WO2007069606A1 - チップ内蔵基板およびチップ内蔵基板の製造方法 - Google Patents
チップ内蔵基板およびチップ内蔵基板の製造方法 Download PDFInfo
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- WO2007069606A1 WO2007069606A1 PCT/JP2006/324764 JP2006324764W WO2007069606A1 WO 2007069606 A1 WO2007069606 A1 WO 2007069606A1 JP 2006324764 W JP2006324764 W JP 2006324764W WO 2007069606 A1 WO2007069606 A1 WO 2007069606A1
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.
- Y10T29/4913—Assembling to base an electrical component, e.g., capacitor, etc.
- Y10T29/49146—Assembling to base an electrical component, e.g., capacitor, etc. with encapsulating, e.g., potting, etc.
Definitions
- Chip embedded substrate and manufacturing method of chip embedded substrate are Chip embedded substrate and manufacturing method of chip embedded substrate
- the present invention relates to a chip built-in substrate that incorporates a semiconductor chip.
- a substrate in which a semiconductor chip is embedded a so-called chip-embedded wiring substrate
- various structures for incorporating the semiconductor chip in the substrate have been proposed.
- the semiconductor chip wiring has been miniaturized, and accordingly, the wiring structure of the chip-embedded substrate has been miniaturized, and the wiring structure of the chip-embedded substrate has been required to be multilayered.
- Patent Document 1 Japanese Patent Laid-Open No. 2003-347722 discloses a method of stacking substrates on which semiconductor chips are mounted.
- the invention disclosed in Patent Document 1 is a method of simply laminating substrates, and a solution to a decrease in production yield when the wiring of a substrate incorporating a semiconductor chip is miniaturized and multilayered. No means are disclosed or suggested.
- Patent Document 1 Japanese Patent Laid-Open No. 2003-347722
- an object of the present invention is to provide a new and useful chip-embedded substrate and a method for manufacturing the chip-embedded substrate that solve the above-described problems.
- a specific problem of the present invention is that the production yield is good and the multilayer wiring connected to the built-in semiconductor chip has high reliability, and the chip built-in substrate is manufactured. It is to provide a manufacturing method.
- the above-described problem is solved by the first step of mounting the semiconductor chip on the first substrate on which the first wiring is formed, and the second wiring is formed.
- the first wiring and the second wiring are electrically connected to form a multilayer wiring connected to the semiconductor chip.
- the above-described problem is solved by a first substrate in which a first wiring is formed and a semiconductor chip is mounted on the first wiring, and a second wiring.
- a chip-embedded substrate having a second substrate bonded to the first substrate, wherein the semiconductor chip is interposed between the first substrate and the second substrate.
- a chip-embedded substrate having a good production yield and high reliability of multilayer wiring connected to a built-in semiconductor chip, and a manufacturing method for manufacturing the chip-embedded substrate. It becomes possible to provide.
- FIG. 1A is a view (No. 1) showing a method for manufacturing a chip-embedded substrate according to Embodiment 1.
- FIG. 1B is a diagram (part 2) illustrating the method for manufacturing the chip-embedded substrate according to the first embodiment.
- FIG. 1C is a diagram (part 3) illustrating the method for manufacturing the chip-embedded substrate according to the first embodiment.
- FIG. 1D is a view (No. 4) illustrating the method for manufacturing the chip-embedded substrate according to the first embodiment.
- ⁇ IE] No. 5 showing the method for manufacturing the chip-embedded substrate according to Example 1.
- ⁇ 1F No. 6 showing the method for manufacturing the chip-embedded substrate according to the first embodiment.
- FIG. 2A is a view (No. 1) showing the method for manufacturing the chip-embedded substrate according to the second embodiment.
- FIG. 2B is a diagram (part 2) illustrating the method for manufacturing the chip-embedded substrate according to the second embodiment.
- FIG. 3 is a view showing a chip built-in substrate according to Example 3.
- FIG. 4A is a diagram (part 1) illustrating the method for manufacturing the chip-embedded substrate according to the fourth embodiment.
- FIG. 4B is a diagram (part 2) illustrating the method for manufacturing the chip-embedded substrate according to the fourth embodiment.
- FIG. 4C is a diagram (part 3) illustrating the method for manufacturing the chip-embedded substrate according to the fourth embodiment.
- FIG. 5A is a diagram (part 1) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5B is a diagram (part 2) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5C is a diagram (part 3) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5A is a diagram (part 1) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5B is a diagram (part 2) illustrating the method for manufacturing the chip-e
- FIG. 5D is a diagram (part 4) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5E is a diagram (No. 5) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5F is a view (No. 6) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5G is a view (No. 7) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5H is a view (No. 8) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 51 is a view (No.
- FIG. 11 is a view (No. 11) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment. ⁇ 5L] (No. 12) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5M is a view (No. 13) illustrating the method for manufacturing the chip-embedded substrate according to the fifth embodiment. ⁇ 5N] (No. 14) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 50 is a view (No.
- FIG. 15 is a view (No. 16) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- FIG. 5P is a view (No. 16) showing the method for manufacturing the chip-embedded substrate according to the fifth embodiment.
- ⁇ 6A] (No. 1) showing the method for manufacturing the chip-embedded substrate according to the sixth embodiment.
- FIG. 6B is a diagram (part 2) illustrating the method for manufacturing the chip-embedded substrate according to the sixth embodiment.
- FIG. 6C is a diagram (part 3) illustrating the method for manufacturing the chip-embedded substrate according to the sixth embodiment.
- FIG. 6D is a diagram (part 4) illustrating the method for manufacturing the chip-embedded substrate according to the sixth embodiment.
- ⁇ 6E] (No. 5) showing the method for manufacturing the chip-embedded substrate according to the sixth embodiment.
- FIG. 7 shows a chip built-in substrate according to Example 7.
- FIG. 8 is a view showing a chip built-in substrate according to Example 8.
- FIG. 9 is a view showing a chip built-in substrate according to Example 9.
- FIG. 10 is a view showing a chip built-in substrate according to Example 10.
- FIG. 11 shows a chip built-in substrate according to Example 11.
- FIG. 12 is a view showing a chip built-in substrate according to Example 12.
- FIG. 13 shows a chip built-in substrate according to Example 13.
- FIG. 14 is a view showing a chip built-in substrate according to Example 14.
- FIG. 15 is a view showing a chip built-in substrate according to Example 15.
- FIG. 16 is a view showing a chip built-in substrate according to Example 16.
- FIG. 17 is a view showing a chip built-in substrate according to Example 17;
- FIG. 18 is a view showing a connecting portion of a chip built-in substrate according to Example 17.
- FIG. 19 is a diagram (No. 1) showing a method for manufacturing the chip-embedded substrate shown in FIG. [19B]
- FIG. 19B is a view (No. 2) showing a method for manufacturing the chip-embedded substrate shown in FIG. [19C]
- FIG. 19C is a diagram (No. 3) showing a method for manufacturing the chip-embedded substrate shown in FIG. [19D]
- FIG. 19D is a diagram (part 4) illustrating the manufacturing method of the chip-embedded substrate shown in FIG. ⁇ 19E] (No. 5) showing a method for manufacturing the chip-embedded substrate shown in FIG.
- FIG. 20 is a view (No.).
- FIG. 21A is a view (No. 2) showing the method for manufacturing the chip-embedded substrate according to Example 18.
- FIG. 21B is a diagram (No. 3) showing the method for manufacturing the chip-embedded substrate according to Example 18;
- Fig. 22 is a diagram (No. 1) showing a method of bonding wiring substrates.
- Fig. 23 is a diagram (No. 2) showing a method of bonding wiring substrates.
- Fig. 24 is a diagram (No. 3) showing a method of bonding wiring substrates.
- Fig. 25 is a diagram (No. 4) showing a method of bonding wiring boards.
- FIG. 26 is a diagram (No. 1) showing a method for manufacturing a chip-embedded substrate according to Example 20.
- FIG. 27 is a view (No. 2) showing the method for manufacturing the chip-embedded substrate according to the embodiment 20.
- FIG. 28] shows a method for manufacturing a chip-embedded substrate according to Example 21 (No. 1).
- FIG. 29 is a diagram (part 2) showing a manufacturing method of an embodiment 21 (; such a chip-embedded substrate;
- FIG. 30 is a diagram (part 1) showing an embodiment 22 (;) showing such a chip-embedded substrate.
- FIG. 31 is a diagram (part 2) showing an example 22 (; showing such a chip-embedded substrate.
- FIG. 32 Example 22 (3) showing such a chip-embedded substrate (No. 3).
- Example 23 (;) is a diagram (part 1) showing such a chip-embedded substrate.
- FIG. 34 is a diagram (part 2) showing an example 23 (;) showing such a chip-embedded substrate.
- FIG. 35 is a diagram (part 1) showing an embodiment 24 (;; showing such a chip-embedded substrate.
- FIG. 36 Example 24 (2) showing such a chip-embedded substrate (part 2).
- FIG. 37 is a diagram (part 1) showing an embodiment 25 (; showing such a chip-embedded substrate.
- FIG. 38 is a diagram (part 2) showing an embodiment 25 (; showing such a chip-embedded substrate.
- FIG. 39 Example 25 (3) showing such a chip-embedded substrate (No. 3).
- FIG. 40 is a diagram (part 4) showing Example 25 (;; showing such a chip-embedded substrate.
