CN105058791B - 光加工模型的造型材料、光加工模型形状的支持材料和光加工模型的制造方法 - Google Patents
光加工模型的造型材料、光加工模型形状的支持材料和光加工模型的制造方法 Download PDFInfo
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Classifications
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- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
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- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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Applications Claiming Priority (5)
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| JP2010244909 | 2010-11-01 | ||
| JP2010-244909 | 2010-11-01 | ||
| JP2011-208389 | 2011-09-26 | ||
| JP2011208389A JP5890990B2 (ja) | 2010-11-01 | 2011-09-26 | インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法 |
| CN201180052940.XA CN103189187B (zh) | 2010-11-01 | 2011-10-17 | 在喷墨三维印刷法中用于形成光加工模型的造型材料、在光加工时用于支持光加工模型的形状的支持材料和光加工模型的制造方法 |
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| CN201510463347.4A Expired - Fee Related CN105111380B (zh) | 2010-11-01 | 2011-10-17 | 光加工模型的造型材料、光加工模型形状的支持材料和光加工模型的制造方法 |
| CN201180052940.XA Active CN103189187B (zh) | 2010-11-01 | 2011-10-17 | 在喷墨三维印刷法中用于形成光加工模型的造型材料、在光加工时用于支持光加工模型的形状的支持材料和光加工模型的制造方法 |
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| CN201180052940.XA Active CN103189187B (zh) | 2010-11-01 | 2011-10-17 | 在喷墨三维印刷法中用于形成光加工模型的造型材料、在光加工时用于支持光加工模型的形状的支持材料和光加工模型的制造方法 |
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| JP5691155B2 (ja) * | 2009-11-10 | 2015-04-01 | ソニー株式会社 | 立体造形物の造形方法及び造形装置 |
| JP5890990B2 (ja) * | 2010-11-01 | 2016-03-22 | 株式会社キーエンス | インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法 |
| WO2014068579A1 (en) * | 2012-11-05 | 2014-05-08 | Yehoshua Sheinman | System and method for direct inkjet printing of 3d objects |
| EP2969465B1 (en) | 2013-03-14 | 2019-05-01 | Stratasys Ltd. | Polymer based molds and methods of manufacturing there of |
| US20140265033A1 (en) * | 2013-03-15 | 2014-09-18 | Michelin Recherche Et Technique S.A. | Method for improved tire mold manufacturing |
| EP3045483B1 (en) * | 2013-09-11 | 2018-04-04 | Sanyo Chemical Industries, Ltd. | Active energy ray curable resin composition, and cured product |
| WO2015049873A1 (ja) * | 2013-10-03 | 2015-04-09 | コニカミノルタ株式会社 | インク組成物および画像又は三次元造形物形成方法 |
| JP6162565B2 (ja) * | 2013-10-04 | 2017-07-12 | 株式会社ミマキエンジニアリング | 三次元造形装置及び三次元造形対象物の成形方法 |
| JP6384485B2 (ja) * | 2013-10-15 | 2018-09-05 | コニカミノルタ株式会社 | 三次元造形用インクジェットインク組成物および三次元造形物の製造方法 |
| JP2015077754A (ja) * | 2013-10-18 | 2015-04-23 | ローランドディー.ジー.株式会社 | 三次元造形装置 |
| GB2521386A (en) | 2013-12-18 | 2015-06-24 | Ibm | Improvements in 3D printing |
| JP2015131398A (ja) * | 2014-01-09 | 2015-07-23 | セイコーエプソン株式会社 | 三次元造形物の製造方法、三次元造形物製造装置、インクセットおよび三次元造形物 |
| JP6387614B2 (ja) * | 2014-01-09 | 2018-09-12 | セイコーエプソン株式会社 | 三次元造形物の製造方法およびインクセット |
| JP6273849B2 (ja) | 2014-01-15 | 2018-02-07 | セイコーエプソン株式会社 | 三次元造形物の製造方法、三次元造形物製造装置およびインクセット |
| JP6367560B2 (ja) * | 2014-01-20 | 2018-08-01 | ローランドディー.ジー.株式会社 | 三次元造形装置および三次元造形方法 |
