RU2450026C2 - Способ полимеризации полиолефинов в растворе - Google Patents

Способ полимеризации полиолефинов в растворе Download PDF

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Publication number
RU2450026C2
RU2450026C2 RU2008149709/04A RU2008149709A RU2450026C2 RU 2450026 C2 RU2450026 C2 RU 2450026C2 RU 2008149709/04 A RU2008149709/04 A RU 2008149709/04A RU 2008149709 A RU2008149709 A RU 2008149709A RU 2450026 C2 RU2450026 C2 RU 2450026C2
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Russia
Prior art keywords
methyl
bis
oxoyl
phenyl
phenoxy
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RU2008149709/04A
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English (en)
Russian (ru)
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RU2008149709A (ru
Inventor
Вэйд В. КОНЗИ (US)
Вэйд В. КОНЗИ
Дэниел Д. ВАНДЕРЛЭНД (US)
Дэниел Д. ВАНДЕРЛЭНД
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ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
RU2008149709/04A 2006-05-17 2007-04-24 Способ полимеризации полиолефинов в растворе RU2450026C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80118206P 2006-05-17 2006-05-17
US60/801,182 2006-05-17

Publications (2)

Publication Number Publication Date
RU2008149709A RU2008149709A (ru) 2010-06-27
RU2450026C2 true RU2450026C2 (ru) 2012-05-10

Family

ID=38572813

Family Applications (4)

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RU2008149711/04A RU2463311C2 (ru) 2006-05-17 2007-04-24 Способ высокотемпературной полимеризации полиэтилена в растворе
RU2008149712/04A RU2008149712A (ru) 2006-05-17 2007-04-24 Высокоэффективный способ полимеризации в растворе
RU2008149714/04A RU2008149714A (ru) 2006-05-17 2007-04-24 Высокотемпературный способ полимеризации в растворе
RU2008149709/04A RU2450026C2 (ru) 2006-05-17 2007-04-24 Способ полимеризации полиолефинов в растворе

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RU2008149711/04A RU2463311C2 (ru) 2006-05-17 2007-04-24 Способ высокотемпературной полимеризации полиэтилена в растворе
RU2008149712/04A RU2008149712A (ru) 2006-05-17 2007-04-24 Высокоэффективный способ полимеризации в растворе
RU2008149714/04A RU2008149714A (ru) 2006-05-17 2007-04-24 Высокотемпературный способ полимеризации в растворе

Country Status (14)

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US (7) US8354484B2 (US08101696-20120124-C00008.png)
EP (8) EP2024402B2 (US08101696-20120124-C00008.png)
JP (6) JP5623738B2 (US08101696-20120124-C00008.png)
KR (6) KR101352674B1 (US08101696-20120124-C00008.png)
CN (8) CN101490094B (US08101696-20120124-C00008.png)
AR (6) AR060642A1 (US08101696-20120124-C00008.png)
AU (1) AU2007254428A1 (US08101696-20120124-C00008.png)
BR (3) BRPI0711018A8 (US08101696-20120124-C00008.png)
CA (5) CA2652456A1 (US08101696-20120124-C00008.png)
ES (7) ES2475159T3 (US08101696-20120124-C00008.png)
MX (4) MX2008014667A (US08101696-20120124-C00008.png)
RU (4) RU2463311C2 (US08101696-20120124-C00008.png)
SG (1) SG158102A1 (US08101696-20120124-C00008.png)
WO (6) WO2007136494A2 (US08101696-20120124-C00008.png)

Families Citing this family (220)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2008014667A (es) * 2006-05-17 2009-01-26 Dow Global Technologies Inc Proceso de polimerizacion en solucion de polietileno a alta temperatura.
CN101918463B (zh) 2007-11-19 2012-09-05 陶氏环球技术有限责任公司 长链支化丙烯-α-烯烃共聚物
KR101149755B1 (ko) 2009-01-06 2012-06-01 에스케이종합화학 주식회사 에틸렌-프로필렌-디엔 공중합체 제조방법
US8722817B2 (en) * 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
MX2011012938A (es) * 2009-06-05 2012-01-27 Dow Global Technologies Llc Proceso para elaborar copolimeros de etileno de bloque o interconectados con ramificacion de cadena larga (lcb).
