CZ284448B6 - Povrchově aktivní prostředky obsahující lipasu a ve vodě rozpustné kvarterní ammoniové sloučeniny - Google Patents
Povrchově aktivní prostředky obsahující lipasu a ve vodě rozpustné kvarterní ammoniové sloučeniny Download PDFInfo
- Publication number
- CZ284448B6 CZ284448B6 CS931410A CS141093A CZ284448B6 CZ 284448 B6 CZ284448 B6 CZ 284448B6 CS 931410 A CS931410 A CS 931410A CS 141093 A CS141093 A CS 141093A CZ 284448 B6 CZ284448 B6 CZ 284448B6
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- CZ
- Czechia
- Prior art keywords
- alkyl
- weight
- water
- quaternary ammonium
- surfactant
- Prior art date
Links
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Classifications
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
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Abstract
Vynález se týká povrchově aktivních prostředků, obsahujících povrchově aktivní činidlo, ve vodě rozpustnou kvarterní ammoniovou sloučeninu obecného vzorce (i) nebo (ii), přičemž je tento prostředek charakterizován tím, že jako přídavnou látku obsahuje enzym lipasu. Uvedené kvarterní ammoniové soli jsou s výhodou vybrány z látek, kde R.sub.1 .n.je C.sub.12 .n.až C.sub.15 .n.alkyl a R.sub.2.n., R.sub.3 .n.a R.sub.4 .n.jsou s výhodou vybrány z methylových a hydroxyethylových skupin. Prostředky podle tohoto vynálezu mohou být ve formě granulí, kompaktních granulí nebo kapalné formě.
ŕ
Description
Oblast techniky
Vynález se týká detergentní směsi se zvýšenou prací schopností a účinkem proti úsadám. Je zvlášť vhodná k odstraňování nečistot obsahujících triglycerid.
Dosavadní stav techniky
Enzymatické povrchově aktivní prostředky jsou velmi dobře známé v dané oblasti techniky. Zvláště pak jsou popsány lipasy, jako vhodné enzymy pro povrchově aktivní prostředky, a to ve více publikacích; reprezentuje je například patent US 4 011 169, popisující použití lipas při přípravě aditiv pro prací prostředky, jakož i EP-A-205 208, EP-A-206 390 nebo EP-A 341 999, vždy vztahující se ke specifickým povrchově aktivním prostředkům, obsahujícím lipasu jako prostředek pro odstraňování znečištění.
Produkování lipasy z určitých mikroorganismů je popsáno například vEP-A-214 761 a EP-A 258 068.
Na druhé straně však projevují povrchově aktivní prostředky, obsahující při použití určité ve vodě rozpustné kvartemí ammoniové sloučeniny, schopnost čistit textilie a změkčovací vlastnosti, což je známo. Zvláště pak patent EP-A-26 529 popisuje takovéto povrchově aktivní prostředky, kde jsou přítomny určité ve vodě rozpustné kvartemí ammoniové sloučeniny, poskytující výhody za podmínek, používaných v továrnách při čištění a měkčení.
Nyní bylo zjištěno, že při kombinaci enzymů lipasy s některými určitými ve vodě rozpustnými kvartemími ammoniovými sloučeninami, dochází k neočekávanému zlepšení při odstraňování nečistot obsahujících triglycerid z látek, a že poskytované efekty ve vztahu protipůsobení na opětné zašpiňování, nebyly zatím dosahovány při žádném z výše uvedených případů.
Podstata vynálezu
Předmětem vynálezu je detergentní směs se zvýšenou prací schopností a účinkem proti úsadám na bázi povrchově aktivního činidla, ve vodě rozpustné kvartemí amoniové sloučeniny a enzymy, vyznačující se tím, že obsahuje enzym lipázu v množství 10 až 5000 lipázových jednotek spolu sl až 70% hmotnostních povrchově aktivního činidla, 0,1 až 10% hmotnostních ve vodě rozpustné kvartemí amoniové sloučeniny obecného vzorce I
R!R2R3R4N+X (I) ve kterém R] je C8.i6 alkyl nebo Rs-T-CO-Ré, kde T je O, NH nebo N-CM alkyl, R5 je divalentní C|.3 alkylen nebo -(C2H4O)m-, kde m je 1 až 8 a Ré je C12.]4 alkyl, R2, R3 a R4 značí jednotlivě Ci.4 alkyl nebo hydroxyalkyl, benzyl nebo ~(C2H4O)XH, kde X je 2 až 5, přičemž nanejvýš jeden ze substituentů R2, R3 a R, je benzyl a X je ve vodě rozpustný solitvomý anion a zbytek do 100 % hmotnostních směsi obvyklé přísady používané do detergentních směsí.
Detergentní směs podle vynálezu s výhodou obsahuje kvartemí amoniovou sůl vybranou ze solí, v nichž Rt je C12-14 alkyl a R2, R3 a R4 značí methyl nebo hydroxyethyl.
