TWI298336B - Films prepared from plasticized polyesters - Google Patents
Films prepared from plasticized polyesters Download PDFInfo
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- TWI298336B TWI298336B TW091106321A TW91106321A TWI298336B TW I298336 B TWI298336 B TW I298336B TW 091106321 A TW091106321 A TW 091106321A TW 91106321 A TW91106321 A TW 91106321A TW I298336 B TWI298336 B TW I298336B
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- 229920000728 polyester Polymers 0.000 title claims description 48
- 239000004014 plasticizer Substances 0.000 claims description 84
- 239000000203 mixture Substances 0.000 claims description 73
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 67
- 229920001634 Copolyester Polymers 0.000 claims description 64
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 54
- 150000002009 diols Chemical class 0.000 claims description 51
- -1 aromatic alcohols Chemical class 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 39
- 238000002425 crystallisation Methods 0.000 claims description 32
- 230000008025 crystallization Effects 0.000 claims description 32
- 238000002844 melting Methods 0.000 claims description 32
- 230000008018 melting Effects 0.000 claims description 32
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 28
- 239000002253 acid Substances 0.000 claims description 27
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 25
- 230000009477 glass transition Effects 0.000 claims description 21
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims description 20
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 235000019441 ethanol Nutrition 0.000 claims description 19
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 16
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 claims description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 238000000137 annealing Methods 0.000 claims description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003490 calendering Methods 0.000 claims description 12
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 12
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 12
- DYJIIMFHSZKBDY-UHFFFAOYSA-N (3-benzoyloxy-2,2-dimethylpropyl) benzoate Chemical group C=1C=CC=CC=1C(=O)OCC(C)(C)COC(=O)C1=CC=CC=C1 DYJIIMFHSZKBDY-UHFFFAOYSA-N 0.000 claims description 9
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 239000001361 adipic acid Substances 0.000 claims description 8
- 235000011037 adipic acid Nutrition 0.000 claims description 8
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 claims description 8
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 claims description 8
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 8
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 8
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000052 vinegar Substances 0.000 claims description 8
- 235000021419 vinegar Nutrition 0.000 claims description 8
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 150000002148 esters Chemical group 0.000 claims description 6
- 239000005711 Benzoic acid Substances 0.000 claims description 5
- 235000010233 benzoic acid Nutrition 0.000 claims description 5
- 230000001747 exhibiting effect Effects 0.000 claims description 5
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical group OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 4
- OONPLQJHBJXVBP-UHFFFAOYSA-N 3-(2-phenylethenyl)phthalic acid Chemical group OC(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1C(O)=O OONPLQJHBJXVBP-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 4
- 239000000539 dimer Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 4
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical group 0.000 claims description 3
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 claims description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 3
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 claims description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 2
