CN103560226B - 制造由硅或者基于硅的材料组成的纤维的方法及其在锂充电电池中的应用 - Google Patents

制造由硅或者基于硅的材料组成的纤维的方法及其在锂充电电池中的应用 Download PDF

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CN103560226B
CN103560226B CN201310461351.8A CN201310461351A CN103560226B CN 103560226 B CN103560226 B CN 103560226B CN 201310461351 A CN201310461351 A CN 201310461351A CN 103560226 B CN103560226 B CN 103560226B
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M·格林
F-M·刘
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Abstract

一种制造硅或者基于硅的材料的纤维的方法，包括蚀刻基底上的柱并使其分离的步骤。可通过使用该纤维作为复合阳极中的活性材料而形成电池阳极。

Description

制造由硅或者基于硅的材料组成的纤维的方法及其在锂充电 电池中的应用
本申请是奈克松有限公司于2007年1月23日申请的申请号为200780002976.0、发明名称为“制造由硅或者基于硅的材料组成的纤维的方法及其在锂充电电池中的应用”的专利申请的分案申请。
技术领域
本发明涉及一种制造由硅或者基于硅的材料组成的纤维的方法及其在可充电锂单体电池（battery cell）的活性阳极材料中的应用。
背景技术
熟知硅可被用作可充电锂离子电化学电池的活性阳极材料（例如参见InsertionElectrode Materials for Rechargeable Lithium Batteries，M.Winter，J.O.Besenhard，M.E.Spahr和P.Novak在Adv.Mater.1998，10，No.10）。图1中示出了常规锂离子可充电单体电池的基本组成，其包括将以基于硅的阳极代替的成份基于石墨的阳极。该单体电池包括单个单体但是还可包括多个单体。
单体电池通常包括合适地外部连接于负载或者再充电源的用于阳极10的铜集电器和用于阴极12的铝集电器。基于石墨的复合阳极层14覆盖集电器10，而基于含锂金属氧化物的复合阴极层16覆盖集电器12。在基于石墨的复合阳极层14和基于含锂金属氧化物的复合阴极层16之间设置多孔塑料隔板或者隔离体20，液态电解质材料分散在多孔塑料隔板或者隔离体20、复合阳极层14和复合阴极层16中。一些情况下，多孔塑料隔板或者隔离体20可被聚合物电解质材料替换，并且在这些情况下在复合阳极层14和复合阴极层16中都出现聚合物电解质材料。
当单体电池完全充电时，锂经电解质被从含锂金属氧化物传输至基于石墨的层，在那里其与石墨反应形成化合物LiC6。作为复合阳极层中电化学活性材料的石墨的最大容量为372mAh/g。注意，所使用的术语“阳极”和“阴极”是指电池被置于负载两端之间的情况。
通常认为，当用作锂离子可充电单体电池中的活性阳极材料时，硅的容量比常用的石墨大得多。当Si通过与电化学单体电池中的锂反应转换为化合物Li21Si5时，硅的容量为4,200mAb/g。
现有的在锂离子电化学电池中使用硅或者基于硅的活性阳极材料的方法未能提供所需数量充电/放电循环内的持续容量因此在商业上不可行。
一种方法采用粉末状的硅，在一些实例中其被形成为可选地具有电子添加剂的复合物并包含涂敷在铜集电器上的合适粘合剂，例如聚偏二氟乙烯。但是在充电/放电循环中该电极不能提供持续容量。认为该容量损失是由于和锂嵌入主体硅/从主体硅提取相关的体积膨胀/收缩引起的硅粉末质量的部分机械分离。这又造成粉末质量在电绝缘“小岛”中的集聚。
在由Ohara等人在Journal of Power Sources136（2004）303－306中所描述的另一种方法中，硅被蒸镀至镍箔集电器上形成薄膜，并且然后利用该结构形成锂离子电池的阳极。但是，尽管该方法可产生良好的容量保持率，但是仅仅对于非常薄的膜才如此，因此这些结构不能产生单位面积上可用量的容量，而提高膜厚度以形成单位面积上可用量的容量又使得良好的容量保持率消除。
在US2004/0126659中所描述的另一种方法中，硅被蒸镀至然后用于形成锂电池阳极的镍纤维上。但是发现其形成了硅在镍纤维上的不均匀分布因此明显影响操作。
在US6,887,511中所描述的另一种方法中，硅被蒸镀至粗糙的基于铜的底上形成10μm的中间厚度膜。在初始嵌入锂离子过程中，硅膜破碎而形成硅柱。这些柱然后可逆地与锂离子反应并获得良好的容量保持率。但是，该过程对较厚的膜运行不好并且形成中间厚度膜是一种昂贵的过程。另外膜破碎所形成的柱状结构不具有内在的多孔性从而该组织可保持长期的容量保持率。
发明内容
在权利要求书中列出了本发明。因为阳极电极结构采用基于硅的材料或者硅的纤维，这些硅或者基于硅的纤维与锂的可逆反应问题被克服。特别是通过在复合结构中设置纤维，即聚合物粘合剂与电子添加剂的混合物，充电/放电过程变得可逆、可重复并且获得良好的容量保持率。此外，其中设置纤维的方式也具有优点。通过提供无序的无纺纤维垫，产生完全可逆以及可重复的充电容量而不会产生明显机械分离的风险。例如，该纤维可被沉积为毡或者毡状结构。对复合结构而言，其可具有其它元件，或者毡可以具有简单粘合剂或者在结构合适的地方松散。
另外，提供了一种制造纤维的简化方法，包括蚀刻基底以形成柱并分离柱，提供了一种可靠而产额高的方法。
附图说明
现在将通过实例参考附图描述本发明的实施例，其中：
图1是示出单体电池元件的示意图；
图2是根据本发明的电极的放大照片；以及
图3示出了硅纤维/PVDF/Super P复合电极的第一循环电压曲线。
具体实施方式
总之，本发明可形成硅或者基于硅的材料的纤维或者细丝，以及将这些纤维用于形成毡状电极结构和具有聚合物粘合剂、电子添加剂（如果需要）和金属箔集电器的复合阳极结构。特别是，认为构成复合物的硅元件结构克服了充电/放电容量损失问题。
例如通过随机或者无序或者真正有序地设置，而将纤维置于复合的或者毡或者毡状结构中，即交叉以提供多个交叉点的多条长细纤维，可缓解充电/放电容量损失问题。
通常，纤维的长度直径比大约为100：1，因此在阳极层例如复合阳极层中每条纤维将沿着其长度接触其它纤维多次，形成一种其中可忽略由断裂硅接触产生的机械分离的可能的结构。而且，尽管会造成体积膨胀和体积收缩，但是将锂嵌入纤维以及从纤维去除锂都不会造成纤维破坏，因此保持了纤维内部的电子传导性。
可通过将柱与基底分离制造纤维。此外，可通过简单可重复的化学工艺提供制造柱的方式。
可形成柱的一种方式为干法蚀，例如在美国申请10/049736中所描述的深反应离子蚀刻，该申请与本申请是共同拥有的，并在此引用作为参考。本领域技术人员熟知该过程从而在这里不需要详细描述。但是简单地，蚀刻并冲洗被涂敷天然氧化物的硅基底以形成亲水表面。氯化铯（CsCl）被蒸镀在表面上，并且在干燥条件下将涂敷的基底输送至水蒸气气压不变的腔内。CsCl薄膜显影成半球的小岛阵列，其尺寸特征取决于初始厚度、水蒸气气压和显影时间。小岛阵列提供了一种有效的掩模，在其后例如通过反应离子蚀刻进行蚀刻形成了对应半球小岛的柱阵列。CsCl抗蚀剂层高度溶于水并且容易被冲洗掉。
可选地，可通过湿法蚀刻/采用例如在我们的共同待审的申请GB0601318.9中所描述的化学电交换方法（chemical galvanic exchange method）形成柱，该申请具有共同的受让人、标题为“Method of etching a silicon－based material”，并且在此引用作为参考。在Peng K-Q，Yan，Y－J Gao，S－P，Zhu J.，Adv.Materials，14（2004），1164－1167（“Peng”）；K.Peng等人，Angew.Chem.Int.Ed.，442737－2742；和K.Peng等人，Adv.Funct.Mater.，16（2006），387－394中公开了也可使用的相关方法。
在优选实施例中，例如长度为100微米、直径为0.2微米的柱形成于硅基底上并从硅基底形成。更通常，长度处于20至300微米范围、直径或者最大横向尺寸处于0.08至0.5微米范围的柱可用于提供纤维。根据该工艺，硅基底可以为n－或者p－型，并且根据化学方法，其可在任何暴露的（100）或者（110）晶面上被蚀刻。因为蚀刻沿着晶面进行，所以所形成的纤维为单晶体。由于该结构特征，该纤维将非常容易地形成长度直径比为大约100：1，并且当处于复合阳极层中时，允许每条纤维沿着其长度多次接触其它纤维。还可在超大规模集成电路（VLSI）电子级晶片上或者其丢弃的样品（单晶晶片）上进行蚀刻工艺。作为更廉价的选择，还可采用如用于太阳能面板的光伏级多晶材料。
为将柱分离以获得纤维，附接有柱的基底被置于大口杯或者任何合适的容器中、被惰性液体例如乙醇覆盖并受到超声搅拌。发现在几分钟内可看到液体变混浊，并且可通过电子显微镜检验看到在该阶段柱被从其硅基底去除。
将认识到，用于“收集”柱的可选方法包括刮擦基底表面以将其分离或者将其化学分离。一种适合于n－型硅材料的化学方法包括在出现对硅晶片的背面照射时在HF溶液中蚀刻所述基底。
一旦硅柱被分离则其可被用作锂离子电化学电池的复合阳极中的活性材料。为制造复合阳极，从溶液中过滤所收集的硅，可将其与聚偏二氟乙烯混合，以及与浇铸溶剂例如n－甲基吡咯烷酮形成浆液。然后该浆液可例如利用刮刀物理地、或者以任何其它合适方式施加或者涂敷至金属板或者金属箔或者其它导电基底，以产生需要厚度的涂敷膜，然后利用可采用50℃至140℃的提高温度的合适干燥系统，将浇铸溶剂从该膜蒸发，以留下没有或基本没有浇铸溶剂的复合膜。所产生的垫或者复合膜具有多孔和/或毡状结构，其中硅纤维的质量通常占70％和95％。复合膜的孔体积百分比为10－30％，优选大约为20％。
图2示出了通过上面方法获得的复合电极结构的SEM。可选地，毡或毡状结构可形成为片材料（不一定在集电器上）并用作其本身的集电器。
其后可以例如根据图1所示出的总体结构但是以硅或者基于硅的活性阳极材料而非石墨活性阳极材料以合适方式制造锂离子单体电池。例如由多孔隔板18覆盖基于硅纤维的复合阳极层，添加到最终结构的电解质充满全部可进入的孔体积。在将电极置于合适的外壳中之后添加电解质，所述添加可包括真空填充阳极，以保证孔体积被填充液态电解质。
请参考下面的实例：
称量0.0140g的硅纤维放入2cm2的Eppendorf离心机管中，并添加0.0167g的SuperP导电碳。然后将N－甲基吡咯烷酮（NMP）移入管中直到分散所有的材料（0.92g）。预先，7.8wt％的PVDF已经溶解于NMP中。将含有0.0074g PVDF的该溶液添加至管。混合成分如下Si：PVDF：Super P＝85.3：4.5：10.1wt％。
该管被置于超声槽中达一小时以使该混合物均匀，然后再搅拌一小时。然后采用刮刀间隙为0.8mm的刮刀将该浆液涂敷至14μm的铜箔上。然后在100℃下对该涂层干燥一小时以蒸发NMP溶剂。经过干燥之后，涂层的厚度为30－40μm。图2示出了没有Super P碳的相似混合物和涂层的SEM。
轻轻轧制涂层，然后电极盘被切削为直径为12mm。在充氩的手套箱将其组装至电化学电池中。反电极和基准电极都为锂金属。电解质为有机碳酸酯混合物中的LiPF6。在VMP3设备上测试该电池。经过三十分钟的浸泡之后，该电池被保持在-0.1mA达一小时，然后获得-0.2mA直到需要的锂化容量。然后在＋0.2mA对电极脱锂化，直到1.0V vs.Li/Li+的电压。图3示出了该第一循环中的电池电压。
这里所描述方法的特别优点在于如果必要可制造、轧制大片的基于硅的阳极，然后和当前锂离子单体电池的基于石墨的阳极一样地随后切开或者冲压，这意味着这里所描述的方法可以以现有的制造能力进行改良。
这里所描述设置的另一个优点在于结构强度实际上随着每次充电操作提高。这是因为由于在形成无定形结构的纤维节点上的破裂晶体结构造成纤维相互“熔合”。这又降低了在多个循环上容量损失的风险，这是因为一旦纤维以上述方式连接则纤维机械分离的可能更低。
当然，将理解可采用任何合适的方法以实现上述方法和装置。例如，柱分离操作可包括摇动、刮擦、化学或者其它操作的任何一种，只要从基底去除柱以形成纤维。合适时，对基于硅的材料的参考包括硅。该纤维可具有任何合适的尺寸，并且例如可以为纯硅或者掺杂的硅或者其它基于硅的材料例如硅－锗混合物或者任何其它合适的混合物。形成柱的基底可以为n－或p－型，从100至0.001欧姆cm，或者其可以为合适的硅合金，例如SixGe1-x。纤维可用于任何合适的目的例如制造通常包括阴极的电极。该阴极材料可以为任何合适的材料，通常为基于锂的金属氧化物或者磷酸盐材料，例如LiCoO2、LiMnxNixCo1－2xO2或者LiFePO4。不同实施例的特征可以相互替换或者并列设置并且以任何合适的顺序进行该方法步骤。

Claims (18)

1.一种包括复合物电池电极的锂离子电池，所述电极包括多孔结构，所述多孔结构包括粘合剂和作为所述电极的活性材料的硅或基于硅的电极纤维，其中所述纤维形成毡，其中所述毡包括被设置为在电极纤维之间提供多个交叉点的多个硅或基于硅的纤维，包括位于纤维交叉点上的无定形硅部分，该无定形硅部分使所述纤维相互熔合，其中所述纤维沿着其长度方向多次接触其它纤维。
2.根据权利要求1的锂离子电池，其中在所述多孔结构中的硅或基于硅的纤维的质量占70-95％。
3.根据权利要求1的锂离子电池，其中所述多孔结构的孔体积百分比为10-30％。
4.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维为基本上直的。
5.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维的纵横比为100:1。
6.根据权利要求1的锂离子电池，其中通过将柱与基底分离制造所述硅或基于硅的纤维。
7.根据权利要求6的锂离子电池，其中通过简单可重复的化学工艺制造所述柱。
8.根据权利要求7的锂离子电池，其中所述简单可重复的化学工艺包括蚀刻。
9.根据权利要求8的锂离子电池，其中所述蚀刻为反应离子蚀刻、化学反应蚀刻或电交换蚀刻。
10.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维具有80到500nm的横向尺寸。
11.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维具有20到300微米的长度。
