CN1044481C - 有载体的链烯聚合催化剂及其制备和应用 - Google Patents
有载体的链烯聚合催化剂及其制备和应用 Download PDFInfo
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- CN1044481C CN1044481C CN94194013A CN94194013A CN1044481C CN 1044481 C CN1044481 C CN 1044481C CN 94194013 A CN94194013 A CN 94194013A CN 94194013 A CN94194013 A CN 94194013A CN 1044481 C CN1044481 C CN 1044481C
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- Prior art keywords
- carrier
- porous support
- characteristic
- zirconium
- aikyiaiurnirsoxan beta
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI934917 | 1993-11-05 | ||
FI934917A FI96866C (fi) | 1993-11-05 | 1993-11-05 | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1134160A CN1134160A (zh) | 1996-10-23 |
CN1044481C true CN1044481C (zh) | 1999-08-04 |
Family
ID=8538908
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94194013A Expired - Fee Related CN1044481C (zh) | 1993-11-05 | 1994-11-04 | 有载体的链烯聚合催化剂及其制备和应用 |
Country Status (19)
Families Citing this family (226)
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KR960704941A (ko) * | 1993-10-22 | 1996-10-09 | 데니스 피. 샌티니 | 올레핀의 중합 또는 공중합 촉매(an olefin polymerization or copoly merization catalyst) |
EP0766700B1 (en) * | 1994-06-24 | 2000-01-19 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US6506866B2 (en) | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
US6043180A (en) * | 1994-11-17 | 2000-03-28 | The Dow Chemical Company | Supported catalyst component, supported catalyst, their preparation, and addition polymerization process |
US5625015A (en) * | 1994-11-23 | 1997-04-29 | Exxon Chemical Patents Inc. | Method for making supported catalyst systems and catalyst systems therefrom |
FI104975B (fi) * | 1995-04-12 | 2000-05-15 | Borealis As | Menetelmä katalyyttikomponenttien valmistamiseksi |
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DE69620760T2 (de) * | 1995-07-06 | 2002-12-05 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polymerisierten geträgerten metallocenkatalysatorsystemen |
SE9504539D0 (sv) | 1995-12-19 | 1995-12-19 | Borealis As | Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation |
DE19548288A1 (de) * | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
WO1997024375A1 (en) * | 1995-12-29 | 1997-07-10 | Exxon Chemical Patents Inc. | Slurry polymerization process |
US5786291A (en) * | 1996-02-23 | 1998-07-28 | Exxon Chemical Patents, Inc. | Engineered catalyst systems and methods for their production and use |
JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
KR20000048478A (ko) * | 1996-09-24 | 2000-07-25 | 엑손 케미칼 패턴츠 인코포레이티드 | 지지된 메탈로센 촉매 시스템을 제조하기위한 개선된 방법 |
US6180736B1 (en) | 1996-12-20 | 2001-01-30 | Exxon Chemical Patents Inc | High activity metallocene polymerization process |
DE19757563A1 (de) | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
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DE19758306B4 (de) * | 1997-12-31 | 2005-06-09 | Basell Polyolefine Gmbh | Katalysator für die Polyolefinsynthese |
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IL111532A0 (en) | 1995-01-24 |
FI934917A (fi) | 1995-05-06 |
HU216545B (hu) | 1999-07-28 |
BR9407968A (pt) | 1996-12-03 |
ATE195325T1 (de) | 2000-08-15 |
JPH09504567A (ja) | 1997-05-06 |
CZ130596A3 (en) | 1996-07-17 |
ES2149950T3 (es) | 2000-11-16 |
CA2175702C (en) | 2002-12-31 |
AU685870B2 (en) | 1998-01-29 |
SK281632B6 (sk) | 2001-06-11 |
WO1995012622A1 (en) | 1995-05-11 |
FI96866B (fi) | 1996-05-31 |
AU8107894A (en) | 1995-05-23 |
DE69425485T3 (de) | 2007-05-24 |
EP0678103B1 (en) | 2000-08-09 |
DE69425485T2 (de) | 2001-01-11 |
JP2990299B2 (ja) | 1999-12-13 |
MY131681A (en) | 2007-08-30 |
CN1134160A (zh) | 1996-10-23 |
DE69425485D1 (de) | 2000-09-14 |
HU9601153D0 (en) | 1996-07-29 |
EP0678103A1 (en) | 1995-10-25 |
CA2175702A1 (en) | 1995-05-11 |
SK56096A3 (en) | 1997-04-09 |
IL111532A (en) | 2000-02-29 |
CZ284859B6 (cs) | 1999-03-17 |
US6291611B1 (en) | 2001-09-18 |
FI934917A0 (fi) | 1993-11-05 |
EP0678103B2 (en) | 2007-02-14 |
FI96866C (fi) | 1996-09-10 |
HUT75187A (en) | 1997-04-28 |
ES2149950T5 (es) | 2007-09-16 |
TW341578B (en) | 1998-10-01 |
KR100262245B1 (ko) | 2000-07-15 |
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