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Detergentní směs podle tohoto vynálezu obsahuje s výhodou povrchově aktivní aniontové číslo, jehož množství vzhledem k ve vodě rozpustné kvarterní amoniové sloučenině je větší než je hmotnostní poměr 1:1.
Předmětná detergentní směs je obvykle v granulované formě, kompaktní granulované formě nebo v kapalné formě.
Vhodnými kvartemími amoniovými sloučeninami shora uvedeného obecného vzorce I pro použití podle vynálezu mohou být například:
kokosový trimethylamoniumchlorid nebo bromid kokosový methyldihydroxyethylamoniumchlorid nebo bromid decyltriethylamoniumchlorid decyldimethylhydroxyethylamoniumchlorid nebo bromid C12 až C]5dimethylhydrixyethylammoniumchlorid nebo bromid kokosový dimethylhydroxyethylammoniumchlorid nebo bromid myristyltrimethylammoniummethylsulfat lauryldimethylbenzylammoniumchlorid nebo bromid lauryldimethyl(ethenoxy)4ammoniumchlorid nebo bromid cholinové estery (sloučeniny obecného vzorce (i) kde Rj je -CH2-O-C-C12-14 alkyl a R2R3R4
II o znamenají methyl) di-alkylimidazoliny I sloučeniny obecného vzorce (i) I.
Tyto výše uvedené ve vodě rozpustné kationtové komponenty v prostředcích podle tohoto vynálezu, jsou schopné existence v kationtové formě v 0,1% vodném roztoku při hodnotě pH 10.
Uvedené ve vodě rozpustné kationtové sloučeniny jsou přítomny v množství od 0,1% hmotnostních do 10 % hmotnostních, vztaženo na celkovou hmotnost uvedených povrchově aktivních prostředků.
Enzym lipasa
Uvedené zde prostředky obsahují enzym lipasu, který lze zvolit z široké oblasti lipas; lipasy jsou zejména popsány pro takovéto případy například v následujících patentových přihláškách: EP 0 214 761, EP 0 258 068, EP 0 205 208, EP 0 206 390. Vhodné jsou zvláště tyto komerčně dostupné Upasové preparáty: Novo Lipolase®, Amono lipases CE, P, B, AP, M-AP, AML a CES, a Meito lipases MY-30, OF, a LP, také esterase MM, Lipozym, SP225, SP285, Saiken lipase, Enzeco lipase, Toyo Jozo lipase a Diosynth lipase (tovární značky).
V genetickém inženýrství se u enzymů může dosáhnout pomocí extrakce vhodných genů lipasy, tj. genu pro lipasu z Humicola lanuginosa nebo z jejich mutantů, a zavedením a expresí genu nebo jeho derivátu do vhodného produkčního organismu jako je Aspergillus. Lze aplikovat a adaptovat způsoby, popsané v WO 88/02775 (Novo), EP 0 243 338 (Labofina) a EP 0 268 452 (Genencor).
V uvedeném prostředkuje daná lipasa přítomna v množství od 10 LU do 5000 LU/g prostředku. 1 LU je lipolytická aktivita, která se vztahuje na 1 mikromol titrovatelné kyseliny butyrové za jednu minutu za následujících podmínek:
teplota: 30 °C pH 7,0 substrát tributyrin (Podrobnosti byly publikovány v NOVO publikaci AF 95,4/1).
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Pokud je lipasa Lipolasa® 100 kLU, pohybuje se její úroveň typicky v rozmezí od 0,01 do 5 % hmotnostních, vztaženo na celkovou hmotnost uvedeného prostředku.
Povrchově aktivní činidlo
V povrchově aktivních prostředcích mohou být použity povrchově aktivní látky z velmi širokého rozmezí. Typický seznam aniontových, neiontových, amfolytických a tříd obojetných iontů a látek, náležejících k těmto povrchově aktivním látkám, je uveden v patentu US 3,664,961, podaném Norrisem dne 23. května 1972.
Zvláště vhodné jsou směsi aniontových povrchově aktivních látek, zejména sulfonatových a sulfátových povrchově aktivních látek v hmotnostním poměru od 5 : 1 do 1 : 2, s výhodou od 3 : 1 do 2 : 3, výhodněji od 3 : 1 do 1 : 1. Mezi výhodné sulfonaty patří alkyl benzen sulfonaty mající od 9 do 15, zejména od 11 do 13 atomů uhlíku v alkylovém radikálu, a alfa-sulfonatované methyl mastné kyseliny a to estery těchto kyselin, v nichž jsou mastné kyseliny odvozeny od Cn-Cig mastných zdrojových látek, s výhodou pak od Ci6-Ci8 mastných zdrojových látek.