- FIG. 41 Example 25 (5) showing such a chip-embedded substrate (part 5).
- FIG. 42 Example 25 (6) showing such a chip-embedded substrate (part 6).
- FIG. 43A is a diagram (part 1) illustrating a method for forming an insulating layer.
- FIG. 43B is a diagram (part 2) illustrating the method for forming the insulating layer.
- FIG. 44A is a diagram (No. 1) showing another method of forming the insulating layer.
- FIG. 44B is a diagram (No. 2) showing another method of forming the insulating layer.
- FIG. 44C is a diagram (No. 3) showing another method of forming the insulating layer.
- FIG. 44D is a diagram (No. 4) showing another method of forming the insulating layer.
- FIG. 44E is a diagram (No. 5) showing another method of forming the insulating layer.
- FIG. 44F is a view (No. 6) showing another method of forming the insulating layer.
- FIG. 44G is a diagram (No. 7) showing another method of forming the insulating layer.
- FIG. 45 is a view (No. 1) showing a method for manufacturing a chip-embedded substrate according to Example 27;
- FIG. 46 is a (second) diagram illustrating the method of manufacturing the chip-embedded substrate according to Example 27.
- the first step of mounting the semiconductor chip on the first substrate on which the first wiring is formed, the second substrate on which the second wiring is formed, and the front substrate A second step of bonding the first substrate together, and in the second step, the semiconductor chip is sealed between the first substrate and the second substrate. Together with the first A wiring and the second wiring are electrically connected to form a multilayer wiring connected to the semiconductor chip.
- a conventional chip-embedded substrate for example, a multilayer wiring structure that is connected to a semiconductor chip by a build-up method and incorporates a semiconductor chip is formed. Therefore, when the wiring is miniaturized or the number of wiring layers increases, There has been a problem that the reliability of the wiring is lowered and the production yield is lowered. For this reason, there has been a problem that a substrate in which an expensive semiconductor chip is embedded must be discarded.
- the multilayer wiring structure connected to the semiconductor chip is formed by bonding (stacking) a plurality of substrates on which wiring is formed.
- the first wiring and the second wiring constitute a multilayer wiring structure connected to the semiconductor chip. Therefore, the reliability of the miniaturized multilayer wiring structure is improved and the manufacturing yield is improved.
- FIG. 1A to FIG. 1F are diagrams for explaining the procedure of the method for manufacturing a chip-embedded substrate according to the first embodiment of the present invention.
- the parts described above are denoted by the same reference numerals and the description thereof may be omitted (the same applies to the following examples).
- a via plug that penetrates the core substrate 101 made of Cu for example, with respect to the core substrate 101 made of a pre-predder material (a material in which glass fiber is impregnated with epoxy resin or the like).
- a pre-predder material a material in which glass fiber is impregnated with epoxy resin or the like.
- 102 is formed.
- a non-turn wiring 103A is formed on the first side of the core substrate 101 (side on which a semiconductor chip is mounted in a later step)
- a pattern wiring 103B is formed on the second side of the core substrate 101, and Cu is used, for example Form.
- a part of the pattern wirings 103 A and 103 B is formed to be connected by the via plug 102.
- a solder resist layer 104A is formed on the first side of the core substrate 101, and a part of the pattern wiring 103A exposed from the solder resist layer cover includes, for example, NiZAu (pattern wiring 103A Connection layer consisting of Ni layer, Au layer, etc.) 5A is formed. Further, the connection layer 105A is not formed in the pattern wiring 103A formed in the opening 106 for mounting the semiconductor chip in a later process. Similarly, a solder resist layer 104B is formed on the second side of the core substrate 101, and the pattern wiring 103B in which the force of the solder resist layer 104B is also exposed is, for example, NiZAu (Ni on the pattern wiring 103B). The connection layer 105B is formed of a layer, a layer laminated in the order of the Au layer, and the like. Here, a wiring substrate 100 for mounting a semiconductor chip is formed.
- connection layer 107 made of, for example, solder is formed on the pattern wiring 103A exposed from the opening 106 by electrolytic plating or the like.
- the semiconductor chip 110 on which the bumps 108 (for example, bumps formed by using a bonding wire such as Au by wire bonding) 108 are formed is bonded to the connection layer 107. Then, flip-chip mounting is performed on the pattern wiring 103A. Next, an underfill (underfill resin) 109 is infiltrated between the semiconductor chip and the wiring substrate 100.
- the bumps 108 for example, bumps formed by using a bonding wire such as Au by wire bonding
- a wiring board 100A is formed, on which the semiconductor chip 110 is flip-chip mounted on the wiring board 100.
- the pattern wiring 103A is not limited to a semiconductor chip, but may be other electronic components (for example, a capacitor, a resistor, an inductor, etc.). You can also use CSP (chip size package), which has rewiring formed on the semiconductor chip.
- a wiring board 200 that is bonded (laminated) to the wiring board 100A is formed in the same manner as when the wiring board 100 is formed.
- via plugs 202 penetrating the core substrate 201 made of Cu, for example, are formed on the core substrate 201.
- pattern wiring 203A is formed on the first side of the core substrate 101 (opposite side facing the semiconductor chip), and pattern wiring 203B is formed on the second side of the core substrate 201, for example, by Cu. .
- a part of the pattern wirings 203A and 203B is formed to be connected by the via plug 202.
- a solder resist layer 204A is formed on the first side of the core substrate 201, and the pattern wiring 203A exposed from the solder resist layer cover is, for example, NiZAu (on the pattern wiring 203A).
- a connection layer 205A is formed, which is made up of a Ni layer, an Au layer, and the like.
- a solder resist layer 204B is formed on the second side of the core substrate 201, and the pattern wiring 203B from which the solder resist layer is exposed is, for example, NiZAu (Ni layer on the pattern wiring 203B).
- a connection layer 205B made of, for example, Au layers stacked in this order is formed, and solder balls 206 are formed on the connection layer 205B.
- a wiring board 200 to be bonded to the wiring board 100A is formed.
- the wiring board 100A and the wiring board 200 are bonded (laminated).
- the semiconductor chip 110 is sealed between the wiring board 200 and the wiring board 100A, and the wiring of the wiring board 200 and the wiring of the wiring board 100 are connected. Then, the sealing connection layer L1 is formed.
- the sealing connection layer L1 is formed of an insulating layer D1 made of, for example, a build-up resin formed by laminating, and an electric connection member (for example, a solder ball 206) formed in the insulating layer D1.
- the solder ball 206 connected to the pattern wiring 203B via the connection layer 205B is electrically connected to the pattern wiring 103A via the connection layer 105A.
- the wiring board 200 and the wiring board 100A are bonded together, they can be bonded together by the following first method or second method.
- the first method can be performed as follows. First, the wiring board 200 is laminated and pressed onto the wiring board 100A via a thermosetting film-like build-up resin (uncured at this stage), and the solder balls (electrical connection) of the wiring board 200 are pressed. Member) 206 is pushed into the film-shaped build-up resin and pressed against the connection layer 105A of the wiring board 100A. By heating in this state, the solder ball 206 is melted, and the solder ball 206 is electrically connected to the connection layer 105A. Further, the build-up resin is cured by heat and becomes the insulating layer D1.
- the second method can be performed as follows. First, the wiring board 200 is connected to the wiring board. Laminate on the plate 100A and heat to melt the solder balls (electrical connection members) 206 and connect them to the connection layer 105A. Next, a liquid resin is filled and hardened between the wiring board 200 and the wiring board 100A to form an insulating layer D1.
- solder balls (external connection terminals) 111 and 207 are formed on the connection layers 105B and 205A, respectively, and the chip-embedded substrate 300 is formed.
- the multilayer wiring structure connected to the semiconductor chip 110 has a plurality of wirings (pattern wirings 103A, 103B, 203A, 203B, etc.) formed thereon.
- the two substrates (wiring substrates 100A, 200) are pasted together (stacked). For this reason, for example, as compared with the case where all multilayer wiring structures are formed by the build-up method, there are features that the wiring reliability is high and the manufacturing yield is good.
- the semiconductor chip mounting side and the upper layer side (upper wiring side) can be manufactured separately, individual inspections and the like are also possible. This has the effect of reducing the rate at which expensive semiconductor chips are discarded because defects are found after the chips are built into the substrate.
- manufacturing a chip-embedded substrate having a multilayer wiring structure by combining the substrates as described above has an advantage that a plurality of substrates can be stocked individually.
- the sealing connection layer L1 is formed by a combination of an insulating layer D1 made of, for example, a build-up resin and an electric connection member (conductive material) such as a solder ball 206, and the sealing connection layer L1
- an insulating layer D1 made of, for example, a build-up resin and an electric connection member (conductive material) such as a solder ball 206
- the sealing connection layer L1 the sealing connection layer L1
- sealing connection layer L1 is not limited to the combination of the build-up resin and the solder ball, and can have various structures as described below.
- Example 2
- FIGS. 2A to 2B are diagrams showing a method for manufacturing a chip-embedded substrate according to Embodiment 2 of the present invention.
- the steps up to the step shown in FIG. 2A are performed in the same manner as the steps shown in FIGS.
- the solder ball 206 is not formed in the process corresponding to FIG. 1D.
- a sealing connection layer L2 corresponding to the sealing connection layer L1 is formed between the wiring board 200 and the wiring board 100A.
- the sealing connection layer L2 is constituted by, for example, a connection layer D2 made of an anisotropic conductive material.
