ZA9610306B - Processes using multistaged reactors - Google Patents

Processes using multistaged reactors

Info

Publication number
ZA9610306B
ZA9610306B ZA9610306A ZA9610306A ZA9610306B ZA 9610306 B ZA9610306 B ZA 9610306B ZA 9610306 A ZA9610306 A ZA 9610306A ZA 9610306 A ZA9610306 A ZA 9610306A ZA 9610306 B ZA9610306 B ZA 9610306B
Authority
ZA
South Africa
Prior art keywords
organophosphite ligand
processes
metal
complex catalyst
ligand complex
Prior art date
Application number
ZA9610306A
Other languages
English (en)
Inventor
Michael Carl Becker
Donald Leroy Bunning
Ernst Billig
David Robert Bryant
James Clair Nicholson
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27485760&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA9610306(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of ZA9610306B publication Critical patent/ZA9610306B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0259—Phosphorus acids or phosphorus acid esters comprising phosphorous acid (-ester) groups ((RO)P(OR')2) or the isomeric phosphonic acid (-ester) groups (R(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Lasers (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Pyridine Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Luminescent Compositions (AREA)
  • Glass Compositions (AREA)
  • Removal Of Specific Substances (AREA)
  • Design And Manufacture Of Integrated Circuits (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
ZA9610306A 1995-12-06 1996-12-06 Processes using multistaged reactors ZA9610306B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US876395P 1995-12-06 1995-12-06
US828695P 1995-12-06 1995-12-06
US828495P 1995-12-06 1995-12-06
US828995P 1995-12-06 1995-12-06

Publications (1)

Publication Number Publication Date
ZA9610306B true ZA9610306B (en) 1998-09-07

Family

ID=27485760

Family Applications (4)

Application Number Title Priority Date Filing Date
ZA9610308A ZA9610308B (en) 1995-12-06 1996-12-06 Processes employing indicator ligands
ZA9610312A ZA9610312B (en) 1995-12-06 1996-12-06 Metal-ligand complex catalyzed processes
ZA9610313A ZA9610313B (en) 1995-12-06 1996-12-06 Metal-ligand complex catalyzed processes
ZA9610306A ZA9610306B (en) 1995-12-06 1996-12-06 Processes using multistaged reactors

Family Applications Before (3)

Application Number Title Priority Date Filing Date
ZA9610308A ZA9610308B (en) 1995-12-06 1996-12-06 Processes employing indicator ligands
ZA9610312A ZA9610312B (en) 1995-12-06 1996-12-06 Metal-ligand complex catalyzed processes
ZA9610313A ZA9610313B (en) 1995-12-06 1996-12-06 Metal-ligand complex catalyzed processes

Country Status (18)

Country Link
US (12) US5741944A (uk)
EP (4) EP0876322B1 (uk)
JP (4) JP2002504888A (uk)
CN (4) CN1106374C (uk)
AT (1) ATE235451T1 (uk)
AU (4) AU719870B2 (uk)
BR (5) BR9611663A (uk)
CA (4) CA2230561C (uk)
DE (5) DE69613858T2 (uk)
EA (4) EA001608B1 (uk)
ES (9) ES2160853T3 (uk)
IN (2) IN228562B (uk)
MX (3) MX203408B (uk)
MY (1) MY115709A (uk)
PL (4) PL327115A1 (uk)
SK (4) SK68498A3 (uk)
WO (5) WO1997020801A1 (uk)
ZA (4) ZA9610308B (uk)

