WO2011108720A1 - リチウムイオン電池用正極活物質、リチウムイオン電池用正極、及びリチウムイオン電池 - Google Patents
リチウムイオン電池用正極活物質、リチウムイオン電池用正極、及びリチウムイオン電池 Download PDFInfo
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
- C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H01M10/05—Accumulators with non-aqueous electrolyte
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- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a positive electrode active material for a lithium ion battery, a positive electrode for a lithium ion battery, a lithium ion battery, and a method for producing a positive electrode active material for a lithium ion battery.
- Lithium-containing transition metal oxides are generally used as positive electrode active materials for lithium ion batteries. Specifically, lithium cobaltate (LiCoO 2 ), lithium nickelate (LiNiO 2 ), lithium manganate (LiMn 2 O 4 ), etc., improved characteristics (higher capacity, cycle characteristics, storage characteristics, reduced internal resistance) In order to improve the rate characteristics and safety, it is underway to combine them. Lithium ion batteries for large-scale applications such as in-vehicle use and load leveling are required to have different characteristics from those of conventional mobile phones and personal computers.
- Patent Document 1 includes secondary particles and / or primary particles composed of a plurality of primary particles, and an average represented by the formula (1).
- m represents the number of primary particles alone
- p represents the number of primary particles constituting the secondary particles
- s represents the number of secondary particles.
- the positive electrode active material for a nonaqueous electrolyte secondary battery having a composition represented by the following formula Li X Co 1-y M y O 2 + Z (Wherein M is Na, Mg, Ca, Y, rare earth element, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ni, Cu, Ag, Zn, B
- Patent Document 2 discloses a non-aqueous secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte, wherein the positive electrode includes a lithium-containing composite oxide, a conductive additive, and a binder.
- the lithium-containing composite oxide is represented by the general formula Li 1 + x + ⁇ Ni ( 1-xy + ⁇ ) / 2 Mn (1-xy- ⁇ ) / 2 M y O 2 [ However, 0 ⁇ x ⁇ 0.05, ⁇ 0.05 ⁇ x + ⁇ ⁇ 0.05, 0 ⁇ y ⁇ 0.4, ⁇ 0.1 ⁇ ⁇ ⁇ 0.1, and M is Mg, Ti 1 or more elements selected from the group consisting of Cr, Fe, Co, Cu, Zn, Al, Ge, and Sn], and a composite oxide in which primary particles aggregate to form secondary particles.
- the lithium-containing composite wherein the primary particles have an average particle diameter of 0.8 to 3 ⁇ m, the secondary particles have an average particle diameter of 5 to 20 ⁇ m, and a BET specific surface area of 0.6 to 2 m 2 / g It is a mixture containing oxide A and lithium-containing composite oxide B having an average particle size smaller than the average particle size of secondary particles of composite oxide A, and the average particle size of composite oxide B is A non-aqueous solution characterized in that it is 3/5 or less of the average particle diameter of the secondary particles of the composite oxide A, and the ratio of the composite oxide B is 10 to 40% by weight of the whole positive electrode active material A secondary battery is disclosed. And according to this, it is described that it is possible to provide a non-aqueous secondary battery that has a high capacity, excellent cycle durability, and storage stability at high temperatures.
- Patent Document 3 discloses LiNi 1-x M x O 2 (where M is at least one selected from the group consisting of Co, Al, Mg, Mn, Ti, Fe, Cu, Zn, and Ga).
- Nickel composite oxide obtained by heat-treating nickel composite hydroxide in which M is dissolved or added in producing a lithium metal composite oxide represented by 0.25> x ⁇ 0). And a lithium compound and a heat treatment to obtain a lithium metal composite oxide, wherein a nickel composite hydroxide in which M is dissolved or added in advance is heat-treated at a temperature of 650 ° C. or higher and lower than 900 ° C.
- the obtained nickel composite oxide and lithium compound mixture is heat-treated at a temperature of 650 ° C. or higher and 850 ° C.
- the method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery characterized by lowering the heat treatment temperature of the mixture of compound and the lithium compound is disclosed. And according to this, it is described that a secondary battery capable of increasing the capacity of the battery, improving the coulomb efficiency and reducing the irreversible capacity can be provided.
- the oxide is defined from the viewpoint of the primary particle diameter, the specific surface area, and the like, thereby trying to improve various battery characteristics. There is room for improvement as a positive electrode active material for a high quality lithium ion battery.