V každém případě je kationtem alkalický kov, vybraný ze sodného mono- nebo polyethanolaminu nebo amonného mono- nebo polyethanolaminu. Výhodné sulfátové povrchově aktivní látky jsou alkyl sulfáty mající od 12 do 18 atomů uhlíku v alkylovém radikálu, popřípadě v příměsi sethoxy sulfáty majícími od 10 do 20, s výhodou od 10 do 16 atomů uhlíku v alkylovém radikálu a průměrný stupeň ethoxylace od 1 do 6. Mezi příklady vhodných alkyl sulfátů patří alkyl sulfát loje, alkyl sulfát kokosového oleje a C14.15 alkyl sulfáty. Kationtem je v každém případě vždy alkalický kov.
Jednu třídu neiontových povrchově aktivních látek podle tohoto vynálezu tvoří kondenzáty ethylenoxidu shydrofobní částí pro poskytnutí povrchově aktivních látek majících průměrnou rovnováhu hydrofilní - lipofilní (hydrophilic - lipophilic balance = HLB) v rozmezí od 8 do 17, s výhodou od 9,5 do 13,5, výhodněji od 10 do 12,5. Hydrofobní (lipofilní) část může být alifatické nebo aromatické povahy a délka dané polyoxyethylenové skupiny, která je kondenzována se zvláštní hydrofobní skupinou, může být snadno upravena pomocí ve vodě rozpustné sloučeniny mající požadovaný stupeň rovnováhy mezi hydrofilními a hydrofobními elementy.
Zvláště výhodnými typy neiontových povrchově aktivních látek jsou C9-C15 primární alkohol ethoxylanty obsahující tři až osm molů ethylenoxidu na mol alkoholu, zvláště C14-C15 primárních alkoholů obsahujících 6-8 molů ethylenoxidu na mol alkoholu a C12 - C14 primárních alkoholů obsahujících 3-5 molů ethylenoxidu na mol alkoholu.
Jinou třídu neiontových povrchově aktivních látek tvoří alkyl polyglukosidy obecného vzorce:
RO(CnH2nO)tZx kde Z je část odvozená od glukózy; R je nasycená hydrofobní alkylová skupina obsahující od 12 do 18 atomů uhlíku; t je od 0 do 10 a n je 2 nebo 3; x je od 1,3 do 4, sloučeniny zahrnují méně než 10% nezreagovaného mastného alkoholu a méně než 50% polyglukosidů s krátkým alkylovým řetězcem. Sloučeniny tohoto typu a jejich použití v povrchově aktivních látkách je popsáno v EP-B 0 070 077, 0 075 996 a 0 094 118.
Rovněž jsou jako neiontové povrchově aktivní látky vhodné póly hydroxy mastné kyseliny a to jejich amidy, obecného vzorce R2-C-N-Z kde R1 je H, hydrokarbyl, 2-hydroxyethyI, II I
O R1
2-hydroxypropyl nebo jejich směs, R2 je C5.31 hydrokarbyl, a Zje polyhydrokarbyl mající lineární hydrokarbylový řetězec s alespoň 3 hydroxyly přímo připojenými na tento řetězec, nebo
-3CZ 284448 B6 jejich směs, a to směs jejich alkoxylovaných derivátů. Výhodné je, jestliže je R1 methyl, R2 je Cn.|5 alkylový nebo alkenylový řetězec jako je alkyl kokosového oleje nebo jejich směs a Z je odvozeno od redukujícího cukru jako je glukóza, fruktóza, maltóza, laktóza, v reduktivní aminační reakci.
Další třídu povrchově aktivních látek tvoří semipolámí povrchově aktivní látky jako jsou aminooxidy. Vhodnými aminooxidy jsou takové, které jsou vybrány ze skupiny, tvořené mon C8-C20, s výhodou C10-C14 N-alkyl nebo alkenyl aminooxidů a propylen-l,3-diamindioxidů, kde jsou v poloze N substituovány methylem, hydroxyethylem nebo hydroxypropylem.
Jinou třídou uvedených povrchově aktivních látek jsou amfoterní povrchově aktivní látky jako jsou látky, založené na polyaminu.
Výhodné jsou směsi typů povrchově aktivních látek, více výhodné jsou pak směsi aniontové a neiontové. Uvedené povrchově aktivní prostředky mohou obsahovat od 1 do 70 % hmotnostních, vztaženo na celkovou hmotnost povrchově aktivní látky, ale obvykle je povrchově aktivní látka přítomna vdaném prostředku v množství od 1 % do 30% hmotnostních, výhodněji pak v množství od 10 % do 25 % hmotnostních.
Výhodné je, je-li molární poměr ve vodě rozpustné kvarterní amoniové sloučeniny ku aniontové povrchově aktivní látce menší než 1:1a žádoucí je, aby byl menší než 1 : 1,5. Ve výhodném provedení podle tohoto vynálezu je vhodné, aby byl molámí poměr menší než 1 : 2.
