RU2024303C1 - СПОСОБ ПОЛУЧЕНИЯ КАТАЛИТИЧЕСКОЙ СИСТЕМЫ ДЛЯ (СО)ПОЛИМЕРИЗАЦИИ α-ОЛЕФИНОВ - Google Patents
СПОСОБ ПОЛУЧЕНИЯ КАТАЛИТИЧЕСКОЙ СИСТЕМЫ ДЛЯ (СО)ПОЛИМЕРИЗАЦИИ α-ОЛЕФИНОВInfo
- Publication number
- RU2024303C1 RU2024303C1 SU904743723A SU4743723A RU2024303C1 RU 2024303 C1 RU2024303 C1 RU 2024303C1 SU 904743723 A SU904743723 A SU 904743723A SU 4743723 A SU4743723 A SU 4743723A RU 2024303 C1 RU2024303 C1 RU 2024303C1
- Authority
- RU
- Russia
- Prior art keywords
- compound
- titanium
- magnesium
- polymerization
- mmol
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 86
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 81
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 150000001336 alkenes Chemical class 0.000 title abstract description 20
- 239000010936 titanium Substances 0.000 claims abstract description 114
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 100
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 96
- 150000001875 compounds Chemical class 0.000 claims abstract description 69
- 150000002681 magnesium compounds Chemical class 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 44
- 150000002148 esters Chemical class 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 35
- 239000012265 solid product Substances 0.000 claims abstract description 33
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 18
- 230000000694 effects Effects 0.000 claims abstract description 17
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000004711 α-olefin Substances 0.000 claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 2
- 235000021317 phosphate Nutrition 0.000 claims abstract 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims abstract 2
- -1 monocarboxylic acid esters Chemical class 0.000 claims description 74
- 239000007787 solid Substances 0.000 claims description 67
- 239000003054 catalyst Substances 0.000 claims description 66
- 229920000642 polymer Polymers 0.000 claims description 61
- 239000001257 hydrogen Substances 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 20
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229940125782 compound 2 Drugs 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 47
- 238000006243 chemical reaction Methods 0.000 abstract description 30
- 229930195733 hydrocarbon Natural products 0.000 abstract description 28
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 26
- 239000011777 magnesium Substances 0.000 abstract description 22
- 229910052749 magnesium Inorganic materials 0.000 abstract description 21
- 150000008064 anhydrides Chemical class 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 66
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 43
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 43
- 125000004432 carbon atom Chemical group C* 0.000 description 36
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 28
- 239000000243 solution Substances 0.000 description 28
- 239000000203 mixture Substances 0.000 description 27
- 238000002360 preparation method Methods 0.000 description 27
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 26
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 26
- 239000011949 solid catalyst Substances 0.000 description 24
- 239000002245 particle Substances 0.000 description 23
- 150000001298 alcohols Chemical class 0.000 description 20
- 229910052736 halogen Inorganic materials 0.000 description 20
- 150000002367 halogens Chemical class 0.000 description 20
- 239000002253 acid Substances 0.000 description 18
- 239000012456 homogeneous solution Substances 0.000 description 17
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 16
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 15
- 239000000460 chlorine Substances 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 14
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 14
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 13
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 150000004820 halides Chemical class 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 150000003961 organosilicon compounds Chemical class 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 125000003545 alkoxy group Chemical group 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 125000005234 alkyl aluminium group Chemical group 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 238000007334 copolymerization reaction Methods 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 7