Families Citing this family (130)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09173835A (ja) * 1995-12-25 1997-07-08 Chiyoda Corp 貴金属用吸着剤及び貴金属の回収方法
EP0839787A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
US5874640A (en) * 1996-11-26 1999-02-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE19654961C2 (de) * 1996-12-12 1999-04-29 Basf Ag Verfahren für die Herstellung von Copolymerisaten aus Kohlenmonoxid und olefinisch ungesättigten Verbindungen
US5919978A (en) * 1997-04-15 1999-07-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing aldehyde acids or salts
DE19954510A1 (de) * 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
EP1172143A1 (en) * 2000-07-14 2002-01-16 Dsm N.V. Process for the recovery of rhodium
FI20002807A0 (fi) * 2000-09-05 2000-12-20 Neste Chemicals Oy Menetelmä alkeenien hydroformyloimiseksi
DE10106482A1 (de) 2001-02-13 2002-08-14 Basf Ag Hydroformylierung
EP1249444A1 (en) * 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process for forming an aldehyde
EP1249438A1 (en) * 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process for producing an aldehyde
DE10201676A1 (de) * 2002-01-17 2003-07-31 Basf Ag Verfahren zur Hydroformylierung von Olefinen mit 2 bis 6 Kohlenstoffatomen
US7074735B2 (en) * 2002-03-13 2006-07-11 Exxonmobil Research And Engineering Company Selectively suppressing catalytic hydrogenation
FR2838431B1 (fr) * 2002-04-11 2005-05-06 Inst Francais Du Petrole Procede d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt dans un liquide ionique non-aqueux avec un recyclage du catalyseur ameliore
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
RU2337090C2 (ru) 2002-08-31 2008-10-27 Оксено Олефинхеми Гмбх Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты
AR041460A1 (es) * 2002-10-03 2005-05-18 Shell Int Research Reduccion de la viscosidad de los productos secundarios de alto peso molecular en la produccion de 1,3- propanodiol
WO2004043654A2 (en) * 2002-11-06 2004-05-27 Eveready Battery Company, Inc. Shaving systems
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
CN1997616B (zh) * 2003-07-03 2011-01-19 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
DE10344690A1 (de) * 2003-09-25 2005-04-14 Basf Ag Verfahren zur Herstellung von 1,7-Octadien und dessen Verwendung
ES2308230T3 (es) * 2003-10-21 2008-12-01 Basf Se Metodo para la produccion continua de aldehidos.
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
DE10357718A1 (de) 2003-12-09 2005-07-21 Basf Ag Verfahren zur Herstellung von Tricyclodecandialdehyd
EP1697585A4 (en) * 2003-12-15 2009-04-08 Univ Yale MAGNETOELECTRONIC DEVICES BASED ON COLOSSAL MAGNETOESISTANT THIN FILMS
US20050143600A1 (en) * 2003-12-26 2005-06-30 Chaudhari Raghunath V. Process for the preparation of 2-hydroxy carboxylic acids
CN1309728C (zh) * 2004-07-30 2007-04-11 中国科学院上海有机化学研究所 一类手性有机－无机高分子组装体催化剂、合成方法及用途
RU2388742C2 (ru) 2004-08-02 2010-05-10 Дау Текнолоджи Инвестментс Ллс. Стабилизация процесса гидроформилирования
KR100744477B1 (ko) * 2004-09-15 2007-08-01 주식회사 엘지화학 인 화합물을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
US8178729B2 (en) * 2005-03-16 2012-05-15 Perstorp Specialty Chemicals Ab Hydroformylation process
