RU2012140144A - Составы для покрытий для упаковочных изделий и способы нанесения покрытий - Google Patents

Составы для покрытий для упаковочных изделий и способы нанесения покрытий Download PDF

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RU2012140144A
RU2012140144A RU2012140144/05A RU2012140144A RU2012140144A RU 2012140144 A RU2012140144 A RU 2012140144A RU 2012140144/05 A RU2012140144/05 A RU 2012140144/05A RU 2012140144 A RU2012140144 A RU 2012140144A RU 2012140144 A RU2012140144 A RU 2012140144A
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polyester polymer
coating
aryl
bisphenol
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RU2544676C2 (ru
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Ричард Х. ЭВАНС
Джеффри НИЕДЕРСТ
Роберт М. О'БРАЙЕН
Бенуа ПРУВОСТ
Кевин РОМАНЬОЛИ
Грант ШУТТЭ
Пауль СТЕНСОН
КУРЕН Том ВАН
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Вэлспар Сорсинг, Инк.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/22—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
    • B05D7/227—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes of containers, cans or the like
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D31/00—Other methods for working sheet metal, metal tubes, metal profiles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
    • B65D25/34—Coverings or external coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C09D171/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C09D171/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2518/00—Other type of polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Mechanical Engineering (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

1. Изделие, содержащее:металлическую подложку из контейнера для пищевых продуктов или напитков или его части; ипокрытие, нанесенное на, по меньшей мере, часть основной поверхности металлической подложки,при этом покрытие содержит:пленкообразующее количество полиэфирного полимера, имеющего:один или более сегментов следующей Формулы I: -O-Ar-(R-Ar)-O-,где:каждый Ar независимо представляет собой арильную или гетероарильную группу,каждый n независимо означает 0 или 1,R, если присутствует, представляет собой двухвалентную органическую группу, идва атома кислорода, каждый, представляют собой эфирный кислород; ипри этом температура стеклования (Tg) составляет, по меньшей мере, 70°С; ипричем состав для покрытия, по меньшей мере, по существу свободен от бисфенола А и диглицидилового эфира бисфенола А.2. Изделие по п.1, в котором полиэфирный полимер имеет Tg от 70 до 150°С.3. Изделие по п.1, в котором полиэфирный полимер имеет Tg от 80 до 110°С.4. Изделие по п.1, в котором полиэфирный полимер содержит одну или более подвешенных гидроксильных групп, присоединенных к атомам углерода каркаса.5. Изделие по п.4, в котором каркас содержит -СН-СН(ОН)-СН- сегменты.6. Изделие по п.1, в котором арильные или гетероарильные группы составляют, по меньшей мере, 20 массовых процентов полиэфирного полимера, исходя из общей массы арильных или гетероарильных групп, присутствующих в полимере, относительно массы полимера.7. Изделие по п.1, в котором полиэфирный полимер является продуктом реакции ингредиентов, включая полиэпоксид и многоатомный фенол.8. Изделие по п.7, в котором каждый из полиэпоксида и многоатомного фенола независимо содержит арильную или гетероарильную г�

Claims (25)