- the anisotropic conductive material include an anisotropic conductive film (ACF) and an anisotropic conductive paste ( AC P). That is, the anisotropic conductive material has a function as a sealing material for sealing the semiconductor chip and a function of an electrical connection member for connecting each wiring pattern of two wiring substrates to be bonded.
- the third method can be performed as follows. First, the wiring board 200 is laminated and pressed onto the wiring board 100A via a thermosetting anisotropic conductive film (uncured at this stage) and heated in this state. By this heating, the anisotropic conductive film is cured by heat, and the connection layer D2 is formed.
- the fourth method can be performed as follows. First, the wiring board 200 and the wiring board 100A are stacked and pressed in a state where the anisotropic conductive paste is applied to the wiring board 200 or the wiring board 100A, and heated in this state. By this heating, the anisotropic conductive paste is cured by heat, and the connection layer D2 is formed.
- solder balls 111 and 207 are formed on the connection layers 105B and 205A, respectively, to form a chip built-in substrate 300A.
- the semiconductor chip 110 is sealed and protected and insulated by the sealing connection layer L2, and the laminated substrates 100A and 200 are bonded to ensure mechanical strength. Further, the pattern wiring 203B of the wiring board 200 and the pattern wiring 103A of the wiring board 100 are electrically connected (the connection layer 205B and the connection layer 105A).
- the chip-embedded substrate 300A according to the present embodiment can be configured with a structure in which the solder ball of the sealing connection layer is omitted, is easy to manufacture, and has a simple structure and reliable connection. It has high characteristics.
- the method for forming the sealing connection layer L2 is not limited to the formation by sticking an anisotropic conductive film, and for example, anisotropic methods such as anisotropic conductive paste and anisotropic conductive ink are used. It may be formed using a conductive conductive adhesive.
- a conductive structure such as a via plug corresponding to the solder ball is formed in the insulating layer D1 in advance. It may be. In this case, the reliability of the electrical connection between the two wiring boards is improved, and the chip built-in board can be easily manufactured.
- FIG. 3 shows another modification of the chip-embedded substrate 300 described in the first embodiment.
- a wiring substrate 200A is further laminated on the chip-embedded substrate 300 (stretching). Are combined).
- the wiring board 200A is formed in the same manner as the wiring board 200.
- the core substrate 301, the via plug 302, the non-turn wiring 303A, 303B, the solder resist layers 304A, 304B, and the connection layers 305A, 305B of the wiring substrate 200A are respectively the core substrates of the wiring substrate 200.
- 201, Via plug 202, Node ⁇ Turn wiring 203A, 203B, Soldering resist layer 204A, 204B, Connection layer 205A, 205B Can be made.
- a semiconductor chip 307 and a semiconductor chip 309 are stacked and mounted on the solder resist layer 304A of the wiring board 200A.
- the semiconductor chip 307 is installed on the solder resist layer 304A through an installation film 306, and the semiconductor chip 309 is installed on the semiconductor chip 307 through an installation film 308.
- the semiconductor chips 307 and 309 are electrically connected to the pattern wiring 303A (the connection layer 305A) through wires 310 and 311, respectively.
- an insulating layer 312 made of a mold resin for sealing the semiconductor chips 307 and 309 and the wire wirings 310 and 311 is formed.
- the configuration of the chip-embedded substrate according to the present invention is not limited to the case where two substrates are used, and may be configured using three or more substrates.
- FIGS. 4A to 4C are diagrams showing a method for manufacturing a chip-embedded substrate according to Embodiment 4 of the present invention.
- the steps up to the step shown in FIG. 4A are the same as the steps shown in FIGS. 1A to C of Example 1.
- the steps in FIG. 4A and subsequent steps corresponding to the subsequent steps shown in FIG. are the same as the steps shown in FIGS. 1A to C of Example 1.
- a wiring board 200B corresponding to the wiring board 200 of Example 1 is formed.
- the wiring board 200B is formed by sealing the semiconductor chips 307 and 309 on the solder resist layer 304A with an insulating layer 312 made of a mold resin in the wiring board 200A shown in the third embodiment. To do. Also, solder balls 313 are formed on the connection layer 305B.
- the wiring board 100A and the wiring board 200B are bonded (laminated) in the same manner as in the step of FIG. 1E shown in the first embodiment.
- the above-described sealing connection layer L1 is formed between the wiring board 200B and the wiring board 100A, and the semiconductor chip is protected by the sealing connection layer L1. Insulated and laminated wiring boards 100A and 200B are bonded together and arranged. Electrical connection between the pattern wirings of the wiring boards 100A and 200B is performed.
- solder balls 111 are formed on the connection layer 105B to form a chip built-in substrate 300C.
- the configuration and order of the wiring boards stacked in the present invention can be variously changed.
- the present invention is not limited to the case where the so-called printed wiring boards (wiring boards 100, 100A, 200, 200A, 200B, etc.) shown above are bonded together, and are formed by a so-called build-up method. It can be applied to the case where the board (the build-up board in the text below) and the printed wiring board are pasted together, or the case where the build-up boards are pasted together.
- the multilayer wiring connected to the semiconductor chip can be easily miniaturized and multilayered. Further, in this way, even when the substrate to be stacked includes a build-up substrate or when the build-up substrates are stacked to form a chip-embedded substrate, the semiconductor chip connected to the semiconductor chip Compared with the case where all the multilayer wirings containing semiconductor chips are formed by the build-up method, the yield is good and the number of discarded semiconductor chips is reduced.
- FIG. 5A to FIG. 5P are diagrams showing a method for manufacturing a chip-embedded substrate according to Embodiment 5 of the present invention.
- a support substrate 401 made of a conductive material, for example, Cu and having a thickness of 00 m is prepared.
- a resist pattern (not shown) is formed on the support substrate 401 by a photolithography method, and the resist pattern is used as a mask to form, for example, an Au layer.
- a connection layer 402 having a structure in which 402a, Ni layer 402b, and Cu layer 402c are laminated is formed.
- the support substrate 401 since the support substrate 401 serves as an energization path, the support substrate 401 is preferably a conductive material, and more preferably a low-resistance material such as Cu.
- an insulating layer 403 is formed on the support substrate 401 so as to cover the connection layer 402.
- the insulating layer 403 is formed of, for example, build-up resin (epoxy resin, polyimide resin, etc.) or solder resist (acrylic resin, epoxy acrylic resin, etc.).
- the insulating layer 403 when the insulating layer 403 is formed of a material having high mechanical strength such as a pre-predder material such as a glass cloth epoxy pre-predder in which a glass fiber is impregnated with a resin, the insulating layer 403 Functions as a reinforcing layer (stiffener) of the wiring board, which is preferable.
- a pre-predder material such as a glass cloth epoxy pre-predder in which a glass fiber is impregnated with a resin
- the insulating layer 403 Functions as a reinforcing layer (stiffener) of the wiring board, which is preferable.
- via holes 403A are formed in the insulating layer 403 by, for example, a laser so that the connection layer 402 is exposed.
- a desmear process is performed as necessary to remove residues of via holes and surface treatment (roughness treatment) of the insulating layer 403, and then the insulating layer
- a Cu seed layer 404 is formed on the surface of 403 and the surface of the connection layer 402 by electroless plating.
- a resist pattern (not shown) is formed by photolithography.
- via plugs 405a are formed in the via holes 403A and pattern wirings 405b connected to the via plugs 405a are formed on the insulating layer 403 by electrolytic plating of Cu, and wiring portions 405 are formed.
- the resist pattern is peeled off, and the exposed excess seed layer is removed by etching.
- an insulating layer (build-up layer) 406 made of, for example, thermosetting epoxy resin is formed on the insulating layer 403 so as to cover the wiring portion 405. Further, the array layer 406 is exposed so that a part of the pattern wiring 405b is exposed. Via hole 406 A is formed by the.
- a desmear process is performed as necessary to remove via-hole residues and surface treatment of the insulating layer 406. Thereafter, a Cu seed layer 407 is formed on the surface of the insulating layer 406 and the exposed surface of the patterned wiring 405b by electroless plating.
- a resist pattern (not shown) is formed by the photolithography method in the same manner as the step shown in FIG. 5E.
- via plugs 408a are formed in the via holes 406A and pattern wirings 408b connected to the via plugs 408a are formed on the insulating layer 406 by Cu electrolytic plating. Form.
- the resist pattern is peeled off, and the exposed excess seed layer is removed by etching.
- an insulating layer (build-up layer) 406a made of, for example, a thermosetting epoxy resin is formed on the insulating layer 406 so as to cover the wiring portion 408.
- an opening 406B is formed in the insulating layer 406a so that a part of the pattern wiring 408b is exposed by, for example, a laser.
- a desmear process is performed as necessary to remove the residue in the opening and the surface treatment of the insulating layer 406, and then, for example, by electrolytic plating.
- a solder connection portion 409 is formed in the opening 406B.
- an opening is formed in the insulating layer 406a so that another part of the pattern wiring 408b is exposed by, for example, a laser, and a mesh is formed in the opening.
- a connection layer 407 made of AuZNi (a layer in which a Ni layer and an Au layer are stacked in this order on the pattern wiring 408b) is formed.
- the semiconductor chip 410 on which the bump 411 formed by, for example, a bonding wire such as Au is formed is placed on the wiring portion 408 so that the bump 411 and the solder connection portion 409 correspond to each other.