US7329783B2 (en) * 2005-06-30 2008-02-12 Shell Oil Company Hydroformylation process
US7718158B2 (en) * 2005-10-13 2010-05-18 Lyondell Chemical Technology, L.P. Polymer-encapsulated ion-exchange resin
GB2452219A (en) * 2006-06-30 2009-02-25 Shell Int Research Catalytic reaction process
US8110266B2 (en) 2007-02-08 2012-02-07 Allegiance Corporation Glove coating and manufacturing process
WO2008115740A1 (en) * 2007-03-20 2008-09-25 Union Carbide Chemicals & Plastics Technology Llc Hydroformylation process with improved control over product isomers
US20080306200A1 (en) 2007-06-11 2008-12-11 Seong Fong Chen Antistatic gloves and process for making same
US8387983B2 (en) * 2007-11-27 2013-03-05 Angel Playing Cards Co., Ltd. Shuffled playing cards and manufacturing method thereof
US7872157B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Phosphonite containing catalysts for hydroformylation processes
US7872156B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Fluorophosphite containing catalysts for hydroformylation processes
CA2716805C (en) * 2008-03-14 2017-11-21 Allegiance Corporation Water-based resin composition and articles made therefrom
US8878917B2 (en) 2008-04-22 2014-11-04 Ehn Spire Limited Liability Company Position-permissive autostereoscopic display systems and methods
TWI577027B (zh) * 2008-07-31 2017-04-01 半導體能源研究所股份有限公司 半導體裝置及其製造方法
US8507731B2 (en) * 2008-08-19 2013-08-13 Dow Technology Investments Llc Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers
MX2011005103A (es) 2008-11-14 2011-08-04 Univ Kansas Complejos de catalizador de metal de transicion soportados en polimeros y metodos de uso.
WO2010117391A1 (en) 2009-03-31 2010-10-14 Dow Technology Investment Llc Hydroformylation process with a doubly open-ended bisphosphite ligand
US7928267B1 (en) 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
EP2516371B2 (en) † 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
US8598390B2 (en) 2009-12-22 2013-12-03 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process
KR101815328B1 (ko) † 2009-12-22 2018-01-04 다우 테크놀로지 인베스트먼츠 엘엘씨. 합성가스 분압의 조절에 의한 혼합된 리간드 하이드로폼일화 공정에서의 노말:아이소 알데하이드 비의 조절 방법
JP2014502254A (ja) 2010-10-05 2014-01-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化の方法
RU2727149C2 (ru) * 2010-11-12 2020-07-21 Дау Текнолоджи Инвестментс Ллс Снижение загрязнения в процессах гидроформилирования посредством добавления воды
US8513468B2 (en) * 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
RU2606629C2 (ru) 2011-12-20 2017-01-10 Дау Текнолоджи Инвестментс Ллс Усовершенствованный способ гидроформилирования
RU2660899C2 (ru) * 2011-12-30 2018-07-11 Басф Се Кристаллический сольват и несольватированные формы 6,6'-[[3,3',5,5'-тетракис(1,1-диметилэтил)-[1,1'-бифенил]-2,2'-диил]бис(окси)]бис-дибензо[d,f][1,3,2]-диоксафосфепина
MX363617B (es) 2011-12-30 2019-03-28 Basf Se Metodo para la purificacion de compuestos de difosfitos organicos.
WO2013107902A1 (en) * 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
MY172695A (en) 2012-04-12 2019-12-10 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
MY172419A (en) * 2012-06-04 2019-11-25 Dow Technology Investments Llc Hydroformylation process
JP6339572B2 (ja) 2012-08-29 2018-06-06 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 触媒製造方法
