JP4960598B2 - 基板表面から未変性酸化物を除去する方法及び装置 - Google Patents
基板表面から未変性酸化物を除去する方法及び装置 Download PDFInfo
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- JP4960598B2 JP4960598B2 JP2005054443A JP2005054443A JP4960598B2 JP 4960598 B2 JP4960598 B2 JP 4960598B2 JP 2005054443 A JP2005054443 A JP 2005054443A JP 2005054443 A JP2005054443 A JP 2005054443A JP 4960598 B2 JP4960598 B2 JP 4960598B2
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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Description
[0001]本発明の実施形態は、一般的には、半導体処理装置に関する。更に詳細には、本発明の実施形態は、半導体製造のための化学気相堆積(CVD)システム及びそれを用いたインサイチュドライクリーニング法に関する。
関連技術の説明
[0002]基板表面が酸素に晒される時に、典型的には未変性酸化物が形成する。基板が大気状態で処理チャンバ間を移動する時に、又は真空チャンバ内の少量の残留酸素が基板表面と接触した時に、酸素に晒されることが生じる。基板表面がエッチングの間汚染される場合には、未変性酸化物も結果として生じてしまう。未変性酸化物は、典型的には、基板表面上に望ましくない膜を形成する。未変性酸化物膜は、5〜20オングストロームのように通常はとても薄いが、後の製造プロセスにおいて困難を引き起こすのに十分厚いものである。
[0010]未変性酸化物を基板表面からエッチングするための方法もまた提供される。一態様においては、本方法は、チャンバ本体と少なくとも一部がチャンバ本体内に配置され且つその上で基板を支持するように適合された支持アセンブリを備えた処理チャンバ内で処理されるべき基板を装填するステップを含んでいる。支持アセンブリは、基板を冷却する流体を供給することができる少なくとも一部がその中に形成された1つ以上の流体チャネルを含んでいる。チャンバは、更に、チャンバ本体の上表面上に配置されたリッドアセンブリを備えている。リッドアセンブリは、第一電極とその間でプラズマキャビティを画成する第二電極とを含み、ここで第二電極は連動して基板を加熱するように適合されている。
[0097]6NH4F+SiO2 → (NH4)2SiF6+H2O
[0098](NH4)2SiF6+熱 → NH3+HF+SiF4
[0099]基板表面上に薄膜が形成された後、その上に基板が支持された支持部材310を加熱された分配プレート225の密接に近接してアニール位置に上げられる。分配プレート225から放射された熱は、(NH4)2SiF6の薄膜を揮発性SiF4、NH3、HF生成物へ十分に解離又は昇華させるのに十分でなければならない。その後、これらの揮発性生成物は、上記のように真空ポンプ125によってチャンバ100から除去される。典型的には、75℃以上の温度を用いて効果的に昇華させるとともに基板から薄膜を除去する。好ましくは、100℃以上の温度、例えば、約115℃〜約200℃が用いられる。
実施例:
[00120]エッチング中、2sccmのNF3、10sccmのNH3、2,500sccmのアルゴンのガス混合物をチャンバへ導入した。ガス混合物のプラズマを100ワットの電力を用いて点火した。底面のパージは1,500sccmのアルゴン、エッジのパージは50sccmのアルゴンであった。チャンバ圧を約6Torrで維持し、基板温度は約22℃であった。基板を120秒間エッチングした。
Claims (17)
- 基板表面から未変性酸化物を除去するための処理チャンバであって、
チャンバ本体と、
該チャンバ本体内に少なくとも一部が配置され且つその上に基板を支持するように適合された支持アセンブリであって、該支持アセンブリが、その中に少なくとも一部が形成され且つ該基板を冷却することができる1つ以上の流体チャネルを含んでいる、前記支持アセンブリと、