12.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维为单晶纤维。
13.根据权利要求1的锂离子电池，其中所述毡包括无序的或有序的所述纤维的层。
14.根据权利要求1的锂离子电池，其中所述硅或基于硅的纤维包括n-型或p-型硅。
15.根据权利要求1的锂离子电池，还包括充满可进入的孔体积的电解质。
16.根据权利要求15的锂离子电池，其中所述电解质为液态电解质。
17.根据权利要求1的锂离子电池，其中所述复合物电池电极为阳极以及所述锂离子电池还包括阴极。
18.一种由根据权利要求17的锂离子电池供电的设备。
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Families Citing this family (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2395059B (en) 2002-11-05 2005-03-16 Imp College Innovations Ltd Structured silicon anode
GB0601318D0 (en) 2006-01-23 2006-03-01 Imp Innovations Ltd Method of etching a silicon-based material
GB0601319D0 (en) * 2006-01-23 2006-03-01 Imp Innovations Ltd A method of fabricating pillars composed of silicon-based material
US8999558B2 (en) 2007-01-12 2015-04-07 Enovix Corporation Three-dimensional batteries and methods of manufacturing the same
GB0709165D0 (en) 2007-05-11 2007-06-20 Nexeon Ltd A silicon anode for a rechargeable battery
GB0713896D0 (en) 2007-07-17 2007-08-29 Nexeon Ltd Method
GB0713895D0 (en) * 2007-07-17 2007-08-29 Nexeon Ltd Production
GB0713898D0 (en) 2007-07-17 2007-08-29 Nexeon Ltd A method of fabricating structured particles composed of silcon or a silicon-based material and their use in lithium rechargeable batteries
US7816031B2 (en) 2007-08-10 2010-10-19 The Board Of Trustees Of The Leland Stanford Junior University Nanowire battery methods and arrangements
GB2464158B (en) * 2008-10-10 2011-04-20 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries
GB2464157B (en) 2008-10-10 2010-09-01 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material
US11996550B2 (en) 2009-05-07 2024-05-28 Amprius Technologies, Inc. Template electrode structures for depositing active materials
US20100285358A1 (en) 2009-05-07 2010-11-11 Amprius, Inc. Electrode Including Nanostructures for Rechargeable Cells
GB2470056B (en) * 2009-05-07 2013-09-11 Nexeon Ltd A method of making silicon anode material for rechargeable cells
GB2470190B (en) * 2009-05-11 2011-07-13 Nexeon Ltd A binder for lithium ion rechargeable battery cells
GB0908089D0 (en) 2009-05-11 2009-06-24 Nexeon Ltd A binder for lithium ion rechargaable battery cells
US9853292B2 (en) 2009-05-11 2017-12-26 Nexeon Limited Electrode composition for a secondary battery cell
GB2495951B (en) * 2011-10-26 2014-07-16 Nexeon Ltd A composition for a secondary battery cell
ES2867474T3 (es) 2009-05-19 2021-10-20 Oned Mat Inc Materiales nanoestructurados para aplicaciones de batería
US8450012B2 (en) 2009-05-27 2013-05-28 Amprius, Inc. Interconnected hollow nanostructures containing high capacity active materials for use in rechargeable batteries
US9373838B2 (en) 2009-09-29 2016-06-21 Georgia Tech Research Corporation Electrodes, lithium-ion batteries, and methods of making and using same
US9061902B2 (en) 2009-12-18 2015-06-23 The Board Of Trustees Of The Leland Stanford Junior University Crystalline-amorphous nanowires for battery electrodes
CN102844917B (zh) 2010-03-03 2015-11-25 安普雷斯股份有限公司 用于沉积活性材料的模板电极结构
US9172088B2 (en) 2010-05-24 2015-10-27 Amprius, Inc. Multidimensional electrochemically active structures for battery electrodes
US9780365B2 (en) 2010-03-03 2017-10-03 Amprius, Inc. High-capacity electrodes with active material coatings on multilayered nanostructured templates
EP2556188A4 (en) * 2010-04-06 2014-01-15 Ndsu Res Foundation LIQUID SILICONE COMPOSITIONS AND METHOD FOR PRODUCING MATERIALS BASED ON SILICON BASE
GB201005979D0 (en) 2010-04-09 2010-05-26 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries
GB201009519D0 (en) 2010-06-07 2010-07-21 Nexeon Ltd An additive for lithium ion rechargeable battery cells
KR101874935B1 (ko) 2010-06-30 2018-07-05 가부시키가이샤 한도오따이 에네루기 켄큐쇼 축전 장치 및 그 제조 방법
KR101899303B1 (ko) 2010-08-05 2018-09-18 후지필름 와코 준야꾸 가부시키가이샤 비수계 전해액 및 그를 사용한 비수계 전해액 전지
JP5861634B2 (ja) 2010-08-05 2016-02-16 和光純薬工業株式会社 非水系電解液、その製造法、及び該電解液を用いた非水系電解液電池
GB201014706D0 (en) 2010-09-03 2010-10-20 Nexeon Ltd Porous electroactive material
GB201014707D0 (en) 2010-09-03 2010-10-20 Nexeon Ltd Electroactive material
US9843027B1 (en) 2010-09-14 2017-12-12 Enovix Corporation Battery cell having package anode plate in contact with a plurality of dies
WO2012067943A1 (en) 2010-11-15 2012-05-24 Amprius, Inc. Electrolytes for rechargeable batteries
WO2012083480A1 (en) * 2010-12-20 2012-06-28 Epro Development Limited Method and apparatus for producing pure silicon
GB2487569B (en) 2011-01-27 2014-02-19 Nexeon Ltd A binder for a secondary battery cell
GB2492167C (en) 2011-06-24 2018-12-05 Nexeon Ltd Structured particles
EP2727175A4 (en) 2011-07-01 2015-07-01 Amprius Inc ELECTRODE TEMPLATE STRUCTURES WITH IMPROVED ADHESION PROPERTIES
EP2764565B1 (en) 2011-10-05 2023-02-22 OneD Material, Inc. Silicon nanostructure active materials for lithium ion batteries and processes, compositions, components, and devices related thereto
CN103030096A (zh) * 2011-10-09 2013-04-10 中国科学院高能物理研究所 一种具有纳米结构表面的硅材料及其制作方法
US8841030B2 (en) 2012-01-24 2014-09-23 Enovix Corporation Microstructured electrode structures
WO2013114095A1 (en) * 2012-01-30 2013-08-08 Nexeon Limited Composition of si/c electro active material
GB2499984B (en) 2012-02-28 2014-08-06 Nexeon Ltd Composite particles comprising a removable filler
GB2502625B (en) 2012-06-06 2015-07-29 Nexeon Ltd Method of forming silicon
CN104662714B (zh) 2012-08-16 2017-09-29 艾诺维克斯公司 三维电池的电极结构
US10374221B2 (en) 2012-08-24 2019-08-06 Sila Nanotechnologies, Inc. Scaffolding matrix with internal nanoparticles
CN102916141A (zh) * 2012-10-10 2013-02-06 东莞新能德科技有限公司 锂离子电池及其制作方法
GB2507535B (en) 2012-11-02 2015-07-15 Nexeon Ltd Multilayer electrode
EP2738839B1 (en) * 2012-11-29 2015-08-12 The Swatch Group Research and Development Ltd. Flexible electrode of an electrochemical cell
JP6524053B2 (ja) * 2013-03-14 2019-06-05 エネヴェート・コーポレーション 電気化学セルスタックのためのクランプ装置
KR102659783B1 (ko) 2013-03-15 2024-04-22 에노빅스 코오퍼레이션 3차원 배터리들을 위한 분리기들
KR20160070119A (ko) 2013-10-15 2016-06-17 넥세온 엘티디 전기화학 셀용 보강 집전 기판 조립체
KR101567203B1 (ko) 2014-04-09 2015-11-09 (주)오렌지파워 이차 전지용 음극 활물질 및 이의 방법
KR101604352B1 (ko) 2014-04-22 2016-03-18 (주)오렌지파워 음극 활물질 및 이를 포함하는 리튬 이차 전지
US9923201B2 (en) 2014-05-12 2018-03-20 Amprius, Inc. Structurally controlled deposition of silicon onto nanowires
CN104009211B (zh) * 2014-05-13 2017-04-12 昆明理工大学 一种多孔硅纳米纤维/碳复合材料的制备方法
