KR940004858A - 반도체장치 및 그 제작방법 - Google Patents
반도체장치 및 그 제작방법 Download PDFInfo
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- KR940004858A KR940004858A KR1019930016789A KR930016789A KR940004858A KR 940004858 A KR940004858 A KR 940004858A KR 1019930016789 A KR1019930016789 A KR 1019930016789A KR 930016789 A KR930016789 A KR 930016789A KR 940004858 A KR940004858 A KR 940004858A
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- Prior art keywords
- film
- silicon oxide
- semiconductor device
- oxide film
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 29
- 239000004065 semiconductor Substances 0.000 title claims abstract 38
- 239000010409 thin film Substances 0.000 claims abstract description 21
- 239000010408 film Substances 0.000 claims abstract 57
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 33
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract 33
- 238000000034 method Methods 0.000 claims abstract 17
- 230000001678 irradiating effect Effects 0.000 claims abstract 11
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract 8
- 239000000758 substrate Substances 0.000 claims abstract 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 7
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract 5
- 239000010703 silicon Substances 0.000 claims abstract 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 4
- 238000000137 annealing Methods 0.000 claims abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- -1 nitrogen ions Chemical class 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- 239000002994 raw material Substances 0.000 claims abstract 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001282 organosilanes Chemical class 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 150000002500 ions Chemical class 0.000 claims 4
- 239000000463 material Substances 0.000 claims 4
- 238000005268 plasma chemical vapour deposition Methods 0.000 claims 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 3
- 229910052731 fluorine Inorganic materials 0.000 claims 3
- 239000011737 fluorine Substances 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims 3
- 238000002230 thermal chemical vapour deposition Methods 0.000 claims 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
- 239000012298 atmosphere Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 230000005669 field effect Effects 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 230000001590 oxidative effect Effects 0.000 claims 2
- 230000001681 protective effect Effects 0.000 claims 2
- 229910000077 silane Inorganic materials 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000005468 ion implantation Methods 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 4
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- H01L21/3143—Inorganic layers composed of alternated layers or of mixtures of nitrides and oxides or of oxinitrides, e.g. formation of oxinitride by oxidation of nitride layers
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Abstract
저온에서의 특성·신뢰성이 우수한 박막트랜지스터를 고 스루풋으로 제조효율이 양효하게 제조하는 방법을 제공한다. 이 방법은 절연기판상에 박막 트랜지스터(TFT)를 형성하는 공정에 있어서, 반로체피막을 형성한 후 TEOS를 원료로 하여 화학적 기상성장법에 의해 게이트 산화막이 되는 산화규소막을 제작하고, 바람직하게는 산소, 오존, 산화질소 분위기 중에서 이것에 펄스 레이저광 또는 자외광을 조사하는 것에 의해 산화규소막 중의 탄소나 탄화수소등의 클러스터를 제거하고, 따라서 막중의 트랩센터를 제거하여, 게이트 산화막으로서 적당한 특성을 나타내는 산화막으로 하는 것을 특징으로 하는 박막형 반도체장치의 제작방법이다.
또한, 산화규소막으로 이루어지는 게이트 절연막에 대하여 질소 이온을 주입하고, 이어서 적외광에 의한 어닐을 행하는 것에 의해 게이트 절연막을 산화 질화규소로 하여 내압의 향상, 비유전율의 향상, 막질의 치밀화를 실현한다. 이렇게 하는 것으로서 TFT의 특성을 안정화시켜 신뢰성을 향상시킨다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 TFT(박막 트랜지스터)의 제작 방법도,
제2도는 본 발명에 의한 TFT의 제작 방법도,
제3도는 본 발명에 사용한 레이저, 자외광 처리장치의 개념도,
제4도는 실시예의 제작 공정도,
제5도는 실시예의 제작 공정도,
제6도는 실시예의 제작 공정도,
제7도는 본 발명에 의한 TFT의 제작방법.
