JPS62116535A - 遷移金属錯体触媒方法 - Google Patents

遷移金属錯体触媒方法

Info

Publication number
JPS62116535A
JPS62116535A JP61206937A JP20693786A JPS62116535A JP S62116535 A JPS62116535 A JP S62116535A JP 61206937 A JP61206937 A JP 61206937A JP 20693786 A JP20693786 A JP 20693786A JP S62116535 A JPS62116535 A JP S62116535A
Authority
JP
Japan
Prior art keywords
group
radical
poly
phosphite
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61206937A
Other languages
English (en)
Japanese (ja)
Other versions
JPH0451531B2 (enExample
Inventor
エルンスト・ビリグ
アントニ・ジヨージ・アバトジヨグルー
デイビツド・ロバート・ブライアント
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of JPS62116535A publication Critical patent/JPS62116535A/ja
Publication of JPH0451531B2 publication Critical patent/JPH0451531B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP61206937A 1985-09-05 1986-09-04 遷移金属錯体触媒方法 Granted JPS62116535A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US772859 1985-09-05
US06/772,859 US4668651A (en) 1985-09-05 1985-09-05 Transition metal complex catalyzed processes

Publications (2)

Publication Number Publication Date
JPS62116535A true JPS62116535A (ja) 1987-05-28
JPH0451531B2 JPH0451531B2 (enExample) 1992-08-19

Family

ID=25096469

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61206937A Granted JPS62116535A (ja) 1985-09-05 1986-09-04 遷移金属錯体触媒方法

Country Status (22)

Country Link
US (2) US4668651A (enExample)
EP (1) EP0214622B1 (enExample)
JP (1) JPS62116535A (enExample)
KR (1) KR910009181B1 (enExample)
CN (2) CN1007348B (enExample)
AR (1) AR242182A1 (enExample)
AT (1) ATE76054T1 (enExample)
AU (1) AU597593B2 (enExample)
BR (1) BR8604261A (enExample)
CA (1) CA1281704C (enExample)
CS (2) CS8606430A3 (enExample)
DE (1) DE3685276D1 (enExample)
DK (1) DK423486A (enExample)
ES (1) ES2001416A6 (enExample)
FI (1) FI88916C (enExample)
HU (1) HU204489B (enExample)
IN (1) IN168034B (enExample)
MX (1) MX164384B (enExample)
NO (1) NO167652C (enExample)
PL (1) PL152601B1 (enExample)
YU (1) YU46024B (enExample)
ZA (1) ZA866728B (enExample)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02149591A (ja) * 1988-08-05 1990-06-08 Union Carbide Chem & Plast Co Inc 均一遷移金属触媒方法におけるイオン性ホスフィットの使用
JPH0977713A (ja) * 1995-09-19 1997-03-25 Mitsubishi Chem Corp アルデヒド類の製造方法
JPH11130718A (ja) * 1997-10-28 1999-05-18 Mitsubishi Chemical Corp アルデヒド類の製造方法及びこれに用いるビスホスファイト
JP2002193987A (ja) * 2000-10-27 2002-07-10 Oxeno Olefinchemie Gmbh ビスホスフィット、その金属錯体、及びビスホスフィット及び錯体の使用
JP2002212195A (ja) * 2000-11-24 2002-07-31 Oxeno Olefinchemie Gmbh ホスフィニン、それらの金属錯体及びホスフィニン及びそれらの金属錯体の使用
US6583324B2 (en) 1998-12-10 2003-06-24 Mitsubishi Chemical Corporation Process for producing aldehyde
JP2003533337A (ja) * 1999-09-20 2003-11-11 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 重合体のホスファイトリガンドを使用した不飽和化合物のヒドロホルミル化
JP2006521385A (ja) * 2003-03-28 2006-09-21 ダウ グローバル テクノロジーズ インコーポレイティド アキラルジオールによって橋架けされた光学活性ビスホスファイトから製造された非対称触媒
WO2007114445A1 (ja) 2006-04-04 2007-10-11 Kuraray Co., Ltd. ビスホスファイトおよび第８～１０族金属化合物を用いたアルデヒドの製造方法、並びに該ビスホスファイト
JP2009519941A (ja) * 2005-12-15 2009-05-21 ザ ペン ステイト リサーチ ファンデーション 触媒性ヒドロホルミル化および関連反応における４リン酸配位子
JP2011521990A (ja) * 2008-06-03 2011-07-28 エボニック オクセノ ゲゼルシャフト ミット ベシュレンクテル ハフツング ヒドロホルミル化によりｃ４−含有炭化水素流から１−ブテンを分離する方法
JP2012505215A (ja) * 2008-10-08 2012-03-01 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ビスホスファイトの合成のためのスラリープロセス
JP2015531402A (ja) * 2012-10-12 2015-11-02 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ 非対称ビスホスフィット
JP2015218172A (ja) * 2014-05-20 2015-12-07 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ カーボネート基を有する、新規モノホスファイト配位子

