CN102160145B - 通过外延层过成长的元件形成 - Google Patents

通过外延层过成长的元件形成 Download PDF

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CN102160145B
CN102160145B CN2009801365471A CN200980136547A CN102160145B CN 102160145 B CN102160145 B CN 102160145B CN 2009801365471 A CN2009801365471 A CN 2009801365471A CN 200980136547 A CN200980136547 A CN 200980136547A CN 102160145 B CN102160145 B CN 102160145B
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conducting material
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詹姆斯·费兰札
安东尼·罗特费尔德
白杰
朴志洙
珍妮佛·海翠克
李继忠
陈志源
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Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Abstract

本发明提供了用于通过使用深宽比捕捉(ART)与外延侧向成长(ELO)技术在包括如晶格失配材料的基板上形成如太阳能电池的装置的方法与结构。一般地,在一第一方面中,本发明的实施例可包括一种形成结构的方法。该方法包括在设置于包括一第一半导体材料的一基板上方的一掩模层内形成一第一开口。在该第一开口内形成包括晶格失配于该第一半导体材料的一第二半导体材料的一第一膜层。该第一膜层具有足够延伸至高于该掩模层的一顶面的一厚度。在该第一膜层上以及该掩模层的至少一部分上方形成包括该第二半导体材料的一第二膜层。该第一膜层的垂直成长速率高于该第一膜层的一侧向成长速率,而该第二膜层的一侧向成长速率高于该第二膜层的一垂直成长速率。

Description

通过外延层过成长的元件形成
相关申请案的交叉引用
本申请案主张2008年9月19日申请的编号US 61/098,597的标题为“Formation of Devices by Epitaxial layer Overgrowth”的美国临时申请案、2008年9月22日申请的编号US 61/099,074的标题为“Light Emitting DevicesFormed with Aspect Ration Trapping and Epitaxial Lateral Overgrowth”的美国专利申请案、以及2008年10月14日申请的编号US 61/104,466的标题为“Hybrid Applications Using Aspect-Ration Trapping,Epitaxial-layerOvergrowth,and Wafer Bonding”的美国申请案的优先权,且其全部内容援引参考于此,并主张其优先权日。
技术领域
本发明涉及包括半导体结晶材料的制作或结构。举例来说,可在包括一半导体结晶材料的一平坦化表面上形成经改善的外延成长情形或结构。
背景技术
本部分提供了背景信息并介绍了在下文中及/或在权利要求中所描述的关于本案多个方面的相关信息。这些背景的陈述并非承认其为现有技术。
