ATE495205T1 - Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung - Google Patents

Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung

Info

Publication number
ATE495205T1
ATE495205T1 AT99971431T AT99971431T ATE495205T1 AT E495205 T1 ATE495205 T1 AT E495205T1 AT 99971431 T AT99971431 T AT 99971431T AT 99971431 T AT99971431 T AT 99971431T AT E495205 T1 ATE495205 T1 AT E495205T1
Authority
AT
Austria
Prior art keywords
olefin
ethylene
fluffilizable
sheer
alpha
Prior art date
Application number
AT99971431T
Other languages
English (en)
Inventor
Larry Cady
Morgan Hughes
Michael Laughner
Larry Meiske
Deepak Parikh
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE495205T1 publication Critical patent/ATE495205T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Medicinal Preparation (AREA)
AT99971431T 1998-11-02 1999-11-02 Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung ATE495205T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10656998P 1998-11-02 1998-11-02
PCT/US1999/025637 WO2000026268A1 (en) 1998-11-02 1999-11-02 SHEAR THINNING ETHYLENE/α-OLEFIN INTERPOLYMERS AND THEIR PREPARATION

Publications (1)

Publication Number Publication Date
ATE495205T1 true ATE495205T1 (de) 2011-01-15

Family

ID=22312137

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99971431T ATE495205T1 (de) 1998-11-02 1999-11-02 Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung

Country Status (13)