Optimální složky
Zde uvedený prostředek bude typicky tvořen tak, aby v sobě zahrnoval takové části, které normálně tvoří povrchově aktivní prostředky. Pro prostředek podle tohoto vynálezu je typické, že obsahuje detergentní (povrchově aktivní) plnivo.
Pro uvedené použití je vhodný jakýkoli systém plniv, který se konvenčně používá, včetně aluminosilikátových materiálů, silikátů, polykarboxylatů a mastných kyselin, materiálů jako je ethylendiamin, tetraacetat, maskovací činidla kovových iontů jako aminopolyfosfonaty, zvláště pak ethylentetramethylenfosfonitá kyselina a diethylentriaminpentamethylenfosfonitá kyselina. Ačkoli mohou být použity méně výhodné, a to z hlediska prostředí, systémy fosfátové.
Vhodnými plnivy mohou být anorganické látky pro výměnu iontů, společně s anorganickými hydratovanými aluminosilikátovými materiály, výhodněji pak hydratované syntetické zeolity, jako je hydratovaný zeolit A, X, B nebo HS.
Jinou výhodnou látkou pro plnění je vrstevnatý silikát, například SKS-6 (Hoechst). SKS-6-je krystalický vrstevnatý silikát, tvořený silikátem sodným (obsahuje Na2Si2O5).
Mezi vhodná polykarboxylanová plniva pro použití podle tohoto vynálezu patří kyselina citrónová, s výhodou ve formě ve vodě rozpustné soli, deriváty kyseliny jantarové obecného vzorce RCH(COOH)CH2(COOH) kde R znamená Clo.2o alkyl nebo alkenyl, s výhodou Ci2.i6, nebo R může být substituován hydroxylovým, sulfonovým, sulfoxylovým nebo sulfo substituentem. Specifickými příklady jsou lauryljantaran, myristyljantaran, palmityljantaran, 2dodecenyljantaran, 2-tetradecenyljantaran. Jantarové plniva se s výhodou používají ve formě svých ve vodě rozpustných solí, včetně solí sodných, draselných, amonných a alkanolamonných.
Jinými vhodnými polykarboxylaty jsou oxodijantarany a směsi tartaratmonojantarové a tartaratdijanatarové kyseliny jak je popsáno v patentu US 4,663,071.
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Zvláště pro kapalné provedení jsou vhodnými plnivy mastné kyseliny pro použití zde uvedené jsou pak vhodné nasycené nebo nenasycené Cio-ιs mastné kyseliny jakož i korespondující mýdla. Pro tento účel výhodné nasycené látky mají od 12 do 16 atomů uhlíku v alkylovém řetězci. Výhodnou nenasycenou mastnou kyselinou je kyselina olejová.
Mezi výhodné systémy plniv pro použití v granulovaných prostředcích patří směs ve vodě nerozpustných aluminosilikatových plniv, jako je zeolit A, a ve vodě rozpustných karboxylatových chelatačních činidel jako je kyselina citrónová.
Jiné materiály jako plniva, která mohou tvořit část uvedených systémů pro plniva pro použití podle tohoto vynálezu, jsou anorganické materiály jako jsou uhličitany alkalických kovů, hydrogenuhličitany alkalických kovů, silikáty alkalických kovů a anorganické materiály jako jsou organické fosfonaty a aminopolykarboxylaty.
Jinými ve vodě rozpustnými organickými solemi jsou homo- a ko-polymemí kyseliny nebo jejich soli, přičemž tyto polykarboxylové kyseliny obsahují alespoň dva karboxylové radikály, oddělené od sebe navzájem ne více než dvěma atomy uhlíku.
Polymery tohoto typu jsou popsány v patentu GB-A-1,596,756. Mezi příklady takových solí 20 patří polyakryláty MW 2000 až 5000 (tj. mající relativní molekulovou hmotnost od 2000 do 5000) a jejich kopolymery s maleinanhydridem, jako jsou kopolymery mající relativní molekulovou hmotnost od 20 000 do 70 000, zvláště pak 40 000.
V daném prostředku jsou povrchově aktivní plnivové soli obsažené běžně v množství od 10 % 25 hmotnostních do 80 % hmotnostních na celkovou hmotnost daného prostředku, s výhodou pak od do 70 % hmotnostních a nejvýhodněji od 30 % hmotnostních do 60 % hmotnostních, vždy vztaženo na celkovou hmotnost daného prostředku.
Mezi jiné optimální složky patří činidla měkčící tkaniny jako je smektická hlinka (kaolín), 30 případné polymery jako polyethylenoxidy, polyvinylpyrrolidony, polyvinylalkoholy, bělící činidla, bělicí aktivátory, supresory a jiné enzymy, vybrané ze skupiny, do níž patří proteosy, amylasové celulasyc, peroxidasy, oxidasy.