US9243087B2 (en) 2009-06-11 2016-01-26 Dow Global Technologies Llc LDPE enabling high output and good optics when blended with other polymers
US8629214B2 (en) 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
US20110003940A1 (en) * 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
WO2011109563A2 (en) * 2010-03-02 2011-09-09 Dow Global Technologies Llc Ethylene-based polymer compositions
EP2448979B1 (en) 2009-07-01 2013-05-01 Dow Global Technologies LLC Ethylenic polymer and its use
CN102481770B (zh) * 2009-07-01 2016-12-21 陶氏环球技术有限责任公司 乙烯类聚合物及其用途
BR112012003072B1 (pt) 2009-08-10 2020-11-17 Dow Global Technologies Llc Polímero à base de etileno, composição e camada de película
US20110054122A1 (en) 2009-08-31 2011-03-03 Jerzy Klosin Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
JP5623043B2 (ja) * 2009-09-04 2014-11-12 出光興産株式会社 ポリオレフィンの製造方法、その製造装置、および、重合装置
BR112012005692B1 (pt) 2009-09-14 2021-07-27 Dow Global Technlogies Inc Polímero compreendendo um siloxano, composição e artigo
CN102695734B (zh) 2009-09-14 2015-05-06 陶氏环球技术有限责任公司 包含源于乙烯和聚链烯的单元的聚合物
WO2011032174A1 (en) 2009-09-14 2011-03-17 Dow Global Technologies Inc. Polymers comprising units derived from ethylene and poly(alkoxide)
US8784996B2 (en) 2009-11-24 2014-07-22 Dow Global Technologies Llc Extrusion coating composition
US8679639B2 (en) 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition
BR112012014242A2 (pt) 2009-12-24 2017-03-28 Dow Global Technologies Llc composição de espuma, artigo e espuma reticulada
JP5602249B2 (ja) * 2010-01-14 2014-10-08 エクソンモービル・ケミカル・パテンツ・インク 連続的溶液重合のための方法および装置
KR101788892B1 (ko) * 2010-05-17 2017-11-15 다우 글로벌 테크놀로지스 엘엘씨 에틸렌의 선택적 중합 방법 및 그를 위한 촉매
BR112012030036A2 (pt) * 2010-05-26 2016-12-13 Dow Global Technologies Llc módulo de dispositivo eletrônico compreendendo copolímero de poliolefina com baixa insaturação e vinil silano opcional
JP2013528951A (ja) 2010-06-04 2013-07-11 ダウ グローバル テクノロジーズ エルエルシー 均質ポリオレフィンコポリマーおよび接着性増強グラフトポリマーの膜を含む電子素子モジュール
JP2013528950A (ja) 2010-06-04 2013-07-11 ダウ グローバル テクノロジーズ エルエルシー 均質ポリオレフィンコポリマーおよび接着性増強グラフトポリマーの膜を含む電子素子モジュール
KR20130089230A (ko) * 2010-06-14 2013-08-09 다우 글로벌 테크놀로지스 엘엘씨 수축 필름 용도에서 블렌드 성분으로서 사용하기 위한 에틸렌 기재 중합체 조성물
US8722819B2 (en) * 2010-07-06 2014-05-13 Ticona Gmbh Process for producing high molecular weight polyethylene
KR101849188B1 (ko) * 2010-11-02 2018-04-17 다우 글로벌 테크놀로지스 엘엘씨 실란트 조성물, 그의 제조 방법
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
EP2646508B1 (en) * 2010-12-03 2014-10-01 Dow Global Technologies LLC Processes to prepare ethylene-based polymer compositions
EP3091038B1 (en) 2010-12-21 2019-09-18 Dow Global Technologies LLC Olefin-based polymers and dispersion polymerizations
SG191202A1 (en) 2010-12-21 2013-07-31 Dow Global Technologies Llc Polymerization process and raman analysis for olefin-based polymers
WO2012092491A2 (en) 2010-12-30 2012-07-05 Dow Global Technologies Llc Compositions, methods of making the same, and articles prepared from the same
EP2751192B1 (en) 2011-09-07 2016-11-02 Dow Global Technologies LLC Polymer compositions and articles prepared from the same
EP2751191B1 (en) 2011-09-12 2020-07-22 Dow Global Technologies LLC Compositions and articles formed from the same
US20160272798A1 (en) 2011-09-23 2016-09-22 Exxonmobil Chemical Patents Inc. Modified Polyethylene Compositions with Enhanced Melt Strength
EP2758441B1 (en) * 2011-09-23 2016-10-26 ExxonMobil Chemical Patents Inc. Modified polyethylene compositions
KR101960559B1 (ko) * 2011-10-05 2019-03-20 다우 글로벌 테크놀로지스 엘엘씨 스펀본드 부직포
US9580587B2 (en) 2011-10-10 2017-02-28 Dow Global Technologies Llc Polymer compositions with improved retention of properties under mechanical and thermal stresses
EP2768899B1 (en) 2011-10-20 2020-12-02 Dow Global Technologies LLC Ethylene-based polymer compositions and articles prepared therefrom
MX370571B (es) * 2011-10-21 2019-12-17 Dow Global Technologies Llc Peliculas de contraccion de capas multiples.
ES2625475T3 (es) * 2011-10-24 2017-07-19 Dow Global Technologies Llc Hebra de césped artificial
KR101938440B1 (ko) 2011-12-13 2019-01-14 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-프로필렌-디엔 혼성중합체 조성물
CN103987742B (zh) 2011-12-19 2017-10-24 陶氏环球技术有限责任公司 通过分散聚合法制备的基于乙烯的聚合物
IN2014CN04444A (US08101696-20120124-C00008.png) * 2011-12-20 2015-09-04 Dow Global Technologies Llc
EP2797963B1 (en) * 2011-12-29 2019-07-03 Dow Global Technologies LLC Hyperbranched olefin oil-based dielectric fluid
US9522855B2 (en) 2011-12-29 2016-12-20 Dow Global Technologies Llc Process for producing low molecular weight ethylene- and alpha-olefin-based materials
EP2617741B1 (en) * 2012-01-18 2016-01-13 Borealis AG Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process
JP6170948B2 (ja) * 2012-02-03 2017-07-26 ダウ グローバル テクノロジーズ エルエルシー フィルムを含むシラン含有エチレンインターポリマー配合物及びそれを含む電子デバイスモジュール
EP2847243B1 (en) 2012-05-09 2018-09-05 Dow Global Technologies LLC Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer
BR112014032673B1 (pt) * 2012-06-29 2021-07-06 Dow Global Technologies Llc composição, composição reticulada e artigo
MX2015000904A (es) * 2012-07-20 2015-04-10 Dow Global Technologies Llc Una composicion de polietileno lineal de baja densidad adecuada para peliculas fundidas.