- the solder connection part 409 is reflowed as necessary to improve the electrical connection between the solder connection part 409 and the bump 411. And are preferred. Further, it is preferable to fill the gap between the semiconductor chip 410 and the insulating layer 406a as necessary to form an underfill 410A.
- the wiring board 400 is formed by mounting the semiconductor chip on the build-up board.
- the wiring board 400 and the wiring board 200 are bonded (laminated) in the same manner as in the process shown in FIG. 1E of Example 1.
- the semiconductor chip 410 is sealed between the wiring board 400 and the wiring board 200, and the wiring of the wiring board 400 and the wiring of the wiring board 200 are connected. Then, the sealing connection layer L1 is formed.
- the sealing connection layer L1 is formed of, for example, an insulating layer D1 made of a build-up resin formed by laminating, and solder balls 206 in the insulating layer D1.
- the solder ball 206 connected to the pattern wiring 203B via the connection layer 205B is electrically connected to the pattern wiring 408b via the connection layer 407.
- the sealing connection layer L2 including the connection layer D2 made of an anisotropic conductive material may be used instead of the sealing connection layer L1. .
- the support substrate 401 is removed, for example, by wet etching.
- the flatness of the wiring substrate 400 which is a build-up substrate, is improved, and by further removing the support substrate 401, the wiring substrate 400 can be thinned.
- the support substrate 401 is preferably removed after the wiring substrate 400 and the wiring substrate 200 are bonded together. In this case, the flatness of the entire chip-embedded substrate is maintained by the core substrate 201 of the wiring substrate 200.
- a solder resist layer 412 is formed so as to cover the insulating layer 403 and to expose the connection layer 402. Note that this step can be omitted when the insulating layer 403 is formed of a solder resist.
- solder balls 413 are formed on the connection layer 402 as necessary. In this way, the chip built-in substrate 300D can be formed.
- the chip-embedded substrate according to the present invention is a wiring substrate 400 that is a build-up substrate.
- the printed circuit board 200 which is a printed circuit board
- a multilayer wiring connected to the semiconductor chip is formed. For this reason, compared with the case where all the multilayer wirings connected to the semiconductor chip are formed by the build-up method, the yield is good and the number of discarded semiconductor chips is reduced. Further, as compared with the case where all the multilayer wirings connected to the semiconductor chip are formed by the printed wiring board, the multilayer wirings have a feature that it is easy to make the multilayer wirings finer.
- 6A to 6E are diagrams showing a method for manufacturing a chip-embedded substrate according to Embodiment 6 of the present invention.
- the wiring substrate 400 is formed by performing the steps of FIGS. 5A to 5L of the fifth embodiment, and the wiring substrate 500 is formed in the same manner.
- the connection layer 507 includes the support substrate 401, the connection layer 402, the insulating layers 403, ⁇ , and 406a, the wiring portion 405 (via plug 405a and the non-turn wiring 405b), and the wiring portion 408 (via plug 408a, It corresponds to the pattern wiring 408b) and the connection layer 407, and is formed in the same manner as the wiring board 400.
- no semiconductor chip is mounted on the wiring substrate 500, and solder balls 510 are formed on the connection layer 507.
- the wiring board 400 and the wiring board 500 are bonded (laminated) in the same manner as in the step shown in FIG. 1E of Example 1.
- the semiconductor chip 410 is sealed between the wiring board 400 and the wiring board 500, and the wiring of the wiring board 400 and the wiring of the wiring board 500 are A sealing connection layer L1 is formed to connect the two.
- the sealing connection layer L1 is formed of, for example, an insulating layer D1 made of a buildup resin formed by laminating, and a solder ball 510 in the insulating layer D1.
- the solder ball 510 connected to the pattern wiring 508b via the connection layer 507 is electrically connected to the pattern wiring 408b via the connection layer 407.
- a sealing connection layer L2 including a connection layer D2 made of an anisotropic conductive material is used. May be used.
- the support substrates 401 and 501 are removed by, for example, wet etching in the same manner as in the step shown in FIG. 5N.
- the flatness of the wiring substrates 400 and 500, which are build-up substrates is improved, and by further removing the support substrates 401 and 501, the wiring substrates 400, 500 can be made thinner.
- the support substrates 401 and 501 are preferably removed after the wiring substrate 400 and the wiring substrate 500 are bonded together in order to maintain flatness.
- a solder resist layer 412 is formed so as to cover the insulating layer 403 and to expose the connection layer 402.
- a solder resist layer 512 is formed so as to cover the insulating layer 503 and to expose the connection layer 502. Note that this step can be omitted when the insulating layers 403 and 503 are formed of a solder resist layer.
- solder balls 413 are formed on the connection layer 402 as necessary. In this way, the chip built-in substrate 300E can be formed.
- FIG. 7 is a view showing a chip built-in substrate 600 according to Example 7 of the present invention.
- a chip built-in substrate 600 according to the present embodiment has a structure in which the chip built-in substrate 300E described in the sixth embodiment is laminated.
- the chip-embedded substrate according to the present invention can be variously configured as necessary, and can be further multilayered by increasing the number of layers stacked as necessary.
- FIG. 8 is a view showing a chip built-in substrate 300F according to Example 8 of the present invention.
- the chip-embedded substrate 300F according to this example is substantially the same as the chip-embedded substrate 300 described in Example 1. It has a structure with a spherical spacer SP1 added.
- the spacer SP1 is formed of, for example, a resin material (for example, dibutene benzene) or a conductive material (for example, Cu).
- the spacing between the wiring board 100A and the wiring board 200 is adjusted by inserting the spacer SP1 into the insulating layer D1 between the wiring board 100A and the wiring board 200. . Inserting the spacer SP1 facilitates control (maintenance) of the distance between the wiring board 100A and the wiring board 200, and reduces the amount of warpage of the chip-embedded board 300F. Is possible. In addition, the parallelism between the wiring board 100A and the wiring board 200 is also improved.
- FIG. 9 is a view showing a chip built-in substrate 300G according to Example 9 of the present invention.
- a spacer SP2 corresponding to the spacer SP1 described in the eighth embodiment is installed in the solder ball (electrical connection member) 206.
- solder balls (electrical connection members) 206 having a spacer inside electrically connect the wiring formed on the wiring board 100A and the wiring formed on the wiring board 200. And has a function of controlling the distance between the wiring board 1 OOA and the wiring board 200. Further, in the case of the present embodiment, it is possible to cope with the narrowing of the wiring pitch without particularly requiring an area for installing the spacer.
- the spacer SP2 is formed of, for example, a resin material (eg, dibutene benzene) or a conductive material (eg, Cu).
- a resin material eg, dibutene benzene
- a conductive material eg, Cu
- the wiring board 100A is compared with the case of the eighth embodiment.
- the resistance of the connection portion between the formed wiring and the wiring formed on the wiring substrate 200 can be reduced.
- the electrical connection member and the metal material are melted.
- the temperature to perform differs. For example, when a solder ball (electrical connection member) is melted, Cu having a melting temperature higher than that of the solder ball serves as a spacer, and keeps the distance between two wiring boards at a predetermined value.
- solder ball electrical connection member
- connection layer D2 (a layer made of an anisotropic conductive material) may be used instead of the insulating layer D1. That is, in order to ensure electrical connection, solder balls and anisotropic conductive materials may be used in combination.
- solder balls are used as electrical connection members that electrically connect the wiring formed on the wiring board 100A and the wiring formed on the wiring board 200.
- a protruding conductive member other than solder balls for the electrical connection member.
- the projecting conductive member include a post-like (for example, columnar) conductive member (described later in Examples 10 to 13) or a bump formed by a bonding wire (described later in Examples 14 to 16). .
- FIG. 10 is a diagram showing a chip built-in substrate 300H according to Example 10 of the present invention.
- the chip-embedded substrate 300H according to the present embodiment is made of Cu for electrically connecting the wiring formed on the wiring substrate 100A and the wiring formed on the wiring substrate 200.
- a conductive post PS1 is formed.
- the post PS1 is connected to the pattern wiring 203B via the connection layer 205B. Further, a connection layer AD1 made of, for example, solder is formed between the post PS1 and the connection layer 105A. In this case, the post PS1 is connected to the pattern wiring 103A via the connection layers AD1, 105A. Further, when forming the connection layer AD1, a solder ball force or a solder ball having a spacer as described in Example 9 may be used.
- the sealing connection layer L3 corresponding to the sealing connection layer L1 of Example 1 includes the insulating layer Dl, the post PS1, and the connection layer AD1.
- the post PS1 is formed on the connection layer 205B of the wiring substrate 200 by, for example, a Cu plating method. Good. Also, the post PS1 should be formed on the wiring board 100A side (on the connection layer 105A).
- the parallelism between the OA and the wiring substrate 200 is also improved.
- connection between the wiring formed on the wiring board 100A and the wiring formed on the wiring board 200 can be made at a narrower pitch than when using, for example, solder balls. It becomes possible to do. For this reason, it is possible to easily cope with the miniaturization of the semiconductor device.
- the electrical connection reliability is low because the resistance of the connection between the wiring formed on the wiring substrate 100A and the wiring formed on the wiring substrate 200 is small. It has the characteristic of being an excellent structure!
- FIG. 11 shows a chip built-in substrate 3001 according to Embodiment 11 of the present invention.
- the post PS2 corresponding to the post PS1 is used in the chip-embedded substrate 300H according to the above-described embodiment 10. Further, the connection with the post PS2 is performed.