| JP6405634B2 (ja) * | 2014-01-28 | 2018-10-17 | セイコーエプソン株式会社 | 三次元造形物の製造方法、三次元造形物製造装置および三次元造形物 |
| US20170173865A1 (en) | 2014-02-10 | 2017-06-22 | Stratasys Ltd. | Composition and method for additive manufacturing of an object |
| JP6085578B2 (ja) * | 2014-03-11 | 2017-02-22 | 住友重機械工業株式会社 | 膜形成方法及び膜形成装置 |
| EP3116961A1 (en) * | 2014-03-11 | 2017-01-18 | 3D Systems, Incorporated | Inks for 3d printing |
| JP6399084B2 (ja) * | 2014-03-14 | 2018-10-03 | コニカミノルタ株式会社 | 3d造形用光硬化性組成物および3d造形物の製造方法 |
| JP6081401B2 (ja) * | 2014-03-25 | 2017-02-15 | アイ−スクウェアード・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | サポート部形成用の光硬化性樹脂組成物 |
| JP6454977B2 (ja) * | 2014-03-26 | 2019-01-23 | セイコーエプソン株式会社 | 三次元造形物製造装置 |
| JP2015189007A (ja) | 2014-03-27 | 2015-11-02 | セイコーエプソン株式会社 | 造形物の製造方法 |
| JP6405721B2 (ja) * | 2014-06-04 | 2018-10-17 | 東洋インキScホールディングス株式会社 | 光学立体造形用硬化性材料および立体造形物 |
| JP6269333B2 (ja) * | 2014-06-09 | 2018-01-31 | コニカミノルタ株式会社 | 3d造形用モデル材組成物、3d造形用インクセットおよび3d造形物の製造方法 |
| JP6269339B2 (ja) * | 2014-06-17 | 2018-01-31 | コニカミノルタ株式会社 | 3d造形用組成液、3d造形用インクセットおよび3d造形物の製造方法 |
| JP6586284B2 (ja) * | 2014-06-20 | 2019-10-02 | 株式会社キーエンス | インクジェット光造形法における光造形品形成用モデル材及び光造形品の製造方法 |
| JP2016020489A (ja) * | 2014-06-20 | 2016-02-04 | 三洋化成工業株式会社 | 活性エネルギー線硬化性樹脂組成物 |
| EP2974850A1 (de) * | 2014-07-17 | 2016-01-20 | Marabu GmbH & Co. KG | Verdruckbares Baumaterial für 3D-Druck |
| FR3024659B1 (fr) | 2014-08-05 | 2016-09-30 | Oreal | Procede de fabrication additive d'un objet tridimensionnel comprenant ou constituant une composition cosmetique par projection directe utilisant un materiau photoactivable, et appareil associe |
| US9694542B2 (en) * | 2014-09-12 | 2017-07-04 | Ricoh Company, Ltd. | Method and apparatus for molding three-dimensional object and molding data generation method for three-dimensional object |
| EP3235630B1 (en) | 2014-12-16 | 2020-08-19 | FUJIFILM Corporation | Actinic-ray-curable inkjet ink composition for 3d printing, three-dimensional modeling method, and actinic-ray-curable inkjet ink set for 3d printing |
| JP6451288B2 (ja) * | 2014-12-17 | 2019-01-16 | コニカミノルタ株式会社 | モデル材インク、インクセットおよび3d造形物を製造する方法 |
| JP6451287B2 (ja) * | 2014-12-17 | 2019-01-16 | コニカミノルタ株式会社 | 3d造形物の製造方法、モデル材インクおよびインクセット |
| TWI592760B (zh) * | 2014-12-30 | 2017-07-21 | 羅門哈斯電子材料韓國有限公司 | 與經外塗佈之光致抗蝕劑一起使用之塗層組合物 |
| JP6578660B2 (ja) * | 2015-01-22 | 2019-09-25 | 富士ゼロックス株式会社 | 三次元造形用支持材、三次元造形用組成物セット、および三次元造形装置、三次元造形物の製造方法 |
| WO2016118151A1 (en) * | 2015-01-23 | 2016-07-28 | Hewlett-Packard Development Company, L.P. | Susceptor materials for 3d printing using microwave processing |
| EP3251818B1 (en) * | 2015-01-26 | 2019-12-11 | KJ Chemicals Corporation | Active energy ray-curable resin composition for three-dimensional model supporting material |
| US10286598B2 (en) | 2015-02-06 | 2019-05-14 | Kj Chemicals Corporation | Method for manufacturing three-dimensional molded product and three-dimensional molded product using the same |