Claims (25)
- 절연 기판상에 반도체 피막을 형성하는 공정과, 상기 반도체 피막상에 유기실란 또는 그 일부의 수소, 탄소 또는 탄화 수소기를 불소에 의해 치환(치환)한 재료를 원료로 하는 화학적 기상 성장법에 의해 산화규소막을 형성하는 공정과, 상기 반도체피막 및 산화규소막에 펄프 레이저광 또는 그것과 동등의 강광을 조사하는 공정과, 상기 산화규소막상에 게이트 전극을 형성하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 산화규소막을 기판온도 200-500℃에서 형성하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 게이트 전극 형성후, 게이트 전극을 주된 마스크로 하여 자기정합적으로 고속 이온을 조사하는 공정과, 상기 이온 조사후 상기 게이트 전극을 주된 마스크로하여 펄스레이저광 또는 그것과 동등의 강광을 조사하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 상기 유기 실란은 테트라·에틸·옥시실란으로 이루어지는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 상기 화학적 기상성장법은 플라즈마 CVD, 열 CVD, 포토 CVD 또는 포토 플라즈마 CVD인 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 상기 조사 공정전에 상기 산화규소막을 400∼700℃의 질소 분위기 중에서 열어닐하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제1항에 있어서, 상기 조사 공정후 상기 산화규소막을 400∼700℃의 질소 분위기 중에서 열어닐 하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 절연기판상에 반도체피막을 형성하는 공정과, 상기 반도체피막상에 레이저광 또는 그것과 동등의 강광에 대하여 실질적으로 투명한 보호절연막을 형성하는 공정과, 상기 반도체피막과 펄스레이저광 또는 그것과 동등의 강광을 조사하는 것에 의해 상기 반도체피막의 결정성을 개선시키는 공정과, 상기 보호 절연피막을 제거하는 것에 의해 상기 반도체피막 표면을 노출시키는 공정과, 유기실란 또는 그 일부의 수소, 탄소 또는 탄화수소기를 불소에 의해 치환한 재료를 원료로 하는 화학적 기상 성장법에 의해 산화규소막을 형성하는 공정과, 상기 반도체피막 및 산화규소막에 펄스 레이저광 또는 그것과 동등의 강광을 조사하는 공정과, 상기 산화규소막상에 게이트 전극을 형성하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 산화규소막을 기판온도 200∼500℃에서 형성하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 게이트 전극 형성후 게이트 전극을 주된 마스크로하여 자기 정합적으로 고속 이온을 조사하는 공정과, 상기 이온 조사후 상기 게이트 전극을 주된 마스크로하여 펄스레이저광 또는 그것과 동등의 강광을 조사하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 상기 유기실란은 테트라·에틸·옥시실란으로 이루어지는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 상기 화학적 기상성장법은 플라즈마 CVD, 열 CVD, 포토 CVD 또는 포토플라즈마 CVD인 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 상기 조사 공정전에 상기 산화규소막을 400∼700℃의 질소 분위기 중에서 열어닐 하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제8항에 있어서, 상기 조사 공정후에 상기 산화규소막을 400∼700℃의 질소 또는 산화 분위기 중에서 열어닐 하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 절연기판상에, 반도체 피막을 형성하는 공정과, 상기 반도체 피막상에 유기실란 또는 그 일부의 수소, 탄소 탄화수소기를 불소에 의해 치환한 재료를 원료로 하는 화학적 기상성장법에 의해 산화규소막을 형성하는 공정과, 상기 반도체피막 및 산화규소막에 산소, 오존 또는 산화질소를 포함한 분위기 중에서 파장 300nm이하의 자외광을 조사하는 공정과, 상기 산화규소막상에 게이트 전극을 형성하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제15항에 있어서, 상기 유기실란은 테트라·에틸·옥시실란으로 이루어지는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제15항에 있어서, 상기 화학적 기상성장법은 플라즈마 CVD, 열 CVD, 포토 CVD 또는 포토플라즈마 CVD인 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 절연기판상에 규소 반도체피막을 형성하는 공정과, 500∼700℃ 온도의 산화물 기체중에서 상기 규소 반도체피막의 표면을 산화하고, 그 표면에 20∼200Å의 두께의 제1의 산화규소층을 형성하는 공정과, 상기 제1의 산화규소층상에 유기실란 또는 그 일부의 수소, 탄소 또는 탄화수소기를 불소에 의해 치환한 재료를 원료로 하는 화학적 기상성장법에 의해 제2의 산화규소막을 형성하는 공정과, 상기 제2의 산화규소층을 광어닐하는 공정과, 상기 반도체피막 및 산화규소막에 펄스레이저광 또는 그것과 동등의 강광을 조사하는 공정과, 상기 산화규소막 상에 게이트 전극을 형성하는 공정을 갖는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제15항에 있어서, 상기 광어닐을 펄스 레이저광 또는 그것과 동등의 강광을 상기 제2의 산화규소층에 조사하는 것에 의해 행하는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 제20항에 있어서, 상기 산화물 기체는 순도 99.9%이상의 건조화 산소로 이루어지는 것을 특징으로 하는 박막형 반도체장치의 제작방법.