- an object of the present invention is to provide a positive electrode active material for a lithium ion battery having good battery characteristics.
- the present inventor has found that there is a close correlation between the amount of oxygen of the positive electrode active material, the average particle size and specific surface area of primary particles, and battery characteristics. That is, it has been found that particularly good battery characteristics can be obtained when the amount of oxygen in the positive electrode active material is greater than or equal to a certain value and the average particle diameter and specific surface area of the primary particles are within predetermined ranges.
- Composition formula Li x Ni 1- y My O 2 + ⁇
- M is one or more selected from Sc, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr. Yes, 0.9 ⁇ x ⁇ 1.1, 0 ⁇ y ⁇ 0.7, and 0.05 ⁇ ⁇ ⁇ 0.2. And includes primary particles and a tap density of 1.3 to 2.6 g / cm 3 ,
- the positive electrode active material for lithium ion batteries has an average primary particle size of 0.3 to 3.0 ⁇ m and a specific surface area of 0.3 to 2.3 m 2 / g.
- the positive electrode active material for a lithium ion battery according to the present invention has a tap density of 1.4 to 2.6 g / cm 3 .
- the positive electrode active material for a lithium ion battery according to the present invention has a tap density of 1.8 to 2.5 g / cm 3 .
- the positive electrode active material for a lithium ion battery according to the present invention is a maximum when the particle size distribution graph (X axis: particle diameter [ ⁇ m], Y axis: relative particle amount [%]) has a particle diameter of 1 ⁇ m or more.
- the difference between the maximum point particle diameter and the median diameter (D50) is 1.5 ⁇ m or less.
- the positive electrode active material for a lithium ion battery according to the present invention has a maximum particle size of 2 to 15 ⁇ m.
- the positive electrode active material for a lithium ion battery according to the present invention is at least one selected from M and Mn.
- the secondary particles have an average particle size of 0.6 to 3.0 ⁇ m and a specific surface area of 0.4 to 1.5 m 2 / g. It is.
- the positive electrode active material for a lithium ion battery according to the present invention has an average primary particle size of 1.6 to 2.0 ⁇ m and a specific surface area of 0.5 to 1.0 m 2 / g. is there.
- the present invention is a positive electrode for a lithium ion battery using the positive electrode active material for a lithium ion battery according to the present invention.
- the present invention is a lithium ion battery using the positive electrode for a lithium ion battery according to the present invention.
- a positive electrode active material for a lithium ion battery having good battery characteristics can be provided.
- FIG. 3 is a graph illustrating firing temperature-primary particle diameter according to examples and comparative examples. It is a SEM photograph concerning an example and a comparative example. It is a primary particle diameter-tap density graph concerning an Example and a comparative example. It is a particle size distribution graph of the positive electrode active material which concerns on an Example and a comparative example.
- lithium cobaltate LiCoO 2
- lithium-containing transition metal oxides such as lithium nickelate (LiNiO 2 ) and lithium manganate (LiMn 2 O 4 ).
- the positive electrode active material for a lithium ion battery of the present invention produced using such a material is Composition formula: Li x Ni 1- y My O 2 + ⁇
- M is one or more selected from Sc, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr. Yes, 0.9 ⁇ x ⁇ 1.1, 0 ⁇ y ⁇ 0.7, and 0.05 ⁇ ⁇ ⁇ 0.2. It is represented by The ratio of lithium to the total metal in the positive electrode active material for lithium ion batteries is 0.9 to 1.1. However, when the ratio is less than 0.9, it is difficult to maintain a stable crystal structure, and when it exceeds 1.1, the capacity is high. This is because of a low.
- oxygen is expressed as O 2 + ⁇ (0.05 ⁇ ⁇ ⁇ 0.2) as described above in the composition formula, and is contained in excess.
- battery characteristics such as capacity, rate characteristics, and capacity retention are improved.
- the positive electrode active material for a lithium ion battery of the present invention contains primary particles, the average particle size of the primary particles is 0.3 to 3.0 ⁇ m, and the specific surface area is 0.3 to 2.3 m 2 / g.
- the average particle diameter of the primary particles is preferably 0.3 to 3.0 ⁇ m.
- the average particle size of the primary particles is preferably 0.6 to 3.0 ⁇ m, more preferably 1.6 to 2.0 ⁇ m.