該チャンバ本体の上面上に配置されたリッドアセンブリであって、該リッドアセンブリが、その間にプラズマキャビティを画成している第一電極と第二電極を備え、前記該第一電極が電源に接続されており、前記第二電極が接地されており、該第二電極が、該第二電極の温度を制御するための電源に結合した加熱素子を含み、該基板を対流的に加熱するように適合されている、前記リッドアセンブリと、
を備えている、前記チャンバ。 - 該支持アセンブリが、該基板本体内で垂直に移動して該基板を該第二電極に接近した加熱位置に置き且つ該基板を該第二電極から取り出されたエッチング位置に置くように適合されている、請求項1記載のチャンバ。
- 該支持アセンブリが、その上に該基板を支持するように適合された受容面を備え、該受容面がリフトメカニズムに結合したシャフトの上に配置されている、請求項1記載のチャンバ。
- 該リフトメカニズムが、該チャンバ本体内に垂直に該受容面を移動させて該基板を該第二電極に近接した加熱位置に置き且つ該基板を第二電極から取り出されたエッチング位置に置くように適用されている、請求項3記載のチャンバ。
- 該支持アセンブリが、その第一端に該受容面と流体で連通している1つ以上のガス通路と、その第二端にパージガス供給源又は真空供給源とを備えている、請求項3記載のチャンバ。
- 該シャフトが、1種以上の流体を該ガス通路に分配するように適合された1つ以上の埋め込みガスコンジットを備えている、請求項5記載のチャンバ。
- 1つ以上の該流体チャネルが、該受容面の下の該支持アセンブリ内に配置されている、請求項1記載のチャンバ。
- 1つ以上の該流体チャネルが該受容面の下の該支持アセンブリ内に配置され、該シャフトが該流体チャネルと流体で連通している1つ以上の埋め込みコンジットを備えている、請求項3記載のチャンバ。
- 1つ以上の該埋め込みコンジットが加熱媒体を1つ以上の該流体チャネルに分配するように適合されている、請求項8記載のチャンバ。
- 1つ以上の該埋め込みコンジットが、冷却剤を1つ以上の該流体チャネルに分配するように適合されている、請求項8記載のチャンバ。
- 該第二電極がシャワヘッドに結合したブロッカーアセンブリを備えている、請求項1記載のチャンバ。
- 該ブロッカーアセンブリと該シャワヘッド各々が、複数のアパーチャを備え、ガスを該チャンバ本体へ一様に分布させるように協働する請求項11記載のチャンバ。
- 該プラズマキャビティが、該リッドアセンブリ内に反応性ガスのプラズマを含有するように適合されている、請求項1記載のチャンバ。
- 該電源が、高周波源、マイクロ波源、又は直流源である、請求項1記載のチャンバ。
- 基板表面から未変性酸化物をエッチングする方法であって、
処理チャンバ内に処理すべき基板を装填するステップであって、該チャンバが
チャンバ本体と、
該チャンバ本体内に少なくとも一部が配置され且つその上に基板を支持するように適合された支持アセンブリであって、該支持アセンブリが、該基板を冷却することができるその中に少なくとも一部が形成された1つ以上の流体チャネルを含んでいる、前記支持アセンブリと、
該チャンバ本体の上面上に配置されたリッドアセンブリであって、該リッドアセンブリが、その間にプラズマキャビティを画成している第一電極と第二電極を備え、前記第一電極が電源に接続されており、前記第二電極が接地されており、該第二電極が、該第二電極の温度を制御するための電源に結合した加熱素子を含み、該基板を対流的に加熱するように適合されている、前記リッドアセンブリと、
を備えている、前記ステップと、
該プラズマキャビティ内で反応性ガスプラズマを生成させるステップと、
該支持アセンブリの1つ以上の該流体チャネルを通って熱伝達媒体を流すことにより該基板を冷却させるステップと、
該第二電極を通って該基板表面に該反応性ガスを流すステップと、
該反応性ガスで該基板表面をエッチングさせるステップと、
加熱素子にそれと接触させて電力を加えることにより該第二電極を加熱するステップと、
加熱した該第二電極に密接に近接して該支持アセンブリを配置することにより加熱した該第二電極を用いて該基板を加熱するステップと、
を含む、前記方法。 - 該基板を冷却するステップが、基板温度を室温より低い温度に維持する工程を含んでいる、請求項15記載の方法。
- 該基板を加熱するステップが、該基板温度を75℃より高い温度に維持する工程を含んでいる、請求項15記載の方法。
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