KR100568478B1 - 폴리프로필렌의 제조방법 - Google Patents

폴리프로필렌의 제조방법 Download PDF

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KR100568478B1
KR100568478B1 KR1020007004979A KR20007004979A KR100568478B1 KR 100568478 B1 KR100568478 B1 KR 100568478B1 KR 1020007004979 A KR1020007004979 A KR 1020007004979A KR 20007004979 A KR20007004979 A KR 20007004979A KR 100568478 B1 KR100568478 B1 KR 100568478B1
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catalyst
propylene
polymer
group
polymerization
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Korean (ko)
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KR20010015802A (ko
Inventor
아미르 카르바시
파울리 레스키넨
피르요 예스켈레이넨
보 말름
패이비 피트케넨
미카 해르캐넨
욘 하우겐
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보레알리스 에이/에스
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0823—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic cyclic olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0838—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with monomers including an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Peptides Or Proteins (AREA)
  • Polymerisation Methods In General (AREA)
  • Measurement Of Force In General (AREA)
  • Materials For Medical Uses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020007004979A 1997-11-07 1998-11-09 폴리프로필렌의 제조방법 Expired - Lifetime KR100568478B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI974175 1997-11-07
FI974175A FI974175L (fi) 1997-11-07 1997-11-07 Menetelmä polypropeenin valmistamiseksi
PCT/FI1998/000866 WO1999024478A1 (en) 1997-11-07 1998-11-09 Process for preparing polypropylene

Publications (2)

Publication Number Publication Date
KR20010015802A KR20010015802A (ko) 2001-02-26
KR100568478B1 true KR100568478B1 (ko) 2006-04-07

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ID=8549898

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Application Number Title Priority Date Filing Date
KR1020007004979A Expired - Lifetime KR100568478B1 (ko) 1997-11-07 1998-11-09 폴리프로필렌의 제조방법

Country Status (16)

Country Link
US (1) US6437063B1 (https=)
EP (1) EP1028984B1 (https=)
JP (1) JP2001522903A (https=)
KR (1) KR100568478B1 (https=)
CN (1) CN1106409C (https=)
AT (1) ATE203548T1 (https=)
AU (1) AU744410B2 (https=)
BR (1) BR9813986A (https=)
CA (1) CA2308076C (https=)
CZ (1) CZ300533B6 (https=)
DE (1) DE69801236T2 (https=)
ES (1) ES2162471T3 (https=)
FI (1) FI974175L (https=)
IL (1) IL135913A0 (https=)
PL (1) PL195824B1 (https=)
WO (1) WO1999024478A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009045043A3 (en) * 2007-10-02 2009-06-25 Lg Chemical Ltd Method of producing highly transparent polypropylene including prepolymerization step
KR101019836B1 (ko) * 2008-08-26 2011-03-04 삼성토탈 주식회사 폴리올레핀의 기상중합 방법
KR101798500B1 (ko) 2010-01-22 2017-11-16 차이나 페트로리움 앤드 케미컬 코포레이션 고 용융강도를 가지는 프로필렌 단일중합체 및 이의 제조 방법

Families Citing this family (455)

* Cited by examiner, † Cited by third party
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FI974178A0 (fi) * 1997-11-07 1997-11-07 Borealis As Polypropensammansaettningar
FI991057A0 (fi) * 1999-05-07 1999-05-07 Borealis As Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
EP1218423B1 (en) 1999-10-02 2005-03-16 Borealis Technology Oy Modified supported catalysts for the polymerization of olefins
EP1174261A1 (en) 2000-07-20 2002-01-23 Borcalis GmbH Single and multilayer polyolefin foam pipes
EP1213375A1 (en) * 2000-12-07 2002-06-12 Borealis GmbH Non-postdrawn polyolefin with high tenacity
EP1213376A1 (en) * 2000-12-07 2002-06-12 Borealis GmbH Non-postdrawn polyolefin fibers with high strength
EP1260545A1 (en) 2001-05-21 2002-11-27 Borealis Technology OY Industrial polyolefin piping system
EP1260546A1 (en) 2001-05-21 2002-11-27 Borealis Technology OY Polyolefin multilayer pipe
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
JP4709748B2 (ja) 2003-07-04 2011-06-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合方法
ES2301893T3 (es) * 2004-04-20 2008-07-01 Borealis Technology Oy Composicion polimerica con rigidez y resistencia al impacto mejorada.
EP1598379A1 (en) * 2004-05-18 2005-11-23 Borealis Technology OY Process for producing polypropylene film
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ATE435243T1 (de) † 2005-05-20 2009-07-15 Borealis Tech Oy Polymer mit hohem schmelzfluss und verbesserter beständigkeit für röhrenanwendungen
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009045043A3 (en) * 2007-10-02 2009-06-25 Lg Chemical Ltd Method of producing highly transparent polypropylene including prepolymerization step
KR101021758B1 (ko) 2007-10-02 2011-03-15 주식회사 엘지화학 전중합 단계를 포함하는 고투명성 폴리프로필렌의 제조방법
KR101019836B1 (ko) * 2008-08-26 2011-03-04 삼성토탈 주식회사 폴리올레핀의 기상중합 방법
KR101798500B1 (ko) 2010-01-22 2017-11-16 차이나 페트로리움 앤드 케미컬 코포레이션 고 용융강도를 가지는 프로필렌 단일중합체 및 이의 제조 방법

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DE69801236D1 (de) 2001-08-30
JP2001522903A (ja) 2001-11-20
ATE203548T1 (de) 2001-08-15
CA2308076A1 (en) 1999-05-20
IL135913A0 (en) 2001-05-20
FI974175A7 (fi) 1999-05-08
AU1035699A (en) 1999-05-31
EP1028984A1 (en) 2000-08-23
CN1285850A (zh) 2001-02-28
DE69801236T2 (de) 2002-05-16
KR20010015802A (ko) 2001-02-26
BR9813986A (pt) 2000-09-26
WO1999024478A1 (en) 1999-05-20
PL340376A1 (en) 2001-01-29
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FI974175A0 (fi) 1997-11-07
US6437063B1 (en) 2002-08-20
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EP1028984B1 (en) 2001-07-25
FI974175L (fi) 1999-05-08

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