菱化学株式会社 | テレフタル酸の連続エステル化方法 |
| US5385773A (en) | 1993-04-27 | 1995-01-31 | Eastman Chemical Company | Copolyester of cyclohexanenedimethanol and process for producing such polyester |
| US5294305A (en) | 1993-05-06 | 1994-03-15 | Mobile Process Technology, Inc. | Ethylene glycol recovery process |
| US5340907A (en) | 1993-06-28 | 1994-08-23 | Eastman Chemical Company | Copolyester of cyclohexanedimethanol and process for producing such polyester |
| JP3309502B2 (ja) | 1993-07-12 | 2002-07-29 | 大日本インキ化学工業株式会社 | 生分解性ポリエステル系ポリマーの連続製造法 |
| US5411665A (en) | 1993-07-20 | 1995-05-02 | Scraggs; Charles R. | Methods for reducing and separating emulsions and homogeneous components from contaminated water |
| US5599900A (en) | 1993-10-18 | 1997-02-04 | E. I. Du Pont De Nemours And Company | Polyesters production process |
| JPH07118208A (ja) | 1993-10-19 | 1995-05-09 | Nippon Ester Co Ltd | テレフタル酸のエステル化方法 |
| EP0650995B1 (de) | 1993-11-02 | 2000-01-05 | Bayer Ag | Verfahren zur Herstellung von Asparaginsäure-haltigen Polymeren |
| JP3375403B2 (ja) | 1993-12-20 | 2003-02-10 | 日本エステル株式会社 | ポリエステルの製造方法 |
| TW330940B (en) | 1993-12-22 | 1998-05-01 | Mitsui Petroleum Chemicals Ind | A method of manufacturing polyesters |
| CA2139061C (en) | 1993-12-28 | 1998-12-08 | Mitsui Chemicals, Inc. | Process for preparing polyester |
| JP3710067B2 (ja) | 1994-02-25 | 2005-10-26 | 三菱化学ポリエステルフィルム株式会社 | ポリエステルの製造方法 |
| US5464590A (en) | 1994-05-02 | 1995-11-07 | Yount; Thomas L. | Reactor trays for a vertical staged polycondensation reactor |
| US5466419A (en) | 1994-05-02 | 1995-11-14 | Yount; Thomas L. | Split flow reactor trays for vertical staged polycondensation reactors |
| DE4419397A1 (de) | 1994-06-03 | 1995-12-14 | Zimmer Ag | Verfahren zur mehrstufigen Vakuumerzeugung bei der Polyester-Herstellung |
| JP3395423B2 (ja) | 1995-01-20 | 2003-04-14 | 三菱化学株式会社 | ポリエステル |
| US5811496A (en) | 1995-12-21 | 1998-09-22 | E.I. Du Pont De Nemours And Company | Process for polymerization of polyester oligomers |
| AU4696896A (en) | 1995-01-20 | 1996-08-07 | E.I. Du Pont De Nemours And Company | Process for polymerization of polyester oligomers |
| US5476919A (en) * | 1995-02-21 | 1995-12-19 | Minnesota Mining And Manufacturing Company | Process for esterification |
| US5466765A (en) | 1995-03-09 | 1995-11-14 | Eastman Chemical Company | Vaccum system for controlling pressure in a polyester process |
| DE19511483A1 (de) | 1995-03-29 | 1996-10-02 | Bayer Ag | Verfahren zur Herstellung von thermoplastischem Polycarbonat |
| JPH08283394A (ja) | 1995-04-10 | 1996-10-29 | Mitsui Petrochem Ind Ltd | ポリエチレンテレフタレートの製造方法 |
| JPH08283398A (ja) | 1995-04-14 | 1996-10-29 | Nippon Ester Co Ltd | ポリエステルの製造方法 |
| DE19524181A1 (de) | 1995-07-03 | 1997-01-09 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymeren |
| DE19524180A1 (de) | 1995-07-03 | 1997-01-09 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymeren |
| EP0755945B1 (de) | 1995-07-26 | 1998-11-25 | Sulzer Chemtech AG | Verfahren und Einrichtung zum Durchführen einer Polymerisation in einem Rohrreaktor |