- 230000006698 induction Effects 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims 3
- 230000001939 inductive effect Effects 0.000 claims 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims 3
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 2
- 229940043375 1,5-pentanediol Drugs 0.000 claims 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims 2
- LAWHHRXCBUNWFI-UHFFFAOYSA-N 2-pentylpropanedioic acid Chemical compound CCCCCC(C(O)=O)C(O)=O LAWHHRXCBUNWFI-UHFFFAOYSA-N 0.000 claims 2
- LUSFFPXRDZKBMF-UHFFFAOYSA-N [3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCC(CO)C1 LUSFFPXRDZKBMF-UHFFFAOYSA-N 0.000 claims 2
- 125000003827 glycol group Chemical group 0.000 claims 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims 2
- WFJUVIYEILFPET-UHFFFAOYSA-N 2,3-dihydroxybutanedioic acid;hexanedioic acid Chemical compound OC(=O)C(O)C(O)C(O)=O.OC(=O)CCCCC(O)=O WFJUVIYEILFPET-UHFFFAOYSA-N 0.000 claims 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 claims 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- STENYDAIMALDKF-UHFFFAOYSA-N cyclobutane-1,3-diol Chemical compound OC1CC(O)C1 STENYDAIMALDKF-UHFFFAOYSA-N 0.000 claims 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- FTIMWVSQXCWTAW-UHFFFAOYSA-N ruthenium Chemical compound [Ru].[Ru] FTIMWVSQXCWTAW-UHFFFAOYSA-N 0.000 claims 1
- 235000015067 sauces Nutrition 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- ALOUNLDAKADEEB-UHFFFAOYSA-N dimethyl sebacate Chemical compound COC(=O)CCCCCCCCC(=O)OC ALOUNLDAKADEEB-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000006085 branching agent Substances 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229960002380 dibutyl phthalate Drugs 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 3
- 229960003656 ricinoleic acid Drugs 0.000 description 3
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FJCYGJHVYRPJOA-UHFFFAOYSA-N CCCCCCCCCCOC(=O)CC(CC(=O)OCCCC)(C(=O)O)O Chemical compound CCCCCCCCCCOC(=O)CC(CC(=O)OCCCC)(C(=O)O)O FJCYGJHVYRPJOA-UHFFFAOYSA-N 0.000 description 2
- NUPSHWCALHZGOV-UHFFFAOYSA-N Decyl acetate Chemical compound CCCCCCCCCCOC(C)=O NUPSHWCALHZGOV-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- HIZCTWCPHWUPFU-UHFFFAOYSA-N Glycerol tribenzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(OC(=O)C=1C=CC=CC=1)COC(=O)C1=CC=CC=C1 HIZCTWCPHWUPFU-UHFFFAOYSA-N 0.000 description 2
- 239000004831 Hot glue Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 229940014772 dimethyl sebacate Drugs 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 2
- 239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 description 1
- WTTJVINHCBCLGX-UHFFFAOYSA-N (9trans,12cis)-methyl linoleate Natural products CCCCCC=CCC=CCCCCCCCC(=O)OC WTTJVINHCBCLGX-UHFFFAOYSA-N 0.000 description 1
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- UTOVMEACOLCUCK-SNAWJCMRSA-N (e)-4-butoxy-4-oxobut-2-enoic acid Chemical compound CCCCOC(=O)\C=C\C(O)=O UTOVMEACOLCUCK-SNAWJCMRSA-N 0.000 description 1
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- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/0063—After-treatment of articles without altering their shape; Apparatus therefor for changing crystallisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/008—Wide strips, e.g. films, webs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B2219/00—Program-control systems
- G05B2219/30—Nc systems
- G05B2219/49—Nc machine tool, till multiple
- G05B2219/49029—Virtual rapid prototyping, create a virtual prototype, simulate rapid prototyping process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28299601P | 2001-04-11 | 2001-04-11 | |
| US10/086,905 US7030181B2 (en) | 2001-04-11 | 2002-02-28 | Films prepared from plasticized polyesters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI298336B true TWI298336B (en) | 2008-07-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091106321A TWI298336B (en) | 2001-04-11 | 2002-03-29 | Films prepared from plasticized polyesters |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7030181B2 (enExample) |
