US9267184B2 - Systems and methods for processing alloy ingots - Google Patents
Systems and methods for processing alloy ingots Download PDFInfo
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- US9267184B2 US9267184B2 US12/700,963 US70096310A US9267184B2 US 9267184 B2 US9267184 B2 US 9267184B2 US 70096310 A US70096310 A US 70096310A US 9267184 B2 US9267184 B2 US 9267184B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D31/00—Other methods for working sheet metal, metal tubes, metal profiles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D25/00—Special casting characterised by the nature of the product
- B22D25/02—Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D7/00—Casting ingots, e.g. from ferrous metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3033—Ni as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/04—Welding for other purposes than joining, e.g. built-up welding
- B23K9/044—Built-up welding on three-dimensional surfaces
- B23K9/046—Built-up welding on three-dimensional surfaces on surfaces of revolution
- B23K9/048—Built-up welding on three-dimensional surfaces on surfaces of revolution on cylindrical surfaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/003—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals by induction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/04—Refining by applying a vacuum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/18—Electroslag remelting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/20—Arc remelting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
Definitions
- the present disclosure is directed to systems and methods for processing alloy ingots.
- the present disclosure is also directed to processes for hot working alloy ingots.
- Metal alloy products may be prepared, for example, using ingot metallurgy operations or powder metallurgy operations.
- Ingot metallurgy operations may involve the melting of an alloy feedstock and the casting of the molten material into an ingot.
- a non-limiting example of an ingot metallurgy operation is a “triple melt” technique, which includes three melting operations: (1) vacuum induction melting (VIM) to prepare a desired alloy composition from a feedstock; (2) electroslag refining (ESR), which may reduce levels of, for example, oxygen-containing inclusions; and (3) vacuum arc remelting (VAR), which may reduce compositional segregation that may occur during solidification after ESR.
- An ingot may be formed during solidification after a VAR operation.
- Powder metallurgy operations may involve atomization of molten alloy and the collection and consolidation of solidified metallurgical powders into an ingot.
- a non-limiting example of a powder metallurgy operation includes the steps of: (1) VIM to prepare a desired alloy composition from a feedstock; (2) atomization of molten alloy into molten alloy droplets that solidify into alloy powder; (3) optionally, sieving to reduce inclusions; (4) canning and degassing; and (5) pressing to consolidate the alloy powder into an alloy ingot.
- the alloy ingots formed from ingot metallurgy operations and powder metallurgy operations may be hot worked to produce other alloy products.
- the ingot may undergo forging and/or extrusion to form a billet or other alloy article from the ingot.
- Embodiments disclosed herein are directed to an ingot processing method.
- An ingot processing method may comprise depositing a metallic material layer onto at least a region of a surface of an alloy ingot.
- the ingot processing method may be characterized in that the metallic material layer reduces an incidence of surface cracking of the alloy ingot during hot working.
- the hot working process may comprise applying force to an alloy ingot to deform the alloy ingot.
- the alloy ingot may include a metallic material layer deposited onto at least a region of a surface of the alloy ingot.
- the hot working process may be characterized in that the force is applied onto the metallic material layer.
- An ingot processing system may comprise an ingot positioning apparatus.
- the ingot positioning apparatus may be configured to rotate an ingot about a long axis of the ingot.
- the ingot processing system may also comprise a welding apparatus.
- the welding apparatus may be configured to deposit a metallic material layer as a weld deposit onto at least a region of a surface of an ingot.
- FIG. 1A is a side view of an ingot having a metallic material layer deposited onto the end surfaces of the ingot
- FIG. 1B is a perspective view of the ingot shown in FIG. 1A ;
- FIG. 2 is a perspective view of an ingot having a metallic material layer deposited onto a circumferential surface of the ingot;
- FIG. 3A is a side view of an ingot having a metallic material layer deposited onto the end surfaces and a circumferential surface of the ingot
- FIG. 3B is a perspective view of the ingot shown in FIG. 3A ;
- FIGS. 4A-4D are perspective views illustrating one method of depositing metallic material as weld deposits onto a circumferential surface of an ingot
- FIGS. 5A-5D are perspective views illustrating another method of depositing metallic material as weld deposits onto a circumferential surface of an ingot
- FIG. 6A is a perspective view illustrating another embodiment of a method of depositing metallic material as a weld deposit onto a circumferential surface of an ingot
- FIG. 6B is a perspective view of the ingot shown in FIG. 6A and having a metallic material layer deposited as a weld deposit over the entire circumferential surface of the ingot;
- FIG. 7A is a side cross-sectional view of an ingot in an upset forging operation
- FIG. 7B is an expanded partial side cross-sectional view of the ingot shown in FIG. 7A after upset forging
- FIG. 7C is a side cross-sectional view of an ingot in an upset forging operation and having a metallic material layer deposited onto the end surfaces of the ingot
- FIG. 7D is an expanded partial side cross-sectional view of the ingot shown in FIG. 7C after upset forging;
- FIG. 8A is a side cross-sectional view of an ingot in a draw forging operation
- FIG. 8B is an expanded partial side cross-sectional view of the ingot shown in FIG. 8A after draw forging
- FIG. 8C is a side cross-sectional view of an ingot in a draw forging operation and having a metallic material layer deposited onto the circumferential surface of the ingot
- FIG. 8D is an expanded partial side cross-sectional view of the ingot shown in FIG. 8C after draw forging;
- FIG. 9 is a photograph of two 3-inch alloy cubes, each having a metallic material layer deposited by a welding operation on the top surface of the cube (as oriented in the photograph);
- FIGS. 10A and 10B are photographs of the two die-contacting surfaces of a 1-inch pancake that was press forged from a 3-inch alloy cube having a metallic material layer deposited by a welding operation onto one die-contacting surface of the alloy cube;
- FIG. 11 is a photograph of a sectioned 1-inch pancake that was press forged from a 3-inch alloy cube having a metallic material layer deposited by a welding operation onto one die-contacting surface of the alloy cube (the top surface as oriented in the photograph), and FIG. 11A is a micrograph taken along the cross-section of the welded surface as indicated in FIG. 11 .