进行基板图案化的相关技术利用了贯穿差排(threading dislocation)受到几何学限制的事实,即结晶物内的差排行为(dislocation)并不会停止。当通过图案化基板以形成更小的成长区域时将使得一自由边(free edge)更接近另一自由边,因而能够降低贯穿差排的密度。在过去技术中,基板的图案化以及外延侧向成长(epitaxial lateral overgrowth,ELO)技术的结合已证明了可极大地降低氮化镓装置(gallium nitride device)内的缺陷密度(defect densities),从而制作出寿命更长的激光二极管(laser diodes)。上述处理工艺大体消除了在外延侧向成长ELO区域内的缺陷但留下了高度劣化的晶种窗(seed window),因而需要重复(repetition)微影(lithography)与外延的步骤以消除所有缺陷。在一相似方法中,悬空外延(pendeo-epitaxy)技术大体消除了在邻近基板的外延区域内的所有缺陷,但其仍需要一次的微影步骤与两次的外延成长步骤。再者,上述两项技术需要提高氮化镓侧向成长速度,其在目前所有的异质外延系统(heteroepitaxial systems)中尚未得到验证。
称为“外延颈缩”的另一已知技术则为Langdo等人揭示于“High QualityGe on Si by Epitaxial Necking”,Applied Physics Letters,Vol.76,No.25,April2000.的文献所相关的位于硅上的锗的异质结构(Ge-on-Si heterostructure)的制作中。上述方法提供了通过利用选择性外延成长(selective epitaxial growth)与缺陷结晶学(defect crystallography)的结合的一简化处理,以使得缺陷仅抵达位于图案化掩模内的开口的侧壁,而上述方法不会依靠侧向成长速率的增加。更明确地,在(111)<110>钻石立方滑移系统(diamond cubic slip system)中,错配差排(misfit dislocations)沿着(100)成长平面的<110>方向而延伸,而贯穿片段(threading segments)以<110>方向产生在(111)平面上。位于(111)平面上沿着<110>方向的贯穿片段以相对于下方的硅(100)基板表面的45度角进行延伸。因此,当位于图案化掩模层内的孔洞的深宽比(aspect ratio)大于1时,贯穿片段会被掩模侧壁所阻挡,造成直接形成在硅之上的低缺陷的上方锗突出物(Ge nodules)。外延颈缩的重要限制之一为其所施行的区域的尺寸。一般来说,如下文中的更详细讨论中所述,在尺寸内的侧向尺寸需要相对较小,以使得上述差排可终止在侧壁处。
如此,该领域中便需要一种用于制作半导体异质结构(semiconductorheterostructure)的多功能且有效的方法,其可抑制位于不同晶格失配材料系统(lattic-mismatched materials systems)中的差排缺陷。且该领域中也需要一种利用具有较低差排缺陷程度的整合型晶格失配材料以改善功能性与性能的半导体装置。
发明内容
为了解决上述问题,本发明提供了用于通过使用深宽比捕捉(aspectration trapping,ART)与外延侧向成长(ELO)技术在包括如晶格失配材料的基板上形成如太阳能电池的装置的方法与结构。
一般地,在一第一方面中,本发明的实施例可包括一种形成结构的方法。该方法包括在设置于包括一第一半导体材料的一基板上的一掩模层内形成一第一开口。在该第一开口内形成包括晶格失配于该第一半导体材料的一第二半导体材料的一第一膜层。该第一膜层具有足够延伸至高于该掩模层的一顶面的一厚度。在该第一膜层之上以及该掩模层的至少一部分之上形成包括该第二半导体材料的一第二膜层。该第一膜层的垂直成长速率高于该第一膜层的一侧向成长速率,而该第二膜层的一侧向成长速率高于该第二膜层的一垂直成长速率。
上述方法可包括一个或多个下述特征。在形成该第一膜层之前,可在该掩模层中形成一第二开口,以及在形成该第二膜层之前,可在该第二开口内形成该第一膜层。在该第二膜层之上可形成包括该第二半导体材料的一第三膜层。该第三膜层可接合在该第一开口与该第二开口之间。