| DE19530765A1 (de) | 1995-08-22 | 1997-02-27 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE19537930B4 (de) | 1995-10-12 | 2006-02-23 | Zimmer Ag | Verfahren zur Herstellung von klarsichtigem Polyester |
| KR100443389B1 (ko) | 1995-12-14 | 2004-11-16 | 이.아이,듀우판드네모아앤드캄파니 | 폴리에스테르 예비중합체의 제조 방법 |
| TW381104B (en) | 1996-02-20 | 2000-02-01 | Eastman Chem Co | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol |
| DE19608614A1 (de) | 1996-03-06 | 1997-09-11 | Basf Ag | Verfahren zur Aufarbeitung von Dihydroxyverbindungen enthaltenden Rückständen |
| PT889922E (pt) * | 1996-03-28 | 2002-10-31 | Du Pont | Aparelho e processo para a preparacao de uma reaccao de policondensacao |
| DE19618678A1 (de) | 1996-05-09 | 1997-11-13 | Basf Ag | Verfahren zur Herstellung von Polystyrol durch kontinuierliche anionische Polymerisation |
| US5898058A (en) | 1996-05-20 | 1999-04-27 | Wellman, Inc. | Method of post-polymerization stabilization of high activity catalysts in continuous polyethylene terephthalate production |
| JPH1036495A (ja) | 1996-07-25 | 1998-02-10 | Nippon Ester Co Ltd | 透明性に優れたポリエステルの連続製造法 |
| DE19634450A1 (de) | 1996-08-26 | 1998-03-05 | Basf Ag | Vorrichtung zur kontinuierlichen Durchführung chemischer Reaktionen |
| US5922828A (en) | 1996-09-03 | 1999-07-13 | Hoechst Celanese Corp. | Process for producing polyethylene terephthalate using a specific catalyst stabilizer system |
| TW541321B (en) | 1996-09-04 | 2003-07-11 | Hitachi Ltd | Process and apparatus for continuous polycondensation |
| JP3836228B2 (ja) | 1996-12-26 | 2006-10-25 | 三井化学株式会社 | 分離流による重合方法 |
| JP3489382B2 (ja) | 1997-03-19 | 2004-01-19 | 株式会社日立製作所 | 連続重縮合装置及び方法 |
| US6103859A (en) | 1997-04-09 | 2000-08-15 | Eastman Chemical Company | Late addition of supplemental ethylene glycol in the preparation of copolyesters |
| TW482790B (en) | 1997-05-06 | 2002-04-11 | Teijin Ltd | Method for continuous production of polyester |
| JP3489408B2 (ja) | 1997-09-19 | 2004-01-19 | 株式会社日立製作所 | ポリエステルの連続製造装置 |
| US5932105A (en) | 1997-10-01 | 1999-08-03 | Mobile Process Technology, Co. | Method of polyester manufacturing using crossflow membrane filtration |
| JPH11106489A (ja) | 1997-10-03 | 1999-04-20 | Nippon Ester Co Ltd | ポリエステル樹脂及びその製造方法 |
| JPH11217429A (ja) | 1998-02-05 | 1999-08-10 | Nippon Ester Co Ltd | ポリエステル樹脂の製造方法 |
| KR100348238B1 (ko) | 1998-02-27 | 2002-08-09 | 미쓰이 가가쿠 가부시키가이샤 | 신규 폴리에스테르 및 그의 제조방법 |
| US6113997A (en) | 1998-05-26 | 2000-09-05 | Shell Oil Company | Process to prepare a polyester resin |
| US6252034B1 (en) * | 1998-06-04 | 2001-06-26 | Teljin Limited | Process for producing a polycarbonate resin |
| FR2780986B1 (fr) | 1998-07-10 | 2000-09-29 | Electrolyse L | Procede de transformation de structures chimiques dans un fluide sous pression et en temperature et dispositif pour sa mise en oeuvre |
| US6069228A (en) | 1998-08-17 | 2000-05-30 | E. I. Du Pont De Nemours And Company | Process for preparing polyamides |
| JP2000095851A (ja) | 1998-09-22 | 2000-04-04 | Hitachi Ltd | ポリエチレンテレフタレートの製造方法 |