- any numerical range recited herein is intended to include all sub-ranges subsumed therein.
- a range of “1 to 10” is intended to include all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10.
- Any maximum numerical limitation recited herein is intended to include all lower numerical limitations subsumed therein and any minimum numerical limitation recited herein is intended to include all higher numerical limitations subsumed therein. Accordingly, Applicants reserve the right to amend the present disclosure, including the claims, to expressly recite any sub-range subsumed within the ranges expressly recited herein. All such ranges are intended to be inherently disclosed herein such that amending to expressly recite any such sub-ranges would comply with the requirements of 35 U.S.C. ⁇ 112, first paragraph, and 35 U.S.C. ⁇ 132(a).
- grammatical articles “one”, “a”, “an”, and “the”, as used herein, are intended to include “at least one” or “one or more”, unless otherwise indicated.
- the articles are used herein to refer to one or more than one (i.e., to at least one) of the grammatical objects of the article.
- a component means one or more components, and thus, possibly, more than one component is contemplated and may be employed or used in an implementation of the described embodiments.
- the various embodiments disclosed and described herein can comprise, consist of, or consist essentially of, the features, aspects, characteristics, and the like, as variously described herein.
- the various embodiments disclosed and described herein can also comprise additional or optional features, aspects, characteristics, and the like, that are known in the art or that may otherwise be included in various embodiments as implemented in practice.
- crack sensitive alloys tend to form cracks during working operations.
- Crack sensitive alloy ingots may form cracks during hot working operations used to produce alloy articles from the crack sensitive alloy ingots.
- alloy billets may be formed from alloy ingots using forge conversion.
- Other alloy articles may be formed from alloy billets or alloy ingots using extrusion or other working operations.
- the production yield of alloy articles (e.g., alloy billets) formed from crack sensitive alloy ingots using hot working operations may be low because of the incidence of surface cracking of the alloy ingots during the hot working (e.g., during forging or extrusion).
- hot working refers to the application of force to a workpiece at a temperature greater than ambient temperature, wherein the applied force deforms the workpiece.
- the temperature of an alloy ingot undergoing the working operation may be greater than the temperature of the dies used to mechanically apply force to the surfaces of the ingot.
- the resulting thermal gradient off-set between the ingot surfaces and the contacting dies may contribute to surface cracking of the ingot during hot working, particularly for ingots formed from crack sensitive alloys, such as, for example, nickel base, iron base, nickel-iron base, and cobalt base alloys and superalloys.
- Embodiments disclosed herein are directed to ingot processing methods and hot working processes characterized by a reduction in the incidence of surface cracking of an alloy ingot during a hot working operation.
- the described methods and/or processes may comprise depositing a metallic material layer onto at least a region of a surface of an alloy ingot.
- the alloy ingot may be hot worked by applying a force to the alloy ingot at the region of the surface having the deposited metallic material layer. The applied force may deform the alloy ingot.
- the alloy ingot may comprise a crack sensitive alloy.
- various nickel base, iron base, nickel-iron base, and cobalt base alloys and superalloys may be crack sensitive, especially during hot working operations.
- An alloy ingot may be formed from such crack sensitive alloys and superalloys.
- a crack sensitive alloy ingot may be formed from alloys or superalloys including, but not limited to, Alloy 718, Alloy 720, Rene 41TM alloy, Rene 88TM alloy, Waspaloy® alloy, and Inconel® 100.
- the methods, processes, and systems described herein are generally applicable to any alloy characterized by a relatively low ductility at hot working temperatures.
- alloy includes conventional alloys and superalloys, wherein superalloys exhibit relatively good surface stability, corrosion and oxidation resistance, high strength, and high creep resistance at high temperatures.
- An alloy ingot may be formed using an ingot metallurgy operation or a powder metallurgy operation.
- an alloy ingot may be formed by VIM followed by VAR (a VIM-VAR operation).
- an alloy ingot may be formed by triple melting in which an ESR operation is performed intermediate a VIM operation and a VAR operation (a VIM-ESR-VAR operation).
- an alloy ingot may be formed using a powder metallurgy operation involving atomization of molten alloy and the collection and consolidation of resulting metallurgical powders into an ingot.
- an alloy ingot may be formed using a spray forming operation.
- VIM may be used to prepare a base alloy composition from a feedstock.
- An ESR operation may optionally be used after VIM.
- Molten alloy may be extracted from a VIM or ESR melt pool and atomized to form molten droplets.
- the molten alloy may be extracted from a melt pool using a cold wall induction guide (CIG), for example.
- CCG cold wall induction guide
- the molten alloy droplets may be deposited using a spray forming operation to form a solidified ingot.
- an alloy ingot may be heat treated and/or surface conditioned.
- an alloy ingot may be exposed to high temperatures to homogenize the alloy composition and microstructure of the ingot.
- the high temperatures may be above the recrystallization temperature of the alloy but below the melting point temperature of the alloy.
- An alloy ingot may be surface conditioned, for example, by grinding or peeling the surface of the ingot.