| EP (1) | EP1379576B1 (enExample) |
| JP (2) | JP2004524426A (enExample) |
| KR (2) | KR20030088501A (enExample) |
| CN (1) | CN100376621C (enExample) |
| BR (1) | BR0208598A (enExample) |
| MX (1) | MXPA03008980A (enExample) |
| TW (1) | TWI298336B (enExample) |
| WO (1) | WO2002083769A1 (enExample) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6917033B2 (en) * | 2002-10-15 | 2005-07-12 | International Business Machines Corporation | Passive touch-sensitive optical marker |
| US7285587B2 (en) * | 2002-12-20 | 2007-10-23 | Eastman Chemical Company | Flame retardant polyester compositions for calendering |
| CA2523546A1 (en) * | 2003-05-15 | 2004-12-02 | Gregory R. Alms | Fast crystallizing polyester compositions |
| US7235623B2 (en) * | 2003-11-26 | 2007-06-26 | Eastman Chemical Company | Polyester compositions for calendering |
| US20050154147A1 (en) * | 2003-12-22 | 2005-07-14 | Germroth Ted C. | Polyester compositions |
| US8071695B2 (en) * | 2004-11-12 | 2011-12-06 | Eastman Chemical Company | Polyeste blends with improved stress whitening for film and sheet applications |
| US20060121219A1 (en) * | 2004-12-07 | 2006-06-08 | Eastman Chemical Co. | Void-containing polyester shrink film with improved density retention |
| US7834129B2 (en) * | 2005-06-17 | 2010-11-16 | Eastman Chemical Company | Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| US20060270773A1 (en) * | 2005-05-26 | 2006-11-30 | Hale Wesley R | Polyester-polycarbonate blends for diffuser sheets with improved luminance |
| US20060270806A1 (en) * | 2005-05-26 | 2006-11-30 | Hale Wesley R | Miscible high Tg polyester/polymer blend compositions and films formed therefrom |
| US20100298523A1 (en) * | 2005-06-17 | 2010-11-25 | Eastman Chemical Company | Polyester Compositions Which Comprise Cyclobutanediol and at Least One Phosphorus Compound |
| US7704605B2 (en) * | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| US20110144266A1 (en) * | 2005-06-17 | 2011-06-16 | Eastman Chemical Company | Thermoplastic Articles Comprising Cyclobutanediol Having a Decorative Material Embedded Therein |
| US20070100125A1 (en) * | 2005-10-28 | 2007-05-03 | Crawford Emmett D | Polyester compositions comprising minimal amounts of cyclobutanediol |
| US8193302B2 (en) * | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| US20100096589A1 (en) * | 2005-10-28 | 2010-04-22 | Emmett Dudley Crawford | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom |
| ATE505500T1 (de) | 2005-10-28 | 2011-04-15 | Eastman Chem Co | Polyesterzusammensetzungen mit cyclobutandiol mit hoher glasübergangstemperatur und daraus hergestellte artikel |
| US20100087574A1 (en) * | 2005-10-28 | 2010-04-08 | Emmett Dudley Crawford | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US20070100122A1 (en) * | 2005-10-28 | 2007-05-03 | Crawford Emmett D | Polyester compositions containing cyclobutanediol and articles made therefrom |
| US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US7737246B2 (en) * | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US20070142511A1 (en) * | 2005-12-15 | 2007-06-21 | Crawford Emmett D | Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
| US20070232778A1 (en) * | 2006-03-28 | 2007-10-04 | Leslie Shane Moody | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
| US20070232779A1 (en) * | 2006-03-28 | 2007-10-04 | Leslie Shane Moody | Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid |
| US20100300918A1 (en) * | 2006-03-28 | 2010-12-02 | Eastman Chemical Company | Bottles comprising polyester compositions which comprise cyclobutanediol |
| US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| US20080085390A1 (en) * | 2006-10-04 | 2008-04-10 | Ryan Thomas Neill | Encapsulation of electrically energized articles |