MX2015003905A (es) * 2012-09-25 2015-07-17 Dow Technology Investments Llc Proceso para estabilizar un ligando fosfito contra la degradacion.
DE102013219506A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Unsymmetrisches Bisphosphit
DE102013219508A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer Bisphosphite
DE102013219512A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
WO2014056735A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer bisphosphite
DE102013219510A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
EP2740535A1 (en) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
JP6174711B2 (ja) * 2012-12-06 2017-08-02 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化方法
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
WO2014145251A1 (en) * 2013-03-15 2014-09-18 Georgetown University Determining stereoisomeric excess, concentration and absolute configuration
RU2527455C1 (ru) * 2013-03-28 2014-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения альдегидов
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
DE102013214378A1 (de) 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
CN106103399B (zh) 2013-12-19 2019-07-09 陶氏技术投资有限责任公司 氢甲酰化方法
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
RU2674698C1 (ru) 2014-03-31 2018-12-12 Дау Текнолоджи Инвестментс Ллк Способ гидроформилирования
WO2015175158A1 (en) 2014-05-14 2015-11-19 Dow Technology Investments Llc Stabilized organophosphorous compounds
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
JP6852046B2 (ja) 2015-07-10 2021-03-31 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ ２−置換ブタジエンのヒドロホルミル化のための方法、及びその二次生成物、特にアンブロックスの製造のための方法
RU2730501C2 (ru) 2015-07-28 2020-08-24 Дау Текнолоджи Инвестментс Ллк Способ приготовления стабилизированного раствора фосфорорганического соединения
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
KR20180066076A (ko) 2015-10-12 2018-06-18 바스프 에스이 1,6-이치환된 헥산 유도체를 제조하기 위한 히드로포르밀화 방법
KR20180081526A (ko) 2015-11-10 2018-07-16 다우 테크놀로지 인베스트먼츠 엘엘씨. 알데하이드를 생산하는 방법
BR112018016320B1 (pt) * 2016-02-11 2022-07-12 Dow Technology Investments Llc Processo para converter olefinas em álcoois, éteres ou combinações dos mesmos
CA3018072A1 (en) 2016-03-18 2017-09-21 Dow Technology Investments Llc Hydroformylation process
RU2619951C1 (ru) * 2016-06-21 2017-05-22 ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) Двухстадийный способ получения пропионового альдегида
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
CN110621663A (zh) 2017-06-13 2019-12-27 巴斯夫欧洲公司 制备1,6-己二醇衍生物的加氢甲酰基化方法
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
EP3700882B1 (en) * 2017-10-25 2022-10-26 Dow Technology Investments LLC Process to reduce heavies formation in a solution comprising aldehyde compounds formed during a hydroformylation process
CN107721195A (zh) * 2017-10-27 2018-02-23 福州瑞克布朗医药科技有限公司 一种增强齿科微晶玻璃理化性能的方法
JP7269238B2 (ja) 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスからロジウムを回収するためのプロセス
CN112074347A (zh) 2018-05-30 2020-12-11 陶氏技术投资有限责任公司 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法
CN112055614A (zh) 2018-05-30 2020-12-08 陶氏技术投资有限责任公司 包括单膦、四膦配位体的组合的催化剂组合物和使用其的加氢甲酰化过程
KR20210015839A (ko) 2018-05-30 2021-02-10 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 공정의 제어 방법