- An alloy ingot may also be sanded and/or buffed.
- Surface conditioning operations may be performed before and/or after any optional heat treatment steps, such as, for example, homogenization at high temperatures.
- a metallic material layer may be deposited and metallurgically bonded to at least a region of a surface of an alloy ingot.
- a metallic material layer may be deposited as a weld deposit onto a surface of an ingot.
- a weld deposit may be metallurgically bonded to at least a region of a surface of an alloy ingot using welding operations including, but not limited to, metal inert gas (MIG) welding, tungsten insert gas (TIG) welding, plasma welding, submerged arc welding, and electron-beam welding.
- MIG metal inert gas
- TOG tungsten insert gas
- the metallic material layer may comprise a metallic material that is more ductile and/or malleable than the alloy of the underlying ingot at the particular working temperature to be used.
- the metallic material layer may comprise a metallic material that exhibits greater toughness and/or lesser hardness than the alloy of the underlying ingot at the particular working temperature to be used.
- the metallic material layer insulates the underlying ingot surface from the surfaces of contacting dies, thereby preventing the underlying ingot surface from cooling to a brittle temperature at which the surface may more readily crack during hot working.
- the metallic material layer may comprise a metallic material that is oxidation resistant. In various embodiments, the metallic material layer does not oxidize during hot working or otherwise.
- the metallic material layer may comprise a metallic material exhibiting a relatively high stiffness (e.g., a relatively low elastic modulus). In various embodiments, the metallic material layer does not thin out substantially during hot working (e.g., where the application of force by one or more dies would cause a relatively low stiffness metallic material to thin out on the underlying ingot surface).
- the metallic material and the alloy forming the underlying ingot may comprise the same base metal.
- the alloy ingot comprises a nickel base alloy or superalloy (e.g., Alloy 720, Rene 88TM alloy, or Waspaloy® alloy)
- the metallic material of the deposited layer may also comprise a nickel base alloy, such as, for example, a nickel base weld alloy (e.g., Techalloy 606TM alloy (available from Techalloy Company/Central Wire)).
- the metallic material layer may be deposited to a thickness sufficient to insulate the underlying ingot surface from the surfaces of contacting dies, thereby preventing the underlying ingot surface from cooling to a temperature at which the underlying surface may more readily crack during hot working. In this manner, greater hot working temperatures may generally correlate with greater metallic material layer thicknesses. In various embodiments, the metallic material layer may be deposited to a thickness of 0.25 inches to 0.5 inches onto at least a region of a surface of an alloy ingot.
- the temperature range over which alloys can be effectively hot worked is based on the temperature at which cracks initiate in the alloy. At a given starting temperature for a hot working operation, some alloys can be effectively hot worked over a larger temperature range than other alloys because of differences in the temperature at which cracks initiate in the alloy. For alloys having a relatively small hot working temperature range (i.e., the difference between the starting temperature and the temperature at which cracks initiate), the thickness of the metallic material layer may need to be relatively greater to prevent the underlying ingot from cooling down to a brittle temperature range in which cracks initiate. Likewise, for alloys having a relatively large hot working temperature range, the thickness of the metallic material layer may be relatively smaller to and still prevent the underlying ingot from cooling down to a brittle temperature range in which cracks initiate.
- the metallic material layer may be deposited onto at least one end of an alloy ingot.
- FIGS. 1A and 1B illustrate an elongated alloy ingot 10 having opposed ends 13 a and 13 b .
- Metallic material layers 15 a and 15 b are deposited onto the ends 13 a and 13 b of the alloy ingot 10 .
- FIGS. 1A and 1B show metallic material layers on both ends 13 a and 13 b of the ingot 10
- a metallic material layer may be deposited onto only one end of an elongated alloy ingot and the other, opposed end may not have a deposited metallic material layer.
- FIGS. 1A and 1B illustrate an elongated alloy ingot 10 having opposed ends 13 a and 13 b .
- Metallic material layers 15 a and 15 b are deposited onto the ends 13 a and 13 b of the alloy ingot 10 .
- FIGS. 1A and 1B show metallic material layers on both ends 13 a and 13 b of the ingot 10
- a metallic material layer may be deposited onto only a portion or region of one or both of the opposed end surfaces of an elongated alloy ingot.
- the metallic material may be more ductile than the alloy of the ingot.
- the metallic material layer may be deposited onto at least a region of a circumferential surface of a cylindrical alloy ingot.
- FIG. 2 illustrates an alloy ingot 20 having opposed ends 23 a and 23 b and a circumferential surface 27 (indicated by dashed lines).
- a metallic material layer 25 is deposited onto the circumferential surface 27 of the alloy ingot 20 .
- FIG. 2 shows the metallic material layer fully covering the circumferential surface 27
- a metallic material layer may be deposited onto only a portion or region of a circumferential surface of a cylindrical alloy ingot.
- FIGS. 3A and 3B illustrate an alloy ingot 30 having opposed ends 33 a and 33 b and a circumferential surface 37 (indicated by dashed lines).
- Metallic material layer 35 is deposited onto the circumferential surface 37 and the ends 33 a and 33 b of the alloy ingot 30 . In this manner, the alloy ingot 30 is entirely covered with a deposited metallic material layer 35 .
- the surfaces of the underlying ingot are shown as dashed lines in FIGS. 3A and 3B .
- 3A and 3B show metallic material layers fully covering the ends and the circumferential surface of the ingot 30
- a metallic material layer also may be deposited onto only portions or regions of one or both of the opposed end surfaces and/or the circumferential surface of an elongated cylindrical alloy ingot.