| EP2225084B1 (en) * | 2007-11-21 | 2013-05-29 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US20090227735A1 (en) * | 2008-03-07 | 2009-09-10 | Eastman Chemical Company | Miscible polyester blends and shrinkable films prepared therefrom |
| US7842761B2 (en) * | 2008-04-03 | 2010-11-30 | Lapol, Llc | Bioderived plasticizer for biopolymers |
| US8198371B2 (en) * | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
| DE102008033834A1 (de) * | 2008-07-19 | 2010-01-21 | Lanxess Deutschland Gmbh | Weichmacherzubereitungen |
| BE1018246A3 (nl) * | 2008-08-14 | 2010-07-06 | Luxilon Ind Nv | Kunststofsnaar. |
| US8895654B2 (en) | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
| US20100159176A1 (en) * | 2008-12-18 | 2010-06-24 | Eastman Chemical Company | Miscible blends of terephthalate polyesters containing 1,4-cyclohexanedimethanol and 2,2,4,4-tetramethylcyclobutane-1,3-diol |
| US9486982B2 (en) | 2008-12-19 | 2016-11-08 | 3M Innovative Properties Company | Method of manufacturing adhesive articles |
| CN103484970A (zh) * | 2009-09-30 | 2014-01-01 | 株式会社Adeka | 聚酯纤维 |
| US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US20130217830A1 (en) * | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
| US10329393B2 (en) * | 2012-12-12 | 2019-06-25 | Eastman Chemical Company | Copolysters plasticized with polymeric plasticizer for shrink film applications |
| DE102013016857A1 (de) * | 2013-10-10 | 2015-04-16 | Klöckner Pentaplast Gmbh | Mehrlagige Schrumpffolie aus Polyester mit verbesserten Verarbeitungseigenschaften |
| TWI495680B (zh) * | 2013-11-07 | 2015-08-11 | Ind Tech Res Inst | 聚酯組成物、電子裝置、與薄膜的形成方法 |
| WO2018035337A1 (en) | 2016-08-18 | 2018-02-22 | Eastman Chemical Company | Polyester compositions which comprise tetramethylcyclobutandiol and ethylene glycol, with improved catalyst system |
| CN109563247B (zh) | 2016-08-18 | 2021-10-08 | 伊士曼化工公司 | 使用改进的催化剂体系的包含四甲基环丁二醇和乙二醇的聚酯组合物 |
| WO2018035341A1 (en) | 2016-08-18 | 2018-02-22 | Eastman Chemical Company | Polyester compositions which comprise tetramethylcyclobutanediol and ethylene glycol for calendering |
| WO2019046061A1 (en) | 2017-08-30 | 2019-03-07 | Eastman Chemical Company | COPOLYESTER RESIN COMPOSITION HAVING IMPROVED FLUIDITY PROPERTIES |
| US12410288B2 (en) | 2022-11-30 | 2025-09-09 | Klöckner Pentaplast Of America, Inc. | Heat-shrinkable films and related systems and methods |
Family Cites Families (139)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US36548A (en) * | 1862-09-23 | Improved machine for cutting crystals | ||
| US2012267A (en) * | 1929-08-01 | 1935-08-27 | Du Pont | Alkylene ester of polybasic acids |
| US2044612A (en) | 1931-07-30 | 1936-06-16 | American Cyanamid & Chem Corp | Plasticizer |
| GB815991A (en) | 1955-02-28 | 1959-07-08 | Union Carbide Corp | Dibenzoate esters of aliphatic diols and process for their preparation |
| GB805587A (en) | 1955-06-30 | 1958-12-10 | Goodyear Tire & Rubber | Plasticised linear aromatic polyester compositions |
| GB805586A (en) | 1955-06-30 | 1958-12-10 | Goodyear Tire & Rubber | Plasticised linear aromatic polyester compositions |
| GB805588A (en) | 1955-06-30 | 1958-12-10 | Goodyear Tire & Rubber | Method of plasticizing linear aromatic polyesters |
| US3186961A (en) | 1962-10-08 | 1965-06-01 | Monsanto Co | Plasticized polycarbonate resins |
| US3658978A (en) * | 1969-07-07 | 1972-04-25 | Union Carbide Corp | Calendering of polymeric materials |
| NL6919151A (enExample) | 1969-12-20 | 1971-06-22 | ||
| US3873496A (en) * | 1973-06-11 | 1975-03-25 | Fmc Corp | Flame-retardant polyester compositions |
| US3883478A (en) * | 1973-12-07 | 1975-05-13 | Fmc Corp | Flame-Retardant Polyester Fiber Compositions |
| US4045431A (en) * | 1975-12-11 | 1977-08-30 | Eastman Kodak Company | Flexible polyester having a melting point of at least 140° C. |
| JPS5930184B2 (ja) * | 1978-03-22 | 1984-07-25 | 東レ株式会社 | 難燃性ポリエステル組成物 |
| JPS5682235A (en) | 1979-11-22 | 1981-07-04 | Toyobo Co Ltd | Preparation of polyester elastomer sheet |