在该第一膜层内的差排缺陷可在该第一开口内而被捕捉到。可通过在形成该第一膜层时掺杂该第一膜层提高该第一膜层的该垂直成长速率。可通过在形成该第一膜层时掺杂该第一膜层减缓该第一膜层的该侧向成长速率。可在形成该第一膜层时通过调整用于该第一膜层的一顶面上形成晶面的成长参数降低该第一膜层的该侧向成长速率。降低该第二膜层的该垂直成长速率可包括在形成该第二膜层时掺杂该第二膜层。
降低该第二膜层的该垂直成长速率可包括在形成该第二膜层时掺杂该第二膜层以在该第二膜层内形成第一类型的晶面并抑制在该第二膜层内一第二类型的晶面的形成。增加该第二膜层的侧向成长速率可包括在形成该第二膜层时掺杂该第二膜层。在形成该第三膜层时掺杂该第三膜层可促进该第三膜层的接合。在形成该第三膜层时掺杂该第三膜层可促进该第一开口与该第二开口之间的该第三膜层的接合。
掺杂该第三膜层可减缓该第三膜层内的晶面成长并降低了在第三膜层内的堆叠错误的形成。该第二半导体材料可包括锗。该第二半导体材料可包括p型掺质。形成至少该第一、第二或第三膜层其中之一可包括外延成长。形成该第一膜层可包括使用四氯化锗作为一前趋物。上述方法还可包括在形成该第三膜层后移除该第三膜层的一顶部(top portion)以移除缺陷。上述方法还可包括在该顶部移除之后形成一光学装置在该第三膜层之上。该第一膜层的一顶部可定义了与该基板的一顶面不平行的一晶面。该第三膜层可自我平坦化。该第三膜层可通过主要地(primarily)在一(100)方向上成长该第三膜层而自我平坦化。
上述方法还可包括在该第三膜层的顶部形成一第四膜层,该第四膜层包括一第三半导体材料。在该第四膜层的顶部形成一第五膜层,该第五膜层包括一第四半导体材料。可将一握持晶片接合至该第五膜层且可移除该基板。该第三半导体材料与该第四半导体材料分别可包括III-V族材料。该基板可包括硅。该握持晶片可包括金属。该第三半导体材料的能隙可高于该第四半导体材料的能隙。该半导体结构可包括一多结(multi-junction)光电电池。
一般地,在另一方面中,本发明的实施例可提供一种结构的形成方法。此方法包括在设置于一基板上的一掩模层之内形成具有一宽度w1的一开口,该基板包括一第一半导体材料。在该开口内形成包括晶格失配于该第一半导体材料的一第二半导体材料的一第一膜层,该第一膜层垂直延伸至高于该掩模层的一顶面且侧向延伸至大于宽度w1的一宽度w2。移除该第一膜层的一部分,而该第一膜层的一剩余部分具有高于邻近于该开口的该基板的一第一区的一厚度t1。在该第一膜层上形成包括该第二半导体材料的一第二膜层,该第二膜层侧向延伸至大于宽度w2的一宽度w3。移除该第二膜层的一部分,该第二膜层的一剩余部分具有高于邻近于该开口的该基板的一第二区的一厚度t2
上述方法还可包括一或多个下述特征。在多个实施例中,t1等于t2。移除该第一膜层的该部分可包括至少蚀刻或化学机械研磨其中之一。形成该第一膜层与移除该第一膜层的该部分的步骤可在不同机台中实施。形成该第一膜层与移除该第一膜层的该部分的步骤可在同一机台中实施。在该第二半导体材料内的差排缺陷在该开口内被捕捉到。高于该基板的表面的该第一膜层的一部分可基本上不具有差排缺陷。该第二半导体材料的一垂直成长速率可大于该第二半导体材料的一侧向成长速率。
该开口的一侧壁可包括一介电材料。外延成长可用作形成至少该第一材料与该第二材料其中之一。上述方法还可包括使用四氯化锗作为一前趋物形成该第一膜层,在形成该第二膜层之后移除该第二膜层的顶部,及/或在该第二膜层上形成一光电装置。该第一膜层的一顶部可定义了与该基板的一顶面不平行的一晶面。该第二膜层可自我平坦化。该第二膜层可通过主要地依照(100)方向成长该第二膜层而自我平坦化。
上述方法还可包括在该第二膜层的顶部形成一第三膜层,该第三膜层包括一第三半导体材料。可在该第三膜层的顶部形成一第四膜层,该第四膜层包括一第四半导体材料。可将一握持晶片接合至该第四膜层并移除该基板。该第三半导体材料与该第四半导体材料可包括III-V族材料,该基板可包括硅,以及该握持晶片可包括金属。该第三半导体材料的能隙可高于该第四半导体材料的能隙。上述半导体结构可包括一多结光电电池。