CN104379541B (zh) 2012-08-03 2018-02-23 埃克森美孚化学专利公司 含Salan配体的非‑对称催化剂
CN104364321A (zh) 2012-08-03 2015-02-18 埃克森美孚化学专利公司 含Salan 配体的卤化催化剂
US9365661B2 (en) 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
CA2877754C (en) 2012-08-03 2018-12-11 Exxonmobil Chemical Patents Inc. Catalysts comprising salan ligands
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
US10836853B2 (en) 2012-09-20 2020-11-17 Exxonmobil Chemical Patents Inc. Crack-resistant polyethylene compositions
US10822479B2 (en) 2012-09-20 2020-11-03 Exxonmobil Chemical Patents Inc. Foamed polyethylene compositions
CN104428324B (zh) 2012-11-02 2018-08-17 埃克森美孚化学专利公司 负载型Salan催化剂
JP6207336B2 (ja) * 2012-11-12 2017-10-04 日本ポリプロ株式会社 ジオール化合物及びオレフィン重合用触媒並びにオレフィン重合体の製造方法
CN104812783B (zh) * 2012-11-30 2021-07-16 陶氏环球技术有限责任公司 乙烯/α-烯烃/多烯基组合物
EP2938645B1 (en) 2012-12-27 2019-05-15 Dow Global Technologies LLC An ethylene based polymer
BR112015015394B1 (pt) * 2012-12-27 2021-09-28 Dow Global Technologies Llc Procatalisador, sistema catalisador e processo de polimerização
EP2938648B1 (en) 2012-12-27 2019-01-30 Dow Global Technologies LLC A polymerization process for producing ethylene based polymers
JP6348512B2 (ja) 2012-12-27 2018-06-27 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーを製造するための重合法
CN104884477B (zh) * 2012-12-27 2018-06-08 陶氏环球技术有限责任公司 乙烯类聚合物
JP6175146B2 (ja) * 2013-01-18 2017-08-02 ダウ グローバル テクノロジーズ エルエルシー 高分子量ポリオレフィンのための重合プロセス
US9676879B2 (en) 2013-02-08 2017-06-13 Mitsui Chemicals, Inc. Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
KR101657262B1 (ko) * 2013-04-05 2016-09-13 한화케미칼 주식회사 올레핀 중합용 촉매 및 이를 이용한 폴리올레핀의 제조 방법
US9150676B2 (en) 2013-06-20 2015-10-06 Exxonmobil Chemical Patents Inc. Thio-salalen catalyst
WO2014204681A1 (en) 2013-06-20 2014-12-24 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
US9200099B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Salenol catalyst
EP2883891A4 (en) 2013-06-28 2016-06-01 Lg Chemical Ltd TERNARY ELASTOMER COPOLYMER WITH A DIEN AND METHOD FOR THE PRODUCTION THEREOF
SG10201802443VA (en) 2013-06-28 2018-05-30 Dow Global Technologies Llc Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
WO2014209082A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
US9650460B2 (en) 2013-06-28 2017-05-16 Lg Chem, Ltd. Elastic diene terpolymer and preparation method thereof
CN105339327B (zh) * 2013-06-28 2020-01-21 陶氏环球技术有限责任公司 基于乙烯的超支化寡聚物
US10155831B2 (en) * 2013-09-05 2018-12-18 Univation Technologies, Llc Process control for long chain branching control in polyethylene production
CN104628920B (zh) * 2013-11-08 2017-02-01 中国石油天然气股份有限公司 一种溶液聚合乙丙橡胶的制备方法
WO2015088819A1 (en) 2013-12-13 2015-06-18 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
WO2015116381A1 (en) * 2014-01-30 2015-08-06 Exxonmobil Chemical Patents Inc. Crack-resistant polyethylene composiitions
WO2015116382A1 (en) * 2014-01-30 2015-08-06 Exxonmobil Chemical Patents Inc. Foamed polyethylene compositions
KR101791810B1 (ko) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌 프로필렌 공중합체의 제조 방법
CN106132924B (zh) 2014-03-31 2019-03-19 埃克森美孚化学专利公司 亚苯基桥连的salalen催化剂
KR102355323B1 (ko) * 2014-04-17 2022-01-25 보레알리스 아게 고온 용액 중합 공정으로 폴리에틸렌 코폴리머를 제조하기 위한 개선된 촉매 시스템
ES2949011T3 (es) * 2014-06-30 2023-09-25 Dow Global Technologies Llc Sistemas de catalizador para la polimerización de olefinas
CN106459288B (zh) 2014-06-30 2020-06-09 陶氏环球技术有限责任公司 烯烃聚合方法
US9975975B2 (en) 2014-07-24 2018-05-22 Dow Global Technologies Llc Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers
CN107041138B (zh) 2014-12-04 2020-11-27 陶氏环球技术有限责任公司 用于制备乙烯类聚合物的五配位双苯基苯氧基催化剂
JP6709789B6 (ja) * 2014-12-31 2020-07-22 ダウ グローバル テクノロジーズ エルエルシー ポリオレフィン組成物及びその生成方法
SG11201707846QA (en) * 2015-03-31 2017-10-30 Dow Global Technologies Llc Processes for the production of high molecular weight ethylene/alpha-olefin/non-conjugated interpolymers with low levels of long chain branching
US10336846B2 (en) 2015-05-28 2019-07-02 Dow Global Technologies Llc Process to form ethylene/α-olefin interpolymers
KR102617008B1 (ko) * 2015-06-17 2023-12-26 다우 글로벌 테크놀로지스 엘엘씨 관형 반응기에서 제조되고 그리고 선택적으로 분기제로 변형된 높은 용융 강도의 에틸렌계 폴리머를 사용하여 가교결합된 케이블 절연체를 제조하는 방법
EP3310818B1 (en) * 2015-06-22 2020-01-22 Dow Global Technologies LLC Process for making ethylene-based polymers using carbon-carbon free radical initiators
ES2811135T3 (es) 2015-06-30 2021-03-10 Dow Global Technologies Llc Un procedimiento de polimerización para producir polímeros a base de etileno
US11041027B2 (en) 2015-06-30 2021-06-22 Dow Global Technologies Llc Polymerization process for producing ethylene based polymers
CN108137855B (zh) 2015-09-02 2021-09-28 陶氏环球技术有限责任公司 柔性交联电缆绝缘材料和其制造方法
MX2018002459A (es) 2015-09-02 2018-06-15 Dow Global Technologies Llc Aislamiento de cable reticulado flexible y metodos para hacer el aislamiento de cable reticulado flexible.