Country Link
US (1) US7750104B2 (de)
EP (2) EP1159320B1 (de)
JP (3) JP5276757B2 (de)
KR (1) KR100623106B1 (de)
CN (1) CN1134467C (de)
AT (1) ATE495205T1 (de)
AU (1) AU1241600A (de)
BR (1) BR9915199B1 (de)
CA (1) CA2347501C (de)
DE (1) DE69943133D1 (de)
ES (2) ES2666708T3 (de)
MX (1) MXPA01004337A (de)
WO (1) WO2000026268A1 (de)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7511104B2 (en) 2001-06-20 2009-03-31 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
EP1402198B1 (de) * 2001-06-21 2006-05-31 Habasit AG Monolithischer riemen mit ethylen-alpha olefin-copolymeren
US7906586B2 (en) * 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
US20050209403A1 (en) * 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
BRPI0512475A (pt) * 2004-06-28 2008-03-11 Dow Global Technologies Inc adesivo de laminação, estrutura de laminado, laminado de pelìcula/não tecido, e produto de higiene pessoal
ES2320591T3 (es) 2005-05-12 2009-05-25 Dow Global Technologies Inc. Laminados extruidos termoconformados con brillo reducido.
EP1926773B1 (de) 2005-09-12 2010-04-21 Dow Global Technologies Inc. Ethylen-/alpha-olefinverbindungen, daraus hergestellte artikel und herstellungsverfahren dafür
EP1934418A1 (de) 2005-10-07 2008-06-25 Pirelli & C. S.p.A. Leitungsmast aus thermoplastischem verbundmaterial
KR20090018896A (ko) * 2006-04-06 2009-02-24 다우 글로벌 테크놀로지스 인크. 팽창성 폴리올레핀 조성물 및 팽창된 폴리올레핀 조성물을 함유하는 절연 차량 부품
JP5645400B2 (ja) * 2006-05-17 2014-12-24 ダウ グローバル テクノロジーズ エルエルシー ポリプロピレン溶液重合方法
JP2010509407A (ja) * 2006-11-01 2010-03-25 ダウ グローバル テクノロジーズ インコーポレイティド 非極性ポリオレフィンおよびポリウレタンを含む物品、ならびにそれらの作製および使用方法
EP2094740B1 (de) 2006-12-21 2021-01-20 Dow Global Technologies LLC Funktionalisierte olefin-polymere, daraus hergestellte zusammensetzungen und artikel sowie herstellungsverfahren dafür
JP5100342B2 (ja) * 2007-12-05 2012-12-19 三井化学株式会社 ゴム組成物およびその用途
WO2010059474A1 (en) * 2008-11-21 2010-05-27 Dow Global Technologies Inc. Medium voltage cable sheath comprising an olefin-based polymer
WO2011002983A1 (en) 2009-07-02 2011-01-06 Dow Global Technologies Inc. Tpo compositions, articles, and methods of making the same
JP5357643B2 (ja) * 2009-07-08 2013-12-04 三井化学株式会社 ゴム組成物およびその用途
CN102548868B (zh) 2009-07-09 2014-12-10 先进技术材料股份有限公司 基于衬里的存储系统和将流体材料输送给半导体工艺的方法
KR101761549B1 (ko) 2009-07-14 2017-07-26 다우 글로벌 테크놀로지스 엘엘씨 개선된 감소된 광택을 갖는 진공 열성형된 압출 시팅
CN102666701B (zh) 2009-11-23 2016-01-20 陶氏环球技术有限责任公司 组合物、膜及其制备方法
BR112012028158B1 (pt) 2010-05-21 2020-04-07 Dow Global Technologies Llc composição termoplástica e artigo
CN102985476B (zh) 2010-05-27 2015-08-19 陶氏环球技术有限责任公司 聚合物组合物、其制备方法、以及由该组合物制备的制品
US9120887B2 (en) 2010-06-22 2015-09-01 Dow Global Technologies Llc Crosslinked compositions and articles prepared therefrom
IT1400743B1 (it) 2010-06-30 2013-07-02 Dow Global Technologies Inc Composizioni polimeriche
EP2643094A4 (de) 2010-11-23 2017-05-24 Advanced Technology Materials, Inc. Spender mit einem inneren behälter
EP2648911B1 (de) 2010-12-10 2017-01-25 Dow Global Technologies LLC Filme mit verbessertem reibungskoeffizient
ES2591328T3 (es) 2010-12-21 2016-11-28 Dow Global Technologies Llc Polímeros basados en olefinas y polimerizaciones en dispersión