| CN107405838A (zh) * | 2015-03-03 | 2017-11-28 | 巴斯夫欧洲公司 | 使用两种预支撑材料生产三维结构的方法 |
| MX2017011244A (es) * | 2015-03-03 | 2017-11-01 | Basf Se | Metodo para producir una estructura tridimensional mediante impresion 3d. |
| WO2016143559A1 (ja) * | 2015-03-10 | 2016-09-15 | コニカミノルタ株式会社 | 立体造形用インク組成物、インクセットおよび立体造形物の製造方法 |
| KR20170129181A (ko) * | 2015-03-11 | 2017-11-24 | 스트라타시스 엘티디. | 지지체 재료 조성물 및 이를 이용한 적층 제조 방법 |
| KR102307599B1 (ko) * | 2015-03-16 | 2021-10-05 | 엘지전자 주식회사 | 3차원 인쇄 장치 |
| KR102523252B1 (ko) | 2015-03-19 | 2023-04-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 광조절된 라디칼 중합을 사용하는 적층 가공 방법 |
| CN104801703B (zh) * | 2015-03-26 | 2016-08-24 | 成都新柯力化工科技有限公司 | 一种用于三维打印的柔性金属粉及其制备方法和应用方法 |
| US20160279881A1 (en) * | 2015-03-27 | 2016-09-29 | Seiko Epson Corporation | Three-dimensional modeling apparatus |
| JP6777414B2 (ja) * | 2015-03-31 | 2020-10-28 | 三洋化成工業株式会社 | 活性エネルギー線硬化性樹脂組成物 |
| JP6543498B2 (ja) * | 2015-04-02 | 2019-07-10 | 株式会社キーエンス | インクジェット光造形法における光造形品の製造方法 |
| KR101644017B1 (ko) * | 2015-04-10 | 2016-07-29 | 제주대학교 산학협력단 | 3차원 프린팅 구조물의 지지 구조 적층 시스템 및 이를 이용한 3차원 프린팅 방법 |
| US9751263B2 (en) * | 2015-04-20 | 2017-09-05 | Xerox Corporation | Injection molding to finish parts printed with a three-dimensional object printer |
| WO2016199611A1 (ja) | 2015-06-08 | 2016-12-15 | 富士フイルム株式会社 | 3次元印刷用活性光線硬化型インクジェットインクセット、3次元印刷方法、及び、3次元印刷システム |
| JP6493875B2 (ja) * | 2015-06-08 | 2019-04-03 | 富士フイルム株式会社 | 3次元造形物の形成方法 |
| GR1009027B (el) * | 2015-06-10 | 2017-05-09 | Κωνσταντινος Σωζοντος Αντωνιου | Διαδικασια απομακρυνσης υποστηριξεων κατα τη δημιουργια τρισδιαστατων μοντελων με τη μεθοδο του φωτοπολυμερισμου με τη χρηση δυο ή περισσοτερων ρητινων |
| JP6485239B2 (ja) * | 2015-06-12 | 2019-03-20 | 富士ゼロックス株式会社 | 造形装置 |
| KR101680334B1 (ko) * | 2015-06-15 | 2016-11-29 | 주식회사 퓨쳐캐스트 | 3차원 프린팅 방식을 이용한 금형 제작방법 |
| US10882245B2 (en) * | 2015-07-06 | 2021-01-05 | Ricoh Company, Ltd. | Method of manufacturing three-dimensional object, liquid set for manufacturing three-dimensional object, device for manufacturing three-dimensional object, and gel object |
| JP6724303B2 (ja) * | 2015-07-22 | 2020-07-15 | 株式会社リコー | 立体造形物の製造方法 |
| JP6724304B2 (ja) * | 2015-07-22 | 2020-07-15 | 株式会社リコー | 立体造形物の製造方法 |
| KR102037558B1 (ko) | 2015-07-20 | 2019-10-28 | 주식회사 엘지화학 | 3d 프린팅 지지체용 잉크 조성물 및 이를 이용한 3d 프린팅 제조방법 |
| JP6679234B2 (ja) * | 2015-07-29 | 2020-04-15 | マクセルホールディングス株式会社 | モデル材用樹脂組成物、サポート材用樹脂組成物、光造形品、および、光造形品の製造方法 |
| JP6720483B2 (ja) * | 2015-07-31 | 2020-07-08 | 富士ゼロックス株式会社 | 三次元造形用組成物セット、及び三次元造形物の製造方法 |
| KR20180031802A (ko) * | 2015-08-14 | 2018-03-28 | 스트라타시스 엘티디. | 세정제 조성물 |
| JP6710506B2 (ja) | 2015-08-21 | 2020-06-17 | 株式会社ミマキエンジニアリング | インクジェット造形方法 |
| JP6574980B2 (ja) * | 2015-09-01 | 2019-09-18 | Kjケミカルズ株式会社 | モデル材用活性エネルギー線硬化性樹脂組成物 |
| JP2017052177A (ja) * | 2015-09-09 | 2017-03-16 | 富士ゼロックス株式会社 | 三次元造形物の製造方法、三次元造形用支持材、三次元造形用支持材カートリッジ、及び三次元造形用組成物セット |