一般地,在又一方面中,本发明的实施例可包括一种形成膜层的方法。该方法包括在设置于一基板上的一掩模层内形成一第一开口。在该第一开口内形成包括立方半导体材料的第一膜层。在该第一膜层之上形成也包括该立方第一半导体材料的一第二膜层。该第一膜层的一垂直成长速率高于该第一膜层的一侧向成长速率,且该第二膜层的侧向成长速率高于该第二膜层的一垂直成长速率。
上述方法的实施例还可包括在形成该第一膜层之前,在该掩模层内形成一第二开口。在形成该第二膜层之前,可在该第二开口内形成一第一膜层。该第二膜层可接合在该第一开口与该第二开口之间。该掩模层可包括一介电材料。在该基板内的该第一开口可包括(110)晶面,且该基板可包括硅。上述方法还可包括在该第一开口内捕捉该第一膜层中的差排缺陷。该第二膜层的垂直成长速率的降低以及该第二膜层的该侧向成长速率的增加可包括改变成长条件。成长条件可包括0.1大气压和750℃。
上述立方半导体材料可包括锗、砷化镓、磷化铟或其他III-V族材料。该立方半导体材料可经过掺杂。在该第一膜层内的缺陷可在该开口内被捕捉。可在该第二膜层内形成一装置。该装置可为一光电装置。该第二膜层的一顶部可经过蚀刻。该第一膜层的一顶部可定义不平行于该基板的一顶面的一晶面。该第二膜层可自我平坦化。该第二膜层可通过主要地依照(100)方向成长该第二膜层而自我平坦化。
上述方法还包括形成一第三膜层在该第二膜层的顶部,该第三膜层包括一第三半导体材料。可形成一第四膜层在该第三膜层的顶部,该第四膜层包括一第四半导体材料。可将一握持晶片接合至该第四膜层并可移除该基板。该第三半导体材料与该第四半导体材料可包括III-V族材料,该基板可包括硅,而该握持晶片可包括金属。该第三半导体材料的能隙可高于该第四半导体材料的能隙。上述结构可包括一多结光电电池。
附图说明
本发明一般概念的这些及/或其他方面及效用可通过实施例的下述描述并结合附图而变得明显或更容易地被理解,其中:
图1为显示了利用在沟槽内使用深宽比捕捉技术(ART)并通过掺质的使用进行控制的外延侧向成长(ELO)的一剖面情形的图示;
图2为显示了利用具有在沟槽内使用深宽比捕捉技术(ART)重复移除与再成长膜层的外延侧向成长(ELO)的一剖面情形的图示;
图3为显示了利用在沟槽内使用深宽比捕捉技术(ART)的立方半导体材料的外延侧向成长(ELO)的剖面情形的图示;
图4为显示了使用深宽比捕捉(ART)与外延侧向成长(ELO)技术所形成的太阳能电池的剖面情形的图示;
图5a与图5b为显示了成长在锗的深宽比捕捉(ART)与外延侧向成长(ELO)基板上的反向型太阳能电池的剖面情形的图示。
具体实施方式
在2008年6月26日申请的编号第12/147,027号以及标题为“Multi-Junction Solar Cell”的美国专利申请案中详细描述了包括剥离(lift-off)技术的基本的深宽比捕捉(aspect ratio trapping,ART)处理。在2008年7月25日申请的编号第12/180,254号以及标题为“Lattice-mismatchedsemiconductor structures with reduced dislocation defect densities and relatedmethods for device fabrication”的美国专利申请案中则描述了使用ART技术以形成太阳能电池(solar cells)。
如图1所示,本发明的实施例应用了外延侧向成长(epitaxial lateralovergrowth,ELO)技术,其中该ELO可通过掺质的使用得到控制。其可通过使用晶面控制(control of faceting)以在晶片上施行外延侧向成长。晶面(faceting)则可通过如改变材料内的掺质程度、改变成长温度、改变成长压力、改变前趋物气体流率及/或改变前趋物的化学物组成而得到控制。晶面的较佳控制可具有至少两个目的:(i)为了于一既定垂直成长中增加外延侧向成长内的侧向成长,以及(ii)为了降低在接合(coalescence)时的堆叠错误(stackingfaults)或差排(dislocations)情形。在一实施例中,位于具(100)晶面的硅晶片上且形成在具(110)晶面的沟槽内的锗的晶面可通过公知晶面表现而得到控制。以上相同技术也可应用至其他材料或晶格方向的应用。以上所示出的实施例显示了在深宽比捕捉(ART)与外延侧向成长(ELO)技术的结合中的晶面控制应用,但上述技术亦可仅应用外延侧向成长中。