Families Citing this family (238)

* Cited by examiner, † Cited by third party
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US4885401A (en) * 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4774361A (en) * 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
JPH0819028B2 (ja) * 1987-07-22 1996-02-28 株式会社クラレ ヒドロホルミル化方法
FR2629367B1 (fr) * 1988-03-30 1990-11-23 Norsolor Sa Systeme catalytique, son procede de preparation et son application a la fabrication d'aldehydes
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
US5135901A (en) * 1989-06-29 1992-08-04 Eastman Chemical Company A catalyst composition comprising rhodium, ruthenium,and a promoter
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
DE4026406A1 (de) * 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
JPH06503808A (ja) * 1990-08-31 1994-04-28 ザ　ガヴァナーズ　オヴ　ザ　ユニヴァーシティ　オヴ　アルバータ 新規の遷移金属触媒先駆物質を用いるメタノールのカルボニル化
US5179055A (en) * 1990-09-24 1993-01-12 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
US5260491A (en) * 1990-09-24 1993-11-09 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
TW213465B (enExample) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
DE4204808A1 (de) * 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5292785A (en) * 1992-05-05 1994-03-08 Ciba-Geigy Corporation Bis-phosphite stabilized compositions
US5334791A (en) * 1992-05-22 1994-08-02 Ligands Inc. Hydrogenation process with transition metal catalysts derived from bifunctional phosphorus-nitrogen ligands
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5364950A (en) * 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5322633A (en) * 1992-11-16 1994-06-21 Albemarle Corporation Preparation of branched chain carboxylic esters
ES2122515T3 (es) * 1993-11-23 1998-12-16 Du Pont Procedimientos y composiciones cataliticas para hidrocianacion de monoolefinas.
US5512695A (en) * 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
DE69519020T2 (de) 1994-04-14 2001-05-17 E.I. Du Pont De Nemours And Co., Wilmington Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
DE4431528A1 (de) * 1994-09-03 1996-03-07 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol
TW315370B (enExample) * 1994-10-07 1997-09-11 Du Pont
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
JPH10509973A (ja) * 1994-11-25 1998-09-29 ディーエスエム エヌ．ブイ． アルデヒドの調製法
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
US5663403A (en) * 1995-01-24 1997-09-02 Mitsubishi Chemical Corporation Bisphosphite compound and method for producing aldehydes
IN187044B (enExample) * 1995-01-27 2002-01-05 Du Pont
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US5648554A (en) * 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
JP3766990B2 (ja) * 1995-10-02 2006-04-19 住友化学株式会社 亜リン酸エステル類、その製造方法及びその用途
US5789625A (en) * 1995-12-06 1998-08-04 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5728893A (en) * 1995-12-06 1998-03-17 Union Carbide Chemicals & Plastics Technology Corporation Process using multistaged reactors
PL328781A1 (en) * 1995-12-06 1999-02-15 Union Carbide Chem Plastic Improved processes being catalysed by means of a metal-ligand complex catalyst
US5741942A (en) * 1996-11-26 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5767321A (en) † 1995-12-06 1998-06-16 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5654455A (en) * 1995-12-21 1997-08-05 Ciba-Geigy Corporation Tris-phosphite ligands and their use in transitioin metal catalyzed processes
US5874641A (en) * 1996-03-15 1999-02-23 Dsm N.V. Process to prepare a terminal aldehyde
US5710306A (en) * 1996-03-15 1998-01-20 Dsm N.V. Process to prepare a multidentate phosphite compound
TW343195B (en) * 1996-03-15 1998-10-21 Dsm Nv Process to prepare a terminal aldehyde
EP0839787A1 (en) † 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
US5821389A (en) * 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
US5886237A (en) * 1996-04-24 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing alkenals and alkenols
US5817883A (en) * 1996-04-24 1998-10-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing hydroxyaldehydes
US5892127A (en) * 1996-04-24 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing 1,6-hexanedials and derivatives
DE19631521A1 (de) * 1996-08-03 1998-02-05 Basf Ag Verfahren zur Herstellung von 6-Aminocapronitril
US6274773B1 (en) 1996-11-04 2001-08-14 Dsm Process for the continuous preparation of alkyl 5-formylvalerate compounds using homogeneous rhodium hydroformylation catalysts
US5710344A (en) * 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
US5874640A (en) * 1996-11-26 1999-02-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5892119A (en) * 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5917095A (en) * 1996-11-26 1999-06-29 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
MY120454A (en) 1997-07-29 2005-10-31 Du Pont Improved process of preparation of linear aldehydes
US6069267A (en) * 1997-07-29 2000-05-30 E. I. Du Pont De Nemours And Company Selective synthesis of organodiphosphite compounds
EP0895811A1 (en) 1997-08-08 1999-02-10 Dsm N.V. Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid
US5962744A (en) * 1998-03-27 1999-10-05 The Research Foundation Of State University Of New York Process for hydrocarbonylations in supercritical carbon dioxide
EP1102634B1 (en) 1998-07-10 2005-02-09 Dupont Canada Inc. Supported dendrimer catalyst and its use in hydroformylation or for carbon-carbon bond formation
US6307107B1 (en) 1999-09-20 2001-10-23 E.I. Du Pont De Nemours And Company Hydroformylation of acyclic monoethylenically unsaturated compounds to corresponding terminal aldehydes
DE60032627T2 (de) * 1999-11-03 2007-10-04 Nexicor, LLC, Cincinnati Induktionshandgerät
DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
US6610891B1 (en) 1999-12-03 2003-08-26 Mitsubishi Chemical Corporation Method of producing aldehydes
EP1172143A1 (en) * 2000-07-14 2002-01-16 Dsm N.V. Process for the recovery of rhodium
DE10038037A1 (de) * 2000-08-02 2002-04-18 Basf Ag Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen
US6350819B1 (en) 2000-10-27 2002-02-26 Union Carbide Chemicals & Plastics Technology Corporation Dendritic macromolecules for metal-ligand catalyzed processes
US6437192B1 (en) 2000-11-17 2002-08-20 E. I. Du Pont De Nmeours And Company Hydroformylation of conjugated dienes to alkenals using phosphonite ligands
US6362354B1 (en) 2000-11-17 2002-03-26 E. I. Du Pont De Nemours And Company Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same
US7012098B2 (en) * 2001-03-23 2006-03-14 Pharmacia Corporation Inhibitors of inducible nitric oxide synthase for chemoprevention and treatment of cancers
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DE10140083A1 (de) * 2001-08-16 2003-02-27 Oxeno Olefinchemie Gmbh Neue Phosphitverbindungen und deren Metallkomplexe
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US6660876B2 (en) 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
MY138064A (en) * 2002-01-24 2009-04-30 Basf Ag Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
KR20050059051A (ko) * 2002-08-02 2005-06-17 파마시아 코포레이션 위장 증상의 치료 및 예방 방법
US6664427B1 (en) 2002-08-29 2003-12-16 E. I. Du Pont De Nemours And Company Process for preparing aldehyde compounds
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JP2015536303A (ja) * 2012-10-12 2015-12-21 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ ビスホスフィットの混合物及びヒドロホルミル化における触媒混合物としてのその使用
JP2015218172A (ja) * 2014-05-20 2015-12-07 エボニック インダストリーズ アクチエンゲゼルシャフトＥｖｏｎｉｋ Ｉｎｄｕｓｔｒｉｅｓ ＡＧ カーボネート基を有する、新規モノホスファイト配位子