- a metallic material layer may be deposited as a weld deposit onto at least a region of a surface of an alloy ingot by rotating the ingot about a long axis of the ingot and depositing the metallic material as a weld deposit onto a first region of a circumferential surface of the rotating ingot.
- the metallic material layer may be deposited using at least one stationary welding torch. The welding torch may deposit the metallic material onto the surface of the ingot as the ingot rotates and the surface passes beneath the torch. In this manner, a ring-shaped layer of metallic material may be deposited onto a first region of the circumferential surface of the cylindrical ingot as the ingot proceeds through at least one rotation.
- At least one welding torch may be re-positioned to a location adjacent to the deposited ring-shaped layer of the metallic material.
- the re-positioning may be performed by moving at least one welding torch relative to the ingot, and/or moving the ingot relative to the at least one welding torch.
- a re-positioned welding torch may then deposit additional metallic material as a weld deposit onto a second or subsequent region of the circumferential surface of the rotating ingot.
- a second or subsequent ring-shaped metallic material layer may be formed adjacent to a previously deposited ring-shaped metallic material layer.
- ring-shaped layers of metallic material may be successively formed adjacent to each other and in contact with each other so that the metallic material layers collectively form a continuous layer covering at least a region of a circumferential surface of a cylindrical ingot.
- the re-positioning of at least one welding torch and the depositing of a ring-shaped layer of metallic material may be repeated successively until the circumferential surface of the alloy ingot is substantially covered with a continuous metallic material layer.
- welding operation parameters, welding torch positioning, and ingot positioning may be predetermined and/or actively controlled to form a uniform metallic material layer over at least a region of a surface of an alloy ingot.
- FIGS. 4A-4D collectively illustrate an embodiment of the deposition of metallic material as weld deposits onto at least a region of a surface of an alloy ingot.
- Alloy ingot 100 rotates about long axis 101 as indicated by arrow 102 .
- Welding torches 110 remain stationary and deposit metallic material 150 onto the circumferential surface 170 of the ingot 100 as the ingot 100 rotates about long axis 101 .
- the metallic material 150 may be more ductile and/or malleable than the alloy of the alloy ingot 100 when the ingot is at a temperature at which the ingot 100 is worked.
- the welding torches 110 deposit metallic material 150 onto first regions 171 of the circumferential surface 170 of the ingot 100 as the circumferential surface 170 passes beneath the welding torches 110 .
- the welding torches 110 remain stationary until the ingot 100 proceeds through at least one rotation, and ring-shaped layers of metallic material 150 are deposited onto the first regions 171 of the circumferential surface 170 of the ingot 100 ( FIG. 4C ).
- the welding torches 110 are re-positioned by moving the torches a distance in a direction parallel to the long axis 101 of the ingot 100 , as indicated by arrows 112 in FIG. 4C .
- the welding torches 110 are re-positioned so that the welding torches 110 are located adjacent to the first regions 171 and, therefore, adjacent to the ring-shaped layers of metallic material 150 already deposited ( FIG. 4D ).
- 4C illustrates re-positioning the welding torches 110 by moving the welding torches 110 parallel to long axis 101
- the position of the welding torches 110 relative to the ingot 100 also may be changed by moving the ingot 100 parallel to long axis 101 .
- the re-positioned welding torches 110 deposit additional metallic material 150 ′ as weld deposits onto second regions 172 of the circumferential surface 170 of the ingot 100 as the ingot 100 rotates about long axis 101 .
- second ring-shaped layers of metallic material 150 ′ are deposited adjacent to the first ring-shaped layers of metallic material 150 .
- the changing of the relative positions of the welding torches 110 and the ingot 100 , and the depositing of ring-shaped layers of metallic material may be successively repeated until the circumferential surface 170 of the alloy ingot 100 is substantially covered with metallic material, as illustrated in FIG. 2 , for example.
- a metallic material layer may be deposited as a weld deposit onto at least a region of a surface of an ingot by moving at least one welding torch along a first region of a circumferential surface of a cylindrical ingot, in the direction of a long axis of the ingot. At least one welding torch may be moved along the first region of the circumferential surface of the cylindrical ingot, in a direction of the long axis of the ingot, while the cylindrical ingot is held stationary. Alternatively, at least one welding torch may be held stationary while the cylindrical ingot is moved in a direction of the long axis of the ingot and the first region of the circumferential surface of the cylindrical ingot passes beneath the at least one welding torch.
- At least one welding torch may deposit metallic material onto the first region of the circumferential surface of the ingot, parallel to the long axis of the ingot. In this manner, a layer of the metallic material may be deposited onto the circumferential surface of the ingot generally parallel to the long axis of the ingot.
- the cylindrical ingot may be re-positioned to move the deposited metallic material layer (and the corresponding region of the circumferential surface) away from at least one welding torch and to move a second or subsequent region of the circumferential surface toward at least one welding torch.
- additional metallic material may be deposited as a weld deposit onto the cylindrical surface of the ingot by moving at least one welding torch in a direction parallel to the long axis of the ingot along the second or subsequent region of the circumferential surface of the ingot.
- At least one welding torch may be moved along the second or subsequent region of the circumferential surface of the cylindrical ingot, in a direction parallel to a long axis of the ingot, while the cylindrical ingot is held stationary.
- at least one welding torch may be held stationary while the cylindrical ingot is moved parallel to the long axis of the ingot and the second or subsequent region of the circumferential surface of the cylindrical ingot passes beneath at least one welding torch.
- At least one welding torch may deposit metallic material onto the second or subsequent region of the circumferential surface of the ingot.