| US6127493A (en) | 1998-11-04 | 2000-10-03 | Arteva North America S.A.R.L. | Pressure polymerization of polyester |
| US6111064A (en) | 1998-11-04 | 2000-08-29 | The Regents Of The University Of California | Pressure polymerization of polyester |
| US6339031B1 (en) | 1998-12-29 | 2002-01-15 | Seng C. Tan | Microcellular carbon foams and microcellular C/C composites fabricated therefrom |
| AR024361A1 (es) | 1999-06-15 | 2002-10-02 | Dow Chemical Co | Proceso y aparato para preparar una composicion utilizando un reactor continuo y mezclador en serie |
| BE1012770A3 (nl) | 1999-07-02 | 2001-03-06 | Ineos Nv | Werkijze en inrichting voor het industrieel aanmaken van producten door middel van een alkoxylatiereactie. |
| US6623643B2 (en) | 1999-11-19 | 2003-09-23 | Microtek Medical Holdings, Inc. | Process for treatment of aqueous environments containing a water soluble polymer |
| US6359106B1 (en) | 2000-03-09 | 2002-03-19 | Hitachi, Ltd. | Production process and production apparatus for polybutylene terephthalate |
| EP1310496B1 (en) * | 2000-08-11 | 2006-12-06 | Kureha Corporation | Process for the preparation of cyclic esters and method for purification of the same |
| DE10048003A1 (de) | 2000-09-26 | 2002-04-11 | Basell Polypropylen Gmbh | Verfahren zur Voraktivierung von Katalysatoren |
| ES2540542T3 (es) * | 2000-12-07 | 2015-07-10 | Grupo Petrotemex, S.A. De C.V. | Procedimiento de poliéster de bajo coste que usa un reactor tubular |
| DE10126133B4 (de) | 2001-05-29 | 2007-03-29 | Karl-Heinz Wiltzer | Verfahren und Vorrichtung zur Herstellung von hochviskosen oder hochstabilisierten Polykondensaten und entmonomerisiertem PA 6 |
| KR100891603B1 (ko) | 2001-07-10 | 2009-04-08 | 가부시끼가이샤 구레하 | 폴리에스테르 제조방법 및 반응 장치 |
| DE10224883B4 (de) * | 2001-07-27 | 2010-07-29 | Heidelberger Druckmaschinen Ag | Trockenstation und Verfahren zum Trocknen von bedruckten Bogen |
| US6672373B2 (en) | 2001-08-27 | 2004-01-06 | Idalex Technologies, Inc. | Method of action of the pulsating heat pipe, its construction and the devices on its base |
| US7067088B2 (en) | 2002-01-12 | 2006-06-27 | Saudi Basic Industries Corporation | Stratified flow chemical reactor |
| US7074879B2 (en) * | 2003-06-06 | 2006-07-11 | Eastman Chemical Company | Polyester process using a pipe reactor |
-
2003
- 2003-06-06 US US10/456,309 patent/US7135541B2/en not_active Expired - Lifetime
-
2004
- 2004-05-24 TW TW093114658A patent/TWI351413B/zh not_active IP Right Cessation
- 2004-05-26 EP EP04776113.5A patent/EP1631379B1/en not_active Expired - Lifetime
- 2004-05-26 BR BRPI0410976A patent/BRPI0410976B1/pt active IP Right Grant
- 2004-05-26 KR KR1020057023136A patent/KR101130871B1/ko not_active Expired - Lifetime
- 2004-05-26 CA CA002527018A patent/CA2527018C/en not_active Expired - Lifetime
- 2004-05-26 MX MXPA05013165A patent/MXPA05013165A/es active IP Right Grant
- 2004-05-26 CN CNB2004800157604A patent/CN100512948C/zh not_active Expired - Lifetime
- 2004-05-26 WO PCT/US2004/016465 patent/WO2005000461A1/en not_active Ceased
- 2004-05-26 SI SI200432178T patent/SI1631379T1/sl unknown
- 2004-05-26 RU RU2005141581/04A patent/RU2342406C2/ru active