- 125000005843 halogen group Chemical group 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 239000010802 sludge Substances 0.000 description 7
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 6
- 150000002576 ketones Chemical class 0.000 description 6
- 150000002902 organometallic compounds Chemical class 0.000 description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
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- 150000001299 aldehydes Chemical class 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
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- 125000004104 aryloxy group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 4
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- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 4
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- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 3
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- 238000000605 extraction Methods 0.000 description 3
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- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
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- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
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- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56181019A JPS5883006A (ja) | 1981-11-13 | 1981-11-13 | オレフインの重合方法 |
| JP181019/81 | 1982-11-13 | ||
| JP4192798A JPH0686491B2 (ja) | 1981-11-13 | 1992-06-29 | オレフイン重合用固体チタン触媒成分 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2024303C1 true RU2024303C1 (ru) | 1994-12-15 |
Family
ID=26500351
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU904743723A RU2024303C1 (ru) | 1981-11-13 | 1990-04-26 | СПОСОБ ПОЛУЧЕНИЯ КАТАЛИТИЧЕСКОЙ СИСТЕМЫ ДЛЯ (СО)ПОЛИМЕРИЗАЦИИ α-ОЛЕФИНОВ |
| SU915001897A RU2091393C1 (ru) | 1981-11-13 | 1991-11-05 | Способ получения (со)полимеров альфа-олефинов |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU915001897A RU2091393C1 (ru) | 1981-11-13 | 1991-11-05 | Способ получения (со)полимеров альфа-олефинов |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4952649A (enExample) |
| JP (2) | JPS5883006A (enExample) |
| KR (1) | KR860001806B1 (enExample) |
| AT (1) | AT392645B (enExample) |
| AU (1) | AU554187B2 (enExample) |
| BE (1) | BE895019A (enExample) |
| BR (1) | BR8206573A (enExample) |
| CA (1) | CA1187865A (enExample) |
| DE (1) | DE3241999A1 (enExample) |
| DK (1) | DK164284C (enExample) |
| FI (1) | FI71325C (enExample) |
| FR (1) | FR2516520A1 (enExample) |
| GB (1) | GB2111066B (enExample) |
| HU (1) | HU196612B (enExample) |
| NL (1) | NL186245C (enExample) |
| NO (1) | NO161178C (enExample) |
| PH (1) | PH18781A (enExample) |
| PL (1) | PL146395B1 (enExample) |
| RO (1) | RO85779B (enExample) |
| RU (2) | RU2024303C1 (enExample) |
| SE (1) | SE458278B (enExample) |
| SU (1) | SU1826972A3 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2289592C2 (ru) * | 2002-07-15 | 2006-12-20 | Юнивейшн Технолоджиз, Ллс | Компонент катализатора, предшественник катализатора и катализатор полимеризации олефинов на основе галогенида магния |
| RU2322457C2 (ru) * | 2002-12-18 | 2008-04-20 | Базелль Полиолефин Италия С.П.А. | Каталитические компоненты для полимеризации олефинов |
| RU2813292C2 (ru) * | 2020-01-28 | 2024-02-09 | Шеврон Филлипс Кемикал Компани Лп | Способы получения катализатора с использованием гидратированных реагентов |
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| RU2289592C2 (ru) * | 2002-07-15 | 2006-12-20 | Юнивейшн Технолоджиз, Ллс | Компонент катализатора, предшественник катализатора и катализатор полимеризации олефинов на основе галогенида магния |
| RU2322457C2 (ru) * | 2002-12-18 | 2008-04-20 | Базелль Полиолефин Италия С.П.А. | Каталитические компоненты для полимеризации олефинов |
| RU2813292C2 (ru) * | 2020-01-28 | 2024-02-09 | Шеврон Филлипс Кемикал Компани Лп | Способы получения катализатора с использованием гидратированных реагентов |
| RU2813293C2 (ru) * | 2020-01-28 | 2024-02-09 | Шеврон Филлипс Кемикал Компани Лп | Способы получения катализатора с использованием гидратированных реагентов |
| RU2813341C2 (ru) * | 2020-01-28 | 2024-02-12 | Шеврон Филлипс Кемикал Компани Лп | Способы получения катализатора с использованием гидратированных реагентов |
| RU2813342C2 (ru) * | 2020-01-28 | 2024-02-12 | Шеврон Филлипс Кемикал Компани Лп | Способы получения катализатора с использованием гидратированных реагентов |
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