US10128496B2 (en) 2014-08-14 2018-11-13 Giner, Inc. Three-dimensional, porous anode for use in lithium-ion batteries and method of fabrication thereof
US10403889B2 (en) 2014-10-21 2019-09-03 RAMOT AT TEL-AVIV UNlVERSITY LTD. High-capacity silicon nanowire based anode for lithium-ion batteries
GB2533161C (en) 2014-12-12 2019-07-24 Nexeon Ltd Electrodes for metal-ion batteries
JP6007994B2 (ja) 2015-01-23 2016-10-19 セントラル硝子株式会社 非水電解液二次電池用電解液及びそれを用いた非水電解液二次電池
US10454139B2 (en) 2015-01-23 2019-10-22 Central Glass Co., Ltd. Electrolytic solution for nonaqueous electrolytic solution secondary batteries and nonaqueous electrolytic solution secondary battery
NL2014588B1 (en) * 2015-04-07 2017-01-19 Stichting Energieonderzoek Centrum Nederland Rechargeable battery and method for manufacturing the same.
EP4113683A1 (en) 2015-05-14 2023-01-04 Enovix Corporation Longitudinal constraints for energy storage devices
JP6098684B2 (ja) 2015-08-12 2017-03-22 セントラル硝子株式会社 非水電解液二次電池用電解液及びそれを用いた非水電解液二次電池
US10199633B2 (en) 2015-12-09 2019-02-05 Ut-Battelle, Llc Method of manufacturing high volumetric density electrodes from self-aligning fiber powders
EP4235898A3 (en) 2015-12-22 2023-11-01 Central Glass Company, Limited Electrolyte for non-aqueous electrolyte cell, and non-aqueous electrolyte cell in which same is used
CN105633407B (zh) * 2016-03-11 2018-07-27 中物院成都科学技术发展中心 锂离子电池用碳基负极材料表面改性方法及其碳基负极材料
CN115425297A (zh) 2016-05-13 2022-12-02 艾诺维克斯公司 三维电池的尺寸约束
JP6245312B2 (ja) 2016-05-30 2017-12-13 セントラル硝子株式会社 非水系電解液二次電池用電解液及びそれを用いた非水系電解液二次電池
WO2017216558A1 (en) 2016-06-14 2017-12-21 Nexeon Limited Electrodes for metal-ion batteries
JP6260735B1 (ja) 2016-07-06 2018-01-17 セントラル硝子株式会社 非水系電解液及びそれを用いた非水系電解液二次電池
EP3386916B1 (en) * 2016-07-27 2021-04-14 Epro Development Limited Improvements in the production of silicon nano-particles and uses thereof
JP7086978B2 (ja) 2016-11-16 2022-06-20 エノビクス・コーポレイション 圧縮性カソードを備えた３次元電池
CN110520431B (zh) 2017-04-10 2022-02-18 中央硝子株式会社 磷酰亚胺盐的制造方法、包含该盐的非水电解液的制造方法和非水二次电池的制造方法
GB2563455B (en) 2017-06-16 2019-06-19 Nexeon Ltd Particulate electroactive materials for use in metal-ion batteries
JP7223221B2 (ja) 2017-09-12 2023-02-16 セントラル硝子株式会社 非水電解液用添加剤、非水電解液、及び非水電解液電池
JP7172015B2 (ja) 2017-09-12 2022-11-16 セントラル硝子株式会社 非水電解液用添加剤、非水電解液電池用電解液、及び非水電解液電池
US10256507B1 (en) 2017-11-15 2019-04-09 Enovix Corporation Constrained electrode assembly
TW202347848A (zh) 2017-11-15 2023-12-01 美商易諾維公司 電極總成、蓄電池組、及製造方法
WO2019111983A1 (ja) 2017-12-06 2019-06-13 セントラル硝子株式会社 非水電解液電池用電解液及びそれを用いた非水電解液電池
WO2019117101A1 (ja) 2017-12-12 2019-06-20 セントラル硝子株式会社 非水電解液電池用電解液及びそれを用いた非水電解液電池
US10833356B2 (en) 2018-07-03 2020-11-10 International Business Machines Corporation Kinetically fast charging lithium-ion battery
US10833311B2 (en) 2018-07-03 2020-11-10 International Business Machines Corporation Method of making an anode structure containing a porous region
US10833357B2 (en) 2018-07-03 2020-11-10 International Business Machines Corporation Battery structure with an anode structure containing a porous region and method of operation
US10777842B2 (en) 2018-07-03 2020-09-15 International Business Machines Corporation Rechargeable lithium-ion battery with an anode structure containing a porous region
US11211639B2 (en) 2018-08-06 2021-12-28 Enovix Corporation Electrode assembly manufacture and device
KR102571720B1 (ko) 2018-08-16 2023-08-28 샌트랄 글래스 컴퍼니 리미티드 비수계 전해액, 및 비수계 전해액 이차 전지
GB201818232D0 (en) 2018-11-08 2018-12-26 Nexeon Ltd Electroactive materials for metal-ion batteries
GB2584615C (en) 2019-05-20 2023-10-25 Nexeon Ltd Electroactive materials for metal-ion batteries
GB201818235D0 (en) 2018-11-08 2018-12-26 Nexeon Ltd Electroactive materials for metal-ion batteries
GB2580033B (en) 2018-12-19 2021-03-10 Nexeon Ltd Electroactive materials for metal-Ion batteries
CN113939938A (zh) 2019-06-05 2022-01-14 中央硝子株式会社 非水电解液
US20220255131A1 (en) 2019-06-05 2022-08-11 Central Glass Co., Ltd. Nonaqueous Electrolytic Solution and Nonaqueous Electrolytic Solution Battery
KR20220016852A (ko) 2019-06-05 2022-02-10 샌트랄 글래스 컴퍼니 리미티드 비수전해액
WO2021006302A1 (ja) 2019-07-08 2021-01-14 セントラル硝子株式会社 非水電解液、及びこれを用いた非水電解液電池
EP3993120A4 (en) 2019-07-09 2024-05-29 Central Glass Co Ltd ANHYDROUS ELECTROLYTE AND SECONDARY BATTERY WITH ANHYDROUS ELECTROLYTE
JP7259792B2 (ja) * 2019-07-26 2023-04-18 トヨタ自動車株式会社 負極活物質、負極活物質の製造方法および電池
TWI740400B (zh) * 2020-03-02 2021-09-21 力哲科技股份有限公司 電池材料及其製備方法
KR20230121171A (ko) 2020-08-03 2023-08-17 넥시온 엘티디. 금속-이온 배터리용 전기활성 물질
EP4189757A1 (en) 2020-08-03 2023-06-07 Nexeon Limited Electroactive materials for metal-ion batteries
RU2743576C1 (ru) * 2020-08-12 2021-02-20 Федеральное государственное бюджетное учреждение науки Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наук (ИФХЭ РАН) Анод литий-ионного аккумулятора для работы при пониженных температурах и способ его изготовления
US20230275271A1 (en) 2020-09-03 2023-08-31 Central Glass Co., Ltd. Nonaqueous electrolytic solution and nonaqueous electrolytic solution battery
US20230361285A1 (en) * 2020-09-16 2023-11-09 Theion Gmbh Advanced heterofibrous monolithic wafer-like silicon anode
JP2023547993A (ja) 2020-09-18 2023-11-15 エノビクス・コーポレイション 電池に使用する電極の製造のための装置、システム、及び方法
US20230395774A1 (en) 2020-10-23 2023-12-07 Wacker Chemie Ag Process for preparing silicon-containing composite particles
WO2022125529A1 (en) 2020-12-09 2022-06-16 Enovix Operations Inc. Method and apparatus for the production of electrode assemblies for secondary batteries
GB2602139A (en) 2020-12-18 2022-06-22 Nexeon Ltd Electroactive materials for metal-ion batteries
GB202106351D0 (en) 2021-05-04 2021-06-16 Univ Oslo Battery
JPWO2022244046A1 (zh) 2021-05-17 2022-11-24
WO2023042871A1 (ja) 2021-09-17 2023-03-23 セントラル硝子株式会社 非水溶液、保持方法、及び、非水電池
GB2612092A (en) 2021-10-21 2023-04-26 Nexeon Ltd Process for preparing electroactive materials for metal-ion batteries
GB2616590B (en) 2021-10-21 2024-05-15 Nexeon Ltd Electroactive materials for metal-ion batteries

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1111074A (zh) * 1993-06-23 1995-11-01 东丽株式会社 电池用电极、使用该电极的二次电池以及该电极的制备方法
CN1447916A (zh) * 2000-06-15 2003-10-08 北卡罗来纳-查佩尔山大学 纳米结构基高能量物质

Family Cites Families (278)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB980513A (en) 1961-11-17 1965-01-13 Licentia Gmbh Improvements relating to the use of silicon in semi-conductor devices