Forma prostředku
Uvedený prostředek může být v granulované formě a zvláště pak v kompaktní formě, tj. může mít relativně vysokou hustotu, tedy konvenční granulované povrchově aktivní prostředky podle tohoto vynálezu mohou obsahovat menší množství „anorganických plnicích solí“, v porovnání s konvenčními granulovanými povrchově aktivními látkami; typickými plnicími solemi jako solí 40 kovů alkalických zemin, a to sírany nebo chloridy, typicky pak síran sodný; „kompaktní“ detergenty typicky obsahují ne více než 10 % plnicích solí.
Uvedený prostředek může být také v kapalné formě, a potom obsahuje typické složky pro takovéto prostředky, jako jsou organická rozpouštědla, zvláště pak ethanol.
Dále budou uvedeny případy provedení tohoto vynálezu jako Příklady provedení, které však mají ilustrativní charakter a nijak neomezují obsah ani rozsah tohoto vynálezu.
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Příklady provedení vynálezu
Příklad 1
Připraví se následující povrchově aktivní prostředky:
| Složky | Složka A | % hmotnostní Složka B | Složka C | Příklad 1 |
| Sodná sůl lineárního dodecylbenzensulfonatu | 6,5 | 6,5 | 6,5 | 6,5 |
| Sodná sůl lojového alkobolsulfatu | 2,5 | 2,5 | 2,5 | 2,5 |
| Mastný alkohol (C]2-Ci5)ethoxylovaný (7 EO) | 5,5 | 5,5 | 5,5 | 5,5 |
| Sodná forma Zeolitu 4A | 25,0 | 25,0 | 25,0 | 25,0 |
| Perborat 4H2O | 20,0 | 20,0 | 20,0 | 20,0 |
| Tetraacetylhylendiamin | 3,5 | 3,5 | 3,5 | 3,5 |
| Sodná sůl uhličitanu | 10,0 | 10,0 | 10,0 | 10,0 |
| Bělidlo | 0,2 | 2,0 | 0,2 | 0,2 |
| Karboxymethylcelulóza | 0,5 | 0,5 | 0,5 | 0,5 |
| Ethylendiamintetraacetat | 0,3 | 0,3 | 0,3 | 0,3 |
| Kopolymer kyseliny akrylové a kyseliny | 2,5 | 2,5 | 2,5 | 2,5 |
| maleinové | ||||
| Kokosový dimethylhydroxyethylammonium | - | 1,5 | - | 1,5 |
| chlorid | ||||
| Lipasa (LipolaseR s 100 kLU) | - | - | 0,36% | 0,36% |
| Sodná sůl sulfátu | 9,3 | 9,3 | 9,3 | 9,3 |
| Menšina + voda | doplnění | bilance na | 100 |
Výše uvedené prostředky se porovnávají podle % odstranění zašpinění a podle efektu udržení bělosti.
% odstranění zašpinění se vyhodnocuje porovnáváním měřené reflektance látky, zašpiněné olivovým olejem, přičemž je tato látka zbarvena barvou Sudan red, a to porovnáním uvedené reflektance před a po vyprání; způsob je následující:
Aby bylo lépe znatelné, nakolik se odstraní znečištění olivovým olejem, je zkoumaný vzorek obarven barvivém Sudan red (v oleji rozpustné barvivo). Potom se měří % odstranění zašpinění určením hodnot reflektance.
Pro ověření takto získaných hodnot reflektance (koncentrace Sudan red) se provádí korelace s aktuálním odstraněním olivového oleje, který se odstraňuje extrakcí před a po vybrání. Měření extraktů se provádí dvěma způsoby: gravimetricky a pomocí infračervené spektroskopie (1735 cm1).
Výsledky jsou následující:
| Reflektance | % odstranění zašpinění | |
| Gravimetricky | Infračervenou spektroskopií | |
| 21 | 19,4 | 21,6 |
Efekt držení bělosti koresponduje s opakovaným vystavováním zašpinění jako procenta odstranění zašpinění. Počítá se podle vztahu:
-6CZ 284448 B6 % opakovaného zašpiňování x 100 % odstranění zašpinění
Tento efekt se pro daný účel monitoruje, stanovuje se reflektance u neznečištěných a znečištěných vzorků.
Podmínky testu jsou následující:
ío Zařízení - Lauderometer
Zahřívání během cyklu - 40 °C
Koncentrace povrchově aktivní látky - 6 g/1
Tvrdost vody - 2,5 mmol/1 Promývací kapalina - 200 ml
Zatížení - 6 polyesterových vzorků tkaniny 7 x 7 cm (3 g) z nich vzorky tkaniny se znečistí 50 ml olivového olej vzorky tkaniny se neznečistí
Počet cyklů - 2
Výsledky jsou následující:
| Prostředek | % odstranění znečištění | efekt udržení bělosti |
| A | 57 | 26 |
| B | 62 | 33 |
| C | 71 | 31 |
| Příklad 1 | 78 | 18 |
Diskuse výsledků:
Výsledky jasně dokázaly výborné vlastnosti prostředku podle tohoto vynálezu (Příklad 1) podle hodnoty veličiny % odstranění znečištění (znečištění obsahovalo triglyceridy) a veličiny efektu udržení bělosti.