- 산화규소막을 갖는 반도체장치로서, 상기 산화규소막의 표면이 질화되어 있는 것을 특징으로 하는 반도체장치.
- 절연게이트형 전계효과 반도체장치로서, 그 표면이 질화된 산화규소막에 의해 게이트 절연막이 구성되어 있는 것을 특징으로 하는 반도체장치.
- 산화규소막을 갖는 반도체장치의 제작방법으로서, 산화규소막으로 이루어진 절연막 표면에 질소 이온을 주입하는 것에 의해 상기 산화규소막 표면을 산화질화규소로 하는 것을 특징으로 하는 반도체장치의 제작방법.
- 절연게이트형 전계효과 반도체장치의 제작방법으로서, 게이트 절연막으로서 산화규소막을 형성하는 공정과, 상기 산화규소막 표면에 질소이온을 주입하는 공정을 갖는 것을 특징으로 하는 반도체장치의 제작방법.
- 제24항에 있어서, 질소이온 주입 다음에 적외광의 조사에 의한 어닐을 행하는 것을 특징으로 하는 반도체장치의 제작방법.
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JP5177410A JPH0786593A (ja) | 1993-06-24 | 1993-06-24 | 半導体装置およびその作製方法 |
JP05191934A JP3122699B2 (ja) | 1992-08-27 | 1993-07-06 | 薄膜状半導体装置の作製方法。 |
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-
1993
- 1993-08-27 CN CN93118309A patent/CN1052569C/zh not_active Expired - Fee Related
- 1993-08-27 CN CNB2005100041534A patent/CN100465742C/zh not_active Expired - Lifetime
- 1993-08-27 KR KR1019930016789A patent/KR0131062B1/ko not_active IP Right Cessation
- 1993-08-27 CN CN2004100589741A patent/CN1560691B/zh not_active Expired - Lifetime
- 1993-08-27 CN CNB200410045674XA patent/CN100483651C/zh not_active Expired - Fee Related
- 1993-08-27 CN CNB991118707A patent/CN1244891C/zh not_active Expired - Lifetime
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1996
- 1996-09-26 US US08/721,526 patent/US6168980B1/en not_active Expired - Lifetime
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1999
- 1999-07-29 CN CNB991118693A patent/CN1156018C/zh not_active Expired - Fee Related
-
2004
- 2004-07-28 US US10/900,462 patent/US7416907B2/en not_active Expired - Fee Related
- 2004-12-22 US US11/017,640 patent/US7329906B2/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100385721B1 (ko) * | 2000-02-16 | 2003-05-27 | 주식회사 엘지화학 | 무광택 내열성 열가소성 수지 조성물 및 그의 제조방법 |
KR100446651B1 (ko) * | 2001-11-16 | 2004-09-04 | 주식회사 엘지화학 | 열용착성이 우수한 열가소성 수지 조성물 |
KR100472018B1 (ko) * | 2001-11-16 | 2005-03-08 | 주식회사 엘지화학 | 열용착성이 우수한 열가소성 수지 조성물 |
Also Published As
Publication number | Publication date |
---|---|
CN1156018C (zh) | 2004-06-30 |
US7329906B2 (en) | 2008-02-12 |
KR0131062B1 (ko) | 1998-04-14 |
CN100483651C (zh) | 2009-04-29 |
US7416907B2 (en) | 2008-08-26 |
CN1560691B (zh) | 2010-05-26 |
CN1052569C (zh) | 2000-05-17 |
US6168980B1 (en) | 2001-01-02 |
CN1248069A (zh) | 2000-03-22 |
CN1088712A (zh) | 1994-06-29 |
CN1637565A (zh) | 2005-07-13 |
CN100465742C (zh) | 2009-03-04 |
US20050003568A1 (en) | 2005-01-06 |
CN1248037A (zh) | 2000-03-22 |
US20050110091A1 (en) | 2005-05-26 |
CN1244891C (zh) | 2006-03-08 |
CN1560691A (zh) | 2005-01-05 |
CN1549316A (zh) | 2004-11-24 |
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