US3351445A (en) * 1963-08-07 1967-11-07 William S Fielder Method of making a battery plate
GB1014706A (en) 1964-07-30 1965-12-31 Hans Ohl Improvements in or relating to devices for controlling the dosing of a plurality of different pourable substances for the production of mixtures
US4002541A (en) * 1972-11-03 1977-01-11 Design Systems, Inc. Solar energy absorbing article and method of making same
SU471402A1 (ru) 1973-03-02 1975-05-25 Предприятие П/Я Г-4671 Травильный раствор
SU544019A1 (ru) 1975-07-22 1977-01-25 Одесский Ордена Трудового Красного Знамени Государственный Университет Им.И.И.Мечникова Травитель дл полупроводниковых материалов
US4973605A (en) 1979-08-30 1990-11-27 Herschler R J Use of methylsulfonylmethane to relieve pain and relieve pain and nocturnal cramps and to reduce stress-induced deaths in animals
US4436796A (en) * 1981-07-30 1984-03-13 The United States Of America As Represented By The United States Department Of Energy All-solid electrodes with mixed conductor matrix
JPS63215041A (ja) 1987-03-04 1988-09-07 Toshiba Corp 結晶欠陥評価用エツチング液
RU2154326C2 (ru) * 1988-03-24 2000-08-10 Федеральное государственное унитарное предприятие "Научно-производственное предприятие "Квант" Активный материал электрода химического источника тока
US4950566A (en) * 1988-10-24 1990-08-21 Huggins Robert A Metal silicide electrode in lithium cells
JPH08987B2 (ja) 1989-02-10 1996-01-10 日産自動車株式会社 アルミニウム合金の表面処理方法
JP2717890B2 (ja) 1991-05-27 1998-02-25 富士写真フイルム株式会社 リチウム二次電池
DE4202454C1 (zh) * 1992-01-29 1993-07-29 Siemens Ag, 8000 Muenchen, De
JP3216311B2 (ja) * 1993-03-26 2001-10-09 松下電器産業株式会社 リチウム電池
JP3541387B2 (ja) 1993-06-23 2004-07-07 東レ株式会社 電池用電極，それを用いた二次電池，および電池用電極の製造方法
JPH07202023A (ja) 1993-12-28 1995-08-04 Nippon Steel Corp 半導体記憶装置及びその製造方法
US5516598A (en) * 1994-07-28 1996-05-14 Polyplus Battery Company, Inc. Secondary cell using organosulfur/metal charge transfer materials as positive electrode
US5660948A (en) 1995-09-26 1997-08-26 Valence Technology, Inc. Lithium ion electrochemical cell
US5907899A (en) * 1996-06-11 1999-06-01 Dow Corning Corporation Method of forming electrodes for lithium ion batteries using polycarbosilanes
US6881520B1 (en) 1996-06-14 2005-04-19 N.V. Umicore S.A. Electrode material for rechargeable batteries and process for the preparation thereof
JP3713900B2 (ja) * 1996-07-19 2005-11-09 ソニー株式会社 負極材料及びこれを用いた非水電解液二次電池
JPH1046366A (ja) 1996-08-02 1998-02-17 Toyota Motor Corp アルミニウム合金用エッチング液およびエッチング方法
US6022640A (en) * 1996-09-13 2000-02-08 Matsushita Electric Industrial Co., Ltd. Solid state rechargeable lithium battery, stacking battery, and charging method of the same
JPH1097833A (ja) 1996-09-20 1998-04-14 Nippon Electric Glass Co Ltd 陰極線管用パネル
JP3296543B2 (ja) 1996-10-30 2002-07-02 スズキ株式会社 めっき被覆アルミニウム合金、及びそのシリンダーブロック、めっき処理ライン、めっき方法
JP3620559B2 (ja) * 1997-01-17 2005-02-16 株式会社ユアサコーポレーション 非水電解質電池
JP4410315B2 (ja) * 1997-05-27 2010-02-03 Ｔｄｋ株式会社 非水電解質電池用電極
US6337156B1 (en) 1997-12-23 2002-01-08 Sri International Ion battery using high aspect ratio electrodes
JP4399881B2 (ja) 1998-12-02 2010-01-20 パナソニック株式会社 非水電解質二次電池
WO2000033401A1 (fr) * 1998-12-02 2000-06-08 Matsushita Electric Industrial Co., Ltd. Cellule secondaire d'electrolyte du type non aqueux
JP3624088B2 (ja) 1998-01-30 2005-02-23 キヤノン株式会社 粉末材料、電極構造体、それらの製造方法、及びリチウム二次電池
JPH11283603A (ja) * 1998-03-30 1999-10-15 Noritake Co Ltd 電池用セパレーター及びその製造方法
US6235427B1 (en) * 1998-05-13 2001-05-22 Fuji Photo Film Co., Ltd. Nonaqueous secondary battery containing silicic material
JP4728458B2 (ja) * 1998-06-12 2011-07-20 宇部興産株式会社 非水二次電池
JP2948205B1 (ja) 1998-05-25 1999-09-13 花王株式会社 二次電池用負極の製造方法
JP2000022162A (ja) 1998-07-06 2000-01-21 Advanced Display Inc 液晶表示装置の製法
US6063995A (en) * 1998-07-16 2000-05-16 First Solar, Llc Recycling silicon photovoltaic modules
KR100276656B1 (ko) 1998-09-16 2001-04-02 박찬구 박막형 복합 재료 양극으로 구성된 고체형 이차 전지
US6809229B2 (en) * 1999-01-12 2004-10-26 Hyperion Catalysis International, Inc. Method of using carbide and/or oxycarbide containing compositions
KR100310824B1 (ko) 1999-01-29 2001-10-17 김영환 반도체장치의 캐패시터 및 그 제조방법
DE19922257A1 (de) * 1999-05-14 2000-11-16 Siemens Ag Verfahren zum Einbringen von Schlitzen in Siliziumscheiben
EP1208002A4 (en) 1999-06-03 2006-08-02 Penn State Res Found MATERIALS WITH NETWORK OF SURFACE POROSITY COLUMNS DEPOSITED IN THIN FILM
GB9919479D0 (en) * 1999-08-17 1999-10-20 Imperial College Island arrays
US7235330B1 (en) 1999-10-22 2007-06-26 Sanyo Electric Co., Ltd. Electrode for use in lithium battery and rechargeable lithium battery
JP3702223B2 (ja) * 1999-10-22 2005-10-05 三洋電機株式会社 リチウム電池用電極材料の製造方法
EP1231654A4 (en) 1999-10-22 2007-10-31 Sanyo Electric Co ELECTRODE FOR LITHIUM BATTERY AND LITHIUM BATTERY
AU7950900A (en) * 1999-10-22 2001-05-08 Sanyo Electric Co., Ltd. Electrode for lithium secondary cell and lithium secondary cell
KR100772467B1 (ko) 1999-11-08 2007-11-02 나노그램 코포레이션 특정 크기의 입자를 갖는 전극
US6780704B1 (en) 1999-12-03 2004-08-24 Asm International Nv Conformal thin films over textured capacitor electrodes
JP2000348730A (ja) 2000-01-01 2000-12-15 Seiko Instruments Inc 非水電解質二次電池
US6353317B1 (en) * 2000-01-19 2002-03-05 Imperial College Of Science, Technology And Medicine Mesoscopic non-magnetic semiconductor magnetoresistive sensors fabricated with island lithography
US7335603B2 (en) * 2000-02-07 2008-02-26 Vladimir Mancevski System and method for fabricating logic devices comprising carbon nanotube transistors
US6835332B2 (en) 2000-03-13 2004-12-28 Canon Kabushiki Kaisha Process for producing an electrode material for a rechargeable lithium battery, an electrode structural body for a rechargeable lithium battery, process for producing said electrode structural body, a rechargeable lithium battery in which said electrode structural body is used, and a process for producing said rechargeable lithium battery
JP2001291514A (ja) 2000-04-06 2001-10-19 Sumitomo Metal Ind Ltd 非水電解質二次電池用負極材料とその製造方法
US6399246B1 (en) 2000-05-05 2002-06-04 Eveready Battery Company, Inc. Latex binder for non-aqueous battery electrodes
JP4137350B2 (ja) 2000-06-16 2008-08-20 三星エスディアイ株式会社 リチウム二次電池用の負極材料及びリチウム二次電池用の電極及びリチウム二次電池並びにリチウム二次電池用の負極材料の製造方法
NL1015956C2 (nl) 2000-08-18 2002-02-19 Univ Delft Tech Batterij en werkwijze voor het vervaardigen van een dergelijke batterij.