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CS275474B2 (en) 1992-02-19
EP0214622A3 (en) 1988-05-18
AR242182A1 (es) 1993-03-31
CA1281704C (en) 1991-03-19
FI863570L (fi) 1987-03-06
PL152601B1 (en) 1991-01-31
PL261286A1 (en) 1987-12-14
CS8807490A3 (en) 1992-02-19
CN1007348B (zh) 1990-03-28
DE3685276D1 (de) 1992-06-17
CN86106811A (zh) 1987-04-29
AU6237386A (en) 1987-03-12
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MX164384B (es) 1992-08-10
ATE76054T1 (de) 1992-05-15
KR870003042A (ko) 1987-04-14
HUT46642A (en) 1988-11-28
CN1021202C (zh) 1993-06-16
NO167652C (no) 1991-11-27
CN1041761A (zh) 1990-05-02
US4769498A (en) 1988-09-06
NO863546D0 (no) 1986-09-04
FI88916B (fi) 1993-04-15
CS275462B2 (en) 1992-02-19
US4668651A (en) 1987-05-26
YU46024B (sh) 1992-12-21
YU155086A (en) 1988-02-29
NO863546L (no) 1987-03-06
EP0214622A2 (en) 1987-03-18
EP0214622B1 (en) 1992-05-13
ZA866728B (en) 1987-04-29
KR910009181B1 (ko) 1991-11-04
JPH0451531B2 (enExample) 1992-08-19
DK423486A (da) 1987-03-06
DK423486D0 (da) 1986-09-04
FI863570A0 (fi) 1986-09-04
IN168034B (enExample) 1991-01-26
CS8606430A3 (en) 1992-02-19

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