WO2017048448A1 (en) 2015-09-14 2017-03-23 Exxonmobil Chemical Patents Inc. Process for making branched epdm and epdm therefrom
JP6829251B2 (ja) 2015-09-30 2021-02-10 ダウ グローバル テクノロジーズ エルエルシー アミノ及びポリメリル基のアルデヒド部分への付加を介する官能性ポリマーの調製プロセス
WO2017058910A1 (en) 2015-09-30 2017-04-06 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
BR112018006183B1 (pt) 2015-09-30 2022-06-14 Dow Global Technologies Llc Pró-catalisador e processo de polimerização
KR102589562B1 (ko) 2015-09-30 2023-10-16 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 폴리머를 제조하기 위한 중합 방법
JP6936795B2 (ja) 2015-10-29 2021-09-22 ダウ グローバル テクノロジーズ エルエルシー 可撓性架橋ケーブル絶縁体のための架橋性ポリマー組成物、及び可撓性架橋ケーブル絶縁体を作製するための方法
JP6874003B2 (ja) 2015-12-29 2021-05-19 ダウ グローバル テクノロジーズ エルエルシー 高度グラフト化エチレン系ポリマー、高度グラフト化エチレン系ポリマー組成物、及びその形成プロセス
ES2703602T3 (es) 2016-03-03 2019-03-11 Dow Global Technologies Llc Composición de polietileno, método para fabricar la misma, y películas fabricadas a partir de la misma
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
SG10202013131WA (en) 2016-06-30 2021-02-25 Dow Global Technologies Llc Procatalyst compositions useful for low comonomer incorporation and process for preparing the same
EP3478762A1 (en) 2016-06-30 2019-05-08 Dow Global Technologies, LLC Ethylene/alpha-olefin/polyene based compositions
EP4029886A3 (en) 2016-06-30 2022-09-28 Dow Global Technologies LLC Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same
CN109641990B (zh) 2016-07-13 2022-08-19 埃克森美孚化学专利公司 双金属茂催化剂共聚物组合物
US11352451B2 (en) 2016-07-13 2022-06-07 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
CN109661457B (zh) 2016-07-14 2022-06-10 埃克森美孚化学专利公司 包含可用作粘度改进剂的双金属茂催化双峰共聚物组合物的润滑油组合物
KR20190032406A (ko) 2016-07-21 2019-03-27 다우 글로벌 테크놀로지스 엘엘씨 복합 쿠션 구조체, 및 그 제조 방법
KR102413982B1 (ko) 2016-07-29 2022-06-30 다우 글로벌 테크놀로지스 엘엘씨 다중모드 엘라스토머 생산용 혼합 촉매 시스템
SG11201900653RA (en) 2016-07-29 2019-02-27 Dow Global Technologies Llc Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
EP3519452B1 (en) 2016-09-29 2024-05-29 Dow Global Technologies LLC Modified ziegler-natta (pro)catalyst and system
WO2018063899A1 (en) 2016-09-29 2018-04-05 Dow Global Technologies Llc Magnesium halide-supported titanium (pro) catalysts
JP7164519B2 (ja) 2016-09-29 2022-11-01 ダウ グローバル テクノロジーズ エルエルシー オレフィンを重合する方法
US11359038B2 (en) 2016-09-30 2022-06-14 Dow Global Technologies Llc Capped multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
KR102464765B1 (ko) 2016-09-30 2022-11-09 다우 글로벌 테크놀로지스 엘엘씨 사슬 이동에 유용한 다중 또는 이중 헤드 조성물의 제조 방법
CN109937217B (zh) 2016-09-30 2021-09-14 陶氏环球技术有限责任公司 适用于链梭移的多头或双头组合物和其制备方法
CA3041067A1 (en) 2016-10-27 2018-05-03 Univation Technologies, Llc Method of preparing a molecular catalyst
WO2018089165A1 (en) 2016-11-11 2018-05-17 Exxonmobil Chemical Patents Inc. Catalyst compositions and use thereof
US10280234B2 (en) 2016-11-11 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and use thereof
TW201829574A (zh) 2016-11-16 2018-08-16 美商陶氏全球科技有限責任公司 黏結層組合物及併有黏結層組合物之多層薄膜
JP7221206B2 (ja) 2017-02-28 2023-02-13 ダウ グローバル テクノロジーズ エルエルシー エチレン系インターポリマーのためのホスホルアミデート触媒
BR112019019076A2 (pt) 2017-03-15 2020-06-30 Dow Global Technologies Llc sistema catalisador de formação de copolímeros de múltiplos blocos
KR102648625B1 (ko) 2017-03-15 2024-03-19 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
CN115260366A (zh) 2017-03-15 2022-11-01 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
SG11201908306TA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
EP3596146B1 (en) 2017-03-15 2023-07-19 Dow Global Technologies LLC Catalyst system for multi-block copolymer formation
JP2018162231A (ja) * 2017-03-27 2018-10-18 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン系重合体の製造方法
EP3409697A1 (en) 2017-05-28 2018-12-05 SABIC Global Technologies B.V. Preparation of polymer dispersions
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
KR20200044032A (ko) 2017-08-24 2020-04-28 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/c5-c10 알파-올레핀/ 폴리엔 혼성중합체
KR102590976B1 (ko) 2017-09-29 2023-10-19 다우 글로벌 테크놀로지스 엘엘씨 개선된 용해도를 위한 금속 상에 메틸렌트리알킬규소 리간드를 갖는 비스-페닐-페녹시 폴리올레핀 촉매
KR102592636B1 (ko) 2017-09-29 2023-10-24 다우 글로벌 테크놀로지스 엘엘씨 개선된 용해도를 위한 금속 상에 두 개의 메틸렌트리알킬규소 리간드를 갖는 비스-페닐-페녹시 폴리올레핀 촉매
CN111164110A (zh) 2017-09-29 2020-05-15 陶氏环球技术有限责任公司 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
JP7394056B2 (ja) 2017-12-26 2023-12-07 ダウ グローバル テクノロジーズ エルエルシー マルチモーダルエチレン系ポリマーおよび低密度ポリエチレン（ｌｄｐｅ）を含む組成物
SG11202005754XA (en) 2017-12-26 2020-07-29 Dow Global Technologies Llc Multimodal ethylene-based polymer compositions having improved toughness