Synergický efekt:
% odstranění znečištění a efekt udržení bělosti se porovnává s Příkladem las celkovými výsledky prostředků B a C:
| Prostředek | % odstranění znečištění efekt udržení bělosti (diference v porovnání se zpracováním A) |
| Příklad 1 B + C | + 21 -8 + 19 +2 |
Výše uvedené výsledky prokazují, že výsledek podle Příkladu 1 prokazuje vyšší účinek než jen přídavný a tím dokazuje existenci synergie.
(Uvedená % odstranění znečištění se zvyšují a % opětného zašpiňování se snižují (WM)).
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Dále byly též připraveny následující povrchově aktivní prostředky: (ve sloupcích na levé straně se uvádí prostředek, % hmotnostní)
| Složky | Prostředek (% hmotnostní) | ||
| Příkl. 2 granulovaný | Příkl. 3 kompaktní granule | Příkl. 4 kapalný | |
| Cn-i2alkylbenzensufonat | 4 | - | 10 |
| Alkoholsulfat (Na) lůje | - | 2 | - |
| Ci4_i5alkylsulfat (Na) | 3 | 6 | 1 |
| Alkoholethoxylat (EOn) lůje | 0,5 | - | - |
| Mastný alkohol (Ci2.i5)ethoxylat (EO7) | 3 | 4 | 7 |
| C12.i5dimethyl(hydroxyethyl) amonium chlorid | 5 | - | 1,5 |
| Kokosový dimethyl(hydroxyethyl) ammonium | - | 3 | - |
| chlorid | |||
| Zeolit A | 20 | 19 | - |
| Citrát sodný | 5 | 6 | - |
| Mastná kyseliny olejová | 1 | ||
| Kyselina citrónová | 2 | ||
| Ci4_i6alkyl jantaran | 10 | ||
| 1,2-Propandiol | 3 | ||
| Ethanol | 7 | ||
| Methaboratoktahydrat sodný | 1 | ||
| Polyethylenoxid, relativní molekulová | 0,3 | - | |
| hmotnost 0,3 MM | |||
| Síran sodný | 15 | 2 | |
| Uhličitan sodný | - | 11 | |
| Silikát sodný | 4 | 3 | |
| Natriumperbora (1 aq.) | 18 | 12 | |
| Ν,Ν,Ν,Ν-Tetraacetylendiamin | - | 3 | |
| CMC | 0,3 | 0,3 | |
| Polyakrylat (MW 4000-5000) | 3 | - | |
| Kopolymer malein-akrylový | - | 4 | |
| Lipasa (Lipolase® 100 kLU) | 0,4 | 0,5 | 1 |
| Smektická/montmorillonitová hlinka | 10,5 | 12 | 4 |
| Příměs a sprejování (parfémy, proteasa a/nebo | bilanční | bilanční | bilanční |
| anylasa, cellulasa, peroxidasa, pufr, supresor, | doplnění | doplnění | doplnění |
| různorodé příměsi, vlhkost a menšinové látky) | do 100 | do 100 | do 100 |
Průmyslová využitelnost
Povrchově aktivní prostředky podle tohoto vynálezu, mající zlepšené vlastnosti vůči odstraňování znečištění, jsou velmi zajímavé též z hlediska možnosti průmyslového využití, především 10 v textilní výrobě.
Claims (4)
1. Detergentní směs se zvýšenou prací schopností a účinkem proti úsadám na bázi povrchově aktivního činidla, ve vodě rozpustné kvartemí amoniové sloučeniny a enzymu, vyznačující se tím, že prostředek obsahuje enzym lipázu v množství 10 až 5000 lipázových jednotek spolu s 1 až 70 % hmotnostních povrchově aktivního činidla, 0,1 až 10 % hmotnostních ve vodě rozpustné kvarterní amoniové sloučeniny obev ho vzorce I (I) ve kterém Ri je C8.i6 alkyl nebo Rs-T-CO-Re, kde T je 0, NH nebo N-CM alkyl, R5 je divalentní C]_3 alkylen nebo kde m je 1 až 8 a R^ je C12-14 alkyl, R2, R3 a R4 značí jednotlivě
Cu alkyl nebo hydroxyalkyl, benzyl nebo -(CJFLOjxH, kde x je 2 až 5, přičemž nanejvýše jeden ze substituentů R2, R3 a R4 je benzyl a X' je ve vodě rozpustný solitvomý anion a zbytek do 100 % hmotnostních směsi obvyklé přísady používané do detergentních směsí.
2. Detergentní směs podle nároku 1, vyznačující se tím, že obsahuje kvartemí amoniovou sůl vybranou ze solí, v nichž R] je C1244 alkyl a R2, R3 a R4 značí methyl nebo hydroxyethyl.