- the specific surface area is preferably 0.3 to 2.3 m 2 / g.
- the specific surface area is less than 0.3 m 2 / g, the reaction area becomes small, the current load characteristics deteriorate, and the capacity decreases, which is not desirable. If the specific surface area exceeds 2.3 m 2 / g, the electrode is produced. This is not desirable because the amount of solvent to be used increases and it becomes difficult to apply to the current collector.
- the specific surface area is preferably 0.4 to 1.5 m 2 / g, more preferably 0.5 to 1.0 m 2 / g.
- the positive electrode active material for a lithium ion battery may be a powder in which primary particles and secondary particles composed of a plurality of primary particles are mixed.
- the positive electrode active material for a lithium ion battery of the present invention has a tap density of 1.3 to 2.6 g / cm 3 .
- the tap density is less than 1.3 g / cm 3 , the filling weight in the same volume is reduced, so that it is difficult to secure a high capacity.
- a high firing temperature is required to improve the tap density.
- the tap density is preferably 1.4 to 2.6 g / cm 3 , more preferably 1.8 to 2.5 g / cm 3 .
- the positive electrode active material for a lithium ion battery of the present invention has a maximum point when the particle diameter is 1 ⁇ m or more.
- the difference between the particle size and the median diameter (D50) is preferably 1.5 ⁇ m or less. According to such a configuration, the uniformity of the particle size and shape of the primary particles is improved, and variations in battery characteristics among individual positive electrode particles are reduced.
- the difference between the maximum point particle size and the median diameter (D50) is more preferably 1.0 ⁇ m or less, and typically 0.2 to 1.0 ⁇ m. Further, it is preferable that the particle size of the maximum point is 2 to 15 ⁇ m.
- the binder is dissolved in an organic solvent (N-methylpyrrolidone), the positive electrode material and a conductive material are mixed to form a slurry, applied onto an Al foil, and dried.
- organic solvent N-methylpyrrolidone
- the positive electrode is pressed to increase the amount of the organic solvent used at this time, there is a possibility that the density of the positive electrode active material in the positive electrode decreases and the battery characteristics become poor.
- the particle size of the maximum point is more than 15 ⁇ m, there is a possibility that a gap between the particles becomes large, the tap density is lowered, and the battery characteristics are deteriorated.
- the particle size at the maximum point is more preferably 2 to 11 ⁇ m.
- the positive electrode for a lithium ion battery includes, for example, a positive electrode mixture prepared by mixing a positive electrode active material for a lithium ion battery having the above-described configuration, a conductive additive, and a binder from an aluminum foil or the like.
- the current collector has a structure provided on one side or both sides.
- the lithium ion battery which concerns on embodiment of this invention is equipped with the positive electrode for lithium ion batteries of such a structure.
- a metal salt solution is prepared.
- the metal is at least one selected from Ni and Sc, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B, and Zr. It is.
- the metal salt is sulfate, chloride, nitrate, acetate, etc., and nitrate is particularly preferable.
- each metal contained in the metal salt is adjusted so as to have a desired molar ratio. Thereby, the molar ratio of each metal in the positive electrode active material is determined.
- lithium carbonate is suspended in pure water, and then the metal salt solution of the metal is added to prepare a lithium salt solution slurry. At this time, fine particles of lithium-containing carbonate precipitate in the slurry. If the lithium compound does not react during heat treatment such as sulfate or chloride as a metal salt, it is washed with a saturated lithium carbonate solution and then filtered off. When the lithium compound reacts as a lithium raw material during heat treatment, such as nitrate or acetate, it can be used as a calcining precursor without being washed, filtered off as it is, and dried. Next, the lithium-containing carbonate separated by filtration is dried to obtain a powder of a lithium salt complex (a precursor for a lithium ion battery positive electrode material).
- a lithium salt complex a precursor for a lithium ion battery positive electrode material
- a firing container having a predetermined capacity is prepared, and this firing container is filled with a precursor powder for a lithium ion battery positive electrode material.
- the firing container filled with the precursor powder for the lithium ion battery positive electrode material is transferred to a firing furnace and fired. Firing is performed by heating and holding in an oxygen atmosphere for a predetermined time. Further, it is preferable to perform baking under a pressure of 101 to 202 KPa because the amount of oxygen in the composition further increases.
- the firing temperature is an important factor affecting the crystallinity (composition, average particle size of primary particles, non-surface area, tap density, particle size distribution) of the positive electrode active material, and can be performed at 700 to 1100 ° C.