| AU543051B2 (en) * | 1980-04-11 | 1985-03-28 | Teijin Limited | Reinforced polyester composition |
| US4340526A (en) | 1980-12-29 | 1982-07-20 | Eastman Kodak Company | Polyester adhesive |
| US4391938A (en) | 1982-02-16 | 1983-07-05 | Rohm And Haas Company | Polyethylene terephthalate compositions having improved crystallization rate and surface appearance |
| US4450250A (en) | 1983-03-28 | 1984-05-22 | Eastman Kodak Company | Polyester adhesives |
| DE3667993D1 (de) * | 1985-07-31 | 1990-02-08 | Toyo Boseki | Waermeschrumpfbarer polyesterfilm und -schlauch und herstellungsverfahren fuer den schlauch. |
| JPS63501725A (ja) * | 1985-11-25 | 1988-07-14 | イ−ストマン・コダック・カンパニ− | ポリエステルとイミドエステルのブレンド |
| JPH0722965B2 (ja) * | 1986-07-18 | 1995-03-15 | ダイアホイルヘキスト株式会社 | ポリエステル系収縮包装フイルム |
| DE3752365T2 (de) * | 1986-12-19 | 2004-02-12 | Toyo Boseki K.K. | Wärmeschrumpfbare Polyesterfolien |
| FR2610635B1 (fr) * | 1987-02-10 | 1989-06-23 | Extrusion Calandrage Ste Fse | Compositions a base de polyurethanne permettant l'obtention par calandrage de materiaux biodegradables |
| JPS6449741A (en) | 1987-08-18 | 1989-02-27 | Toyota Motor Corp | Manual transmission of vehicle |
| JPH01138260A (ja) | 1987-11-24 | 1989-05-31 | Mitsui Petrochem Ind Ltd | ポリエステル樹脂組成物およびその製造方法 |
| US5256714A (en) * | 1987-12-29 | 1993-10-26 | General Electric Company | Flame retardant polyester blends |
| US4837254A (en) * | 1988-03-02 | 1989-06-06 | Eastman Kodak Company | Poly(1,4-cyclohexylene dimethylene terephthalate) molding compositions |
| JP2986197B2 (ja) | 1989-11-24 | 1999-12-06 | 積水化学工業株式会社 | 熱収縮性ポリエステル系フィルム |
| JPH0462144A (ja) | 1990-06-27 | 1992-02-27 | Unitika Ltd | 液晶ポリマー成形物の処理方法 |
| US5017680A (en) * | 1990-07-03 | 1991-05-21 | Eastman Kodak Company | Process and catalyst-inhibitor systems for preparing poly(ethylene terephthalate) |
| JPH04166309A (ja) | 1990-10-30 | 1992-06-12 | Unitika Ltd | 液晶ポリマーフィルム乃至シートの製造法 |
| DE69124193T2 (de) | 1990-11-07 | 1997-06-05 | Hoechst Celanese Corp | Umarbeitung einer flüssigkristallinen Folie durch Walzen |
| ATE199383T1 (de) * | 1990-11-30 | 2001-03-15 | Eastman Chem Co | Aliphatisch-aromatische copolyester |
| JP3217338B2 (ja) | 1991-07-31 | 2001-10-09 | 東洋紡績株式会社 | 複合配向ポリエステルフィルム |
| FR2682956B1 (fr) * | 1991-10-29 | 1994-01-07 | Rhone Poulenc Chimie | Procede de preparation de polyesters hydrosolubles et/ou hydrodispersables et utilisation de ces polyesters pour l'encollage de fils textiles. |
| US5703160A (en) * | 1992-07-15 | 1997-12-30 | Solvay S.A. | Biodegradable moulding compositions comprising a starch, a biodegradable polyester, and a salt of a hydroxycarboxylic acid |
| JP3244233B2 (ja) | 1992-11-02 | 2002-01-07 | 東レ株式会社 | 熱可塑性ポリエステル組成物およびフィルム |
| GB9311399D0 (en) * | 1993-06-02 | 1993-07-21 | Zeneca Ltd | Polyester composition |
| JP2962975B2 (ja) | 1993-08-27 | 1999-10-12 | 三菱樹脂株式会社 | 多層ポリエステルシート |
| IL110514A0 (en) | 1993-10-04 | 1994-10-21 | Eastman Chem Co | Concentrates for improving polyester compositions and a method for preparing such compositions |
| US5484632A (en) * | 1993-10-07 | 1996-01-16 | Eastman Chemical Company | Non-oriented, heat-sealing polyester film |
| US5532049A (en) * | 1993-11-01 | 1996-07-02 | Diafoil Hoechst Company, Limited | Magnetic recording medium having a calendered polyester layer with a specified deformation ratio |
| JP3378253B2 (ja) * | 1993-11-26 | 2003-02-17 | イーストマン ケミカル カンパニー | 収縮フィルム用途のための可塑化ポリエステル |
| ZA95627B (en) * | 1994-01-28 | 1995-10-05 | Procter & Gamble | Biodegradable copolymers and plastic articles comprising biodegradable copolymers |
| ID23491A (id) | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
| EP1375556A3 (en) | 1994-01-28 | 2004-08-11 | The Procter & Gamble Company | Biodegradable copolymers and plastic articles comprising biodegradable copolymers of 3-Hydroxyhexanoate. |
| BR9506664A (pt) * | 1994-01-28 | 1997-09-16 | Procter & Gamble | Copolímeros biodegradâveis e artigos plásticos compreendendo copolímeros biodegradâveis de 3-hidroxihexanoato |