US11555084B2 (en) 2017-12-26 2023-01-17 Dow Global Technologies Llc Multimodal ethylene-based polymer processing systems and methods
JP7467341B2 (ja) 2017-12-26 2024-04-15 ダウ グローバル テクノロジーズ エルエルシー マルチモーダルエチレン系ポリマーの製造のためのプロセス
CN111479832B (zh) 2017-12-26 2024-03-15 陶氏环球技术有限责任公司 用于生产多峰乙烯类聚合物的双反应器溶液法
BR112020012014A2 (pt) 2017-12-26 2020-11-24 Dow Global Technologies Llc composição de polímero, filme, filme de múltiplas camadas, e, artigo.
SG11202005667PA (en) 2017-12-29 2020-07-29 Dow Global Technologies Llc Dual-headed organoaluminum compositions
EP3732211B1 (en) 2017-12-29 2024-05-22 Dow Global Technologies Llc Capped dual-headed organoaluminum compositions
WO2019156794A1 (en) 2018-02-09 2019-08-15 Exxonmobil Chemical Patents Inc. ETHYLENE-α-OLEFIN-DIENE ELASTOMERS AND METHODS OF MAKING THEM
WO2019157687A1 (en) 2018-02-14 2019-08-22 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
US11814555B2 (en) 2018-03-19 2023-11-14 Dow Silicones Corporation Hot melt adhesive compositions containing polyolefin-polydiorganosiloxane copolymers and methods for the preparation and use thereof
US20210017195A1 (en) 2018-03-19 2021-01-21 Dow Global Technologies Llc Process for functionalization of organo-zinc compounds with halosilanes using basic nitrogen containing heterocycles and silyl-functionalized compounds prepared thereby
EP3768687A1 (en) 2018-03-19 2021-01-27 Dow Global Technologies LLC Silicon-terminated organo-metal compounds and processes for preparing the same
TW201938602A (zh) 2018-03-19 2019-10-01 美商陶氏全球科技有限責任公司 矽封端之遙爪聚烯烴組成物及其製備程序
KR20200135420A (ko) 2018-03-19 2020-12-02 다우 글로벌 테크놀로지스 엘엘씨 규소-말단화된 유기-금속 화합물 및 이를 제조하는 방법
KR20200133349A (ko) 2018-03-19 2020-11-27 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 - 폴리디오르가노실록산 블록 공중합체 및 이의 합성을 위한 히드로실릴화 반응 방법
TW201938569A (zh) 2018-03-19 2019-10-01 美商陶氏全球科技有限責任公司 用基於矽烷基之官能化試劑官能化有機金屬化合物之方法及由此製備之矽烷基官能化化合物
WO2019182720A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyolefin-polydiorganosiioxane block copolymer and method for the synthesis thereof
EP3768792B1 (en) 2018-03-19 2023-09-20 Dow Silicones Corporation Hot melt adhesive composition containing a polyolefin - polydiorganosiloxane copolymer and methods for the preparation and use thereof
ES2970290T3 (es) 2018-03-29 2024-05-27 Dow Global Tech Llc Resinas para usar como capa de unión en estructura multicapa y estructuras multicapa que comprenden las mismas
EP3774941B1 (en) 2018-03-30 2022-11-02 Dow Global Technologies LLC Binuclear olefin polymerization activators
BR112020019547B1 (pt) * 2018-03-30 2023-11-28 Dow Global Technologies Llc Processo para polimerizar olefinas
CN111971311B (zh) 2018-03-30 2024-01-23 陶氏环球技术有限责任公司 高度可溶的烷基取代的碳鎓硼酸盐作为烯烃聚合的助催化剂
EP3774035A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Olefin polymerization activators
US11834570B2 (en) 2018-05-31 2023-12-05 Dow Global Technologies Llc Molded articles, and methods thereof
US11873393B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
CA3103015A1 (en) * 2018-06-15 2019-12-19 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
BR112020025506B1 (pt) 2018-06-15 2024-01-23 Dow Global Technologies Llc Método de produção de polímero à base de etileno bimodal
US11873377B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Blown films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
JP7334195B2 (ja) 2018-07-17 2023-08-28 ダウ シリコーンズ コーポレーション ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法
EP3841168B1 (en) 2018-08-29 2024-01-17 ExxonMobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
WO2020112526A1 (en) 2018-11-30 2020-06-04 Dow Global Technologies Llc Polymer-based film with balanced properties
EP3902808A1 (en) 2018-12-28 2021-11-03 Dow Global Technologies LLC Curable compositions comprising unsaturated polyolefins
KR20210121028A (ko) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 유기금속 사슬 이동제
SG11202107071XA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Curable compositions comprising telechelic polyolefins
BR112021012836A2 (pt) 2018-12-28 2021-09-21 Dow Global Technologies Llc Composição curável, e, artigo
WO2020140058A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
US11028805B2 (en) 2019-01-09 2021-06-08 Saudi Arabian Oil Company System and method for on-board catalytic upgrading of hydrocarbon fuels
KR101995951B1 (ko) * 2019-03-12 2019-07-03 주식회사 라이온켐텍 폴리올레핀 공중합체의 연속식 제조방법
CN113631585B (zh) 2019-03-28 2023-10-20 陶氏环球技术有限责任公司 作为烯烃聚合催化剂活化剂的弱配位阴离子的第iii族阴离子络合物