3. Detergentní směs podle nároků 1 a 2, vyznačující se tím, že obsahuje povrchově aktivní činidlo, jehož množství vzhledem k ve vodě rozpustné kvartemí amoniové sloučenině je větší než je hmotnostní poměr 1:1.
4. Detergentní směs podle nároků laž3, vyznačující se tím, že je v granulované formě, kompaktní granulované formě nebo kapalné formě.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP91870006.3A EP0495344A1 (en) | 1991-01-16 | Compact detergent compositions | |
| PCT/US1992/000073 WO1992013054A1 (en) | 1991-01-16 | 1992-01-16 | Detergent compositions containing lipase and water-soluble quaternary ammonium compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CZ141093A3 CZ141093A3 (en) | 1994-03-16 |
| CZ284448B6 true CZ284448B6 (cs) | 1998-12-16 |
Family
ID=8209007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS931410A CZ284448B6 (cs) | 1991-01-16 | 1992-01-16 | Povrchově aktivní prostředky obsahující lipasu a ve vodě rozpustné kvarterní ammoniové sloučeniny |
Country Status (22)
| Country | Link |
|---|---|
| EP (3) | EP0495258A1 (cs) |
| JP (1) | JP2996726B2 (cs) |
| KR (1) | KR100229561B1 (cs) |
| AT (1) | ATE219136T1 (cs) |
| AU (1) | AU661672B2 (cs) |
| BR (2) | BR9205451A (cs) |
| CA (1) | CA2100097A1 (cs) |
| CZ (1) | CZ284448B6 (cs) |
| DE (1) | DE69133035T2 (cs) |
| ES (1) | ES2174820T3 (cs) |
| FI (1) | FI933224A0 (cs) |
| HU (1) | HU212981B (cs) |
| IE (1) | IE920118A1 (cs) |
| MA (1) | MA22389A1 (cs) |
| NO (1) | NO304235B1 (cs) |
| PL (1) | PL172961B1 (cs) |
| PT (1) | PT100030B (cs) |
| RU (1) | RU2108374C1 (cs) |
| SG (1) | SG52693A1 (cs) |
| SK (1) | SK72493A3 (cs) |
| TW (1) | TW260704B (cs) |
| WO (3) | WO1992013053A2 (cs) |
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| JPS61276897A (ja) * | 1985-05-31 | 1986-12-06 | 花王株式会社 | 洗浄剤組成物 |
| DK163591C (da) * | 1985-10-08 | 1992-08-24 | Novo Nordisk As | Fremgangsmaade til behandling af et tekstilstof med en cellulase |
| GB8525269D0 (en) * | 1985-10-14 | 1985-11-20 | Unilever Plc | Detergent composition |
| US4637890A (en) * | 1986-01-23 | 1987-01-20 | The Procter & Gamble Company | Detergent composition providing rinse cycle suds and turbidity control containing a soap, quaternary ammonium salt and a silicone |
| US4806260A (en) * | 1986-02-21 | 1989-02-21 | Colgate-Palmolive Company | Built nonaqueous liquid nonionic laundry detergent composition containing acid terminated nonionic surfactant and quarternary ammonium softener and method of use |
| JP2787941B2 (ja) * | 1986-09-12 | 1998-08-20 | 花王株式会社 | 酵素含有高密度粒状洗剤組成物 |
| GB8627914D0 (en) * | 1986-11-21 | 1986-12-31 | Procter & Gamble | Softening detergent compositions |
| GB8627915D0 (en) * | 1986-11-21 | 1986-12-31 | Procter & Gamble | Detergent compositions |
| US4822516A (en) * | 1986-12-08 | 1989-04-18 | Kao Corporation | Detergent composition for clothing incorporating a cellulase |
| GB8629536D0 (en) * | 1986-12-10 | 1987-01-21 | Unilever Plc | Enzymatic detergent composition |
| DE3704465C2 (de) * | 1987-02-13 | 1995-11-02 | Roehm Gmbh | Flüssig-Formulierungen von Enzymen |
| MY103738A (en) * | 1987-06-30 | 1993-09-30 | Procter & Gamble | Detergent/softening compositions containing hectorite clays |
| US4931195A (en) * | 1987-07-15 | 1990-06-05 | Colgate-Palmolive Company | Low viscosity stable non-aqueous suspension containing organophilic clay and low density filler |
| GB8727081D0 (en) * | 1987-11-19 | 1987-12-23 | Procter & Gamble | Granular detergent compositions |
| GB8727659D0 (en) * | 1987-11-26 | 1987-12-31 | Unilever Plc | Machine dishwashing compositions |
| US4844821A (en) * | 1988-02-10 | 1989-07-04 | The Procter & Gamble Company | Stable liquid laundry detergent/fabric conditioning composition |