EP2681124A4 (de) 2011-03-01 2015-05-27 Advanced Tech Materials Verschachtelte blasgeformte innere auskleidung und umverpackung sowie herstellungsverfahren dafür
CN103476809A (zh) 2011-05-18 2013-12-25 三井化学株式会社 丙烯系共聚物、丙烯系共聚物组合物、其成型体及其发泡体、及它们的制造方法
KR101212637B1 (ko) * 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타[b]플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
EP2751187B1 (de) 2011-09-23 2016-11-02 Dow Global Technologies LLC Alpha-olefinbasierte polymerzusammensetzung und daraus hergestellte artikel
IN2014CN02606A (de) 2011-10-10 2015-08-07 Dow Global Technologies Llc
CA2857290C (en) 2011-12-13 2020-02-11 Brian W. Walther Ethylene-propylene-diene interpolymer composition
IN2014CN04398A (de) * 2011-12-19 2015-09-04 Dow Global Technologies Llc
BR112014027665B1 (pt) 2012-05-09 2021-04-13 Sasol Technology (Proprietary) Limited Processo para separar um fluxo de hidrocarbonetos multicomponente e processo de oligomerização de etileno
WO2014046777A1 (en) * 2012-09-20 2014-03-27 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions for films
US8901236B2 (en) * 2012-10-09 2014-12-02 Lion Copolymer Geismar, Llc Process for creating an ethylene elastomer
US10160819B2 (en) 2012-11-30 2018-12-25 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
KR102038178B1 (ko) 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리올레핀을 위한 중합 방법
KR101585204B1 (ko) 2013-06-28 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
KR101585206B1 (ko) * 2013-07-22 2016-01-13 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
WO2014209085A1 (ko) 2013-06-28 2014-12-31 주식회사 엘지화학 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법
CN104736579A (zh) 2013-06-28 2015-06-24 株式会社Lg化学 弹性二烯三元共聚物及其制备方法
EP3110885B1 (de) 2014-02-24 2018-10-03 Dow Global Technologies LLC Thermoplastisches polyolefin mit reduziertem glanz für nichtteppichfussboden
BR112018077391B1 (pt) 2016-06-30 2023-01-03 Dow Global Technologies Llc. Composição, composição reticulada e artigo
EP3478762A1 (de) 2016-06-30 2019-05-08 Dow Global Technologies, LLC Auf ethylen/alpha-olefin/polyen basierende zusammensetzungen
US20190169411A1 (en) 2016-08-12 2019-06-06 Dow Global Technologies Llc Propylene-based compositions comprising carbon fibers and a thermoplastic polyolefin elastomer
WO2019040845A1 (en) 2017-08-24 2019-02-28 Dow Global Technologies Llc ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS
BR112020003532B1 (pt) 2017-08-30 2023-05-09 Dow Global Technologies Llc Composição elastomérica, processo para produzir um assoalho sem carpete de veículo e assoalho sem carpete de caminhão ou automóvel
US11970602B2 (en) 2018-02-14 2024-04-30 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance
ES2949785T3 (es) 2018-02-14 2023-10-03 Dow Global Technologies Llc Composiciones de interpolímero de etileno/alfa-olefina con resistencia mejorada a altas temperaturas continuas
KR102520418B1 (ko) 2018-02-14 2023-04-11 다우 글로벌 테크놀로지스 엘엘씨 지속적 고온 내열성이 개선된 에틸렌/알파-올레핀 혼성중합체 조성물
US20230074326A1 (en) * 2019-12-27 2023-03-09 Dow Global Technologies Llc Ethylene/Butene Multi-Block Copolymer and Process for Producing Same
KR102572495B1 (ko) 2021-06-07 2023-09-01 (주) 화승소재 열가소성 가황물 및 이의 제조방법