- 2004-05-26 JP JP2006514954A patent/JP4938446B2/ja not_active Expired - Lifetime
- 2004-05-26 PT PT47761135T patent/PT1631379E/pt unknown
- 2004-05-26 ES ES04776113.5T patent/ES2483899T3/es not_active Expired - Lifetime
- 2004-05-26 PL PL04776113T patent/PL1631379T3/pl unknown
- 2004-05-27 MY MYPI20042044A patent/MY141971A/en unknown
- 2004-06-04 AR ARP040101950A patent/AR044620A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP1631379B1 (en) | 2014-05-14 |
| PL1631379T3 (pl) | 2014-10-31 |
| ES2483899T3 (es) | 2014-08-08 |
| US20040249111A1 (en) | 2004-12-09 |
| CN1802203A (zh) | 2006-07-12 |
| CA2527018C (en) | 2008-08-19 |
| MY141971A (en) | 2010-08-16 |
| CA2527018A1 (en) | 2005-01-06 |
| BRPI0410976A (pt) | 2006-07-04 |
| WO2005000461A1 (en) | 2005-01-06 |
| MXPA05013165A (es) | 2006-03-17 |
| TW200505958A (en) | 2005-02-16 |
| SI1631379T1 (sl) | 2014-09-30 |
| EP1631379A1 (en) | 2006-03-08 |
| KR101130871B1 (ko) | 2012-03-28 |
| JP2006527279A (ja) | 2006-11-30 |
| RU2342406C2 (ru) | 2008-12-27 |
| RU2005141581A (ru) | 2006-05-27 |
| KR20060012660A (ko) | 2006-02-08 |
| CN100512948C (zh) | 2009-07-15 |
| TWI351413B (en) | 2011-11-01 |
| PT1631379E (pt) | 2014-07-29 |
| AR044620A1 (es) | 2005-09-21 |
| US7135541B2 (en) | 2006-11-14 |
| BRPI0410976B1 (pt) | 2015-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4938446B2 (ja) | パイプ反応器を用いるポリエステル化方法 | |
| JP5411179B2 (ja) | パイプ型反応器を用いるポリエステルプロセス | |
| RU2287536C2 (ru) | Способ введения компонента процесса получения сложного полиэфира в реакционную смесь при использовании рециркуляции (варианты) | |
| TWI332014B (en) | Polyester process using a pipe reactor | |
| RU2478423C2 (ru) | Реакторное устройство с оптимизированным нагреванием и разделением фаз | |
| CN101687168B (zh) | 带有间隔的有序塔板的倾斜管状反应器 | |
| TWI436821B (zh) | 具有垂直間隔段之多階式管狀反應器 | |
| TW200914122A (en) | Multi-level tubular reactor with internal tray | |
| CN101743058B (zh) | 水平的带有塔板的反应器 | |
| TH35756A (th) | เครื่องมือและกระบวนการที่ใช้ในปฏิกิริยาการควบแน่นของการเกิดโพลีเมอร์ | |
| TH20077B (th) | เครื่องมือและกระบวนการที่ใช้ในปฏิกิริยาการควบแน่นของการเกิดโพลีเมอร์ | |
| BRPI0808057B1 (pt) | " processo para a produção de poliéster ". |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070322 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070322 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091126 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091201 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100226 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100305 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100601 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110301 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110526 |
|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20110727 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120124 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120223 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150302 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4938446 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |