YU45798B - Postupak hidroformilovanja za dobijanje aldehida - Google Patents

Postupak hidroformilovanja za dobijanje aldehida

Info

Publication number
YU45798B
YU45798B YU154986A YU154986A YU45798B YU 45798 B YU45798 B YU 45798B YU 154986 A YU154986 A YU 154986A YU 154986 A YU154986 A YU 154986A YU 45798 B YU45798 B YU 45798B
Authority
YU
Yugoslavia
Prior art keywords
group
hydrogen
radical
butene
radicals
Prior art date
Application number
YU154986A
Other languages
English (en)
Other versions
YU154986A (en
Inventor
E. Billig
A.G. Abatjoglou
D.R. Bryant
Original Assignee
Union Carbide Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corporation filed Critical Union Carbide Corporation
Publication of YU154986A publication Critical patent/YU154986A/xx
Publication of YU45798B publication Critical patent/YU45798B/sh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
    • C07F9/10—Phosphatides, e.g. lecithin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

POSTUPAK HIDROFORMILOVANJA ZA DOBIJANJE ALDEHIDA, naznacen time, sto obuhvata kontinualno katlizovanje u reciklovanju olefinskog nezasicenog organskog jedinjenja iz grupe koju cine alfa olefini sa 2 do 20 atoma ugljenika, unutrasnji olefini sa 4 do 20 atoma ugljenika i smese takvih olefina i unutrasnjih olefina, sa ugljen monoksidom i vodonikom, u prisustvu kompleksnog katalizatora koji se sastoji od prelaznog metala iz grupe VIII, kao sto je rodijum, kompleksiranog sa ugljen monoksidom i bis-fosfitnim ligandom formula pri cemu svako Q pojedinacno predstavlja divalentnu premoscenu grupu izabranu iz grupe koju cine -CR1R2-, -O-, -S-, pri cemu svaki R1 i R2 radikal pojedinacno predstavljaju radikal izabran iz grupe koju cine vodonik, C1-C4 alkil, pri cemu svako n pojedinacno ima vrednost 0 ili 1, pri cemu svaki radikal Y1, Y2, Y3, Y4, Z2, Z3, Z4 i Z5 pojedinacno predstavlja radikal izabran iz grupe koja se sastoji od vodonika, C1-C10 alkil radikala, fenil, halogen, hidroksi, oksikarbonil, sulfinil, sulfonil, C1-C4 alkoksi radikala, pri cemu svaka Z grupa pojedinacno predstavlja identicni ili razliciti radikal izabran iz grupe koja se sastoji od nesupstituisanih C1-C4 alkil radikala i aril radikala formule u kojoj svaki X1, X2 i X3 radikal pojedinacno predstavlja radikal izabran iz grupe koja se sastoji od vodonika, C1-C10 alkil radikala, halogen, hidroksi, amido, sulfinil, C1-C4 alkoksi radikala, pri cemu se reakcija izvodi na temperaturi od oko 50 do 120 C, ukupnom pritisku vodonika, ugljen monoksida i olefinski nezasicenog organskog jedinjenja od oko 0,0689 do oko 103,35 bara, parcijalnom pritisku vodonika od oko 1,033 do oko 11,024 bara, parcijalnom pritisku ugljenmonoksida od oko 0,0689 do oko 8,268 bara, pri cemu reakciona sredina sadrzi od oko 4 do oko 100 molova bis-fosfitnog liganda po molu rodijuma u reakcionoj sredini. 2. Postupak prema zahtevu 1, naznacen time, sto olefinska polazna materija je olefin izabran iz grupe koju cine 1-buten, 2-buten i smesa koja se sustinski sastoji od 1-butena i 2-butena.
YU154986A 1985-09-05 1986-09-04 Postupak hidroformilovanja za dobijanje aldehida YU45798B (sh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/772,891 US4748261A (en) 1985-09-05 1985-09-05 Bis-phosphite compounds

Publications (2)

Publication Number Publication Date
YU154986A YU154986A (en) 1988-06-30
YU45798B true YU45798B (sh) 1992-07-20

Family

ID=25096548

Family Applications (1)

Application Number Title Priority Date Filing Date
YU154986A YU45798B (sh) 1985-09-05 1986-09-04 Postupak hidroformilovanja za dobijanje aldehida

Country Status (24)

Country Link
US (1) US4748261A (sh)
EP (1) EP0213639B1 (sh)
JP (2) JPS62116587A (sh)
KR (1) KR930001327B1 (sh)
CN (1) CN1019104B (sh)
AR (1) AR242218A1 (sh)
AT (1) ATE64739T1 (sh)
AU (1) AU598749B2 (sh)
BR (1) BR8604262A (sh)
CA (1) CA1271773A (sh)
CZ (2) CZ284301B6 (sh)
DE (1) DE3679945D1 (sh)
DK (1) DK423086A (sh)
ES (1) ES2001654A6 (sh)
FI (1) FI85863C (sh)
HU (1) HU204747B (sh)
IN (1) IN168017B (sh)
MX (1) MX3655A (sh)
NO (1) NO172494C (sh)
PL (1) PL147093B1 (sh)
SK (2) SK642986A3 (sh)
SU (1) SU1537133A3 (sh)
YU (1) YU45798B (sh)
ZA (1) ZA866729B (sh)

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US4748261A (en) 1988-05-31
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