CN108927216B (zh) * 2018-06-29 2020-07-28 同济大学 一种补丁约束的多孔载体催化材料及其制备方法与应用
WO2020056012A1 (en) 2018-09-11 2020-03-19 Georgetown University Quantitative auxiliary-free chirality sensing with a metal probe
KR20210098486A (ko) 2018-11-29 2021-08-10 다우 테크놀로지 인베스트먼츠 엘엘씨. 히드로포르밀화 공정
RU2691064C1 (ru) * 2018-12-17 2019-06-10 Акционерное Общество "Газпромнефть - Московский Нпз" (Ао "Газпромнефть - Мнпз") Способ приготовления катализатора и способ гидрооблагораживания дизельных дистиллятов с использованием этого катализатора
CN111320656A (zh) * 2018-12-17 2020-06-23 中国石油化工股份有限公司 膦配体化合物及其制备方法、催化剂组合物及其应用和醋酸乙烯酯氢甲酰化的方法
CN111408407B (zh) * 2019-01-04 2023-07-21 中国石油化工股份有限公司 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
SE543297C2 (en) * 2019-07-18 2020-11-17 Perstorp Ab USE OF A METHOD FOR REDUCTION OF HEAVY END FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS COMPRISING A BIDENTATE PHOSPHITE LIGAND
EP3994119A4 (en) * 2019-07-05 2023-07-26 Perstorp AB METHOD OF REDUCING HEAVYEND FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS
SE1930237A1 (en) 2019-07-05 2020-11-17 Perstorp Ab A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process
TW202126385A (zh) 2019-11-05 2021-07-16 美商陶氏科技投資有限公司 自氫甲醯化製程回收銠之方法
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
PL4103571T3 (pl) 2020-02-11 2024-04-29 Basf Se Niskociśnieniowe hydroformylowanie diizobutenu
US20230227388A1 (en) 2020-05-29 2023-07-20 Dow Global Technologies Llc Process for Producing Mixed Alcohols from Purge Stream Containing Octene
CN115461318A (zh) 2020-05-29 2022-12-09 陶氏环球技术有限责任公司 用于非水羟醛缩合的有机催化剂
CN115551977A (zh) 2020-05-29 2022-12-30 陶氏环球技术有限责任公司 具有混合的c13-c14醇的组合物及表面活性剂
CN115515919A (zh) 2020-05-29 2022-12-23 陶氏环球技术有限责任公司 具有混合的c8-c18醇的组合物及其表面活性剂
CN112174791A (zh) * 2020-11-02 2021-01-05 中国海洋石油集团有限公司 一种烯烃氢甲酰化制醛中催化剂的分离方法
KR20230120131A (ko) 2020-12-14 2023-08-16 다우 테크놀로지 인베스트먼츠 엘엘씨. 히드로포르밀화 공정에서 촉매 금속 책임량을 개선시키는 방법
JP2024500349A (ja) 2020-12-22 2024-01-09 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化反応方法
CN112791680A (zh) * 2020-12-24 2021-05-14 华阳新材料科技集团有限公司 一种用于己二腈生产的镍磷络合物合成系统
JP2024513740A (ja) 2021-03-31 2024-03-27 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
CN118103532A (zh) 2021-11-11 2024-05-28 陶氏技术投资有限责任公司 用于从加氢甲酰化过程中回收铑的方法
CN118338965A (zh) 2021-12-16 2024-07-12 陶氏技术投资有限责任公司 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
WO2023114579A1 (en) 2021-12-16 2023-06-22 Dow Technology Investments Llc Compounds, transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
CN114243113A (zh) * 2021-12-27 2022-03-25 天津中电新能源研究院有限公司 一种高温电解液添加剂、电池电解液以及钠离子电池
CN114835751A (zh) * 2022-03-17 2022-08-02 江西苏克尔新材料有限公司 一种亚磷酸酯-磷酸酯类化合物及其制备方法和应用
CN114832860A (zh) * 2022-03-17 2022-08-02 江西苏克尔新材料有限公司 一种烯烃加氢甲酰化催化剂组合物及其制备方法和应用
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1338698A (en) * 1915-11-26 1920-05-04 Swift & Co Apparatus for making catalyzers
US2192124A (en) * 1937-02-24 1940-02-27 Du Pont Chemical process and apparatus
US2582899A (en) * 1946-12-14 1952-01-15 Blaw Knox Co Autoclave reactor
US2590436A (en) * 1948-06-21 1952-03-25 Shell Dev Method for controlling chemical reactions
US2757202A (en) * 1952-03-22 1956-07-31 Exxon Research Engineering Co Aldehyde synthesis process