- a connection layer AD2 made of, for example, solder is formed between the layers 205B. Further, the connection layer AD2 can be formed by the same method as the connection layer AD1.
- the sealing connection layer L4 corresponding to the sealing connection layer L1 of Example 1 includes the insulating layer Dl, the post PS2, and the connection layers AD1 and AD2. That is, in the above structure, a connection layer made of solder is formed on both surfaces of the post PS2.
- connection layer made of solder By adding a connection layer made of solder, the reliability of electrical connection can be improved.
- FIG. 12 is a diagram showing a chip built-in substrate 300J according to Example 12 of the present invention.
- the connection layer AD1 is not formed in the chip-embedded substrate 300H according to the above-described embodiment 10, and the insulating layer D1 is replaced with an anisotropic layer.
- a connection layer D2 made of a conductive material is formed.
- the electrical connection between the post PS1 and the connection layer 105A is made by the connection layer D2. That is, in the above structure, the sealing connection layer L5 corresponding to the sealing connection layer L3 of Example 10 has the connection layer D2 and the post PS1.
- the above structure has a feature that the manufacture of the chip-embedded substrate is facilitated.
- the electrical connection between the post PS1 and the connection layer 105A can be easily performed by inserting (pushing) the post PS1 into the connection layer D2. Therefore, a special process such as thermocompression bonding or ultrasonic bonding for connecting the post PS1 and the connection layer 105A is not required, and the manufacturing process is simplified.
- the post PS1 may be formed on the connection layer 105A side.
- FIG. 13 is a view showing a chip built-in substrate 300K according to Embodiment 13 of the present invention.
- a post PS3 is formed on the connection layer 105A
- a post PS4 is formed on the connection layer 205B.
- a connection layer AD3 made of solder is formed between the post PS3 and the post PS4, for example.
- the posts PS3 and PS4 can be formed by, for example, a plating method. That is, in the above structure, the sealing connection layer L6 corresponding to the sealing connection layer L1 of Example 1 includes the insulating layer Dl, the post PS3, PS4, and the connection layer AD3. become.
- the posts that electrically connect the wiring formed on the wiring board 100A and the wiring formed on the wiring board 200 are provided on both the wiring board 100A side and the wiring board 200 side. You may form in.
- FIG. 14 is a diagram showing a chip-embedded substrate 300L according to Embodiment 14 of the present invention. Referring to FIG. 14, in the chip-embedded substrate 300L according to the present example, the above-described example 12 is described. In the chip-embedded substrate 300J, the post PS1 is replaced with the bump BP1.
- connection layer D2 made of an anisotropic conductive material. That is, in the above structure, the sealing connection layer L7 corresponding to the sealing connection layer L5 of Example 12 has the connection layer D2 and the bump BP1.
- the above structure has an advantage that the manufacturing process of the chip built-in substrate is simple in addition to the effects described in the twelfth embodiment.
- the bump BP1 is formed by laminating a plurality of (for example, two) bumps formed using a bonding wire such as Au by wire bonding. This eliminates the need for complicated processes (such as chemicals) such as a plating method, and makes it possible to reduce manufacturing costs. Further, the bump BP 1 may be formed on the connection layer 105A side.
- FIG. 15 is a view showing a chip-embedded substrate 300M according to Embodiment 15 of the present invention.
- the insulating layer D1 is used in place of the connection layer D2 in the chip built-in substrate 300L described in the fourteenth example.
- the electrical connection between the bump BP1 and the connection layer 105A is performed by a connection layer AD4 made of, for example, solder. That is, in the above structure, the sealing connection layer L8 corresponding to the sealing connection layer L1 of Example 1 includes the insulating layer Dl, the bump BP1, and the connection layer AD4. .
- the resistance of connection between the bump BP1 and the connection layer 105A is smaller than that of the chip-embedded substrate 300L.
- the bump BP1 may be provided on the connection layer 105A
- the connection layer AD4 may be provided on the connection layer 205B.
- FIG. 16 is a view showing a chip-embedded substrate 300N according to Embodiment 16 of the present invention.
- a bump is formed on the connection layer 105A (a bump formed using a bonding wire such as Au by wire bonding) BP2 and the connection layer 205B.
- Bumps bonding such as Au by wire bonding
- BP3 is formed, and the bump BP2 and the bump BP3 are connected by, for example, ultrasonic bonding or thermocompression bonding.
- the sealing connection layer L9 corresponding to the sealing connection layer L1 of Example 1 has the insulating layer Dl and the bumps BP2 and BP3.
- the bumps that electrically connect the wiring formed on the wiring board 100A and the wiring formed on the wiring board 200 have both the wiring board 100A side and the wiring board 200 side. You may form in.
- the pitch of the connecting portion can be reduced compared to when using solder balls.
- the chip-embedded substrate has the following structure.
- the chip-embedded substrate described below has a structure in which posts for connecting two wiring substrates can be installed at a narrow pitch.
- FIG. 17 is a diagram schematically showing a chip built-in substrate 700 according to Embodiment 17 of the present invention.
- a chip-embedded substrate 700 according to the present embodiment has a sealing connection layer L10 between a wiring substrate 800 on which a semiconductor chip 704 is flip-chip mounted and a wiring substrate 900 on the wiring substrate 800. It has a structure formed.
- the sealing connection layer L10 includes an insulating layer 701 corresponding to the insulating layer D1, a post 702 corresponding to the post PS1, and a connection layer 703 made of solder.
- the sealing connection layer L10 seals the semiconductor chip 704 mounted on the wiring board 800, and connects the wiring formed on the wiring board 800 and the wiring formed on the wiring board 900. It has a function.
- the wiring board 800 has a structure in which wirings are formed on both surfaces of a core substrate 801 made of, for example, a pre-predder material.
- a pattern wiring 804 is formed on the side of the core substrate 801 where the semiconductor chip 704 is mounted (hereinafter referred to as an upper side), and an insulating layer (build-up layer) 802 is formed so as to cover the pattern wiring 804.
- an insulating layer (a solder resist layer or a build-up layer! /) 803 is formed on the insulating layer 802 !.
- a via plug 805 connected to the pattern wiring 804 is formed in the insulating layer 802, and the uppermost layer patterns 806A to 806D are connected to the via plug 805.
- the insulating layer 803 is formed so as to cover the uppermost layer pattern, while the insulating layer 803 has an opening that exposes a part of the uppermost layer pattern.
- the opening corresponds to a portion where the uppermost layer pattern is connected to a semiconductor chip or a post.
- the semiconductor chip 704 is mounted so as to be connected to the uppermost layer pattern 806D.
- the post 702 is formed so as to be connected to the uppermost layer patterns 806A to 806C. Details of this structure will be described later.
- a non-turn wiring 809 is formed on the side opposite to the side on which the semiconductor chip 704 is mounted (hereinafter referred to as the lower side) of the core substrate 801, and an insulating layer (build) is formed so as to cover the pattern wiring 809.
- Up layer) 807 is formed, and further, an insulating layer (which may be a solder resist layer or a binored up layer) 808 is formed on the insulating layer 807 so as to cover it.
- a via plug 810 connected to the pattern wiring 809 is formed in the insulating layer 807. Furthermore, a via plug 812 that is connected to the pattern wiring 804 and extends through the core substrate 801 and extends toward the insulating layer 807 is formed. In addition, an electrode pad 811 connected to the via plug 810 or the via plug 812 and surrounded by the insulating layer 808 is formed.
- the wiring substrate 900 has a structure in which wiring is formed on both surfaces of a core substrate 901 made of, for example, a pre-predder material.
- Pattern wiring 904 is formed on the side opposite to the side facing the semiconductor chip 704 (hereinafter referred to as the upper side) of the core substrate 901, and an insulating layer (build-up layer) 902 is formed so as to cover the pattern wiring 904. Further, an insulating layer (which may be a solder resist layer or a build-up layer) 903 is formed on the insulating layer 902.
- a via plug 905 connected to the pattern wiring 904 is formed in the insulating layer 902, and an electrode pad 906 surrounded by the insulating layer 903 is connected to the via plug 905. Yes.
- a pattern wiring 909 is formed on the side of the core substrate 901 facing the semiconductor chip 704 (hereinafter referred to as a lower side), and an insulating layer (build-up) is formed so as to cover the pattern wiring 909.
- Layer) 907 is formed, and an insulating layer (solder resist layer or build-up layer! /) 908 is formed so as to cover the insulating layer 907.
- a via plug 910 connected to the pattern wiring 909 is formed in the insulating layer 907. Further, a via plug 912 that is connected to the pattern wiring 904 and penetrates the core substrate 901 and extends toward the insulating layer 907 is formed. In addition, an electrode pad 911 connected to the via plug 910 or the via plug 912 and surrounded by the insulating layer 908 is formed, and a part of the plurality of electrode pads 911 are formed as described above. It is structured to be connected to the post 702 through a connection layer 703.
- the wiring structure on the upper side of the wiring substrate 800 is a multi-layer wiring structure, and the uppermost layer pattern (the uppermost layer patterns 806A to 806C) and the uppermost layer pattern of the multilayer wiring structure are changed.
- the structure of the covering insulating layer is characterized in that the post 702 can be arranged at a narrow pitch.
- FIG. 18 is a plan view showing the positional relationship between the uppermost layer patterns 806A to 806C and the post 702 formed so as to be connected to the uppermost layer patterns 806A to 806C.