| US5399595A (en) | 1994-08-22 | 1995-03-21 | Eastman Chemical Company | Foamable copolyesters |
| CN1069260C (zh) | 1994-08-30 | 2001-08-08 | 东丽株式会社 | 双轴拉伸聚酯薄膜及其制造方法 |
| DE19507144A1 (de) * | 1994-10-18 | 1996-04-25 | Giesecke & Devrient Gmbh | Mehrschichtiger Datenträger mit Deckschichten aus modifiziertem PET |
| JPH08142290A (ja) | 1994-11-15 | 1996-06-04 | Maruyama Kogyo Kk | 繊維補強シートおよびその製造方法 |
| JP3582887B2 (ja) | 1995-04-11 | 2004-10-27 | 丸山工業株式会社 | カレンダー加工用ポリエステルエラストマ組成物 |
| EP0744439B1 (en) | 1995-05-25 | 1998-12-09 | Idemitsu Petrochemical Co., Ltd. | Polypropylene composition comprising lubricants for calendering |
| JP3577614B2 (ja) | 1995-08-02 | 2004-10-13 | オカモト株式会社 | カレンダ加工用ポリプロピレン樹脂組成物 |
| US5624987A (en) | 1995-09-15 | 1997-04-29 | Brink; Andrew E. | Polyalkylene ethers as plasticizers and flow aids in poly(1,4-cyclohexanedimethylene terephthalate) resins |
| US5696176A (en) | 1995-09-22 | 1997-12-09 | Eastman Chemical Company | Foamable polyester compositions having a low level of unreacted branching agent |
| JPH09217014A (ja) | 1996-02-08 | 1997-08-19 | Tsutsunaka Plast Ind Co Ltd | 生分解性樹脂組成物とこれを用いたシートの製造方法 |
| EP0890614A4 (en) * | 1996-03-26 | 2000-04-12 | Gunze Kk | Biodegradable card holder |
| JPH09272191A (ja) | 1996-04-03 | 1997-10-21 | Kanebo Ltd | ポリエステル多層シートおよびそれからなる容器 |
| CH690438A5 (de) | 1996-05-03 | 2000-09-15 | Forbo Giubiasco Sa | Flächiges Belagsmaterial aus Kunststoff. |
| WO1997049757A1 (en) * | 1996-06-24 | 1997-12-31 | Eastman Chemical Company | Plasticized polyester for shrink film applications |
| US5824398A (en) | 1996-06-24 | 1998-10-20 | Eastman Chemical Company | Plasticized polyester for shrink film applications |
| WO1998020066A1 (en) * | 1996-11-08 | 1998-05-14 | Icc Industries, Inc. | Plastic composition |
| US5859116A (en) * | 1997-01-21 | 1999-01-12 | Eastman Chemical Company | Clarity and adjustable shrinkage of shrink films using miscible polyester blends |
| JPH10291225A (ja) | 1997-04-21 | 1998-11-04 | Teijin Ltd | ポリエステル樹脂組成物からなるカレンダー成形されたシート状成型品及びその製造方法 |
| US6103857A (en) * | 1997-06-19 | 2000-08-15 | Eastman Chemical Company | Poly(ethylene terephthalate) (PET) copolymers containing both 1,4-cyclohexanedimethanol and isophthalic acid moieties |
| DE69834726T2 (de) * | 1997-07-25 | 2007-06-06 | Metabolix, Inc., Cambridge | Pha-zusammensetzungen und deren verwendung zur herstellung von pha-filmen |
| DE69841061D1 (de) * | 1997-10-31 | 2009-09-24 | Metabolix Inc | Verwendung von organischen Phosphon- oder Phosphinsäuren, oder von Metall-oxiden oder -hydroxiden, oder von Carbonsäuresalzen eines Metalls als Hitzestabilisatoren für Polyhydroxyalkanoate |
| JP3667061B2 (ja) | 1997-12-01 | 2005-07-06 | 丸山工業株式会社 | カレンダー加工用ポリエステルエラストマ組成物 |
| EP1529809B1 (en) | 1998-02-06 | 2007-10-24 | Riken Technos Corporation | Resin composition and resin sheet |
| US6068910A (en) * | 1998-03-17 | 2000-05-30 | Eastman Chemical Company | Polyester resin compositions for calendering |
| DE69925665T2 (de) * | 1998-03-30 | 2006-03-16 | Sumitomo Bakelite Co. Ltd. | Folie aus einer Polyesterharzzusammensetzung |
| JPH11343353A (ja) | 1998-03-30 | 1999-12-14 | Sumitomo Bakelite Co Ltd | ポリエステル系樹脂シ―ト及び製造方法 |
| JP3622495B2 (ja) * | 1998-04-07 | 2005-02-23 | ブラザー工業株式会社 | 通信装置および記憶媒体 |
| US6025061A (en) * | 1998-04-23 | 2000-02-15 | Hna Holdings, Inc. | Sheets formed from polyesters including isosorbide |
| US5958581A (en) * | 1998-04-23 | 1999-09-28 | Hna Holdings, Inc. | Polyester film and methods for making same |
| ITTO980524A1 (it) | 1998-06-17 | 1999-12-17 | Novamont Spa | Composizioni contenenti amido aventi elevata resistenza all'invecchiam ento. |
| US6054551A (en) * | 1998-07-14 | 2000-04-25 | Eastman Chemical Company | Polyester comprising a residue of isophthalic acid, terephthalic acid, ethylene glycol and an aromatic diol derivative |
| JP3300674B2 (ja) | 1998-10-30 | 2002-07-08 | 信越ポリマー株式会社 | 非結晶性ポリエチレンテレフタレート樹脂組成物とそのカレンダー加工方法 |