- an additional axial layer of the metallic material may be deposited onto the circumferential surface of the ingot generally parallel to the long axis of the ingot and adjacent to and in contact with a previously deposited layer of the metallic material that also was deposited generally parallel to the long axis of the ingot.
- both the position of at least one welding torch and the ingot may be moved so that the position of the at least one welding torch relative to the circumferential surface of the ingot is changed.
- the relative re-positioning of the cylindrical ingot and at least one welding torch and the depositing of layers of metallic material on the ingot's circumferential surface in directions parallel to a long axis of the ingot may be successively repeated until the circumferential surface of the alloy ingot is substantially covered with metallic material.
- welding operation parameters, welding torch positioning, and ingot positioning may be predetermined and/or actively controlled to form a uniform metallic material layer over at least a region of a surface of an alloy ingot.
- FIGS. 5A-5D collectively illustrate an embodiment of the deposition of metallic material as weld deposits onto at least a region of a surface of an alloy ingot.
- alloy ingot 200 is shown having a long axis 201 and a circumferential surface 270 .
- a layer of metallic material 250 is shown deposited onto region 271 of the circumferential surface 250 of the ingot 200 , positioned in a direction parallel to long axis 201 .
- Welding torches 210 deposit additional metallic material as weld deposits 250 ′ onto the region 272 of circumferential surface 270 as the welding torches 210 move along region 272 in a direction parallel to long axis 201 , as indicated by arrows 212 .
- the welding torches 210 move as indicated by arrows 212 until a layer of metallic material 250 is deposited along generally the entire length of ingot 200 in region 272 of the circumferential surface 270 ( FIG. 5C ).
- the ingot 200 is re-positioned to move the metallic material layer 250 (and the region 272 ) away from the welding torches 210 and to move a region 273 of the circumferential surface 270 toward the welding torches 210 .
- the ingot 200 is re-positioned by rotating the ingot 200 through a predetermined index angle, indicated by the Greek letter theta ( ⁇ ) in FIGS. 5A-5D .
- another layer of metallic material is deposited as weld deposits 250 ′′ onto the region 273 of the cylindrical surface 270 of the ingot 200 by moving the welding torches 210 along the region 273 of the circumferential surface 270 of the cylindrical ingot 200 in a direction parallel to long axis 201 , as indicated by arrows 212 .
- additional layers of metallic material 250 are formed adjacent to each other and in contact around the circumferential surface 270 of the ingot 200 .
- a first layer of metallic material was deposited onto region 271 of the circumferential surface 270 .
- the alloy ingot 200 was then rotated through a predetermined index angle ⁇ 1 .
- a second layer of metallic material was deposited onto region 272 of the circumferential surface 270 .
- the alloy ingot was then rotated through a predetermined index angle ⁇ 2 .
- a third layer is shown being deposited onto region 273 of the circumferential surface 270 in FIG. 4D in a direction parallel to long axis 201 .
- the re-positioning of the ingot 200 , movement of the welding torches 210 , and deposition of layers of metallic material may be successively repeated until the circumferential surface 270 of the alloy ingot 200 is substantially covered with metallic material, as illustrated in FIG. 2 , for example.
- FIGS. 5A-5D show welding torches 210 moving along regions ( 271 , 272 , 273 ) of the circumferential surface 270 of the ingot 200 in direction parallel to long axis 201 , indicated by arrows 212 , while the ingot 200 is held stationary.
- the welding torches 210 may be held stationary and the ingot 200 may be moved in the direction of long axis 201 so that regions ( 271 , 272 , 273 ) of the circumferential surface 270 of the ingot 200 pass beneath the stationary welding torches 210 .
- the welding torches 210 may deposit layers of metallic material 250 onto the regions ( 271 , 272 , 273 ) of the circumferential surface 270 of the ingot 200 .
- additional layers of the metallic material may be deposited onto the circumferential surface 270 of the ingot 200 generally parallel to the long axis 201 of the ingot 200 and adjacent to each other until the ingot 200 is substantially covered with metallic material, as illustrated in FIG. 2 , for example.
- the metallic material layer may be deposited as a weld deposit onto a surface of an ingot by rotating the ingot about a long axis of the ingot and depositing the metallic material as a weld deposit onto a circumferential surface of the rotating ingot.
- the metallic material layer may be deposited using at least one moving welding torch. At least one welding torch may move parallel to the long axis of the ingot and deposits the metallic material onto the surface of the ingot as the ingot rotates. In this manner, a deposit of metallic material may be deposited in a helical fashion onto the circumferential surface of the cylindrical ingot as the ingot rotates and at least one welding torch moves.
- FIG. 6A illustrates the deposition of metallic material as a weld deposit onto at least a region of a surface of an alloy ingot.
- Alloy ingot 300 is shown having a long axis 301 and a circumferential surface 370 .
- a deposit of metallic material 350 is shown deposited in a helical fashion onto the circumferential surface 370 of the ingot 300 .
- Welding torch 310 deposits the metallic material layer 350 onto the circumferential surface 370 as the welding torch 310 moves parallel to long axis 301 , as indicated by arrow 312 , while the ingot 300 simultaneously rotates about long axis 301 , as indicated by arrow 302 .
- the welding torch 310 moves as indicated by arrow 312 and the ingot 300 rotates as indicated by arrow 302 until a layer of metallic material 350 is deposited along generally the entire circumferential surface 370 ( FIG. 6B ).
- An alloy ingot including a metallic material layer deposited onto at least a region of a surface of the alloy ingot may be hot worked by applying force to the alloy ingot.