- the length of the adjacent uppermost layer pattern that extends is appropriately changed.
- the top layer pattern is arranged so that short and long patterns are alternately arranged. Therefore, the posts 702 connected to the uppermost layer patterns 806A to 806C are arranged alternately when viewed in plan.
- portions of the uppermost layer patterns 806A to 806C other than the portion connected to the post 702 are covered with the insulating layer 803. 18 corresponds to FIG. 17, but it is obvious that the uppermost layer pattern 806B is covered with the insulating layer 803 in the cross section.
- the posts 702 can be installed at a narrower pitch.
- the conductive pattern of the uppermost layer connected to the post is appropriately changed, and if necessary, the part other than the connection part of the post is covered with an insulating layer (solder resist layer) to cope with a narrow pitch of the connection part. It is possible to do.
- an insulating layer solder resist layer
- the wiring board 800 is formed by a known method (for example, a semi-additive method).
- the pattern wirings 804 and 809 are formed by pattern-etching the surface of a pre-preda material with copper foil, and the via plugs 805, 810 and 812, the electrode pads 811 and the uppermost layer node are formed by a Cu plating method.
- ⁇ Turns 806 A ⁇ 806D etc. are formed.
- the uppermost layer patterns 806A to 806D are all covered with the insulating layer 803! /.
- openings h that penetrate the insulating layer 803 and reach the uppermost layer patterns 806A to 806D are formed by, for example, a laser.
- the opening h corresponding to the uppermost layer pattern 806B is not shown. This is because the openings corresponding to the uppermost layer patterns 806A to 806C are formed alternately when viewed in plan. That is, in the cross section shown in the drawing, the uppermost layer pattern 806B is covered with the insulating layer 803.
- a resist layer FR is formed on the insulating layer 803 by coating or pasting.
- the resist layer FR is patterned to form an opening H corresponding to a portion where the uppermost layer patterns 806A to 806C are exposed (the opening h).
- a post 702 is formed by, for example, a Cu plating method so as to correspond to the opening H and the opening h, and the resist layer FR is peeled off.
- the semiconductor chip 704 is flip-chip mounted so as to be connected to the uppermost layer pattern 806D, and the semiconductor chip is sealed with the insulating layer 7001. Further, the wiring board 900 is bonded onto the wiring board 800, and in this case, a connection layer 703 made of, for example, solder is formed between the post 702 and the electrode pad 911. In this way, the wiring board 800 and the wiring board 900 are electrically connected, and the semiconductor chip 704 between the wiring board 800 and the wiring board 900 is sealed, and the chip-embedded board 700 is formed. [0153] According to the above manufacturing method, it is possible to manufacture a high-performance semiconductor device having a fine wiring structure, corresponding to the narrowing of the pitch of the connection portion of the wiring board.
- Example 8 to Example 17 are built up like the chip embedded substrate 3 OOD of Example 5 (Fig. 5P) and the chip embedded substrate 300E of Example 6 (Fig. 6E). It can also be applied to a chip-embedded substrate (manufactured by a build-up method) using a substrate.
- solder balls are formed as external connection terminals of the chip-embedded substrate.
- the solder balls 111 and 207 may be omitted.
- the connection layers 105B and 205A function as external connection terminals.
- the present invention is not limited to the case where substrates having a size corresponding to the chip-embedded substrate are bonded together.
- a plurality of chip-embedded substrates may be simultaneously formed using a large-sized substrate, and the large-sized substrate may be cut (diced) in a later process to separate the chip-embedded substrates individually.
- a chip-embedded substrate can be formed by variously combining substrates of various sizes.
- the wiring substrate 100A as the first substrate and the wiring substrate 200 as the second substrate.
- a plurality of first substrates are formed on a large substrate (or a large substrate formed on a support substrate), and individual second substrates are stacked on the first substrate on the large substrate. Do (paste together). Thereafter, the large substrate can be cut to form a chip-embedded substrate so that the first substrates are individually separated.
- a large substrate (or a support substrate) A plurality of second substrates are formed on the large substrate formed in (1), and the individual first substrates are laminated (bonded) to the second substrate on the large substrate. Thereafter, the large substrate can be cut to form a chip-embedded substrate so that the second substrates are individually separated.
- a fourth example there is the following method. First, a plurality of first substrates are formed on a first large substrate (or a large substrate formed on a support substrate), and similarly, a second large substrate (or a support substrate is formed). A plurality of second substrates are formed on the large-sized substrate). Next, the first large-sized substrate and the second large-sized substrate are stacked (bonded), and the second substrate is stacked on the first substrate. Thereafter, the first large substrate and the second large substrate bonded together are cut so that the first substrate and the second substrate are individually separated to form a chip built-in substrate. be able to.
- the shape of the underfill or the method of forming the underfill may be variously changed.
- a resin material called an underfill for example, liquid resin
- an underfill is generally infiltrated between a semiconductor chip and a substrate to be cured. Yes.
- the wiring board is further repeatedly heated and cooled, so the difference in thermal history, thermal expansion coefficient, or stress between the underfill and the surrounding material Warping may occur in the underfill (wiring board).
- the area (volume) where the underfill is formed may be reduced as shown below.
- the step shown in Fig. 20 may be performed instead of the step shown in Fig. 1C.
- the underfill 109A does not penetrate the entire area between the semiconductor chip and the wiring board, and the bumps 108 on the four sides of the semiconductor chip 110 and the vicinity of the bumps 108 are shown. Only applied to. Because of this The area (volume) in which the durfill is formed becomes smaller, and it becomes possible to suppress warping of the wiring board and the like caused by underfill.
- the underfill may be formed only near the center of the semiconductor chip as shown in FIGS. 21A to 21B below. In this case, the steps shown in FIGS. 21A to 21B may be performed instead of the steps shown in FIG.
- liquid grease (underfill) 109B is dropped by potting at the center of the position where the semiconductor chip on the solder resist layer 104A of the wiring board is mounted.
- the underfill 109B can be formed only near the center of the semiconductor chip 101 by flip-chip mounting the semiconductor chip 101.
- an electrical connection member (for example, a solder ball) used when two wiring boards are bonded together may be installed on the side of the board on which the semiconductor chip is mounted. It may be installed on the side of the substrate that is to be bonded to the substrate on which the chip is mounted.
- Example 1 For example, in the case of Example 1, as described above, the electrical connection member is installed on the side of the wiring board to be bonded to the wiring board on which the semiconductor chip is mounted.
- FIG. 22 is a diagram for explaining the process shown in FIG. 1E of Example 1 in more detail. In accordance with the method for manufacturing the wiring board shown in Example 1, the wiring board 100A and the wiring board 200 are bonded together. It is the figure which showed the process to match
- the electrical connection member (solder ball 206) is installed on the side of the wiring board 200 to be bonded to the wiring board 100A on which the semiconductor chip 110 is mounted. Has been.
- an electrical connection member (solder ball 206) is installed on the side of the wiring board 100A on which the semiconductor chip 110 is mounted.
- the gap between the board on which the semiconductor chip is mounted and the board on which the semiconductor chip is mounted is bonded to the lower (upper) side. Good.
- the upper and lower relations between the wiring board 100A and the wiring board 200 are used, and the wiring installed on the lower side (for example, on the work table)
- the wiring substrate 100A on which the semiconductor chip 110 is mounted may be pasted on the substrate 200.
- the electrical connection member (solder ball 206) is installed on the lower wiring board 200 side.
- the wiring installed on the lower side with the vertical relationship between the wiring board 100A and the wiring board 200 in the process shown in FIG.
- the wiring substrate 100A on which the semiconductor chip 110 is mounted may be pasted on the substrate 200.
- the electrical connection member (solder ball 206) is installed on the upper wiring board 100A side.
- the semiconductor chip is mounted on the wiring board by face down (for example, flip chip mounting) is described as an example. It is not limited.
- the semiconductor chip may be mounted (mounted) on the substrate face up.
- FIG. 26 to FIG. 27 are diagrams schematically showing a manufacturing method in the case where a semiconductor chip is mounted face-up on a wiring board to manufacture a chip-embedded substrate.
- FIG. 26 in the present embodiment, first, FIG. 1A to FIG. 1B of Embodiment 1 are performed, and wiring board 100 is brought into the state shown in FIG. 1B. That is, in the wiring substrate 100 shown in FIG. 1A, the connection layer 107 made of, for example, solder is formed on the pattern wiring 103A exposed from the opening 106 of the solder resist layer 104A by electrolytic plating or the like.
- the semiconductor chip 110 is face-upd using the grease 208 (for example, called a die attach film) on the film on the wiring board 200 (on the solder resist layer 204B) shown in FIG. 1D of the first embodiment. Paste with. On the semiconductor chip 110, bumps (electric connection members) 108 formed of a bonding wire such as Au are formed.
- connection layer 205B on the pattern wiring 203B of the wiring board 200, a plurality of laminated bumps (from the wire bonding insulator, Au, etc.) are used as electrical connection members instead of the solder balls 206. Bumps 209 are formed using the bonding wires. [0180] Next, in the step shown in FIG. 27, the wiring board 100 and the wiring board 200 are bonded together in the same manner as described above with reference to FIG. 1E.
- the wiring substrate 200 and the wiring substrate 100 are bonded together, they can be bonded together by the following first method or second method.
