JP6321209B2 - 成形研磨粒子を含む研磨物品 - Google Patents
成形研磨粒子を含む研磨物品 Download PDFInfo
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- JP6321209B2 JP6321209B2 JP2016562490A JP2016562490A JP6321209B2 JP 6321209 B2 JP6321209 B2 JP 6321209B2 JP 2016562490 A JP2016562490 A JP 2016562490A JP 2016562490 A JP2016562490 A JP 2016562490A JP 6321209 B2 JP6321209 B2 JP 6321209B2
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
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- 238000006243 chemical reaction Methods 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
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- 230000006835 compression Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
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- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004924 electrostatic deposition Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
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- 238000007499 fusion processing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008131 herbal destillate Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
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- 239000008101 lactose Substances 0.000 description 1
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- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
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- 238000013508 migration Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
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- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/14—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1436—Composite particles, e.g. coated particles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
様々な方法を用いて、成形研磨粒子を得ることができる。粒子は、商業的供給源から入手してもよく、または作製してもよい。成形研磨粒子を作製するために使用される一部の好適なプロセスとしては、蒸着、印刷(例えば、スクリーン印刷)、鋳型成形、プレス、流延、分割、切断、ダイス切断、打抜き、プレス、乾燥、硬化、コーティング、押出、圧延、及びこれらの組み合わせを挙げることができるがこれらに限定されない。
成形研磨粒子を形成または供給した後、粒子を他の材料と併せて、固定研磨物品を形成することができる。固定研磨体では、成形研磨粒子を、マトリクスまたは基質に連結させて、材料除去操作に使用することができる。一部の好適な例示的な固定研磨物品としては、結合研磨物品を挙げることができ、ここで、成形研磨粒子は、結合材料の三次元マトリクスに収容されている。他の事例では、固定研磨物品は、研磨布紙物品であってもよく、ここで、成形研磨粒子は、バッキング(例えば、基材)を覆う単一の層に分散され、1つ以上の接着層を用いてバッキングに結合され得る。