| JP6796069B2 (ja) * | 2015-09-15 | 2020-12-02 | マクセルホールディングス株式会社 | 光造形用インクセット、および、光造形品の製造方法 |
| CN108025486B (zh) * | 2015-09-15 | 2021-05-04 | 麦克赛尔控股株式会社 | 模型材用树脂组合物、光造型用油墨组及光造型品的制造方法 |
| EP3147707B1 (de) * | 2015-09-25 | 2019-04-24 | Ivoclar Vivadent AG | Keramik- und glaskeramikschlicker für die stereolithography |
| FR3042195B1 (fr) | 2015-10-09 | 2017-11-24 | Arkema France | Oligomere ionique et composition polymerisable le contenant pour materiaux hydro-fragmentables a usage provisoire |
| JP6808439B2 (ja) * | 2015-10-30 | 2021-01-06 | キヤノン株式会社 | 立体物の製造方法および立体物の製造に用いる除去液 |
| JP6669985B2 (ja) | 2015-11-12 | 2020-03-18 | セイコーエプソン株式会社 | 三次元造形物の製造方法 |
| CN105440200B (zh) * | 2015-12-15 | 2017-08-22 | 中山职业技术学院 | 一种有机‑无机杂化3d打印材料及其制备方法 |
| EP3402644A4 (en) | 2016-01-15 | 2019-08-14 | Stratasys Ltd. | BRUSH FORMULATION IN THE WATER AND METHOD FOR THE GENERATIVE MANUFACTURE THEREWITH |
| JP6672874B2 (ja) * | 2016-02-22 | 2020-03-25 | 富士ゼロックス株式会社 | 三次元造形用支持材、三次元造形用支持材カートリッジ、三次元造形用組成物セット、三次元造形装置、及び三次元造形物の製造方法 |
| KR101942244B1 (ko) | 2016-02-26 | 2019-01-28 | 주식회사 엘지화학 | 3d 프린팅 지지체용 잉크 조성물 및 이를 이용한 3d 프린팅 제조방법 |
| JP6812116B2 (ja) * | 2016-03-14 | 2021-01-13 | マクセルホールディングス株式会社 | モデル材用樹脂組成物、および、光造形品の製造方法 |
| JP6819671B2 (ja) * | 2016-03-18 | 2021-01-27 | 株式会社リコー | 活性エネルギー線硬化型組成物、立体造形物の製造方法、及び立体造形物の製造装置 |
| JP6926395B2 (ja) * | 2016-03-28 | 2021-08-25 | 東洋インキScホールディングス株式会社 | 重合性組成物 |
| KR102125596B1 (ko) | 2016-04-08 | 2020-06-22 | 주식회사 엘지화학 | 3d 프린팅 지지체용 잉크 조성물 |
| JP6680887B2 (ja) | 2016-04-15 | 2020-04-15 | ヒューレット−パッカード デベロップメント カンパニー エル.ピー.Hewlett‐Packard Development Company, L.P. | 複合粒状構築材料 |
| JP6903283B2 (ja) * | 2016-05-13 | 2021-07-14 | 株式会社リコー | 活性エネルギー線硬化型組成物、硬化物、組成物収容容器、像形成装置、及び像形成方法 |
| JP6891474B2 (ja) * | 2016-06-13 | 2021-06-18 | 株式会社リコー | 形状支持用液体、及び立体造形物の製造方法 |
| US11078374B2 (en) | 2016-06-13 | 2021-08-03 | Ricoh Company, Ltd. | Active-energy-ray-curable liquid composition, three-dimensional object forming material set, method for producing three-dimensional object, and three-dimensional object producing apparatus |
| JP6870275B2 (ja) * | 2016-10-27 | 2021-05-12 | 株式会社リコー | 立体造形用支持材、立体造形物の製造方法、及び立体造形物の製造装置 |
| JP6938860B2 (ja) * | 2016-06-13 | 2021-09-22 | 株式会社リコー | 形状支持用液体、及び立体造形物の製造方法 |
| CN109312177B (zh) * | 2016-06-13 | 2022-03-29 | 株式会社理光 | 活性能量射线固化性液体组合物、三维物体形成材料套组、三维物体制备方法和三维物体制备设备 |
| CN109328201A (zh) * | 2016-06-22 | 2019-02-12 | 麦克赛尔控股株式会社 | 模塑材料用树脂组合物和光造型品的制造方法 |
| JP6848223B2 (ja) | 2016-06-28 | 2021-03-24 | 株式会社リコー | 活性エネルギー線硬化型液体組成物、立体造形物の製造方法、立体造形物の製造装置 |
| WO2018005501A1 (en) | 2016-06-30 | 2018-01-04 | 3M Innovative Properties Company | Printable compositions including highly viscous components and methods of creating 3d articles therefrom |
| KR102261399B1 (ko) | 2016-06-30 | 2021-06-07 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 자외선 경화성 실리콘 조성물 및 그의 경화물 |
| JP6819106B2 (ja) * | 2016-07-12 | 2021-01-27 | 株式会社リコー | 活性エネルギー線硬化型組成物、インク、収容容器、2次元又は3次元の像形成装置、2次元又は3次元の像形成方法、及び、塗工物 |