- the first method can be performed as follows. First, the wiring substrate 200 is laminated and pressed 100 ° C. through a thermosetting film-like buildup resin (uncured at this stage). Here, the bump (electrical connection member) 209 of the wiring board 200 is pressed into a film-like build-up resin and pressed against the connection layer 105A of the wiring board 100. At the same time, the bump 108 is pressed into the build-up resin and pressed against the connection layer 107 of the wiring board 100. By heating in this state, the connection layer 107 is melted and the resin build-up resin is cured by heat to become the insulating layer D1. As a result, the sealing connection layer Lla including the insulating layer D1 and the bump 209 is formed.
- the second method can be performed as follows. First, the wiring board 200 is stacked on the wiring board 100 and pressed. Here, the bump 209 of the wiring board 200 is pressed against the connection layer 105 A of the wiring board 100. At the same time, the bump 108 is pressed against the connection layer 107. By heating in this state, the connection layer 107 is melted. Next, a liquid resin is filled between the wiring board 200 and the wiring board 100 and cured to form the insulating layer D1. As a result, the sealing connection layer Lla including the insulating layer D1 and the bump 209 is formed.
- the pattern wiring 203B of the wiring board 200 and the pattern wiring 103A of the wiring board 100 are electrically connected by the bump 209. .
- the semiconductor chip 110 and the pattern wiring 103A of the wiring board 100 are electrically connected by the non-power supply 108.
- the semiconductor chip 110 is electrically connected to the substrate (wiring board 200) on which the semiconductor chip 110 is first mounted (installed or attached). I have not been told. That is, “mounting” in this embodiment means that at least a semiconductor chip is attached (installed), and is not necessarily used to include electrical connection. [0186] According to this embodiment, it is not necessary to fill the underfill with the substrate on which the semiconductor chip is mounted (installed). For this reason, there is an effect of suppressing the occurrence of warpage of the substrate due to underfill.
- the power described using an example in which bumps are used to connect the semiconductor chip and the pattern wiring is not limited to this.
- a bonding wire may be used to connect the semiconductor chip and the pattern wiring.
- FIG. 28 to FIG. 29 are diagrams showing a method for manufacturing a chip-embedded substrate according to the twenty-first embodiment.
- a film-like resin DF for example, a diamond
- the semiconductor chip 110 is attached face up using a touch film). Further, the semiconductor chip 110 and the pattern wiring 103A are connected by the bonding wire WB.
- the shape of the pattern wiring 103A and the opening formed in the solder resist layer 104A may be appropriately changed according to wire bonding.
- a chip-embedded substrate can be manufactured by performing the same process as that in FIG. 1E of Example 1.
- the semiconductor chip may be face-up with respect to the substrate to be mounted, or electrical connection may be performed by shear bonding.
- the electronic component includes an electronic component called a surface mount device.
- the electronic component includes a capacitor, an inductor, a resistance element, an oscillation element (for example, a crystal resonator), a filter, a communication element (for example, a SAW element), and the like.
- FIG. 30 is a diagram showing an example in which electronic components EL1, EL2, and EL3 are mounted on the chip-embedded substrate 300 shown in the first embodiment.
- the electronic components EL2 and EL3 are mounted on the opposite side (upper side) of the wiring board 200 facing the semiconductor chip 110 so as to be connected to the pattern wiring 203A.
- the wiring board 200 (chip built-in board) needs to be enlarged.
- the electronic component EL1 is mounted on the same surface as the surface on which the semiconductor chip 110 of the wiring substrate 100A is mounted. Further, the electronic component EL1 is further mounted on the side of the wiring board 200 facing the semiconductor chip 110. In this case, the electronic component EL1 is sealed with the sealing connection layer L1 (insulating layer D1) similarly to the semiconductor chip 110. In addition, when the electronic component EL1 is mounted on the side of the wiring board 200 facing the semiconductor chip 110, the electronic component is positioned at a position where the semiconductor chip 110 is avoided (position adjacent to the semiconductor chip 110) when viewed in plan. Preferably EL1 is implemented. In this case, the chip built-in substrate can be made thinner.
- the electronic component EL1 may be mounted on both the wiring board 200 and the wiring board 100A.
- the electronic component EL1 is mounted only on the wiring board 200 and only on the wiring board 100. Be it!
- FIG. 31 is a diagram showing an example in which the electronic component EL4 is further mounted on the chip-embedded substrate 300 shown in the first embodiment in addition to the electronic components EL1, EL2, and EL3.
- the electronic component EL4 is mounted on the side facing the semiconductor chip 110 of the wiring substrate 200 (the substrate bonded to the substrate on which the semiconductor chip is mounted). Further, the electronic component EL4 is disposed immediately above the semiconductor chip 110. As described above, when the electronic component is arranged immediately above the semiconductor chip 110, the electronic component can be mounted with high density, and the area of the chip-embedded substrate when viewed in plan can be reduced. [0197] In addition, in the chip-embedded substrate shown in this figure, conductive layer 100P is formed (built-in) on wiring substrate 100A (lower wiring substrate), and conductive layer 200P is formed on wiring substrate 200 (upper wiring substrate). Formed (built-in). The conductive layer 100P is formed substantially on the entire surface of the wiring board 100A when the wiring board 100A is viewed in plan. Similarly, the conductive layer 200P is formed substantially on the entire surface of the wiring board 200 when the wiring base 200 is viewed in plan.
- electronic components EL1, EL4 and semiconductor chip 110 mounted between wiring board 100A and wiring board 200 are electromagnetically shielded.
- electronic components (semiconductor chips) that are electromagnetically shielded are less susceptible to the effects of noise such as the electronic components EL2 and EL3.
- an electromagnetic component (semiconductor chip) that is electromagnetically shielded exerts the effect of ⁇ influencing noise on the electronic components EL2, EL3, etc.
- a conductive layer (ground plane) that is grounded and has a potential at the ground level, and a conductive layer (power plane) that is given a predetermined potential with respect to the ground potential are formed on the wiring board.
- a conductive layer (ground plane) that is grounded and has a potential at the ground level, and a conductive layer (power plane) that is given a predetermined potential with respect to the ground potential are formed on the wiring board.
- the conductive layers such as the ground plane and power plane described above for electromagnetic shielding. It becomes.
- an analog element is mounted between the wiring board 100A and the wiring board 200, and a digital element (analog element) is placed on the wiring board 200 (the opposite side of the wiring board 200 facing the semiconductor chip). If implemented ,.
- a wiring structure 102a (via plug, pattern wiring, etc.) is formed between the pattern wiring 103A and the conductive layer 100P, and a wiring structure 102b is formed between the pattern wiring 103B and the conductive layer 100P as necessary. Also good.
- a wiring structure 202a may be formed between the non-turn wiring 203A and the conductive layer 200P, and a wiring structure 202b may be formed between the non-turn wiring 203B and the conductive layer 200P as necessary.
- FIG. 31 has been changed as shown in FIG. It may be stacked and mounted on the chip 110.
- some electronic components are thicker (higher) than the semiconductor chip, so when mounting an electronic component between the wiring board 100A and the wiring board 200, the electronic component If the distance between the wiring board 100A and the wiring board 200 is set to match, the chip-embedded board may become thicker (larger).
- FIG. 33 is a diagram showing an example in which the electronic component EL5 is mounted on the chip-embedded substrate 300 shown in the first embodiment.
- the electronic component EL5 is mounted on the wiring board 100A, and the electronic component EL5 and the pattern wiring 103A are connected.
- the chip-embedded substrate shown in this figure is characterized in that an opening 200a for exposing the electronic component EL5 mounted on the wiring substrate 100A is formed in the wiring substrate 200. For this reason, when the electronic component EL5 whose height from the mounting surface is higher than that of the semiconductor chip 110 is mounted, it is possible to suppress the influence of increasing the thickness of the chip-embedded substrate.
- opening 100a for exposing electronic component EL1 mounted on wiring board 200 is exposed on wiring board 100A.
- an opening for exposing the semiconductor chip may be formed in the wiring board 200.
- an opening for exposing the semiconductor chip may be formed on the wiring board 100A.
- the semiconductor chip to be mounted is large (thick), or when multiple stacked semiconductor chips are mounted, by forming openings in the wiring board, the effect of increasing the size of the chip-embedded board can be affected. Can be suppressed.
- the portion occupied by the solder resist layer be as small as possible.
- the solder resist layer is not solder It is a resin material that is used as a solder flow stop when melted, but it may contain photosensitive material so that patterning is easy. What is a general resin material called build-up resin? The ingredients are different.
- the solder resist layer is characterized by a lower physical strength and a lower glass transition temperature (lower heat resistance) than the build-up resin. Therefore, for example, as shown below, it is preferable to make the area of the solder resist layer as small as possible (or avoid using it).
- FIG. 35 is a diagram showing an example in which the solder resist layer 204B of the wiring board 200 is made smaller in the chip-embedded substrate 300 shown in the first embodiment.
- the area where the solder resist layer 204B is formed is reduced, and the solder resist layer 204B is formed only in the vicinity of the pattern wiring 203B to which the solder connection is performed.
- the volume (area) occupied by the insulating layer D1 made of the buildup resin instead of the solder resist layer is increased between the wiring board 100A and the wiring board 200, and the reliability of the substrate with a built-in chip is good. The effect which becomes.
- Such a configuration may also be applied to the solder resist layer 104A on the wiring board 100A side!
- FIG. 36 is a diagram showing a configuration in which the solder resist layer 204B of the wiring substrate 200 is deleted from the chip-embedded substrate 300 shown in the first embodiment.