- the quantity of lithium carbonate used as a metal composition it is not only necessary to simply adjust the firing temperature within a certain range, but in relation to the composition of the lithium salt complex, etc., an appropriate firing temperature range. It is necessary to perform firing in the temperature range.
- the tap density of the positive electrode active material is 1.3 to 2.6 g / cm 3 , but in order to obtain such a high tap density, the composition of the lithium salt composite as a raw material is not used. However, it is necessary to carry out at a temperature higher than the firing temperature generally used. Thereafter, the powder is taken out from the firing container and pulverized to obtain a positive electrode active material powder.
- Examples 1 to 15 First, after suspending lithium carbonate of the input amount shown in Table 1 in 3.2 liters of pure water, 4.8 liter of metal salt solution was charged. Here, the nitrate hydrate of each metal was adjusted so that each metal might become the composition ratio of Table 1, and the total metal mole number might be set to 14 mol.
- the suspended amount of lithium carbonate was such that the product (lithium ion secondary battery positive electrode material, ie, positive electrode active material) was Li x Ni 1- y My O 2 + ⁇ and x was a value shown in Table 1. Are respectively calculated by the following equations.
- W (g) 73.9 ⁇ 14 ⁇ (1 + 0.5X) ⁇ A
- “A” is a numerical value to be multiplied in order to subtract the amount of lithium from the lithium compound other than lithium carbonate remaining in the raw material after filtration from the amount of suspension in addition to the amount necessary for the precipitation reaction. is there.
- “A” is 0.9 when lithium salt reacts as a firing raw material such as nitrate or acetate, and “1” when lithium salt does not react as a firing raw material such as sulfate or chloride. 0.
- fine particles of lithium-containing carbonate were precipitated in the solution, and this precipitate was filtered off using a filter press.
- the precipitate was dried to obtain a lithium-containing carbonate (a precursor for a lithium ion battery positive electrode material).
- a firing container was prepared, and this firing container was filled with a lithium-containing carbonate.
- the obtained oxide was crushed to obtain a powder of a lithium ion secondary battery positive electrode material.
- Example 16 Example 16 was carried out except that each raw material had a composition as shown in Table 1, the metal salt was chloride, lithium-containing carbonate was precipitated, washed with a saturated lithium carbonate solution, and filtered. The same treatment as in Examples 1 to 15 was performed.
- Example 17 Example 17 was carried out except that each material of the raw material had the composition shown in Table 1, the metal salt was sulfate, the lithium-containing carbonate was precipitated, washed with a saturated lithium carbonate solution, and filtered. The same treatment as in Examples 1 to 15 was performed.
- Example 18 As Example 18, the same processing as in Examples 1 to 15 was performed, except that each metal of the raw material had a composition as shown in Table 1 and calcination was performed not under atmospheric pressure but under a pressure of 120 KPa.
- Comparative Examples 1 to 7 As Comparative Examples 1 to 7, the raw materials were made of the compositions shown in Table 1, and the same treatment as in Examples 1 to 15 was performed.
- each positive electrode material was measured with a laser diffraction particle size distribution analyzer SALD-3000J manufactured by Shimadzu Corporation.
- the metal content in each positive electrode material was measured with an inductively coupled plasma emission spectrometer (ICP-AES), and the composition ratio (molar ratio) of each metal was calculated.
- the oxygen content was measured by the LECO method and ⁇ was calculated.
- the average primary particle size is determined by observing 100 primary particles with SEM (Scanning Electron Microscope) photographs of the powder of each positive electrode material, calculating the particle size, and calculating the average value. Calculated.
- the specific surface area was the BET value, and the tap density was the density after 200 taps.
- each positive electrode material, conductive material, and binder are weighed in a ratio of 85: 8: 7, and the positive electrode material and the conductive material are mixed with the binder dissolved in an organic solvent (N-methylpyrrolidone). Then, it was made into a slurry, applied onto an Al foil, dried and pressed to obtain a positive electrode. Subsequently, a 2032 type coin cell for evaluation with Li as the counter electrode was prepared, and 1M-LiPF 6 dissolved in EC-DMC (1: 1) was used as the electrolyte, and the current density was 0.2C. The discharge capacity was measured. Moreover, the ratio of the discharge capacity at the current density of 2C to the battery capacity at the current density of 0.2C was calculated to obtain rate characteristics.