如图2所示,本发明的其他实施例的应用了具有膜层的重复移除与再成长的外延侧向成长。外延侧向成长为用于成长失配外延(mismatched epitaxy)的技术。最大侧向成长宽度可为薄膜的最大允许厚度所限制。侧向成长宽度可通过重复地薄化与再成长此薄膜而增加。上述的薄化与再成长步骤可在不同机台内施行,或可在相同机台内施行。此技术可使用深宽比捕捉(ART)或传统外延侧向成长(ELO)技术。
如图3所示,本发明的其他实施例提供用于立方半导体材料(cubicsemiconductor materials)的有效外延侧向成长的方法。GaN与其他III-N族半导体皆具有六方结晶(hexagonal crystal)结构。对于如锗(Ge)的立方半导体材料或如砷化镓(GaAs)或磷化铟(InP)的III-V族材料而言目前尚未发现有利于水平成长速率(GR水平)与垂直成长速率(GR垂直)间的高比率(GR水平/GR垂直)的条件。上述事实使得外延侧向成长的使用变得较为困难。可能的解决方案之一为选择性地控制垂直与水平成长速率。在一实施例处理中,可采用具(110)晶面的基板,例如为(110)晶面的硅。可在上述基板之上沉积一绝缘物并图案化之。例如,在传导给垂直成长和水平成长的成长条件下成长锗(Ge)或III-V族立方材料。接着,将参数切换为允许在<110>方向上几乎无成长但是在垂直于<110>方向的方向(如<111>方向)上有显著成长的成长条件。请参照Noborisaka等人于Applied Physics Letters 86 213102(2005)以及Noborisaka等人于Applied Physics Letters 87093109(2005)等文献的揭示情形。在此的关键是使用了具(110)晶面的基板。如此便实际上允许了由高GR垂直/GR水平改变至高GR水平/GR垂直,如此较有利于外延侧向成长的实施。
如图4所示,本发明的实施例包括了使用深宽比捕捉与外延侧向成长技术形成太阳能电池。图4显示了应用锗材料的深宽比捕捉与外延侧向成长(GeART+ELO)以替代传统多结结构中所使用的锗基板。在传统结构中,可在一锗晶片上成长GaAs p/n结以及InGaP p/n结。InGaP膜层的p/n结具有高能隙(1.8eV)且可收集最高能量的光线,而GaAs的p/n结(1.4eV)则具有一中阶能隙且可收集中能量的光线。在传统结构中,最低能量的光线则由形成在锗晶片的顶部上的锗的p/n结所收集。
当使用锗的深宽比捕捉与外延侧向成长技术(Ge ART+ELO)取代锗晶片时,传统结构的表现并不好。可能的两个原因如下。第一个原因是,传统结构所应用的锗电池可能太厚。锗的热膨胀系数(coefficient of thermalexpansion,CTE)远不同于硅的热膨胀系数CTE。锗的成长通常在成长温度中并未承受到应力,但是在其冷却后会承受到应力。故当锗成长至一过厚程度时,为了释放应力便可能在锗中形成破裂(cracks)。可导致破裂的上述厚度约介于5-10微米,其确切厚度则依据成长温度而定。在传统的多结结构中所应用的锗电池优选为至少20微米厚。优选上述厚度是由于锗的能隙(band-gap)为间接(indirect)的,故对于光而言锗并非为一极佳的吸收物。当所制作的锗电池太薄时,大多数的光线会穿透锗电池而没有为其所吸收,如此将降低电池效率。上述厚度的需求亦基于电流匹配(current matching)特性,即当锗电池太薄时,在电池底部所产生的电流可能低于其顶部处所产生的电流,进而降低了串连装置内的电流与其效率。