BR112021021366A2 (pt) 2019-04-30 2022-03-15 Dow Global Technologies Llc Processo de polimerização
EP3963005A4 (en) 2019-04-30 2022-11-23 Dow Global Technologies LLC ETHYLENE/PROPYLENE/UNCONJUGATED DIENE INTERPOLYMER COMPOSITION
US11945888B2 (en) 2019-05-15 2024-04-02 Exxonmobil Chemical Patents Inc. Solution polymerization process and product control using effluent density
US20220275121A1 (en) 2019-06-26 2022-09-01 Dow Global Technologies Llc Controlled Long Chain Branching in EPDM by Post-Reactor Modification
US20220251360A1 (en) 2019-06-26 2022-08-11 Dow Global Technologies Llc EPDM Blends with Long Chain Branching
EP3763745A1 (en) 2019-07-10 2021-01-13 Borealis AG High temperature solution process for the copolymerization of alpha-olefins
WO2021022014A1 (en) 2019-07-31 2021-02-04 Dow Global Technologies Llc Polymerization of ethylene in solution processes using a ziegler-natta catalyst and a hydrogenation procatalyst
WO2021035709A1 (en) 2019-08-30 2021-03-04 Dow Global Technologies Llc Polyolefin compositions having improved electrical properties
US20220298344A1 (en) 2019-09-24 2022-09-22 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene interpolymer compositions
WO2021061580A1 (en) 2019-09-24 2021-04-01 Dow Global Technologies Llc Polymer compositions for extruded profiles
EP4085042A1 (en) 2019-12-30 2022-11-09 Dow Global Technologies LLC Process for preparing an alpha-substituted acrylate
EP4085043A1 (en) 2019-12-30 2022-11-09 Dow Global Technologies LLC Process for preparing an alpha-substituted acrylate
KR20220158262A (ko) 2020-03-27 2022-11-30 다우 글로벌 테크놀로지스 엘엘씨 장쇄 분지형 에틸렌계 중합체의 제조 방법
JP2023518728A (ja) 2020-03-27 2023-05-08 ダウ グローバル テクノロジーズ エルエルシー 長鎖分岐エチレン系ポリマー
EP4126990A1 (en) 2020-03-27 2023-02-08 Dow Global Technologies LLC Long-chain branched ethylene-based polymers
KR20220158763A (ko) 2020-03-27 2022-12-01 다우 글로벌 테크놀로지스 엘엘씨 장쇄 분지형 에틸렌계 중합체
EP4127061A1 (en) 2020-03-30 2023-02-08 ExxonMobil Chemical Patents Inc. Comb-block copolymers and methods thereof
EP4143259A1 (en) 2020-04-29 2023-03-08 Dow Global Technologies LLC High flow propylene-based interpolymer compositions
CN111662403B (zh) * 2020-07-14 2022-08-05 万华化学集团股份有限公司 串级催化体系及使用该体系制备lldpe的方法
WO2022015369A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
WO2022015368A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
KR20230039687A (ko) * 2020-07-17 2023-03-21 다우 글로벌 테크놀로지스 엘엘씨 비스-페닐페녹시 금속-리간드 착물을 위한 히드로카르빌-개질된 메틸알루미녹산 공촉매
CN111909196B (zh) * 2020-08-10 2023-05-26 万华化学集团股份有限公司 一类含ivb族双金属配合物催化剂及其制备方法与应用
WO2022073805A1 (en) 2020-10-05 2022-04-14 Borealis Ag High temperature solution process for the copolymerization of ethylene with one ore more α-Olefin comonomer(s)
JP2023552056A (ja) 2020-11-10 2023-12-14 ダウ グローバル テクノロジーズ エルエルシー ビニル末端ポリオレフィンを介した非極性－極性ブロックコポリマーの調製
CN116419941A (zh) 2020-11-10 2023-07-11 陶氏环球技术有限责任公司 用于增加聚乙烯的表面能的聚烯烃-聚丙烯酸酯嵌段共聚物添加剂的制备
WO2022115410A2 (en) 2020-11-24 2022-06-02 Dow Global Technologies Llc Process to produce long chain branching in epdm and product
KR20230152075A (ko) * 2021-02-26 2023-11-02 다우 글로벌 테크놀로지스 엘엘씨 Iv족 폴리올레핀 촉매작용을 위한 비스-페녹시-에테르 리간드
TW202323424A (zh) 2021-08-04 2023-06-16 大陸商中國石油化工科技開發有限公司 一種柔性聚丙烯改性絕緣材料及其製備方法與應用
WO2023039514A1 (en) 2021-09-10 2023-03-16 Dow Global Technologies Llc Hydrocarbon soluble borate cocatalysts for olefin polymerization
WO2023039515A2 (en) 2021-09-10 2023-03-16 Dow Global Technologies Llc Borate cocatalysts for polyolefin production
WO2023072009A1 (zh) 2021-10-26 2023-05-04 中国石油化工股份有限公司 促进聚合物溶液相分离的方法和制备烯烃聚合物的方法
CN114957530B (zh) * 2022-06-28 2023-09-29 杭州双安科技有限公司 一种乙烯和α-烯烃的溶液聚合方法
CN115160472B (zh) * 2022-08-09 2023-07-11 万华化学集团股份有限公司 一种高插入率的乙烯共聚物溶液聚合方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6420507B1 (en) * 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
US6448355B1 (en) * 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
RU2258712C2 (ru) * 2000-12-04 2005-08-20 Юнивейшн Технолоджиз, Ллс Способ полимеризации

Family Cites Families (151)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3914342A (en) 1971-07-13 1975-10-21 Dow Chemical Co Ethylene polymer blend and polymerization process for preparation thereof
US3953413A (en) 1974-06-13 1976-04-27 Chemplex Company Supported chromium-containing catalyst and process of polymerizing 1-olefins
US4173548A (en) 1977-02-02 1979-11-06 Chemplex Company Ethylene polymerization catalyst and method
US4330646A (en) 1979-08-13 1982-05-18 Asahi Kasei Kogyo Kabushiki Kaisha Polymerization of an α-olefin
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