AU2001282569A1 (en) 2000-09-01 2002-03-22 Sanyo Electric Co., Ltd. Negative electrode for lithium secondary cell and method for producing the same
JP4212263B2 (ja) 2000-09-01 2009-01-21 三洋電機株式会社 リチウム二次電池用負極及びその製造方法
US20040061928A1 (en) 2000-09-25 2004-04-01 William Stewart Artificially structured dielectric material
WO2002047185A2 (en) 2000-12-06 2002-06-13 Huggins Robert A Improved electrodes for lithium batteries
KR100545613B1 (ko) 2001-01-18 2006-01-25 산요덴키가부시키가이샤 리튬 이차 전지
JP2002279974A (ja) 2001-03-19 2002-09-27 Sanyo Electric Co Ltd 二次電池用電極の製造方法
US7141859B2 (en) * 2001-03-29 2006-11-28 Georgia Tech Research Corporation Porous gas sensors and method of preparation thereof
JP2002313319A (ja) 2001-04-09 2002-10-25 Sanyo Electric Co Ltd リチウム二次電池用電極及びリチウム二次電池
US6887623B2 (en) * 2001-04-09 2005-05-03 Sanyo Electric Co., Ltd. Electrode for rechargeable lithium battery and rechargeable lithium battery
JP2002313345A (ja) 2001-04-13 2002-10-25 Japan Storage Battery Co Ltd 非水電解質二次電池
EP1258937A1 (en) 2001-05-17 2002-11-20 STMicroelectronics S.r.l. Micro silicon fuel cell, method of fabrication and self-powered semiconductor device integrating a micro fuel cell
JP4183401B2 (ja) 2001-06-28 2008-11-19 三洋電機株式会社 リチウム二次電池用電極の製造方法及びリチウム二次電池
US7070632B1 (en) * 2001-07-25 2006-07-04 Polyplus Battery Company Electrochemical device separator structures with barrier layer on non-swelling membrane
KR100382767B1 (ko) 2001-08-25 2003-05-09 삼성에스디아이 주식회사 리튬 2차 전지용 음극 박막 및 그의 제조방법
EP1313158A3 (en) 2001-11-20 2004-09-08 Canon Kabushiki Kaisha Electrode material for rechargeable lithium battery, electrode comprising said electrode material, rechargeable lithium battery having said electrode , and process for the production thereof
US7252749B2 (en) 2001-11-30 2007-08-07 The University Of North Carolina At Chapel Hill Deposition method for nanostructure materials
JP4035760B2 (ja) * 2001-12-03 2008-01-23 株式会社ジーエス・ユアサコーポレーション 非水電解質二次電池
US20030135989A1 (en) * 2002-01-19 2003-07-24 Huggins Robert A. Electrodes for alkali metal batteries
WO2003063271A1 (en) 2002-01-19 2003-07-31 Huggins Robert A Improved electrodes for alkali metal batteries
JP4199460B2 (ja) 2002-01-23 2008-12-17 パナソニック株式会社 角形密閉式電池
DE10392291B4 (de) 2002-02-14 2013-01-31 Rec Silicon Inc. Energie-effizientes Verfahren zum Züchten von polykristallinem Silicium
WO2003078688A1 (en) 2002-03-15 2003-09-25 Canon Kabushiki Kaisha Porous material and process for producing the same
US7147894B2 (en) 2002-03-25 2006-12-12 The University Of North Carolina At Chapel Hill Method for assembling nano objects
JP3607901B2 (ja) 2002-04-26 2005-01-05 ムネカタ株式会社 熱可塑性樹脂用難燃性付与剤
JP2004071305A (ja) * 2002-08-05 2004-03-04 Hitachi Maxell Ltd 非水電解質二次電池
US6916679B2 (en) * 2002-08-09 2005-07-12 Infinite Power Solutions, Inc. Methods of and device for encapsulation and termination of electronic devices
US8445130B2 (en) * 2002-08-09 2013-05-21 Infinite Power Solutions, Inc. Hybrid thin-film battery
US8021778B2 (en) 2002-08-09 2011-09-20 Infinite Power Solutions, Inc. Electrochemical apparatus with barrier layer protected substrate
US8236443B2 (en) * 2002-08-09 2012-08-07 Infinite Power Solutions, Inc. Metal film encapsulation
US20080003496A1 (en) * 2002-08-09 2008-01-03 Neudecker Bernd J Electrochemical apparatus with barrier layer protected substrate
US20070264564A1 (en) * 2006-03-16 2007-11-15 Infinite Power Solutions, Inc. Thin film battery on an integrated circuit or circuit board and method thereof
JP2004095264A (ja) 2002-08-30 2004-03-25 Mitsubishi Materials Corp リチウムイオン二次電池用負極及び該負極を用いて作製したリチウムイオン二次電池
WO2004022484A1 (ja) * 2002-09-05 2004-03-18 National Institute Of Advanced Industrial Science And Technology 金属酸化物、金属窒化物又は金属炭化物コート炭素微粉末、その製造方法、当該炭素微粉末を用いたスーパーキャパシター及び二次電池
US20040126659A1 (en) 2002-09-10 2004-07-01 Graetz Jason A. High-capacity nanostructured silicon and lithium alloys thereof
JP4614625B2 (ja) * 2002-09-30 2011-01-19 三洋電機株式会社 リチウム二次電池の製造方法
US7051945B2 (en) * 2002-09-30 2006-05-30 Nanosys, Inc Applications of nano-enabled large area macroelectronic substrates incorporating nanowires and nanowire composites
GB2395059B (en) 2002-11-05 2005-03-16 Imp College Innovations Ltd Structured silicon anode
CA2411695A1 (fr) * 2002-11-13 2004-05-13 Hydro-Quebec Electrode recouverte d'un film obtenu a partir d'une solution aqueuse comportant un liant soluble dans l'eau, son procede de fabrication et ses utilisations
JP4088957B2 (ja) 2002-11-19 2008-05-21 ソニー株式会社 リチウム二次電池
JP3664252B2 (ja) 2002-11-19 2005-06-22 ソニー株式会社 負極およびそれを用いた電池
JP4025995B2 (ja) * 2002-11-26 2007-12-26 信越化学工業株式会社 非水電解質二次電池負極材及びその製造方法並びにリチウムイオン二次電池
KR20050084226A (ko) 2002-12-09 2005-08-26 더 유니버시티 오브 노쓰 캐롤라이나 엣 채플 힐 나노구조체 함유 물질 및 관련 물품의 조립 및 분류 방법
US7491467B2 (en) * 2002-12-17 2009-02-17 Mitsubishi Chemical Corporation Negative electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery using the same
US20040214085A1 (en) 2003-01-06 2004-10-28 Kyou-Yoon Sheem Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery
US8048568B2 (en) * 2003-01-06 2011-11-01 Samsung Sdi Co., Ltd. Negative active material for rechargeable lithium battery and rechargeable lithium battery
JP3827642B2 (ja) 2003-01-06 2006-09-27 三星エスディアイ株式会社 リチウム二次電池用負極活物質及びその製造方法並びにリチウム二次電池
US7244513B2 (en) 2003-02-21 2007-07-17 Nano-Proprietary, Inc. Stain-etched silicon powder
JP2004281317A (ja) * 2003-03-18 2004-10-07 Matsushita Electric Ind Co Ltd 非水電解質二次電池用電極材料とその製造方法、ならびにそれを用いた非水電解質二次電池
US20040185346A1 (en) * 2003-03-19 2004-09-23 Takeuchi Esther S. Electrode having metal vanadium oxide nanoparticles for alkali metal-containing electrochemical cells
US6969690B2 (en) 2003-03-21 2005-11-29 The University Of North Carolina At Chapel Hill Methods and apparatus for patterned deposition of nanostructure-containing materials by self-assembly and related articles
CN1322611C (zh) * 2003-03-26 2007-06-20 佳能株式会社 电极材料、具有该材料的构造体和具有该构造体的二次电池
JP4027255B2 (ja) 2003-03-28 2007-12-26 三洋電機株式会社 リチウム二次電池用負極及びその製造方法
US20040241548A1 (en) 2003-04-02 2004-12-02 Takayuki Nakamoto Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same
CN100347885C (zh) * 2003-05-22 2007-11-07 松下电器产业株式会社 非水电解质二次电池及其制造方法
JP4416734B2 (ja) 2003-06-09 2010-02-17 三洋電機株式会社 リチウム二次電池及びその製造方法