传统结构可能无法施行锗的深宽比捕捉与外延侧向成长技术的第二理由是由于这种结构中位于锗与硅基板之间的高电阻值。电流可能仅能通过连结于锗与硅之间的窄的沟槽而在锗与硅之间流通。而形成沟槽的氧化物阻挡了在其他路径中的电流传导情形。如此高电阻值将降低太阳能电池的效率。
图5a与图5b则描述了用于解决上述问题的可能方法。如图5a中所示,可在使用锗的深宽比捕捉与外延侧向成长技术的一锗基板上成长一反向型太阳能电池(inverse solar cell)。首先成长高能隙的InGaP,接着成长GaAs,且接着成长InGaAs。在GaAs与InGaAs之间可使用一GaInP缓冲层以调和GaAs与InGaAs间的晶格常数的差异。InGaAs材质的太阳能电池可具有极薄厚度,通常为2微米,由于InGaAs为直接能隙半导体,因此该太阳能电池可有效地吸收光线。在电池成长完毕之后,可反置此晶片且将之接合至导电的一握持晶片(handle wafer)。接着可通过选择性蚀刻移除使用锗的深宽比捕捉与外延侧向成长技术的锗基板。由于欲移除的硅基板远厚于不欲移除的化合物半导体太阳能电池部分,故优选非常精确地完成上述选择性蚀刻。此选择性蚀刻可通过使用如氢氧化钾(KOH)的选择性极佳的湿蚀刻(其可快速地蚀刻硅但却非常缓慢地蚀刻锗)而完成。而薄氧化物与由深宽比捕捉与外延侧向成长技术所形成的锗膜层则可接着在另一步骤中移除,且在此步骤中由于这些膜层相对于化合物半导体太阳能电池来说并不厚,故其挑战性并不高。
参照图5b的显示情形,在反向型太阳能电池方法中可极佳地解决前述两个问题。可吸收低能量光线的InGaAs太阳能电池够薄,故可成长于使用锗的深宽比捕捉与外延侧向成长技术的锗基板上而不会造成破裂情形。而握持晶片则提供了用于太阳能电池电流的一低电阻值路径。

Claims (44)

1.一种形成结构的方法,包括:
在设置于一基板上的一掩模层中形成一第一开口,其中该基板包括一第一半导体材料;
在该第一开口内形成包括晶格失配于该第一半导体材料的一第二半导体材料的一第一膜层,该第一膜层具有足够延伸至高于该掩模层的一顶面的一厚度;以及
在该第一膜层之上以及该掩模层的至少一部分上形成包括该第二半导体材料的一第二膜层,
其中该第一膜层的垂直成长速率高于该第一膜层的一侧向成长速率,而该第二膜层的一侧向成长速率高于该第二膜层的一垂直成长速率。
2.如权利要求1所述的方法,还包括:
在形成该第一膜层之前,在该掩模层中形成一第二开口;
在形成该第二膜层之前,在该第二开口内形成该第一膜层;以及
在该第二膜层之上形成包括该第二半导体材料的一第三膜层,
其中该第三膜层接合在该第一开口与该第二开口之间。
3.如权利要求2所述的方法,其中在该第一开口内捕捉该第一膜层中的差排缺陷。
4.如权利要求2所述的方法,其中通过在形成该第一膜层时掺杂该第一膜层而增加该第一膜层的该垂直成长速率。
5.如权利要求2所述的方法,其中通过在形成该第一膜层时掺杂该第一膜层而降低该第一膜层的侧向成长速率。
6.如权利要求2所述的方法,其中通过在形成该第一膜层时调整用于该第一膜层的一顶面上形成晶面的成长参数而降低该第一膜层的该侧向成长速率。
7.如权利要求2所述的方法,其中降低该第二膜层的该垂直成长速率包括在形成该第二膜层时掺杂该第二膜层。
8.如权利要求7所述的方法,其中降低该第二膜层的该垂直成长速率包括在形成该第二膜层时掺杂该第二膜层以在该第二膜层内形成第一类型的晶面并抑制在该第二膜层内一第二类型的晶面的形成。
9.如权利要求2所述的方法,其中增加该第二膜层的侧向成长速率包括在形成该第二膜层时掺杂该第二膜层。
10.如权利要求2所述的方法,其中通过在形成该第三膜层时掺杂该第三膜层促进该第三膜层的接合。
11.如权利要求2所述的方法,其中通过在形成该第三膜层时掺杂该第三膜层促进该第一开口与该第二开口之间的该第三膜层的接合。
12.如权利要求11所述的方法,其中掺杂该第三膜层减缓了该第三膜层内的晶面成长且降低了在第三膜层内的堆叠错误的形成。
13.如权利要求2所述的方法,其中该第二半导体材料包括锗。
