RU95122121A - Синтетический слоистый материал, мсм-56, его получение и использование - Google Patents
Синтетический слоистый материал, мсм-56, его получение и использованиеInfo
- Publication number
- RU95122121A RU95122121A RU95122121/04A RU95122121A RU95122121A RU 95122121 A RU95122121 A RU 95122121A RU 95122121/04 A RU95122121/04 A RU 95122121/04A RU 95122121 A RU95122121 A RU 95122121A RU 95122121 A RU95122121 A RU 95122121A
- Authority
- RU
- Russia
- Prior art keywords
- synthetic
- denotes
- calcined
- moles
- chosen
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims 7
- 229920002994 synthetic fiber Polymers 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 239000007858 starting material Substances 0.000 claims 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-Dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N Mesitylene Chemical compound CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000002648 laminated material Substances 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 229920003219 poly( p-phenylene oxide) Polymers 0.000 claims 1
Claims (8)
1. Синтетический слоистый материал, состав которого соответствует молярному соотношению
X2O3 : (n)YO2
где n имеет значение, не превышающее приблизительно 35, Х обозначает трехвалентный элемент, а Y обозначает четырехвалентный элемент, при этом указанный материал характеризуется сорбционной способностью по отношению к 1,3,5-триметилбензолу, равной по крайней мере 35 мкл на грамм прокаленного синтетического материала, первоначальным поглощением в течение 20 с, составляющим 15 мг 2,2-диметилбутана на грамм прокаленного синтетического материала, а рентгенограмма прокаленного синтетического материала имеет максимумы постоянной d, равные 12,4 +/- 0,2, 9,9 +/- 0,3, 6,9 +/- 0,1, 6,2 +/- 0,1, 3,55 +/- 0,07 и 3,42 +/- 0,07 ангстрем.
X2O3 : (n)YO2
где n имеет значение, не превышающее приблизительно 35, Х обозначает трехвалентный элемент, а Y обозначает четырехвалентный элемент, при этом указанный материал характеризуется сорбционной способностью по отношению к 1,3,5-триметилбензолу, равной по крайней мере 35 мкл на грамм прокаленного синтетического материала, первоначальным поглощением в течение 20 с, составляющим 15 мг 2,2-диметилбутана на грамм прокаленного синтетического материала, а рентгенограмма прокаленного синтетического материала имеет максимумы постоянной d, равные 12,4 +/- 0,2, 9,9 +/- 0,3, 6,9 +/- 0,1, 6,2 +/- 0,1, 3,55 +/- 0,07 и 3,42 +/- 0,07 ангстрем.
2. Синтетический материал по п. 1, где X выбирают из алюминия, бора, железа и галлия, а Y выбирают из кремния и германия.
3. Материал по п. 1, где Х обозначает алюминий, а Y обозначает кремний.
4. Материал по п. 1, где величина n составляет от 5 до не более 25.
5. Материал по п. 1, где n равно от 10 до 20.
6. Материал по п. 1, имеющий состав сразу после получения, в пересчете на безводную основу в терминах молей оксидов на n молей УО2, который выражается следующей формулой
(0-2)М2О:(l-2)R:Х2О3:(n)УО2,
где М обозначает щелочной или щелочноземельный металл, а R обозначает органический фрагмент.
(0-2)М2О:(l-2)R:Х2О3:(n)УО2,
где М обозначает щелочной или щелочноземельный металл, а R обозначает органический фрагмент.
7. Материал по п. 6, где R выбирают из группы, включающей циклоалкиламин, азациклоалкил, диазациклоалкан и их смеси, при этом алкил содержит от 5 до 8 атомов углерода.