- Force may be applied to an alloy ingot in at least one region of at least one surface of the alloy ingot having a metallic material layer deposited onto at least one region.
- force may be applied to an ingot by applying the force to the metallic material layer deposited onto the ingot.
- a hot working operation may comprise a forging operation and/or an extrusion operation.
- an alloy ingot having a metallic material layer deposited onto at least a region of a surface of the alloy ingot may be upset forged and/or draw forged.
- An upset-and-draw forging operation may comprise one or more sequences of an upset forging operation and one or more sequences of a draw forging operation.
- the end surfaces of an ingot may be in contact with forging dies that apply force to the ingot that compresses the length of the ingot and increases the cross-section of the ingot.
- the side surfaces e.g., the circumferential surface of a cylindrical ingot
- forging dies that apply force to the ingot that compresses the cross-section of the ingot and increases the length of the ingot.
- FIGS. 7A and 7C illustrate an upset forging operation.
- Forging dies 480 / 480 ′ apply force to the opposed ends of an ingot 400 / 400 ′. The force is applied generally parallel to the long axis 401 / 401 ′ of the ingot 400 / 400 ′, as indicated by arrows 485 / 485 ′.
- FIG. 7A shows an ingot 400 without a deposited metallic material layer on opposed ends of the ingot 400 .
- FIG. 7C shows an ingot 400 ′ including metallic material layers 450 deposited onto the opposed ends of the ingot 400 ′.
- the ends of the ingot 400 are in contact with the forging dies 480 ( FIG. 7A ).
- the metallic material layers 450 are in contact with the forging dies 480 ′ ( FIG. 7C ).
- FIGS. 7B and 7D illustrate a die-contacting surface of each of the ingots 400 and 400 ′ after upset forging as illustrated in FIGS. 7A and 7C , respectively.
- the die-contacting surface 490 of the ingot 400 exhibits surface cracking.
- the die-contacting surface 490 ′ of the ingot 400 ′ which includes metallic material layer 450 , does not exhibit surface cracking.
- the deposited metallic material layer 450 reduces the incidence of surface cracking in a forged alloy ingot relative to an otherwise identical forged alloy ingot lacking such a metallic material layer.
- FIGS. 8A and 8C illustrate a draw forging operation.
- Forging dies 580 / 580 ′ apply force to an ingot 500 / 500 ′.
- the force is applied generally perpendicular to the long axis 501 / 501 ′ of the ingot 500 / 500 ′, as indicated by arrows 585 / 585 ′.
- the forging dies 580 / 580 ′ apply force to the ingot 500 / 500 ′ along generally the entire length of the ingot 500 / 500 ′ by moving generally parallel to the long axis 501 / 501 ′ of the ingot 500 / 500 ′, as indicated by arrows 587 / 587 ′.
- FIG. 8A shows an ingot 500 without a metallic material layer.
- FIG. 8C shows an ingot 500 ′ having a metallic material layer 550 deposited onto a circumferential surface of the ingot 500 ′.
- the circumferential surface of the ingot 500 is in contact with the forging dies 580 ( FIG. 8A ).
- the metallic material layer 550 is in contact with the forging dies 580 ′ ( FIG. 8C ).
- FIGS. 8B and 8D illustrate the die-contacting surfaces of the ingots 500 and 500 ′ after draw forging as illustrated in FIGS. 8A and 8C , respectively.
- the die-contacting surface 590 of the ingot 500 exhibits surface cracking.
- the die-contacting surface 590 ′ of the ingot 500 ′ which includes metallic material layer 550 , does not exhibit surface cracking.
- the deposited metallic material layer 550 reduces the incidence of surface cracking in a forged alloy ingot relative to an otherwise identical forged alloy ingot lacking such a metallic material layer.
- an ingot having a metallic material layer deposited onto at least a region of a surface of the ingot may be subjected to one or more upset-and-draw forging operations.
- an ingot may be first upset forged and then draw forged.
- the upset and draw sequence may be repeated twice more for a total of three sequential upset and draw forging operations.
- One or more of the die-contacting surfaces of the ingot may have a metallic material layer deposited onto the die-contacting surfaces of the ingot before the ingot is forged.
- an ingot having a metallic material layer deposited onto at least a region of a surface of the ingot may be subjected to one or more extrusion operations.
- a cylindrical ingot may be forced through a circular die, thereby decreasing the diameter and increasing the length of the ingot.
- One or more of the die-contacting surfaces of the ingot may have a metallic material layer deposited onto die-contacting surfaces of the ingot before the ingot is extruded.
- the methods and processes described herein may be used to produce a wrought billet from a cast, consolidated, or spray formed ingot.
- the forge conversion or extrusion conversion of an ingot to a billet or other worked article may produce a finer grain structure in the article as compared to the former ingot.
- the methods and processes described herein may improve the yield of forged or extruded products (such as, for example, billets) from alloy ingots because the metallic material layer may reduce the incidence of surface cracking of the ingot during the forging and/or extrusion operations.
- a relatively more ductile metallic material layer deposited onto at least a region of a surface of a relatively less ductile alloy ingot may more readily tolerate the strain induced by working dies. It also has been observed that a metallic material layer deposited onto at least a region of a surface of an alloy ingot may also more readily tolerate the temperature differential between the working dies and the ingot during hot working. In this manner, it has been observed that a deposited metallic material layer may exhibit zero or minor surface cracking while surface crack initiation is prevented or reduced in the underlying ingot during working.
- At least a portion of a deposited metallic material layer may be removed from the product formed from the ingot during the hot working.
- a grinding, peeling, and/or turning operation may be used to remove at least a portion of the metallic material layer.