1. Изделие, содержащее:
металлическую подложку из контейнера для пищевых продуктов или напитков или его части; и
покрытие, нанесенное на, по меньшей мере, часть основной поверхности металлической подложки,
при этом покрытие содержит:
пленкообразующее количество полиэфирного полимера, имеющего:
один или более сегментов следующей Формулы I: -O-Ar-(Rn-Ar)n-O-,
где:
каждый Ar независимо представляет собой арильную или гетероарильную группу,
каждый n независимо означает 0 или 1,
R, если присутствует, представляет собой двухвалентную органическую группу, и
два атома кислорода, каждый, представляют собой эфирный кислород; и
при этом температура стеклования (Tg) составляет, по меньшей мере, 70°С; и
причем состав для покрытия, по меньшей мере, по существу свободен от бисфенола А и диглицидилового эфира бисфенола А.
2. Изделие по п.1, в котором полиэфирный полимер имеет Tg от 70 до 150°С.
3. Изделие по п.1, в котором полиэфирный полимер имеет Tg от 80 до 110°С.
4. Изделие по п.1, в котором полиэфирный полимер содержит одну или более подвешенных гидроксильных групп, присоединенных к атомам углерода каркаса.
5. Изделие по п.4, в котором каркас содержит -СН2-СН(ОН)-СН2- сегменты.
6. Изделие по п.1, в котором арильные или гетероарильные группы составляют, по меньшей мере, 20 массовых процентов полиэфирного полимера, исходя из общей массы арильных или гетероарильных групп, присутствующих в полимере, относительно массы полимера.
7. Изделие по п.1, в котором полиэфирный полимер является продуктом реакции ингредиентов, включая полиэпоксид и многоатомный фенол.
8. Изделие по п.7, в котором каждый из полиэпоксида и многоатомного фенола независимо содержит арильную или гетероарильную группу.
9. Изделие по п.7, в котором один или более из полиэпоксида или многоатомного фенола выбран из 1,1-ди(4-гидроксифенил)-циклогексана, 1,1-ди(4-гидрокси-3-метилфенил)-циклогексана, 1,1-ди(4-гидрокси-3,5-диметилфенил)-циклогексана, или диглицидилового эфира любых из них.
10. Изделие по п.7, в котором один или более из полиэпоксида или многоатомного фенола выбран из: 1,1-бис(4-гидроксифенил)-3,3,5-триметил-циклогексана или диглицидилового эфира 1,1-бис(4-гидроксифенил)-3,3,5-триметил-циклогексана.
11. Изделие по п.1, в котором полиэфирный полимер имеет среднечисленную молекулярную массу, по меньшей мере, 2000.
12. Изделие по п.1, в котором R, если присутствует, представляет собой двухвалентную группу, отличную от -С(СН3)2-.
13. Изделие по п.1, в котором n означает 1, и R содержит четвертичный атом углерода в сегменте каркаса, соединяющего две Ar группы.
14. Изделие по п.13, в котором R содержит, по меньшей мере, одну циклическую группу.
15. Изделие по п.14, в котором: (i) R свободен от сложноэфирных связей и (ii) упомянутая, по меньшей мере, одна циклическая группа является двухвалентной алициклической группой.
16. Изделие по п.1, в котором n означает 1, и R содержит, по меньшей мере, одну сложноэфирную связь.
17. Изделие по п.16, в котором R содержит сегмент приведенной ниже формулы:
− R t 5 − C ( O ) − O − R 4 − O − C ( O ) − R t 5 −
Figure 00000001
 ,
где:
R4 представляет собой двухвалентную органическую группу;
каждый R5 представляет собой двухвалентную органическую группу; и
каждый t означает 0 или 1.
18. Изделие по п.1, в котором полиэфирный полимер свободен от сложноэфирных связей.
19. Изделие по п.1, в котором состав для покрытия содержит жидкий носитель и содержит систему на водной основе.
20. Изделие по п.1, в котором состав для покрытия содержит жидкий носитель и содержит систему на основе органических растворителей.
21. Изделие по п.1, в котором состав для покрытия является покрытием для контакта с пищевыми продуктами.
22. Способ, включающий стадии, на которых:
обеспечивают металлическую подложку;
обеспечивают состав для покрытия, содержащий:
полиэфирный полимер, имеющий:
один или более сегментов следующей Формулы I: -O-Ar-(Rn-Ar)n-O-,
где:
каждый Ar независимо представляет собой арильную или гетероарильную группу,
каждый n независимо означает 0 или 1,
R, если присутствует, представляет собой двухвалентную органическую группу, и
два атома кислорода, каждый, представляют собой эфирный кислород; и
при этом температура стеклования (Tg) составляет, по меньшей мере, 70°С; и
причем состав для покрытия, по меньшей мере, по существу свободен от бисфенола А и диглицидилового эфира бисфенола А; и
наносят состав для покрытия на, по меньшей мере, часть основной поверхности подложки до или после формирования подложки в контейнер для пищевых продуктов или напитков или его часть.
23. Способ по п.22, дополнительно включающий стадию, на которой:
формируют металлическую подложку, содержащую состав для покрытия, нанесенный на нее, в контейнер для пищевых продуктов или напитков или его часть.
24. Способ по п.22, в котором металлическая подложка содержит часть предварительно сформированного контейнера для пищевых продуктов или напитков.
25. Состав для покрытия, содержащий:
пленкообразующее количество полиэфирного полимера, имеющего:
один или более сегментов следующей Формулы I: -O-Ar-(Rn-Ar)n-O-,
где:
каждый Ar независимо представляет собой арильную или гетероарильную группу,
каждый n независимо представляет собой 0 или 1,
R, если присутствует, представляет собой двухвалентную органическую группу, и
два атома кислорода, каждый, представляют собой эфирный кислород; и
при этом температура стеклования (Tg) составляет, по меньшей мере, 70°С; и
жидкий носитель;
причем состав для покрытия, по меньшей мере, по существу свободен от бисфенола А и диглицидилового эфира бисфенола А.
RU2012140144/05A 2010-04-16 2011-04-15 Составы для покрытий для упаковочных изделий и способы нанесения покрытий RU2544676C2 (ru)

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