US7094499B1 (en) * 2003-06-10 2006-08-22 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Carbon materials metal/metal oxide nanoparticle composite and battery anode composed of the same
JP4610213B2 (ja) 2003-06-19 2011-01-12 三洋電機株式会社 リチウム二次電池及びその製造方法
US7318982B2 (en) * 2003-06-23 2008-01-15 A123 Systems, Inc. Polymer composition for encapsulation of electrode particles
JP4095499B2 (ja) * 2003-06-24 2008-06-04 キヤノン株式会社 リチウム二次電池用の電極材料、電極構造体及びリチウム二次電池
EP1662592A4 (en) * 2003-07-15 2008-09-24 Itochu Corp ELECTRICITY STRUCTURE AND ELECTRON STRUCTURE
KR100595896B1 (ko) * 2003-07-29 2006-07-03 주식회사 엘지화학 리튬 이차 전지용 음극 활물질 및 그의 제조 방법
KR100496306B1 (ko) * 2003-08-19 2005-06-17 삼성에스디아이 주식회사 리튬 금속 애노드의 제조방법
KR100497251B1 (ko) * 2003-08-20 2005-06-23 삼성에스디아이 주식회사 리튬 설퍼 전지용 음극 보호막 조성물 및 이를 사용하여제조된 리튬 설퍼 전지
US7479351B2 (en) 2003-10-09 2009-01-20 Samsung Sdi Co., Ltd. Electrode material for a lithium secondary battery, lithium secondary battery, and preparation method for the electrode material for a lithium secondary battery
DE10347570B4 (de) 2003-10-14 2015-07-23 Evonik Degussa Gmbh Anorganische Separator-Elektroden-Einheit für Lithium-Ionen-Batterien, Verfahren zu deren Herstellung, Verwendung in Lithium-Batterien und Lithium-Batterien mit der anorganischen Separator-Elektroden-Einheit
JP4497899B2 (ja) 2003-11-19 2010-07-07 三洋電機株式会社 リチウム二次電池
US7816032B2 (en) * 2003-11-28 2010-10-19 Panasonic Corporation Energy device and method for producing the same
US20110039690A1 (en) 2004-02-02 2011-02-17 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
US7553371B2 (en) 2004-02-02 2009-06-30 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
US8025960B2 (en) 2004-02-02 2011-09-27 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
JP2005235358A (ja) 2004-02-23 2005-09-02 Tdk Corp 磁気記録媒体
KR100578870B1 (ko) 2004-03-08 2006-05-11 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질, 그의 제조 방법 및 그를포함하는 리튬 이차 전지
US7521153B2 (en) * 2004-03-16 2009-04-21 Toyota Motor Engineering & Manufacturing North America, Inc. Corrosion protection using protected electron collector
US7348102B2 (en) * 2004-03-16 2008-03-25 Toyota Motor Corporation Corrosion protection using carbon coated electron collector for lithium-ion battery with molten salt electrolyte
US7468224B2 (en) * 2004-03-16 2008-12-23 Toyota Motor Engineering & Manufacturing North America, Inc. Battery having improved positive electrode and method of manufacturing the same
JP4623283B2 (ja) 2004-03-26 2011-02-02 信越化学工業株式会社 珪素複合体粒子及びその製造方法並びに非水電解質二次電池用負極材
US7790316B2 (en) * 2004-03-26 2010-09-07 Shin-Etsu Chemical Co., Ltd. Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
DE102004016766A1 (de) * 2004-04-01 2005-10-20 Degussa Nanoskalige Siliziumpartikel in negativen Elektrodenmaterialien für Lithium-Ionen-Batterien
US8231810B2 (en) * 2004-04-15 2012-07-31 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
US7781102B2 (en) 2004-04-22 2010-08-24 California Institute Of Technology High-capacity nanostructured germanium-containing materials and lithium alloys thereof
EP1747577A2 (en) 2004-04-30 2007-01-31 Nanosys, Inc. Systems and methods for nanowire growth and harvesting
KR100821630B1 (ko) * 2004-05-17 2008-04-16 주식회사 엘지화학 전극 및 이의 제조방법
US20060019115A1 (en) * 2004-05-20 2006-01-26 Liya Wang Composite material having improved microstructure and method for its fabrication
GB2414231A (en) 2004-05-21 2005-11-23 Psimedica Ltd Porous silicon
TWI344953B (en) 2004-07-01 2011-07-11 Basf Ag Preparation of acrolein or acrylic acid or a mixture thereof from propane
FR2873854A1 (fr) 2004-07-30 2006-02-03 Commissariat Energie Atomique Procede de fabrication d'une electrode lithiee, electrode lithiee susceptible d'etre obtenue par ce procede et ses utilisations
US20060088767A1 (en) * 2004-09-01 2006-04-27 Wen Li Battery with molten salt electrolyte and high voltage positive active material
US20060051670A1 (en) 2004-09-03 2006-03-09 Shin-Etsu Chemical Co., Ltd. Non-aqueous electrolyte secondary cell negative electrode material and metallic silicon power therefor
US7955735B2 (en) 2004-11-15 2011-06-07 Panasonic Corporation Non-aqueous electrolyte secondary battery
US7635540B2 (en) 2004-11-15 2009-12-22 Panasonic Corporation Negative electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery comprising the same
US7939218B2 (en) 2004-12-09 2011-05-10 Nanosys, Inc. Nanowire structures comprising carbon
CN101107737B (zh) 2004-12-09 2012-03-21 奈米系统股份有限公司 用于燃料电池的基于纳米线的膜电极组件
JP4824394B2 (ja) * 2004-12-16 2011-11-30 パナソニック株式会社 リチウムイオン二次電池用負極、その製造方法、およびそれを用いたリチウムイオン二次電池
KR100738054B1 (ko) * 2004-12-18 2007-07-12 삼성에스디아이 주식회사 음극 활물질, 그 제조 방법 및 이를 채용한 음극과 리튬전지
JP4229062B2 (ja) 2004-12-22 2009-02-25 ソニー株式会社 リチウムイオン二次電池
CN100511781C (zh) 2004-12-22 2009-07-08 松下电器产业株式会社 复合负极活性材料及其制备方法以及非水电解质二次电池
FR2880198B1 (fr) 2004-12-23 2007-07-06 Commissariat Energie Atomique Electrode nanostructuree pour microbatterie
JP4095621B2 (ja) 2005-03-28 2008-06-04 アドバンスド・マスク・インスペクション・テクノロジー株式会社 光学画像取得装置、光学画像取得方法、及びマスク検査装置
JP2006290938A (ja) 2005-04-06 2006-10-26 Nippon Brake Kogyo Kk 摩擦材
CA2506104A1 (en) 2005-05-06 2006-11-06 Michel Gauthier Surface modified redox compounds and composite electrode obtain from them
WO2007037787A1 (en) 2005-05-09 2007-04-05 Vesta Research, Ltd. Porous silicon particles
US7781100B2 (en) * 2005-05-10 2010-08-24 Advanced Lithium Electrochemistry Co., Ltd Cathode material for manufacturing rechargeable battery
US7887954B2 (en) * 2005-05-10 2011-02-15 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
US7700236B2 (en) * 2005-09-09 2010-04-20 Aquire Energy Co., Ltd. Cathode material for manufacturing a rechargeable battery
US20080138710A1 (en) * 2005-05-10 2008-06-12 Ben-Jie Liaw Electrochemical Composition and Associated Technology
TWI254031B (en) * 2005-05-10 2006-05-01 Aquire Energy Co Ltd Manufacturing method of LixMyPO4 compound with olivine structure
US7799457B2 (en) * 2005-05-10 2010-09-21 Advanced Lithium Electrochemistry Co., Ltd Ion storage compound of cathode material and method for preparing the same
FR2885734B1 (fr) 2005-05-13 2013-07-05 Accumulateurs Fixes Materiau nanocomposite pour anode d'accumulateur au lithium
JP2006351516A (ja) 2005-05-16 2006-12-28 Toshiba Corp 負極活物質及び非水電解質二次電池
FR2885913B1 (fr) 2005-05-18 2007-08-10 Centre Nat Rech Scient Element composite comprenant un substrat conducteur et un revetement metallique nanostructure.