| EP3508335B1 (en) * | 2016-09-01 | 2023-02-01 | Nippon Shokubai Co., Ltd. | Photocurable support material composition for inkjet 3d printers, ink for inkjet 3d printers, cartridge for inkjet 3d printers, method for producing support material and method for producing optically shaped article |
| US11607844B2 (en) | 2016-10-04 | 2023-03-21 | Tokyo Printing Ink Mfg. Co., Ltd. | Treatment agent for additive manufacturing apparatus |
| JP6774288B2 (ja) * | 2016-10-04 | 2020-10-21 | 共栄社化学株式会社 | 活性線硬化性樹脂組成物 |
| JP7701780B2 (ja) | 2016-10-28 | 2025-07-02 | ストラタシス,インコーポレイテッド | 熱硬化性組成物及びそれからの三次元物体の形成 |
| CN106738874B (zh) * | 2016-11-24 | 2019-01-29 | 南京航空航天大学 | 一种快速去除3d打印支撑的方法 |
| JP6381614B2 (ja) * | 2016-11-29 | 2018-08-29 | マクセルホールディングス株式会社 | サポート材組成物 |
| EP3560683A4 (en) * | 2016-12-22 | 2020-08-26 | Maxell Holdings, Ltd. | INK SET FOR OPTICALLY SHAPED AND OPTICALLY SHAPED OBJECT PRODUCTION PROCESS USING IT |
| JPWO2018142485A1 (ja) * | 2017-01-31 | 2019-11-14 | マクセルホールディングス株式会社 | 光造形用インクセット、光造形品、及び、光造形品の製造方法 |
| JP2018122499A (ja) * | 2017-01-31 | 2018-08-09 | マクセルホールディングス株式会社 | 光造形用インクセット、光造形品、及び、光造形品の製造方法 |
| US20200407581A1 (en) * | 2017-01-31 | 2020-12-31 | Maxell Holdings, Ltd. | Optical shaping ink set, optically shaped article, and method for producing optically shaped article |
| CN110023058B (zh) * | 2017-02-06 | 2021-08-10 | 惠普发展公司,有限责任合伙企业 | 3d打印 |
| US10781228B2 (en) * | 2017-02-06 | 2020-09-22 | Hewlett-Packard Development Company, L.P. | Fusing agent including a metal bis(dithiolene) complex |
| US11945152B2 (en) | 2017-03-06 | 2024-04-02 | Maxell, Ltd. | Model material ink set, support material composition, ink set, three-dimensional shaped object, and method for manufacturing three-dimensional shaped object |
| CN106915084B (zh) * | 2017-03-07 | 2019-04-02 | 杭州杭景模型有限公司 | 3d打印机及其打印平台 |
| JP2018154092A (ja) * | 2017-03-21 | 2018-10-04 | 株式会社リコー | 立体造形物の製造方法、及び立体造形物のデータの作成方法 |
| JP6880912B2 (ja) * | 2017-03-28 | 2021-06-02 | 株式会社リコー | 立体造形用液体セット、立体造形物の製造方法、及び立体造形装置 |
| JP6930176B2 (ja) | 2017-03-29 | 2021-09-01 | 株式会社リコー | 立体造形用組成物のセット、立体造形物の製造方法、及び立体造形装置 |
| ES2920055T3 (es) | 2017-04-25 | 2022-08-01 | Basf Se | Una composición utilizada en un sistema de impresión 3D y su aplicación |
| CN114750408A (zh) * | 2017-05-15 | 2022-07-15 | 霍洛公司 | 粘性膜三维打印系统和方法 |
| EP3415314A1 (en) * | 2017-06-15 | 2018-12-19 | Mimaki Engineering Co., Ltd. | Building apparatus and building method |
| JP6815940B2 (ja) * | 2017-06-15 | 2021-01-20 | 株式会社ミマキエンジニアリング | 造形装置及び造形方法 |
| EP4574852A3 (en) * | 2017-06-30 | 2025-10-15 | Align Technology, Inc. | 3d printed composites from a single resin by patterned light exposures |
| CN111148483B (zh) | 2017-07-28 | 2022-11-15 | 斯特拉塔西斯公司 | 制造具有血管特性的物体的方法和系统 |
| DK3658352T3 (da) * | 2017-07-28 | 2024-01-02 | Stratasys Ltd | Additive fremstillingsprocesser, der anvender et materiale med et blødt kropsvævs egenskaber |
| EP4289607B1 (en) | 2017-07-28 | 2024-10-30 | Stratasys Ltd. | Method and system for fabricating object featuring properties of a hard tissue |