| US6160199A (en) * | 1998-12-21 | 2000-12-12 | The Procter & Gamble Company | Absorbent articles comprising biodegradable PHA copolymers |
| US6174990B1 (en) * | 1998-12-21 | 2001-01-16 | The Procter & Gamble Company | Films comprising biodegradable PHA copolymers |
| US6077931A (en) * | 1998-12-21 | 2000-06-20 | The Procter & Gamble Company | Biodegradable PHA copolymers |
| US6326435B1 (en) * | 1999-03-12 | 2001-12-04 | Polyplastics Co., Ltd. | Polyester resin composition |
| US6482872B2 (en) * | 1999-04-01 | 2002-11-19 | Programmable Materials, Inc. | Process for manufacturing a biodegradable polymeric composition |
| JP4267751B2 (ja) | 1999-04-16 | 2009-05-27 | オカモト株式会社 | カレンダー成形用ポリエステル樹脂組成物 |
| JP2000327891A (ja) | 1999-05-19 | 2000-11-28 | Tsutsunaka Plast Ind Co Ltd | カレンダー成形用樹脂組成物 |
| JP4292626B2 (ja) | 1999-06-01 | 2009-07-08 | 住友ベークライト株式会社 | カレンダー成形用樹脂組成物 |
| US6632390B1 (en) * | 1999-06-15 | 2003-10-14 | Eastman Chemical Company | Process for profile extrusion of a polyester |
| JP2001040197A (ja) | 1999-08-03 | 2001-02-13 | Katsuta Kako Kk | ポリエステル樹脂組成物 |
| JP2001064496A (ja) | 1999-08-30 | 2001-03-13 | Dainippon Ink & Chem Inc | 樹脂組成物及び樹脂の成形加工方法 |
| JP4657411B2 (ja) * | 1999-11-25 | 2011-03-23 | オカモト株式会社 | カレンダー加工用軟質ポリエステル樹脂組成物およびこれから製造したフイルム |
| US6231970B1 (en) * | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
| JP4633217B2 (ja) | 2000-01-19 | 2011-02-16 | シーアイ化成株式会社 | ポリエステル系樹脂組成物およびシ―トの製造方法 |
| JP2001214044A (ja) | 2000-01-31 | 2001-08-07 | C I Kasei Co Ltd | ポリエステル系樹脂組成物およびシ―トの製造方法 |
| DE10010826A1 (de) * | 2000-03-08 | 2001-09-13 | Basf Ag | Verfahren zur Reduktion der Wasserdampfpermeabilität von Folien oder Beschichtungen |
| JP2001279068A (ja) | 2000-03-30 | 2001-10-10 | C I Kasei Co Ltd | ポリエステル系樹脂組成物およびシ―トの製造方法 |
| JP4616963B2 (ja) * | 2000-04-11 | 2011-01-19 | ロンシール工業株式会社 | コポリエステル系樹脂組成物及びその組成物製シート並びにコポリエステル系樹脂組成物の製造方法 |
| JP4527842B2 (ja) | 2000-04-25 | 2010-08-18 | オカモト株式会社 | 軟質ポリエステル樹脂組成物及び該組成物からの壁紙 |
| WO2001085451A1 (en) | 2000-05-05 | 2001-11-15 | 3M Innovative Properties Company | Durable security card and method for making same |
| EP1152105B1 (en) * | 2000-05-05 | 2007-07-04 | Juan Jose Saura Sotillos | Modular fence |
| US6903053B2 (en) * | 2000-06-09 | 2005-06-07 | The Procter & Gamble Company | Agricultural items and agricultural methods comprising biodegradable copolymers |
| JP2001354842A (ja) | 2000-06-09 | 2001-12-25 | Mitsubishi Rayon Co Ltd | カレンダー成形用ポリエステル組成物 |
| JP4633892B2 (ja) | 2000-08-07 | 2011-02-16 | 理研ビタミン株式会社 | Ｐｅｔ−ｇ樹脂組成物及び成形加工改良方法 |
| JP2002053740A (ja) | 2000-08-10 | 2002-02-19 | Achilles Corp | 難燃性ポリエステル樹脂組成物 |
| CN1446247A (zh) * | 2000-08-11 | 2003-10-01 | 生物技术生化学自然包装两合公司 | 生物可降解的聚合物共混物 |
| DE10040691A1 (de) | 2000-08-19 | 2002-02-28 | Leder Kunstledertech Forsch | Kalandrierfähige Polyestermischung |
| WO2002028967A1 (en) | 2000-10-02 | 2002-04-11 | Katsuta Kako K.K. | Polyester resin composition for calendering and polyester resin for calendering |
| JP2002121362A (ja) | 2000-10-11 | 2002-04-23 | Achilles Corp | 難燃性ポリエステル樹脂組成物 |
| JP4570230B2 (ja) | 2000-10-20 | 2010-10-27 | オカモト株式会社 | 共重合ポリエステル壁紙 |
| JP4688272B2 (ja) | 2000-10-23 | 2011-05-25 | シーアイ化成株式会社 | ポリエステル系樹脂組成物およびシ―トの製造方法 |
| CN1476459A (zh) * | 2000-11-30 | 2004-02-18 | ����贻�ѧ��ҵ��ʽ���� | 脂肪族聚酯共聚物及其制造方法、脂肪族聚酯系生物降解性树脂成形物、和含内酯的树脂 |
| US6551688B2 (en) * | 2001-02-28 | 2003-04-22 | Eastman Chemical Company | Calendered polyester films or sheets having a haze value of less than five percent |
| JP2002275217A (ja) | 2001-03-22 | 2002-09-25 | Sumitomo Chem Co Ltd | 生分解性樹脂改質用エチレン−α−オレフィン共重合体、その組成物及びその成形体 |
| JP2002294043A (ja) | 2001-04-02 | 2002-10-09 | Tatsuta Kagaku Kk | シート用樹脂及びそれを用いた樹脂シート |
| JP2003020386A (ja) | 2001-07-10 | 2003-01-24 | Tsutsunaka Plast Ind Co Ltd | 熱圧プレス成形用非晶性ポリエステル樹脂組成物及び非晶性ポリエステル樹脂シートの製造方法 |
| JP3988113B2 (ja) | 2001-09-10 | 2007-10-10 | 東洋紡績株式会社 | カレンダー加工用ポリエステル樹脂組成物及びこれを用いたシート |
| DE10152716C1 (de) * | 2001-10-19 | 2003-07-03 | Byk Chemie Gmbh | Prozesshilfsmittel für die Verarbeitung von Kunststoffmassen |