- an organic solvent N-methylpyrrolidone
- the capacity retention was measured by comparing the initial discharge capacity obtained with a 1 C discharge current at room temperature with the discharge capacity after 100 cycles. Further, for the examples and comparative examples, the particle size distribution graphs of the positive electrode active material (X axis: particle diameter [ ⁇ m], Y axis: relative particle amount [%]) are drawn, and based on the graph, the main peak having a particle diameter of 1 ⁇ m or more The maximum particle size and median diameter (D50) were confirmed. These results are shown in Table 2.
- Comparative Example 4 since the amount of lithium carbonate suspended was excessive, the lithium content (x) in the composition formula: Li x Ni 1- y My O 2 + ⁇ was large, and the battery characteristics were poor. In Comparative Example 5, since the holding temperature in the firing step was too high, the oxygen content (2 + ⁇ ) in the composition formula: Li x Ni 1- y My O 2 + ⁇ was small, and the particles were coarsened, resulting in battery characteristics. Was bad.
- FIG. 1 shows that the particle size of the primary particles grows as the firing temperature (the holding temperature during firing) increases.
- FIG. 2 SEM photographs of Examples 1 and 2 and Comparative Example 1 are shown in FIG. From FIG. 2, it can be seen that primary particles gather together to form large particles at a firing temperature of 1000 ° C., and primary particles are well dispersed at 1030 ° C. This is because the primary particles are fine at a calcination temperature of 1000 ° C. or lower in the crushing step, and the powder is soft and cannot be crushed to disperse the secondary particles as primary particles. It was because it was able to disintegrate.
- Example 1 and 2 the results obtained in Examples 1 and 2 and Comparative Example 1 are shown in FIG.
- the firing temperature is 1030 ° C. and 1050 ° C.
- the particles are uniformly dispersed as primary particles by crushing, and the particle size distribution is uniform.
- Comparative Example 1 when the firing temperature is 1000 ° C. or lower, the primary particles are fine, so that the powder is soft and cannot be crushed so as to disperse the secondary particles as primary particles. Therefore, the primary particles gather together to form large particles, and the particle size distribution is also nonuniform. Further, from FIGS.
- Examples 1 and 2 there are a sub-peak due to fine particles having a particle size of less than 1 ⁇ m and a main peak having a particle size of 1 ⁇ m or more, and the main peak has a uniform distribution shape having one maximum point. You can see that Further, it can be seen that the difference between the particle size at the maximum point of the main peak and D50 is 1.5 ⁇ m or less. Thus, Examples 1 and 2 had a uniform particle size distribution, and therefore various battery characteristics were good. On the other hand, in Comparative Example 1, there are a plurality of main peak maxima, indicating an uneven distribution shape.
- the state having a plurality of local maxima means a state having a local minimum showing a frequency of 95% or less of the local maxima having a lower frequency between the local maxima.
- the difference between the particle size at the maximum point of the main peak and D50 is more than 1.5 ⁇ m.
- Comparative Example 1 has a non-uniform particle size distribution, and therefore various battery characteristics are poor.