JP4603422B2 (ja) 2005-06-01 2010-12-22 株式会社タカギセイコー 樹脂製タンクの表面処理方法
EP1833109A1 (en) * 2005-06-03 2007-09-12 Matsushita Electric Industrial Co., Ltd. Rechargeable battery with nonaqueous electrolyte and process for producing negative electrode
US7682741B2 (en) 2005-06-29 2010-03-23 Panasonic Corporation Composite particle for lithium rechargeable battery, manufacturing method of the same, and lithium rechargeable battery using the same
KR100684733B1 (ko) 2005-07-07 2007-02-20 삼성에스디아이 주식회사 리튬 이차 전지
US7851085B2 (en) 2005-07-25 2010-12-14 3M Innovative Properties Company Alloy compositions for lithium ion batteries
JP4876468B2 (ja) 2005-07-27 2012-02-15 パナソニック株式会社 非水電解質二次電池
US8080334B2 (en) * 2005-08-02 2011-12-20 Panasonic Corporation Lithium secondary battery
CN100438157C (zh) 2005-08-29 2008-11-26 松下电器产业株式会社 用于非水电解质二次电池的负极、其制造方法以及非水电解质二次电池
US7524529B2 (en) * 2005-09-09 2009-04-28 Aquire Energy Co., Ltd. Method for making a lithium mixed metal compound having an olivine structure
KR100738057B1 (ko) 2005-09-13 2007-07-10 삼성에스디아이 주식회사 음극 전극 및 이를 채용한 리튬 전지
CN100431204C (zh) 2005-09-22 2008-11-05 松下电器产业株式会社 负极和使用该负极制备的锂离子二次电池
JP2007123242A (ja) 2005-09-28 2007-05-17 Sanyo Electric Co Ltd 非水電解質二次電池
CN101288200B (zh) 2005-10-13 2012-04-18 3M创新有限公司 电化学电池的使用方法
KR100759556B1 (ko) * 2005-10-17 2007-09-18 삼성에스디아이 주식회사 음극 활물질, 그 제조 방법 및 이를 채용한 음극과 리튬전지
KR100749486B1 (ko) * 2005-10-31 2007-08-14 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질, 그의 제조 방법 및 그를포함하는 리튬 이차 전지
US20070099084A1 (en) * 2005-10-31 2007-05-03 T/J Technologies, Inc. High capacity electrode and methods for its fabrication and use
JP2007128766A (ja) * 2005-11-04 2007-05-24 Sony Corp 負極活物質および電池
JP5474352B2 (ja) * 2005-11-21 2014-04-16 ナノシス・インク． 炭素を含むナノワイヤ構造
US20070117018A1 (en) * 2005-11-22 2007-05-24 Huggins Robert A Silicon and/or boron-based positive electrode
KR100949330B1 (ko) * 2005-11-29 2010-03-26 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질 및 그를 포함하는 리튬 이차전지
JP2007165079A (ja) 2005-12-13 2007-06-28 Matsushita Electric Ind Co Ltd 非水電解質二次電池用負極とそれを用いた非水電解質二次電池
US7906238B2 (en) * 2005-12-23 2011-03-15 3M Innovative Properties Company Silicon-containing alloys useful as electrodes for lithium-ion batteries
KR100763892B1 (ko) * 2006-01-20 2007-10-05 삼성에스디아이 주식회사 음극 활물질, 그 제조 방법, 및 이를 채용한 음극과 리튬전지
GB0601318D0 (en) 2006-01-23 2006-03-01 Imp Innovations Ltd Method of etching a silicon-based material
GB0601319D0 (en) 2006-01-23 2006-03-01 Imp Innovations Ltd A method of fabricating pillars composed of silicon-based material
US7951242B2 (en) * 2006-03-08 2011-05-31 Nanoener Technologies, Inc. Apparatus for forming structured material for energy storage device and method
US7972731B2 (en) * 2006-03-08 2011-07-05 Enerl, Inc. Electrode for cell of energy storage device and method of forming the same
CN100467670C (zh) 2006-03-21 2009-03-11 无锡尚德太阳能电力有限公司 一种用于制备多晶硅绒面的酸腐蚀溶液及其使用方法
US7776473B2 (en) * 2006-03-27 2010-08-17 Shin-Etsu Chemical Co., Ltd. Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
KR100984684B1 (ko) 2006-03-30 2010-10-01 산요덴키가부시키가이샤 리튬 2차 전지 및 그 제조 방법
KR101328982B1 (ko) * 2006-04-17 2013-11-13 삼성에스디아이 주식회사 음극 활물질 및 그 제조 방법
CN100563047C (zh) 2006-04-25 2009-11-25 立凯电能科技股份有限公司 适用于制作二次电池的正极的复合材料及其所制得的电池
JP5003047B2 (ja) 2006-04-28 2012-08-15 東ソー株式会社 エッチング用組成物及びエッチング方法
KR101483123B1 (ko) * 2006-05-09 2015-01-16 삼성에스디아이 주식회사 금속 나노결정 복합체를 포함하는 음극 활물질, 그 제조방법 및 이를 채용한 음극과 리튬 전지
KR100863733B1 (ko) 2006-05-15 2008-10-16 주식회사 엘지화학 바인더로서 폴리우레탄을 물리적으로 혼합한폴리아크릴산이 포함되어 있는 전극 합제 및 이를 기반으로하는 리튬 이차전지
JP2007305546A (ja) * 2006-05-15 2007-11-22 Sony Corp リチウムイオン電池
US20070269718A1 (en) 2006-05-22 2007-11-22 3M Innovative Properties Company Electrode composition, method of making the same, and lithium ion battery including the same
KR100830612B1 (ko) 2006-05-23 2008-05-21 강원대학교산학협력단 리튬 이차 전지용 음극 활물질, 그의 제조 방법 및 그를포함하는 리튬 이차 전지
US8080335B2 (en) * 2006-06-09 2011-12-20 Canon Kabushiki Kaisha Powder material, electrode structure using the powder material, and energy storage device having the electrode structure
JP5200339B2 (ja) * 2006-06-16 2013-06-05 パナソニック株式会社 非水電解質二次電池
JP5398962B2 (ja) * 2006-06-30 2014-01-29 三洋電機株式会社 リチウム二次電池及びその製造方法
WO2008024573A1 (en) 2006-07-20 2008-02-28 Toppan Photomasks, Inc. System and method for performing high flow rate dispensation of a chemical onto a photolithographic component
US7964307B2 (en) * 2006-07-24 2011-06-21 Panasonic Corporation Negative electrode for lithium ion secondary battery, method for producing the same, and lithium ion secondary battery
JP2008034266A (ja) 2006-07-28 2008-02-14 Canon Inc リチウム二次電池用負極材料の製造方法
US7722991B2 (en) * 2006-08-09 2010-05-25 Toyota Motor Corporation High performance anode material for lithium-ion battery
EP2058882A4 (en) 2006-08-29 2013-03-06 Unitika Ltd BINDER FOR MANUFACTURING ELECTRODE, MELT FOR ELECTRODE MANUFACTURING USING THE BINDER, ELECTRODE USING THE SLUDGE, SECONDARY BATTERY USING THE ELECTRODE AND CAPACITOR USING THE ELECTRODE
JP5039956B2 (ja) 2006-09-07 2012-10-03 トヨタ自動車株式会社 負極活物質、負極およびリチウム二次電池
US8734997B2 (en) 2006-10-10 2014-05-27 Panasonic Corporation Negative electrode for nonaqueous electrolyte secondary battery
US8187754B2 (en) * 2006-10-11 2012-05-29 Panasonic Corporation Coin-type non-aqueous electrolyte battery
KR100778450B1 (ko) * 2006-11-22 2007-11-28 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지
KR100814816B1 (ko) * 2006-11-27 2008-03-20 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질 및 그를 포함하는 리튬 이차전지
JP4501081B2 (ja) * 2006-12-06 2010-07-14 ソニー株式会社 電極の形成方法および電池の製造方法
JP2008171802A (ja) 2006-12-13 2008-07-24 Matsushita Electric Ind Co Ltd 非水電解質二次電池用負極とその製造方法およびそれを用いた非水電解質二次電池
JP4321584B2 (ja) * 2006-12-18 2009-08-26 ソニー株式会社 二次電池用負極および二次電池
US7709139B2 (en) * 2007-01-22 2010-05-04 Physical Sciences, Inc. Three dimensional battery
JP5143437B2 (ja) 2007-01-30 2013-02-13 日本カーボン株式会社 リチウムイオン二次電池用負極活物質の製造方法、負極活物質及び負極
WO2008097723A1 (en) 2007-02-06 2008-08-14 3M Innovative Properties Company Electrodes including novel binders and methods of making and using the same