| JP3988115B2 (ja) | 2001-10-25 | 2007-10-10 | 東洋紡績株式会社 | カレンダー加工用ポリエステル樹脂組成物及びこれを用いたシート |
| JP3912579B2 (ja) | 2001-10-25 | 2007-05-09 | 東洋紡績株式会社 | カレンダー加工用ポリエステル樹脂組成物 |
| JP2003128773A (ja) | 2001-10-29 | 2003-05-08 | Toyobo Co Ltd | カレンダー加工用難燃性ポリエステル樹脂及び樹脂組成物、並びにこれらを用いたシート |
| JP2003128894A (ja) | 2001-10-29 | 2003-05-08 | Toyobo Co Ltd | カレンダー加工用ポリエステル樹脂組成物及びそれを使用したシート |
| JP3662880B2 (ja) | 2001-11-21 | 2005-06-22 | 勝田化工株式会社 | カレンダー加工用ポリエステル樹脂組成物及びそのシート |
| JP3661858B2 (ja) | 2001-11-21 | 2005-06-22 | 東洋紡績株式会社 | カレンダー加工用ポリエステル樹脂組成物及びこれを用いたシート |
| JP2003171537A (ja) | 2001-12-06 | 2003-06-20 | Toyobo Co Ltd | カレンダー加工用ポリエステル樹脂組成物及びこれを用いたシート |
| JP3983539B2 (ja) | 2001-12-27 | 2007-09-26 | ロンシール工業株式会社 | 樹脂組成物および該樹脂組成物を用いたシート・フィルム |
| JP2003201391A (ja) | 2002-01-07 | 2003-07-18 | Toyobo Co Ltd | カレンダー加工用ポリエステル樹脂組成物及びこれを用いたシート |
| US6608167B1 (en) * | 2002-03-26 | 2003-08-19 | E. I. Du Pont De Nemours And Company | Bis(2-hydroxyethyl isosorbide); preparation, polymers derived therefrom, and enduses thereby |
| JP4121295B2 (ja) | 2002-03-22 | 2008-07-23 | ロンシール工業株式会社 | 樹脂組成物および該樹脂組成物を用いたシート・フィルム |
| US7625994B2 (en) * | 2002-07-30 | 2009-12-01 | E.I. Du Pont De Nemours And Company | Sulfonated aliphatic-aromatic copolyetheresters |
| US20040024102A1 (en) * | 2002-07-30 | 2004-02-05 | Hayes Richard Allen | Sulfonated aliphatic-aromatic polyetherester films, coatings, and laminates |
| NL1021548C2 (nl) | 2002-09-27 | 2004-04-02 | Tno | Biologisch afbreekbaar polymeer materiaal uit zetmeel en dialdehyde-polysacharide. |
| JP4022127B2 (ja) | 2002-10-28 | 2007-12-12 | 大和製罐株式会社 | ポリエステル樹脂製成形品 |
| US7576152B2 (en) * | 2002-11-12 | 2009-08-18 | Kao Corporation | Additive for polyester base synthetic resin containing plasticizer and plasticizer for biodegradable resin |
| JP2004182759A (ja) | 2002-11-29 | 2004-07-02 | Kanebo Ltd | カレンダー加工用ポリエステル樹脂組成物及びその成形品 |
| US7285587B2 (en) | 2002-12-20 | 2007-10-23 | Eastman Chemical Company | Flame retardant polyester compositions for calendering |
| JP4156395B2 (ja) | 2003-02-06 | 2008-09-24 | アキレス株式会社 | 非結晶性ポリエチレンテレフタレート樹脂組成物及び樹脂シート |
| US6787245B1 (en) * | 2003-06-11 | 2004-09-07 | E. I. Du Pont De Nemours And Company | Sulfonated aliphatic-aromatic copolyesters and shaped articles produced therefrom |
| JP4292029B2 (ja) | 2003-06-19 | 2009-07-08 | ロンシール工業株式会社 | カレンダー成形用ポリエステル系樹脂組成物および該樹脂組成物を用いてなるフィルムまたはシート |
-
2002
- 2002-02-28 US US10/086,905 patent/US7030181B2/en not_active Expired - Lifetime
- 2002-03-29 TW TW091106321A patent/TWI298336B/zh not_active IP Right Cessation
- 2002-04-04 CN CNB028079833A patent/CN100376621C/zh not_active Expired - Lifetime
- 2002-04-04 KR KR10-2003-7013395A patent/KR20030088501A/ko not_active Ceased
- 2002-04-04 WO PCT/US2002/010316 patent/WO2002083769A1/en not_active Ceased
- 2002-04-04 EP EP02726694.9A patent/EP1379576B1/en not_active Expired - Lifetime
- 2002-04-04 BR BR0208598-4A patent/BR0208598A/pt not_active Application Discontinuation
- 2002-04-04 JP JP2002582116A patent/JP2004524426A/ja not_active Withdrawn
- 2002-04-04 KR KR1020127027607A patent/KR101226312B1/ko not_active Expired - Lifetime
- 2002-04-04 MX MXPA03008980A patent/MXPA03008980A/es not_active Application Discontinuation
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2011
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20030088501A (ko) | 2003-11-19 |
| EP1379576B1 (en) | 2017-02-15 |
| JP2012012609A (ja) | 2012-01-19 |
| KR101226312B1 (ko) | 2013-01-24 |
| EP1379576A1 (en) | 2004-01-14 |
| US7030181B2 (en) | 2006-04-18 |
| KR20120126125A (ko) | 2012-11-20 |
| US20030060546A1 (en) | 2003-03-27 |
| JP5662279B2 (ja) | 2015-01-28 |
| WO2002083769A1 (en) | 2002-10-24 |
| JP2004524426A (ja) | 2004-08-12 |
| CN1501954A (zh) | 2004-06-02 |
| CN100376621C (zh) | 2008-03-26 |
| MXPA03008980A (es) | 2004-02-18 |
| BR0208598A (pt) | 2004-08-10 |
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