US3222141A (en) * 1960-03-23 1965-12-07 Kaiser Aluminium Chem Corp Digesting apparatus
US3266872A (en) * 1962-04-13 1966-08-16 Sumitomo Chemical Co Reaction and separation apparatus
US3194638A (en) * 1962-11-21 1965-07-13 Kimberly Clark Co Combined slaker-causticizer apparatus
US3271458A (en) * 1962-11-23 1966-09-06 Exxon Research Engineering Co Cooling and catalyst recycle in oxo synthesis
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
US3917661A (en) * 1970-01-07 1975-11-04 Union Carbide Corp Hydroformylation of unsaturated organic compounds
DE2012807A1 (de) * 1970-03-18 1971-10-07 Faserwerke Hüls GmbH, 4370 Mari Verfahren und Vorrichtung zur kontinu lerlichen Umesterung von Dialkylestern aro matischer Dicarbonsäuren mit Diolen
DE2045169A1 (en) * 1970-09-12 1972-03-23 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Treatment of oxo reaction mixts - by addn of aqs alkali hydroxide
US3868422A (en) * 1971-12-23 1975-02-25 Eastman Kodak Co Multistage hydroformylation process
US3909207A (en) * 1973-03-09 1975-09-30 Monsanto Co Vertical stirred mass polymerization apparatus
CA1023389A (en) * 1973-04-06 1977-12-27 Uop Inc. Hydroformylation process
DE2343788C3 (de) * 1973-08-30 1980-07-10 Wacker-Chemie Gmbh, 8000 Muenchen Vorrichtung zur kontinuierlichen Durchführung von chemischen Umsetzungen, insbesondere Polymerisationen und Verfahren zur kontinuierlichen Suspensionspolymerisation von Vinylchlorid
JPS5638576B2 (uk) * 1974-07-25 1981-09-08
US4137240A (en) * 1976-01-31 1979-01-30 E. I. Du Pont De Nemours And Company Hydroformylation process for preparation of predominantly linear aldehydes
US4277627A (en) * 1977-01-25 1981-07-07 Union Carbide Corporation Hydroformylation process
DE2840168A1 (de) * 1978-09-15 1980-03-27 Basf Ag Verfahren zur herstellung von aldehyden
US4267383A (en) * 1979-05-04 1981-05-12 Celanese Corporation Hydrocarbonylation
US4258215A (en) * 1979-08-29 1981-03-24 Eastman Kodak Company Hydroformylation process
US4283562A (en) * 1979-10-26 1981-08-11 Union Carbide Corporation Hydroformylation process using stable rhodium catalyst
US4374093A (en) * 1981-02-20 1983-02-15 Mobil Oil Corporation Continuous-stream upflow zeolite crystallization apparatus
DE3361212D1 (en) * 1982-06-11 1985-12-19 Davy Mckee London Hydroformylation process
US4483624A (en) * 1982-08-25 1984-11-20 Freeport Kaolin Company High intensity conditioning mill and method
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
DE3415968A1 (de) * 1984-04-28 1985-10-31 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
FR2615606B1 (fr) * 1987-05-22 1990-07-27 Faiveley Ets Reacteur echangeur de chaleur
JPH0763706B2 (ja) * 1988-04-21 1995-07-12 有限会社パラサイト 多重気相式液処理装置
US5114473A (en) * 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
JPH0763601B2 (ja) * 1989-01-13 1995-07-12 鐘淵化学工業株式会社 粘性物質の撹拌反応装置
JP2893902B2 (ja) * 1989-10-19 1999-05-24 三菱化学株式会社 オレフィンのヒドロホルミル化法
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5410091A (en) * 1994-06-02 1995-04-25 Quimica Oxal C.A. Rhodium catalyzed oxo process in tubular reactor
US5498801A (en) * 1994-12-30 1996-03-12 Council Of Scientific & Industrial Interest Process for the catalytic hydroformylation of alkenes