JP5277656B2 (ja) 2007-02-20 2013-08-28 日立化成株式会社 リチウムイオン二次電池用負極材、負極及びリチウムイオン二次電池
JP5165258B2 (ja) 2007-02-26 2013-03-21 日立マクセルエナジー株式会社 非水電解質二次電池
US20090053589A1 (en) 2007-08-22 2009-02-26 3M Innovative Properties Company Electrolytes, electrode compositions, and electrochemical cells made therefrom
US20080206641A1 (en) * 2007-02-27 2008-08-28 3M Innovative Properties Company Electrode compositions and electrodes made therefrom
US20080206631A1 (en) * 2007-02-27 2008-08-28 3M Innovative Properties Company Electrolytes, electrode compositions and electrochemical cells made therefrom
JP2008234988A (ja) 2007-03-20 2008-10-02 Sony Corp 負極およびその製造方法、ならびに電池およびその製造方法
KR100859687B1 (ko) * 2007-03-21 2008-09-23 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질 및 그를 포함하는 리튬 이차전지
KR100796664B1 (ko) * 2007-03-21 2008-01-22 삼성에스디아이 주식회사 리튬 이차 전지용 음극 활물질 및 이를 포함하는 리튬 이차전지
EP1978587B1 (en) 2007-03-27 2011-06-22 Hitachi Vehicle Energy, Ltd. Lithium secondary battery
JP4979432B2 (ja) 2007-03-28 2012-07-18 三洋電機株式会社 円筒型リチウム二次電池
US20080241703A1 (en) 2007-03-28 2008-10-02 Hidekazu Yamamoto Nonaqueous electrolyte secondary battery
JP2008243717A (ja) 2007-03-28 2008-10-09 Mitsui Mining & Smelting Co Ltd 非水電解液二次電池及びその製造方法
WO2008119080A1 (en) * 2007-03-28 2008-10-02 Life Bioscience Inc. Compositions and methods to fabricate a photoactive substrate suitable for shaped glass structures
JP5628469B2 (ja) 2007-04-26 2014-11-19 三菱化学株式会社 二次電池用非水系電解液及びそれを用いた非水系電解液二次電池
JP2008269827A (ja) * 2007-04-17 2008-11-06 Matsushita Electric Ind Co Ltd 電気化学素子の電極材料およびその製造方法並びにそれを用いた電極極板および電気化学素子
GB0709165D0 (en) 2007-05-11 2007-06-20 Nexeon Ltd A silicon anode for a rechargeable battery
JP5338041B2 (ja) 2007-06-05 2013-11-13 ソニー株式会社 二次電池用負極および二次電池
GB0713898D0 (en) 2007-07-17 2007-08-29 Nexeon Ltd A method of fabricating structured particles composed of silcon or a silicon-based material and their use in lithium rechargeable batteries
GB0713895D0 (en) 2007-07-17 2007-08-29 Nexeon Ltd Production
GB0713896D0 (en) 2007-07-17 2007-08-29 Nexeon Ltd Method
CN104392933B (zh) 2007-08-21 2017-11-07 加州大学评议会 具有高性能热电性质的纳米结构
EP2204867A4 (en) 2007-09-06 2012-06-06 Canon Kk METHOD FOR PRODUCING LITHIUM ION STORAGE / RELEASE MATERIAL, LITHIUM ION STORAGE / RELEASE MATERIAL, ELECTRODE STRUCTURE USING THE MATERIAL, AND ELECTRICITY STORAGE DEVICE THEREOF
US20090078982A1 (en) 2007-09-24 2009-03-26 Willy Rachmady Alpha hydroxy carboxylic acid etchants for silicon microstructures
US20090087731A1 (en) 2007-09-27 2009-04-02 Atsushi Fukui Lithium secondary battery
US8119288B2 (en) 2007-11-05 2012-02-21 Nanotek Instruments, Inc. Hybrid anode compositions for lithium ion batteries
CN101442124B (zh) 2007-11-19 2011-09-07 比亚迪股份有限公司 锂离子电池负极用复合材料的制备方法及负极和电池
JP2009176719A (ja) 2007-12-26 2009-08-06 Sony Corp 電解液、二次電池およびスルホン化合物
US20090186267A1 (en) 2008-01-23 2009-07-23 Tiegs Terry N Porous silicon particulates for lithium batteries
WO2009105546A2 (en) 2008-02-19 2009-08-27 Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno Target and process for fabricating same
US8105718B2 (en) 2008-03-17 2012-01-31 Shin-Etsu Chemical Co., Ltd. Non-aqueous electrolyte secondary battery, negative electrode material, and making method
US8273591B2 (en) 2008-03-25 2012-09-25 International Business Machines Corporation Super lattice/quantum well nanowires
JP2009252348A (ja) 2008-04-01 2009-10-29 Panasonic Corp 非水電解質電池
JP4998358B2 (ja) 2008-04-08 2012-08-15 ソニー株式会社 リチウムイオン二次電池用負極およびリチウムイオン二次電池
WO2009128800A1 (en) 2008-04-17 2009-10-22 The Board Of Trustees Of The University Of Illinois Silicon nanowire and composite formation and highly pure and uniform length silicon nanowires
JP4844849B2 (ja) 2008-04-23 2011-12-28 ソニー株式会社 リチウムイオン二次電池用負極およびリチウムイオン二次電池
CN100580876C (zh) 2008-04-25 2010-01-13 华东师范大学 一种选择性刻蚀硅纳米线的方法
US8034485B2 (en) 2008-05-29 2011-10-11 3M Innovative Properties Company Metal oxide negative electrodes for lithium-ion electrochemical cells and batteries
US20100085685A1 (en) 2008-10-06 2010-04-08 Avx Corporation Capacitor Anode Formed From a Powder Containing Coarse Agglomerates and Fine Agglomerates
GB2464158B (en) 2008-10-10 2011-04-20 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries
GB2464157B (en) 2008-10-10 2010-09-01 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material
KR101065778B1 (ko) 2008-10-14 2011-09-20 한국과학기술연구원 탄소나노튜브 피복 실리콘-구리 복합 입자 및 그 제조 방법과, 이를 이용한 이차전지용 음극 및 이차전지
JP4952746B2 (ja) 2008-11-14 2012-06-13 ソニー株式会社 リチウムイオン二次電池およびリチウムイオン二次電池用負極
CN101740747B (zh) 2008-11-27 2012-09-05 比亚迪股份有限公司 一种硅负极和含有该硅负极的锂离子电池
KR101819035B1 (ko) 2009-02-16 2018-01-18 삼성전자주식회사 14족 금속나노튜브를 포함하는 음극, 이를 채용한 리튬전지 및 이의 제조 방법
US20100285358A1 (en) 2009-05-07 2010-11-11 Amprius, Inc. Electrode Including Nanostructures for Rechargeable Cells
GB2470056B (en) 2009-05-07 2013-09-11 Nexeon Ltd A method of making silicon anode material for rechargeable cells
GB2470190B (en) 2009-05-11 2011-07-13 Nexeon Ltd A binder for lithium ion rechargeable battery cells
GB0908089D0 (en) 2009-05-11 2009-06-24 Nexeon Ltd A binder for lithium ion rechargaable battery cells
ES2867474T3 (es) 2009-05-19 2021-10-20 Oned Mat Inc Materiales nanoestructurados para aplicaciones de batería
US20100330419A1 (en) 2009-06-02 2010-12-30 Yi Cui Electrospinning to fabricate battery electrodes
JP5220698B2 (ja) 2009-07-06 2013-06-26 富士フイルム株式会社 結晶性ポリマー微孔性膜及びその製造方法、並びに濾過用フィルタ
KR20120128125A (ko) 2009-11-03 2012-11-26 엔비아 시스템즈 인코포레이티드 리튬 이온 전지용 고용량 아노드 물질
GB201005979D0 (en) 2010-04-09 2010-05-26 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1111074A (zh) * 1993-06-23 1995-11-01 东丽株式会社 电池用电极、使用该电极的二次电池以及该电极的制备方法
CN1447916A (zh) * 2000-06-15 2003-10-08 北卡罗来纳-查佩尔山大学 纳米结构基高能量物质

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Uniform, Axial-Orientation Alignment of One-Dimensional Single-Crystal Silicon Nanostructure Arrays;Kuiqing Peng, et al;《Angew.Chem.Int.Ed.》;20051231;第44卷;第2737-2742页 *

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