| JP7165186B2 (ja) * | 2017-07-28 | 2022-11-02 | ストラタシス リミテッド | 軟らかい材料からなる三次元物体の付加製造において使用可能な配合物 |
| CN111344328B (zh) * | 2017-11-09 | 2023-05-30 | 科思创德国股份有限公司 | 制造物件的方法和可自由基交联树脂在增材制造法中的用途 |
| US10899088B2 (en) | 2017-11-17 | 2021-01-26 | Matsuura Machinery Corporation | Support and method of shaping workpiece and support |
| WO2019129560A1 (en) | 2017-12-29 | 2019-07-04 | Basf Se | A composition to produce support sub-structures for 3d photopolymer jetting |
| EP3732044A1 (en) * | 2017-12-31 | 2020-11-04 | Stratasys Ltd. | Modeling material formulations usable in additive manufacturing of three-dimensional objects at low temperatures |
| IL275770B2 (en) | 2017-12-31 | 2024-07-01 | Stratasys Ltd | Support material formulations usable in additive manufacturing of three-dimensional objects at low temperatures |
| CN108117799A (zh) * | 2017-12-31 | 2018-06-05 | 中山市威傲联复合材料有限公司 | 一种室内led显示屏间隙遮蔽油墨及其制备方法 |
| JP7052397B2 (ja) * | 2018-02-14 | 2022-04-12 | 株式会社リコー | 立体造形物用組成物、立体造形物の製造装置、及び立体造形物の製造方法 |
| JP7112207B2 (ja) | 2018-02-20 | 2022-08-03 | 株式会社ミマキエンジニアリング | 三次元造形物 |
| CN111615447B (zh) | 2018-03-02 | 2023-04-04 | 株式会社日本触媒 | 支撑材料及光造型物的制造法、喷墨三维打印机用光固化性支撑材料用组合物、墨水、墨盒 |
| EP3753957B1 (en) * | 2018-03-30 | 2023-09-06 | Mitsui Chemicals, Inc. | Photolithographic curable composition, evaporative pattern, and method for producing three dimensional shaped article |
| EP3825102A4 (en) | 2018-07-18 | 2022-05-11 | KJ Chemicals Corporation | ACTIVE ENERGY RADIATION CURING RESIN COMPOSITION FOR THREE-DIMENSIONAL MOLDING BACKING MATERIALS, AND INK |
| WO2020015905A1 (en) | 2018-07-18 | 2020-01-23 | Arkema France | Articles prepared using curable compositions based on polymerizable ionic species |
| WO2020028232A1 (en) * | 2018-08-01 | 2020-02-06 | Carbon, Inc. | Production of low density products by additive manufacturing |
| JP6962290B2 (ja) | 2018-08-02 | 2021-11-05 | 信越化学工業株式会社 | 光造形用紫外線硬化型シリコーン組成物およびその硬化物 |
| CN109232791B (zh) * | 2018-08-20 | 2020-06-16 | 珠海赛纳打印科技股份有限公司 | 一种3d打印用光固化非透明材料及其制备方法、3d打印制品及3d打印机 |
| JP7180684B2 (ja) | 2018-09-20 | 2022-11-30 | 信越化学工業株式会社 | 紫外線硬化性シリコーン組成物及びその硬化物 |
| JP7541011B2 (ja) | 2018-09-24 | 2024-08-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 3d印刷において使用するための光硬化性組成物 |
| WO2020095846A1 (ja) * | 2018-11-07 | 2020-05-14 | ナガセケムテックス株式会社 | 光硬化性樹脂組成物および樹脂硬化物 |
| JP2020117603A (ja) * | 2019-01-22 | 2020-08-06 | 株式会社リコー | 活性エネルギー線硬化型組成物、活性エネルギー線硬化型インクジェットインク、組成物収容容器、インクジェット吐出装置および硬化物 |
| JP2020151958A (ja) * | 2019-03-20 | 2020-09-24 | 株式会社リコー | 立体造形物の製造装置、立体造形物の製造方法、及び立体造形プログラム |
| WO2020189654A1 (en) * | 2019-03-18 | 2020-09-24 | Ricoh Company, Ltd. | Three-dimensional object forming apparatus, three-dimensional object forming method, and program |
| JP7549616B2 (ja) * | 2019-07-19 | 2024-09-11 | ストラタシス リミテッド | 透明材料を含む三次元物体の付加製造 |
| JP7451967B2 (ja) * | 2019-11-28 | 2024-03-19 | 株式会社リコー | 活性エネルギー線急速硬化型組成物、造形方法、及び造形装置 |