DZ520A1 (fr) 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
US4588790A (en) * 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4430563A (en) 1982-04-30 1984-02-07 Minnesota Mining And Manufacturing Company Data processing form
US4564660A (en) 1983-06-30 1986-01-14 Union Carbide Corporation Use of alkylaluminum compounds and hydroxyl-containing compounds to initiate polymerization of ethylene with chromium oxide catalysts
US4612300A (en) * 1985-06-06 1986-09-16 The Dow Chemical Company Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
WO1988002378A1 (en) 1986-09-24 1988-04-07 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefin
JPH0780933B2 (ja) 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
JPS63154753A (ja) 1986-12-18 1988-06-28 Nippon Oil Co Ltd ポリエチレン系組成物
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
JPH0742301B2 (ja) 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
JP2538588B2 (ja) 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US4981927A (en) 1987-05-20 1991-01-01 National Distillers And Chemical Corporation Chromium catalyst compositions and polymerization utilizing same
FR2634212B1 (fr) * 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
EP0426637B2 (en) 1989-10-30 2001-09-26 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
EP0841349B1 (en) 1990-07-24 2002-06-12 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5296443A (en) * 1991-03-01 1994-03-22 Dai Nippon Printing Co., Ltd. Thermal transfer image receiving sheet
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5308815A (en) 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5674342A (en) * 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5453410A (en) * 1992-01-06 1995-09-26 The Dow Chemical Company Catalyst composition
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5288933A (en) * 1992-04-16 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polyethylene
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
BE1005957A5 (fr) 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
US5504049A (en) 1992-07-01 1996-04-02 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
CA2145635A1 (en) 1992-09-29 1994-04-14 Patrick Brant Long chain branched polymers and a process to make long chain branched polymers
ES2105331T3 (es) 1992-10-02 1997-10-16 Dow Chemical Co Complejos cataliticos homogeneos soportados para polimerizacion de olefinas.
DE4322884A1 (de) 1992-10-09 1994-04-14 Bayer Ag Biologisch aktive Polymere
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5391793A (en) 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5391529A (en) 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
TW298593B (US08101696-20120124-C00008.png) 1993-02-12 1997-02-21 Hoechst Ag
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
EP0699212A1 (en) 1993-04-26 1996-03-06 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
PL176767B1 (pl) * 1993-04-28 1999-07-30 Dow Chemical Co Kompozycja polimeru etylenowego i sposób wytwarzania folii
BE1007148A3 (fr) 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
FR2705252B1 (fr) 1993-05-19 1995-07-21 Bp Chemicals Snc Procédé d'introduction d'un solide dans un réacteur et appareillage.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5372682A (en) * 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
CA2164525C (en) 1993-06-24 2005-03-01 David D. Devore Titanium (ii) or zirconium (ii) complexes and addition polymerization catalysts therefrom
WO1995014044A1 (en) 1993-11-19 1995-05-26 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
JPH07144455A (ja) * 1993-11-25 1995-06-06 Canon Inc インクジェット記録装置
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5674795A (en) 1993-12-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5461123A (en) * 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
DE4436392C2 (de) 1994-10-12 2002-10-31 Fraunhofer Ges Forschung Metallniobate und/oder Tantalate, Verfahren zu ihrer Herstellung sowie deren Weiterverarbeitung zu Perowskiten
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
US5869723A (en) 1995-06-08 1999-02-09 Showa Denko K.K. Ionic compound and olefin polymerization catalyst containing the same
US5731253A (en) 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
US5693838A (en) 1995-11-13 1997-12-02 Albemarle Corporation Aluminoxane process and product
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
DE69720823T2 (de) 1996-01-25 2004-01-22 Tosoh Corp., Shinnanyo Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators.