Family Cites Families (111)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8003A (en) 1851-03-25 Improvement in scythe-tastenings
US304314A (en) 1884-09-02 Method of casting steel
US1305296A (en) 1919-06-03 Kwotss op bendebjng objects less visible against backgrounds
US547718A (en) 1895-10-08 Joseph fletcher
US545403A (en) 1895-08-27 Type weiting machine
US702475A (en) 1902-02-14 1902-06-17 William Powers Harrow.
US876268A (en) 1907-03-05 1908-01-07 Alfred J Diescher Apparatus for washing coal, ore, &c.
US1095893A (en) 1911-09-13 1914-05-05 Clarence P Landreth Process of and apparatus for treating water.
US2491396A (en) 1939-08-11 1949-12-13 Ernst J Seckel Adhesive thread and fabric
DE1276331B (de) 1963-11-21 1968-08-29 Gen Electric Verfahren zur Herstellung eines homogenen halbleitenden Einkristalls
US3706718A (en) 1971-05-10 1972-12-19 Uniroyal Inc Catalyst and method for making epdm having improved processability
GB1534003A (en) * 1975-04-11 1978-11-29 Sola Basic Ind Inc Electrical stress-relieving elastomeric material devices made therewith and method of making shielded electrical conductor terminations
US4177160A (en) 1975-08-08 1979-12-04 Montedison S.P.A. Catalytic components and catalysts for the polymerization of olefins
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
DZ520A1 (fr) 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
JPS58191705A (ja) * 1982-05-06 1983-11-09 Mitsui Petrochem Ind Ltd エチレン共重合ゴム
KR880700016A (ko) * 1985-02-21 1988-02-15 에프 알렉크너 존 자동차페인트를 수용하는 열가소성 제품
DE3524342A1 (de) 1985-07-08 1987-01-15 Daimler Benz Ag Punktschweisszange fuer maschinellen einsatz
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
AU7875791A (en) 1990-05-07 1991-11-27 Exxon Chemical Patents Inc. Unsaturated alpha-olefin copolymers and method for preparation thereof
PL166690B1 (pl) 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US6545088B1 (en) * 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
US5414040A (en) 1992-09-15 1995-05-09 The Dow Chemical Company Formulated ethylene/α-olefin elastomeric compounds
EP0662980A1 (de) 1992-09-29 1995-07-19 Exxon Chemical Patents Inc. Polymere mit langen seitenketten, und ein verfahren zur herstellung von polymeren mit langen seitenketten
US5604043A (en) 1993-09-20 1997-02-18 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
US5326602A (en) 1992-12-01 1994-07-05 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene blends
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
JPH06306121A (ja) * 1993-04-21 1994-11-01 Dow Chem Co:The 弾性で実質的に線状であるオレフィンポリマー
AU681147B2 (en) 1993-04-26 1997-08-21 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
WO1994025495A1 (en) 1993-05-20 1994-11-10 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ES2235285T3 (es) 1993-05-13 2005-07-01 Exxonmobil Chemical Patents Inc. Copolimeros de etileno con una distribucion de la composicion relativamente estrecha, su produccion y uso.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
FR2706330B1 (fr) 1993-06-15 1995-08-25 Conceptair Anstalt Dispositif polyvalent de pulvérisation et de fumigation de substance fluide vaporisable.
CA2164525C (en) 1993-06-24 2005-03-01 David D. Devore Titanium (ii) or zirconium (ii) complexes and addition polymerization catalysts therefrom
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
CN1043648C (zh) 1993-09-17 1999-06-16 陶氏化学公司 烯烃的气相聚合法
WO1995013305A1 (en) 1993-11-08 1995-05-18 Mobil Oil Corporation Process for the polymerization or copolymerization of ethylene
WO1995014024A1 (en) 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst
CA2138572C (en) 1993-12-21 1999-08-24 Univation Technologies Llc Production of polyolefins containing long chain branches by a gas phase process
JP3548619B2 (ja) * 1994-03-04 2004-07-28 アドバンスド エラストマー システムズ,エル.ピー. 半透明熱可塑性エラストマー
NL9400758A (nl) 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5616664A (en) 1994-08-02 1997-04-01 The Dow Chemical Company Polymerization process with biscyclopentadienyl diene complex containing catalysts
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
CA2198136A1 (en) * 1994-09-02 1996-03-14 Dow Global Technologies Inc. Thermoset elastomers
US5869591A (en) * 1994-09-02 1999-02-09 The Dow Chemical Company Thermoset interpolymers and foams
US5541349A (en) 1994-09-12 1996-07-30 The Dow Chemical Company Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom
US5495036A (en) 1994-09-12 1996-02-27 The Dow Chemical Company Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
JP3468886B2 (ja) 1994-10-14 2003-11-17 丸善工業株式会社 発泡チューブラーフィルム、その製法および物品包装用袋
JP3560379B2 (ja) * 1995-02-28 2004-09-02 三菱化学株式会社 エチレン重合体およびその製造法
KR19990007827A (ko) 1995-04-19 1999-01-25 말콤디.킨 직쇄 폴리에틸렌으로의 장쇄 측쇄 도입
CA2178459A1 (en) 1995-06-07 1996-12-08 William Scott Lambert Low shrink force shrink film containing homogeneous substantially linear polymer having long chain branching
JP3483173B2 (ja) * 1995-06-29 2004-01-06 三井化学株式会社 オレフィン系熱可塑性エラストマー組成物
MY114719A (en) * 1995-06-29 2002-12-31 Mitsui Chemicals Inc Olefin thermoplastic elastomer compositions
JPH11511203A (ja) 1995-08-16 1999-09-28 シーメンス アクチエンゲゼルシヤフト 高温酸化性ガスの案内部品
US5670595A (en) * 1995-08-28 1997-09-23 Exxon Chemical Patents Inc. Diene modified polymers
AU717869B2 (en) 1995-10-27 2000-04-06 Dow Chemical Company, The Substituted indenyl containing metal complexes and olefin polymerization process
CA2198998C (en) 1996-03-04 2001-08-21 Keiji Okada Foamable olefin thermoplastic elastomer compositions and foamed products thereof
CN1098344C (zh) 1996-03-08 2003-01-08 杜邦唐弹性体公司 用作粘度指数改进剂或胶凝剂的基本线性乙烯/α-烯烃聚合物
US5958905A (en) 1996-03-26 1999-09-28 Texas Biotechnology Corporation Phosphoramidates, phosphinic amides and related compounds and the use thereof to modulate the activity of endothelin
ATE241203T1 (de) * 1996-04-10 2003-06-15 Dow Chemical Co Ethylenpolymer-zusammensetzung für electrische kabel
JPH09316254A (ja) * 1996-05-27 1997-12-09 Arai Pump Mfg Co Ltd ローラ用ゴム組成物およびこれを用いた記録媒体搬送ローラ
TR199900487T2 (xx) 1996-08-08 1999-06-21 The Dow Chemical Company �� heteroatom ikameli siklopentadienil i�eren metal kompleksleri ve olefin polimerizasyonu i�in i�lem.
JP2001505949A (ja) 1996-12-12 2001-05-08 ザ・ダウ・ケミカル・カンパニー インターポリマー組成物およびそれから作られたキャストストレッチフィルム
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
US6506842B1 (en) 1997-01-29 2003-01-14 Dupont Dow Elastomers L.L.C. Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom
CN1246127A (zh) 1997-02-07 2000-03-01 埃克森化学专利公司 含乙烯基的大分子单体的制备
KR100488833B1 (ko) * 1997-04-30 2005-05-11 듀폰 다우 엘라스토마스 엘. 엘. 씨. 에틸렌/알파-올레핀/디엔 공중합체 및 그의 제조 방법
AR012645A1 (es) * 1997-05-01 2000-11-08 Dow Global Technologies Inc Polimeros de alfa-olefinas preparados por polimerizacion en presencia de complejos de metales que contienen grupos indenilo
US6207754B1 (en) 1997-05-29 2001-03-27 Exxon Chemical Patents, Inc. Low modulus thermoplastic olefin compositions
EP1003812B1 (de) 1997-08-15 2005-02-09 Dow Global Technologies Inc. Filme aus im wesentlichen homogenen linearen olefinischen polymerzusammensetzungen
EP1007586B1 (de) * 1997-08-27 2005-10-12 Dow Global Technologies Inc. Rheologieänderung in polyethylen niedriger dichte
US6680361B1 (en) 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
US6815062B2 (en) 1999-06-21 2004-11-09 Pirelli Cavi E Sistemi S.P.A. Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein
US6369176B1 (en) 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6372847B1 (en) 2000-05-10 2002-04-16 Exxon Mobil Chemical Patents, Inc. Polyolefin compositions having improved low temperature toughness
JP4723732B2 (ja) 2000-07-12 2011-07-13 セイコーインスツル株式会社 脈検出装置及び超音波診断装置
US6498214B2 (en) 2000-08-22 2002-12-24 Dupont Dow Elastomers L.L.C. Soft touch TPO compositions comprising polypropylene and low crystalline ethylene copolymers
US6548600B2 (en) 2000-09-22 2003-04-15 Dupont Dow Elastomers L.L.C. Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents
AU2003222054A1 (en) 2002-03-22 2003-10-13 Dow Global Technologies Inc. Thermoplastic vulcanizate composition and method of making same
US7338994B2 (en) 2002-10-01 2008-03-04 Dow Global Technologies Inc. Rheology-modified thermoplastic elastomer compositions for extruded profiles
US20050209403A1 (en) 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
US7906586B2 (en) 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
EP1846505B1 (de) 2005-02-09 2015-11-11 Covidien LP Synthetische dichtungsmittel
US7592362B2 (en) 2006-01-19 2009-09-22 Pfizer Limited Substituted imidazoles
WO2008024815A2 (en) 2006-08-22 2008-02-28 Dimensions Imaging Method and system for providing tolerance to interference and obstructions of line of sight observation
JP2009049520A (ja) 2007-08-14 2009-03-05 Fuji Xerox Co Ltd 画像処理装置及びシステム
US7904770B2 (en) 2008-09-09 2011-03-08 Qualcomm Incorporated Testing circuit split between tiers of through silicon stacking chips