- at least a portion of a deposited metallic material layer may be removed from a billet formed by working an ingot by peeling (lathe-turning) and/or grinding the billet.
- ingots having a deposited metallic material layer may be hot worked to form products that may be used to fabricate various articles.
- the processes described herein may be used to form nickel base, iron base, nickel-iron base, or cobalt base alloy or superalloy billets.
- Billets or other products formed from hot worked ingots may be used to fabricate articles including, but not limited to, turbine components, such as, for example, disks and rings for turbine engines and various land based turbines.
- Other articles fabricated from ingots processed according to various embodiments described herein may include, but are not limited to, valves, engine components, shafts, and fasteners.
- Embodiments disclosed herein are also directed to an ingot processing system and an ingot processing apparatus.
- the ingot processing system and apparatus may comprise an ingot positioning apparatus and a welding apparatus.
- the ingot positioning apparatus may comprise an ingot rotating apparatus configured to rotate an ingot about a long axis of the ingot.
- the welding apparatus may be configured to deposit a metallic material layer as a weld deposit onto at least a region of a surface of an ingot.
- the ingot rotating apparatus may comprise a lathe configured to rotate an ingot about the long axis of the ingot.
- the ingot rotating apparatus may rotate the ingot continuously through one or more full rotations, or the ingot rotating device may discontinuously rotate the ingot sequentially through predetermined index angles, depending, for example, upon the configuration of the welding apparatus.
- the welding apparatus may comprise at least one welding torch, such as, for example, a wire-fed MIG welding torch. At least one welding torch may be configured to deposit a layer of a metallic material as a weld deposit onto at least a region of a surface of an ingot. At least one welding torch may be configured to deposit a metallic material layer as a weld deposit onto at least a region of an end surface of an ingot. At least one welding torch may be configured to deposit a metallic material layer as a weld deposit onto at least a region of a circumferential surface of a cylindrical ingot. At least one welding torch may be configured to deposit metallic material onto the top of the circumferential surface of a cylindrical ingot. In this manner, gravity effects on a deposited weld bead may be reduced or eliminated.
- At least one welding torch may be a MIG welding torch. At least one welding torch may have a wire feed. At least one welding torch may be positioned a predetermined distance from a surface of an ingot. At least one welding torch may be configured with a predetermined wire feed rate, a predetermined wire voltage, and/or a predetermined inert gas purge flow rate. The torch-ingot surface distance, wire feed rate, voltage, inert gas purge flow rate, and/or various other welding operation parameters may be predetermined so that a metallic material layer is uniformly weld deposited onto the ingot. The identity of various other welding operation parameters may depend upon the particular type of welding operation utilized (e.g., MIG, TIG, etc.).
- the heat input (e.g., energy per unit length) used in the particular welding operation may be maintained substantially uniform over the surface of the ingot onto which the metallic material is weld deposited. In this manner, weld-associated cracking of the underlying ingot surface may be reduced or eliminated, and the quality of the metallurgical bond between the underlying ingot and the weld deposit may be enhanced. In various embodiments, the heat input to the ingot during a welding operation may be minimized.
- the welding apparatus may comprise one welding torch, a linear array of two or more welding torches, or a two- or three-dimensional array of three or more welding torches.
- FIGS. 4A-4D , 5 A- 5 D show a linear array of three welding torches.
- FIG. 6A shows one welding torch.
- the number and configuration of the welding torches comprising the welding apparatus may vary depending upon the particular implementation of the described ingot processing methods, systems, and apparatuses.
- the ingot processing system may comprise a control system.
- the control system may be configured to move and position the welding apparatus in conjunction with the ingot positioning apparatus to uniformly deposit a metallic material layer onto at least a region of a surface of the ingot.
- the control system may control the torch-surface distance, welding operation parameters, the movement and position of at least one welding torch relative to an ingot surface, and/or the movement and positioning of an ingot.
- the control system may be configured to move at least one welding torch in a generally linear manner parallel to the long axis of an ingot and along a region of the circumferential surface of the ingot parallel to the long axis.
- the control system may also be configured to position at least one welding torch to deposit metallic material as a weld deposit onto opposed end surfaces of an ingot.
- control system may be configured to control at least one welding torch to uniformly deposit the metallic material onto a rough surface of the ingot.
- the wire feed rate of a consumable electrode in a MIG welding torch, the voltage of the wire electrode, the torch-ingot surface distance, and the torch movement/positioning may be actively controlled to deliver a stable arc over a rotating or stationary ingot. In this manner, a substantially uniform layer of metallic material may be deposited onto the ingot.
- the control system may be configured to automate the deposition of a metallic material layer as a weld deposit onto at least one end of an alloy ingot.
- the control system may be configured to automate the deposition of a metallic material layer as a weld deposit onto a circumferential surface of a cylindrical alloy ingot.
- the ingot processing system may be configured to deposit metallic material as a weld deposit onto a first region of a circumferential surface of a rotating cylindrical ingot using at least one stationary welding torch. In this manner, the ingot processing system may deposit a ring-shaped layer of the metallic material around the circumferential surface of the cylindrical ingot.
- the ingot processing system may be configured to re-position at least one welding torch adjacent to a deposited ring-shaped layer of the metallic material after a rotating cylindrical ingot proceeds through at least one rotation.
- the ingot processing system may be configured to deposit the metallic material as a weld deposit onto a second or subsequent region of the circumferential surface of the rotating cylindrical ingot using at least one re-positioned stationary welding torch.
- the ingot processing system may deposit another ring-shaped layer of the metallic material onto the circumferential surface of the cylindrical ingot.