それらが画像に完全に存在していないという事実を考慮して、倍率±0.5を適用した。
6つの成形研磨粒子サンプルを作製し、性能の比較のために試験した。第1のサンプルであるサンプルS1を、まず、およそ45〜50重量%のベーマイトを含む混合物から形成した。ベーマイトは、Sasol CorpからCatapal Bとして入手し、Catapal Bと脱イオン水及び硝酸との30重量%混合物をオートクレーブすることによって改変させた。硝酸とベーマイトの比は、オートクレーブ内において、ならびに5分間〜24時間の範囲の時間で100℃〜250℃において処理すると、およそ0.025であった。オートクレーブしたCatapal Bのゾルを、従来的な手段により乾燥させた。Sasol CorpからDisperalとして市販されている代替的なベーマイトを用いてもよい。ベーマイトを、混合物の総アルミナ含量に対して1%のαアルミナシードと混合し、撒いた。αアルミナシードは、例えば、米国特許第4,623,364号に記載されている従来技術を用いてコランダムをミリングすることによって作製した。混合物には、混合物の所望される粘度に応じて、45〜50重量%の水及び2.5〜7重量%の追加の硝酸が含まれており、これらはゲル混合物を形成するために使用された。成分を、従来的な設計の遊星型ミキサで混合し、混合物からガス要素(例えば、気泡)を除去するために減圧下で混合した。
サンプルS1及びS2で概説した形状及び微細構造を有する研磨粒子を、ゲル混合物をダイの下を移動する生産用治具の開口部に押し出すためのダイを含む機械を使用して形成した。これらの結晶粒を使用して、以下に概説され、それぞれCAS1及びCAS2と示される構成を有する、研磨布紙サンプルを形成した。3MからCII 984Fとして市販され、CACS4と示される、比較用のベルト。サンプルCAS1及びCAS2は、以下に示す同じ構成を有していた。1連当たり47ポンドの仕上げ布紙のバッキングを入手し、表4に提供されるフェノールホルムアルデヒド樹脂を含むメイク配合物でコーティングした。静電沈着プロセスを使用して、サンプルS1またはS2に関して概説したものと実質的に同じ形状及び微細構造を有する1連当たり41ポンドの研磨粒子を、メイクコートを有するバッキングに適用した。構造体を80℃で2時間、炉内で乾燥させた。メイクコートは、表4に示される構成成分の合計が100%となるように作製したことが理解されるであろう。
項目1.成形研磨粒子であって、第1の主表面と、第2の主表面と、第1の主表面と第2の主表面との間に延在する側面と、を備える本体を備え、本体は、約0.7〜約1.7の範囲内の鋭度−形状−強度係数(3SF)、及び少なくとも約0.01〜約〜0.47以下の範囲内の形状指数を有する、成形研磨粒子。
互いに隣り合う本体の第2の隅部と第3の隅部との間に延在する側面の第2の部分を備え、側面の第2の部分は、第3の直線区間に連接した第2の曲線区間を含む、項目1、2、3、4、5、6、7、及び8のいずれか1項目に記載の成形研磨粒子。
側面の第3の部分は、互いに隣り合う本体の第1の隅部と第3の隅部との間に延在し、側面の第3の部分は、第5の直線区間に連接した第3の曲線区間を含む、項目1、2、3、4、5、6、7、及び8のいずれか1項目に記載の成形研磨粒子。
本体の第2のアームの最大幅を画定する第2の最大先端部幅(Wt2)であって、第2のアームの第2の末端部と本体の中点との間に配置される、第2の最大先端部幅(Wt2)と、
本体の第3のアームの最大幅を画定する第3の最大先端部幅(Wt3)であって、第3のアームの第3の末端部と本体の中点との間に配置される、第3の最大先端部幅(Wt3)と、をさらに有する、項目8及び91のいずれか1項目に記載の成形研磨粒子。
本体は、第2のアームの第2の最大先端部幅の位置と中点との間にある第2のアームの最も狭い部分を画定する第2のスロート幅(Wth2)をさらに有し、第2のスロート幅(Wth2)は、第2のアームの軸に沿った第2のスロート幅の位置を画定し、第2のスロート位置は、第2の最大先端部幅の位置よりも中点に近く、
本体は、第3のアームの第3の最大幅の位置と中点との間にある第3のアームの最も狭い部分を画定する第3のスロート幅(Wth3)をさらに有し、第3のスロート幅(Wth3)は、第3のアームの軸に沿った第3のスロート幅の位置を画定し、第3のスロート位置は、第3の最大先端部幅の位置よりも中点に近い、項目100に記載の成形研磨粒子。
i)少なくとも約350MPa〜約1500MPa以下の範囲内の所定の強度を有する材料を選択し、所定の強度に基づいて、所定の先端部鋭度及び所定の形状指数を有する成形研磨粒子の本体を形成すること、