| WO1989008694A1 (en) * | 1988-03-14 | 1989-09-21 | Novo-Nordisk A/S | Granulate detergent enzyme product, method for production thereof, use thereof, and detergent containing such product |
| WO1989009259A1 (en) * | 1988-03-24 | 1989-10-05 | Novo-Nordisk A/S | A cellulase preparation |
| GB8815975D0 (en) * | 1988-07-05 | 1988-08-10 | Procter & Gamble | Method for evaluating detergent cellulases |
| JPH0633439B2 (ja) * | 1988-07-28 | 1994-05-02 | 花王株式会社 | 高密度粒状濃縮洗剤組成物 |
| DE68925938T2 (de) * | 1988-11-02 | 1996-08-08 | Unilever Nv | Verfahren zur Herstellung einer körnigen Reinigungsmittelzusammensetzung mit hoher Schüttdichte |
| GB8826110D0 (en) * | 1988-11-08 | 1988-12-14 | Unilever Plc | Enzyme-containing detergent compositions |
| US4973422A (en) * | 1989-01-17 | 1990-11-27 | The Procter & Gamble Company | Perfume particles for use in cleaning and conditioning compositions |
| GB8902009D0 (en) * | 1989-01-30 | 1989-03-22 | Unilever Plc | Particulate detergent compositions and their use |
| GB8902286D0 (en) * | 1989-02-02 | 1989-03-22 | Bp Chem Int Ltd | Detergent formulations |
| US5002681A (en) * | 1989-03-03 | 1991-03-26 | The Procter & Gamble Company | Jumbo particulate fabric softner composition |
| FI921662L (fi) * | 1989-10-19 | 1992-04-14 | Genencor Int | Slitageminskande detergen- kompositioner. |
| EP0517762B1 (en) * | 1990-03-01 | 1993-12-08 | Novo Nordisk A/S | Process for treatment of textiles |
| JP3110452B2 (ja) * | 1990-05-09 | 2000-11-20 | ノボ ノルディスク アクティーゼルスカブ | エンドグルカナーゼ酵素を含んでなるセルラーゼ調製物 |
-
1991
- 1991-11-06 DE DE69133035T patent/DE69133035T2/de not_active Expired - Lifetime
- 1991-11-06 SG SG1996007961A patent/SG52693A1/en unknown
- 1991-11-06 AT AT91202879T patent/ATE219136T1/de not_active IP Right Cessation
- 1991-11-06 EP EP91202880A patent/EP0495258A1/en not_active Withdrawn
- 1991-11-06 ES ES91202879T patent/ES2174820T3/es not_active Expired - Lifetime
- 1991-11-06 EP EP91202879A patent/EP0495257B1/en not_active Expired - Lifetime
-
1992
- 1992-01-13 WO PCT/US1992/000190 patent/WO1992013053A2/en active Application Filing
- 1992-01-15 WO PCT/US1992/000203 patent/WO1992013057A1/en active Application Filing
- 1992-01-15 IE IE011892A patent/IE920118A1/en unknown
- 1992-01-15 MA MA22674A patent/MA22389A1/fr unknown
- 1992-01-15 BR BR9205451A patent/BR9205451A/pt not_active IP Right Cessation
- 1992-01-16 WO PCT/US1992/000073 patent/WO1992013054A1/en not_active Application Discontinuation
- 1992-01-16 CZ CS931410A patent/CZ284448B6/cs not_active IP Right Cessation
- 1992-01-16 EP EP92904540A patent/EP0646165A1/en not_active Ceased
- 1992-01-16 BR BR9205427A patent/BR9205427A/pt not_active Application Discontinuation
- 1992-01-16 CA CA002100097A patent/CA2100097A1/en not_active Abandoned
- 1992-01-16 RU RU93052400A patent/RU2108374C1/ru active
- 1992-01-16 SK SK724-93A patent/SK72493A3/sk unknown
- 1992-01-16 PT PT100030A patent/PT100030B/pt not_active IP Right Cessation
- 1992-01-16 FI FI933224A patent/FI933224A0/fi unknown
- 1992-01-16 AU AU12305/92A patent/AU661672B2/en not_active Ceased
- 1992-01-16 KR KR1019930702124A patent/KR100229561B1/ko not_active Expired - Fee Related
- 1992-01-16 HU HU9302065A patent/HU212981B/hu not_active IP Right Cessation
- 1992-01-16 JP JP50445392A patent/JP2996726B2/ja not_active Expired - Lifetime
- 1992-01-16 PL PL92300105A patent/PL172961B1/pl unknown
- 1992-04-09 TW TW081102736A patent/TW260704B/zh active
-
1993
- 1993-07-12 NO NO932527A patent/NO304235B1/no unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| IF00 | In force as of 2000-06-30 in czech republic | ||
| MM4A | Patent lapsed due to non-payment of fee |
Effective date: 20010116 |