| JP2021084410A (ja) * | 2019-11-29 | 2021-06-03 | 株式会社リコー | 立体造形用組成物セット、立体造形物、立体造形物の製造方法、2次元又は3次元の像形成装置及び2次元又は3次元の像形成方法 |
| JP7463718B2 (ja) * | 2019-12-25 | 2024-04-09 | Dic株式会社 | 硬化性樹脂組成物、硬化物及び立体造形物 |
| WO2022051521A1 (en) * | 2020-09-03 | 2022-03-10 | Basf Se | Reactive polyurethane elastomer |
| US20230407132A1 (en) * | 2020-10-28 | 2023-12-21 | Covestro (Netherlands) B.V. | (meth)acrylate-functional radiation curable compositions for additive fabrication |
| CN112831022B (zh) * | 2020-12-31 | 2022-07-15 | 中电保力(北京)科技有限公司 | 一种手办模型材料及其制备方法 |
| US20240117097A1 (en) * | 2021-01-29 | 2024-04-11 | Nagase Chemtex Corporation | Resin composition for three-dimensional photoshaping |
| KR20230164045A (ko) * | 2021-04-02 | 2023-12-01 | 디아이씨 가부시끼가이샤 | 광 조형용 경화성 수지 조성물, 경화물 및 입체 조형물 |
| JP7342910B2 (ja) | 2021-04-23 | 2023-09-12 | 信越化学工業株式会社 | 光造形用紫外線硬化性シリコーン組成物、その硬化物および硬化物の製造方法 |
| WO2023084517A1 (en) | 2021-11-12 | 2023-05-19 | Polyfos 3D Ltd | Vat polymerization process |
| JP7757746B2 (ja) * | 2021-12-06 | 2025-10-22 | セイコーエプソン株式会社 | 放射線硬化型インクジェット組成物及びインクジェット記録装置 |
| JP7124948B1 (ja) | 2021-12-15 | 2022-08-24 | 株式会社リコー | 活性エネルギー線硬化型組成物、活性エネルギー線硬化型インク組成物、インクジェット用インク組成物、組成物収容容器、2次元又は3次元の像形成装置、2次元又は3次元の像形成方法、硬化物、加飾体、積層体、フレキシブルデバイス用部材、及びフレキシブルデバイス |
| US20230391935A1 (en) * | 2022-06-06 | 2023-12-07 | Toyota Motor Engineering & Manufacturing North America, Inc. | Resins for digital light processing 3d printing |
| CN116237516B (zh) * | 2022-12-19 | 2024-12-27 | 深圳奇遇科技有限公司 | 用于光固化3d打印的金属浆料及其制备方法、应用 |
| WO2024214654A1 (ja) * | 2023-04-12 | 2024-10-17 | 三井化学株式会社 | 複合樹脂硬化物の製造方法、硬化性樹脂組成物、インク、インクセット、および、硬化物 |
| JP2025002169A (ja) | 2023-06-22 | 2025-01-09 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物を用いた3次元(3d)成形品を製造する方法及び該方法で製造した3次元(3d)成形品 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1671810A (zh) * | 2002-05-24 | 2005-09-21 | 亨斯迈先进材料(瑞士)有限公司 | 可喷射组合物 |
| JP2010155889A (ja) * | 2008-12-26 | 2010-07-15 | Jsr Corp | 光硬化性液状樹脂組成物およびインクジェット光造形法による支持体の製造方法 |
| JP2010155926A (ja) * | 2008-12-26 | 2010-07-15 | Jsr Corp | 光硬化性液状樹脂組成物およびインクジェット光造形法による立体造形物の製造方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4228049A (en) * | 1978-11-13 | 1980-10-14 | Desoto, Inc. | Aqueous coatings based on copolymers with a mixture of unsaturated esters of polymeric polyol and bisphenol-ethylene oxide adduct |
| JP2525216B2 (ja) | 1988-01-27 | 1996-08-14 | ディーエスエム・エヌヴィ | 光学的立体造形用樹脂組成物 |
| JP3356558B2 (ja) | 1994-08-18 | 2002-12-16 | ジェイエスアール株式会社 | 光学的立体造形用樹脂組成物 |
| JP3205487B2 (ja) | 1995-07-04 | 2001-09-04 | ローレルバンクマシン株式会社 | 硬貨処理機 |
| JP3705511B2 (ja) | 1995-10-20 | 2005-10-12 | ナブテスコ株式会社 | 光学的立体造形用の光硬化性樹脂組成物 |
| JP3657057B2 (ja) | 1996-05-30 | 2005-06-08 | Jsr株式会社 | 成型用樹脂製型製造用光硬化性樹脂組成物および成型用樹脂製型の製造方法 |
| US7754807B2 (en) * | 1999-04-20 | 2010-07-13 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| EP1741545B1 (en) | 2000-03-13 | 2013-07-17 | Stratasys Ltd. | Compositions for use in three dimensional model printing |