Also Published As

Publication number Publication date
SK69098A3 (en) 1999-03-12
ZA9610308B (en) 1998-09-07
US5741943A (en) 1998-04-21
WO1997020793A1 (en) 1997-06-12
ZA9610312B (en) 1998-09-07
CN1203578A (zh) 1998-12-30
ES2164936T3 (es) 2002-03-01
EP0904259B1 (en) 2002-06-12
ZA9610313B (en) 1998-09-07
MX9804494A (es) 1998-12-31
PL327076A1 (en) 1998-11-23
DE69633800D1 (de) 2004-12-09
AU1329597A (en) 1997-06-27
CA2239696A1 (en) 1997-06-12
WO1997020795A1 (en) 1997-06-12
MY115709A (en) 2003-08-30
CN1203580A (zh) 1998-12-30
US5763670A (en) 1998-06-09
EP1019353A1 (en) 2000-07-19
AU721638B2 (en) 2000-07-13
SK69198A3 (en) 1999-03-12
ES2156306T3 (es) 2001-06-16
ES2160853T3 (es) 2001-11-16
DE69633800T2 (de) 2005-10-27
CN1080252C (zh) 2002-03-06
DE69613858D1 (de) 2001-08-16
EA199800516A1 (ru) 1998-12-24
ES2158369T3 (es) 2001-09-01
MX9804284A (es) 1998-10-31
US5731473A (en) 1998-03-24
CN1106374C (zh) 2003-04-23
PL327115A1 (en) 1998-11-23
JP2002515028A (ja) 2002-05-21
DE69611765T2 (de) 2001-08-23
IN1996CH02301A (uk) 2006-06-09
AU1328797A (en) 1997-06-27
MX9804489A (es) 1998-12-31
CA2239536A1 (en) 1997-06-12
US5741944A (en) 1998-04-21
US5763680A (en) 1998-06-09
EA001608B1 (ru) 2001-06-25
SK68498A3 (en) 1999-02-11
SK68898A3 (en) 1999-02-11
AU724425B2 (en) 2000-09-21
PL327074A1 (en) 1998-11-23
AU1129297A (en) 1997-06-27
CN1090169C (zh) 2002-09-04
IN1996CH02299A (uk) 2006-06-09
CN1077874C (zh) 2002-01-16
DE69621839T2 (de) 2003-01-02
ES2190485T3 (es) 2003-08-01
IN228562B (uk) 2009-03-20
EP0904259A1 (en) 1999-03-31
EA001834B1 (ru) 2001-08-27
JP2002504888A (ja) 2002-02-12
CA2230561A1 (en) 1997-06-12
CA2239518A1 (en) 1997-06-12
US5763677A (en) 1998-06-09
EA001650B1 (ru) 2001-06-25
CN1203577A (zh) 1998-12-30
DE69613858T2 (de) 2002-04-11
EP1019353B1 (en) 2004-11-03
AU719870B2 (en) 2000-05-18
US5763671A (en) 1998-06-09
ES2155949T3 (es) 2001-06-01
ATE235451T1 (de) 2003-04-15
EA001482B1 (ru) 2001-04-23
BR9611830A (pt) 1999-03-09
JP2002515859A (ja) 2002-05-28
DE69626990D1 (de) 2003-04-30
ES2227625T3 (es) 2005-04-01
BR9611665A (pt) 1999-07-13
AU1280197A (en) 1997-06-27
EA199800519A1 (ru) 1998-12-24
WO1997020796A1 (en) 1997-06-12
EA199800518A1 (ru) 1998-12-24
US5741945A (en) 1998-04-21
WO1997020792A1 (en) 1997-06-12
EA199800513A1 (ru) 1998-12-24
BR9611776A (pt) 1999-02-23
BR9611857A (pt) 1999-05-04
DE69611765D1 (de) 2001-03-15
MX203409B (es) 2001-08-01
EP0874797A1 (en) 1998-11-04
IN207646B (uk) 2007-07-06
JP2002515027A (ja) 2002-05-21
CN1203576A (zh) 1998-12-30
EP0876322B1 (en) 2001-07-11
JP3970927B2 (ja) 2007-09-05
CA2239696C (en) 2007-05-22
EP0874797B1 (en) 2001-02-07
EP0876322A1 (en) 1998-11-11
DE69626990T3 (de) 2009-07-09
BR9611663A (pt) 1999-02-23
PL327078A1 (en) 1998-11-23
DE69626990T2 (de) 2004-02-05
JP2002504076A (ja) 2002-02-05
US5744650A (en) 1998-04-28
CA2230561C (en) 2002-09-24
MX203408B (es) 2001-08-01
ES2203725T3 (es) 2004-04-16
US5728893A (en) 1998-03-17
US5744649A (en) 1998-04-28
DE69621839D1 (de) 2002-07-18
JP3867998B2 (ja) 2007-01-17
AU722459B2 (en) 2000-08-03
WO1997020801A1 (en) 1997-06-12
ES2174125T3 (es) 2002-11-01
US5763679A (en) 1998-06-09

Similar Documents

Publication Publication Date Title
ZA9610306B (en) Processes using multistaged reactors
MX9804076A (es) Procesos mejorados catalizados por complejo metal-ligando.
WO2000001485A3 (en) Improved metal-ligand complex catalyzed processes
MX220352B (en) Stereoselective ring opening reactions
GB9705699D0 (en) Process for the carbonylation of ethylene
MX9804491A (es) Procesos mejorados catalizados por complejo metal-ligando.
MY115227A (en) Improved metal-ligand complex catalyzed processes.
MX9804490A (es) Procesos mejorados catalizados por complejo metal-ligando.
TW372950B (en) Processes using multistaged reactors a process for producing one or more products in a staged reactor having more than one reactive stage