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Abstract
Description
A=(m+p)/(m+s) (1)
(式中、mは一次粒子単独の個数、pは二次粒子を構成する一次粒子の個数、sは二次粒子の個数を示す。)
下記式で表される組成を有する非水電解質二次電池用正極活物質
LiXCo1-yMyO2+Z
(式中、MはNa、Mg、Ca、Y、希土類元素、Ti、Zr、Hf、V、Nb、Ta、Cr、Mo、W、Mn、Fe、Ni、Cu、Ag、Zn、B、Al、Ga、C、Si、Sn、N、P、S、F、Clから選択される一種以上の元素を示す。xは、0.9≦x≦1.1、yは、0≦y≦0.1、zは、-0.1≦z≦0.1である。)が開示されている。そして、これによれば、負荷特性が高く、品質安定性に優れ、さらには高容量な特性を有する電池を作製することができる、と記載されている。
組成式:LixNi1-yMyO2+α
(前記式において、MはSc、Ti、V、Cr、Mn、Fe、Co、Cu、Zn、Ga、Ge、Al、Bi、Sn、Mg、Ca、B及びZrから選択される1種以上であり、0.9≦x≦1.1であり、0<y≦0.7であり、0.05≦α≦0.2である。)
で表され、且つ、一次粒子を含み、タップ密度が1.3~2.6g/cm3であり、
一次粒子の平均粒径が0.3~3.0μmであり、比表面積が0.3~2.3m2/gであるリチウムイオン電池用正極活物質である。
本発明のリチウムイオン電池用正極活物質の材料としては、一般的なリチウムイオン電池用正極用の正極活物質として有用な化合物を広く用いることができるが、特に、コバルト酸リチウム(LiCoO2)、ニッケル酸リチウム(LiNiO2)、マンガン酸リチウム(LiMn2O4)等のリチウム含有遷移金属酸化物を用いるのが好ましい。このような材料を用いて作製される本発明のリチウムイオン電池用正極活物質は、
組成式:LixNi1-yMyO2+α
(前記式において、MはSc、Ti、V、Cr、Mn、Fe、Co、Cu、Zn、Ga、Ge、Al、Bi、Sn、Mg、Ca、B及びZrから選択される1種以上であり、0.9≦x≦1.1であり、0<y≦0.7であり、0.05≦α≦0.2である。)
で表される。
リチウムイオン電池用正極活物質における全金属に対するリチウムの比率が0.9~1.1であるが、これは、0.9未満では、安定した結晶構造を保持し難く、1.1超では容量が低くなるためである。
一次粒子の平均粒径がこのように0.3~3.0μmであると好ましい。平均粒径が0.3μm未満であると集電体への塗布が困難となる。平均粒径が3.0μm超であると充填時に空隙が生じやすくなり、充填性が低下する。また、一次粒子の平均粒径は、好ましくは0.6~3.0μmであり、より好ましくは1.6~2.0μmである。
比表面積がこのように0.3~2.3m2/gであると好ましい。比表面積が0.3m2/g未満であると反応面積が小さくなり、電流負荷特性が低下し、容量が低くなるため望ましくなく、比表面積が2.3m2/g超であると電極作製時に使用する溶剤量が増加し、集電体への塗布が困難となるため望ましくない。また、比表面積は、好ましくは0.4~1.5m2/gであり、より好ましくは0.5~1.0m2/gである。また、リチウムイオン電池用正極活物質は、一次粒子と、複数の一次粒子からなる二次粒子とが混合した粉末であってもよい。
また、前記極大点の粒径が2~15μmであるのが好ましい。極大点の粒径が2μm未満であると、バインダーを有機溶媒(N-メチルピロリドン)に溶解したものに、正極材料と導電材とを混合してスラリー化し、Al箔上に塗布して乾燥後にプレスして正極電極とするが、この際に用いる有機溶媒量が多くなるため、正極電極中の正極活物質密度が低下して電池特性が不良となるという問題が生じる可能性がある。また、極大点の粒径が15μm超であると、粒子間同士の空隙が大きくなり、タップ密度が低下して電池特性が不良となるという問題が生じる可能性がある。極大点の粒径は、より好ましくは、2~11μmである。
本発明の実施形態に係るリチウムイオン電池用正極は、例えば、上述の構成のリチウムイオン電池用正極活物質と、導電助剤と、バインダーとを混合して調製した正極合剤をアルミニウム箔等からなる集電体の片面または両面に設けた構造を有している。また、本発明の実施形態に係るリチウムイオン電池は、このような構成のリチウムイオン電池用正極を備えている。
次に、本発明の実施形態に係るリチウムイオン電池用正極活物質の製造方法について詳細に説明する。