8. Способ конверсии исходного материала, содержащего органические соединения, в продукты конверсии, который заключается в контактировании указанного исходного материала с синтетическим слоистым материалом по п. 1.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/051,952 US5362697A (en) | 1993-04-26 | 1993-04-26 | Synthetic layered MCM-56, its synthesis and use |
US08/051,952 | 1993-04-26 | ||
PCT/US1994/004284 WO1994025539A1 (en) | 1993-04-26 | 1994-04-19 | Synthetic layered material, mcm-56, its synthesis and use |
Publications (2)
Publication Number | Publication Date |
---|---|
RU95122121A true RU95122121A (ru) | 1997-10-20 |
RU2140962C1 RU2140962C1 (ru) | 1999-11-10 |
Family
ID=21974430
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU95122121A RU2140962C1 (ru) | 1993-04-26 | 1994-04-19 | Синтетический слоистый материал мсм-56, его получение и использование |
Country Status (20)
Country | Link |
---|---|
US (4) | US5362697A (ru) |
EP (1) | EP0696308B1 (ru) |
JP (1) | JP3718222B2 (ru) |
KR (1) | KR100301080B1 (ru) |
CN (1) | CN1041216C (ru) |
AT (1) | ATE174616T1 (ru) |
AU (1) | AU678235B2 (ru) |
BR (1) | BR9406361A (ru) |
CA (1) | CA2161414C (ru) |
CZ (1) | CZ277495A3 (ru) |
DE (1) | DE69415313T2 (ru) |
DK (1) | DK0696308T3 (ru) |
ES (1) | ES2126106T3 (ru) |
HU (1) | HU217019B (ru) |
PL (1) | PL175647B1 (ru) |
RO (1) | RO115361B1 (ru) |
RU (1) | RU2140962C1 (ru) |
TW (1) | TW311889B (ru) |
WO (1) | WO1994025539A1 (ru) |
ZA (1) | ZA942733B (ru) |
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-
1993
- 1993-04-26 US US08/051,952 patent/US5362697A/en not_active Expired - Lifetime
-
1994
- 1994-04-19 JP JP51846594A patent/JP3718222B2/ja not_active Expired - Lifetime
- 1994-04-19 RO RO95-01864A patent/RO115361B1/ro unknown
- 1994-04-19 CN CN94192390A patent/CN1041216C/zh not_active Expired - Lifetime
- 1994-04-19 CZ CZ952774A patent/CZ277495A3/cs unknown
- 1994-04-19 ES ES94913426T patent/ES2126106T3/es not_active Expired - Lifetime
- 1994-04-19 PL PL94311293A patent/PL175647B1/pl unknown
- 1994-04-19 HU HU9503056A patent/HU217019B/hu not_active IP Right Cessation
- 1994-04-19 DE DE69415313T patent/DE69415313T2/de not_active Expired - Lifetime
- 1994-04-19 AU AU65596/94A patent/AU678235B2/en not_active Expired
- 1994-04-19 BR BR9406361A patent/BR9406361A/pt not_active IP Right Cessation
- 1994-04-19 EP EP94913426A patent/EP0696308B1/en not_active Expired - Lifetime
- 1994-04-19 CA CA002161414A patent/CA2161414C/en not_active Expired - Lifetime
- 1994-04-19 DK DK94913426T patent/DK0696308T3/da active
- 1994-04-19 KR KR1019950704692A patent/KR100301080B1/ko not_active IP Right Cessation
- 1994-04-19 AT AT94913426T patent/ATE174616T1/de not_active IP Right Cessation
- 1994-04-19 RU RU95122121A patent/RU2140962C1/ru active
- 1994-04-19 WO PCT/US1994/004284 patent/WO1994025539A1/en not_active Application Discontinuation
- 1994-04-20 ZA ZA942733A patent/ZA942733B/xx unknown
- 1994-05-05 TW TW083104092A patent/TW311889B/zh not_active IP Right Cessation
- 1994-05-26 US US08/249,609 patent/US5453554A/en not_active Expired - Lifetime
- 1994-06-27 US US08/266,082 patent/US5536894A/en not_active Expired - Lifetime
-
1995
- 1995-05-30 US US08/452,919 patent/US5557024A/en not_active Expired - Lifetime
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