14.如权利要求13所述的方法,其中该第二半导体材料包括p型掺质。
15.如权利要求2所述的方法,其中形成至少该第一、第二或第三膜层其中之一包括外延成长。
16.如权利要求2所述的方法,其中形成该第一膜层包括使用四氯化锗作为一前趋物。
17.如权利要求2所述的方法,还包括在形成该第三膜层后移除该第三膜层的一顶部以移除缺陷。
18.如权利要求17所述的方法,还包括在该顶部移除之后形成一光电装置在该第三膜层之上。
19.如权利要求2所述的方法,其中该第一膜层的一顶部定义了与该基板的一顶面不平行的一晶面。
20.如权利要求2所述的方法,其中该第三膜层为自我平坦化。
21.如权利要求20所述的方法,其中通过主要地在一(100)方向上成长该第三膜层而自我平坦化该第三膜层。
22.如权利要求2所述的方法,还包括:
在该第三膜层的顶部形成一第四膜层,该第四膜层包括一第三半导体材料;
在该第四膜层的顶部形成一第五膜层,该第五膜层包括一第四半导体材料;
接合该第五膜层与一握持晶片;以及
移除该基板。
23.如权利要求22所述的方法,其中该第三半导体材料与该第四半导体材料分别包括III-V族材料。
24.如权利要求22所述的方法,其中该基板包括硅。
25.如权利要求22所述的方法,其中该握持晶片包括金属。
26.如权利要求22所述的方法,其中该第三半导体材料的能隙高于该第四半导体材料的能隙。
27.如权利要求22所述的方法,其中该结构包括一多结光电电池。
28.一种形成结构的方法,包括:
在设置于一基板上的一掩模层中形成具有一宽度w1的一开口,该基板包括一第一半导体材料;
在该开口内形成包括晶格失配于该第一半导体材料的一第二半导体材料的一第一膜层,该第一膜层垂直延伸至高于该掩模层的一顶面且侧向延伸至大于该宽度w1的一宽度w2
移除该第一膜层的一部分,而该第一膜层的一剩余部分具有高于邻近于该开口的该基板的一第一区的一厚度t1
在该第一膜层上形成包括该第二半导体材料的一第二膜层,该第二膜层侧向延伸至大于该宽度w2的一宽度w3;以及
移除该第二膜层的一部分,该第二膜层的一剩余部分具有高于邻近于该开口的该基板的一第二区的一厚度t2
29.如权利要求28所述的方法,其中t1等于t2
30.如权利要求28所述的方法,其中移除该第一膜层包括至少蚀刻或化学机械研磨其中之一。
31.如权利要求28所述的方法,其中形成该第一膜层与移除该第一膜层的步骤在不同机台中所实施。
32.如权利要求28所述的方法,其中形成该第一膜层与移除该第一膜层的步骤在同一机台中所实施。
33.如权利要求28所述的方法,其中在该开口内捕捉该第二半导体材料中的差排缺陷。
34.如权利要求28所述的方法,其中高于该基板的该表面的该第一膜层的一部分大体不具有差排缺陷。
35.如权利要求28所述的方法,其中该第二半导体材料的一垂直成长速率大于该第二半导体材料的一侧向成长速率。
36.如权利要求28所述的方法,其中该开口的一侧壁包括一介电材料。
37.如权利要求28所述的方法,其中形成至少该第一膜层与该第二膜层其中之一为使用外延成长。
38.如权利要求28所述的方法,还包括使用四氯化锗作为一前趋物以形成该第一膜层。
39.如权利要求28所述的方法,还包括在形成该第二膜层之后移除该第二膜层的顶部。
40.如权利要求28所述的方法,还包括在该第二膜层上形成一光电装置。
41.如权利要求28所述的方法,其中该第一膜层的一顶部定义了与该基板的一顶面不平行的一晶面。
42.如权利要求28所述的方法,其中该第二膜层为自我平坦化。
43.如权利要求28所述的方法,其中通过主要地依照(100)方向成长该第二膜层而自我平坦化该第二膜层。
44.如权利要求28所述的方法,还包括:
在该第二膜层的顶部形成一第三膜层,该第三膜层包括一第三半导体材料;
在该第三膜层的顶部形成一第四膜层,该第四膜层包括一第四半导体材料;
接合该第四膜层与一握持晶片;以及
移除该基板。
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