| US6569373B2 (en) | 2000-03-13 | 2003-05-27 | Object Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| US7300619B2 (en) * | 2000-03-13 | 2007-11-27 | Objet Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| JP4282873B2 (ja) | 2000-04-26 | 2009-06-24 | 三菱レイヨン株式会社 | 光造形用硬化性組成物および成形品 |
| JP2002067174A (ja) | 2000-08-30 | 2002-03-05 | Minolta Co Ltd | データ処理装置及び方法、並びに三次元造形装置及び方法 |
| JP2002178412A (ja) | 2000-12-14 | 2002-06-26 | Sanyo Electric Co Ltd | 光造形装置及び光造形品の制作方法 |
| WO2003029365A1 (en) * | 2001-10-03 | 2003-04-10 | 3D Systems, Inc. | Phase change support material composition |
| JP2004059601A (ja) | 2002-07-24 | 2004-02-26 | Mitsubishi Rayon Co Ltd | 光学的立体造形用樹脂組成物、及び立体造形物 |
| JP2004255839A (ja) | 2003-02-28 | 2004-09-16 | Hitachi Printing Solutions Ltd | インクジェット方式の三次元造形装置及びその造形法 |
| WO2005021248A1 (ja) * | 2003-08-27 | 2005-03-10 | Fuji Photo Film Co., Ltd. | 三次元造形物の製造方法 |
| JP2008146685A (ja) | 2005-03-30 | 2008-06-26 | Pioneer Electronic Corp | 光ピックアップ装置及び情報記録再生装置 |
| JP2007131789A (ja) * | 2005-11-11 | 2007-05-31 | Fujifilm Corp | 着色分散液、インク組成物、それを用いた画像形成方法、及び記録物 |
| EP2664442B1 (en) | 2006-12-08 | 2018-02-14 | 3D Systems Incorporated | Three dimensional printing material system |
| JPWO2008146685A1 (ja) * | 2007-05-23 | 2010-08-19 | 昭和電工株式会社 | エーテル結合を有する反応性ウレタン化合物、硬化性組成物および硬化物 |
| JP2011020412A (ja) * | 2009-07-17 | 2011-02-03 | Altech Co Ltd | 三次元造型方法 |
| JP5606817B2 (ja) * | 2010-07-27 | 2014-10-15 | 富士フイルム株式会社 | 活性放射線硬化型インクジェット用インク組成物、印刷物、印刷物成形体、及び印刷物の製造方法 |
| KR101446091B1 (ko) * | 2010-10-27 | 2014-10-06 | 파일2파트, 인코포레이티드 | 3차원 물체 제작 방법 및 장치 |
| JP5890990B2 (ja) | 2010-11-01 | 2016-03-22 | 株式会社キーエンス | インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法 |
-
2011
- 2011-09-26 JP JP2011208389A patent/JP5890990B2/ja active Active
- 2011-10-17 WO PCT/JP2011/073778 patent/WO2012060204A1/ja not_active Ceased
- 2011-10-17 CN CN201510462996.2A patent/CN105058791B/zh active Active
- 2011-10-17 KR KR1020137013811A patent/KR101884038B1/ko active Active
- 2011-10-17 EP EP11837855.3A patent/EP2636511B1/en active Active
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- 2013-04-23 US US13/868,157 patent/US9556346B2/en active Active
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- 2016-05-26 US US15/164,906 patent/US9796863B2/en active Active
- 2016-05-26 US US15/164,905 patent/US9790382B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1671810A (zh) * | 2002-05-24 | 2005-09-21 | 亨斯迈先进材料(瑞士)有限公司 | 可喷射组合物 |
| JP2010155889A (ja) * | 2008-12-26 | 2010-07-15 | Jsr Corp | 光硬化性液状樹脂組成物およびインクジェット光造形法による支持体の製造方法 |
| JP2010155926A (ja) * | 2008-12-26 | 2010-07-15 | Jsr Corp | 光硬化性液状樹脂組成物およびインクジェット光造形法による立体造形物の製造方法 |
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| US9790382B2 (en) | 2017-10-17 |
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| US9796863B2 (en) | 2017-10-24 |
| US20160264796A1 (en) | 2016-09-15 |
| EP2636511A1 (en) | 2013-09-11 |
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