- the ingot processing system may be configured to repeat the re-positioning of at least one welding torch and the deposition of ring-shaped metallic material layers in an automated manner until the circumferential surface of a cylindrical ingot is substantially covered with a metallic material layer.
- the ingot processing system may be configured to deposit metallic material as a weld deposit onto a first region of a circumferential surface of a stationary ingot along a direction parallel to a long axis of the ingot using at least one welding torch configured to move parallel to the long axis of the ingot and along the first region. In this manner, the ingot processing system may deposit a layer of the metallic material onto the first region of the circumferential surface of the cylindrical ingot.
- the ingot processing system may be configured to re-position the cylindrical ingot to move the first region of the circumferential surface away from at least one welding torch and to move a second region of the circumferential surface toward at least one welding torch. For example, the ingot may be rotated through a predetermined index angle by the ingot rotating device.
- the ingot processing system may be configured to deposit metallic material as a weld deposit onto a second or subsequent region of the circumferential surface of the stationary ingot along a direction parallel to a long axis of the ingot using at least one welding torch configured to move parallel to the long axis of the ingot and along the second region. In this manner, the ingot processing system may deposit a layer of the metallic material onto the second region of the circumferential surface of the cylindrical ingot.
- the ingot processing system may be configured to repeat the re-positioning of the ingot and the depositing of metallic material layers along a direction parallel to a long axis of an ingot in an automated manner until the circumferential surface of a cylindrical ingot is substantially covered with a metallic material layer.
- the ingot processing system may be configured to deposit metallic material as a weld deposit onto a surface of an ingot by rotating the ingot about a long axis of the ingot and simultaneously moving the welding torch parallel to a long axis of the ingot.
- the metallic material layer may be deposited using at least one moving welding torch under the control of the control system. In this manner, a deposit of metallic material may be deposited in a helical fashion onto the circumferential surface of the cylindrical ingot as the ingot rotates about the long axis and as at least one welding torch moves parallel to the long axis.
- Three-inch cubes of Rene 88TM alloy were used in a hot working operation.
- the cubes were randomly cut from scrap portions of a Rene 88TM billet.
- the cubes were heat treated at 2100° F. for 4 hours to increase the grain size of the alloy cubes to match the workability characteristics of a Rene 88TM ingot.
- One face surface of each cube was conditioned by grinding on a disk grinder followed by sanding with a belt sander.
- a TechAlloy 606TM alloy layer was deposited as a weld deposit onto the conditioned face surface of each cube using MIG welding (0.045 inch diameter TechAlloy 606 wire, 220 inch-per-minute, 18V wire voltage, 50 cubic feet per minute argon purge).
- FIG. 9 is a photograph of two 3-inch cubes of Rene 88TM alloy each having TechAlloy 606TM alloy layers weld deposited onto the top surfaces as oriented in the photograph.
- a Rene 88TM alloy cube having a TechAlloy 606TM alloy layer was heated to 2000° F. over a one-hour period and press forged at temperature.
- the face surface having the TechAlloy 606TM alloy layer was placed in contact with the bottom die and the opposite face surface, which lacked a TechAlloy 606TM alloy layer, was placed in contact with the upper die.
- the 3-inch cube was press forged to a 1-inch pancake using an approximately 1-inch-per-second strain rate.
- FIGS. 10A and 10B are photographs of opposing sides of a 1-inch pancake pressed forged from a 3-inch cube.
- FIG. 10A shows the non-layered side surface of the pancake
- FIG. 10B shows the side surface having the TechAlloy 606TM alloy layer.
- the crack sensitivity of the Rene 88TM alloy is visible on the forged, non-layered surface shown in FIG. 10A .
- Surface cracking is clearly visible on the surface lacking a TechAlloy 606TM alloy layer as shown in FIG. 10A .
- the TechAlloy 606TM alloy layer substantially reduced the incidence of surface cracking of the alloy during the forging.
- FIG. 11 is a photograph of a sectioned 1-inch pancake pressed forged from a 3-inch alloy cube as described above.
- the interface between the TechAlloy 606TM alloy layer and the underlying forged Rene 88TM was imaged using optical microscopy at a mid-radius location (labeled “ 11 A” in FIG. 11 ), which corresponded to the cross-section of the welded surface of the pancake (the top surface as oriented in the photograph).
- FIG. 11A is a micrograph taken at the mid-radius location as indicated in FIG. 11 .
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UAA201210478A UA111712C2 (uk) | 2010-02-05 | 2011-01-24 | Системи і способи для обробки зливків із сплавів |
AU2011213196A AU2011213196B2 (en) | 2010-02-05 | 2011-01-24 | Systems and methods for processing alloy ingots |
RU2012137783/02A RU2599925C2 (ru) | 2010-02-05 | 2011-01-24 | Системы и способы для обработки слитков из сплавов |
ES11703525T ES2699697T3 (es) | 2010-02-05 | 2011-01-24 | Sistemas y métodos para el procesamiento de lingotes de aleación |
JP2012551996A JP5894087B2 (ja) | 2010-02-05 | 2011-01-24 | 合金インゴットを処理するためのシステムおよび方法 |
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CN201180007922.XA CN102741005B (zh) | 2010-02-05 | 2011-01-24 | 用于加工合金锭的系统和方法 |
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PT11703525T PT2531319T (pt) | 2010-02-05 | 2011-01-24 | Sistemas e métodos para processar lingotes de liga |
TW100104023A TWI584890B (zh) | 2010-02-05 | 2011-02-01 | 加工合金錠之系統及方法 |
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