- the solder ball 206 is formed at a position corresponding to the pattern wiring 203B force via plug 202 to which the solder ball 206 is melted and connected.
- the shape of the pattern wiring 203B is reduced, and the space where solder flows on the pattern wiring 203B is reduced.
- the non-turn wiring 203B has a shape (area) close to a so-called electrode pad.
- the number of semiconductor chips to be mounted is not limited to one, and a plurality of semiconductor chips may be mounted.
- FIG. 37 to FIG. 42 show that a plurality of semiconductor chips are mounted on the chip-embedded substrate 300 shown in the first embodiment. It is the figure which showed the example to wear.
- the electronic parts EL2 and EL3 described above are mounted on the chip-embedded board, and the detailed structure (pattern wiring, via plugs, etc.) of the wiring board 100A and wiring board 200 is partially omitted. Therefore, it is a schematic description.
- the semiconductor chip 110A is further stacked and mounted on the semiconductor chip 110 flip-chip connected to the wiring board 100A.
- the semiconductor chip 110A is connected to the wiring substrate 100A by bonding wires.
- the semiconductor chips 110 and 110A both laminated face-up on the wiring board 100A are connected to the wiring board 100A by bonding wires.
- the semiconductor chip 110B is further flip-chip connected on the semiconductor chip 110 flip-chip connected to the wiring substrate 100A.
- a through plug (not shown) is formed in the semiconductor chip 110, and the semiconductor chip 110B is connected to the wiring substrate 100A through the through plug.
- the semiconductor chip 110B is flip-chip connected to the wiring substrate 200 on the semiconductor chip 110 flip-chip connected to the wiring substrate 100A. That is, the semiconductor chip 110B is flip-chip mounted on the side of the wiring board 200 facing the semiconductor chip 110 (wiring board 100A).
- the semiconductor chip 110B is flip-chip mounted on the side opposite to the side on which the semiconductor chip 110 is mounted on the wiring board 100A on which the semiconductor chip 110 is flip-chip mounted. ing. That is, in the case shown in this figure, semiconductor chips are flip-chip mounted on both surfaces of the wiring board 100A.
- the number of semiconductor chips to be mounted is not limited to two, and a larger number of semiconductor chips may be mounted.
- a plurality of semiconductor chips 110 are installed between the wiring board 100A and the wiring board 200, and positions where the semiconductor chips 110 avoid each other when viewed in plan (semiconductor value) Chips 110 are mounted at adjacent positions).
- the chip built-in substrate can be thinned, which is preferable.
- the electronic component EL3 may be mounted via an interposer.
- the first method is a method using a thermosetting film-like build-up resin
- the other method is a method using liquid resin.
- FIGS. 43A to 43B show a wiring board using a mold press instead of a method of sandwiching a resin film or a method of infiltrating liquid resin in the process shown in FIG. 1E of Example 1.
- FIG. 5 is a diagram schematically showing a method of forming an insulating layer (layer made of a resin) D1 between 100A and a wiring board 200.
- the detailed structure of the wiring boards 100A and 200 is partially omitted, and there is a part schematically shown.
- the wiring board 100A and the wiring board 200 are installed in the mold KG0 in a state where the wiring boards 100A and 200B are facing each other.
- the mold KG0 opening (mold gate) OP force is also introduced by pressurizing mold resin between the wiring board 100A and the wiring board 200, and cured.
- the wiring board can be taken out from the mold KG0 (Fig. 43B).
- the insulating layer D1 (sealed connection layer L1) can be formed even by using the mold press technique.
- mold press may be performed using, for example, the following method (mold).
- a mold KG 1 having a recess KGa is prepared.
- the wiring board 100A and the wiring board 200 are installed in the concave portion KGa of the mold KG1 in a state where the forces are combined.
- the molds KG2 and KG3 are sequentially installed.
- the uniformity of the stress applied to the surface of the mold KG3 is improved by separately pressing the mold KG3 with a plurality of pressurizing means SP.
- an opening (mold gate) OP for introducing mold resin is formed in the mold KG2.
- the molds KG2, KG3 may be placed on the wiring board 200 after the film FL is adsorbed on the molds KG2, KG3.
- mold resin is pressed and introduced between the wiring board 100A and the wiring board 200 from the mold gate OP, and cured to form the insulating layer D1.
- the mold force can also be removed from the wiring board (FIG. 44F).
- the wiring board can be cut into pieces by dicing (cut along the dotted line) to produce a chip-embedded board.
- a chip-embedded substrate substrates of various sizes can be used as described above.
- the combination shown in Fig. 45 is an example of this, and a plurality of wiring boards 200 corresponding to the size of the chip-embedded board are placed on and bonded to a large wiring board 100A to form the wiring board. is doing.
- the mounted semiconductor chip is indicated by a dotted line.
- the chip-embedded substrate can be manufactured by cutting the wiring substrate 100A into pieces by dicing.
- the large-sized wiring board 100A and the large-sized wiring board 200 are bonded together, and both of the wiring boards 100A and 200 are cut by dicing into individual pieces, thereby manufacturing a chip-embedded board. A little.
- a wiring board 200 of a size (so-called two-chip use) that can form two chip-embedded boards is placed on a large wiring board 100A.
- the substrate with a built-in chip may be manufactured by a method of bonding together.
- a chip built-in substrate can be manufactured by dicing the wiring substrate 200 into pieces.
- the mounted semiconductor chip and the portion that becomes one chip-embedded substrate are indicated by dotted lines.
- the substrate to be placed is not limited to a size that allows two chip-embedded substrates to be formed (for taking two), but is large enough to form a chip-embedded substrate.
- Various changes can be made, such as the size (for 4 chips) and the size that can form 6 chip-embedded substrates (for 6 chips).
- a chip-embedded substrate having a good production yield and high reliability of multilayer wiring connected to a built-in semiconductor chip, and a manufacturing method for manufacturing the chip-embedded substrate. It becomes possible to provide.
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
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- Toxicology (AREA)
- Geometry (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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US11/815,580 US7989707B2 (en) | 2005-12-14 | 2006-12-12 | Chip embedded substrate and method of producing the same |
JP2007518400A JPWO2007069606A1 (ja) | 2005-12-14 | 2006-12-12 | チップ内蔵基板の製造方法 |
EP06834519A EP1962342A4 (en) | 2005-12-14 | 2006-12-12 | SUBSTRATE WITH INTEGRATED CHIP AND METHOD FOR MANUFACTURING THE SAME |
US13/167,203 US8793868B2 (en) | 2005-12-14 | 2011-06-23 | Chip embedded substrate and method of producing the same |
US14/321,030 US9451702B2 (en) | 2005-12-14 | 2014-07-01 | Chip embedded substrate and method of producing the same |
US15/241,482 US9768122B2 (en) | 2005-12-14 | 2016-08-19 | Electronic part embedded substrate and method of producing an electronic part embedded substrate |
US15/676,288 US10134680B2 (en) | 2005-12-14 | 2017-08-14 | Electronic part embedded substrate and method of producing an electronic part embedded substrate |
Applications Claiming Priority (4)
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JP2005-360519 | 2005-12-14 | ||
JP2005360519 | 2005-12-14 | ||
JP2006-117618 | 2006-04-21 | ||
JP2006117618 | 2006-04-21 |
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US11/815,580 A-371-Of-International US7989707B2 (en) | 2005-12-14 | 2006-12-12 | Chip embedded substrate and method of producing the same |
US13/167,203 Division US8793868B2 (en) | 2005-12-14 | 2011-06-23 | Chip embedded substrate and method of producing the same |
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WO2007069606A1 true WO2007069606A1 (ja) | 2007-06-21 |
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PCT/JP2006/324764 WO2007069606A1 (ja) | 2005-12-14 | 2006-12-12 | チップ内蔵基板およびチップ内蔵基板の製造方法 |
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US (5) | US7989707B2 (ja) |
EP (2) | EP2290682A3 (ja) |
JP (1) | JPWO2007069606A1 (ja) |
KR (1) | KR100892935B1 (ja) |
TW (1) | TW200737383A (ja) |
WO (1) | WO2007069606A1 (ja) |
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- 2006-12-12 JP JP2007518400A patent/JPWO2007069606A1/ja active Pending
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- 2006-12-13 TW TW095146596A patent/TW200737383A/zh unknown
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Also Published As
Publication number | Publication date |
---|---|
US9451702B2 (en) | 2016-09-20 |
EP2290682A3 (en) | 2011-10-05 |
US20090008765A1 (en) | 2009-01-08 |
US9768122B2 (en) | 2017-09-19 |
US20170365559A1 (en) | 2017-12-21 |
US10134680B2 (en) | 2018-11-20 |
TWI361467B (ja) | 2012-04-01 |
US20110256662A1 (en) | 2011-10-20 |
EP1962342A4 (en) | 2010-09-01 |
US7989707B2 (en) | 2011-08-02 |
JPWO2007069606A1 (ja) | 2009-05-21 |
US20160358858A1 (en) | 2016-12-08 |
US8793868B2 (en) | 2014-08-05 |
EP1962342A1 (en) | 2008-08-27 |
TW200737383A (en) | 2007-10-01 |
KR100892935B1 (ko) | 2009-04-09 |
EP2290682A2 (en) | 2011-03-02 |
KR20070100355A (ko) | 2007-10-10 |
US20140313681A1 (en) | 2014-10-23 |
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