まず、金属塩溶液を作製する。当該金属は、Ni、及び、Sc、Ti、V、Cr、Mn、Fe、Co、Cu、Zn、Ga、Ge、Al、Bi、Sn、Mg、Ca、B及びZrから選択される1種以上である。また、金属塩は硫酸塩、塩化物、硝酸塩、酢酸塩等であり、特に硝酸塩が好ましい。これは、焼成原料中に不純物として混入してもそのまま焼成できるため洗浄工程が省けることと、硝酸塩が酸化剤として機能し、焼成原料中の金属の酸化を促進する働きがあるためである。金属塩に含まれる各金属を所望のモル比率となるように調整しておく。これにより、正極活物質中の各金属のモル比率が決定する。
次に、濾別したリチウム含有炭酸塩を乾燥することにより、リチウム塩の複合体(リチウムイオン電池正極材用前駆体)の粉末を得る。
その後、焼成容器から粉末を取り出し、粉砕を行うことにより正極活物質の粉体を得る。
まず、表1に記載の投入量の炭酸リチウムを純水3.2リットルに懸濁させた後、金属塩溶液を4.8リットル投入した。ここで、金属塩溶液は、各金属の硝酸塩の水和物を、各金属が表1に記載の組成比になるように調整し、また全金属モル数が14モルになるように調整した。
なお、炭酸リチウムの懸濁量は、製品(リチウムイオン二次電池正極材料、すなわち正極活物質)をLixNi1-yMyO2+αでxが表1の値となる量であって、それぞれ次式で算出されたものである。
W(g)=73.9×14×(1+0.5X)×A
上記式において、「A」は、析出反応として必要な量の他に、ろ過後の原料に残留する炭酸リチウム以外のリチウム化合物によるリチウムの量をあらかじめ懸濁量から引いておくために掛ける数値である。「A」は、硝酸塩や酢酸塩のように、リチウム塩が焼成原料として反応する場合は0.9であり、硫酸塩や塩化物のように、リチウム塩が焼成原料として反応しない場合は1.0である。
この処理により溶液中に微小粒のリチウム含有炭酸塩が析出したが、この析出物を、フィルタープレスを使用して濾別した。
続いて、析出物を乾燥してリチウム含有炭酸塩(リチウムイオン電池正極材用前駆体)を得た。
次に、焼成容器を準備し、この焼成容器内にリチウム含有炭酸塩を充填した。次に、焼成容器を空気雰囲気炉に入れて、900℃まで3時間で昇温させた後、表1に記載の保持温度まで4時間で昇温させ、次いで当該保持温度で2時間保持した後、3時間で放冷して酸化物を得た。次に、得られた酸化物を解砕し、リチウムイオン二次電池正極材の粉末を得た。
実施例16として、原料の各金属を表1に示すような組成とし、金属塩を塩化物とし、リチウム含有炭酸塩を析出させた後、飽和炭酸リチウム溶液で洗浄し、濾過する以外は、実施例1~15と同様の処理を行った。
実施例17として、原料の各金属を表1に示すような組成とし、金属塩を硫酸塩とし、リチウム含有炭酸塩を析出させた後、飽和炭酸リチウム溶液で洗浄し、濾過する以外は、実施例1~15と同様の処理を行った。
実施例18として、原料の各金属を表1に示すような組成とし、焼成を大気圧下ではなく120KPaの加圧下で行った以外は、実施例1~15と同様の処理を行った。
比較例1~7として、原料の各金属を表1に示すような組成とし、実施例1~15と同様の処理を行った。
各正極材の粒度分布は、島津製作所製レーザ回折式粒度分布測定装置SALD-3000Jにより測定した。各正極材中の金属含有量は、誘導結合プラズマ発光分光分析装置(ICP-AES)で測定し、各金属の組成比(モル比)を算出した。また、酸素含有量はLECO法で測定しαを算出した。一次粒子の平均粒径は、各正極材の粉末のSEM(Scanning Electron Microscope:走査型電子顕微鏡)写真により100個の一次粒子を観察し、それらの粒子径を算出して平均値を求めることにより算出した。比表面積はBET値を、タップ密度は200回タップ後の密度とした。
また、各正極材と、導電材と、バインダーとを85:8:7の割合で秤量し、バインダーを有機溶媒(N-メチルピロリドン)に溶解したものに、正極材料と導電材とを混合してスラリー化し、Al箔上に塗布して乾燥後にプレスして正極とした。続いて、対極をLiとした評価用の2032型コインセルを作製し、電解液に1M-LiPF6をEC-DMC(1:1)に溶解したものを用いて、電流密度0.2Cの際の放電容量を測定した。また電流密度0.2Cのときの電池容量に対する電流密度2Cのときの、放電容量の比を算出してレート特性を得た。さらに、容量保持率は、室温で1Cの放電電流で得られた初期放電容量と100サイクル後の放電容量を比較することによって測定した。
さらに、実施例及び比較例について、それぞれ正極活物質の粒度分布グラフ(X軸:粒子径[μm]、Y軸:相対粒子量[%])を描き、それに基づき粒径1μm以上の主ピークの極大点の粒径とメジアン径(D50)とを確認した。
これらの結果を表2に示す。