DE69707107T2 (de) * 1996-03-05 2002-03-07 Dow Chemical Co Rheologisch modifizierte polyolefine
ATE234870T1 (de) 1996-03-27 2003-04-15 Dow Global Technologies Inc Lösungspolymerisationsverfahren mit dispergierten katalysator-aktivierer
AU2214997A (en) 1996-03-27 1997-10-17 Dow Chemical Company, The Highly soluble olefin polymerization catalyst activator
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US5731451A (en) 1996-07-12 1998-03-24 Akzo Nobel Nv Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
JP2001507046A (ja) 1996-09-06 2001-05-29 ヒュンダイ・ペトロケミカル・カンパニー・リミテッド オレフィン（共）重合用触媒及びそれを用いるオレフィン（共）重合体の製造方法
US5744656A (en) 1996-10-25 1998-04-28 Boulder Scientific Company Conversion of hexafluorobenzene to bromopentafluorobenzene
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
FI970349A (fi) 1997-01-28 1998-07-29 Borealis As Uudet metalloseeniyhdisteiden aktivaattorisysteemit
EP0975641A4 (en) 1997-04-03 2003-03-12 Univ Colorado State Res Found POLYHALOGENED MONOHETEROBORANANION PREPARATIONS
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6319989B1 (en) * 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
PL339339A1 (en) 1997-09-19 2000-12-18 Dow Chemical Co Modified alumoxanate-type catalyst activator
BR9812478A (pt) * 1997-09-19 2000-09-26 Dow Chemical Co "composição de interpolìmero de etileno composicionalmente otimizada, com uma distribuição estreita de peso molecular, processo de obtenção e artigos fabricados com a mesma"
US6696379B1 (en) * 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
JP4722287B2 (ja) 1998-02-20 2011-07-13 ダウ グローバル テクノロジーズ インコーポレーテッド 拡大したアニオンを含む触媒活性化剤
US6262202B1 (en) 1998-03-04 2001-07-17 Univation Technologies, Llc Noncoordinating anions for olefin polymerization
US6827976B2 (en) 1998-04-29 2004-12-07 Unaxis Trading Ag Method to increase wear resistance of a tool or other machine component
US6140521A (en) 1998-08-11 2000-10-31 The Dow Chemical Company Ansa group 4 metal bis (μ-substituted) aluminum complexes
JP4817209B2 (ja) 1998-08-11 2011-11-16 ダウ グローバル テクノロジーズ エルエルシー 触媒活性剤組成物
DE69922548T2 (de) * 1998-10-23 2006-01-05 Exxonmobil Chemical Patents Inc., Baytown Verbrückte metallocene zur olefincopolymerisation
JP2000129045A (ja) * 1998-10-27 2000-05-09 Asahi Chem Ind Co Ltd ポリエチレン製クリーン容器
ATE495205T1 (de) * 1998-11-02 2011-01-15 Dow Global Technologies Inc Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung
US6500135B2 (en) * 1998-12-31 2002-12-31 Homedics, Inc. Percussive massager
WO2000049023A1 (en) 1999-02-19 2000-08-24 The Dow Chemical Company Process for preparing trifluoroarylaluminum etherates
US6420298B1 (en) * 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
JP2001098028A (ja) * 1999-09-29 2001-04-10 Japan Polychem Corp 医療容器用ポリエチレン系樹脂及び医療容器
US6750302B1 (en) * 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6727361B2 (en) 2000-11-07 2004-04-27 Symyx Technologies, Inc. Phosphino substituted pyridine amine ligands
JP3549868B2 (ja) * 2001-02-08 2004-08-04 三井化学株式会社 エチレン系重合体およびその製造方法およびそれを用いる成形品
MY137183A (en) 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
JP2004536871A (ja) 2001-07-23 2004-12-09 ダウ グローバル テクノロジーズ インコーポレイティド ルイス酸／酸付加体の塩、およびそれより得られる触媒活性化剤
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US6794908B2 (en) * 2002-05-31 2004-09-21 Honeywell International Inc. Radiation-hard circuit
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
CA2557870A1 (en) * 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US8263722B2 (en) 2004-03-24 2012-09-11 Exxonmobil Chemical Patents Inc. Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
CN101001885B (zh) * 2004-08-09 2011-05-25 陶氏环球技术公司 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂
CA2479704C (en) * 2004-08-31 2013-08-13 Nova Chemicals Corporation High density homopolymer blends
BRPI0516675A (pt) * 2004-11-05 2008-09-16 Dow Global Technologies Inc composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10
KR100639696B1 (ko) * 2005-07-01 2006-10-30 에스케이 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용아릴페녹시 촉매계
MX2008014667A (es) * 2006-05-17 2009-01-26 Dow Global Technologies Inc Proceso de polimerizacion en solucion de polietileno a alta temperatura.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6448355B1 (en) * 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US6420507B1 (en) * 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
RU2258712C2 (ru) * 2000-12-04 2005-08-20 Юнивейшн Технолоджиз, Ллс Способ полимеризации

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KR20090026147A (ko) 2009-03-11
KR20090026150A (ko) 2009-03-11
WO2007136495A3 (en) 2008-01-17
WO2007136496A2 (en) 2007-11-29
RU2008149709A (ru) 2010-06-27
US8450438B2 (en) 2013-05-28
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US8354484B2 (en) 2013-01-15
CA2652456A1 (en) 2007-11-29
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KR101396058B1 (ko) 2014-05-15
BRPI0711018A8 (pt) 2017-09-19
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WO2007136494A2 (en) 2007-11-29
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US8299189B2 (en) 2012-10-30
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WO2007136496A3 (en) 2008-01-31
US20100036069A1 (en) 2010-02-11
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WO2007136493A2 (en) 2007-11-29
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SG158102A1 (en) 2010-01-29
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