ii)成形研磨粒子の本体の所定の形状指数を、少なくとも約0.01〜約0.49以下の範囲内で選択し、所定の形状指数に基づいて、所定の先端部鋭度及び所定の強度を有する本体を形成すること、ならびに
iii)成形研磨粒子の本体の所定の先端部鋭度を、少なくとも約1ミクロン〜約80ミクロン以下の範囲内で選択し、所定の先端部鋭度に基づいて、所定の形状指数及び所定の強度を有する成形研磨粒子の本体を形成すること、のうちの少なくとも1つを含む、成形研磨体の本体を形成することを含む、方法。
部分的に凹んだ形状を有する側面の第1の部分、
互いに隣り合う本体の第1の隅部と第2の隅部との間に延在する側面の第1の部分であって、第1の直線区間に連接した第1の曲線区間を含む、側面の第1の部分、
第1の直線区間に連接し、かつ鈍角を画定する入隅部を画定する、第1の曲線区間を含む、側面の第1の部分、
実質的に180度の出隅部の和を有し、かつ第1の曲線区間を有する側面の第1の部分をさらに含む、ハイブリッド多角形、
本体の第1のアームの最大幅を画定する第1の最大先端部幅(Wt1)であって、第1のアームの第1の末端部と本体の中点との間に配置される、第1の最大先端部幅(Wt1)、及びこれらの組み合わせ、のうちの少なくとも1つを含む、項目102に記載の方法。
Claims (15)
- 成形研磨粒子であって、
第1の主表面と、第2の主表面と、前記第1の主表面と前記第2の主表面との間に延在する側面と、を備える本体を備え、前記本体は、約0.7〜約1.7の範囲内の鋭度−形状−強度係数(3SF)、及び少なくとも約0.01で、約0.47以下の範囲内の形状指数を有し、前記鋭度−形状−強度係数は、3SF=[(S*R*B 2 )/2500]として表現され、Sは、前記本体のヘルツ強度(MPa)を表し、Rは、前記本体の出隅部に最も良く適合する円の半径である前記本体の先端部鋭度(ミクロン)を表し、Bは、前記本体に重ねられた最も良く適合する外円の外半径を、前記本体内に適合する最も大きな適合内円の内径で除することによって計算される前記本体の前記形状指数を表す、成形研磨粒子。 - 前記本体は、少なくとも約0.1で、約0.45以下の形状指数を有する、請求項1に記載の成形研磨粒子。
- 前記本体は、少なくとも約0.72で、約1.65以下の3SFを有する、請求項1に記載の成形研磨粒子。
- 前記本体は、少なくとも約350MPaで、約1500MPa以下の範囲内の強度を有する、請求項1に記載の成形研磨粒子。
- 前記本体は、約80ミクロン以下で、少なくとも約1ミクロンの範囲内の先端部鋭度を有する、請求項1に記載の成形研磨粒子。
- 前記本体は、結晶粒を含む多結晶性材料を含み、平均粒度は、約1ミクロン以下である、請求項1に記載の成形研磨粒子。
- 前記本体は、結合研磨物品、研磨布紙物品、及びこれらの組み合わせからなる群から選択される固定研磨体の一部として基材に連結されている、請求項1に記載の成形研磨粒子。
- 前記本体は、第1の直線区間と第2の直線区間の間の第1の曲線区間を有する前記側面の第1の部分を含む前記上部表面に平行な面で見たときに、二次元形状を有し、前記第1の直線区間が前記本体の第1の出隅部で終結し、前記第2の直線区間が前記本体の第2の出隅部で終結する、請求項1に記載の成形研磨粒子。
- 前記第1の曲線区間は、少なくとも2つの明確に異なる湾曲を有する、請求項8に記載の成形研磨粒子。
- 前記第1の直線区間は、第1の直線区間の長さ(Ll1)を有し、前記第1の曲線区間は、第1の曲線区間の長さ(Lc1)を有し、Ll1は、Lc1と比較して異なっている、請求項9に記載の成形研磨粒子。
- 約1以下で、少なくとも約0.05の長さ係数(Ll1/Lc1)をさらに含む、請求項10に記載の成形研磨粒子。
- 前記第1の曲線区間および前記第1の直線区間は、鈍角を画定する入隅部を画定する、請求項8に記載の成形研磨粒子。
- 前記側面の第1の部分は、第1の入隅部及び第2の入隅部を備え、前記第1の入隅部及び前記第2の入隅部は、前記第1の曲線区間の両端で互いから離間しており、前記第1の入隅部は、前記第1の直線区間と前記第1の曲線区間との間の縁部に配置され、前記第2の入隅部は、前記第1の曲線区間と第2の直線区間との間の縁部に配置される、請求項8に記載の成形研磨粒子。
- 前記第1の曲線区間は、前記側面の第1の部分の全長(Lfp1)の小部分である第1の曲線区間の長さ(Lc1)を有し、0.95以下の長さ係数(Lc1/Lfp1)をさらに備える、請求項8に記載の成形研磨粒子。
- 前記第1の曲線区間は、凹んだ形状を画定する、請求項8に記載の成形研磨粒子。
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