YU46024B - Postupak za dobijanje aldehida hidroformilovanjem olefina u prisustvu katalizatora - Google Patents

Postupak za dobijanje aldehida hidroformilovanjem olefina u prisustvu katalizatora

Info

Publication number
YU46024B
YU46024B YU155086A YU155086A YU46024B YU 46024 B YU46024 B YU 46024B YU 155086 A YU155086 A YU 155086A YU 155086 A YU155086 A YU 155086A YU 46024 B YU46024 B YU 46024B
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YU
Yugoslavia
Prior art keywords
hydrogen
radical
bar
group
carbon monoxide
Prior art date
Application number
YU155086A
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English (en)
Other versions
YU155086A (en
Inventor
E. Billig
A.G. Abatjoglou
D.R. Bryant
Original Assignee
Union Carbide Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corporation filed Critical Union Carbide Corporation
Publication of YU155086A publication Critical patent/YU155086A/xx
Publication of YU46024B publication Critical patent/YU46024B/sh

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

POSTUPAK ZA DOBIJANJE ALDEHIDA HIDROFORMILOVANJEM OLEFINA U PRISUSTVU KATALIZATORA, naznacen time, sto nezasiceno olefinsko jedinjenje odabrano iz grupe koju sacinjavaju alfa-olefini sa 2-10 ugljenikovih atoma, unutrasnji olefini sa 4-10 ugljenikovih atoma i smese ovih alfa-olefina i unutrasnjih olefina, kao sto su buten-1, buten-2, izobutilen i propilen, reaguje sa ugljenmonoksidom i vodonikom u prisustvu slobodnog polifosfitnog liganda i katalizatora koji se sastoji od rodijuma kompleksiranog sa ugljenmonoksidom i polifosfitnim ligandom, pri cemu su identicni ili razliciti ligandi odabrani iz grupe koju sacinjavaju ligandi sledecih formula: gde: Q je -CR1R2 tako sto svaki R1 i R2 radikal pojedinacno predstavlja radikal odabran iz grupe koju sacinjavaju vodonik, alkil sa 1 do 6 ugljenikovih atoma, fenil, tolil, anizil; n je nula ili jedan; Y1, Y2, Z2 i Z3 grupa pojedinacno predstavlja identican ili razlicit radikal odabran iz grupe koju sacinjavaju vodonik, alkil radikal sa 1 do 8 ugljenikovih atoma, odnosno alkoksi radikal pri cemu je narocito pogodan t-butil odnosno metoksi radikal; W je 1,4-naftilen, 1,5-naftilen, alkilen posebno etilen, ili supstituisani fenilen-(Q)n-fenilen u kome Q predstavlja metilen (-CH2-) ili alkiliden (-CHR2-) grupu, gde je R2 alkil radikala posebno metil kao sto je -CHCH3-; i m ima vrednost od 2 do 6, pozeljno 2 do 4, a najbolje 2; i sto se reakcija hidroformilovanja vrsi na temperaturi od 50 -120° C, pri ukupnom pritisku vodonika, ugljenmonoksida i nezasicenog olefinskog organskog jedinjenja od oko 0,0689 do 103,35 bara, pri parcijalnom pritisku vodonika od oko 1,0335 bara do ko 11,024 bara, i pri parcijalnom pritisku ugljenmonoksida od oko 0,0689 do oko 8,268 bara, pri cemu reakciona sredina sadrzi oko 4 do oko 100 molova pomenutog polifosfitnog liganda po molu rodijuma u sredini.
YU155086A 1985-09-05 1986-09-04 Postupak za dobijanje aldehida hidroformilovanjem olefina u prisustvu katalizatora YU46024B (sh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/772,859 US4668651A (en) 1985-09-05 1985-09-05 Transition metal complex catalyzed processes

Publications (2)

Publication Number Publication Date
YU155086A YU155086A (en) 1988-02-29
YU46024B true YU46024B (sh) 1992-12-21

Family

ID=25096469

Family Applications (1)

Application Number Title Priority Date Filing Date
YU155086A YU46024B (sh) 1985-09-05 1986-09-04 Postupak za dobijanje aldehida hidroformilovanjem olefina u prisustvu katalizatora

Country Status (22)

Country Link
US (2) US4668651A (sh)
EP (1) EP0214622B1 (sh)
JP (1) JPS62116535A (sh)
KR (1) KR910009181B1 (sh)
CN (2) CN1007348B (sh)
AR (1) AR242182A1 (sh)
AT (1) ATE76054T1 (sh)
AU (1) AU597593B2 (sh)
BR (1) BR8604261A (sh)
CA (1) CA1281704C (sh)
CS (2) CS8807490A3 (sh)
DE (1) DE3685276D1 (sh)
DK (1) DK423486A (sh)
ES (1) ES2001416A6 (sh)
FI (1) FI88916C (sh)
HU (1) HU204489B (sh)
IN (1) IN168034B (sh)
MX (1) MX164384B (sh)
NO (1) NO167652C (sh)
PL (1) PL152601B1 (sh)
YU (1) YU46024B (sh)
ZA (1) ZA866728B (sh)

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IN168034B (sh) 1991-01-26
HUT46642A (en) 1988-11-28
CN1007348B (zh) 1990-03-28
AU6237386A (en) 1987-03-12
CN86106811A (zh) 1987-04-29
CS275462B2 (en) 1992-02-19
ATE76054T1 (de) 1992-05-15
CS275474B2 (en) 1992-02-19
MX164384B (es) 1992-08-10
DK423486A (da) 1987-03-06
HU204489B (en) 1992-01-28
CN1021202C (zh) 1993-06-16
US4769498A (en) 1988-09-06
AU597593B2 (en) 1990-06-07
JPH0451531B2 (sh) 1992-08-19
CS8606430A3 (en) 1992-02-19
JPS62116535A (ja) 1987-05-28
ES2001416A6 (es) 1988-05-16
BR8604261A (pt) 1987-05-05
CA1281704C (en) 1991-03-19
CN1041761A (zh) 1990-05-02
AR242182A1 (es) 1993-03-31
PL261286A1 (en) 1987-12-14
NO167652B (no) 1991-08-19
EP0214622B1 (en) 1992-05-13
FI863570A (fi) 1987-03-06
YU155086A (en) 1988-02-29
ZA866728B (en) 1987-04-29
CS8807490A3 (en) 1992-02-19
NO863546D0 (no) 1986-09-04
DK423486D0 (da) 1986-09-04
NO863546L (no) 1987-03-06
KR910009181B1 (ko) 1991-11-04
KR870003042A (ko) 1987-04-14
PL152601B1 (en) 1991-01-31
DE3685276D1 (de) 1992-06-17
NO167652C (no) 1991-11-27
US4668651A (en) 1987-05-26
EP0214622A2 (en) 1987-03-18
FI863570A0 (fi) 1986-09-04
FI88916C (fi) 1993-07-26
EP0214622A3 (en) 1988-05-18
FI88916B (fi) 1993-04-15

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