比較例1は、炭酸リチウムの懸濁量と金属組成と焼成温度との関係から、組成式:LixNi1-yMyO2+αにおけるリチウム分(x)が大きくなり、正極材層状結晶構造以外にある余剰リチウムが導電性を妨げる不純物となるために電池特性が不良であった。
比較例2、6及び7は、焼成工程における保持温度が低すぎたため、粒子の成長が不均一且つ不十分となり、電池特性が不良であった。
比較例3は、炭酸リチウムの懸濁量が過少のため、組成式:LixNi1-yMyO2+αにおけるリチウム分(x)が小さく、電池特性が不良であった。
比較例4は、炭酸リチウムの懸濁量が過多のため、組成式:LixNi1-yMyO2+αにおけるリチウム分(x)が大きく、電池特性が不良であった。
比較例5は、焼成工程における保持温度が高すぎたため、組成式:LixNi1-yMyO2+αにおける酸素分(2+α)が小さく、且つ、粒子が粗大化し、電池特性が不良であった。
また、図4から、実施例1及び2では、粒径1μm未満の微細粒子による副ピークと粒径1μm以上の主ピークとからなり、主ピークが一つの極大点を有する均一な分布形状となっていることがわかる。さらに、主ピークの極大点における粒径とD50との差が1.5μm以下となっていることがわかる。このように実施例1及び2は粒度分布が均一となっており、そのため種々の電池特性が良好であった。一方、比較例1では、主ピークの極大が複数存在しており不均一な分布形状を示している。ここで、極大が複数ある状態とは、極大と極大との間に頻度が低い方の極大の95%以下の頻度を示す極小を有している状態を意味する。また、比較例1では、主ピークの極大点における粒径とD50との差が1.5μm超となっている。このように、比較例1は粒度分布が不均一となっており、そのため種々の電池特性が不良であった。
Claims (10)
- 組成式:LixNi1-yMyO2+α
(前記式において、MはSc、Ti、V、Cr、Mn、Fe、Co、Cu、Zn、Ga、Ge、Al、Bi、Sn、Mg、Ca、B及びZrから選択される1種以上であり、0.9≦x≦1.1であり、0<y≦0.7であり、0.05≦α≦0.2である。)
で表され、且つ、一次粒子を含み、タップ密度が1.3~2.6g/cm3であり、
前記一次粒子の平均粒径が0.3~3.0μmであり、比表面積が0.3~2.3m2/gであるリチウムイオン電池用正極活物質。 - 前記タップ密度が1.4~2.6g/cm3である請求項1に記載のリチウムイオン電池用正極活物質。
- 前記タップ密度が1.8~2.5g/cm3である請求項2に記載のリチウムイオン電池用正極活物質。
- 粒度分布グラフ(X軸:粒子径[μm]、Y軸:相対粒子量[%])において、粒径1μm以上で極大点を有し、前記極大点の粒径とメジアン径(D50)との差が1.5μm以下である請求項1~3のいずれかに記載のリチウムイオン電池用正極活物質。
- 前記極大点の粒径が2~15μmである請求項4に記載のリチウムイオン電池用正極活物質。
- 前記Mが、Mn及びCoから選択される1種以上である請求項1~5のいずれかに記載のリチウムイオン電池用正極活物質。
- 前記一次粒子の平均粒径が0.6~3.0μmであり、比表面積が0.4~1.5m2/gである請求項1~6のいずれかに記載のリチウムイオン電池用正極活物質。
- 前記一次粒子の平均粒径が1.6~2.0μmであり、比表面積が0.5~1.0m2/gである請求項7に記載のリチウムイオン電池用正極活物質。
- 請求項1~8のいずれかに記載のリチウムイオン電池用正極活物質を用いたリチウムイオン電池用正極。
- 請求項9に記載のリチウムイオン電池用正極を用いたリチウムイオン電池。
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US8623551B2 (en) | 2014-01-07 |
EP2544280A1 (en) | 2013-01-09 |
CN102763247A (zh) | 2012-10-31 |
KR20120136381A (ko) | 2012-12-18 |
JP5467144B2 (ja) | 2014-04-09 |
CN102763247B (zh) | 2016-07-20 |
KR101443996B1 (ko) | 2014-09-23 |
JPWO2011108720A1 (ja) | 2013-06-27 |
TW201138189A (en) | 2011-11-01 |
EP2544280A4 (en) | 2014-06-11 |
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US20120321956A1 (en) | 2012-12-20 |
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