Also Published As

Publication number Publication date
ES2666708T3 (es) 2018-05-07
ES2356612T3 (es) 2011-04-11
JP5276757B2 (ja) 2013-08-28
BR9915199B1 (pt) 2010-09-08
EP1159320A1 (de) 2001-12-05
JP6039906B2 (ja) 2016-12-07
CN1332755A (zh) 2002-01-23
AU1241600A (en) 2000-05-22
EP2277928B1 (de) 2018-02-21
JP6117143B2 (ja) 2017-04-19
KR100623106B1 (ko) 2006-09-13
CA2347501A1 (en) 2000-05-11
CN1134467C (zh) 2004-01-14
JP2014145082A (ja) 2014-08-14
EP1159320B1 (de) 2011-01-12
JP2012136706A (ja) 2012-07-19
US7750104B2 (en) 2010-07-06
CA2347501C (en) 2010-03-23
MXPA01004337A (es) 2002-04-24
DE69943133D1 (de) 2011-02-24
BR9915199A (pt) 2001-12-04
EP2277928A1 (de) 2011-01-26
US20070203314A1 (en) 2007-08-30
JP2002528610A (ja) 2002-09-03
KR20010080925A (ko) 2001-08-25
WO2000026268A1 (en) 2000-05-11

Similar Documents

Publication Publication Date Title
ATE495205T1 (de) Unter scherwirkung verflüssigbare ethylen/alpha- olefin/dien polymere und ihre herstellung
EP0839823A3 (de) Metallocene
AU7845000A (en) Catalyst compositions and method of polymerization therewith
ATE217891T1 (de) Metallocen-alumoxan-trägerkatalysator für die herstellung von polyethylen mit breiter monomodaler molekulargewichtsverteilung
MX9501383A (es) Metalocenos que contienen fluorenilo para utilizarse en polimerizacion de olefinas.
RU94033101A (ru) Способ получения полимеров этилена и продукты, полученные из них
DE69532461D1 (de) Katalysatorsysteme und Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtverteilung
BR0013335B1 (pt) mistura polimérica baseada em etileno, e artigo
DE59409990D1 (de) Verfahren zur Herstellung von Polyolefinen
NO952217L (no) Etylenselektive metallocener med höy aktivitet
EG24910A (en) Polymerization catalysts for producing polymers with low levels of long chain branching
CA2146208A1 (en) Polymerisation process
TW200628503A (en) Supported metallocene catalyst and method of preparing ethylene-based copolymer using the same
EP0666267A3 (de) Organometall-Fluorenylverbindungen deren Herstellung und deren Verwendung
WO2004060930A3 (en) Processes for transitioning between metallocene and ziegler-natta polymerization catalysts
ATE293643T1 (de) Propen dien copolymerisate
ATE269887T1 (de) Pigmentkonzentrate und verfahren zu ihrer herstellung
ATE200496T1 (de) Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators
DK1082356T3 (da) Kontrol af molekylvægten ved polymerisation af olefiner
DE69214256D1 (de) Verfahren zur Herstellung von Elastomer-Ethylencopolymeren
ES2116188A1 (es) Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
AU7540700A (en) Modified supported catalysts for the polymerization of olefins
ATE425172T1 (de) Monocyclopentadienylkomplexe
ES2182490T3 (es) Nuevos compuestos dendrimeros, un procedimiento para su obtencion asi como su empleo como catalizadores.
DE50103646D1 (de) Pigmentkonzentrate und verfahren zu ihrer herstellung

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties